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By P. Somasundaran, D. W. Fuerstenau

Adsorption isotherms for dodecyl sulfonate on alumina were determined at 45°C and 25°C and the data was used for calculating the partial molar heat and entropy of adsorbed ions under various concentrations. Changes in OH and AS observed at certain concentrations agree with the postulate of interaction of surfactant ions to form two-dimensional aggregates at the solid-liquid interface. Values of the total OH and AS for the aggregation process calculated using the Clausius-Clapeyron equation is used to interpret the interactions of surfactant ions with each other as well as with the solvent molecules.

Jan 1, 1973

By J. O. G. Posada

Magnesium derived foams were prepared by using the so-called baking of powder blended precursor material method. This method comprises mixing magnesium powder with a small fraction of blowing agent (ZrH2, Cs2CO3 and CaH2) and Ni like catalyst, compacting this mix and creating a foam by heat treatment above the magnesium melting temperature. The resulting samples were characterised by microscopy, gas adsorption (BET method) and by small angle neutron scattering. Several mathematical models were used in order to determine particle size distribution, fractal dimension and total pore volume fractions.

Jan 1, 2005

Discussion, at the Virginia Beach Meeting, February, 1894, of the Paper of Prof. Posepny. (Trans., xxiii., 197, 587.) Including communications subsequently received. a T. A. Rickard, Denver, Colorado (communication to the Secretary) : The paper of Professor Posepny was printed so short a time

Jan 1, 1895

By W. S. Sadik

This paper presents the ventilation design for an underground testing facility in a salt medium. The underground workings consist of two-12 ft. (3.66 m) diameter watertight shafts and approximately 6000 ft. (1830 m) plus of drifting. These facilities are designed for the purpose of providing access for an in-situ testing of a salt horizon in which a variety of hazardous and non-hazardous materials could be temporarily stored or permanently deposited. The ventilation system includes a design basis for gassy mine conditions and provides for the option of bulk air cooling and heating.

Jan 1, 1988

By AIME AIME

ONE hundred and eighty-three A.I.M.E. members, W. S. Morris with an excellent technical program, John Suman, "oil" President of the Institute, and a Texas norther blew into Dallas for the fall meeting of the Petroleum Division at the Adolphus Hotel, Oct. 16-18. and the most successful result will give future meeting committees a high mark to equal. People were still talking of the terrific heat the week before and it was quite noticeable that with the lowered temperatures, the members were in fine fettle for the technical sessions. The total attendance on Friday noon was

Jan 1, 1941

By Geza Kisvarsanyi

Ore deposits composed of enargite, tennantite, gold, and pyrite have been mined in volcanic rocks of Oligocene age (35 m.y.) at Recsk, Hungary. Vertical and horizontal zoning of the alunitic-argillic alteration and of the ore minerals led to the concept of an intrusive heat source at depth. Subse-quent drilling disclosed a series of ore deposits in a zoned pattern in and around a stock, separated by a barren gap of 1000 meters from the shallow ore. The ore system is in a intracaldera horst-graben structure, formed by collapse and intrusion in a microplate subduction. volcanic-arc tectonic environment.

Jan 1, 1987

By F. W. Hoertel

Near-optimum parameters were determined by the Bureau of Mines for vapor deposition of rhenium on heated copper substrates by hydrogen reduction of rhenium hexafluoride (ReF6). High-purity deposits of nearly 90-percent theo¬retical density were obtained with the reaction chamber at 250° C, with an H2 to ReF6 volume ratio of 25 to 1, and with an ReF6 flow rate of 5 grams per hour. Some rhenium deposited as a loose, black powder. When the established near-optimum parameters were carefully followed, this could be minimized but never completely avoided. Varying the reaction chamber pressure, both above and below atmospheric, yielded excessive quantities of rhenium powder. Deposition efficiencies, based on only the coherent metal, ranged between 70 and 75 percent. Massive deposits contained only spectrographic traces of impurities. The average microhardness (Knoop, 100-gram load) of vapor-deposited rhenium was 907. Limited research on the deposition of rhenium-tungsten alloys by reduction of the mixed hexafluorides produced deposits in which linear composition gradients were pronounced; this nonhomogeneity was attributed to the wide variation in optimum hydrogen-reduction temperatures of the two hexafluorides (250° C for ReF6 and 550° C for WF6). Using deposition temperatures between 250° and 550° C did not eliminate the composition variations.

