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By Y. A. Topkaya

In this research work, a process was described for the recovery of copper and zinc in copper converter flue dust from the Black Sea Copper Works' Samsun Smelter Plant. After characterization of a representative flue dust sample, the process included roasting of the flue dust and then leaching in dilute sulfuric acid solution. Roasting time and temperature were studied to determine the optimum roasting conditions. Sulphuric acid concentration, duration, temperature of leaching and solid to liquid ratio were the parameters studied in the bench scale laboratory leaching experiments.

Jan 1, 2007

By B T. Qin, C Zhu, Y W. Jia, Y Lu, F L. Li, Q L. Shi

Air leakage through rock fractures in coal mining is a major cause of coal spontaneous combustion. In order to overcome the deficiency of the existing fire control technology and prevent coal spontaneous combustion by isolating coal from oxygen, the article proposes a novel technology of inorganic solidified foam (ISF) with high expansion to fill fractures effectively. ISF consists of fly ash, cement, setting accelerator, redispersible polymer powder, water and aqueous foam. For preparing homogeneous and stable ISF, a preparation system with a pore type foam generator, a mixer device installed with a hollow shaft and helical blades, air compressor, slush pump and monitoring instruments was developed, and the working principles of key devices were elucidated. Based on a series of experiments on the different ratios of each component material and technological parameters of the preparation system, ISF with a foam expansion ratio of 8~10 and dry density of 250–400 kg/m3 was prepared. The relationship between elastic compressive strength, modulus of elasticity and density was summarised. Based on the injection experiment for fracture of loose coal pile with high temperature, the characteristics of sealing air leakage, compressive strength, thermal insulation, flow and cooling of ISF in the fresh state were investigated, indicating that ISF can effectively cut off the air leakage and cover the coal sample to reduce the temperature in the earlier stage, and ISF can remain stable and not crack. The ISF was applied to Luwa coalmine to seal small coal pillar pressure fractures and loose coal fractures in goaf. After press-casting the ISF in Luwa coalmine, the pressure-difference of inner-outer increased, meaning the effect of external conditions on the pressure-difference decreased, showing that it could plug the air leakage effectively.CITATION:Qin, B T, Shi, Q L, Lu, Y, Zhu, C, Li, F L and Jia, Y W, 2015. The novel technology of inorganic solidified foam with high expansion for preventing coal spontaneous combustion, in Proceedings The Australian Mine Ventilation Conference, pp 121–126 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By Z. Sun

The hydrogen embrittlement and stress-corrosion cracking (SCC) behavior of an a -titanium alloy and its two kinds of welding samples have been investigated. The results show that this alloy has very low susceptibility to SCC, and the values of Kiscc for the alloy are 46.4 MPa ? m' 65.86 MPa ? mu2 in the direction of T-L and L-T, respectively. The scanning electron fractographs show transgranular and quasi-cleavage fracture. The hydrogen embrittlement results show that the notch sample of the alloy is not sensitive to hydrogen, but the electro-beam welding and diving-arc welding samples are sensitive.

Jan 1, 2005

By Kevin C. Milne

"The solution of problems associated with development of a sour gas reserve will be of increasing importance in tl1e next few years if gas export is approved •by the National Energy Board. The purpose of this paper is to review briefly the history of the Carstairs gas field, and tCI describe in a general manner the reservoir, and the producing and processing facilities.HISTORYThe Carstairs gas field was discovered in April 1958 when the discovery well, Home Carstairs 10-17, was successfully completed as a gas well in the Elkton member of the Turner Valley formation. Geo-graphic location of the field is shown in Figure No. 1. Note that the field is about five miles west of the town of Carstairs, Alberta, which in turn is about 40 miles north of Calgary. Drilling subsequent to the discovery well resulted in three addition-al producing wells and one dry hole during I.958; two producing wells during 1959; and one producing well and one dry hole during 1960. Thus, seven producing wells and two dry holes have been drilled in the Carstairs field to date.In November 1959 a 12-section block in the Carstairs field was unitized on a surface acre basis. Mean-while, in June 1959, operators in the field executed an ""Interim Plant Agreement"" that provided the money needed to start construction of a joint venture processing plant and gathering system. Construction of the plant and gathering system was completed in February 1960."

