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By J. Gordon Parr, G. R. Purdy

The phase boundaries of "TiNi" have been accurately determined by high-tewperature X-ray diffraction and metallo-graphic techniques. The phase (centered at 51 pct Ni) has a restricted range of homogeneity at 500°C, and a much greater range at 800°C. "TiNi" in all alloys containing less than 51 pct Ni decomposes rapidly and reversibly at 36°C to form a previously unreported phase. ThE region of the titanium nickel system corresponding to the phase "TiNi" has been the subject of several investigations.1,2,4-7 Laves and wallbaum1 reported "TiNi" as a body-centered cubic (a2) Phase, and Duwez and Taylor2 determined its para- meter to be 2.986. Duwez and Taylor also reported that "TiNi" decomposed into "Ti2Ni" and "TiNi3" on prolonged heating at 650" and 800°C, which led McQuillan3 to suggest a sluggish eutectoid reaction between "TiNis" and "Ti2Ni". Margolin, Ence, and Nielsen,' working with higher purity alloys, found no evidence of this decomposition. They showed the "TiNi" phase region extending from 49 to 54 pct*

Jan 1, 1962

By W. H. Bassett, J. C. Bradley

In their paper on the directional properties in cold-rolled and annealed commercial bronze,' Phillips and Samans suggest that cupronickel, under distinctly different treatments, shows both "45" ears" and "90" ears. Fig. I shows the ears on some cupronickel cups made some 17 years ago for bullet jackets for small arms ammunition. In this case the material heated to 425° C. had "45" ears, while that annealed at 950°C. showed long "90" ears" when drawn with the same tools. The method of cupping, the shape of cupping tools, etc., were found to have very little influence on the earing tendency, but the deeper the cup was drawn, the higher the ears would be. Method of Manufacture Cupronickel cast bars were 1 in. thick. Ordinarily, they were rolled with numerous passes to a thickness of 0.4 to 0.2 in., according to conditions. They were then given a single intermediate anneal, and rolled to finish thickness, frequently 0.032 in. After a last anneal the material was cupped with a "cut and draw" operation. Progress of this is indicated in Fig. 2, illustrating five different stages at which the drawing

Jan 1, 1933

By William Newton Best

Oil burners, oil furnaces, and methods of installation, have been the subject of many articles, but information concerning oil-burning systems, based upon scientific principles, is still in great demand, especially in the manufacturing districts of our country. Fuel oil, as it is termed (this being the residuum from oil refineries), has for many years been of great service to our manufacturers, and has justified its popularity not only by producing a superior manufactured product, but by turning out approximately 50 per cent. more product than can be made with coa1 fuel under like conditions. To install a system requiring only an oil-storage tank, a small pump, and an oil-supply main with numerous laterals leading to the various burners, furnaces, boilers, etc., is a comparatively simple matter; and, because fuel oil is very volatile, it is not necessary to heat it, even during the winter months in a very cold climate. Furthermore, only a small amount of power is required to atomize fuel oil, this often being done by a positive pressure blower, or by a mechanical burner. An analysis of fuel oil, together with that of various other liquid fuels, is given in Table I.

Jan 1, 1915

By J. H. Tylczak, R. Blickensderfer

Impact and abrasion properties of various commercial US grinding halls were evaluated and compared by the Bureau of Mines, US Department of the Interior. Laboratory tests were conducted on balls obtained from eight major US manufacturers. The halls included forged steel, cast steel, and alloyed white cast iron and were subjected to repeated impacts until they broke or until 300,000 impacts were exceeded. Pin abrasion tests also were conducted. The results showed wide differences in impact lives, ranging from a few thousand to over 500,000 impacts. The life of inferior commercial halls was increased five to six times by a laboratory tempering heat treatment. For halls that did not break, the major impact wear mode was spalling and ranged from an average rate of 0.28 to 4.46 mg per impact. The softest halls (steel) had excellent impact resistance but low abrasion resistance. The abrasion resistance of the steel halls generally increased with hardness. The alloyed white cast irons had about twice the abrasion resistance of the steel halls. Users should become aware of the wide variations among commercial halls, and ball manufacturers should be aware that their product can he improved.

