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By L Usoni

Collectors commonly used in flotation to date fall into two main classes: ionic and nonionic. The use of neutral or oily collectors is generally limited to the flotation of nonpolar minerals onto which they are adsorbed by forces of a physical or 'Van der Waals' type, while ionizable chemical collectors are utilized for all other types of minerals, adsorption in this case involving bonds essentially of a chemical nature. Though chemical adsorption is more selective than physical adsorption, even heteropolar collectors are active towards certain classes of minerals (sulphides for example) rather than towards one individual mineral. Thus, in order to float a given mineral from a mixture of minerals belonging to the same class, modifiers have to be used to render the action of the collector more specific. However, there are often considerable difficulties involved in this procedure and the desired results are not always attained, especially in the case of minerals of complex composition whose surface properties are not sufficiently well known. Hence the importance of seeking out collectors capable of linking selectively with given minerals. Selective linkage is possible if the collector structure incorporates active groups having specific affinity for certain cations characteristic of the mineral surface. The decision to investigate the possibility of utilizing chelate--forming reagents for flotation was based on the premise that phenomena which occur in solution and involve chemical reactions in the strict sense of the meaning and those which occur on the surface are closely correlated (1)

Jan 1, 1971

By A. M. Gaudin

In a recent paper we have reviewed principles and applications of measurement methods for contact angles and their hysteresis (22). In this paper we apply these methods to a system consisting of rutile, an organic liquid (benzene, decane, or dodecane) and water. Surfactant (dodecylamine hydrochloride) was used at various concentrations and various pH values.

Jan 1, 1964

By J. K. Whyatt

Assuring ground control safety in many mining and tunneling projects depends, at least in part, on an understanding of in situ stress conditions that will be encountered. Yet it is rarely practical to conduct more than a very limited number of stress measurements. Stresses along the route of a proposed excavation are typically interpolated from available measurements, often assuming a linear variation of stress with depth (or elevation). However, projects where multiple stress measurements are conducted often report more complex variations of in situ stress, usually in apparent relationship to geologic structures. These structures often include lithologies of contrasting elastic properties. A method is proposed for estimating stresses in these cases by first back-calculating regional loads from available stress measurements and then modeling the distribution of stress throughout the rock mass. The method has been successfully applied to a set of in situ stress measurements from the Coeur d’Alene Mining District of northern Idaho, USA. Results provided new insights into district stress conditions and the distribution of rockburst hazards along mine drifts and between various mines. This success should transfer readily to suitable deep tunneling projects.

By J. Defreyne

CESL has developed a proprietary hydrometallurgical process for base metal concentrates, notably those of copper and nickel. The process is based on pressure oxidation (PO) of the sulphide minerals, which is done at elevated temperatures in mixed sulphate-chloride liquor at about pH 2 ? 3. The process achieves maximum oxidation of the metals whilst minimizing sulphur oxidation to sulphate. Almost all base metal sulphide minerals are efficiently treated under these conditions. In the case of copper minerals, pressure oxidation does not generally put the copper into solution, because of the relatively high pH prevailing in this process. Therefore, PO is followed by an acidic leaching stage, which specifically aims at maximum copper dissolution with minimal leaching of iron. The overall copper recovery is largely determined by the efficiency of this stage. The process has low capital and operating costs, partly because there is minimal use of acid or neutralizing agents for iron dissolution or precipitation, respectively; this is achieved by minimizing iron leaching during both the oxidation and leaching stages. Iron sulphides in the feed concentrate deport almost entirely to the solid leach residue as hematite, which has superior handling characteristics for filtering and washing. Iron minerals play a key role in the process, with pyrrhotite and pyrite having very different responses to the oxidation process. Acid management for the whole process is affected by the iron mineralogy, and the flowsheet is therefore tuned to the specific concentrate.