Jan 1, 1960

By L. Hacini

The start-up is the most critical phase of the cell life, as an uncontrolled start-up could lead to early infiltrations, instabilities, and in some cases to the cell death. Lots of efforts are put to increase the lifespan of cells, as it has a major impact on both the operating costs and the environmental footprint of the aluminum industry. Obviously, a true size test on a cell is a resources- and time-consuming approach that could be used only to validate mature concepts. Moreover, numerical modelling is a low-cost and versatile tool capable to test a wide range of potential ideas and concepts. In the present article, a thermal electrical mechanical slice model is presented. This model describes the preheating and bath periods of a P155 aluminum cell start-up, as used at the Grande Baie smelter. The impact of sodium diffusion and expansion is also included in the model. This model will be useful to study different problematical issues such as the global behaviour of lining materials, shell and cradle deformations during start-up and several start-up scenarios. Such a model will also be able to answer some interrogations regarding early infiltrations and their impact on the lifespan of the electrolysis cell.

Jan 1, 2011

By G. Plascencia, C. López, J. González, D. Jaramillo, M. A. Barrón

Air jet and molten matte interaction within a Peirce - Smith converter is analyzed during the first stages of blowing using Computational Fluid Dynamics (CFD), by means of the Large Eddy Simulation and Reynolds Stress turbulence models. Jet velocities ranging from 5 to 150 mis, which involve the bubbling and open jet regimes, were considered in 2 and in 3-D numerical simulations. As a result of the computer simulations, it was found that low velocities results in gas bubbling in the molten copper, whereas higher gas velocities results in well defined plumes. The consequence of such different behaviours results in an increment in the rate of refractory wear or in copper splashing respectively. The analysis of the results may lead to improve the design of the tuyeres currently used in copper converting. Bottom blowing of air is also explored in this work. Numerical results show a strong non-linear parabolic behaviour of the jet velocity on the average velocity of copper; which means that beyond certain jet velocity, the copper de-accelerates thus reducing its velocity. This may be due to the open nature of the jet, which prevents the momentum transfer from the injected gas to the molten copper.

Jan 1, 2007

By H. J. Heinen

A technique offering promise as a metallurgical processing sequence the recovery of molybdenum (Mo) from the sulfide mineral--molybdenite?was investigated. The method consists of two steps: (1) electrosynthesis of pure dimolybdenum carbide (Mo2C) from molybdenite (MoS2) and (2) interaction of Mo2C and molybdic oxide (MoO3) to produce pure molybdenum metal. Two molten salt systems were satisfactory for electrosynthesizing Mo2C. The first was a mixture of potassium chloride (KCl), potassium fluoride (KY), and sodium metasilicate (Na2SiO3), and the second consisted of sodium fluoride (NaF), KF, sodium tetraborate (Na2B4O7), and sodium carbonate (Na2CO3). Yields up to 0.42 gram of Mo2C per ampere-hour were obtained. The carbide, mixed with monitored amounts of MoO3, was converted to molybdenum metal of 99.9 percent purity by sintering at 1,500° C.

Jan 1, 1965

By W. A. MacDonald, C. M. McGibbon, J. H. Reynolds

This paper traces the development of the Seaboard Power Plant, which plays such an important role in the industrial life of Nova Scotia. It also shows the involvement of the plant in the siting of a heavy water production facility in Cape Breton. The paper concludes with an outline of the new installations which the Nova Scotia Power Commission has undertaken as an extension to the Seaboard Plant.

Jan 1, 1966

By T. Iriyama, Y. Fujita, R. Omatsuzawa, T. Nishio, N. Okochi

Sm-Fe-N hard magnetic materials are good candidates for high performance bonded magnets. Rapid-quenching method should be highly favorable for the fabrication of isotropic magnet powder with high coercivity. We report here the magnetic properties of Sm-Fe-N powders produced by a few kinds of rapid-quenching processes. Sm2Fe17 powders were prepared by gas-atomization (GA), rotating-disk atomization (RDA), or melt-spinning (MS) method. The Sm2Fe17 GA powder had dendritic solidification structure, while the RDA powder had micro crystalline structure with size of 3-5 µm. Coercivities (HcI) of their nitrides were 56 (for GA) and 217 ka/m (for RDA). The H cI of nitrided Sm2Fe17 MS powder with wheel velocity (V5) of 5-20 m/s, which had also microcrystalline structure, was 53 to 509 Wm. These coercivity values are not sufficient for bonded magnet applications. From the study of additive effects, it was found that C, C-Si, C-Ga, or C-Al addition decreased the crystal size of quenched Sm2Fe17 powder. Consequently, high coercivity was obtained; the HcI of nitrided Sm2Fe1C1Si1 MS powder with V5 of 10 m/s was 898 kA/m, and 708 kA/m for the nitrided Sm2Fe15C1Si1 RDA powder. The compression-molded bonded magnet made from Sm2Fe18Si0.1Nx MS powder showed a high (BH)max of 82.7 kJ/m3.