Jan 1, 1990

By Dorsey Lyon

I. INTRODUCTION THE utilization of hydro-electric power in electro-metallurgical indus¬tries, aside from purely mechanical operations, may he of two kinds. The electric energy may be used to supply the heat necessary for the per¬formance of the chemical reactions of a metallurgical process, or the elec¬trolytic action of a direct current may be employed for extraction of metals, either in a reduction process or a refining process. In discussing this subject, it is well to distinguish between established industries, which are producing metals and alloys at a profit by use of the electric current, and the many processes which are either still in the experimental stage or have not even passed the paper stage of development of a patent. That is, we consider electro-metallurgical industries as commercial operations which are now consuming large blocks of electric energy, while processes which are not in commercial operation are only prospective consumers. Also, owing to the difficulty and risk of any attempt to foresee the effect of the European war upon electro-metallurgical industries, we have felt obliged to disregard the war entirely, and state our opinions regardless of its existence.

Jan 8, 1915

By Gregory P. Cole, Jeffrey Shawn Peterson

The Pittsburgh Research center3 conducted research to study and improve electrical fault detection on coal mine direct-current (dc) trolley systems. A suspended trolley line delivers power at voltages of 300 or 600 V dc to the haulage equipment and other loads. Roof falls or other accidents may force the trolley line down so that an electrical fault current may flow between the trolley line and rail. This fault current could result in localized heating, arcing, and perhaps fire. Such faults are not always preventable by the existing circuit protection because the current magnitude is well below typical operating levels of the trolley system. The research discussed in this report studies the applicability of computerized signal analysis techniques to solve this problem. Tests were conducted at cooperating coal mines. Measurements were taken during normal loading of the trolley system (light, intermediate, and heavy traffic), during induced fault conditions (arcing and bolted faults), and during transitions between the two. These data were then used to train and test a microprocessor-based fault detection algorithm. Later, field tests of the detection algorithm found that it correctly classified the state of the trolley system greater than 95% of the time.

Jan 1, 1997

By Winrove G. S, Herdie G. J, McCarthy C. A

Production of hot metal from the Hlsmelt Research and Development Facility at Kwinana, Western Australia commenced in October 1993. The stand-alone facility is a unique, coal-based, integrated ironworks equipped to process iron ore fines to pig iron and simultaneously undertake a wide range of research tasks. The data generated will be used to verify the commercial potential of the technology and to set the design and operating parameters for a full-scale production plant. The design, construction, commissioning and initial operation of the HRDF has required many innovative and practical solutions to be developed and implemented by the international group of organisations contributing to the Hlsmelt Project. Initial operation has produced results which demonstrate the potential of the unique process technology associated with the core plant smelting unit. The recent achievement of post-combustion levels of 60 per cent with heat transfer efficiencies greater than 85 per cent demonstrates that the performance obtained with the Small Scale Pilot Plant in Maxhutte, Germany can be reproduced at a larger scale. The results presented in this paper support the thrust for further intensification and future commercialisation of the process.

Jan 1, 1995

By L. D. Hall, S. J. Rothman

The diffusion of lead and of trace amounts of bismuth in liquid lead have been investigated by the capillary method, using ROD and ROE as tracers. The results are compared with existing theories of diffusion in liquids, the agreement with theory being fair. The heat of activation for self-diffusion in lead is found experimentally to be close to the corresponding activation energy obtained from viscosity data. The pioneer data of Groh and von Hevesi for the self-diffusion of liquid lead, using ThB as a tracer, fit in with the present results. OMPARED with the volume of effort expended on solid state diffusion, there has been little attention paid to diffusion in liquid metals. A review of experimental work in this field, covering most of the studies up to 1951, was given by Jost.' More recent papers include those by Hoffman2 on self-diffusion in mercury, Morgan and Kitchener" and Stark, Shchilishchev, and Kazachkev4 on the diffusion of various elements in liquid iron, and Grace and Derge on the diffusion of bismuth in bismuth-lead alloys. The need for more experimental data to aid in the evaluation of existing theories prompted the

