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By R. W. Smith, M. E. Brookes

The temperature at which th: quenched 0' (ordered bcc) phase transfo.rms to the ( (complex hexagonal) phase on heating has been examined for certain Ag-Zn and Ag-Au-Zn alloys using an electrical resistivity method. The transition temperature decreases by approxinzately 7°C as the zinc content is reduced by 1 at. pct. The critical temperature, Tc, for long-range order has also been measured for a number of Ag-Au-Zn alloys. Extrapolation to zero gold content suggests that Tc decreases by approximately 5°C per 1 at. pct reduction in zinc content. The 0 phase of the Ag-Zn system exists over a narrow range near the composition Ag zn,' Fig. 1, and has a bcc structure which is disordered above 272°C. Slow cooling to temperatures below the range 274"/258"C allows the complex hexagonal phase, r° to form.2 This is the stable structure at room temperature.3 Upon quenching 0 -phase alloys from high temperatures, it is found that the 0 — (' transformation is suppressed; but ordering takes place (i.e., 0 -0'). This ordered structure can also be obtained by the room-temperature aging of cold-worked (0.4 Deformation of the 0' phase gives rise to a fur- ther hexagonal phase ( (of nearly ideal axial ratio) which reverts to b' within a few hours.= In view of this, it has been suggested that the equilibrium struc-

Jan 1, 1969

By Henry J. Williams

The main difficulty in the determination of silicon in pig-irons containing very high percentages of that element, has been due to their almost complete insolubility in acids, or mixtures of acids. The object of the present paper, which presents no new principle, is to suggest a method of determination which has repeatedly given accurate results, and which obviates completely the tediousness and uncertainty of the usual slow solution in acids. This method has been tried with pig-irons containing from 7 to 14 per cent. of combined silicon, and properly called ferro-silicons. When reduced to an impalpable powder in the agate mortar, an 11 per cent. ferro-silicon was found to resist the action of all acids, or mixtures of acids, with the exception of sulphuric acid of about 1.25 specific gravity. But the action of this acid, even during long continued heating, was very slow, 72 hours being necessary to com pletely dissolve half a gramme of the metal. The complete decomposition of 1 gramme of the metal may, on the other hand, readily he effected in a few minutes by fusion with sodium carbonate in a covered platinum crucible over a blast-lamp —the idea being to dissolve the silicon, leaving the iron in condi tion to be readily attacked by acids. The silicon dissolves as soluble sodium silicate, and metallic iron remains in a very spongy and finely divided condition. The addition of a little hot water

Jan 1, 1889

Asbestos is a commercial term applied to fibrous varieties of several minerals, the properties of which are not generally appreciated by the majority of geologists. A thorough knowledge of these properties and of the uses of asbestos is of fundamental importance in the assessment of the economic value of an occurrence of asbestos. The varieties of asbestos that are used predominantly by the manufact- urers of asbestos products are chrysotile, crocidolite and amosite but chrysotile constitutes 95% of the world's usage. It is the properties of high tensile strength, 'heat resistance and large surface area that make chrysotile asbestos the most acceptable of the mineral fibres. There are no known exploration aids, other than direct visual inspec- tion of outcrops in ultrabasic environments, that could be used in the exploration of chrysotile asbestos. The surface exploration of an occurrence of chrysotile asbestos is relatively routine, though it lends itself to a unique form of bulk sampling by the use of a twelve inch diameter diamond drill core. The laboratory assessment of the prop- erties of the actual fibre requires specialized techniques and tests to assess not only the amount of fibre present but also its length distri- bution, inherent strength, filterability, dust content and other prop- erties. The way a fibre reacts to milling will determine what milling process- es must be implemented to ensure a product that is acceptable to the asbestos product manufacturing industry.