Jan 1, 2000

By C. N. Rosenecker

The power required to circulate a gas-solids suspension was determined using a centrifugal compressor and a closed system. The suspension consisted of 18- to 40-micron glass beads in a mixture of 89 percent N2 and 11 percent CO2 at 20 psig. Solids-to-gas (S/G) ratios w re O to 2.2 lb/lb; gas flow rates were l.2 to 2.5 lb/min. Power requirement was found to follow the relationship hp t = hp(. + l), where hp t = the total power, and hpg = the power required for pure gas.

Jan 1, 1967

By R. L. Brown

The burning sulphide ores in the Sullivan Mine generate sulphur dioxide gases. This paper is concerned with a description of the environmental impact of SO2 on air quality in the mine and on the surface in the vicinity of the mine. As a result of surface caving, SO2 has been able to vent to surface and winds have carried it into one residential area of Kimberley. Monitoring practices are described.

Jan 1, 1977

By M. H. Staia

A Venezuelan ilmenite concentrate has been chlorinated at a temperature of 700" C by carbon tetrachloride. In the experimental rig, built at laboratory level, the direct chlorination process yielded a TiCI, recovery of approximately 85% after 280 minutes processing. The partial pressure of carbon tetrachloride was nearly atmospheric (0.94 atm). Product vapors from the reactor were fractionally condensed in a condenser which was maintained at a temperature of 250°C meanwhile TiCl, vapors were condensed in refrigerated coils at a temperature of -20°C. The concentrate used in this investigation was obtained by applying gravitational and magnetic concentration methods to the black sands. The experimental results have shown the need to asses the influence of the weight ratio of ilmenite to carbon tetrachloride on the resultant products. The equilibrium of the heterogeneous system has been calculated taking into account the initial experimental conditions.

Jan 1, 1995

By Z. Y. Ma, M. D. Liu, Z. Z. Liu, J. K. Zhou

"An optimization method of microwave assisted leaching of copper anode slime was proposed based on Taguchi method. The results showed that the solid-liquid ratio was the most important factor affecting SNR(signal noise ratio) of the copper, tellurium and selenium leaching efficiencies, and its contributions to the copper, tellurium and selenium leaching efficiencies were 58.34%, 55.54% and 60.74%, respectively. Solid-liquid ratio was a significant factor to SNR(copper, tellurium and selenium). Reaction period was a less significant factor to SNR(copper and tellurium) and concentration of sulphuric acid was a less significant factor to SNR(selenium) while microwave power was an non-significant factor, its contributions to the copper, tellurium and selenium efficiencies were 3.22%, 11.73% and 12.73%, respectively. The optimized parameters of the microwave assisted leaching of copper were as follow: microwave power of 500 W, reaction period of 10 min, solid-liquid ratio of 0.10 g·mL-1 and H2SO4 concentration of 1.0 mol·L-1. The optimized parameters of the microwave assisted leaching of tellurium and selenium were as follow: microwave power of 800 W, reaction period of 15 min, solid-liquid ratio of 0.10 g·mL-1 and H2SO4 concentration of 1.0 mol·L-1. The validation experiments under the optimized conditions has been carried out, the copper, tellurium and selenium leaching efficiencies were 98.66%, 84.32% and 64.54%, respectively. INTRODUCTION As important valuable by-products, copper anode slimes are collected from the bottom of the electrolytic bath in the electrolytic copper refining process(Kilic, 2013). The value of the anode slime is determined by the content of rare metals and precious metals(Liu, 2014). Generally, pretreatment of copper anode slime is the first stage of the whole process. The aim of the pretreatment process is to remove Cu, Te and Se etc and enrich the valuable metals. The methods of pretreatment process can be differentiated into: pyrometallurgical processing and hydrometallurgical processing(Amer, 2003). The hydrometallurgical processes are more promising compared to pyrometallurgical processes in terms of cost effectiveness, low energy consumption and environmental concerns(Ranjbar, 2014). However, the disadvantages of the hydrometallurgy process are evident, such as lengthy processing times and low efficiency. Therefore, it is necessary to develop a highly efficient and environmentally friendly pretreatment method."

