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By C. M. Frost

The hydrodesulfurization characteristics of a residual fuel prepared from Wilmington, Calif., crude oil were determined at temperatures from 600° to 900° F, pressures of 200 to 800 pSig, and space velocities from 0.2 to 2.0 Vo/Vc/hr, using cobalt molybdate type catalysts. A prediction equation, developed from the experimental data, satisfactorily predicts the fraction of total sulfur that can be removed under any combination of operating conditions within the ranges investigated. Yields and properties of the low sulfur product are correlated with the fraction of total sulfur removed. Kinetic calculations show that the apparent reaction order and activation energy change with space velocity and temperature.

Jan 1, 1970

By J. L. Jambor, E. J. Reardon, E. C. Appleyard, J. A. Cherry

Abstract- Since the 1957 initiation of deposition of mill tailings at the Heath Steele mine, New Brunswick, periodic detailed studies of the tailings geochemistry and mineralogy have been con­ ducted, thereby providing a unique opportunity to examine the geochernical evolution of a sulfide- rich mine-tailings impoundment. When deposited, the tailings contained about 85 wt% sulfide minerals, 1 wt% to 3 wt% carbonate minerals, and 12 wt% to 14 wt% aluminosilicate minerals. Mineralogical examination of samples of the tailings from deep in the impoundment indicates that little oxidation occurred prior to tailings deposition. The mill process-water deposited with the tailings was neutral to slightly basic and contained low concentrations of Cu, Pb, Zn and As. Sampling of the tailings five years after deposition indicated that sulfide-oxidation reactions, occurring near the tailings surface, had decreased the tailings-water pH and increased the concentrations of Fe, SOi-, Cu, Zn and Pb (up to 10 000 mg/L, 25 000 mg/L, 2.5 mg/L, 200 mg/L, and 4.5 mg/L, respectively) . In 1975, ten years after decommissioning, the tailings could be divided into three zones: an upper oxidation zone in which sulfide oxidation is actively occurring, a hardpan layer, 15 cm to 20 cm thick, composed of tailings cemented by secondary Fe minerals, and an underlying reduction zone in which the tailings are relatively tinoxidized (Boorman and Watson, 1976). Chemical analyses indicated the presence of low-pH waters containing very high concentrations of SO42- , Fe, and other metals (up to 63 600 mg/L SO42-, 28 600 mg/L Fe, 10 mg/L Pb, 600 mg/L Cu and 4000 mg/L Zn), suggesting that there was a period of intense sulfide oxidation between five and ten years after tailings deposition. More recent sampling, conducted some 20 years after the end of tailings deposition, indicates that relatively little change has occurred in the last ten years, thereby suggesting that the hardpan layer has provided an impediment to the downward movement of dissolved constituents . Analyses of the tailings solids show increased accumulations of many metals at or near the depth of the hardpan layer. Evaluations of the long-term evolution of the tailings can be enhanced by comparison of descriptions of the tailings with descriptions of the gossan that overlay the massive­ sulfide orebody prior to mining. At Heath Steele, this comparison suggests that many of the mechanisms controlling the distribution of metals in the tailings will probably persist over geologic time.

Jan 1, 1992

By C. F. McCarroll

[Laboratory research and, control in the u?odnction an; utilization of petroleum and its product s have eqLmde& greatly during the past decade, rind much of the routine control and experimental equipment noirr requires the con-stant daily use of liquid nercury. In spite of this greater use, very little consideration has becn given to the hazard that might be occasioned by the toxic vapors of mercury unavoicl.a~l.p spilled or otherwise exposed to the atmosphere during the normcl 2rgced1u.e of ln30r~tor;~r operations. A sfmple visual exami~stion gf' sone of the laborztories reveals the prescnce of a considerable quantity of mercury in the craclcs of floors, on work tebles, ad on and mo7md eql~ipmeilt st.ads. Usually this yercurj ie contaminated with oily and dirt BO th~t it remint; in R finely divided state and a srnarl amount presents a relativell- lag? surface for evaporation. Since mercury shows meas~rable vo!-atility st a tempero.turc as lor^ 2s 8.5O F., mercury vapor will bo present in the atnosphere of anjr laboratory wbr.e mercury is exposed. promiscuously]

