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By E. Van Der Lingen

This paper provides a review on coloured gold, platinum, andpalladium intermetallic compounds, and discusses the models thatwere developed to obtain these materials. These compounds have acrystal structure of high symmetry, such as the CaF2or CsClstructures, ensuring distinct electron band structures. Variousexamples of coloured gold, platinum, and palladium intermetalliccompounds are provided. More in-depth discussion is provided on thepurple gold (AuAl2) and yellow platinum-aluminium (PtAl2)compounds with CaF2structure, as well as the purplish-pinkpalladium-indium (PdIn) compound with CsCl structure. Precious metal intermetallic compounds are used in jewellery andprovide a new dimension to design. Some of these compounds havealso found use as barrier coatings on turbine blades for jet engines,and more recently, research has been conducted into their potentialuse as catalysts, electro-catalysts, sensors, capacitors, and fordecorative coatings.

Jan 1, 2014

By F. Elgersma

Hydrometallurgical zinc winning processes ?are frequently based on iron containing concentrates which yield a goethite, jarosite or hematite residue. Jarosite or goethite are mostly stored in waste ponds which ,are lined with foil. Water percolating through the pond is withdrawn from the deposit ,and decontaminated before discharge. Despite these measures, more and more pressure is put upon zinc companies to treat their (historical) residues and to produce environmentally acceptable residues. The criterion which determines this acceptability is the potentiality of leaching out hazardous elements by natural processes. This paper provides the comparison of five different process designs for integrated jarosite treatment in a hydrometallurgical zinc winning plant leading to environmentally acceptable residues. The processes are esigned for producing 200 ktons/yr zinc and for treating 80 ktonslyr historical jarosite. Mass and energy balances are used to determme parameters such as: the energy use per ton waste treated and the amount and composition of final residues. The conclusion of the work is that. pyrometallurgical jarosite treatment integrated in hydrometallurgical zinc winning is preferable to hydrometallurgical jarosite treatment. Integrated pyrometallurgical processes lead to a ?smaller quantity of remaining hazardous residues and require less energy.

Jan 1, 1992

By D. L. Sawyer

Aqueous C12-02 leaching procedures developed by the Bureau of Mines to produce zinc chloride from zinc sulfide bulk concentrates were effective in extracting 99 pct of the zinc and 97 pet of the silver contained in samples of massive seafloor sulfides from the southern Juan de Fuca Ridge. Zinc sulfide (sphalerite and wurtzite) mineralization comprised 55 and 88 pct of two specimens provided by the U.S. Geological Survey for this study. Minor occurrences of galena, chalcopyrite, and other minerals in the sulfides permitted the recovery of pregnant liquors that were low in metal values other than zinc, which were successfully purified by a two-step cementation procedure using zinc dust.

Jan 1, 1983

By L. C. Johnston, J. N. Gills

This paper reviews the basic reactions of the blast furnace and the open hearth furnace, and then discusses the quarrying and sizing requirements of the limestone feed for each. Particular emphasis is placed on the lime-stone at Irish Cove, now being mined under an agreement between Scotia Limestone Limited and Dosco Steel Limited. The drilling and blasting operations are described, along with loading and haulage, plant flow, water supply, power supply and transportation facilities.

Jan 1, 1967

By Robert L. Lagace

[Suuple Iheorctrccil models are I'M lllolalcd to cltaraclerl/c medium frequency (MF) radio vase pi opaiation in undcrgiounli room arid pillar coal mines fur the purpose of predleiln the most lavolable operating fIegtucncics,md nr,ixunum communic;IIIoil ranges for pottahIe rldu)s with I top antennas. I or conductul IrCC areas, at hree layer propaeaIion IltodcI wit II a Iiallsmissloil IIIIi- lhlllllIIal'u11 lot the plupa!edti ii unlstallt Iris been dcvcloped ;md verified experimentally. 1 lie mode u1 propaCaUetl lakes Ills form of i parallel plane (0,t)) TIM lransnussu)nhne 1% PC of mode with the electric held vertical and the magnetic held hoti/cntal t itliin a planar coal scam in which the tunnels Can he ignored and which 1s hounded above and below hp richer conductivity rock. 1lie model lilt the data best river the 200 io 1000 kH/ frequency hand and exhibits a rc;;lon of optlnrul1l Pelffelntance, with respect Io maxnluiulg radio Communication range, between 300 and 100 klf/. Maximum cunununlcatrorl ranges are sliongls dependent oil the sigiial alleilliatroil sale, ant) Illelclulc on the electrical conductivltles of the coal seam and surrounding ruck. These ranges v;ny tutu about ,,5 Io 100 nleleis Ill a high Iuss scam such as the Ilelllit No. fl to about .100 to 400 meters in a low loss seam such as the Pittsburgh foil portable intrinsically safe radios. The ieslllls die haled on the comparison oftheorc' and experiment for eleven n n. ill sesen coal seams. V OT ate is dice: a conductor such as a power Cable, is present a model has been developed for the coupling of loop antennas to a low loss Coaxial TEM ti;u?smisslon line mode in which the cable acts as the inner conducl,lr and the rock above and below acts as the outer conductor. The electuc and md' nctic Itelds for till` (node are apprlixitllatcly transverse to the cahlC and fall oil expontially with distance in the transverse plane. The principle of reciprocity is used to simplify the analysis. More expelitnental data arc needed to help resolve discrepancies between the theory and the limited data available to date.]