Jan 1, 1957

By Warner N. A

There is an inherent problem in producing simultaneously lead, zinc and copper as metals in a single polymetallic smelting furnace. It relates to the condensation of lead and zinc from the gas phase under vacuum conditions such that metals in bulk form, either solid or liquid, are obtained as products rather than a fume or dust containing both metallic and non-metallic components. To understand this phenomenon, it has been necessary to establish mathematical models with computer simulation to identify the process requirements for effecting the objective of maximum bulk metal production with minimum fog formation. The theoretical framework of simultaneous heat and mass transfer involved in condensation from gas mixtures containing a non-condensable gas has been extended to the high temperature and reduced pressure conditions. These apply to new technology for polymetallic smelting now being developed in a project currently funded jointly by the Commission of the European Communities and the Mineral Industry Research Organisation. Under the right conditions it is theoretically possible to condense out both lead and zinc with minimal fume formation, but in all practical cases it is anticipated that some circulating load for reversion back to the smelter will be needed.

Jan 1, 1989

By Bluhm S. J, Feio L, Ramsden R

A new mining area at the Vaal Reefs gold mine is to have a shaft. system which will extend to a depth of 4 200 m and will require 130 MW of cooling. A novel feature of the proposed cooling system is a large underground air cooling installation in which an ice slurry is sprayed into the ventilation air. The design of the ice slurry bulk air cooler, in the form of counter.flow cooling towers, is discussed. Comparative thermal tests with cold water and ice slurries (with ice mass fractions up to 22 per cent), were carried out in a 5 m high test tower. The presence of the ice in the water spray increases the resistance to heat flow and reduces the overall thermal characteristics of the air cooler by 8 per cent. Notwithstanding this, the use of ice slurries is indeed beneficial in terms of overall costs. It is concluded that a 25 MW air cooler should use 410 kg/s of ice slurry with a 10 per cent ice mass fraction to cool 550 kg/s of air which is 75 per cent of the total air flow rate.

Jan 1, 1988

By N. Haghdadi, D. M. Maijer, A. B. Phillion

B206 is a recently-developed high-strength Al-Cu casting alloy with reduced Ti and Fe, as compared to the well-known AA 206 alloy, for improved hot tearing resistance. In the current study, the solidification kinetics of this alloy as a function of cooling rate from 1 to 15 K/min were studied using differential scanning calorimetry (DSC) and microscopy. Specifically, the evolution in fraction solid, grain size, and secondary dendrite arm spacing have been characterized. The DSC results show the occurrence of three peaks during cooling from the liquid state, which are related to the formation of primary aluminum, a pre-eutectic intermetallic, and the eutectic phases. Thermal analysis also indicates that while the liquidus temperature is not sensitive to the cooling rate, the temperatures at which the pre-eutectic and eutectic phases form are strongly coupled to the rate of heat extraction. A decrease in the latter temperatures was observed when the rate of solidification was increased, leading to a lengthening of the freezing range of the primary phase. The results will be useful for improving B206 casting processes, specifically through modification of mould cooling conditions.

Jan 1, 2014

By John V. Beall

Hard as the Revett quartzite are conditions governing the deep mines of the Coeur d'Al6ne. In fourscore years of mining, heat and pressure have been the rewards of preseverance. Such obstacles are the natural concommitant to search for ore at depth. But high cost and shortage of miners is a creeping frustration of the decade. These grim observations were made on a trip to the mines of the Coeur d'Al6ne in the first week of May. But the bouncy optimism of competent mining engineers and geologists overrides by far the tough conditions. This is the story of what they are doing. I think they are setting the stage for the wonder mines of tomorrow. I didn't meet all the people or see all the mines, so there are unfortunate gaps in the story. Then too, sometimes the muck and water blotched my notes, or I couldn't write fast enough or I was too tired. No matter. There is much to tell and, because it is basically a human story, I am flouting the rules of technical journalism and couching it in the neglected "I" person. First then, a little history . . . .