Jan 1, 1939

By H. F. Yancey

This report, dealing with the separation of coal from its associated impurities by means of a pulsator-type jig, continues the series of reports that have been issued by the Bureau of Mines, in which detailed study has been made of the efficiency and mechanism of separating coal and impurities in various coal-cleaning appliances. The previous reports have dealt with the piston jig, coal-washing table, pneumatic table, and Baum-type jig.5/ Such studies of the separation accomplished by any form of concentration device are essential and necessarily preliminary to any intelligent attempt to improve the performance of such equipment Object and Plan The pulsator-type jig was developed recently by G. A. Vissac. Although two articles(2) describing plants using this type of cleaning unit appeared in 1936, both dealt principally with plant design and layout rather than with plant performance The object of the stork described in this report was to determine the efficiency of the separation made by the pulsator jig on a sized feed, the specific gravity at which the separation between coal and impurity was effected, and the influence of the specific-gravity composition of the coal on the character of the separation made.

Jan 1, 1938

By Stephen E. Kesler

Carbonaceous sedimentary rocks are abundant in the upper part of the caldera or maar that hosts the Puebio Viejo Au-Ag district, and much of the Moore sulfide zone is in these rocks. These rocks are thinly layered and contain scattered plant remains and variable amounts of volcaniclastic debris and pyrite. The carbonaceous matter in the sediments yields no X-ray diffraction pattern and is not graphite. It has C/N ratios of 4 to 10, and &13C values of about -25 per mil, which indicate that it is dominantly of marine organic origin and partly degraded. Atomic S/C ratios in the unmineralized part of the carbonaceous rocks have a median of about 1.2, much higher than most similar unmineralized rocks, reflecting not only the abundance of pyrite in the sediments, but also the fact that the organic material contains several percent sulfur. Extracts from the organic material indicate that it is thermally mature and that it reacted with the hydrothermal solutions. Atomic S/C ratios in the mineralized carbonaceous rocks are generally higher than those in unmineralized carbonaceous rocks, ranging to values of 5 and more. These differences indicate that significant amounts of carbon were consumed by the reduction of sulfate and metal chloride complexes in the mineralizing fluids as they passed through the carbonaceous sediments. Direct reaction between organic material and ferrous chloride-bearing, acid-sulfate hydrothermal solutions probably caused continuous deposition of pyrite during this period. Intermittent deposition of gold from chloride complexes by the same reaction was probably facilitated by boiling or C02 effervescence.

Jan 1, 2013

By Ernest W. Johnson

In most underground iron mines in the Lake Superior district the active workings are at considerable depth. When additional openings into such. nines are needed, operating officials are eager to discover more efficient methods of constructing them. In recent years, openings into two mines in the district were made by the borehole method,-which employs chilled-iron shot as the cutting medium. Others were made by the churn-drill method, in which pilot hole is churn-drilled and subsequently reamed to a desired but relatively small diameter. Both methods are comparatively new and unique, at least in some phases and in their application.

Jan 1, 1946

By Bates H. Murphy

There is one quick way to substantially reduce the operating cost of a great many pining operations. It is to cut the demand charge on the use of electricity and gas. Demand charge is the utility company's charge for the maximum rate of energy usage which is in addition to the charge for the total amount of energy used. Energy demand is reduced by prohibiting simultaneous operation of devices, especially those that consume large amounts of energy, or by deferring the use of such equipment as air conditioners from one demand period to a subsequent period. To achieve that end, a control system can continuously measure the demand and turn off selected loads in accordance with established rules. Because of the complexity of most industrial plants, a computer is the best means of storing, measuring, calculating, and controlling the many variables associated with the many devices involved. A computer system for that use has been developed by the Westinghouse Computer and Instrumentation Division in Orlando, Florida. For most applications, this demand control system can be installed and operated by industrial plant engineering personnel with no special knowledge of computer technology. It can be used with both electrical and gas service. For clarity, let us examine electrical demand first.