Jan 1, 2006

By S. Torizuka, I. Mizushima. Kawasakitohri, A. Ohmori, K. Nagai

Strain (work)-hardening in tensile tests were examined for low carbon steels with various ferrite grain sizes ranged from 0.4µm to 16µm. The steels had microstructures composed of ferrite grains and dispersed cementite particles. They were fabricated through warm caliber rolling with an accumulative area reduction of 93%. Strain-hardening rate at a given strain increased with an increase in volume fraction of cementite particles. The balance of yield strength and uniform elongation for ultrafine-grained structures could be improved by the dispersion of cementite particles. Effects of the cementite dispersion and the ferrite grain size on the strain-hardening rate can be roughly explained by the work-hardening model with GN-dislocation density. Strain-hardening design using dispersed cementites was proved to be effective in controlling ductility of the ultrafine-grained steels.

Jan 1, 2004

By Suguru Kohno, Yoshihiro Momose, Masakazu Honma, Tokirou Kamosawa

Copper metal surfaces have been examined by an extremely sensitive surface analysis technique called temperature programmed photoelectron emission (TPPE). The surfaces were ultrasonically cleaned and subsequently abraded by a screw in organic solvents and water. The TPPE apparatus is composed of a Geiger counter with Q gas (He+ iso-C4H10). The curve of photoelectron emission (PE) intensity vs. wavelength from 300 to 170 nm, termed PE spectrum, was repeatedly measured at different temperatures in the temperature- increase process from 25 to 350°C. The number of emitted electrons in a PE spectrum (PE total count) increased, reached a maximum at-250°C, and decreased with increasing temperature. With the surfaces cleaned alone in the liquids the maximum PE total count decreased in the order C3H70H > (CH3) 2CHOH > C2HpH > CHPH > H2O. With the mechanically abraded surfaces in the liquids the maximum PE total count changed as a function of the abrasion period and the maximum tended to appear at higher temperature with increasing abrasion period; the maximum value at 10-min abrasion decreased in the order H2O > CHpH > C2HPH > (CH3) 2CHOH > n-C3HpH. It was suggested that the TPPE behavior can be related to the acid-base interaction between the alcohols and the abraded metal surfaces and the presence of a contaminant over layer on the surface. From the XPS analysis of the 01 s spectra it was suggested that the chemical change of the adsorbed oxygen to oxide oxygen with temperature plays a substantial role in the appearance of the maximum PE total count.

Jan 1, 2000

By C. J. Thompson

This Bureau of Mines study describes the preparation of sulfur compound concentrates boiling from 225° to 400° C, and reports the sulfur types detected in these concentrates by low-voltage mass spectrometry (LVMS). Existing LVMS methods were extended; the procedures described should be generally applicable to high-boiling petroleum distillates and concentrates as a preliminary means of narrowing the number of factions to be considered for more detailed separation and identification studies. The following major sulfur compound constituents of petroleum are indicated by the data: benzothiophenes, dibenzothiophenes, naphthanothiophenes, naphthenobenzothiophenes, and homologs and isomers of these. Cyclic and chain sulfides comprise a significant portion of the gas-oil range sulfur compound types. The presence of some classes of sulfur compounds containing two sulfur atoms per molecule was indicated.

Jan 1, 1966

By Dalene Joalet Steenkamp

Excavation of industrial-scale furnaces allows for the systematic study of reaction sequences by identifying the different reaction zones within the furnace. In 2013, Transalloys excavated a 48 MVA submerged arc furnace that was used for silicomanganese production using the ore-based route. The excavation method was reported elsewhere as was observations made in terms of refractory wear and modes of electrical energy dissipation prior to excavation. The paper presented here, reports on the process reaction zones observed during the excavation and subsequent phase chemical analyses of a number of process samples obtained during the excavation. The zones identified were a loose burden zone, a dry coke-bed zone, a wet coke-bed zone, a hard build-up zone, and an alloy zone. The results are compared to observations made in the excavation of an industrial-scale SAF and a pilot-scale SAF in Norway. The presence of the hard build-up zone below one of the electrodes and absence of a slag zone below all three electrodes are unique features of the SAF excavated at Transalloys.