Jan 1, 1980

By Garland Likins, Gray Mullins, George Piscsalko

"Quality control of drilled shafts is greatly dependent upon the practices of the site personnel. For drilled shafts cast under slurry, inspection of the hole prior to concreting is very difficult or impossible. There are numerous non-destructive test (NDT) methods currently available to assess the integrity of drilled shafts. This paper will discuss the theory and use of an emerging NDT technology known as Thermal Integrity Profiling (TIP). The Thermal Integrity Profiling method measures the elevated concrete temperatures that occur during the hydration process. These temperature measurements are made along the length of the pile and can determine the integrity over 100% of the pile cross section, both inside and outside the reinforcing cage. With the known shaft volume information, TIP can evaluate the effective shaft radius at each measurement location. With the increased use of TIP on highway projects, there is a need to have standard criteria for shaft acceptance. Shaft acceptance criteria can be based upon thermal measurements and subsequent analysis of the data to determine the average shaft radius, local concrete cover, and cage alignment. With this additional information obtained via the thermal testing method, acceptance methods based upon concrete cover can be developed. In this paper the Thermal Integrity Profiling method will be described, results from a case history will be discussed, and an acceptance criteria based upon concrete cover will be proposed.INTRODUCTIONDrilled shafts are an attractive foundation element in many applications due to their large axial and lateral capacities. When drilled shafts are cast in a dry hole, it is possible to inspect the hole prior to casting, allowing for very basic level of quality control, although the shape of the completed element is still unknown without some form of post construction testing. When drilled shafts are installed where soil conditions are unstable, the shafts will often be cast under slurry to support the surrounding soils during the construction process. When casting a drilled shaft under slurry, it is very difficult to impossible to accurately and efficiently inspect the hole prior to casting concrete and it is equally difficult or impossible to inspect the shaft during the casting process"

Jan 1, 2016

By R. G. Knickerbocker, C. T. Baroch, A. W. HACKWOOD

The difficulties inherent in the production of alumina by the formation of potassium alum and its subsequent thermal dehydration and decomposition have been overcome , to a large extent , in a process developed at the Boulder City Station of the Bureau of Mines . This process is applicable to the reserves of alunite known to occur in several Western States and , possibly , to certain clay and low-grade bauxite deposits known to exist in this country . The operations sequence of the process is shown in the flow sheet (fig . 1) . Only those steps included within the heavy line are considered in this report . Four different procedures for dehydration of alum were investigated ; ( 1 ) Spray drying , ( 2 ) rotary - kiln drying , ( 3 ) dry grinding in a thermal ball mill , and ( 4 ) dehydration in the vertical- column flash dehydrator . Based upon fuel requirements and other practical considerations , the vertical- column dehydrator , or some modification of its operating principle , offers the botter possibility for commercial use .