Jan 1, 1967

By R. J. Roman

The "mass balance" is unquestionably the most common class of problems for the process engineer'. Closely related, mathematically, is the "heat balance". Every laboratory test requires a mass balance to describe the results. Mass balance calculations can be subdivided into several sub-categories based on whether the results are time dependant or not and depending on whether the input data are measurements that contain errors or are hypothetical values with no errors. Time dependent mass balances are dynamic process simulations and in addition to the conservation of mass constraints require kinetic data input. They are one step beyond simple mass balances.

Jan 1, 1992

By K. A. Clark

A meeting between representatives of the Scientific and Industrial Research Council of Alberta and the Deputy Minister of Mines for Canada was held at Edmonton in May, 1929, for the purpose of formulating a co-operative plan for carrying forward studies in aid of the development of commercial methods for utilizing the bituminous sands of Alberta. It was agreed that to the Alberta Research Council should be allocated the general problem of investigation of the processes for the separating of bitumen from the sands, including studies of methods of emulsifying, dehydrating and otherwise preparing separated bitumen for industrial applications. It was further agreed that during the present year the work of the Alberta Research Council should be to continue its laboratory investigations of points of design of its separation plant; to further perfect its separation procedure; to recondition its existing separation plant at Dunvegan Yards, Edmonton, in the light of laboratory studies and to operate it for the purpose of demonstrating its efficiency; to carry on tests in emulsifying and dehydrating or otherwise preparing separated bitumen for industrial application; and on the basis of the experience gained in the operation of the preliminary plant at Dunvegan Yards to prepare and design and, as far as possible, to proceed with the erection of, a semi-commercial separation plant at a site to be chosen, probably at the bituminous sand deposits near McMurray, Alberta. This paper presents, in the main, a progress report of the carrying out of this programme.

Jan 1, 1929

By G. Folmo

Allis Mineral Systems' GRATE-CAR agglomeration/induration/reduction process is currently being operated to process ilmenite at Tinfos Titan & Iron KS in Tyssedal, Norway. In this process, balled ilmenite concentrate is fed to a traveling grate where pellets are dried and preheated, using fully oxidized kiln exhaust gas. Hot preheated, semi-indurated pellets are fed directly to a ported kiln where reduction of the ilmenite's iron oxide fraction occurs in the presence of lump coal. The reduced pellet sand coal char are discharged from the kiln to an indirect rotary drum cooler. Cooled pellets and char are screened and magnetically separated prior to their further processing in a downstream smelting operation. The pellets are melted and the titanium dioxide and iron are separated. Operation commenced in late 1986.

Jan 1, 1992

By F J. Kelly

A chemical process, based on laboratory investigations, is proposed for the production of high-purity niobium oxide from a pyrochlore-perovsk1te flotation concentrate produced from ore obtained at the Oka, Quebec property of Columbium Mining Products Limited. The method developed included the decomposition and dissolution of the flotation concentrate with hot, concentrated sulphuric acid. The dissolved niobium was purified and concentrated by a solvent extraction step, using methyl isobutyl ketone as the extractant. The niobium was recovered from the extractant with ammonium fluoride solution from which niobium oxide was precipitated with ammonia. Finally, the filtered and washed precipitate was calcined. Ninety-six per cent of the niobium was recovered in a product analysing 99.9 per cent Nzo.. The reagent cost was in the range of $1.00 to $1.25 per pound of niobium recovered. Introduction OVER the past few years, Columbium Mining Products Limited has been engaged in the development of a niobium-bearing mineral deposit in the vicinity of Oka, Quebec. One phase of this program resulted in a flotation process capable of producing concentrates containing up to 50 per cent Nb205? Flotation pilot-plant

Jan 1, 1965

Novel techniques were developed to obtain samples from and make measurements in the shaft of the flash furnace at the Kalgoorlie Nickel Smelter. The data obtained was used to validate mathematical models of the burners and the reaction shaft. Particle, gas and wall temperatures were measured along with the oxygen potential of the molten particles. Collected particles were characterised by sizing, chemical analysis and optical microscopy. The region of the shaft immediately beneath the burner where the rate of change was most rapid received special attention.

