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By G. B. McClurg

China was nota factor in the supply of fluorspar to the United States until the early 1980's when it shipped in its first package of Metallurgical lump, that not only was higher grade than the Mexican Metallurgical spar but was also about $30.00 a ton cheaper landed at Burnside. Representatives of the Mexican Fluorspar Institute and several producers made trips to see the Chinese operations supplying their once reserved market place. China, an enigma to most Westerners suddenly became the new contender, with prices that were disgustingly low or so thought the other exporters. Of course China has been mining, producing, consuming and exporting from 400,000 to 500,000 tons per year of various grades of fluorspar but until the first partloads came to the U.S., very little attention was paid to their exports by American-continent producers or consumers.

Jan 1, 1986

By H. M. Kim, J. Rutqvist, D. W. Ryu

"Demand of high pressurized gas storage in underground rock caverns is increasing. Compressed natural gas (CNG) and compressed air energy storage (CAES) are one of the promising examples after since lined rock cavern (LRC) concept has been verified through in-situ pilot tests. Two key essential concerns of high pressured gas storage in underground rock caverns are mechanical stability of the cavern against high inner storage pressure and the risk of gas leakage from the caverns.In this study, we introduce our results of numerical simulations so as to investigate the potential of monitoring for gas leakage at a pilot facility for CAES in underground LRCs. The pilot facility was constructed at a comparatively shallow depth of 100 m, compared to the previous cases with several hundreds of meters, aiming at validating the feasibility of the LRC storage concept in which inner sealing liners, consisting of steel plate and concrete linings, are installed inside the excavated rock caverns (KIGAM, 2011). Compressed air may leak through either initial defects of inner containment liners such as imperfect welding regions and in-situ construction joints of the liners, or through structurally damaged points of the liners during the CAES operation where compression and decompression of the caverns are necessarily repeated and their structural robustness can be deteriorated.For this perspective, we carried out a coupled thermodynamic and geomechanical deformation analysis using TOUGH-FLAC simulator, and investigated the effectiveness of strain monitoring method in detecting mechanical failure of liners which may provide major pathways of air leakage. We therefore used an equivalent continuum model to relate the localized tangential strain to fracture permeability changes, which was developed in our early work (Rutqvist et al, 2012). In detecting and characterizing the leakage location, we tested a cross correlation technique using the synthetic pressure responses monitored in case of the failure of the inner liners. From the investigations, we showed that tangential strain, rather than radial, monitoring especially at the inner face of the sealing liners can be more effective in detecting the mechanical failure of the liners.In localizing the leakage point, we noted that the interface between the inner liners and surrounding rock may not be perfectly bonded so as to increase permeability through which any leaking air pressure may migrate more dominantly. We also demonstrated that the cross correlation of the time histories of pressure measurement especially at these interfaces can be useful in identifying the leakage point. These results may provide useful information in overall design of monitoring and alarming system of our upcoming CAES pilot facilities."

Jan 1, 2015

By C. O. Campbell

THE recognition by C. W. McKee, field engineer for Springer Sturgeon Gold Mines, Limited, in the fall of 1940, of the economic possibilities of a small outcrop of baryres near Pembroke, in Hants county, Nova Scotia, followed by aggressive exploration and development by the Company, has placed Canada for the first time in its history in the position of becoming a major producer of barytes and its products. In past years, production of this mineral in Canada has been unimportant. Thus the coral output from 1885 ro 1933, inclusive, amounted to only 41,027 short tons, following which there was no production until 1939. Deposits in Nova Scotia, and particularly in the Lake Ainslie district, Cape Breton, have been the main source of supply, with a production between 1866 and 1925 of 31,689 tons. Following the examination of the outcrop of baryres near Pembroke by Mr. C. W. McKee in October, 1940, the area surrounding it was trenched, and, as this work gave encouraging results, a diamond drilling programme was commenced. A grid system was laid our and sixteen holes aggregating 2809.3 feet were put down, spaced at 100-foot intervals, the deepest hole being 300 feet. This drilling outlined a body of high-grade baryres over 600 feet long and 200 to 250 feet wide, with an average depth of 120 feet and estimated to contain well over one million tons of ore. The limits of the body were reached on the west, north, and southwest, but the drilling was suspended before the eastern limit was determined. Quarrying operations, and construction of a 100-ton mill, were commenced in February, 1941. The mill was placed in operation on May 29th, and on June 15th, eight months after the initial discovery, the first shipment of 2,500 long rons of milled baryres was made to Trinidad, British West Indies.

