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By F. M. Boler

The U.S. Bureau of Mines conducts research at the Galena Mine, Wallace, ID, with the aim of mitigating the effects of rock bursting. Destress blasting is commonly used as a stress control technique at the mine. A digital seismic array and an array of borehole pressure cells (BPC's) had been installed near the site of a stope undergoing mining and periodic de stressing. The instrumentation was being monitored at the time of a destress blast of the 46-99 stope. No significant seismic events occurred coincident with the destress. However, the destress was followed by a 2 ½ -week period of increased seismic activity, including two damaging events on February 7, 1990, at 034500 (hour, minute, and second) and 122020 Pacific standard time. BPC measurements indicated coseismic ground pressure changes on the order of 200 to 300 kPa associated with the damaging events. Fault plane solutions and dislocation models established that stress changes induced by the event at 034500 may have been significant in promoting the occurrence of the event at 122020. Theoretical investigations suggest that applying knowledge of the existing stress field, an understanding of rock burst mechanics, and fracture mechanics principles can improve destress effectiveness.

Jan 1, 2010

By S. Fazluddin, K. C. Sole, M. R. Serwale, T. Coetsee

The CSIR-Ti process employs lithiothermic reduction of titanium tetrachloride feedstock to produce titanium sponge. The product is therefore contaminated by a range of lithium and chloride species. In this study we examine the effects of particle size, temperature, and HCl concentration as input leaching variables on the removal of chlorides from the crude titanium sponge. A review of the aqueous chloride chemistry of Li and Ti provided initial conditions for leaching of impurity species from the sponge. Experimental results confirm that the effectiveness of leaching and removal of dissolved impurities from the sponge are dependent on leaching kinetics, which are influenced by temperature, particle size, and morphology. Of the variables tested, reaction temperature had the strongest influence on the oxygen content of the leached product. The HCl lixiviant concentration had a negligible effect under the conditions tested. Leaching of crude titanium sponge (−10 mm size fraction after crushing) at 14°C in either 1 M or 0.032 M HCl yielded a titanium sponge product that met the ASTM standard specification for commercially pure Grade 1 titanium, i.e., oxygen content < 0.18 mass% and chloride content < 0.15 mass%.

Dec 13, 2022

By Jun Dai

Based upon research findings from several countries, the combination of microwave and mechanical means to break hard rock holds promise for the future. To achieve this goal, it is essential to understand the laws governing strength reduction of hard rock, such as granite, induced by microwave irradiation. Two aspects to consider are: 1) laws associated with the tensile strength of hard rock after microwave irradiation and 2) the sensitivity of different types of rock strengths to microwave energy. In this study, granite with a range of tensile strengths was exposed to microwaves for various time periods to compare the response of rocks with different strength values exposed to the same microwave irradiation. In addition, a method based on hotspots is presented to explain the mechanism by which granite strength is reduced by microwave irradiation. Granite extracted from Qinling Mountain in Shaanxi Province, China is used in the research. ?50 × 50 mm cylindrical granite specimens were exposed to microwaves at a specific power level. The strength values of the heated granite specimens were compared with those of unheated specimens. Through the comparison and analyses, relationships were determined between 1) reduction in granite strength and microwave irradiation time period, and 2) granite strength and sensitivity to a given energy of microwave irradiation. Finally, a mechanism to explain the experimental results is proposed. Research findings will aid in the design of a microwave + machine rock-breaking system for use in rock breakage in underground mines at depth and for future mine applications on earth and other planets. In addition, the experimental approach could be used to test other rock types to further our understanding of rock damage induced by microwave irradiation.

Aug 1, 2013

This field guide is designed for use in planning pollution control and reclamation activities on small sand and gravel operations. Its purpose is to assist operators in selecting environmentally desirable pollution control and reclamation procedures based upon their particular mining situation. The guide includes information on interpreting physical and cultural factors that must be considered in planning and implementing a mining and reclamation program, achieving environmental protection objectives, and improving community/industry cooperation. Included as appendices are a summary of state laws and a list of additional readings on the subject.