Jan 7, 1966

By David C. Byrne

From an engineering perspective an ideal industrial noise control solution focuses directly on the actual source of the poise. Eliminating the noise-generating mechanism altogether obviates the need for other noise contra l treatments or hearing protection devices. However, in cases where attenuating the source is not feasible engineering controls must be oriented toward blocking the path that the sound waves travel toward employees. Acoustical enclosures are commonly used as sound path treatments to contain the noise from a machine: alternatively a control room/booth or equipment operator's cab may be used to isolate the worker from the noise. Anyone who has successfully used acoustical enclosures knows that the design procurement, and installation process is deceptively simple. Alt too often First-time efforts fait to account for many of the constraints that can render the enclosure essentially useless. Things that cannot be overlooked include: providing convenient worker access (physical and visual): allowing for proper machine operation/product flow; and supplying fresh air or preventing undue heat or contaminate build-up inside the enclosure. All of these factors must be given careful consideration, otherwise the enclosure will not perform adequately.

By W. Gundaker, F. C. Schwerer

Natural chromium-bearing spinels (chromites), which are used as refractory materials in basic steelmaking, are the only commercially important chromium ore and are also encountered as difficult-to-separate contaminants in ore deposits of potential economic value. Techniques for characterization and separation of ore materials frequently are dependent on the magnetic properties of the constituent minerals. An experimental program was initiated to explore the effects of temperature and of simple mechanical and thermal treatments on the static magnetic properties of several ore-grade natural chromites. Studies of the temperature dependence of the magnetic properties showed that the natural chromites, which are dilute in the magnetic ions Fe and Cr, order magnetically only at cryogenic temperatures. However, mechanical treatment in the form of crushing produces a magnetic component that is ordered at room temperature and that is of sufficient strength to alter magnetic-separation characteristics. The additional magnetic component apparently is associated with surface structures which develop during crushing and disappear after heating to above about 500°C. Preliminary studies indicate that this surface structure enhances the susceptibility of the chromite grain surfaces to gas reactions at moderate temperatures.

Jan 1, 1976

By B. G. Klugh

(New York Meeting, February, 1913.) THE present paper represents a preliminary investigation of the ultimate structure of iron-bearing materials which have been subjected to heat treatment for the purpose of agglormer-ating the fines, or for chemical changes, or for both. Primarily, the object of this inquiry was to determine the relation of the microstructure of each of these materials-to its specific susceptibility to the action in the blast-furnace. It is hoped that this small contribution will serve as a nucleus to a line of research that will throw some light upon the debated questions involved in blast-roasting. Thus far the investigation has been conducted along lines of analogy of known principles, rather than through the applica-tion of any well-defined system of microscopic petrography. This is obviously due to the fact that we are dealing with materials which are the artificial products of a new art, rather than with the natural materials from which the essence of the pure science has been evolved. In the limited tune allowed for this research, it has been conducted upon those materials the chemical content of which allows of their use commercially in the blast-furnace.

Jan 5, 1913

By Piga P, Sammarco O

Ventilation and the environmental climate in the Campiano mine is the subject of this re- search. The mine is located in Southern Tuscany (Central Italy), a region where geothermal gra- dients are very high (three times the average gradient of the earth). The research produced interesting indications as to the influence of surface climatic conditions on the environmental parameters inside the mine. A close correlation has been found between dry-bulb temperature and humidity ratio of the air in the mine for dif- ferent metereological conditions and for differ- ent mass flow rate values. Variations in air enthalpy, caused only by the heat exchange with the rock walls during the flowing of the air through the mine, depends on the surface temperature values. Statistical analyses have been used to ex- press air enthalpy variations on surface tempe- ratures, on the variations of the humidity ratio that the air undergoes inside the mine and on the mass flora rate. The application in practice of the results will permit the identification of correct mea- sures to be adopted so that optimal microcli- matic conditions are produced in the mine.