Feb 1, 1946

By J. Sjöberg, T. Savilahti, S. B. Umar

"Sublevel caving in Malmberget mine results in mining-induced surface deformation. One of the currently mined orebodies is the Printzsköld orebody. As mining deepens there is need to assess the behaviour of the cave formed in the subsurface above this orebody. Numerical analysis was used to assess the effects of extraction to deeper levels and perform strength parametric studies. Stress redistribution was studied, and the results showed high stress buildups in the hangingwall and the crown pillar. Two failure mechanisms have been identified – shear and tensile. Reducing cohesion by 50% increased the area of the yielded zone by more than 100% in the hangingwall.IntroductionThe Malmberget mine is owned and operated by the Luossavaara-Kiirunavaara AB (LKAB) mining company. Iron ore is extracted by large-scale sublevel caving. The mine comprises a total of 20 orebodies, about 10 of which are in production today (Figure 1). The mine is located in the municipality of Gallivare, about 100 km north of the Arctic Circle (Figure 2).Successful sublevel caving requires progressive caving of the orebody after initial blasting. This results in caving of the hangingwall, sometimes all the way to surface, resulting in surface deformation. As mining progresses to deeper levels a larger area is affected by deformation. Over the years, extraction from the Malmberget orebodies has led to deformation of the ground surface, affecting residential areas and existing infrastructure.Forecasting the caving process is not straightforward as it can be rapid or slow, depending on the rock mass conditions, stress conditions, the failure mechanisms at work, etc. Moreover, several of the orebodies in Malmberget are non-daylighting, which makes reliable caving analysis even more difficult, primarily since there is less available experience from such cases. The present study was designed to improve the understanding of the caving and deformation mechanisms at Malmberget, and in particularly for the Printzskold orebody"

Jan 1, 2017

By S. M. Molloy

The postwar demand for insulating material such as mineral wool, in-creased in proportion to the rapid construction of new buildings, placing an enormous burden on the existing mineral-wool industry both in known sources of raw materials and in available plant facilities. In view of the increased demand on the industry, the Bureau of Mines in its Mississippi Valley Experiment Station" Rolla, Mo., undertook an investigation to aid the industry by establishing resources of raw materials through actual laboratory wool-blowing tests and by developing certain methods for evaluating the physical proper-ties of a mineral wool. As material was received from the public, laboratory-evaluation technique had to be developed, the results of which would reflect in the mineral-wool-industry standards. The methods of testing used by the mineral-wool industry, not only would have required a pilot-plant installation capable of producing a large tonnage of mineral wool, but each wool-blowing campaign would have been very expensive and necessitated considerable personnel and equipment. The present laboratory wool-blowing equipment can produce as high as eight wool-blowing campaigns a day. The nature, simplicity, and size of the physical testing equipment permit testing as small a sample of wool as 25 grams and give information as reasonably accurate as in a 40-pound bag of wool. The purpose of this report is to describe the laboratory method of production and the evaluation of the physical properties of small quantities of mineral wool. Considerable work has already been done, and the interest of the public and industry is measured in the number of samples being submitted for testing.

Jan 1, 1948

The following are abstracts from papers presented at the 4th Symposium on Respirable Dust in the Mineral Industries and· were produced through research funding under the Generic Mineral Technology Center for Respirable Dust. Full articles appear in the proceedings published in July 1996 in Applied Occupational and Environmental Hygiene. (Volume 11, Number 7). The two addresses included in the proceedings point to the progress, prospects, problems, and perspectives on control of respirable dust and dust-related disease in the mineral industries. The symposium papers deal with respirable dust issues that are longstanding such as characterization, health effects, control of airborne coal dust, new and emerging issues such as iron toxicity, diesel particulates, and sampling. The papers were grouped into the following topics: continuous dust monitoring, encompassing the development of a fixed-site monitor that will provide continuous information on instantaneous and time-weighted respirable dust concentrations; mechanisms involved in the generation of dusts in mine environments, important for dust control at the source; characterization and control of diesel emissions (particularly diesel particulates) in mine atmospheres; mining systems effects and models; dust control in mine working faces and in milling environments; characterization of the physical, chemical mineralogical, and biological properties of the dust and their relevance to health effects and sampling; dust-lung interactions, encompassing results from several biomedical studies dealing with acute and chronic inhalation of airborne dusts and associated lung responses; the role of iron in causing lung injury; and therapeutic strategies for ·the control of pulmonary disease. All papers submitted to the organizers were peer-reviewed. In the proceedings, we have not differentiated among the platform and poster papers; rather, they have been grouped into the above topical areas. Taken together, these papers reveal significant progress in the control of dust generation, characterization of dust, understanding of dust-lung interaction, and mining and milling practices to reduce dust exposure - all essential for reducing dust-related occupational hazards at the workplace.

Jan 1, 1998

By ALBERT C. DURHAM

In anthracite mining , pumping is a problem of major importance , and water must be handled and rehandled in almost every mine whether the mine is in operation or idle . The motor - driven centrifugal pump is the most commonly used type of unit for the large pumping installations, and experience has . proved that fully automatic control has certain advantages over manual control . Some of these advantages are greater safety for maintenance personnel , continuous protection against faulty operation , which could cause damage to the Lumping apparatus , and lower pump -room operating costs .