By Larissa Fernandes Nunes

O presente trabalho teve como objetivo caracterizar a temperabilidade de uma liga Fe-Ni-Cr. Amostras do material foram submetidas a temperaturas de encharque de 800ºC e 1100ºC e resfriadas utilizando salmoura e nitrogênio líquido. Para a caracterização do material, foram realizadas análises de EDS, MEV e DRX para se determinar, respectivamente, a composição química das fases, a microestrutura e a transformação de fases que podem ter ocorrido. Os resultados microestruturais não mostraram evidencias de transformação de fase, mas que houve o surgimento de maclas de deformação associadas à ciclagem térmica. No entanto a difração de raios-x para amostras tratadas a 800ºC, com aparentemente segregação intergranular, evidenciou alguma transformação de fase.

Oct 30, 2017

By William I. Weisman

Natural sodium sulfate is obtained from both brines and solid deposits. The brines almost always contain other salts with sodium chloride predominating. They may be obtained from surface occurrences, such as Great Salt Lake or from shallow subterranean deposits. Althought many sodium sulfate minerals are known to exist, only three are of commercial significance. These are thenardite, the anhydrous salt; mirabilite, the decahydrate; and glauberite, the double salt of sodium and calcium sulfate. The reader is referred to Weisman (1983) for details on mineralogy and geology of sodium sulfate minerals. Sodium sulfate deposits, either in the form of brine or solid minerals, are found in many parts of the world. Natural sources, by far, provide the primary supply of commercial grades in Canada, Mexico, Spain, and probably in the U.S.S.R., Chile, Argentina, and Turkey. In the United States, production of natural material and synthetic (including by-product) are about equal in volume and have been for many years.

Jan 1, 1984

Application of flotation for the removal of hydrophobic compounds from soils was studied. Bench scale flotation tests were conducted on artificially contaminated soil, using both conventional mechanically agitated machine and flotation column. Flotation parameters tested include surfactant collector type, conditioning time, flotation time, surfactant dosage, pulp pH, solid/liquid ratio in conditioning and pulp temperature. It is found that with conventional flotation 74% removal of the contaminant was achieved from soil particles in the range of 75-830 µm; with column flotation up to 80% of oil could be removed from the 250-830 µm soil fraction, and 65% from the 75-830 µm fraction. Flotation was found to have considerable potential for cleaning up contaminated soils.

Jan 1, 1998

A processing scheme is presented to use one single chemical that has multiple functions to re-duce the use of chemicals and achieve more efficient mineral flotation and solids dewatering. Sti mulisensitive polymers which display hydrophilic/hydrophobic transitions in response to changes in temperature or pH have been found to be useful as such multiple function reagents. They can cause the mineral particles to be either hydrophilic or hydrophobic at one stimuli condition and the opposite at the reverse stimuli condition. Therefore, both particle surface wettability and inter-particle interaction forces are reversibly controllable. When the surface is hydrophilic, particle dispersion is achieved by repulsive inter-particle forces whereas when the surface is hydrophobic, particle aggregation is induced by inter-particle hydrophobic attractive forces. In addition, the hydrophobic surface condition allows for the attachment of particles to bubbles. Flotation and solid settling tests have been conducted with a silica suspension treated with the temperature-sensitive polymer poly (N-isopropyl acrylamide) (PNIPAM). The results indicated that PNIPAM can be used to induce a transition between hydrophilic and hydrophobic surface character at temperature lower or higher than its critical solution temperature (CST around 32oC). Thus, both effective silica dispersion or hydrophobic aggregation and flotation without adding any additional collector have been demonstrated. In tailings treatment, rapid silica settling was obtained with hydrophobic aggregation at temperature above the CST and further sediment consolidation (and water release) occurred at temperature below the CST. Contact angle measurements confirmed the hydrophilic/hydrophobic transition induced by PNIPAM.

Jan 1, 2014

By S. A. Jacob

Magnesium sheet is notoriously difficult to form at low temperatures without initiating failure, In the present work cold rolling and annealing conditions are varied to produce samples of AZ3lB sheet with a range of grain sizes. The formability of these samples is investigated using tensile testing and forming limit diagrams (FLD's), The results are discussed in terms of twin types and frequencies.

