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By F. W. Hoertel

Tungsten from the hydrogen reduction of WF was vapor - deposited to coat MERM (Material Evaluation Rocket Motor ) graphite and rhenium- lined graphite nozzles . These nozzles have surface configurations that preclude the conventional fabrication of high- density- tungsten liners . Operation at 550 ° C produced selectively placed uniform coatings of specified thicknesses at near theoretical density . An acceptable coating could not be deposited on a beryllia nozzle because of an undesirable side reaction between the substrate and one or more of the products of the reduction reaction .

Jan 1, 1964

By S A. Ravishankar, W Perez

Flotation is one of the main concentration processes to purify kaolin clay via the removal of naturally occurring impurity minerals containing Ti and Fe. Currently, there are two types of collector chemistries used in the industry to float coloured impurity minerals. These are traditional tall oil fatty acids (TOFA) and specialty hydroxamate (AHX) based collectors. AHX based collectors have long been known to be the most selective collectors to float Ti and Fe based coloured impurity minerals (CIMs) as compared to TOFA based systems. AHX based collectors provide, not only improved selectivity and simplified process, but also more importantly, make it possible to treat certain kaolin resources that do not respond to standard TOFA systems. However, the relatively higher cost of straight AHX collectors has restricted broader application of these collectors in kaolin clay and other oxide flotation applications for a long time. Recent technological advancements, in both making and formulating AHX products more economically, increased the usage of these collectors in kaolin applications. Modified AHX products offer more economical alternatives and process options to provide high purity kaolin clay products for specialty applications based on cost-performance criteria. In this paper, the flotation performance of a series of newly developed AHX formulations is provided along with the characteristics of AHX flotation in general. In addition, flotation performance of earlier AHX collectors is provided based on published literature as background data.

Jan 1, 2005

By T Duff

This paper describes results from small scale tests conducted to determine the distribution of pressure on target plates when subjected to loading due to the detonation of a buried mine in various media. The tests are conducted by using saturated sand, dry sand, and water as the loading media. Different stand-off distances are investigated. Kolsky bars and pressure sensors are used to determine the free-field pressure - time profile of the output of the charge at any location on the vehicle bottom. For verification of the pressure results at certain distances, the specific impulse measured by utilizing different size round plates are employed. In order to investigate the loading mechanisms, high speed cameras are applied. The small-scale test results can be scaled to full scale by using verified scaling laws.

Jan 1, 2014

By K. J. Ashley

Over the last six years I have been involved with the calculation of ore reserves and mine planning using various computer systems and soft- ware packages. This experience has given me a unique perspective from which to view the needs of the engineers and geologists whose job it is to produce geologic and mineable ore reserves. The purpose of this paper is to share that perspective with those who are in this field or are thinking of purchasing computer software to aid in these calculations. My first experience with computers in mining was the creation of a mini-computer based coal reserve and mine planning package written as part of my Easter's thesis. This package took about ten weeks to write, four weeks to document, and two weeks to install at the mine for which it was written. It did what it was designed to do, which was to emulate the hand procedure which had been used prior to its installation. The package was specific to its application which involved several small seams of coal being mined simultaneously and would have required major modification for it to be applied to a mine where, say, one thick seam was mined in two benches.

Jan 1, 1985

By Rollin A. Slater

The bulk materials handling industry has served silently for years as the skeleton structure and often the central system of nerves and nourishment for the body of basic production industries. During the past two decades, this body has undergone substantial growth and mutation to meet the surging demands of our national economy for more and better products. The steel industry has been prominent in this phenomena and plants of the sixties are as unlike the second war vintage as our current crop of basketball players differ from their fathers. Steel has kept pace with spiralling demand by innovation which has resulted in new processes and improved designs which generally yield greater production from fewer units. The supporting industry of materials handling has likewise improved its techniques and currently has a new stronger generation of equipment to perform its necessary supporting function. It has been my fortunate experience to have been instrumental in the creative stages of several new steel mills which are currently in conceptual design or actual construction. Drawing upon exerpts from this experience, this paper will describe a basic approach to the selection and application of modern bulk materials handling systems to an entirely new steel plant. Specific details of past work are not available for publication, therefore, the plant described herein is a composite of ideas and will be the new plant of the Hypothetical Steel Corporation which will be located on the lower shores of the Great Lakes.