Jan 1, 1981

By D. A. Reynolds

THIS PAPER gives results of an investigation of the composition and carbonizing properties of coals from the Beckley bed, Caretta No. 5 mine, Susanna, McDowell County, and Glen Rogers No. 2 mine, Glen Rogers, Wyoming County, W. Va. The investigation included BM-AGA carbonization tests at. 800° and 900° C. and various chemical and physical tests designed to evaluate agglutinating, plastic, and expanding properties of coal. Both coals were of low-volatile bituminous rank, and each was blended with 70 and 80 percent high-volatile A coal from the Pittsburgh bed, Warden mine, Allegheny County, Pa. The Beckley bed was 39 to 58 inches thick at three points in the Caretta No. 5 mine, and the coal was 39 to 49 inches thick. The carbonizing sample contained 83.0 percent fixed carbon on the dry, mineral-matter-free basis. It contained 3.1 percent moisture, 15.8 percent volatile matter, 72.4 percent fixed carbon, 0.7 percent sulfur, and 8.7 percent ash, as carbonized. The ash softened at 2,680° F. The free-swelling index was 7;i, and the agglutinating value was 7.7. This sample fused weakly in the Gieseler plastometer; its blends with 70 and 80 percent Pittsburgh coal attained maximum fluidities of 830 and 600 dial divisions per minute, respectively. The single coal yielded 83.0 percent coke at 900° C. Yields of other carbonization products per ton of coal at 900° C. were: Gas, 9,950 cubic feet; tar, 3.5 gallons; light oil, 1.36 gallons; and ammonium sulfate, 16.3 pounds. Blending with Pittsburgh coal lowered the yield of coke and raised the yields of other products significantly. Caretta coal yielded strong, blocky coke at 900° C., 89 percent of which was plus-2-inch size. Strength indexes of 900° C. coke from 30:70 blends of Caretta No. 5 and Pittsburgh and of Pocahontas No. 3 and Pittsburgh coals were, respectively: 2-inch shatter, 68 and 53; 1%-inch shatter, 90 and 85; 1-inch tumbler, 50 and 53; and %-inch tumbler, 62 and 65. The specific gravity of the 900° C. gas from Caretta No. 5 coal was 0.272, and the heating values were 491 B. t. u. per cubic foot and 2,440 B. t. u. per pound of coal. The blends yielded much richer gas. Yields of tar acids and bases (0.09 and 0.04 gallon per ton, respectively) were within the normal ranges for low-volatile coals. Caretta No. 5 coal expanded 7.5 percent in the sole-heated oven at a charge density of 55.5 pounds per cubic foot. The blends containing 70 and 80 percent Pittsburgh coal contracted 4.8 and 7.5 percent, respectively.

Jan 1, 1953

By L. Yuan, A. C. Smith

MFIRE, the mine-fire simulation program of the U.S. National Institute for Occupational Safety and Health (NIOSH), is widely accepted as a standard for assessing and predicting the impact of a fire on the mine ventilation system and the spread of fire contaminants in coal and metal/nonmetal mines. MFIRE has been used by U.S. and international companies to simulate fires for planning and response purposes. It is a dynamic, transient-state, mine ventilation network simulation program that performs normal planning calculations. It can also be used to analyze ventilation networks under thermal and mechanical influence, such as changes in ventilation parameters; external influences, such as changes in temperature; and internal influences, such as a fire. The program output can be used to analyze the effects of these influences on the ventilation system. Since its original development by Michigan Technological University for the former U.S. Bureau of Mines in the 1970s, several updates have been released. In 2012, NIOSH completed a major redesign and restructuring of the program with the release of MFIRE 3.0. MFIRE’s outdated Fortran programming language was replaced with an object-oriented C++ language and packaged into a dynamic-link library. However, the MFIRE 3.0 release included no change or improvement to the fire-modeling algorithms inherited from its previous version, MFIRE 2.20. This paper reports on improvements that have been made to the fire-modeling capabilities of MFIRE 3.0 since its release. These improvements include the addition of the t-squared fire as a new fire-source model and the ability to include available heat-release-rate versus time data, the addition of a moving fire source for conveyor-belt fire simulations, improvement of the fire location algorithm, and the identification and prediction of smoke-rollback phenomena. All of the improvements discussed in this paper will be included in MFIRE 3.1 and released by NIOSH in the near future.

Jun 1, 2016

By Fay B. Dillard

This Bureau of Mines report reviews the disposition of natural gas as delivered to industrial consumers via main line sales. Salient information on main line, or direct, natural gas sales to industrial users is presented by State) standard industrial classification code (SIC) revenue, and type of sales for the years 1968 through 1973.

Jan 1, 1975

By B Beale

Bow-tie analysis is a commonly used tool in the Major Hazard Facility sector to identify, display and control risks that have the potential to pose serious harm to personnel. It is a simple but powerful risk management tool that displays traditional risk assessment outputs as easily interpreted ‘bow-tie diagrams’. These are an effective and versatile communication format that can be applied to any type of risk (eg safety, environmental, assets etc) and as such show great benefit in managing operational hazards in mining.