Jan 1, 1942

By Elizaveta Cheremisina

In steelmaking process lime serves as flux. Rapid lime assimilation and slag formation of the desired composition have a significant effect on the refining reactions. It is important to know the rate limiting step of lime dissolution to control and improve the converter process. Kinetics of pure CaO and industrial lime dissolution in model slag has been studied in the range of temperatures 1300 –1600°C. Lime samples were prepared in cylinder form and immersed in the melt for predetermined time. Considering the total mass balance of CaO in the slag and linear dimensions of lime samples, mass transfer coefficients were derived. Diffusion coefficients were calculated under conditions of non-stationary diffusion. The derived activation energy of less than 200 kJ/mol indicates that diffusion is the limiting step in the process of lime-dissolution in slag.

Oct 30, 2017

By M. Razavi

This investigation is part an overall investigation on the effect of sodium silicate on the properties of the mine backfill. The results presented will highlight the effects of binder dosage, sodium silicate concentration, and pulp density on the performance of stabilized sodium silicate-fortified sand pastefill samples. Binders implemented for these experiments consisted of cement, slag, and sodium silicate in various proportions. The binder content varied from 3 to 9 wt% (total dry weight) and sodium silicate concentrations was adjusted at 2 and 4% (total binder weight). Moreover, pulp density was adjusted to values between 80 and 83 wt%. For completion of the aforementioned phase of the study, series of sand pastefill test samples were prepared and cured for 28, 56, or 120 days, in a humidity and temperature controlled room. The specimens were tested for uniaxial compressive strength (UCS). In order to study the effect of sodium silicate on microstructures of stabilized sand pastefill, some MIP tests were conducted on selected samples. The results of this investigation evaluate the use of sodium silicate as a partial replacement of cement in stabilized backfill. The analyses of the results demonstrates that, with an increase in binder content and a decrease in pulp density, the UCS values of sand pastefill samples increase. Further more, the results indicate that increase in addition of sodium silicate does not necessarily result in higher strength minefill.

May 1, 2007

By A. Lam

The use of a liquid fed direct methanol fuel cell (DMFC) as a power source for micro and small portable applications is attractive due to its system simplicity, low temperature, etc. The aqueous methanol is directly oxidized and does not require additional fuel processing steps as in reformate based PEM fuel cells. In addition, the use of a liquid fuel is advantageous with respect to humidification, stack cooling and system energy density. The DMFC however, has technological issues that must be addressed before it can be widely adopted, particularly in larger applications such as small utility and transportation. At present, the crossover of methanol from the anode to the cathode is a major limitation on DMFC performance and fuel utilization efficiency. In this paper we discuss the influence of fuel modification on the control of crossover. This involves the use of different fuel additives and concentrations to minimize crossover. This appears to be the first reported case of the use of fuel modification (additives) to reduce methanol crossover. The rate of methanol permeation under passive conditions is discussed with respect to the different conditions.

Jan 1, 2005

By E. W. Davis

This paper deals with the role of the Maintenance Department in a milling operation; specifically, the Mines Development, Inc., processing plant at Edgement, South Dakota. The goal of very maintenance department is the smooth and uninterrupted operation of the plant it serves, To achieve this goal, maintenance men adapt various features and procedures into a program designed to fit the characteristics of their particular plant operation. A few of the basic elements of a sound maintenance program are: 1, A periodic preventive maintenance schedule. 2, A systematic inspection and lubrication procedure. 3. A training program for maintenance personnel. 4 A good equipment-history file system, 5. A carefully planned spare parts inventory.

Jan 1, 1962

By J. D. Scott

The counter-current jarosite acid wash circuit presently in operation in the zinc plant produces a combined jarosite plus Pb/Ag residue which is discarded. Extensive pilot-scale testwork, and some past in-plant operational experience, has shown that the zinc plant can be easily reconfigured to produce two residues during periods of high silver feeds and/or prices. Plant.optimized circuit configurations are available for silver recovery to a Pb/Ag residue and are in use for the prevention of Pb/Ag-jarosite formation in both the neutral and high-acid leaching circuits. Silver in the zinc plant undergoes several changes in state as it proceeds through these circuits. The roaster calcine is ~3:1 silver sulfate: silver metal, with metallic silver mainly as micro-Inclusions In an aluminosilicate phase. In neutral leach residue, the majority is as silver sulfide or Pb/Ag/Zn-sulfide coatings on unroasted sphalerite grains, with minor Pb/Ag-jarosite and some residual metallic silver in unreacted alumina-silicate grains. In high-acid leach residue, silver occurs as Se-rich silver sulfide particles in sulfur/jarosite ball aggregates, as silver sulfate impregnations in silica-gel masses and in solid solution in Pb/K/Zn~jarosite. Silver concentrations in solution range from 20 to 60 ppb.

