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By Rod L. Norfleet

Cemented tungsten carbides are a sintered powder - metallurgical product essential to modern industry. Because of their moderate unit price and our dependence upon foreign sources for the component raw materials, a growing recycling industry has developed in the United States. There are two basic approaches taken to recycling cemented carbides; those which leave constituting materials unaltered or direct-reuse and those which separate the constitutes back to the raw components. To separate the carbides back to their raw components usually requires expensive chemical processing and is thus confined to the lower value materials such as grinding sludges. The direct-reuse methods recycle cemented carbides back to an intermediate level, a powder capable of being recompacted and resintered into a functional end-product. The three most commonly used methods of direct-reuse recycling, the coldstream process, bloaching and the Bernard or zinc process, are reviewed,

Jan 1, 1984

By E. D. Gardner, Edmund Stein

"IntroductionMassive sulphides occurring in metal mines are inflammable and furnish the fuel for many mine fires. Actual sampling has shown that dangerous amounts of sulphur dioxide and hydrogen sulphide may occur in mine atmospheres after blasting in massive sulphides. Probably some .of the finer sulphide in the material being blasted burns while it is in contact with the flame from the explosion. It’s also possible that oxygen of the explosive enters into the reaction.That sulphide dusts are explosive under some conditions has long been suspected, but the theory has not been generally accepted as having been proved. Evidence now at hand appears to be conclusive that such explosions do occasionally occur in mine workings in massive sulphides. Information from several mines working in heavy sulphides shows that occasionally, sulphur dioxide in larger amounts than could be expected from the blasting alone are occasionally thrown out into the mine atmosphere during blasting. Accidents have occurred and lives have been lost by men being caught in such gases. Also it appears in a few cases that damage done to timber in stopes by concussions has been greater than could 112.ve been expected from the regular blasts. In most of these cases the unusually large amounts of Sulphur dioxide could only be accounted for by an explosion or by an ignition of sulphide dusts. When this occurs it is probable that the settled dust is stirred up by the first shot of a round, then the dust cloud is ignited by this or a succeeding shot.In one instance, the senior author, while wearing breathing apparatus, returned to a station to take a gas sample immediately after a raise round had been blasted, and encountered a heavy white fume or smoke that was corrosive to the skin and which forced a retreat. The sample, which was taken farther back in a greatly diluted atmosphere, showed a high percentage (0.18) of sulphur dioxide. The station and the raise which was just being started were very dry and the walls and floor of the station contained settled sulphide dust which apparently was ignited by the blast."

Mar 1, 1928

By William H. Pomroy

This report describes research leading to the design, prototype fabrication, and successful in-mine proof-of-concept testing of two improved stench fire warning systems for underground noncoal mines. The stench system, widely used in underground noncoal mines to warn of fire or other emergency suffers several serious shortcomings, including the toxicity of the odorant leading to debility in miners; reactivity of the odorant with iron oxide, resulting in unreliable warning because the odor may fade when transported long distances in steel pipe; lack of control over the rate at which agent is released into the air-stream, resulting in some work areas receiving unbearably high stench concentrations and other areas being missed altogether; lack of visual indication of system status, valve positions, or proper system operation; and excessively long stench transit times. In 1979, the Bureau of Mines, U.S. Department of the Interior, began research to upgrade the stench warning system. Two systems were subsequently developed which offer significant advantages over current systems.

Jan 1, 1984

By Pratima Meshram Abhilash

In this review, availability of germanium in primary and secondary resources and its recovery from these resources are presented. With nearly 40% germanium consumed in fiber optics and scarcity of resources, the global consumption outplays the primary production. Germanium exists as a substituted element in zinc sulfide matrix of lead–zinc sulfides and lignites. Nearly 60% of the germanium supply is met by zinc refining residues, and about 20–30% of germanium is produced from coal and its by-products. Germanium recovery from various resources such as zinc plant residues, coal and coal plant waste, spent optical fibers, and copper flue dust has been examined. Bioleaching was exploited by few researchers to extract germanium from zinc sulfides, sulfide tailings, jarosite, coal fly ash, and flue dust. This review covers the various work carried out by different chemical separation processes, viz., chemical precipitation, solvent extraction (SX), ion exchange (IX), and membrane processes, as well as biological approaches.