Jan 1, 1971

By W. Rostoker, S. Spachner

A N alloy of 50 pct Ni-50 pct Fe is currently manu- factured in tape thickness down to 1/8 mil. In the annealed form, this alloy produces an almost square hysteresis loop. This has generally been related to the fact that by proper rolling and annealing practice a sharp cube, (100) [OOl], texture can be developed. As part of a program directed toward an understanding of the relationships between magnetic properties and structure of tape core materials, analyses were made of preferred orientations in tapes of various thicknesses. Annealed tapes of this alloy in 2, 1, 1/2, ¼, and Y' mil gages were acquired from commercial sources. Pole figures constructed for the 2 and 1 mil tapes showed the expected sharp cube texture. However, the ½, ¼, and ? mil annealed tapes showed no evidence of any preferred orientations. A comparison of two transmission patterns is shown in Fig. 1. The origin of the absence of texture in the tapes of less than 1 mil thickness was explored in some detail. The basic questions were whether the heat treatment for the thinner tapes was wrongly selected, whether the initial cold worked textures were different, or whether the actual thickness of the tape exercised some influence on its annealing characteristics. Quantities of the five gages of tape were acquired in the as-rolled condition just prior to the final anneal. Pole figures of the cold worked textures were constructed for each of the tapes. Eye estimates of in-

Jan 1, 1956

By E. E. Russell Tratman

The use of dynamite in cold weather is attended with some difficulty, owing to the freezing of the material and its consequeut liability to fail to explode when the fuse is fired. With proper methods and care the dynamite can be thawed with reasonable safety, but numerous accidents occur (more than get reported in the public press), due to carelessness in the operation and to the treacherous nature of the material, or a combination of both conditions. Dynamite will stand treatment at one time which at another time will result in explosion. An expert on explosives says that the most dangerous means of thawing cartridges are ingeniously devised by ignorant laborers; baking, boiling and toasting being favorite methods, while at a stone-quarry, in one instance, an apparatus was arranged for steaming the cartridges over a pot of boiling water. In this latter case the nitro-glycerine leaked through the canvas cover and settled on the bottom of the pot, with the result that an explosion occurred, the water acting as a tamping to the charge. The fact that small quantities of explosives containing nitroglycerine will burn quietly and without explosion if ignited by direct contact with a flame, has led to the dangerously mistaken reasoning that merely heating the explosive can produce no ill effect. If . a dynamite cartridge is ignited or placed in a fire it will probably burn harmlessly away, but if placed on a stove or in an oven and

Jan 1, 1893

By G. J. Wolga, W. W. Tyler, A. C. Wilson

THE physical properties of uranium have been reviewed by Katz and Rabinowitch.1 Their review includes thermal conductivity data for ternperatures above 375°K. Recently, Mendelssohn and Rosenberg' have published data on the thermal conductivity of uranium from 2" to 20°K. Our measuremerits indicate the temperature dependence of the thermal conductivity in the temperature interval from 20" to 300°K. Electrical resistivity and thermoelectric power were measured on the same sample. The material studied was normal uranium which had been heated at 700°C in a lead bath for 10 min and then quenched in a water bath held at 50°C. From this material a rod M in. in diameter and 2 1/2 in. long was machined. Two 0.040 in. holes were drilled into the rod 1 3/4 in. apart. Copper-constantan thermocouples for temperature and potential measurements were soldered to copper pins which were pressed tightly into these holes. Details of the equipment and experimental techniques used in making the measurements have been described elsewhere." Fig. 1 shows micrographs of a section of the sample studied. Fig. la was taken with unpolarized light and shows impurity inclusions, probably uranium carbide. Fig. lb, showing the same field, was taken with polarized light and gives some indication of the grain size and twinning within the grains. Experimental Results Thermal conductivity and electrical resistivity data are shown in Fig. 2. Table I shows values of

Jan 1, 1954

By McKinnon R. L

Laboratory and field work on the use of wetting agents for suppression of colliery dust is described. Although the results were inconclusive they were not discouraging and further investigation is required. The use of certain wetting agents may constitute a healthhazard.INTRODUCTIONCoal dust presents explosion and health hazards to the coal mining industry. The problem of dust suppression is particularly acute where water alone is unsatisfactory for this purpose. The addition of a surface active agent (wetting agent) to the water should enable the dust particles to be more easily wetted and thus more easily prevented from entering and spreading through the mine atmosphere.Investigations into this effect carried out at The University of Sydney mainly under research grants from The Joint Coal Board (Dawson and Hargraves, 1955; Charlton and Curnow, 1957) are summarized, and information on the possible harmful effects of certain wetting agents is given.Twelve local manufacturers and five importers supplied 52 wetting agents in liquid, solid, powder, and paste form.The active material content varied from approximately 10 per cent to 100 per cent and the cost per pound from 8d. to 14/3.LABORATORY TESTINGPossible test methodsThree methods of laboratory testing were considered.1. The standard method for comparing wetting agents is the Draves test, used in the textile industry on cotton...