May 5, 2022

By E. H. Burroughs

Persons interested in th_e study of petroleum and allied substances have long felt the need of a bibliographic index to the literature. This bibliography, which is intended to be the first elf a yearly series, has been compiled by the petroleum division of the Bureau of Mines with a view to satisfying this need. The references include only the more noteworthy writings that appeared during the year 191.5 in both ·the United States and foreign countries. Only patents plainly applicable to the industries in point have been included, although, of course, a close scrutiny of the great volume of patent literature might reveal many other patents of possible value. The references are arranged according to the subject classification on pages 3 to 11. This classification, which is to be followed in the succeeding bibliographies of this series, is offered as a guide for further study and classification of the pertinent literature.

Jan 1, 1918

By Stephen C. Tadolini, Anand Bhagwat

"Intrinsic supports installed in mines with limited seam or mining heights have always proven to be difficult when the required support length is longer. To date, three solutions have been used to ensure that the correct length bolt is installed to achieve the required anchorage or to maintain immediate roof material: combination bolts, milled-notch bolts, and hot-notch bolts. The combination bolts use threaded sections and couples, which can be screwed together to form the required length. The primary bolt of choice, to minimize costs and achieve the desired support, has been milled- or hot-notch rebar bolts. These notches can be placed at strategic (required) locations along the bolt axis, so the bolt can be successfully bent and straightened during the installation process. However, these notches can reduce the strength of the bolting system; special reductions are detailed in ASTM F432-13 (2013). Technical advances in steel rolling and forged heading processes have led to the development of a deformed rebar bolt termed, the BORE bolt, which stands for Bendable Oval REbar. The BORE bolt can be bent at any location and straightened during the bolt installation cycle. This support exceeds the minimum designed capacities described in ASTM F432-13 and meets the yield and tensile strength requirements of a full diameter no. 6 rebar bolt. The profile and shape also reduces the resin annulus during the installation process to enhance mixing and shreds the cartridge film to help eliminate glove fingering.INTRODUCTIONThe height or depth of competent strata material, in the immediate mine roof, can be greater than the developed mine openings heights. This is especially true in coal mine openings where 50% of the minable seams in the US are less than 50 inches (132 cm). When this scenario occurs, it can be difficult to insert steel bolts in a solid single length. Figure 1 illustrates what difficulties can be experienced when a roof bolter operator is working and supporting a thin seam coal mine. There are three viable options currently available. Lengths of the bolt can be threaded and a steel coupler can be used between the sections to reach the required depth of anchorage. These systems, called “coupled bolts,” usually require a larger diameter hole to facilitate the larger coupler diameter and can be anchored with an expansion shell, resin, or a combination of both. To ensure that the coupler will develop the tensile capacity of the bolting system, required by ASTM 432-13 Standard Specifications for Roof and Rock Bolts and Accessories (2013), the threaded bars should be completely rotated and engaged into the coupler. Premature failures can occur when the threads “strip out” if not inserted completely."

Jan 1, 2018

By Manuel Gomez

The Bureau of Mines used data from 31 core samples to develop prediction equations for evaluating chemical and carbonization properties of six seam units in a lignite deposit approximately 2 miles wide and 8 miles long in the Wilcox Formation of central Texas. Statistical response surfaces, based on core analyses, were computed for 14 parameters indicative of lignite quality. These computed surfaces, and their mathematical equations, can be used to predict values of the selected properties of the lignite seams at any desired surface coordinate position between core hole locations. The wide range of application shown by this study indicates that the methods of statistical regression analysis may be useful to evaluate large deposits of lignite or higher rank coal.

