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By Sydney H. Ball

AMERICAN consumption of industrial diamonds has increased five fold in the past 25 years and today accounts for 15 to 20 percent of the world's sale of rough diamonds. In another decade the value of industrial diamonds sold may well equal or exceed that of gemstones. It is generally understood that industrial diamonds are one of the strategic minerals being stocked by the Government in the present crisis to ensure rapid and efficient armament production. Diamond die making is a trade largely confined to artisans in Switzerland and in certain parts of France. Today, in addition to turning out pilots, we should train expert artisans in diamond die making, for thousands of miles of tremendously small-gauge wire will be needed to make the instruments by which the efficiency and safety of these pilots is assisted.

Jan 1, 1941

By Andrews Allen

WE all remember when, a few years ago the preparation of coal was nothing but a matter of having somebody at the face or somebody in the railroad car pick out the impurities; also the sizes were generally' made" over a bar screen. Anything that was black was coal; and the only matecia1 picked out was the slate or rock-impurities that could be distinguished by eye or by hefting. This was all right as long. & coal could be sold at. a good price. After all, we are all in business to -make the most money honestly out of a certain acreage of coal and a certain plant. For this purpose what is required is the greatest possible recovery of marketable coal and the highest market price.

Jan 1, 1929

By C. H. Benedict

Largest and most important of the milling plants under construction during the year is the Morenci plant of the Phelps Dodge Corp., in Arizona, where plans are being rushed for production in 1942. Grate mills will be used for fine-grinding, and in the pilot plant, classifiers of the spiral type have the preference for the closed- circuit work. The flotation units will be chiefly of the pneumatic type, with some mechanical units as auxiliaries. The Fagergren, Pan American, and Agitair machines were left in the competition as the year closed. If the absence of European markets for finished products has dislocated the mining industry, fortunately the lack of raw materials required in the beneficiation of ores has not been serious. except possibly as to the inability to import flint grinding pebbles. Some of the less important gold mines still use pebbles for grinding as is also the practice in the comminution of nonmetallics used in various industries. T the Calumet & Hecla in the Lake A Superior copper district pebbles have been used exclusively in open- circuit grinding in the Hardinge mills treating the

Jan 1, 1941

By Mühlböck Marlene

Increasingly stringent global environmental regulations are forcing steel producers to continually improve the efficiency of sinter waste gas treatment. With the Selective Waste Gas Recirculation (SWGR) system from Primetals Technologies, lower production costs can be achieved and the size of downstream waste gas cleaning units can be reduced for investment savings. SWGR features the extraction and reuse of hot sinter off gas from selected wind boxes along the sinter strand, which contributes to improved energy efficiency and off gas treatment in the sintering process. With the next generation of SWGR, Primetals Technologies can provide an energy optimized, emission optimized and environmentally friendly solution that meet customer requirements and country specific regulations. This paper demonstrates the latest developments in selective waste gas recirculation, especially results from pot grate tests and comparison from lab to real plant data. Furthermore theoretical finding and mathematical modelling is presented.

Aug 16, 2017

By Orlando Guerreiro Meira

A utilização de revestimentos com aços inoxidáveis superausteníticos em substituição às ligas a base de níquel na indústria de óleo e gás pode ser uma alternativa interessante, uma vez que é possível a manutenção de bom desempenho e corrosão com um menor custo. O presente trabalha avalia as propriedades mecânicas e microestruturais de revestimentos depositados com a liga AISI 904L sobre o aço carbono ASTM A 516 pelo processo eletroescória, tanto na condição de como soldado quanto após tratamento térmico de alívio de tensões. Após a soldagem, foram realizados ensaios mecânicos e metalográficos para verificar o efeito do ciclo térmico de soldagem nas propriedades do revestimento. O ensaio de dobramento não mostrou indicação de defeitos, sendo considerado aprovado. Os ensaios de microdureza apresentaram valores inferiores a 300HV0.5, em decorrência da microestrutura austenítica com baixo percentual de fases secundárias no metal de solda e de bainita na ZTA. O tratamento térmico de alívio de tensões não provocou mudanças significativas nas propriedades do revestimento

Aug 17, 2017

By Enrui Dai, Weibing Chen, Bin Yang, Wenhui Ma, Haisheng Fang, Hui Wang

LiMn0.8Fe0.2PO4/C composite was prepared by an improved solid-state method and the effect of calcination temperature on properties of the obtained materials was investigated. The results showed that increasing calcination temperature from 600 to 700 oC improved the performance of the LiMn0.8Fe0.2PO4/C due to enhanced crystallinity and increased conductivity, but further increase in calcination temperature to 800 oC led to degraded performance due to particle growth and decrease in porosity. Therefore, the LiMn0.8Fe0.2PO4/C composite prepared at 700 oC exhibited the best electrochemical performance, and could deliver a high capacity of 152 mAh g−1 at 0.1 C, 147 mAh g−1 at 1 C and 114 mAh g−1 at 10 C. In addition, the performance of the LiMn0.8Fe0.2PO4/C and LiMn0.8Fe0.19Mg0.01PO4/C was compared when they were obtained at the optimum calcination temperature.