Jan 1, 1961

By John E. Kelley

A method for measuring the spark-shower radiance of metals when abraded on a grinding wheel was developed by the Bureau of Mines for evaluating the sparking tendency of metals. The radiance was measured in units of emissive power per solid angle per area of the detector. Over 100 metals were tested and rated relative to commercially pure iron. The metals tested included elemental metals, iron binary and ternary alloys, iron-carbon ternary alloys, commercial steels, nonferrous alloys, and a few hard-metal compounds. Some alloys were synthesized; others were obtained commercially. Alloys that possessed good strength properties were emphasized for selection. The results indicate that the spark-shower radiance of plain carbon steels and carbon alloy steels was greater than that of pure iron. Certain elements, particularly vanadium and chromium, reduced the sparking tendency of iron. Stainless steels and particularly nickel alloys displayed low spark-shower radiance. Some metallic elements had much lower radiance than iron; others, much greater. Plain carbon steels, heat treated to a variety of hardnesses, gave radiance values that generally increased with increasing hardness. The effect on sparking tendency of an increase in hardness of an alloy steel was studied. The sparking tendency increased with an increase in hardness to a maximum, then decreased with a further increase in hardness.

Jan 1, 1974

By L. W. Higley

It is estimated that well over 20 million lb of chromium and 8 million lb of nickel, plus other metal values, are diverted annually to furnace dusts, mill scale, and contaminated swarfs in the domestic stainless and other specialty steelmaking industry. Little inroad has been made toward the in-plant recycling of these wastes to reclaim the metal values. The Bureau of Mines has devised a process for recovering about 90 pct of the chromium and molybdenum and well over 90 pct of the nickel and iron from stainless steelmaking furnace dusts, swarf, and mill scale. Other metals such as manganese are also recovered. Initial laboratory results were confirmed and expanded to include a wide variation of stainless steelmaking waste mixtures. Later experiments have included specialty steelmaking wastes other than from stainless steelmaking. Significantly, the ease of technology transfer has been demonstrated by a number of industrial-sized (19-ton) commercial electric furnace heats, in which the pelletized wastes represented some 10 to 20 pct of the furnace charge, replacing part of the normal scrap charge. Results of these successful large-scale trials are presented. Some information is also presented on incorporation into the pellets of chromium-bearing particulate wastes originating from other than steelmaking production. Cost evaluation indicates the process is economically attractive.

Jan 1, 1982

By J. A. Dubinski

One of the greatest threats of mining in hard coal mines are underground fires, which in the past often resulted in the mining disasters. Implementation of scientific principles of fire fighting into practice contributed to a significant reduction of fire hazard in coal mines. However, despite numerous achievements of science in the fight against the underground fires, they still occur creating a potential hazard for the miners and contributing to generate significant costs of fire-fighting operations, the temporary suspension of production or loss of longwalls. This concerns both spontaneous fires and exogenous ones. A significant decrease in the number of spontaneous fires was the result of cooperation between Polish scientists with experts in the field of new methods of fire hazard prediction and selection of new fire prevention and fire hazard monitoring methods. A significant part played here researchers from the Central Mining Institute. The original method of endogenous fire risk assessment based on calorimetric tests of coal and developed mathematical model of the process of coal self-heating allow to predict the risk of spontaneous fires and select proper fire prevention measures adequate to the involved risk. The frequency of exogenous fires is in the last few years is low, but their share in the total number of fires is relatively high and constitutes about 30%. This results from the prevention activities, carried out regularly in mines which are aimed at reducing the fire hazard connected with the use of fire-resistant conveyor belts and other non-metallic materials. Further directions to reduce the hazards connected with underground fires should focus on improving the methods for monitoring hazards together with automation of fire fighting operations.