Jan 1, 2018

By A. B. Young

THERE were produced in this country in 1923 probably in the neighborhood of 12,000 or 13,000 tons of refined and crude arsenic, by far the greater portion coming as a by product of smelting operations. Early this year copper smelters were producing arsenic at the rate of about 425 tons per month and lead smelters at the rate of 7;0 tons per month. During the entire eighteen years prior to 1919, there were produced in the United States only 47,000 tons of arsenic, which amounts to only 25 per cent. of the present output. The great increased demand has come about through the augmented use of arsenates as insecticides and arsenates as weed killers. In an extract from "Mineral Resources of the United States" on "Arsenic in 1922," Messrs. Heikes and Loughlin say, "The minimum possible demand for arsenic in 1923 was estimated at the end of 1922 to be about 13,000 tons, including 2000 tons for plate glass manufacturers, 3000 tons for lead arsenate, 3500 tons for calcium arsenate, 1500 tons for weed killers, 1200 tons for Paris green, 1000 tons for sheep dips and 750 tons for proprietary mixtures. More recent information, however, indicates twice as great a demand for calcium arsenate." The latter has found great use in the last three or four years as a weapon to combat the boll weevil pest of the southern cotton belt. ~t the present writing refined white arsenic is being quoted on the New York market at from 13)d c. to 1455 c. per Ib., while the average price during the eighteen-year period just mentioned was 4.8 c.

Jan 1, 1924

By Jun Chang, Jin-hui Peng, Jing Chen, Li-bo Zhang

The leaching of indium from refractory zinc oxide flue dust(ZOFD) is attempted to utilize microwave sulfating roasting process, followed by water leaching. The ZOFD and roasted product were characterized by XRD and SEM/EDS analysis. The effects of various roasting parameters, such as roasting temperature/duration, the proportion of sulfuric acid, as well as the leaching parameters such as the leaching duration and liquid/solid ratio, were assessed. The results indicate that nearly 97% of indium could be leached under the following conditions: mass ratio of concentrated sulfuric acid to ZOFD to be 0.5, roasting temperature of 150 ℃ and duration of 1.5 hours; while the optimal leaching conditions hold at temperature of 25 ℃ for 1 hour, with 4:1 of liquid/solid ratio. The indium leaching rate by the microwave roasting increased by 8% as compared with the conventional roasting process under identical conditions.

Jan 1, 2015

By Flavio Viana Diniz Soares

Neste trabalho foi avaliada a desnitrogenação ao longo do tratamento no Desgaseificador a vácuo – RH2 da Usiminas, a partir da amostragem de 10 corridas de aço estrutural para chapa grossa de classe de resistência mecânica de 50 kgf/mm2 microligado com nióbio e titânio, de composição química e em condições de processo similares. Foram retiradas amostras de aço nos tempos 0, 5, 10, 15 e 20 minutos de cada corrida. Os dados foram tratados em dois grupos baseado no teor inicial de nitrogênio. Para o grupo de corridas com o teor menor que 39 ppm, não se verificou redução nos valores de nitrogênio após o tratamento no RH. No grupo de corridas com teor de nitrogênio acima de 39 ppm, evidenciou-se uma redução média de 17% do teor de nitrogênio. Além disso, o teor médio final de nitrogênio em ambos os grupos ficaram com diferença de apenas 2 ppm, evidenciando que o desgaseificador a vácuo RH foi eficiente na redução de nitrogênio para teores acima de 39 ppm.