Jan 1, 1969

By J. R. Kish, J. Dabrowski

"The susceptibility to intergranular corrosion modes is a major technical issue preventing widespread utilization of higher strength welded AA7xxx extruded beam profiles, in the peak-aged T6 condition, in automotive bumper assemblies. A study was undertaken to evaluate the relative exfoliation corrosion resistance (ASTM G85-A2) as a function of joint design parameters, namely the base alloy composition, heat-treated condition and beam orientation after exposure to a cyclic acidified salt spray test. This paper documents the major findings extracted from this study.INTRODUCTIONBumper systems play a predominant role in the passive safety of an automobile, since they are one of the main structures for absorbing the collision energy in the event of an automobile crash. Heattreatable AA6xxx-series (Al-Mg-Si) and AA7xxx-series (Al-Zn-Mg) Al alloys, with relatively high strength, toughness, energy absorption, weldability and formability, make it possible to design costcompetitive bumper systems to crush in a controlled fashion. In this context, Cu-lean AA7xxx extrusions, such as AA7003 and AA7108, which exhibit higher strength than AA6xxx extrusion, such as AA6082, represent an attractive light weight material from which to fabricate bumper assemblies (Clausen et al., 2000; Pedersen et al., 2008; Chen et al., 2009).Arc welding is a key joining process for AA7xxx alloys within the transportation industry. A major technological issue preventing widespread utilization of arc-welded AA7xxx joints is the susceptibility to severe localized corrosion (Kent, 1970, Reboul et al., 1985; Holroyd et al., 1987). It generally occurs as exfoliation corrosion within a heat affected zone (HAZ) a few millimeters from the weld bead, or a type of stress corrosion cracking (weld-toe cracking), which initiates at the weld toe and propagates into the interfacial region between the weld bead and the HAZ (so called “white zone”). In addition to the micro-galvanic cell activity induced by the intermetallic compound constituent and strengthening particles present, there is strong evidence that macro-galvanic cell activity between the weld bead and base AA7xxx alloy may be playing a controlling role. Electrochemical profiles taken across fusion welded joints, in cross-section, during exposure to saline solutions suggest that a significant potential difference exists across the AA7xxx arc-welded joint (Shumaker et al., 1967; Grauer and Wiedmer, 1980; Tuck, 1985, Onoro and Ranninger, 1993). These studies consistently show that the HAZ and base alloy are more electronegative with respect to the weld bead (arc-welded with AA5xxx filler wire). Despite this initial important work, the majority of the recent corrosion research effort on welded AA7xxx alloys has focused on the performance of friction stir welds (Lumsden et al., 1999; Wadeson et al., 2006; Hatamleh et al., 2009)."

Jan 1, 2012

By B. Samanta

LHD (load haul dumper) is now used as a loading machine for intermediate mechanization in underground coal mining. For survival in the intense competition in the global business environment in recent years it is essential that LHD machine should be reliable and maintained effectively and efficiently. This paper seeks to study the reliability, availability and maintainability (RAM)of an LHD machine with failure and repair data by Markov modelling. The constraints and reasons for machine unavailability are outlined. The reliability and maintainability of an LHD and its subsystems are evaluated. Possible modification or design alternatives are highlighted. Reliability and maintainability of an LHD system are disappointing. There is room to take decisions on optimal maintenance planning and machine improvement from this analysis. Keywords: reliability, availability, maintainability, Markov model, LHD

Jan 1, 2004

By Richard F. Link

A statistical technique, useful to analyze assay and other data characterized by location in three dimensions, is described in this Bureau of Mines report. If present, trends in the data are defined for the purposes of improving ore estimation, predicting ore beyond existing workings, and aiding geological interpretation. The technique is to fit linear and quadratic polynomial equations to the data through the statistical method of regression analysis. The fitted linear equations have the geometric form of hyperplanes; the fitted quadratic equations have the geometric form of ellipsoids or elliptic hyperboloids of one or two sheets. To visualize these three-dimensional forms, contour maps of a series of plane sections through the fitted surfaces are plotted. Both the fitting of the polynomial equations and the plotting of the con-tour maps are done by electronic computer to facilitate calculations and to obtain accurate results. Computer programs are described in appendixes. Methods employed are illustrated by an example analysis) based on data from a part of the Fresnillo mine) Zacatecas, Mexico.

Jan 1, 1966

By N. Theron, R. F. Meeser

The global emphasis on conserving energy resources has led to the adoption of hybrid power systems in vehicles. Optimally applied, hybrid systems can save up to 40% on fuel costs. To optimally manage a hybrid vehicle's energy flow it is necessary to know, in real time, all the energy requirements to complete a given route. The energy consumption depends mainly on the vehicle mass, speed profile, and route topography. Of these, the topographic profile is the one factor that is only route-dependent and not influenced by the vehicle or driving styles. The heading vs. distance profile is also an example of a route characteristic not influenced by the vehicle or driving style. In this study the topographic and heading profiles are used to identify routes, and are easily measured by means of digital barometric pressure and compass sensors. Correlations between the current route and previously travelled/stored routes are performed based on their topographic and heading profiles in a point-by-point manner. Above-ground tests were first performed using a road vehicle and six routes to evaluate the system. The system consistently and correctly identified a 20 km route within the first 4 km. It also proved to function correctly in underground tests through the implementation of an instrumented hand-held surveyor's wheel. This system finds direct practical application in optimizing the energy management of an underground hybrid locomotive used by the mining industry in South Africa, but can also be of benefit in applications where route identification is required and using GPS is not feasible.