Aug 1, 2013

By Raphael G. Kazmann

The predicted warming of the earth's surface, presently the subject of much debate, controversy and legislation, is based on what is termed "the greenhouse effect." This is the result of the property of certain atmospheric gases. These gases allow the passage of radiant energy to the earth's surface and reflect back, to the earth, the infrared radiation given out by the heated surface. Physicists have computed that if there were no greenhouse effect the average temperature of the earth, now about 15° C (60T), would be close to -18° C (OT). Just what gases have produced this salubrious effect? Water vapor is the most important. Then come carbon dioxide, methane and a number of minor constituents of the atmosphere, both natural and man-made. Climate change, its cause and its impact on human activities have been the subject of scientific and historical study for more than a century. Recently, some scientists have concluded that if the man-made increase in the carbon dioxide and other greenhouse gases continues, by the late 21st century the earth's global average temperature will rise between 2° to 8° F. This temperature rise would cause the water in the oceans to expand and the massive polar glaciers to melt. In 1980, it was predicted that the sea level would rise 7.6 m (25 ft) by the late 21st century. By 1985, the predicted rise was 1 m (3 ft); and by 1989, it was 0.3 m (1 ft) (Jastrow, Nierenberg and Seitz, 1990). Agricultural scientists have pointed out that an increase in atmospheric carbon dioxide would enhance biological growth including the production of foodstuffs.

Jan 1, 1992

By A. Koursaris, J. B. See

An investigation is described in which the resistivities of Mamatwan manganese ore, Delmas coal, and Iscor coke, at temperatures or up to 1400°C were determined, as well as the resistivities of mixtures of ore of a constant size range with Delmas coal or Iscor coke of three different size ranges. The resistivities of the ore and the coal were characteristic of those for semi-conducting materials, were strongly influenced by temperature, and decreased by several orders of magnitude between room temperature and IOOO°C. The resistivity of the coke changed only slightly between room temperature and 1400°C, and the resistivity of the coal approached that of the coke at I300°C. This provides support for the theory that the resistivity of carbonaceous reducing agents is primarily a function of heat treatment, and not of the rank and composition of the coal. Above 1200°C, the resistivity of mixtures of ore and coke fell steeply owing to an increase in the volume fraction of coke in the mixture and to the formation of slag. The results were similar for the three different size ranges of coke. The extremely high resistivities of ore-coke and ore-coal mixtures at Iow temperatures indicate that there is unlikely to be much conduction of current in the higher regions of a furnace. Thus, the resistance of a furnace is governed mainly by the conditions at the electrode tips and in the molten regions. To explain the very Iow resistances of furnaces, usually, about I m£?, it would be necessary for investigations to be conducted under conditions similar to those in the active zone of a furnace.

Jan 1, 1980

THE first session of the production engineering group on Wednesday, morning, with J. B. Umpleby as chairman, recorded the principal developments since the Fort Worth meeting. Added to this was a lively discussion of pressure maintenance. Recent advances in the air-gas lift have resulted from the need of applying the method to smaller wells at lower costs. In many places intermittent flow has given excellent results, and numerous mechanical de-vices for its automatic control have been, developed. Papers by C. V. Millikan on the Mid-Continent field and by A. H. Bell on California, fields formed the basis for discussion. The maintenance of initial sand pressures was ably discussed for two Texas fields by t. V. Foran in a paper that not only outlined the technic of operation and the results obtained but also contained noteworthy cost data in terms of increased ultimate production. Mr. Foran recommends the use of air in the first stages of pressure maintenance as a means of determining sand conditions and directions of flow, later turning to gas, if available, because of its greater solubility on oil. A round table discussion on petroleum engineering educational problems, with H. G. George as chairman, brought out much interesting discussion that is difficult to summarize. The other Wednesday morning session was a refinery engineering symposium with T. G. Del-bridge as chairman and the economical application of heat for the general topic. A paper on the modern pipe -still, by H. S. Bell, and another by C. W. Stratford on the modernization of the cylindrical still elicited a lively discussion.

Jan 3, 1928

By Luther Wagoner

Having given in a former paper1 the results of assays of sea-water, bay-mud, dredgings from San Francisco bay, etc., and believing it might be interesting to extend the work to include some deep-sea dredgings, I procured from the Smithsonian Institution six samples taken by the U. S. steamer Albatross, and marked as follows: Depth in No. station. Locality. Latitude. Longitude. Fathoms. 1. 2103. Off Delaware bay. 38' 47' 20" N., 72o 37' W., 1,091. 2. 2265 to Between Chesapeake 35° 37' N., 74O to 75O W., 49 to 70. 2297. bay and Hatteras. 3. 2420. Off Chesapeake bay. 37' 03' 20" N., 74O 31' 40" W., 104. 4. 2528. East of Georges 41° 47' N., 65o 37' 30" W., 677. bank. 5. 2572. SE. of Georges bank. 40° 29' N., 66O 041 W., 1,769. 6. 2681 South of Nantucket. 39' 43' N., 70' 29' W., 990. The above samples were assayed by the cyanide-method, described in my former paper (p. 807), about 30 g. of sample being used, and the following results were obtained: Value in Milligrams Per Metric Ton. No. Station. Gold. Silver. 1. 2103. 145 1,014 2. 2265 to 2297. 44 304 3. 2420. 15 353 4. 2628. 267 1,963 5. 2572. 125 377 6. 2681. 66 414 No. 4, Station 2528, consisting of red clay and volcanic ash, mas re-assayed ; 35 g. was roasted at a low heat for one hour and weighed 34.05 g. after roasting; the color was changed to a deep brick-red; and when assayed by the cyanide-method