Jan 1, 2005

By D. Van Tonder

ABSTRACT The comparative economics of ion exchange and direct precipitation have been analyzed by developing indicative CAPEX/OPEX models for typical alkaline leach uranium circuits. An agitated tank ore leach application is considered, comparing resin-in-pulp and direct precipitation as recovery options. Capital and operating cost estimates are derived from rates and factors used in recent studies and projects. The analysis showed the main economic drivers to be the ore grade and resin loading. The resin loading is impacted by the prevalence of competing ions, especially chloride. At resin-in-pulp solution chloride concentrations below 3 g/L and uranium grade below 640 g/t U3O8, resin-in-pulp is more economical, whereas at chloride concentrations above 3 g/L, direct precipitation is more economical.

Jan 1, 2012

By G. Viramontes-Gamboa, A. Encinas-Oropesa, S. Velázquez-Roque, L. A. Ibarra-Bracamontes

Some industrially relevant applications for pyrite nano/micro-particles have been proposed in the literature, such as the catalysis of chalcopyrite leaching, the removal of As(III), As(V) and Cr(VI) from solution, as photovoltaic devices, and others. Even though pyrite can be recovered from solution by flotation, for some applications it may be beneficial to provide pyrite with magnetic properties. In this work, a methodology to synthesize magnetic shell/core composites made of pyrite as the shell and either natural or synthetic magnetite as the core is presented. The size of the magnetic composite may range from tenths to hundreds of microns. The synthesis is basically made by stoichiometrically mixing iron nano/micro-particles with sulfur microparticles with magnetite particles, and bringing the mixture in an oxygen free atmosphere from 200 to 300 °C for 4 h. The composites were characterized by optical microscopy, Scanning Electron Microscopy and X-Ray diffraction.

Jan 1, 2014

An AFM has been applied to study in situ the adsorption of oleic acid on fluorite in aqueous solutions. The AFM images show that fluorite surface becomes smoother with the adsorption of 7 × 10-5 M oleic acid solution at pH 9. Force measurement shows that fluorite is strongly positively charged in water at pH 6, suggesting a neglectable surface carbonation of fluorite. The adsorption of oleic acid at pH 9 renders fluorite more and more negatively charged. The surface morphology change of fluorite as shown by the AFM images suggests that oleic acid chemisorbs on fluorite at pH 9. Increasing temperature can help increase the adsorption of oleic acid on fluorite. It may also improve the lateral polymerization of unsaturated oleic acid on fluorite as suggested by the smoother mineral surface in oleic acid solutions at an elevated temperature.

Feb 23, 2014

"The pressure leaching of alkali-pretreated limonitic laterite ore in nitric acid was studied. The optimal leaching conditions are as follows: leaching temperature of 458 K, initial nitric acid of 2.44 mol/L, leaching time of 60 min, liquid to solid ratio of 2:1 mL/g, agitation speed of 500 RPM. Under the above conditions, the extraction of nickel and cobalt can be achieved as approximate 95% and 80% respectively while that of iron is as lower as 1%. The leaching residue containing 70% of iron in the form of hematite and trace amount of chromium is suitable as the raw material for iron-making. The nitric acid in the leaching solution can be regenerated and further recycled to leach. INTRODUCTIONIt has been estimated that 60%-70% of the world land-based nickel resources presented in nickel laterites containing 130 million tons of nickel although these only accounted for about 42% of the world nickel production (Sudol, 2005; Luo et al., 2010). The nickel resource of laterite has not yet been fully utilized. Due to the increasing global demand of nickel and the declining global reserves of nickel sulphides, there is an increasing focus on the processing of the huge reserves of laterite ores today. Nickel laterite ores can be simply divided into two types, namely, silicate-rich and limonite. The former can be treated effectively by pyrometallurgical process in which the ferronickel product or nickel/iron sulphide matte is produced (Monhemius, 1987). The limonitic laterite is rich in iron in the form of goethite which is the main nickel-bearing mineral and usually contains cobalt associated with a manganese phase (Chang et al., 2010; Georgiou and Papangelakis, 2004). The limonitic laterite is usually processed by hydrometallurgical methods, such as atmosphere acid leaching (AL) (Xu et al., 2005; McDonald and Whittington, 2008), high pressure acid leaching (HPAL) (Chou et al., 1977; Georgiou and Papangelakis, 1998; Rubisov et al., 2000; Whittington and Muir, 2000) and reductive roasting-ammonia leaching (Caron Process) (Whittington and Muir, 2000; Valix and Cheung, 2002). The AL process can proceed at lower temperature, thus the operation costs may be very low. But two biggest problems associate with the AL process, namely, the slow rates of nickel extraction and potentially the significant amount of impurities such as iron and aluminum in the leaching solutions, which hampers the wide application of the AL process. The Caron Process uses the pyrometallurgical and hydrometallurgical methods together to obtain the metallic values, but the overall metal recovery is relatively low, especially for cobalt. In recent years, the environment-friendly process of HPAL has become increasingly important because it is most suitable for low-grade ores and leads to high extraction of the valuables. However, the HPAL process needs a much higher temperature and pressure (503-533 K, 4-5 MPa) to maintain a relatively fast leaching rates, which results in higher operation costs. Moreover, another serious problem of scale formation in autoclaves occurs in the HPAL process, for example, in Moa Bay, up to 20 cm scale may build up resulting in 5 days descale downtime per month. In addition, the iron residues cannot be utilized for ironmaking due to the presence of high content chromium (Ema and Harada, 1987; Owada and Harada, 1987; Takagi and Furui, 1987)."