Aug 1, 1948

By G. St. J. Perrott, N. A. Tolch

"PURPOSE OF TESTSThe propulsive strength4 developed by the Cardox blasting device depends on the thickness of disk, weight of heater element, and weight of carbon dioxide charge. It might be supposed that the maximum weight of carbon dioxide that can be charged into the shell should give the greatest strength. However, according to the ballistic pendulum, the maximum weight of carbon dioxide with certain conditions of heater and disk has less propulsive strength than a smaller charge; in one condition of test a loss of 39 per cent in propulsive strength was noted. It is therefore of interest to study the effect of the variables that determine the strength of Cardox.ACKNOWLEDGMENTGrateful acknowledgment is made to A. B. Coates, associate mechanical engineer who developed the testing method for measuring pressures in the Cardox shell.DESCRIPTION OF DEVICEThe Cardox blasting device as fully described by the bureau in Report of Investiga¬tions 2920 (1929), consists essentially of hollow—steel shell, cylindrical in shape, an electrode, valve assembly, shearing disk, and discharge cap. The shell is prepared for use by inserting a heater element, closing the open end with a shearing disk, and screwing in place the discharge cap. The charge of carbon dioxide enters the shell through the electrode.The heater element is fired by an electric igniter of the match—head type. The heat released by the heater element completely gasifies the carbon dioxide and raises the pressure of the gas until it is enough to shear the disk."

Apr 1, 1931

By B. R. Conard

Copper refining at Vale Canada (previously known as Inco) has been associated with Ni production. Because Cu and Ni carry risks for adverse health endpoints through inhalation exposure, it is critical that their aerosol levels, and the metallurgical processes through which they enter the air, are understood. Because certain Ni substances have been linked to respiratory cancers, it is also important to characterize the amounts and types of Ni compounds in occupational settings. This paper describes electrorefining and electrowinning operations near Sudbury, Ontario (1930–present), and gives aerosol measurements (1978–present).

Jan 1, 2014

By M. W. Lightner

IN 1947 the steel industry rebounded from its wartime effort and produced a record-breaking peacetime tonnage of steel ingots. During the first six months of the year the industry produced 42,000,000 tons of ingots and expected to produce 85,000,000 tons for the year. With a rated capacity of some 91,000,000 tons, production was at a rate of about 93 per cent of capacity. Credit must be extended to the steel producers who have maintained this steady state of operations while faced with many problems, not the least of which was a continued shortage of satisfactory scrap. Furthermore, the steel industry started a record-breaking peacetime expansion program at a total cost of more than $1,000,000,000. This program will increase the ingot-making capacity of the country by 2,500,000 tons and should be completed in 1948.

Jan 1, 1948

A Discussion of the papers of James Gayley, on "The Application of Dry-Air Blast to the Manufacture of Iron" (see Trans., XXXV., 746, 1022, also pp. 315 and 745 of the present volume, and of J. E. Johnson, Jr., on "The Physical Action of the Blast-Furnace," p. 454. Chas. B. Dudley, Altoona, Pa.:—I am not a blast-furnace man, and this always puts me at a disadvantage because I cannot go into the details of the making of iron and steel. I have not the experience, and have to take the statements of other people, so what I say regarding the subject of this paper is not in the sense of an expert. When I first heard of Mr. Gayley's experiments, I said to myself, a I fear they will result in failure, since, apparently, Mr. Gayley has forgotten one chemical fact, namely, that carbon does not combine with oxygen in the absence of mater-vapor." This fact which was so astonishing when it was first brought out some years ago, and which those who are interested may find in the Journal of the Chemical Society of London, for 1885, page 349, and 1894, page 611, led me to think that the drying of the air would be a mistake. The general subject of the influence of water-vapor on chemical action is a large one; but the special point in which we are, for the moment, interested, namely, the influence of water-vapor on the combustion of carbon, was especially treated by Mr. H. B. Baker, in the papers referred to. Apparently, however, as the result of Mr. Gayley's experiments, we are to learn that the amount of moisture still left in the desiccated air is sufficient to secure perfectly satisfactory combustion. In thinking over Mr. Gayley's paper, it occurred to me that there were two alternatives, either of which might be chosen, namely, we might dry the air as Mr. Gayley does, or possibly we might, in a very much easier way, simply saturate the air at a constant temperature, and thus get uniform working and