Jan 1, 1974

By F. E. Lathe

INTRODUCTION THE present study, based largely upon phase equilibrium diagrams and other theoretical considerations but nevertheless addressed primarily to the practical metallurgist, has been undertaken with a view to discovering what light can be thrown upon the role of alumina in slags. According to Liddell (23), "alumina apparently acts as .a base if much silica is present, as an acid if the silica is low, always as a nuisance." Newton and Wilson (26) state that .alumina "is never added intentionally, as it makes the slag viscous, and is generally an undesirable constituent of slags". Camp and Francis (3) sum up their views by saying, "alumina is seldom used intentionally as a flux, but it is present in nearly all raw material, hence unavoidable". One has only to read The Function of Alumina in Slags, by Henrich (I3), and the very extensive discussion that followed the presentation of his paper, to realize that, before the days of phase equilibrium diagrams, it was a very serious question indeed as to whether alumina should be calculated as a basic, acid, or neutral constituent. Opinions then differed widely, as well they might; today, even though no categorical answer can be given to the question raised, the function of alumina can be at least partly clarified by a study of the fundamental work done by the Geophysical Laboratory in Washington and by certain universities in both America and Europe. It will be a source of gratification to Canadian metallurgists and ceramists to know that work of this type is now under way in the recently organized Physical and Crystal Chemistry Section of the Mines Branch, Ottawa, and that results of practical value have in fact already been obtained.

Jan 1, 1951

By E. O. Stensholt

The Hybinette electrorefining process for production of cathode nickel was in use at Falconbridge Nikkelverk A/S, Norway, until 1975 when conversion to the new chlorine leach process was started. In 1978 the conversion to electrowinning had been completed, but further major improvements to the process have been made up to 1987. After a major expansion program in 1985 - 87 the refinery has a nickel capacity of 54 000 mt Ni/year. The main feed materials to the process are converter matte from the Falconbridge smelter in Sudbury, Ontario, Canada, and from the BCL smelter in Selebi-Phikwe, Botswana. A typical composition of the mixed feed to the refinery is: 40 - 45% Ni, 25 - 30% Cu, 20 - 22% S, 2 - 3% Fe and 1.0 - 1.5% Co. The matte is chlorine-leached in the first process step, nickel being dissolved selectively in a train of leach-cementation tanks. Essentially all copper and sulphur that was present in matte appears in the leach residue as CuS. In 1986 an autoclave treatment stage was added to the process to improve nickel extraction from the leach residue. The resulting strong nickel chloride solution is purified by the process steps (1) precipitation of iron and arsenic, (2) solvent extraction of cobalt and other minor elements and (3) precipitation of lead and the remaining impurities. The nickel solution is then fed to the tankhouse, where various nickel products are produced by electrowinning. The chlorine gas that is produced during the electrolysis is returned directly to the chlorine leaching tanks to dissolve more matte. After stripping from the loaded organic phase and solution purification cobalt is also produced by electrowinning. The copper sulphide leach residue, which contains some nickel, is dead- roasted in fluidized-bed roasters. The sulphur is recovered and sold as sulphuric acid. The calcine is leached in spent copper electrolyte, from which cathode copper is produced by electrowinning. Precious metals and the remaining base metals are recovered from the copper leach residue. The Falconbridge chlorine process is very versatile. It can accept a wide range of impurities in the feed and still produce metals of exceptional purity.

Jan 1, 1988

By Virgil A. Marple, Susanne V. Hering

"5.1 IntroductionTraditional impactors do not offer much size resolution for submicrometer particles; typically their finest size cut is around 0.4 µ.m. Yet for many aerosol applications it is useful to be able to size segregate aerosols in the size range below 0.4 µ.m. Diesel emissions, welding fumes, cigarette smokes and photochemically generated smog aerosols typically exhibit mass median diameters between 0.1 and 0.6 µ.m. When sampling these aerosols with a traditional impactor, fifty percent or more of the aerosol mass can penetrate the final impactor stage. Allhough the material can still be collected on a backup filter, the filter gives no size resolution. As a result, the investigator has no size information on a substantial portion of the sample. One needs a sampler that size-segregates the majority of the aerosol mass. A lower size cut of 0.1 µ.m or less is required for most combustion smokes and smog aerosol s.To obtain smaller cutpoints two types of impactors have been developed, namely low-pressure impactors and micro-orifice impactors. Both instruments can provide cutpoints as small as 0.05 µ.m. Low-pressure impactors were introduced more than twenty years ago (Stem et al., 1962), and a variety of these samplers are in use today. Micro-orifice impactors have been developed at the University of Minnesota within the last five years (Marple et al., 1981 ). To date theirs are the only examples of these instruments in use.5.2 Operating PrinciplesThe low-pressure and micro-orifice impactors use two different approaches to achieve their very small particle-size cuts. Low pressure impactors resemble ordinary impactors, but are operated at reduced pressures of 5-40 kPa (0.05 - 0.4 atm). They take advantage of the decreased aerodynamic drag on particles that occurs when the mean free path in the air is as large or larger than the particle diameter. Micro-orifice impactors operate at near atmospheric pressure, but employ very small orifices, 40 µ.m to 200 µ.m in diameter. The streamlines of the air impinging upon the impaction plate have correspondingly smaller radii of curvature; the air is accelerated more quickly, making it more difficult for the particles to follow. The basic operating principles for both types of impactors are evident from the particle Stokes number, defined as:"

