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By Vera Lúcia Othéro de Brito

Literature has shown that spinel Co-Mn ferrite have potential application in magneto-mechanical sensors, due to its relatively high magnetoelastic sensitivity. In this work, Co-Mn ferrite was processed by means of the ceramic method, using Fe2O3, MnO and Co3O4 as raw materials. Samples were liquid-phase sintered, using Bi2O3 additive as liquid-phase former. X-ray fluorescence analysis was carried out in the raw materials in order to evaluate their impurity content. Atomic absorption spectrometry analysis was used for quantifying the Co/Mn/Fe proportion in the ferrite. The microstructure of the sintered sample was analyzed by means of Scanning Electron Microscopy. The magnetization and magnetostrictive behavior of the ferrite were evaluated, obtaining curves for magnetic hysteresis, magnetostriction and magnetoelastic sensitivity. The impurity inclusions and the Bi-rich particles formed from the liquid phase were characterized. The sintered ferrite had a total magnetostriction of -126ppm, which is lower than the values reported in literature for a Co-Mn ferrite of similar composition. It was verified that sintering was carried out within a critical temperature range, in which the decomposition of Mn ferrites may occur when sintering in air. This decomposition affects the magnetic properties of the material, and it may be avoided by using controlled sintering atmospheres.

Aug 8, 2018

By Dae Jin Ha

Sticking phenomenon occurring during hot rolling of two STS 430JlL ferritic stainless steels was analyzed by hot-rolling simulation tests. The sticking started from the initial nucleation stage in which the rolled materials were stuck onto the roll specimen surface, proceeded to the growth stage in which stuck fragments grew further, and reached the saturation stage. The modified 430JlL steel had a smaller number of sticking nucleation sites and slower growth rate than the conventional 430JlL steel because of higher high temperature hardness, thereby leading to less serious sticking. When the simulation test was conducted at 1070 °c, Cr oxides were formed on the surface of the rolled materials, and thus the sticking was drastically reduced because of the increased surface hardness of the rolled materials. In order to prevent the sticking, high-temperature properties of the rolled materials should be enhanced when rolled at 900°C or 1000 °C, and rolling conditions and alloying compositions, under which the oxide formation was promoted, were more important than high-temperature properties when rolled at higher temperatures than 1000 oC.

Jan 1, 2008

By Bora Derin

This work deals with the recovery of valuable metals from the ancient copper smelting slags located in Küre-Turkey. In this process, copper and cobalt were recovered in metallic form and/or as their compounds, whereas iron was recovered as magnetic oxide or pigment. Abrasive grit material was produced using reduced final slag. The process stages involved carbothermal reduction in a DC arc furnace, granulation, leaching, chemical precipitation, selective sulfidizing roasting and product preparations. In this paper, the process stages were described as theoretically and experimentally whereas slag and products were characterized in detail.

Jan 1, 2003

By R. G. S. Mussi

An inclined cooling plate is utilized as a modification in the compocasting process of magnesium alloy and the mechanical properties of the composites obtained are studied in this work. Based on crystal separation theory, molten AZ91D is poured onto an inclined plate in order to produce solidification nuclei inside the fluid metal, and is mechanically stirred while reinforcement is added. Particulate SiC was utilized as reinforcement in quantities varying from 0 to 15%vol. Dispersion of the reinforcement was observed by macro and microstructure analysis. SiC was properly mixed into matrix until 15%vol., and Vickers hardness tests were carried out for the composites produced. Results obtained for hardness were shown to increase with reinforcement addition and comparable to those of traditional compocasting. Utilization of Inclined Cooling Plate produced good inclusion and homogenization of SiC through an AZ91D matrix, at lower temperatures and shorter times than traditional compocasting.