Jan 16, 2022

By F. W. Davis

SOME idea may be gained of the tremendous consumption of refractories by the open-hearth steel manufacturers from a statement made by A. T. Green at a meeting reported by T11.e Industrial Chemist of London, as follows: "At a very progressive steel plant in the Midlands, with a battery of five open-hearth furnaces working. twelve months and making 3000 tons of steel per week, the cost of refractories per ton of steel produced averages about $0.50 for the actual open- hearth casting and $0.12 for those operations incidental to the rolling of the metal." .These figures, when translated into the annual tonnage of steel, represent a very considerable expenditure.

Jan 1, 1930

The following pages discuss the objectives, the background, the scope and a statement of the problem of the study of methods to improve the pillar extraction practices in underground coal mines. 1. OBJECTIVES The objectives of this project were: ? to determine the principal factors contributing to high accident frequency and severity in both conventional and continuous mining operations; ? to compare and evaluate the safety aspects of the "open end" and "split and fender" systems of pillar mining; to establish basic data required to decide what constitutes an adequate pillaring plan that will optimize efficiency, recovery, and safety; ? to determine what measurements or information should be collected, (e.g. roof sag, pillar stress,) to make on-the-spot judgment of impending roof or pillar collapse; ? to make recommendations to improve existing methods or to insure proper techniques are implemented, and ? to suggest areas where additional studies or new research may be of value.

Jan 1, 1975

By E. W. Sawyer

Attapulgite is a magnesium aluminosilicate clay mineral which exhibits unique, processing-enhanceable physical and chemical properties that are related to its current commercial uses. Properties of commercial interest are gelling, absorption, adsorption, binding, acid neutralization and many others. Major industrial applications are: (1) absorption by heat treated grades utilized in industrial oil and grease absorbents and in agricultural pesticide carriers; (2) gelling of aqueous liquid products by colloidal grades for stabilization and viscosity control in salt water drilling fluids, suspension fertilizers, liquid animal feed supplements, paints and tape joint compounds; (3) adsorption by heat treated varieties for the removal of catalysts, color bodies and other polar compounds from hydrocarbon streams; (4) gelling of organic liquids by colloidal attapulgite/surfactant blends in oil-type paints, fibrated and nonfibrated asphaltic coatings and mastic compositions, and (5) the binding of feeds and molecular sieve sorpents with colloidal type attapulgite products. These applications and other less common uses and potential uses will be discussed along with, the necessary selective mining and plant processing features related to each property and application.

Jan 1, 1986

By Lowell Stroud

Ten natural gases containing from 0.023 to 8.4 percent helium were investigated. In seven high-helium samples, the isotopic abundance of Ne21 was greater than in the atmosphere, being supplemented by 33 to 85 percent of "excess" or "radiogenic" Ne21. The ratio of He4/Ne21(rad) in these gases was evaluated and found to vary between 2.9 x 107 and 5.9 x 107 , a factor of approximately 2. Argon concentrations were determined by the isotope dilution method. The isotopic ratios of Ar40/Ar36 in the high-helium gases were from 5 to 75 times the atmospheric value, with the Ar40 being about 80 to 99 percent radiogenic in nature. The ratios of He4/Ar40(rad) in all 10 gases were evaluated and found to range from 4 to 18. The isotopic ratio of N14/N15 in four of the high-helium gases was essentially the same as in the atmosphere; in three cases it was approximately 5 percent higher than the atmospheric value of 272.0. The genesis of nitrogen and the relationship of nitrogen to helium in natural gases were reviewed and are discussed in terms of a theory for the concurrent generation of nitrogen, helium, radiogenic neon 21, and petroleum (hydrocarbon gases and liquids).

Jan 1, 1967

By G. M. L. Robinson

Mineral Processing Wastes, as defined by the Environmental Protection Agency (EPA), has determined that most of the mine wastes will be regulated pursuant to subtitle D (Solid Waste Regulations) of the Solid Waste Disposal Act while specific mine waste categories will be regulated within the framework of the Toxic Substance Control Act. Though EPA's determination currently relieves the industry of the regulatory constraints mandated by the Resource Conservation and Recovery Act (Hazardous Waste Regulations) Subtitle C regulatory framework; the industry is not granted immunity from historical or current environmental regulations related to listed or characteristically hazardous or solid wastes. Because of the current regulatory trends and the need to implement cost effective remediation alternatives; advanced currently available on-site remediation technologies are available to minimize, reduce, contain or prevent environmental impacts related to mining and processing activities. In light of industry technical needs, an overview of the research and commercially available remediation technologies will be discussed and a brief discussion of the strengths and weakness of each technology will be presented. Technologies to be discussed includes stabilization, solidification, soil wash, soil flush, thermal distillation, pump and treat, metal extraction, centrifuges, filter presses, bioremediation, and incineration.