Jan 1, 1967

By Piyush Rai, Suresh Kumar Sharma, Punit Paurush

The present study has been conducted in surface limestone mine to select the controllable blasting design parameters affecting the peak particle velocity (PPV) for assessment of ground vibration. The study aims at using two prominent statistical tools, namely, principal component analysis (PCA) and stepwise selection and elimination (SSE) techniques for identifying the key controllable parameters affecting the PPV. For determining the correlation coefficient between blasting design parameters and PPV from 44 field scale trial blasts, multi-variate linear regression (MLR) technique was done. It was found that the PCA and SSE eliminated a huge number of controllable parameters to identify the most important parameters, affecting the PPV. The PCA eliminated 6 number of parameters while SSE eliminated 5 number of parameters, and the coefficients of determination (R2) obtained were 0.616 and 0.584 for PCA and SSE respectively. The predictor equations were evolved, and these equations were used to validate the PPV results for another set of 21 field scale trial blasts. The predictor equations have been found to be fairly accurate in predicting the PPV values. Further, the PCA technique provides very near prediction of PPV with high degree of correlation in comparison to SSE technique. The paper highlights the role of state-of-art statistical tools in selecting the blasting design parameters affecting the PPV in field-scale blasting.

Mar 1, 2021

By S C. Dominy

Gravity amenable gold ores are those that after comminution produce liberated particles, composites and/or carriers that can be recovered by gravity separation means. Recovery depends upon mineralisation type and the comminution and concentration method used. Any in situ ore with more than 20 per cent of gold greater than 100 µm in size is likely to have a strong gravity recoverable component. A less traditional approach is where the gold is sulfide-locked and the gold carrier plus any liberated gold is recovered via continuous gravity recovery following fine crushing. Specific tests are undertaken to determine the level of gravity amenable gold within a deposit. The principal methodology is the gravity recoverable gold (GRG) test, which consists of three sequential liberation and recovery stages. For continuous gravity recovery (CGR), the sample is fed over a laboratory Wilfley table to simulate continuous recovery of the gold. Tails from the feed can be progressively re-ground and re-tabled to develop a grade-recovery curve. Primary geology and gold particle size-distribution have a strong effect on the mass of sample required to provide representative results for both tests. Where low-grade ore contains very coarse gold, substantially larger sample masses are required. Experience has shown that GRG and CGR values can vary throughout an orebody, particularly within different geological-grade domains. A testing regime must consider sample frequency and support.

Sep 5, 2011

By Paul F. Ziemkiewicz, Aaron Noble, Christopher R. Vass

The conventional rare earth element (REE) industry has historically sought to develop ore deposits where geologic processes have produced mineralized zones with commercially attractive REE concentrations. These deposits are extremely uncommon, particularly in the USA. Given the criticality of these materials and the need for sustainable domestic supply, the current research seeks to leverage other autogenous processes that lead to concentrated REE resources. One such process is the generation of acid mine drainage (AMD). AMD is very common in many coal mining districts and results from the exposure and oxidation of pyrite during mining. During the generation and migration of AMD, liberated sulfuric acid mobilizes several metal ions including REEs. Treatment of AMD is required under U.S.C §1251, the Clean Water Act, and often consists of neutralization, oxidation, and metal hydroxide precipitation. To investigate the deportment of REEs during this process, a field sampling campaign was undertaken, whereby the concentration of REEs in AMD and AMD precipitates was measured directly. In the nine sites evaluated in this study, the REE concentrations of the precipitates varied from 29 to 1286 ppm with an average of 517 ppm among the sampled sites. The individual elements were enriched compared with the associated bulk Northern Appalachian (NAPP) coal material by factors ranging from 3 to 15. Furthermore, the distribution of REEs in all precipitate samples favored the heavy REEs (HREEs) when compared with traditional REE ores. This research represents the first part of multi-part research endeavor to characterize, classify, and determine the practicality of refining REEs from AMD and its by-products.