Jan 1, 1906

By James Westfield

Following is a resume of activities of the Division of Coal-Mine Inspection that have had a favorable effect on health, safety, and the reduction o1 injuries at coal mines: 1. The Federal Mine Safety Code for Bituminous Coal and Lignite Mines of the United States was issued originally by the Director of the Bureau of Mines July 24, 1946, after consultation with management and labor representatives of the coal-mining industry. The code has been used by Federal coal-mine inspectors while inspecting bituminous coal and lignite mines as a basis for determining the existence of unhealthful and unsafe conditions and practices in these mines. A revised code was issued by the Secretary of the Interior October 8, 1953, after further consultations with representatives of management and mine workers and was incorporated by reference in the 1952 and subsequent bituminous coal wage agreements. The agreement of May 29, 1946, between the Secretary of the Interior, acting as Coal Mines Administrator under authority of Executive Order 9728, and the United Mine Workers of America, covering bitumi¬nous coal and lignite mines in Government possession, charged Federal coal-mine inspectors with the responsibility of making periodic investigations of the mines and reporting to the Coal Mines Administrator any violations of the Federal Mine Safety Code. Federal coal-mine inspectors also had temporary authority to close mines found to be imminently dangerous, but such authority (under Executive Order 9728) was removed June 30, 1947, when Government control of the mines was terminated.

Jan 1, 1959

By R. F. Coulter

THE Flin Flon concentrating and metallurgical plants (Figure 1) of the Hudson Bay Mining and Smelting Co., Limited, lie adjacent to the town of Flin Flon, on the Manitoba-Saskatchewan border, 400 miles northwest of Winnipeg. Since the start of milling operations in 1930, over 50 million tons of ore from the Flin Flon mine have been treated in the concentrator. During the past few years, newly discovered orebodies have been brought into production and their ores processed at the company's main metallurgical plants. All these properties are within a 75-mile radius of Flin Flon and have aided substantially in augmenting plant metal production as well as retarding depletion of ore reserves in the Flin Flon mine. •Current satellite producers are the Schist Lake, Coronation, and Chisel Lake mines. The Schist Lake mine, located 3 ½ miles southeast of the main plant, is a copper-zinc producer. It was brought into production in 1954. The

Jan 1, 1962

By C. R. Montgomery

Coal companies in order to supply their customers En the metallurgical market, both home and abroad, must be able to control their production in order to meet carbonization specifications over and above those of the proximate analyses which has been the prime consideration of purchases in the past. It is the purpose of this paper to review in brief some of the tests used and give data to show the application of such as it applies to the customers needs. It is now recognized that coal is not homogeneous in any of its properties and an amazing fact is that it has been used for so long a time as the principal raw material for the manufacturing of coke without more emphasis having been placed on the variation between coals; yes, even from coals in the same seam at different geographical locations, Recently Kuchta and Clendenin pointed this fact out In a study of the(1) carbonizing behavior as related to chemical and plastic properties of Alabama medium volatile coal.

Jan 1, 1962

By H. P. Holmes

Tonnage quantities of hafnium metal have been prepared in Kroll-process equipment designed for producing zirconium. Some slight process modifications have been necessary, but overall operation is the same as for zirconium. Hafnium oxide is chlorinated in the presence of carbon and the resultant hafnium tetrachloride reduced by magnesium metal. Byproduct magnesium chloride is removed in a high-vacuum distillation step and the hafnium sponge metal crushed for further use. Arc-melted metal can be forged and rolled to sheet, but the best material produced to date would not be considered cold ductile. INTRODUCTION This investigation is part of the program for the production of pure metals from domestic and foreign ores that has been underway at the Bureau of Mines for several years. It was done in cooperation with the Atomic Energy Commission and the Bureau of Ships.

Jan 1, 1955

By James W. Estep

The sulphur shortage that has occurred in the past two years has directed attention more and more toward sour natural gas reserves, Wellhead values of sour gas vary widely depending upon the acid gas composition, location, market conditions, and necessary processing charges. Preparation of a saleable residue gas is considerably more involved and expensive than that normally encountered in treating a sweet gas. Recent revisions in sales gas specifications have increased capital costs and processing charges. The presence of hydrogen sulphide and carbon dioxide in a natural gas contributes to shrinkage factors that may approach 50%. Fuel required by the gas sweetening process and sulphur slant tail gas incineration also contributes to a further reduction in the volume of residue gas available for sale. The additional processing facilities involving gas sweetening, mercaptan removal, expanded utilities, sulphur recovery and sulphur handling, all demand additional operating and maintenance staff. A favorable sulphur market under certain conditions may justify the processing of sour gas whereby sulphur is either a by-product or a co-product, Five typical cases involving different compositions of sour gas are presented for evaluation. Capital costs, operating problems, and operating costs are presented in detail for full economic evaluation

Jan 1, 1967