Jan 1, 1990

By M Hood, X S. L, W J. T Daniel, H Gurgenci

It is believed that disc cutter shape affects rock fracture and therefore cutter performance and cutter life. However, the current generation of disc cutters is made of hardened steel and these cutters wear rapidly and consequently they are unable to maintain their original shape in strong and abrasive rock. This wear problem could be reduced if the cutter was made from a harder material. Unfortunately as material hardness increases so does the propensity for brittle failure. In this study the optimum cutter shapes were identified by studying the mechanics of rock/tool interaction. The results showed that bevel and wedge cutters are better than cutters with dome and flat edges. A new cutter was designed, based on this result, using a harder material to increase the life by a factor of 20.

Jan 1, 1998

By W. A. Weimer

Coal and coal mining is no longer the mighty king of industry and in our daily lives and homes that it once had the privilege of commanding. Many of you will remember that one of the chores of your youth was to bring in the scuttles of coal, morning and night, to feed the heater or stoke the furnace in the morning and bank it at bedtime. Growth of gas and oil have displaced coal in home furnaces and commercial buildings, and have taken over some segments of industrial markets. The coal burning locomotives have virtually disappeared in favor of the more efficient diesel engine. However, coal as a prime mover still holds its strategic position as is evidenced by act that the electric power industry almost entirely depends upon coal for its generation.

Jan 1, 1961

By E. Fockedey

he destruction of free cyanide on a Co3O4 doped carbon felt was studied. The experiments were done with an eiectrochemical filter press cell on dilute alkaline solutions containing 250 mg/l NaCN. No chloride ions were added to the solutions. The cobalt oxide protects the felt against corrosion and has a catalytic effect on the degradation of the cyanide. This kind of electrode allows working with current density as high as 1200 Aim without any visible degradation of the felt. The most interesting results were obtained with a current density of 400 Aim' at which the cyanide concentration can be lowered to 5 mg/l with a current efficiency of more than 70 % and a specific energy consumption of about 10 kWh/ kg CN.

Jan 1, 1998

By Y. Guo, C. Cao

"China is rich in tungsten resource, but they are mainly associated minerals. The similar flotability of scheelite, fluorite, and calcite resulted in the difficult separation by flotation. This work summarized the current situation and the development of flotation reagents, technological process, and mineral processing equipments in China. Fatty acid served as the collector and water glass was the depressant to expand the flotability differences in traditional flotation technology. However the water glass inevitably influenced the flotation of tungsten minerals to a large extend, and the suppressed fluorite was difficult to recover by flotation. Abundant water glass lead to the bad settleability of the tailings and the tail water was difficult to circulate, resulted in serious environmental problems. Recent study proved that the selectivity of benzene armour hydroxyl oxime acid (BAHA) salts was adequate for the separation of tungsten minerals from fluorite, calcite and most silicate minerals without any depressant. By this way, sodium silicate was canceled completely in tungsten flotation, greatly improving the recovery of tungsten and the environmental problems caused by tail water treatment would be solved fundamentally. TUNGSTEN RESOURCES AND DISTRIBUTION IN CHINA China is rich in tungsten resources and the proved reserves accounted for 60% of the world's reserves [1]. However the wolframite has been dried up and the scheelite resources had become the main resource of the tungsten metal. Table 1 showed the most large and superlarge scheelite deposits in China. China has more than 40 large and superlarge scheelite deposits and the total metallic deserves is more than 3 million ton [2]. But most of the deposits were low-grade and the associated relationship was complicated. For example, scheelite was usually associated with wolframite, molybonite, bismuthinite, pyrite, fluorite, and calcite in Shizhuyuan and Yaogangxian mine."

Jan 1, 2016

By F. C. Gibson

An electrical method for the continuous determination of propagation velocities in opaque, confined explosives, and propellants is described. A resistance element imbedded in the reactive material generates electrical signals that are displayed oscillographically and indicate the position and progress of a reactive zone associated with progress of a reactive zone associated with burning or detonation. The method is applicable to both solids and liquids.

Jan 1, 1963

By Phillip J. Maddex

Transportation is a major part of yours in the industrial minerals industry. Whereas federal income taxes merely take 50 per cent of your firms profits, transportation cost may take 50 per cent of the gross realization - selling price plus transportation - on your product, f. o. b. customers plant.