Oct 30, 2017

By José Eustáquio da Silva

Este trabalho mostra a versatilidade e praticidade do uso da metodologia denominada “Método e Aparelho para Avaliar as Propriedades de Coqueificação do Carvão”, metodologia esta desenvolvida e patenteada pelo corpo técnico da SunCoke Energy. Esta técnica tem possibilitado o desenvolvimento de novas misturas de carvões totalmente alinhadas com os dois grandes pilares da Siderurgia mundial: misturas e coque com baixo custo e qualidade adequada. A fidelização com todas as particularidades do processo real de coqueificação faz desta metodologia uma poderosa ferramenta para tomada de decisão na definição de novos blends, como também para a caracterização de carvões dos quais ainda não se conhece seu potencial para produzir um coque de boa qualidade. Diferentemente das tecnologias similares existentes, o “Box Test” da SunCoke Energy tem robustez suficiente para ser reutilizado para até quatro enfornamentos e é capaz de produzir massa suficiente de coque para que sejam realizadas todas as análises para uma perfeita caracterização do coque.

Aug 17, 2017

By Peter Schmäh, Tobias Engel

The E-Power Pipe technology was originally developed for the trenchless installation of protective pipes and pipelines of 10" to 28" diameter, over long distances of more than 4,000 ft. The twostage process combines elements from Horizontal Directional Drilling (HDD) and microtunnelling technology. A microtunnelling boring machine (MTBM) excavates the borehole using a specially designed, temporary jacking pipe. A Rack & Pinion jacking frame pushes the equipment during the pilot bore and pulls in the prefabricated pipe string in a second step. The slurry microtunnelling machine is equipped with a jet pump, creating the so-called AVNS machine type. A new generation of small hard rock cutting wheels complements this considerable achievement for the tunnelling industry

Dec 1, 2022

By Shawn P. Coughlin, Michael A. Schimmenti, Juan Leonardo Tello del Pino

"PROJECT OVERVIEWThe Sistema de Potabilización Área Norte project (Northern Area Purification System) was a major expansion of the potable water system in Buenos Aires Province, Argentina. The aim of the project was to transport and purify raw water from the Paraná River to provide potable water for five communities in the northern part of the province, benefitting up to two million inhabitants. The project was constructed by a joint venture of four South American contractors (“the JV”), and consisted of the following key components:• Treatment Plant: A 16 hectare area was cleared for the construction of a treatment plant to purify 900,000 m3/day of raw water from the Paraná River and distribute it to the surrounding communities.• Bored Tunnel: Nearly 15 km of 3.6 m inner diameter tunnel, ranging from 18 to 22 m below grade, was bored with two EPB tunnel boring machines to draw the raw water from the river. The TBMs started from a central launch shaft and proceeded in opposite directions: Cristina advanced northbound to the Paraná River Intake System, and Liliana advanced southbound to the new treatment plant.• Access & Ventilation Shafts: Five access shafts and eight ventilation shafts were installed along the length of the tunnel. The access shafts were designed to provide entry points for inspection and maintenance of the final tunnel. The five shafts consisted of: one central launch shaft in the middle of the tunnel alignment, one retrieval shaft at each end of the tunnel (Intake and Treatment Plant, respectively), and two intermediate shafts. The intermediate shafts were installed before the TBM passed, with a final liner to be installed afterwards. Access Shaft 3, the intermediate shaft located between the launch shaft and the treatment plant, experienced persistent leaks during initial excavation attempts."

Jan 1, 2016

By B. Kweto, W. Legodi, C. van Buuren, R. F. Sandenbergh

Biooxidation, and especially the BIOX® process, is a viable, economical and environmentally attractive process to liberate gold hosted in refractory sulfides by oxidatively leaching the sulfides as soluble sulfates. The moderate to high cyanide consumption during the subsequent cyanidiation of the washed biooxidation residue is probably caused by the retention on the solids of labile sulfur species formed during the multi-electron oxidation process of sulfide to sulfate. In this work the nature and mode of transport of the cyanicides in the products from the mesophile BIOX® process, as well as that of the combined mesophile and thermophile bioxidation process, were considered and strategies to reduce cyanide consumption evaluated. It was found that labile sulfur species were the major cyanide consumers in the mesophile biooxidation product, forming predominantly thiocyanate during cyanidation. The transfer of labile sulfur species was only marginally decreased by more intensive and thorough washing of the biooxidation products with warm and hot water, intense stirring and warm caustic leaching. A major reduction in cyanide consumption was however achieved by using a combined mesophile and thermophile biooxidation process. Keywords: Biooxidation, refractory sulfide gold ores, cyanide consumption

Jan 1, 2020