Jan 26, 2023

By MATT RENAUD, Mustafa Kumral

As high-quality mineral deposits are thoroughly exploited, mines of the future will have to move towards more remote and lower quality projects. With these projects comes an increased business risk to the operator. Even now, mining companies often turn to foreign countries for new deposits to produce, introducing the concept of country risk into their portfolio. Furthermore, feasibility studies often fail to accurately quantify the risks associated with various projects, and as such, this study proposes a technique of risk quantification which can both aid mining companies to evaluate the viability of investment and assist in risk disclosure to public investors for the mining industry of the future. This paper aims to quantify the effects of country risk on the valuation of potential mining projects, using a combination of modular and risk-weighting techniques to evaluate the country risk premium (CRP) required to obtain capital for operation of risky foreign mining projects. The techniques proposed in this paper are demonstrated using fictional examples and then evaluated for accuracy against a recently developed debt-funded precious metal project in a country in the Americas.

Sep 30, 2021

By P Collier

From 1972 until 1989 when operations were suspended Bougainville Copper Limited (BCL, owned 53.58 per cent by Rio Tinto Limited) operated a large open pit mine and processing facility at Panguna on Bougainville Island, Papua New Guinea producing copper concentrate containing significant quantities of gold and silver.BCL has a stated vision of recommencing operations at Panguna. In 2008, Rio Tinto, on behalf of BCL, conducted a multi-disciplinary study to assess the technical and financial viability of redeveloping the Panguna operation. One of the key outputs of the study was a Joint Ore Reserves Committee (JORC) Code compliant mineral resource statement based on the existing block model and fundamental data, archived since mine closure. Historical data (including the resource block model and drill hole data) was recovered from computer archives by a former Panguna mine employee familiar with the various obsolete data formats, thus maintaining an unbroken chain of custody of the data by Rio Tinto since operations were suspended. No additional data were collected as part of this study.The extensive data and documentation archive facilitated a sufficiently detailed evaluation of the fundamental data and model to support an updated resource statement. Table 1 of the JORC Code was used to guide the model validation process.Reconciliation of blasthole and metallurgical plant data with the reserve model, indicated that the copper and gold drill hole composite database was significantly biased towards underestimation in several key domains due to a combination of the following: mineralisation loss during core loss, core loss (minor), vertical drill holes failing to intersect sufficient subvertical mineralised fractures and veins, drill hole spacing too wide, and variable diamond drill hole core size. The resource model evaluation was based on three material types (all previously mined at Panguna), that were defined based on cut-off grade and rock type parameters: direct feed ore – material for delivery directly to the plant, preconcentration and screening ore – subeconomic material beneficiated to produce fines of economic grade, and waste. Three pit shells and designs were generated based on three separate sets of economic parameters. These economic parameters were also used to assign material types to the block model. The three resulting models were then evaluated against the corresponding pit shells.Classification of the resource was approached conservatively due to the inherent bias in the drill hole data. Consequently only Indicated and Inferred resources were tabulated.The study highlighted the importance of maintaining detailed documentation pertaining to resource estimates and operational history, particularly reconciliation, and the value that can be added by a simple, low-cost data compilation exercise.

Aug 22, 2011

By Manuel Gomez, V. F. Parry, John B. Goodman

"INTRODUCTION The need for an accurate and precise analytical method for determining moisture in coals of high water content has been recognized by the coal industry as well as the fuel technologist. Interest in this particular phase of coal technology extends back to the early work of German investigators on the brown coals of Central Europe. Studies by these workers led to the establishment of a direct immiscible liquid-distillation method 4/ as the accepted moisture determining technique in European laboratories. Direct moisture determining methods, those methods that utilize various techniques to drive off the water from a given sample of coal and either collect the water in a calibrated receiver or selectively trap the water driven off in a suitable absorber, have found little favor in the United States. They have been treated merely as research tools.5/ The problem of moisture determination in low-rank coals of the United States has not been given much consideration because such coals contribute only about 2 percent of the total United States production. With renewed activity in low-temperature carbonization and with the growth of interest in coal and coal-tar hydrogenation, the American coals of lover rank containing 20 to 40 percent bed moisture will be subjected to extensive investigation. If the low-rank coals of the United States are to be accurately appraised, the need for qualitative and quantitative analytical proceeded becomes more pronounced. These coals, especially the lignites of Texas and North Dakota, are highly susceptible to oxidation, a process that proceeds to a greater or less extort when low-rank, high-moisture coals are treated by oven-drying methods. The extent of this atmospheric oxidation has been described and evaluated by numerous workers. 7/In many respects, the problem of moisture determination in low-rank coals, those found in the United States and the high-moisture coals of Central Europe, is similar. Conversely, the problem of moisture determination assumes a different aspect when the coals of the eastern and the middle-west sections of the United States are considered. Present methods, the loss in weight gravimetic-type procedures, serve adequately to test these low-moisture coals. The determination of moisture in coals containing 20 to 40 percent water should be approached from a direct method rather than from an indirect gravimetic-type procedure because of the oxidative tendencies of these coals and the demonstratrated inability of a loss-in-weight technique to remove all the water in a given sample of coal."