Mar 1, 1989

By J. A. Harrison

Most coal being used in the United States has been subjected to one or' more processes of coal preparation. The physical and chemical characteristics of a coal have a marked influence on the ultimate uses that coal may have. The selection of the proper preparation processes may similarly be important in producing the best practical coal product for any particular use. The physical composition and distribution of physical constituents in the coal will partially determine the efficiency of the preparation process chosen and conversely distribution and concentration of coal macerals will, to a degree, be controlled by the preparation process. A number of preparation processes have been evaluated to determine this interrelation. If a coal having' certain specifications is desired, these evaluations trill assist in providing information needed for the production of this coal.

Jan 1, 1962

By Derek H. C. Wilton

"The Nain Province (NP) of northern Labrador is a >600 km long by =100 km wide Archean craton that has undergone relatively little mineral exploration until economically signifcant concentrations of orthomagmatic nickel sulphide were discovered by Diamond Fields Resources (DFR) at Voisey’s Bay. Due to the great time span between crust formation andfnal intrusive activity (ca. 3.9 Ga to 1.27 Ga),there were, however, numerous metallogenic events within the NP.The NP was intruded by the ca. 1.3 Ga to1.2 Ga Nain Plutonic Suite (NPS) composite anorthosite-granite complex. The NPS dividesthe NP into the southern Hopedale Block (90 km by 150 km) and the northern SaglekBlock (375 km long by =50 km wide). These two blocks appear to represent two distinct Archean cratonic nuclei, each with its own distinct metallogenic history. The NPS is a coalesced assemblage of composite intrusions which include anorthosite, troctolite, norite, gabbro and granite.The Hopedale Block contains the Hunt River and Florence Lake greenstone belts, and the Weekes Amphibolite which represents remnantsf the older Hunt River greenstone belt. Geologically, these belts have some potential to host komatiitic Kambalda-style nickel, volcanogenic massive sulphide (VMS) and meso -thermal lode gold mineralization. The unconformity between Paleoproterozoic cover sequences and the trondhjemite-tonalite-granodiorite (TTG)suite which engulfed the greenstones was the locus for lead-zinc-bearing quartz-carbonate veins. Minor fracture-hosted uraninite showings are also present in the TTG.The Saglek Block is a high-grade gneissterrane with deformed Archean supracrustal sequences but no greenstone belts. Within the gneiss are variably-sized enclaves that range in composition from anorthositic to ultramafic; some of these latter xenoliths contain abun-dant fuchsite. There are also three small anorthositic to ultramafic meta-igneous complexes present in the gneiss near Okak Bay.Some Archean meta sedimentary and maficgneiss supracrustal sequences contain iron-oxide and sulphide members. The sulphide-bearing Tasiuyak parag neiss defines the cra-tonic suture between the NP and Churchill(Rae) Province. Along the cratonic suture between the NP and Churchill Province from Ramah Bay north are remnants of the Archean(or Paleoproterozoic) Hutton Anortho site Suite. Ultramafc layers within the suite contain chromite and elevated Ni values.Three ca. 2.0 Ga supracrustal sequenceswere deposited in small fault-bounded basins within the NP. The Snyder Group contains pyrrhotitiferous massive sulphide horizons. TheMugford Group contains SEDEX-like massive sulphide blocks in a debris fow and ultramafic sills with unusual PGE concentrations; alaskitic granite cutting basement gneiss to the group contains stockwork-like pyritiferous quartz veins. The Ramah Group contains numerous MVT-style zinc-lead sulphide occurrences.The Reid Brook Intrusion of the NPS contains enormous and high-grade nickel-copper-cobalt massive sulphide bodies at the Voisey’s Bay deposit. Exploration in the northern portions of the NPS in 1995 has indicated the presence of other potentially economic nickel sulphide horizons."