Jan 1, 1908

By L. W. Helle

This paper summarizes the investigations carried out into a defect involving the corners of billets rolled from continuously cast blooms, which broke open during the rolling process. As it was believed that the defect must be connected with the formation of subcutaneous blowholes in the bloom, the investigations were directed towards an understanding of the roles of the three gases involved in the process. In an extensive trial programme, samples were taken from the heat at all stages of processing, as well as from all the raw materials and alloys. The main sources of nitrogen were found to be re blows, pick-up from the alloys added to the ladle (especially graphite), and open-stream casting. The major source of hydrogen was moisture in the alloys, especially high-carbon ferromanganese and silicomanganese. Further, it was established that the moisture content of the alloys is closely related to the appearance of the defect in steels with a carbon content of less than 0,20 per cent; 72 per cent of all the defects were present in this type of steel. Most of the remaining defects were found in steels with a carbon content of more than 0,60 per cent, where the nitrogen content was substantially higher than in the lower-carbon steels. It is suggested that the defect arises from the combined effect of oxygen. nitrogen, and hydrogen. Its occurrence in low- and high-carbon steels is triggered by the formation of subcutaneous blowholes when the critical oxygen level for carbon monoxide blowholes is lowered by the presence of excessive amounts of hydrogen and nitrogen respectively.

Jan 1, 1984

By James W. Mitchell

On December 2, 1942, a scientific team lead by Nobel Prize winner Enrico Fermi first initiated and controlled a self-sustaining nuclear chain reaction. This historic event occurring beneath the stands of the University of Chicago football stadium instantly created an entirely new and tremendously broad area of technology. Indeed, the event probably changed the course of world history and considering the curret energy shortage, it probably came none too soon. Following many technological breakthroughs in the ensuing years, this event led to the first full scale nuclear fueled electric generating plant. In December, 1957, the Shippingport Nuclear Power Plant became operational and the United States had entered the era of the nuclear fueled electric generating station. Today, only fifteen years later, there are some thirty-five operating nuclear power plants in the United States with another 56 under construction and 116 on order. Still, we are only scratching the surface of this tremendous energy source. In 1970, less than one-percent of the total electric generating capacity in the United States was nuclear fueled. By 1985, it is projected that 45% of our generating capacity will result from nuclear power plants. These projections are based upoa statistics of six months to a year ago and considering the current energy shortage and recent attempts by the United States Atomic Energy Commission (USAEC) to speed the licensing process and encourage standardized plants, the contribution of nuclear power to our total generating capacity may be even greater. In summary, it is obvious that nuclear power is now, and will continue, playing an important role in our future. Those factions of government, industry and the professional community charged with fully developing this tremendous energy source must deal with it rationally, logically and expediently. The various environmental considerations in nuclear plant siting play an important role in the overall plan.

Jan 1, 1974

By Clarence Linville

IN an article published in the Iron. Trade Review 1 I gave a convenient arrangement for the installation of wet and dry bulb thermometers for use in making moisture determinations in the air being blown into a blast furnace, and also gave a chart for use in obtaining moisture values from the thermometer readings. The data from which this chart was prepared were obtained from the tables in use by the U. S. Weather Bureau.2 The work of Carrier 3 has shown that these tables are somewhat in error. He has recalculated the values for moisture as referred to, wet and dry bulb thermometer readings, and he has prepared a psychrometric chart from the values thus obtained. This work has priced the subject of psychrometry upon a correct scientific basis. I think it is proper that we should recognize the importance of his work and give him credit for one of the most interesting and valuable researches that have been published in recent years. Blast-furnace men are not ready to use, as he suggests 4 a value expressed in grains of water accompanying a pound of dry air. However convenient this may be for heating and ventilating work and other engineering problems, there are several reasons for preferring the use of a value expressed in grains of water in a. cubic foot of mixed air and water vapor, in connection with combustion phenomena and the effects of moisture on blast-furnace operation. Previous papers presented to the Institute have used such values and we have