By Raghavan Srinivasan, Y. V. R. K. Prasad, William G. Frazier, Steve C. Medeiros

"Aerospace gas turbine disks operate in an environment of relatively high stresses caused by centrifugal forces and elevated temperatures. These severe conditions necessitate the need for materials with good high temperature strength and low cycle fatigue resistance. One class of alloys used for this task is the nickel base superalloys, out of which, lN 718 is the most widely used in the aerospace industry [I]. The properties of IN 718 are attributed to the combined effects of the chemistry, heat treatment, and microstructure. The chemistry is tailored not only for solid solution strengthening but also for precipitation hardening developed during heat treatment, which combined with a fine grained microstructure lead to excellent mechanical properties such as low cycle fatigue resistance and elevated temperature strength. The properties of a gas turbine disk are sensitive to the microstructure, in particular the grain size, which is dependent on the processing history. The ability to precisely control the microstructural development during forging is dependent on controlling the process so that the workpiece is deformed within a ""safe"" region where no microstructural damage or flow instabilities occur. The microstructural mechanisms during deformation may themselves vary within the ""safe"" region and it is desirable to determine them within the range of parameters that are commonly used in industrial processing. The objective of this work is to establish a relationship between the grain size and the process control parameters i.e., temperature and strain rate, in the hot working of IN 178.BackgroundIN 718 belongs to a class of nickel-iron base superalloys with a face-centered cubic (FCC) austenitic matrix strengthened by precipitation of ordered intermetallic or carbide precipitates and is a nickel-rich alloy strengthened by ordered body centered tetragonal (BCT) precipitates, Y"". The alloying of nickel and iron results in the formation of the austenitic matrix, y, while the addition of chromium and molybdenum cause solid solution strengthening. Also, alloying with niobium causes precipitation of the metastable hardening constituent Y"" (Ni3(Nb,Ti)). Extended aging treatments in the temperature range 650 °C - 980 °C allow the more stable orthorhombic 8 phase (Ni3Nb) to form. Trace amounts of boron are also added to serve as grain boundary strengtheners for high temperature creep resistance. Hot deformation of IN 718 is performed between the Y"" and 8 solvus temperatures to facilitate recrystallization and to control grain growth. While deformation below the Y"" solvus (""""962°C) produces no change in grain size, deformation above the Y"" solvus but below the 8 solvus will lead to a dynamically recrystallized microstructure. The presence of the 8 precipitates will pin the grain boundaries after recrystallization and restrict grain growth so that a fine grain microstructure is obtained. Deformation above the 8 solvus ("""" 1038°C) will lead to a microstructure which has undergone grain growth during deformation."

Jan 1, 2000

By Edward P. Hagarty

The Hazardous and Solid Waste Amendments (HSWA) of 1984 added Subtitle I to the Resource Conservation and Recovery Act (RCRA), authorizing the Environmental Protection Agency (EPA) to develop and implement a new regulatory program for Underground Storage Tanks (USTs) containing petroleum and other regulated substances. Technical standards required for release detection, prevention, and correction as necessary to protect human health and the environment were promulgated as described in 53 Federal Register 37082 (September 23, 1988). Virginia State Regulations (VR 680- 13-02) and U.S. Army Regulations require that a Corrective Action Plan and a Site Clearance Report be prepared to explain the details of remediation of any contaminated media. Construction of new buildings is proposed in two different areas at Fort Myer in Arlington, Virginia, where USTs containing gasoline, diesel and heating oil were located. Tightness testing performed on these USTs in September 1991 indicated that some of the tanks were leaking. Many of the tanks were removed for permanent closure. Initial Abatement (excavation of contaminated soil) was &ed out immediately. A detailed Site Characterization Study which included Hydropunch", field screening using immunoassay, and pilot test - dual phase (water and soil gas) extraction was conducted. Environmental media were analyzed for volatiles, semi-volatiles and metals. A detailed risk analysis (RA) was performed to determine risk-based clean up levels for benzene, toluene, ethylbenzene, xylenes (BTEX); polycyclic aromatic hydrocarbons (PAHs); and methyl-tertiary butyl ether (MTBE). The RA also discussed the presence of lead in the soil. Before constructing any buildings in these contaminated areas, remediation must be conducted in accordance with the State, Federal and other applicable regulations. The remedial alternatives evaluated included Vapor Enhanced Groundwater Extraction, Soil Vacuum Extraction, Soil Washing, Soil Steaming, Active and Passive Ventilation SolidificationlStabilization, Vapor Barrier Construction, and Excavation with Off-site Disposal. This paper discusses: (a) delineation of soil contamination @) risk analysis (c) evaluation of remedial alternatives and selection of the most appropriate technology and (d) consideration of various regulatory issues.