Jan 1, 1969

By Stanley Davidson

"This description of the structural geology of the Beattie mine has been condensed from a more comprehensive paper published previously (4).The property is in western Quebec, a short distance east of the Ontario boundary on the extension of the so-called Porcupine belt into Quebec.According to the geological surveys of the Dominion and Provincial Governments the regional structure in the vicinity of the mine is an easterly pitching, overturned syncline with several thousand feet of Timiskaming sediments in the centre surrounded by Keewatin volcanics (1, 2, 3).The mine lies on the north limb of the syncline, and the Keewatin series in this locality is, with few exceptions, overturned, dipping steeply north and facing south.The mineralization is closely related in space, and possibly genetically, to a body of syenite porphyry intruded into the Keewatin series along the north limb of the syncline. No ore has been found very far from the syenite or related lath-porphyry dykes, and the largest orebodies are composite, consisting of bleached and brecciated volcanics ( primarily tuffs) adjacent to altered syenite porphyry, both silicified and mineralized with very fine pyrite and arsenopyrite. In addition there are important ore shoots following a fracture zone within the syenite."

Jan 1, 1954

By Thierry De Nys

A direct leaching process of sulphidic zinc-based concentrates in aqueous sulphuric acid solutions has been developed by the V.M. R & D Department. By a very accurate control of the oxidation potential of the leach solution, this process enables a separate recovery of the zinc, copper, silver, lead and sulphur of the concentrate and makes it extremely attractive for treating more complex ores. The iron, solubilized during leaching, is eliminated out of the zinc solution by means of the V.M. goethite process. Alternative flow sheets for a conventional zinc electrolysis plant are presented.

Jan 1, 1990

By X. Cao, H. Huang, Z. Dai

"Crystal phase of copper-containing slag regulation by the slag viscosity, cooling speed and cooling method, where the slag viscosity is related to the temperature and alkalinity. According to the mineralogy properties of a copper-containing slag, experiments of crystal phase regulation and flotation were conducted. When the copper-containing slag that adding a small amount of calcium oxide was cooled slowly at a rate of 3°C/min and about 1050°C n a cinder inclusion system, the viscosity of slag can be remained under 0.25 Pa·S and more than ??% of copper particles that the grain size is larger than 20 ?m in slag. The whole flow of flotation experiment was carried out to recover copper from the copper-containing slag with crystal phase regulating and the copper concentrate grade was ?????%, the recovery efficiency of copper was 94.18%.INTRODUCTIONChina's annual output of copper slag is more than 6 million tons, the current total has reached 80 million tons. It is equivalent to 640 thousand tons of copper metal with the copper grade of 0.82%. Most of the smelting slag were storage. It is not only occupy the land and pollute the environment, but also make a huge waste of resource (Alp, Deveci, & Süngün, 2008; Carranza, Iglesias, Mazuelos, Romero, & Forcat, 2009; Gorai, & Jana, 2003), therefore, it is good way to achieve copper slag resources by the effective recovery of valuable component from copper smelting slag, which is an important measure of the current process of copper smelting slag and implement the central authorities to vigorously develop the circular economy, improve the recycling of resources, increase copper production of intensive development (Zhou, et al., 1994; Zhang, Zhang, & Wang, 2005). Currently, researches on comprehensive utilization of the coppercontaining slag made a much progress (Wei, 2004; Liu, Gai, Yang, Sui, Li, & Fu, 2008; Liu & Zhu, 2008; Zhang, 2010; Sun, Chen, & Tang, 2012; Qin, Wang, Ren, Wei, Peng, & Gu, 2012). Flotation is one of the most effective method to recover the copper from smelting slag, which has the features of low cost and high efficiency (Song & Liu, 2001; Zhang, Wang, & Li, 2012). But the copper particles in the copper smelting slag distribution is very uneven, and the thickness of the material is very serious. The copper content in the micro level is higher, the size of copper sulfide ore is less than 0.043 mm, which leads to the difficulty of the monomer dissociation (Tossavainen, Engstrom, Yang, Menad, Lidstrom, Larsson, & Bjorkman, 2007; Moustakas, Mavropoulos, Katsou, Haralambous, & Loizidou, 2012). In this study, according the process mineralogy of a smelting copper slag, the crystal of smelting copper slag was optimized by controlling the temperature, alkalinity, cooling rate and cooling method, which makes the fine copper mineral particles in the copper slag crystal further, and can be used to meet the particle size requirements of flotation, thereby enhancing the flotation of copper."