Jan 10, 1913

By John Tyssowski

IN 1925, Harry Howard Stout, then metallurgist for Phelps Dodge Corporation, while investigating the cleaning of cathode copper by various gases at elevated temper-atures below the melting point of the metal, observed in the laboratory that particles of pure copper heated in a closed tube filled with hydrogen seemingly "stuck together." By further investigation he found that there was actual crystal growth across the boundaries of the particles of pure metal; in other words, there was a complete new crystal realignment and growth throughout the newly formed copper mass. It was coalescence, not adhesion; the several parti-cles had become one unit. From this dis-covery has been developed the coalescence process, whereby copper of cathode purity is squirted out in semifabricated form from an extrusion press, by the appli-cation of about 30c0 tons pressure on a 10-in. piston. Stout decided that cathode copper pro-duced by electrolytic deposition was the logical source of the pure copper required for the coalescence process, but as there was no way of reducing the ordinary tough commercial cathodes to the small particles required he was confronted by a serious problem at the outset. Under his direction, this problem was solved by William H, Osborn and Harry Howard Stout, Jr. They developed the process and technique for producing cathode copper in brittle, friable form, and to them must be given the greater part of the credit for this phase of the development program as well as for that relating to the gas cleaning of the cathode particles.

Jan 1, 1940

By M. R. P. Snow

"This paper outlines geotechnical conditions that commonly exist in underground, hardrock mines and the challenges posed for ground-support steel, specifically rockbolts, used in these environments. A model is proposed whereby the in-situ stress and rock-mass classifications (based on Bieniawski’s rock mass rating) form the basis of determining the desired steel properties of the rockbolts used. Based on the ASTM F432 bolting specification, recommended minimum steel properties are defined for three ranges of in-situ stress levels, each with their own six ranges of RMR values. Heat treatment for the steel can be specified once these minimum steel properties are known.RÉSUMÉ Le présent article décrit les conditions géotechniques qui existent fréquemment dans les mines souterraines de roches dures et les défis que cela pose pour le soutien de terrain en acier, plus spécifiquement les boulons d’ancrage utilisés dans ces environnements. Un modèle est proposé dans lequel les contraintes in situ et les classifications de la masse rocheuse (selon la classification de la masse rocheuse de Bieniawski) servent de base pour la détermination des propriétés désirées pour l’acier des boulons d’ancrage utilisés. En se basant sur les spécifications de boulonnage de l’ASTM F432, les propriétés minimales recommandées pour l’acier sont définies pour trois plages de niveaux de contraintes in situ, chacune avec sa propre plage de six valeurs de classification de la masse rocheuse (RMR). Un traitement thermique pour l’acier peut être spécifié une fois que ces propriétés minimales pour l’acier sont connues."

Jan 1, 2016

By S. J. Rothman, A. L. Harkness, L. T. Lloyd

Self-diffusion in Y uranium has been measured using U235 as the tracer isotope. The diffusion coefficient fits an Arrhenius-type equation D = 2.33 x 10 -3 exp (- 28,5000/RT) cm2/sec The values of Do and Q are unusually low and are not consistent with the values expected from theories based on a simple vacancy mechanism of diffusion. CYLINDRICAL samples, 1 cm in diam and 1/2 to 1 cm long, were prepared from high-purity uranium containing 0.0343 pct u235, Table I. The samples were water quenched from 690°C (the a-ß transformation is at 668°C) to remove preferred orientation, and annealed at 450 "C to minimize residual stresses. One end of each cylinder was polished on a 1-µ diamond lap and electropolished in a phosphoric acid solution. After a final cleaning by cathodic sputtering, a 1- to 3-µ thick layer of the tracer isotope, uranium containing 93 pct u235, was sputtered onto the sample.' To prevent contamination during the diffusion anneal, the diffusion couples were placed in a tantalum cup and covered with another piece of uranium, and the whole assembly was sealed off in an evacuated quartz tube. Annealing temperatures were constant within +2.0°C. The samples were heated and cooled slowly between room temperature and the ß-? transformation (774°C) in order to minimize distortion of the sample surface that might arise from aniso-tropic thermal expansion and density changes during phase transformations. After machining off 1/16 in. from the radius to

Jan 1, 1961