Jan 1, 2012

By C R. Fountain, R J. Sinclair

The zinc industry is dominated by the electrolytic zinc (EZ) process. The EZ process has a low tolerance for impurities, resulting in tight concentrate specifications. Many mining companies sacrifice zinc recovery in order to meet smelter specifications. Some have ore-bodies that cannot be economically developed because too much metal has to be sacrificed, or it is just not possible to meet the specification. The BUKA Zinc Process (BZP) has been developed as a method of producing high-quality zinc from a wide range of concentrates. It can have lower capital and operating costs than the conventional zinc and lead production routes. Advantages accrue from increases in metal recovery during concentrating, smelting and refining; the elimination of most of the capital and operating costs associated with lead smelting; reduced transport costs; lower zinc refining costs; reduced refinery residue disposal costs; and reduced future environmental liabilities. This paper describes results of testwork that has been undertaken to demonstrate the viability of the BZP on both test rig and laboratory-bench scale.

Jan 1, 1998

By Chas. F. Jackson

The work of the mining division is divided between seven sections, each in charge of a supervising engineer, as follows: 1. Metal-mining methods section, the supervising engineer of which is also supervising engineer of the Southwest Experiment Station at Tucson, Ariz. 2. Metal-mining research section. 3. Nonmetal minim section. 4. Coal-mining section. 5. Mine-ventilation section. 6. Mineral-industries survey section. 7. Electrical section. The names of the sections indicate broadly the fields covered by each, and in the following pages the objectives and type of work of each section will be summarized briefly and the active problems listed. The work done during the calendar year 1936 will also be summarized.

Jan 1, 1937

By J. H. D. Hargrove, A. F. Snowball

Atmospheric pollution control has become increasingly important in re-cent years with laws and public opinion having required the reduction of contaminants from industrial gas effluents. Treatment methods have advanced to make possible, with proper plant design and operation, a satisfactory removal of these contaminants. Gases from Cominco's metallurgical operations at Trail, approximating 900,000 c.f.m., are treated by baghouses, electrostatic precipitators, cyclones, or wet scrubbers. The tabulated data include gas and dust conditions, plant performance, and some details of plant equipment. Discussion emphasizes the special features, scope of application, and basic design principles of the treatment methods, all based on Cominco experience. Recovery of over 99 per cent of the fume and dust is achieved by the major installations from which effluent gases go to atmosphere. Cooling of gases for baghouse recovery and conditioning for electrostatic precipitation are mentioned. Co3ts are tabulated for some of the installations on the basis of a unit of 1,000 cubic feet of gas. Suggestions are made on the procedure for assessing a smoke treatment problem and for selection of suitable equipment.

Jan 1, 1959