Jan 1, 2006

By Andrzej Warczok

Liquid slags produced in smelting of copper concentrates contain copper in a dissolved form as well as mechanically entrained inclusions of copper matte. Coalescence and sedimentation of inclusions during slag cleaning plays a key role in copper recovery. Liquid matte inclusion in a molten slag presents a system of metallic conductor in an ionic solution. Constant electric field induces migration of the matte droplet along the current lines. Additional phenomena occur in a system under crossed electric and magnetic fields. Electromagnetic buoyancy force acting on the inclusion affects its settling rate. Electromagnetic buoyancy force of insulating and metal spheres has been measured in a liquid synthetic slag. It was found that depolarisation of the metal sphere, related to the electrode reactions occurring in the surface, plays an important role in the determination of the direction and magnitude of the electromagnetic force. On the basis of the existing theories and results of measurements a mathematical model describing the behaviour of metallic inclusions in the liquid slag under the influence of crossed electric and magnetic fields was developed. Simulation of behaviour of copper matte inclusions under crossed fields showed trajectory of motion in a liquid slag as a function of the slag properties and the inclusion size.

Jan 1, 2003

By E. Burdukova

Long-chain primary amines are utilized as collectors in potash ore flotation. Krafft temperature of long-chain amines in brine is about 100 °C, and this makes such amines practically insoluble in brine at room temperature. When dodecylamine, melted at 70 °C and dispersed in hydrochloric acid (or acetic acid) aqueous solution, is added to a KCl-NaCl saturated brine at room temperature, the amine precipitates. The experimental results demonstrate that the precipitating amine hydrochloride particles are selectively abstracted by KCl particles, but not by NaCl particles.

Jan 1, 2009

By Bhagyadhar Bhoi, Chitta Ranjan Mishra, Hara Prasanna Mishra

"In the Sukinda Valley of Orissa, India, the total quantity of nickel ore reserves comprising of both lateritic and chromite over burden(COB) have been estimated at around 231 million tonnes containing 0.3 to 0.9% Ni. While mining of one tonne of Chromite ore, around 6-7 tonnes of chromite over burden are removed. These overburden materials are disposed as waste materials, which causes lot of environmental hazards and ecological imbalance. India imports a large amount of nickel and ferro-nickel to meet its growing demands in various sectors. For import substitutions, efforts have been made to produced ferro-nickel from the lean deposits of nickel bearing lateritic ores/ chromite over burden materials by reduction roasting followed by magnetic separation and then the nickel rich magnetic fraction is smelted to produce ferro-nickel. It has been possible to produce ferro-nickel of grade varying from 4-25% nickel.IntroductionDuring mining of chromite ore, large quantities of overburden materials are being generated. The materials amount to approximately 10 million tones per year contain around 0.3-0.9% Ni, 0.02-0.06% Co, 20-50% Fe and 4-9% Cr2O3 depending upon the location and the depth of the mine. These materials presently do not find any application for the extraction of nickel due to lack of a suitable technology. The materials are also unsuitable for ferro-nickel making because of their very high iron to nickel ratio. The country is seriously looking for a suitable technology to utilize these resources as its entire domestic requirements of nickel is met though imports. In this connection, a systematic approach has been made at the Institute of Minerals and Materials Technology, Bhubaneswar to develop a process for ferro-nickel making from this indigenous resource."

Jan 1, 2011

Selective Flocculation process development generally involves single mineral flocculation tests to identify the appropriate polymer and experimental conditions for achieving the desired selectivity. Invariably the selectivity predicted on the basis of such tests is not realized when mixed mineral tests are conducted. A systematic experimental investigation revealed that adsorption of the polymer on various substrates is critical to selecting the suitable flocculent. Simultaneously, a mathematical model was developed to predict the overall process efficiency with a given polymer. In this paper, results of these efforts to scientifically design a suitable selective flocculation process are presented.

Jan 1, 1991

By M. N. Collison

"In 1960, with the opening of the Chisel Lake mine near Snow Lake, Manitoba, the Hudson Bay Mining and Smelting Co., Limited, commenced a new phase in their mining operation -that of bringing ore to Flin Flon over 100 miles of railroad.The schedule of operations required to accomplish this, together with an outline of some of the problems of handling ore at 40° and 50,0 below zero, are discussed. The facilities required to thaw and unload from twenty to fifty cars per working day are also described."