Jan 1, 1994

By VIVEK KASHYAP, Evody Tshijik Karumb, PATRICK TAYLOR

The partial reduction of zinc ferrite to zinc oxide and iron (II, III) oxide can enhance the leaching rate of zinc. Zinc ferrite has often been found as a major component of zinc residues and electric arc furnace dust. The Waelz process is an existing process for zinc ferrite processing, which requires a temperature of more than about 1200 °C to produce Waelz oxide containing ZnO. Since zinc residues have been deemed as a potential way for the extraction of zinc and other critical metals, it is important to analyze the reaction kinetics in the temperature range of interest. This manuscript discusses the chemical kinetics of zinc ferrite reduction by hydrogen gas. Several researchers studied the reduction of zinc ferrite with CO; however, unlike CO, the use of H2 gas as a reductant allows partial reduction of zinc ferrite even at low-temperature range (400–600 °C). Thermogravimetric analyses (TGA) experiments were performed in the temperature range of 300–700 °C with 10% and 30% H2, and the data obtained was analyzed using the isoconversional method of kinetic analyses. The standard models used for isoconversional kinetic analysis were chosen from literature and experimental data were fitted to determine the controlling mechanism and calculation of kinetic parameters of reduction of zinc ferrite. The rate of reaction was found to be increasing with an increase in temperature and partial pressure of H2 gas. The reaction could be divided into three stages, where reaction interface contraction was found to be the controlling mechanism at the initial stage of reaction. As the reaction proceeds, product layer thickness increases, and thus, diffusion was found to be the controlling mechanism. Roasting products obtained from TGA experiments were also characterized using a scanning electron microscope (SEM) to verify critical morphological details.

Jul 26, 2022

By R J. Longbottom

In this study the bonding within reduced titanomagnetite-coal compacts was investigated. The aim of the study was to better understand the binding mechanisms in the reduced compacts and, based on this understanding, to improve on their strength.Titanomagnetite ore was combined with sub-bituminous coal to form compacts. The compacts were then reduced by heating in a thermogravimetric furnace (TGA) to temperatures between 1000 - 1300°C under argon. The reaction progress was monitored by measuring the weight loss with time. The reduced compacts were found to have low strength in compression testing. The main form of bonding between the reduced titanomagnetite particles in the compact was by the formation of a slag-like material. Increasing the fi nal reduction temperature was found to have a profound effect on the strength of the compacts by promoting the formation of this slag-like material.Attempts to improve the strength of the compacts were made by changing two variables, the type of coal and the addition of rice husks. The addition of coking coal gave reacted samples that had little strength, while the addition of rice husks may have enhanced the strength of the reduced compacts.

Jul 11, 2011

By M Malec, J Szczerbinski

Hazards in underground mines are concomitant with the mining of mineral deposits and have their source in a minerÆs work environment. The authors of the paper have undertaken a trial classification of these hazards into three groups, depending on the sphere of their occurrence:lithosphere, ie rock mass, atmosphere, ie air in mine workings, and technosphere, ie machines, equipment and facilities in mine workings. The lithosphere creates such hazards as bumps, rock outbursts, the atmosphere is a factor causing fires, methane explosions and climatic hazards, whereas accidents concomitant with an operation of machines and equipment occur in the technosphere. Assuming that the number of accidents in the mining industry, concomitant with hazards, reflects the degree of safety, it has been shown, that in Poland they are under control to a large extent.