Jan 1, 1992

By Walter W. Focke, Zola Kwela, Willem van der Merwe, Arao Manhique

"The advantages of the de Wet zirconium process for the manufacture of AZST from zircon sand include: Fewer processing steps; removal of radioactivity by leaching rather than by precipitation; alkali reagent recovery in the form of a sodium silicate solution that is essentially free of radioactivity; fewer waste streams and less waste to discard.Here we report on our efforts at maximizing the alkali recovery in the sodium silicate product stream: Milled zircon, d50 ˜ 9 µm, was fused with caustic soda pearls in open reaction vessels at temperatures between 650°C and 850°C. Fusion times of 1, 2, 4, 24 and 336 hours (with intermittent milling) were investigated.For prolonged fusion times the fusion products approached equilibrium compositions. However, the phases Na2ZrSiO5 and Na4Zr2Si3O12 observed at 850°C did not form at 650°C. Since they do not hydrolyse in water they limit the recovery of alkali. For 2-hour fusions a broad spectrum of non-equilibrium reaction-products, that are rich in sodium silicates, is formed. Optimum process conditions, with respect to NaOH recovery, correspond to a 2:1 stoichiometry and fusing for 2-hour at 850°C. At these conditions the alkali recovery is ca. 78% and the zirconia yield is ca. 57%."

Jan 1, 2003

By C. Doyle, J. Brennan, C. Díaz, J. Hrepic, K. Cushnie

"In 1991/1992, INCO undertook a successful R&D program aimed at extending the lining lives of the top blown rotary converters (TBRCs)at its Copper Cliff Nickel Refinery (CCNR) and the electric furnace at INMETCO. At the laboratory scale, this effort was divided into three phases. In the first part, mineralogical work was performed on six refractories that were either currently being used to line these vessels or were considered suitable alternatives. In the second part, this mineralogical knowledge was used to help determine the compositions of slags that would not corrode the bricks at the operating temperature (1600°C) of the above furnaces. Finally, several important properties of the six refractories were measured to complete their evaluation as candidate linings. This paper reports the results of all three phases of the laboratory scale R&D work.The mineralogical work showed that rebonded fused grain magnesite-chrome (RFG-MC) bricks consist principally of periclase with minor amounts of free chromite and trace quantities of silicates monticellite and sometimes olivine. The bricks are principally held together by periclase-periclase direct bonding. Of note, the bulk of the chromite exists as exsolved precipitated blebs within the periclase grains. These likely redissolve at high temperature.Slags on the periclase liquidus coexist stably with these refractories. Examples are presented using CaO-MgO-Al2O3-SiO2 slags at~1600°C.Finally, the two refractories manufactured using close to 100% fused grain material generally outperformed the others in terms of physical properties and certainly were superior in their resistance to slag penetration damage."

Jan 1, 1997

By Ray Y. Lin, Randall A. Blue

"Joining of silicon carbide with infrared using a mixture of Si-30wt.%C as the brazing material has been investigated. Joining was performed at a temperature of 1500 °C in a flowing argon atmosphere for processing times ranging from 5 to 60 seconds. The joining filler materials include thin film silicon obtained by thinning down silicon wafers to about 70 /!m and graphite powder of a 15 /!m average particle size. Joint strengths were determined with a specially designed shear-in-compression jig for testing shear strengths of brittle materials. Cross section examinations of the joined specimens with optical microscopy, scanning electron microscopy and transmission electron microscopy have shown that all joints are essentially void free with excellent wetting between the base SiC and the brazing material. Silicon carbide in the B form has been identified as the reaction product in the joining zone with a transmission electron microscope (TEM) and selected area diffiaction (SAD) analysis. At 1500 °C with a joining time of 60 seconds, the joint has consisted of primarily SiC. With such a high SiC content in the joint, the joint strength is comparable to those by other joining techniques, such as diffusion bonding, as reported in the literature. A kinetic model for the formation of SiC from liquid silicon and carbon is proposed to explain the observed joint microstructural evolution.IntroductionSilicon carbide is of great interest for high temperature structural applications because of its excellent high temperature strength, wear resistance and anticorrosive characteristics [1]. Even though the interest in SiC is high, the use of the material has been limited by the high cost and difficulties involved in forming components of complicated shapes [2]. It is these limitations that necessitate the development of effective joining techniques that are cost effective and able to provide strong joints."