Jan 1, 1966

By Peter K. Everett

One of the major driving forces behind the development of the Intec Copper Process has been the increasingly stringent regulations governing SO2 emissions and, in some parts of the world, a declining H2SO4 market. Other incentives include operating cost (9.2 US c/lb Cu), capital cost (US $1400/annual tonne Cu compared with smelter cost of US$3-4000/annual tonne Cu) and the ability to treat low grade and contaminated concentrates. With such advantageous features, widespread use of the process is expected over time, leading to the production of large amounts of residues containing around 25% elemental sulfur, together with approximately 50-60 % akaganeite (FeOOH) and the ganggue minerals originally present in the concentrate feed. This paper briefly describes the Intec process chemistry involved in the formation of elemental sulfur, thereby avoiding atmospheric sulfur dioxide pollution, and the investigations to be carried out either to extract it or to turn the residue into a valuable by-product while minimising any adverse environmental effects, The process is being developed jointly by a group of fifteen major international mining companies.

Jan 1, 1996

By Mikiya Tanaka, Mikio Kobayashi, Kazuya Koyama, Yoshihiro Nishisu

Preparation of multicomponent powders are very useful and important for producing the materials with complicated and homogeneous structure. Therefore multicomponent powders have a lot of attention in the field of advanced value-added materials. The aqueous processing in hydrometallurgy has a broad potential for producing multicomponent homogeneous precipitates. Furthermore the aqueous processing has a future potential for integrating the separation, precipitation and synthesis processes. In this presentation the precipitation from homogeneous solution including rare-earths and/or common metals is presented. These precipitates probably consist of almost monodispersed, multicomponent and spherical particles by precisely controlling several reaction factors, reaction temperature, concentrations of starting materials, pH and so on. The separation of the nucleation stage and the growth stage of the particles is very important and how to control the reaction factors to realize enough separation is discussed. In this presentation the systems of Y-Eu-0, Y-Fe-0 and Y-Al-0 are mainly presented. In addition the precipitation-stripping method from organic phase is presented focusing the synthesis of multicomponent powders of Ni-La-0 system. These precipitates have multicomponents homogeneously and so they are converted to multicomponent ceramic powders by calcination. They are important compounds as phosphor, opto-magnetic materials, optical materials, hydrogen storage alloy or as the related precursors. In this presentation some characterization of these particulate materials is included.

Jan 1, 1998

By C. Damiani

The Chuquicamata smelter, operating since 1952, has gone through several developing stages which have been characterized by the addition of peak technology for copper concentrate smelting (Teniente converter and Outokumpu flash furnace) with an intensive use of technical oxygen, which has permit-ted to partially discontinue the reverberatory furnace utilization. This paper shows the main indicators and operational practices at present, as well as those concerning maintenance aspects. Finally, the most relevant topics related to the future development of the smelter are mentioned with special remarks on the Decontamination Plan, which allows US to keep the high level of production, reducing the emission of contaminants according to the legal requirements in force.

Jan 1, 1993

By Y. Hayashi, A. Fuwa

To analyze zinc vaporization kinetics of zinc smelting slag in the ISP furnace, reduction reaction rate of zinc oxide from ZnO-FeOx-CaO-SiO2 slag system with CO-CO2-Ar gas mixtures has been measured by a therm o-gravim etric apparatus at various ZnO content, Pco, and temperature. The reduction rate was measured under a chemical reaction control in the initial three minutes where surface zinc content can be assumed constant. Through the reaction rate dependency analysis on ZnO contents, Pco and temperature, discussion has been made on its reaction mechanistic information in terms of rate coefficient, adsorption/desorption mechanism and activation energy.

Jan 1, 2008

By H. Perez, A. Lavoie, V. Prévost, P. Létourneau, P. Lind

The Home smelter is a custom copper smelter located in Rouyn-Noranda, Quebec. In 2005, the smelter produced 145,000 t of copper containing 807,000 oz of gold, 20,388,000 oz of silver in addition to 515,000 t of sulphuric acid. Recently, a flexible flow sheet has been developed incorporating the intermittent use of the Noranda Continuous Converter allowing for the increasing or decreasing of production based on market conditions, while attaining 90% or greater sulphur fixation regardless of operating mode. For 2006, the smelter is operating in full production mode and production is expected to be approximately 185,000 tm of copper. Mechanical modifications, process changes, metallurgical concepts, minor element treatments, and operational techniques that have allowed the smelter to develop this flexibility are presented. Current efforts to increase the productivity of the converter aisle and anode furnaces as well as improvements being made to address fugitive emissions are also discussed.