Jan 1, 1986

By F. R. Hensel

Up to the present time few attempts have been made to produce hard nonmagnetic materials by heat treatment of austenitic steels. The usual result has been to cause them to pass into the martensitic stage, thus destroying to a great extent the typical austenitic properties, since this involves a transition of a portion of the iron from a face-centered to a body-centered type of atomic arrangement. High-strength nonmagnetic materials such as might be provided by properly hardening austenite are required in the electrical industry for different machine parts. In Europe nonmagnetic retainer rings for restraining the end-turns of the rotor windings in turbo-alternators have been developed as a special application of high-strength austenite. In testing1 a 28,000-kva. three-phase Siemens turbo generator running at 3000 r.p.m. at full load current, the losses in the short-circuit test were 450 kw. for the magnetic ring and 286 kw. for the nonmagnetic, and the difference should be attributable to the magnetic ring. The differences in temperatures during the same test are given in Table 1 and these show the advantage of a nonmagnetic over a magnetic retainer ring.

Jan 1, 1931

By De Jong HJ

During the forthcoming reline of No.3 Blast Furnace at the Newcastle Steelworks of the Broken Hill Proprietary Co. Ltd., facilities for the screening and weighing o' coke will be installed. The equipment is needed to optimise the sizing and the quantity of coke immediately prior to it being charged to the furnace. Up till the time the furnace was blown out in November, 1982, coke was charged to the furnace by volume, ie by skip fulls only. This resulted in variation to the ore/coke ratio charged due to bulk density changes and erratic skip filling levels. This in turn affects the heat balance of the furnace and causes fluctuations in hot metal chemistry and temperature. A coke rate penalty has to be paid also. Coke layer thickness in the furnace burden cannot be controlled closely, resulting in loss of control over gas distribution in the furnace. A grizzly type screen was incorporated in the skip loading chute but this ineffective method left a great amount of fines with the coke being charged to the furnace. Furnace permeability was therefore reduced, particularly in the hearth.

Jan 1, 1984

By X. Cao, P. Wanjara, J. L. Fihey, X-T. Pham, F. Mirakhorli

Single-pass hybrid laser-arc welding of 10-mm thick cast plates of CA6NM, a low carbon martensitic stainless steel, was carried out in butt joint configuration using a continuous wave fiber laser at its maximum power of 5.2 kW over welding speeds ranging from 0.75 m/min to 1.2 m/min. The microstructures from the fusion zone to the heat affected zone and base metal were characterized after post-weld tempering at 600°C for 1 hour. From optical and scanning electron microscopy examination, the fusion zone was observed to mainly consist of tempered lath martensite and some residual delta-ferrite. The mechanical properties including microindentation hardness, ultimate tensile strength and Charpy impact energy were evaluated in the post-weld tempered condition and correlated to the microstructures and defects. The ultimate tensile strength and Charpy impact energy values of all the fully penetrated welds in the tempered condition were acceptable according to ASTM, ASME and industrial specifications. The failure mechanisms during tensile deformation and Charpy impact loading were examined by scanning electron microscopy, fractography and optical metallographic analysis near the fracture origin.

Jan 1, 2015

By J. G. Henning, T. R. Yu, J. E. Croxall

"Test work was carried out to investigate the thermal response of loose and solid rock under varying environmental conditions. The primary interest was to develop a technique that could be used to increase the thermal variation between loose and solid rock for better detectability of loose rock underground with a thermal imaging infrared scanner.A variety of thermal enhancement methods were evaluated both in the laboratory and in the mine environment. Air temperature variation created by the exhaust from diesel driven, mobile mining machinery was studied in detail. When sufficient hot exhaust was supplied to the air, unsteady thermal conditions became more pronounced on the rock surf ace. This allowed a greater percentage of loose rock to be detected by a high-resolution infrared scanner within minutes.The degree of thermal enhancement of loose rock was found to be dependent directly on the thermal conductivity of rock, looseness, air temperature change, and inversely on the size of loose, airflow rate and distance downwind from the heat source. It was also found that an air temperature rise of at least r c, or rock temperature differential of1°C was necessary for minimal thermal enhancement required f or infrared detection."

Jan 1, 1990