Jan 1, 1999

By S. S. Szoke

The concrete masonry industry, represented by the National Concrete Masonry Association has significantly expanded its markets since the industry's inception. The concrete masonry industry has developed and refined concrete masonry units by producing a variety of quality products on automated machines. In the sixties, architectural concrete masonry units gained popularity. In the seventies, the concrete paver market expanded. In the eighties, segmental retaining wall units became popular. The industry continues to research and develop new products and applications for concrete masonry to satisfy the needs of designers, specifiers, installers and owners. Both existing and innovative technologies in the concrete masonry industry are discussed.

Jan 1, 1993

By F. Dinter, C. McGregor, Q. G. Reynolds, L. Hockaday

The necessity of reducing greenhouse gas emissions to limit the impact of anthropogenic climate change means that all industrial processes should investigate their options towards decarbonization. Iron, steelmaking, aluminium, and cement production produce the most industrial emissions. Although most research focuses on decarbonizing these industries, minerals processing industries must be decarbonized to achieve net zero emissions goals by 2050. Incorporating renewable energy sources and avoiding the combustion of fossil fuels are two ways to reduce greenhouse gas emissions. This paper reports on the results from a dynamic process model developed to investigate the feasibility of concentrating solar thermal pretreatment of manganese ores to pretreat carbonate-rich manganese ores for increased ferromanganese smelter productivity and reduced greenhouse gas emissions. The results indicate that pretreated ores reduce the energy requirement for smelting significantly for some ores and lowers total carbon dioxide emissions by 13 to 19% compared to the traditional smelting route. A high-level economic evaluation shows that solar thermal treatment is financially viable for low cryptomelane, high braunite ore that is common in the Kalahari Manganese Field.

Dec 11, 2024

By J. R. Hammond, I. C. Herbert

Report of discussion at October, 1970, IMM general meeting (Chairman: M. J. Cahalan, President) and contributed remarks on the paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, June, 1970, pp. C128-36 and introduced by I.C. Herbert. Contributors were von Struve G., on the application of balling discs and the use of basic additives; Young P.A., asking for details of the drying, grinding, balling, induration and specification testing equipment and processes; Davison J. on pellet swelling properties and Carter G.C. on disc operation, refractories and green ball properties.

Dec 1, 1971

The principal activities of the Bureau of Mines Explosives Research Center (now Safety Research Center) during fiscal year 1968 (July 1, 1967, to June 30, 1968) are reviewed in part 1. Part 2 presents short abstracts of the publications issued during this period in the Bureau series and in other media. Part 3 describes a short study on the thermal decomposition of RDX and HMX not destined for publication elsewhere. ACKNOWLEDGMENTS The Bureau gratefully acknowledges the support received through cooperative agreement in fiscal year 1968 from The Manufacturing Chemists Association.

Jan 1, 1970

By A. M. A. Mohamed, F. H. Samuel, S. Alkahtani

"This article was undertaken to investigate the effect of nickel and zirconium additions on the strength of 354 aluminum cast alloy. The cast alloys were given a solutionizing treatment followed by artificial aging at 190 ºC for 2 hr. High temperature tensile tests were conducted at various temperatures from 25ºC to 300ºC. Optical microscopy and scanning electron microscopy were used to study the microstructure of the samples. The results revealed that the intermetallics phases of (Al,Si)3(Zr,Ti), Al3CuNi and Al9NiFe are the main feature in the microstructures of alloys with Zr and Ni additions. The results also indicated that the tensile strength of alloy decreases with an increase in temperature. The combined addition of 0.2 wt% Zr and 0.2 wt% Ni leads to a 30% increase in the tensile properties at 300ºC compared to the base alloy.INTRODUCTIONThe task of improving the mechanical properties in an aluminum alloy at high temperatures should include the knowledge of several factors which are related principally to a decrease in the strength of the metal with increasing temperatures. This behavior is linked to the change or deterioration in the principal metallurgical parameters of the specific cast aluminum alloy during its performance at higher temperatures. Most of applications of Al-Si casting alloys are generally used at temperatures of no more than 230°C (Lee & Chen, 2002). This recommendation is made in view of the fact that, for certain applications such as those required by the automotive industry, these alloys must operate over a wide range of temperatures and stress conditions where temperatures are liable to rise even higher than 230ºC (Robson & Pragnell, 2003).Aluminum-silicon-copper-magnesium alloys such as the 354 alloys show a greater response to heat treatment as a result of the presence of both Mg and Cu. These alloy types display excellent strength and hardness VALUES (although at some sacrifice of ductility and corrosion resistance. These alloys are used for a wide range of applications, such as engine cooling fans, crankcases, high speed rotating parts, structural aerospace components, air compressor pistons, fuel pumps, compressor cases, timing gears, rocker arms, machine parts, and so forth (Cáceres, Svensson, & Taylor, 2003; Rurrxia, Rong-de, Yu-hua, Cherrxi, Xiao-feng, Heng-rong, & H. Zhuang-qi, 2004)."