Jan 1, 1996

By C. O. Aksoy, P. M. Ozfirat, M. K. Ozfirat, C. Tatar, C. Pamukcu

"Temporal and other factors contributing to the occurrence of occupational accidents at an underground coal mine in Turkey between 1992 and 2000 have been analyzed. The time period of the study spanned the transition from hand-worked mining methods (1992 to 1996) to hand-worked mining methods and mechanized mining methods (1997 to 2000).The mine selected for the study employed an average of 5,835 men per year on three separate eight-hour production shifts for 302 d/y (Sundays are not worked, and there are 11 holiday days per year). Production on an annual basis averaged 190,000 tons per year between 1992 and 1996, and 300,000 tons per year between 1997 and 2000.The purpose of the study was to determine which, if any, of the factors studied contributed to the occurrence of accidents so that the mine could take the necessary steps to reduce the risk to the workforce. Regression analysis was used to determine the strength of the relationship between each factor studied and the number of occupational accidents.The strongest relationships observed were between the age of the employee, the day of the week, and the total yearly labour."

Jan 1, 2006

By Samuel Filgueiras Rodrigues

An austenitic stainless steel ISO 5832-9 was deformed in a torsion test machine over the temperature range of 1,000°C – 1,200°C and strain rates of 0.05, 0.1, 1.0 and 5.0s-1. The Steel plastic behavior was studied by analyzing the flow curves shapes and using the constitutive equations under the conditions of thermomechanical treatment. The curves initially presented an increase in stress characterized by hardening work, followed by a drop in stress to an intermediate level that reached or not, for certain conditions, the steady state softening. The plastic flow curves of ISO 5832-9 steel displayed in three different ways: (i) Curves with continuous softening presenting plastic instability for low temperatures and high strain rates; (ii) curves type flat, here after the peak there is little variation of stress with strain presenting softening mechanism by higher contribution of dynamic recovery at low temperatures and low and intermediate strain rates; (iii) curves with softening after the critical deformation favored by high temperatures and low strain rates. These behaviors indicate the influence of the stacking fault energy (SFE) and precipitated particles on the softening kinetics of this steel.

Aug 8, 2018

By Thomas G. Chapman

The four major steps in the production of marketable copper are mining, concentrating, smelting, and refining. In a few cases, however, leaching takes the place of concentrating, smelting, and refining, and in others ores are smelted without being concentrated. Copper ores have been milled since the early days of mining in the United States. Except in the Michigan district, most copper ores went direct to the smelter until the so-called porphyry mines were developed. At present, although considerable leaching and direct-smelting ores are produced, the bulk of the copper ore mined is concentrated. Improved methods of concentration have kept pace with the increased tonnages of ores milled.

Jan 1, 1936

By E. G. Davis

The Bureau of Mines made laboratory-scale experiments to examine the technical possibilities of reclaiming manganese from slags produced by oxygen lancing of high-manganese pig iron. Ferromanganese was added to molten pig iron to yield a 4-to 5-percent manganese hot metal, which simulated a product obtainable from the blast furnace. This was injected with oxygen to reduce the metal to 1 percent or less manganese and form a slag containing about 40 percent manganese. The molten slag was water-quenched, treated with H2SO4) roasted at 660° C, and water-leached to give soluble manganese and iron sulfates. The sulfates were precipitated as hydroxides, converted to the oxide form, and smelted to produce a standard ferromanganese containing 74.6 percent Mn and 0.01 percent P. As an alternate method of manganese recovery, a manganese cell feed was prepared from the leach solutions and electrolytic manganese was produced. Direct smelting of the high-manganese slag resulted in 74.2 ferromanganese meeting ASTM specifications except for phosphorus content. The high phosphorus content of the metal and high slag-to-metal ratio obtained made this approach unattractive.