Jan 1, 2007

By S. P. Song

A computational methodology based on the coupled finite element and boundary methods is developed to predict the free surface shapes of electrically conducting liquids supported by the electromagnetic field. The work is an extension of our previous FEIBE model for induction calculations. The free surface algorithm is developed using the Weighted Residual Method, the very same used for nonlinear finite element formulation. This allows the treatment of field computation and free surface prediction in the same manner, thus making easier the formulation of the magnetically-supported free surface problems. Like other nonlinear algorithms, the boundary/finite element free surface scheme is also iterative owing to the fact that free surface shapes are unknown a priori. But the numerical scheme is robust and efficient and is capable of handling rather complex free surface deformations. Computational algorithms will be given and are tested by comparing with other solutions whenever available. Computed results of magnetically-supported free surface shapes are presented for magnetic levitation under microgravity and floating zone refining processes under normal gravity.

Jan 1, 1996

By Robert P. Harrison, Marie-Christine Patoinel, Kristian E. Waters

This paper describes a collaboration between McGill University and Hatch Ltd. to expose undergraduate students to real-world industrial projects. As part of the final-year design course, the students receive a detailed lecture on Scale-Up of New Technologies', including seven case studies drawn from over fifty years of full-scale industrial projects. The students are taught the basic concepts of scale-up, including the limits of pure theory and the need for empiricism. Insights from real scale-up failures and successes are fictionalized as Projects A, B, C, etc. The students are then asked to identify the guiding principles that can be distilled from these case studies.

Jan 1, 2011

Bateman Engineering managed the establishment of a second diamond treatment plant at the Letseng Mine in the Mokhotlong District of northern Lesotho, about 100 km from the town of Buthe Buthe. Letseng Diamonds Proprietary Limited, is owned 70 % by Gem Diamonds and 30 % by the Government of the Kingdom of Lesotho. The second plant, which commenced construction in late 2006, doubled Letseng Mines' hard rock processing capacity from 2.6 million t/yr to 5.2 million t/yr, making it the worlds' seventh largest diamond mine by throughput. Bateman Engineering provided the engineering design, procurement and construction management of the new plant.

Jan 1, 2010

By T. E. Warner

In order to detect arsenic and antimony in zinc, various electrochemcial experiments were performed involving the electrochemical introduction of sodium atoms into molten zinc using a solid electrolyte. Under high rates, the formation of the intermetallic phase NaZn13 was assumed to form. Under more moderate injection rates of sodium, employing a symmetric "zinc/zinc cell", a qualitative relationship between the current generated during cyclic voltammeuy and the arsenic and antimony concentrations in molten zinc was observed.

Jan 1, 1999

By Curtiss O. Ehrsam, M. Naseem Mian

Alaska’s Red Dog Mine is strengthening its position within Cominco’s “Vision 2000”strategic plan by continually improving quality and quantity of production while reducing costs. Red Dog has evolved into a stable and mature operation, after six years of milling experience. A high grade, partially oxidized orebody in the severe Arctic environment, along with competing producers in a volatile metals market, are the continuing challenges facing Red Dog. The Red Dog Mine is striving to meet these challenges with emphasis on operator training combined with creative systems development and increased production. This paper describes developments in operations along with future plans.

Jan 1, 1996

By Bogdan Petkovic, Boban Todorovic

In the early 90's a completely unknown problem was encountered at the converter Department: it was a chronic shortage of the cold copper charge needed for the second operating period. A high temperature operating regime was caused which further provoked a chain of consequences such as a drastic drop of the number of operations in campaigns. The consumption of repair bricks reached the quantity of 8.3955 kg / tonne of anode Cu. In 1994, we won the process of cold material smelting during the "copper" blowing [2]. The number of operations per campaign reached 180-200 again. Also in 1994 we won the process of smelting cold materials to obtain "tin" blowing with the purpose of completing their processing cycle [2]. During the period 1994 – 2007 a total of 107,845 tonnes of cold material were remelted to make copper and 56,794 tonnes were re-smelted to obtain "tin". Upon synthesizing these two processes, a completely new model was achieved in 2005, by Bogdan Petkovic, which entirely utilized all available energy of the Peirce-Smith (PS) converters of the Bor Copper Smelter and now represents the basis of the time cycle. The cold material now enters the converter plant, copper recovery is increased and the method itself is environmentally friendly. 167

Jan 1, 2009