Jan 1, 1993

By G. Cailletaud, I. Guillot, D. Larouche, R. Martinez, D. Massinon

The precipitation of Al2Cu particles in a 319 T7 aluminum alloy has been modeled. A theoretical approach enables the concomitant computation of nucleation, growth and coarsening, based on an implicit scheme using the finite differences. The equation of continuity is discretized in time and space in order to obtain a matricial form. The inversion of a tridiagonal matrix allows us to determine the evolution of the size distribution of Al2Cu particles at t + dt. The fluxes of solute in-between the boundaries, as well as the ones at the boundaries, are computed in order to respect the conservation of the mass of the system. The main results of the model are compared to TEM measurements. Simulations provide quantitative features on the impact of the cooling rate on the size distribution of Al2Cu particles in good agreement with the TEM measurements. This metallurgical model is integrated into FEA software in order to perform mechanical computations. This kind of multiscale approach allows new perspectives to be investigated in the process of designing cylinder heads. It enables a more precise prediction of the microstructure, its evolution as a function of continuous cooling rates and its impact on the integrity of the structure.

Jan 1, 2015

By T. M. Chagwedera, A. E. Lewis, J. Chivavava

Eutectic freeze crystallisation is a novel separation technique that can be applied to treat brine solutions such as reverse osmosis retentates, which are often a mixture of different inorganic salts. The treatment of calcium sulphate-rich brine solutions through eutectic freeze crystallisation has resulted in gypsum scale formation on the walls of the crystallisers and ancillary equipment. In order to prevent gypsum scaling on equipment surfaces, it is essential to understand the mechanism of gypsum scaling on cold surfaces. This paper focused on the interaction between gypsum crystallisation in the bulk solution and scaling on the crystalliser walls in the presence of gypsum seeds. A cooled, U-shaped stainless-steel tube suspended in the saturated solution was employed as the scaling surface. Preliminary results showed that the scale layer was predominantly composed of needle-type and hexagonal prismatic crystals. The rate of scale deposition was highest during the first 24 hours, thereafter it decreased. A thin scale layer was observed to have coated the tube within the first hour of the experiment. Seeding, using reagent grade gypsum crystals, was effective in reducing scale layer formation through providing a surface for growth. The highest scale reduction, 81%, was realised at a seed loading of 0.50 g/L. At a high seed loading of 4.01 g/L, the seed material adhered to the tube. Keywords: Gypsum, eutectic freeze crystallization, seeding, scaling, cooling crystallisation

Jan 1, 2020

By João Paulo Meneguelli Campos

O objetivo deste trabalho foi validar o modelo proposto por Kasuya et al para prever as durezas máximas da zona termicamente afetada (ZTA) em juntas soldadas de um aço com médio teor de carbono através de ensaios empíricos. Para isto, se faz necessário o cálculo da energia de soldagem, quando foram testados modelos apresentados por Marques e Modenesi e também o modelo proposto por Perdigão. As juntas soldadas foram produzidas usando chapas de aço SAE 1045 com espessura de 12,7 mm como material base, chanfro de 70º e arame sólido do tipo ER70S-6. Para mudar as condições de resfriamento das juntas soldadas, foram testadas variações nos parâmetros de soldagem, tais como: energia de soldagem, taxa de resfriamento e temperaturas de pré-aquecimento e interpasses. Foram feitos experimentos com e sem pré-aquecimento e testados pós-aquecimento e alívio de tensões. As amostras da zona fundida e da ZTA tiveram as durezas medidas e foram analisadas por meio de microscopia eletrônica de varredura. Em linhas gerais, os resultados empíricos para a dureza na ZTA seguem a mesma tendência prevista pelo modelo de Kasuya et al, mas observam-se desvios na proporcionalidade validando a equação parcialmente para o material estudado. Também foi possível constatar que para o cálculo da energia de soldagem são adequados os modelos propostos por Perdigão e Marques e Modenesi.