Jan 1, 1996

By Gary L. Hundley

The Bureau of Mines has devised and demonstrated an ammoniacal sulfate leach process for recovering nickel and cobalt from low-grade domestic laterites. Solvent extraction of cobalt, one of the process steps, requires the reduction of hexammine complexes of C03+ to C02+ in an ammo-niacal leach solution. Previously, reduction was accomplished using cobalt metal shot in a column. This report presents experimental results and an economic evaluation comparing two alternate techniques with the shot column: (1) an electrolytic reduction cell with an extended surface area cathode and (2) direct electrowinning from purified leach solution using a cell with a fluid bed cathode. The second alternative eliminates the conventional solvent extraction-electrowinning steps. The costs of the three methods, based on the requirements of a pro-posed commercial-sized plant, including all unit operations, were deter-mined by the Bureau's process evaluation group. The operating costs for the shot column, $1.19/kg Co, and for electrolytic reduction, $1.20/kg, are essentially the same, but the cost of direct electrowinning, $3.77/ kg Co, would eliminate this method as a practical alternative. The cap-ital cost of approximately $14.4 million for reduction in a shot column is much higher than the approximately $4.4 million for electroreduction.

Jan 1, 1985

By Lathrop E. Roberts

[The opinion is general among smelter operators that magnetite formed in the converter and reverberatory furnace has much to do with the loss of copper in the slag. Its action appears to be due in part to its relatively high infusibility, chemical stability, and specific gravity, as a result of which it tends to fern a layer of highly viscous. "magnetite mush" between slag and matte. Particles of matte which might otherwise settle out of the slag are unable to pass through this layer. Maier and, Van Arsdale4 have shorn that the inclusion of prills of matte in the slag is also at times very probably due to chemical reaction between magnetite and the constituents of the matte. In smelter control and in envy laboratory study of slats the determination of magnetite is therefore a matter of some importance. The difficulties in the ray of making such a determination with any accuracy are rather obvious. Iron may occur in slog as ferric oxide, magnetite, various intermediate oxides, sulphides, silicates, as free metal, and in solid solution of several of these substances. Even of only the total iron content is to be determined, accuracy can be obtained only by painstaking and time-consuming separation ions from interfering elements. The determination of ferrous, ferric, and free iron in the presence of each other is a difficult matter under the most favorable conditions, and linen present in a slag the difficulties are increased by the refractory nature of the sample, by the presence of sulphides, and by ouch elements as vanadium and molybdenum.]

Jan 1, 1931

By Richard A. Brown

The direct precipitation of uranium with hydrogen peroxide has been known since 1877. Commercial use of the process began in the 1960's. During 1967 the Bureau of Mines assisted the Climax Uranium Co., Grand Junction, Colorado in the development of a uranyl peroxide precipitation process to control a molybdenum impurity problem (1). Atlas Minerals, Moab, Utah has used hydrogen peroxide to control vanadium and sodium levels in their uranium concentrates since 1969 (2). Recently, the use of hydrogen peroxide by the uranium industry has grown, particularly since the increased demand for uranium has led to the processing of low grade ores. Impurities present in low grade ores can be concentrated with the uranium during milling and will substantially complicate the refining of uranium yellowcake concentrates. Consequently, commercial nuclear fuel processors have imposed stringent specifications and penalties to control these impurities. The ability to produce a pure uranium yellowcake can eliminate penalty or reprocessing costs. Hydrogen peroxide precipitation of uranium is specific and quantitative, producing a very high purity product.