Jan 1, 2012

By D. Stüben, G. P. Glasby

"Abstract - Shallow submarine hydrothermal fluids from Paleohori Bay off the Greek Island of Milos have been investigated in detail. The extensive gas and warm (max. 93°C) water vents are enriched in major components such as C1-, Na+, Si, Ca2+, Mn, PO4 3-, NH4 +, K+, Sr2+, H2S and CH4 and depleted in Mg2+, O2 and SO4 2- relative to ambient seawater. Based on zero-Mg calculations, it is deduced that the submarine vent fluids are related to the geothermal reservoir beneath Milos which has a similar chemical composition. Fluid samples from each vent in Paleohori Bay represent a mixture of hydrothermal end-member fluids derived from the upper and deeper geothermal reservoir systems of Milos, a mantle-derived source, a high-chloride fluid resulting from phase separation of geo thermal fluids and a steam-heated CO2-rich meteoric water. Résumé - À l’île de Milos dans la mer d’Égée, des fluides sous-marins hydrothermaux en eau profonde ont été récherchés en détail près de la baie de Paleohori. Les larges émanations de gaz et d’eau chaude (temperature maximale: 93°C) sont enrichies en constituants principaux tels que de Cl-, Na+, Si, Ca2+, Mn, PO4 3-, NH4+, K+, Si, Sr2+, H2S et CH4 et appauvries en Mg2+, O2, SO4 2- comparé à l’eau de mer environnante. Selon le calcul du zéro-Mg, nous en déduisons que les fluides sous-marins hydrothermaux sont dérivés du réservoir géothermal sous l’île de Milos car leur composition chimique est la même. Les prélèvements des fluides de chaque source hydrothermale représentent un mélange de fluides hydrothermaux dérivés des réservoirs géothermaux supérieur et inférieur, d’une source dérivée du manteau, d’un fluide très enrichi en chlorure produit par la séparation des phases et de l’eau météorique enrichie en CO2 et chauffée par la vapeur."

Jan 1, 1999

By Sandra K. Zacharias

Brass, a deliberate alloy of copper and zinc, has been known since before Roman times. There are two main methods of making brass: (1) Cementation or calamine process - crushed zinc ore (calamine, ZnC03 , or calcined calamine, ZnO), is mixed with charcoal and small pieces of metallic copper and heated to about 900°C in a closed crucible, (2) Alloying - metallic copper and zinc are melted together in a reverberatory furnace. According to most modern authorities (e.g. Smith and Forbes 1955), the calamine process was the only one used in western Europe prior to the 18th century. At that time, the alloying technique began to take over, because metallic zinc was successfully produced on a large scale for the first time. Previously, this had been a problem because zinc vapourizes at 906°C or about the same temperature at which it can be reduced from its ore. Thus, some means had to be devised to collect and condense the zinc vapour (Tylecote 1976). Metallic zinc was known, however, earlier than the 18th century A.O. Several early finds have been made, including a rolled sheet of metallic zinc found in excavations at the Athens Agora dating to the 3rd to 2nd century B. C. (Farnsworth et al. 1949). The Chinese were producing zinc by at least the 10th century A. D. and, by the 17th century, Chinese zinc ingots were being imported into Europe by the Dutch East India Company (Needham 1974). Metallic zinc is also mentioned in several European documentary sources from the 16th century (e.g. Paracelsus, Agricola). This study traces the changes in Western brass making methods from Classical to Renaissance times by examining documentary and archaeological evidence.

Jan 1, 1999