Aug 17, 2017

By Huaqing Xie, Qingbo Yu, Qin Qin

A novel sorption-enhanced steam reforming (SESR) process of hot coke oven gas (HCOG) was proposed for tar removal and H2 amplification, and was studied with the comparison of conventional steam reforming (SCR) process. Both of the processes could remove tar effectively and improve the H2 amount in the COG obviously. For CSR process, after the temperature and the S/HCOG ratio reached 700 °C and 2.4 respectively, the H2 amplification factor kept 4.30 around, with its concentration less than 75%. However, for SESR process, the H2 amount and concentration get improved further, with the optimal temperature moving toward low temperature. At 600 °C and the S/HCOG ratio of 2.4, the H2 amplification factor and concentration could reach 4.91 and 97.55% respectively when the CaO/C ratio was 2.0. Under the respective optimal reforming conditions of the two processes, the energy consumption of the SESR process was lower than that of CSR process.

Mar 1, 2018

By D. P. Lindroth

The thermal diffusivity above 298 K, up to 400 K and at pressures from ambient down to 10-10 torr was measured for the following six igneous rock types: tholeiitic basalt, obsidian, rhyolite, granodiorite, gabbro, and dunite. The thermal diffusivity data were obtained by the laser flash method. Extreme values range from a low of 5.3X10-3 cmF/sec for rhyolite at 383 K and 2X10-7 torr to a high of 13.4x10-3 crrf/sec for dunite at 298 K and 760 torr. Data are also included on a commercial fused silica, which was used as a standard.

Jan 1, 1974

By A. D. Dalvi

Economics, Resources, Environment and Technology are the major driving forces in the base metals industry. However, these factors are intertwined and together will propel the industry in the future. The demand for metals has grown with economic expansion, between 2 to 4 % p.a. The current growth cycle has been driven by economic expansion in China where the demand for base metals has risen from - 7 % of the world demand in the 90's to - 25 % of world demand today, and rising. Base metals are commodities and their demand and price are cyclical. Historically metal prices have declined in constant dollars, forcing the industry to reduce costs, increase productivity and increase the scale of operation for economies of scale. Due to resource depletion and capacity expansion the industry is driven to expand its reserve and resource base. However, in the case of sulphide deposits of copper and nickel it appears to be a losing battle. For nickel the laterites represent a vast source at this time. Their development requires development of new technologies to make these resources economic. Emission reduction is being increasingly mandated in most jurisdictions with all governments enacting progressively more stringent regulations. The industry has been responding with technological innovation. With the Kyoto protocol there is a push to reduce energy intensity in metal production. Technological innovation is driven by all the other factors and is leading to novel ways of doing exploration, mining and processing, that would maximize resource delineation and utilization, reduce costs, increase productivity, reduce energy consumption, maximize asset utilization and reduce environmental affects. Development of alternative technologies such as Pressure Acid Leach of laterite for nickel, bio-leaching, heap leaching, SX-EW etc are being adopted to achieve the aims of the industry.

Jan 1, 2005

By P. L. Weston

The Bureau of Mines used high-temperature reduction roasting, magnetic separation, acid-leaching, and autoclave precipitation processes to recover iron and manganese from brown Cuyana range ores of Minnesota. Wet magnetic separation concentrated over 90 percent of the iron in 3 of 4 ores as high grade products analyzing 74 to 85 percent iron, 2.5 to 6 percent manganese, and 3 to 10 percent SiO2. The nonmagnetic fractions were leached with dilute sulfuric acid extracting 83 to 93 percent of the contained manganese and small amounts of iron. The leach solutions contained Mn-to-Fe and Mn-to-SiO2 ratios favorable enough for possible consumption in metallurgical mane operations. Exceptionally pure Mn solutions were achieved by pressure precipitation of the remaining iron in an autoclave followed by lime precipitation of silica and alumina.

Jan 1, 1966

By Hongsheng He, Xiaofang Lv, Jianfeng Wang

This paper provided an overview of characteristics of limonite ores as well as their influence on sintering performance. Evaluation experiments focusing on basic characteristics, granulation characteristics, and high temperature sintering characteristics had been conducted by using two types of limonite ores, then the principles of high effective utilization technology of limonite ores were discussed, and the sintering pot tests were conducted. Limonite ores possessed low total iron content, high combined water content, high SiO2 content, large average particle size, low adhering particles proportion, high porosity, high water absorption rate, short water absorbing time, poor granulation ability, high melt formation ability, low melt fluidity ability, low melt penetration ability, high melt absorption ability, low bonding phase strength, and high forming ability of SFCA. By taking the technical measures of ore-proportioning optimization, increasing the proportion of burntlime and segmentation granulation, the usage of limonite ores could reach 50% in sintering.

Aug 27, 2021