Jan 1, 1980

By L. S. Beck

"The Athabasca region forms part of the Churchill province of the Canadian Shield and is underlain by an Archean or Aphebian assemblage of rocks that underwent severe metamorphism and granitization during the Hudsonian orogeny (1750-1950 m.y. ago). In places, the eroded orogen is overlain by unmetamorphosed cover rocks (in-cluding the Martin and Athabasca formations) of probable Paleohelikian age. Basic dykes cut all the rocks of the region.There are innumerable vein-type pitchblende deposits and many syngenetic occurrences of uraninite in crystalline basement rocks. Evidence is presented to show that pitch-blende was emplaced during the final stages of the Hud-sonian granitization and followed the crystallization of syngenetic uraninite transitionally. In terms of P-T condi-tions, the pitchblende deposits belong essentially to Lindgren's mesothermal group.Based on the postulated uranium metallogenesis, the possibilities of finding further deposits of pitchblende and other types of uranium deposits are discussed."

Jan 1, 1970

In presenting this list of permissible explosives and blasting devices, the Bureau of Mines desires to call attention to pages 19 and 24 outlining, the conditions in use under which, and only under which, the explosive or blasting device is permissible. In view of a recent publication recounting trade practice favoring the use of a blasting device without stemming, particular emphasis is placed upon condition 4 on page 19 and condition 2 on page 24. An explosive or a blasting device enumerated in the permissible lists of this Bureau is not permissible in use unless it is properly confined with clay or other incombustible stemming.

Jan 1, 1940

By Ralph C. Kirby

The U.S. produces about 34 percent of the world's aluminum yet must import 90 percent of the raw materials needed. There are abundant resources of aluminum-bearing minerals such as clay, anorthosite, alunite, shale, and dawsonite, but none of the numerous processes proposed for recovering alumina from them has yet proved economically competitive with the Bayer process using imported bauxite. To help develop an economically viable process for utilizing these resources, the Bureau of Mines is testing on a common basis several proudsing processing techniques. New improvements and approaches developed by industry and the Government are being evaluated on a mall scale to obtain enough information on which to form a judgment regarding the best processes for commercial adoption. A continuous miniplant having a feed rate of about 70 pounds per hour is being operated now to investigate the nitric acid process for recovering alumina from clay. Parts of this plant will be used subsequently for work on other processes for recovering alumina from clay, anorthosite, alunite, and dawsonite. Initial results of the operation and plans for the overall project will be discussed.

Jan 1, 1974

By Angel Mamani, Marcel Hürlimann

El deslizamiento superficial de tipo traslacional se encuentra al lado del pueblo Cercs, que pertenece a la región Berguedà de Cataluña; este deslizamiento tiene volumen aproximado de 250 m3, 12° de pendiente y la superficie de rotura se sitúa a 0.6 m de profundidad en roca altamente meteorizada. La caracterización geológica se realizó mediante mapeo superficial y tres sondajes manuales, las cuales permitieron identificar tres estratos; coluvial, argilita alterada y argilita inalterada; la superficie de falla del deslizamiento se ubica en estrato de argilita alterada. También, se efectúo la caracterización geotécnica mediante ensayos de laboratorio, donde se realizó 10 análisis granulométrico y límites de Atterberg, 3 ensayos de permeabilidad por carga variable, 5 ensayos de corte directo y 1 corte anular.

Sep 30, 2022

By Stanton L. Tainter

When the disruption of gold mining stopped the usual source of siliceous flux needed by copper smelters , sandstone copper deposits in northern Arizona offered possibilities as a source of the flux during the war emergency . The Federal Geological Survey , while making a comprehensive survey of sandstone copper deposits , investigated the Warm Springs mining district in northcentral Coconino County in August 1943. A month later , J. H. Hedges , chief of the Tucson Division , Mining Branch , Bureau of Mines , examined the operations in connection with an application for an access road . Both investigations concluded that the district , as an emergency source of copper-bearing siliceous flux , had considerable merit , provided high prices for copper continued in effect . Early in 1944 , V. M. Ryan and S. B. Atherley requested assistance from the Bureau in exploring various deposits on their property . The Bureau / drilled 152 holes , aggregating 3,756 feet , on the Petoskey and Mackin groups of claims . This report is based upon churn drilling done under contract from October 7 to November 25 , 1944 .

Feb 1, 1947