Jan 1, 1966

By A. L. Engel

Simple treatment methods, employing the least possible equipment, can sometimes be established for marginal ores and economical results achieved. In continuation of a long-established part of the hydrometallurgical and ore-dressing program of the Reno Station of the Bureau of Mines, typical ores from newly discovered or recently explored mining districts have been investigated. The purpose of such investigations is to encourage the search for and development of mineral resources and particularly to assist in the economical exploitation of low-grade and marginal ores, as well as the conservation and recovery of values in products from former operations that were discarded because of past inability to treat them economically. Several of these investigations have been limited to preliminary tests of samples from prospecting operations, whereas some involved samples of old dumps or tailings piles. The test, work in these cases was not extensive enough to warrant publication as individual reports, but is of considerable interest inasmuch as it indicates the possibilities as well as the limitations of treating the respective materials; and because, inasmuch as the samples were representative of the districts from which they were obtained, this in-formation should be helpful in the future development of these districts. The present report is a compilation of results of brief preliminary tests on oxide ores only, which contained gold and silver and in some cases base metals. The methods of treatment used include gravity concentration, amalgamation, flotation, and cyanidation. For the most part, only standard laboratory procedures were employed. No attempts were made to develop new methods for the low-grade refractory ores in this group of samples if simple treatment was not successful, as the stage of development of the properties did not warrant extensive experimentation on the samples submitted.

Jan 1, 1951

By J. H. East, D. Harrington

"INTRODUCTION Considerable interest has been shown in the prospective use of Diesel-powered haulage equipment in both coal and non-coal mines. Foreign technical magazines have devoted considerable space to discussions of the use of Diesel locomotives in European mines and some mention of it has been made in technical papers in the United States. The Bureau of Mines has extensively tested the gases produced in the exhaust of the Diesel engine under various atmospheres and conditions of use; it has established a schedule of tests for permissibility of Diesel engines for use in underground coal mines, including, gassy or dusty mines.This publication provides information as to the successful use of Diesel-powered equipment underground workings in the United States and Europe, briefly discusses the characteristics of some of the toxic gases found in the exhaust of Diesel engines, and points out that Diesel-powered equipment can be used with reasonable safety in underground minus if necessary and entirely feasible precautions are taken."

Apr 1, 1947

R. W. Raymond, New York City: As was announced in the Secretary's note, appended to the pamphlet edition of Dr. Ledoux's paper, I have undertaken to superintend the preparation of the samples required by his plan, and the ollation for publication of the results reported. Promises of cordial co-operation hare been received already from a number of leading assayers;? and it is to he expected that the data thus collected, and the discussion to be based upon them, will shed much light upon the important question raised in this paper. Although a detailed discussion of methods on the present occasion might be deemed premature, I am sure that suggestions on the subject from members engaged in assaying would be timely and valuable as a preliminary to later and more detailed criticism. Herbert G. Torrey (U. S. Assay Office), New York City : I may say in relation to the losses in the furnace that I have made a number of experiments, and on my little blank form years ago I put down a place for the losses in the cupel. It met with a good deal of opposition among the smelters, but I claimed that it was my duty to give the full amount of the gold and silver present, and that it

Jan 1, 1895

By A. B. Campbell

The Bureau of Mines is developing alloys using ion implantation as an alternative to bulk alloys that consume large quantities of strategic materials such as chromium and nickel. These alloys are formed at the outer layer of relatively common materials. To more fully understand the corrosion characteristics and physical properties of this outer layer, it was necessary to deter-mine the alloy concentration as a function of depth into the substrate material. Also, since many of the ion-implanted alloys would be utilized at elevated temperatures, it was necessary to determine the diffusion behavior of the implanted element. Proton-induced X-ray emission and inert gas ion sputtering have been utilized to generate composition depth profiles for Fe-Cr, Fe-Ni, and Fe-AI ion implanted alloys fabricated by implanting 25-kev Cr+, Ni+, or AI+ into iron substrates. The data were fitted (utilizing a computer program) with symmetrical Gaussian profiles yielding values for the range and range straggle of the ions. These parameters were then compared with those calculated from theory. Changes in the profiles due to annealing were investigated and values for the diffusion coefficient were obtained assuming diffusion according to Fick's Law. For the Cr+ and Ni+ implantation, the profiles as-implanted agree reason-ably well with theory and exhibit ?norrmal" diffusion characteristics at 500° C. For the Al+ implantation, the profile as-implanted is much broader than predicted and exhibits substantial enhanced diffusion at temperatures up to 500° C.

Jan 1, 1979