Jan 1, 2016

By M. B. Greyver

The results of laboratory tests on iron precipitation from non-decopperized nickel anolyte are discussed. The parameters (pH, oxygen consumption and stirring speed) for iron precipitation from the anolyte, using the oxygen in the air, were determined. In the experiments conducted under optimized conditions, the residual concentration of iron in the anolyte after precipitation was 0.7-2.7 mg/L, and the copper and nickel losses to the solid phase were 0.05-0.07% and 0.05-0.16%, respectively. The filtration ability of the iron slurry obtained was 2 to 5 times higher as compared to that after chlorine oxidation and oxyhydrolysis. The leaching of the non-ferrous metals from the iron cake made using the separate nickel anolyte purification process was possible by dissolution in sulphuric acid. It was established that after cobalt precipitation from the copper- and iron-depleted anolyte, the precipitates obtained had lower ratios of Fe:Co and Ni:Co.

Jan 1, 2006

By John Wightman

LOCATION OF PROPERTY THE property of Caribou Gold Mines, Limited, is situated in the north-eastern part of Halifax county, seven miles south of the Canadian National railway line at Upper Musquodoboit. Approach to the village is by a secondary road, improved recently by waste rock from the mine dump. A two-wire telephone line, seven miles long, built and owned by the present operators, provides communication to the nearest telephone exchange, Parker's Corner. HISTORY In 1870, the Caribou area was recognized as a proclaimed gold district. From then on, operations were intermittent, with periods of considerable activity by small companies until there were no fewer than seven mines in a district two miles long by three-quarters of a mile wide. These were the Holman, Truro, Caffrey, MacDonald or Elk, Lake, Dixon, and Hilchey properties, all of which have had separate stamp-mills, and have produced gold for varying periods. Depths of the workings range from 100 feet to 1,000 feet. Power was generated at each property by means of steam boilers. At the present time, the Consolidated Mining and Smelting Company of Canada, Limited, controls all the leased areas, approximately 800 acres, and is operating by means of one central vertical shaft. GEOLOGY The district in and about Caribou Mines has an elevation of approximately five hundred feet above sea level. The area is fairly well wooded, with rock outcrops here and there. These outcrops, along with information from test-pits and shafts, have been the basis for the very excellent geological map of the district prepared by E. R. Faribault some years ago. The rock structure, which is one of the best examples in Nova Scotia of an elliptical dome, has its anticlinal axis in a northeast-southwest direction, and flat plunges in the same directions.

Jan 1, 1938

By G. Azimi, C. A. Ang, F. Zhang

"Nickel recovery from laterite ores generates large amounts of solid and liquid wastes. This is primarily due to the low concentration of Ni (about 1.4 wt%) in the feed ore to the High-Pressure-Acid-Leaching (HPAL) process. It is known that the HPAL residue contains a high concentration of hematite, a commercially important source of iron in the steelmaking industry. However, the balance is natroalunite, containing sulfur, which is a detrimental element in the steelmaking process. Hence, to make the HPAL residue a suitable feed for steelmaking, natroalunite must be removed. The current work is focused on: 1) a thorough characterization of the HPAL residue obtained from Vale, and 2) a systematic investigation of an alkaline leach process to remove natroalunite. The characterization results indicated that there are about 83 and 12 wt% hematite and natroalunite in the HPAL residue, respectively. The leaching results indicate that sodium hydroxide is the best leaching agent, which results in 55 wt% reduction in the sulfur content. The results of this work enable the conversion of an otherwise waste product into a useful feedstock for steelmaking. Furthermore, this project could potentially have significant environmental benefits by reducing the amount of residue produced during the HPAL process.INTRODUCTION Conventionally, crude steel has been obtained by reducing iron ore containing oxides such as hematite (Fe2O3), magnetite (Fe3O4), and wüstite (FeO) in a blast furnace with coke. The product is then refined in a basic oxygen furnace to produce steel with useful properties (McGannon, 1969; Turkdogan, 1978). Steel has been sought for its desirable properties and its application is widespread throughout modern civilizations. Surpassing the growth rate of other materials, the annual demand of steel has increased at a compound growth rate of 5% over the last 20 years (Baddoo, 2008). The global demand for steel was reported to be 1501 Mt in 2016 and demand is expected to double by 2050 (Cullen, Allwood, & Bambach, 2012; World Steel Association, 2016). In recent years, to meet the rapid growth of demand, secondary resources for iron have been identified as strategic sources of iron (Das, Kumar, & Ramachandrarao, 2000; Li, Sun, Bai, & Li, 2010; Matschullat et al., 2000). The residue produced from high-pressure acid leaching (HPAL) of laterite ore has been identified as one of the important secondary sources of iron (McDonald & Whittington, 2008). Laterite ore represents 60% of the world’s nickel resources and accounts for approximately 40-50% of the world annual nickel production (U.S. Geological Survey, 2016). Therefore, the amount of iron residue produced by the process is substantial and its utilization will produce both economic and environmental benefits."

Jan 1, 2017