May 1, 1953

By T. L. Marchewka

As part of its program to conserve the Nation&apos;s natural resources by developing improved performance materials, the Bureau of Mines, U.S. Department of the Interior, in cooperation with the U.S. Department of Energy, has conducted an investigation of materials of construction able to withstand the high temperature and hostile environments encountered in coal gasification units. Refractory pipe liners are required when extremely hot gases or abrasive solids are transported between processing units in the gasification plants. One promising technique for producing refractory pipe (or refractory pipe liners) is centrifugal casting. For this study, the effect of processing variables such as workability, additives, reinforcement and spinning time, and centrifugal force were evaluated using four commercial refractory concretes. In addition, data on characteristics such as strength, density, abrasion, and spalling resistance of 5-inch-diam refractory pipe were developed. Techniques for forming large-diameter (19-inch) refractory pipe also were evaluated. The test results indicated that all four refractory concretes could be made into strong, homogeneous pipe, but that optimum casting parameters had to be determined for each specific composition. The investigation revealed that the major controlling factor in the production of the centrifugally cast pipe was the workability of the refractory concrete.

Jan 1, 1979

By Dao-Wu Yang, Ju-Lan Zeng, Li-Xian Sun, Yan Yao

"The hydration heat of the pure cement, the fly ash single-dopped cement, as well as the fly ash and fluorgypsum co-dopped cement were investigated by means of micro-calorimety with an eight-channel micro-calorimeter (TAM Air). The results showed that the hydration heat and the hydration rate could be reduced significantly by fly ash and fluorgypsum. However, the reduction was not proportional to the loading of dopant. The exothermic peak of the fly ash and fluorgypsum co-doped cement was appeared earlier than the fly ash single-doped cement. As the temperature decreased, the hydration heat and the hydration rate of the doped cement were reduced, and the exothermic peak appeared later. The effects of fly ash and fluorgypsum on the compressive strength of cement were also investigated. The results revealed that the early compressive strength of concrete made up of the co-doped cement was largely higher than that of the fly ash single-doped cement. Based on the experiment results obtained in this paper, we could conclude that fluorgypsum is a suitable additive for fly ash-doped cement.IntroductionFly ash and fluorgypsum are industrial waste. In 2008, nearly 400 million tons of fly ash has been produced by coal-burning power plants in China. And it is estimated that this number would exceed 500 million at the year of 2015. Besides, every year the fluoride salt factories in China discharge more than 100 million tons of fluorgypsum. Tremendous of fly ash and fluorgypsum occupy considerable land and contaminate air and water sources [1]. As a result, comprehensive utilization of this two industrial waste has draw great attention from all over the world.Cement is the most-used construction material on earth. But the production of cement consumes huge energy and destroys the environment. This problem might can be partly solved by applying fly ash and fluorgypsum as additive for cement [2-4]. During the last decade, some papers that focused on applying fly ash and fluorgypsum as additive for cement have been published [5, 6]. However, to the best of our knowledge, none of these papers investigated the hydration heat of the fly ash and fluorgypsum co-doped cement.The hydration of cement is an exothermic reaction, which can result in serious problem for mass concrete: The interior of the concrete could reach very high temperature as the hydration proceeded [7-9]. As a result, the great temperature difference between the interior and the outer of the concrete would exist and cause serious thermal stresses. Thus, the concrete would be destroyed by the cracks which in tum are resulted from the thermal stresses [10, 11]. The heat released by the cement hydration and the hydration rate is commonly regulated by adding mixed materials or transferring additive such as fly ash and fluorgypsum [12-14]."

Jan 1, 2011