Jan 1, 2015

By J. T. Birkholzer, M. Rutenberg, K. -H. Lux, R. Wolters, J. Rutqvist, L. Blanco Martin

In this paper, we present numerical results corresponding to the Thermal Simulation for Drift Emplacement (TSDE) test, conducted in the Asse salt mine (Germany) between 1990 and 1999 to simulate reference repository conditions for spent nuclear fuel in rock salt. This test is of significant relevance for nuclear waste disposal in salt because extensive research and measurement programs were set up for the experiment. In our numerical study, we use two sequential simulators, TOUGH-FLAC and FLAC-TOUGH, and we investigate two-way coupled processes, focusing on thermo-mechanical analyses due to the main effect of heating. The two simulators used have recently been updated and are able to deal with large strains and creep processes. Moreover, specific constitutive relationships and coupling functions for rock salt and crushed salt under repository conditions are available. Within the framework of a benchmark exercise between Lawrence Berkeley National Laboratory and Clausthal University of Technology, the same scenario has been modeled in three dimensions using the two simulators mentioned. The main objective of the current, first stage of the benchmark is to evaluate the capabilities of these two simulators to predict relevant processes under repository conditions for high-level nuclear waste in saliniferous media. The comparison of the numerical predictions between them is very satisfactory, leading to a successful code-to-code verification. The comparison between measurements and numerical results shows that the most important processes are captured by the codes and constitutive models used. However, some differences exist between measurements and numerical results. These differences will be addressed in the next stage of the benchmark exercise, in which a parameter fitting effort will be undertaken. Overall, from the results obtained it can be concluded that TOUGH-FLAC and FLAC-TOUGH have the necessary capabilities to reproduce relevant processes under repository conditions for high-level nuclear waste in saliniferous formations.

Jan 1, 2015

By Terry J. Close

At the request of the Idaho Congressional Delegation, the U.S. Bureau of Mines Western Field Operations Center investigated the mineral resources of the 140,000-acre Red Mountain roadless area, located northeast of Lowman, in central Idaho. The area includes U.S. Forest Service Red Mountain RARE II area (4-063). The highly mineralized road less area is underlain mainly by granitic rocks which are transected by a northeast-trending fault system. Associated with the granitic rocks and fault system are gold and black sand mineral resources. At least 1,395 ounces of gold and 858 ounces of silver have been recovered from six lode and placer mines within the roadless area. A total of 525 tons of columbium-tantalum, 2,049 tons of euxenite, 83.5 tons of columbite, and 54,862 tons of ilmenite concentrates have been produced from a nearby black sand mineral placer. Mine workings and facilities in the roadless area consist of two dismantled mills, 15 open and caved underground excavations totaling about 2,900 ft of workings, seven large pits and quarries, over 166 smaller dozer-and hand-dug prospect pits and trenches, and in excess of 66 drill holes. The mineralized sites in the roadless area are covered by about 690 current (1992) mining claims. About 130 individuals are holding the claims. Also within the roadless area are four patented lode mining claims. Twenty-five of the 54 mineralized sites identified during the study of the roadless area have, or likely have, mineral resources. One has gold and three have black sand mineral resources that are marginal or subeconomic. There also are two hot springs with thermal water resources, some veins that could be sources of decorative quartz, and dimension stone which was quarried in the past and could be again.

Jan 1, 1993

By P Hulteberg

In this article, an integrated catalytic reactor design approach to produce PEMFC-quality hydrogen is evaluated. The design is based on a high level of heat exchanging perfonned internally, highly active noble metal catalysts and a woven wire mesh catalyst support system. It consists of an integrated steam refonner and a catalytic burner section, a water gas shift section and a preferential carbon monoxide oxidation section. The reactor design is described and experiments perfonned to evaluate the two reactors built are reported. The two reactors have a maximum output of 3 Nm and 10 Nm3 hydrogen/h respectively. In the larger unit, a total of six fuels, three gaseous (methane, natural gas and liquid propane gas) and three liquid (naphtha, ethanol and methanol), were evaluated. The larger unit was also used to investigate how variations of parameters such as steam-to-carbon ratio in the steam reforming part of the system and the relation between oxygen and carbon monoxide in the preferential carbon monoxide oxidation affect the reactor perfonnance. The smaller unit was used, after implementing automatic control, to run a system life time test for 480 h. The refonner system perfonned according to specifications on almost every aspect.

Jan 1, 2005

By Richard B. Reese, George R. St. Pierre, Robert A. Rapp

The vapor pressures of pure iron and pure chromium have been measured using a Knudsen cell coupled with a mass spectrometer. The experimental results agree well with some previously reported data; heats of sublimation and vaporization have been calculated. From vapor pressure rr~easurernents, the activities of iron and chromium in their binary alloys have been determined for NcY = 0.10 to 0.65 over a 1400" to 1700~ temperature range. The activity of chromium in the liquid alloys was found to exhibit positive deviation from ideal behavior when referred to solid chromium as the standard state; however, for the activity of chromium referred to nonequilibrium undercooled liquid chromium as standard state, the activity behavior is almost ideal. ALTHOUGH the Fe-Cr system is important as the basic system of alloy steels, the thermodynamic properties of this system have not been thoroughly investigated at elevated temperatures. In view of the potential practical applications of such data as well as their contribution to alloy theory, further study of the Fe-Cr system was undertaken. In addition, further development of experimental techniques for equilibrium measurements at high temperature is required. The present research involved an application of the Knudsen effusion method in conjunction with a time-of-flight mass spectrometer. Belton and ~ruehan' have measured the activities in Fe-Ni and Fe-Co alloys by a similar method. Speiser, Johnston, and lackbburn' have determined the vapor pressure of pure solid chromium between 1283" and 1561°K by a Langmuir free evaporation technique. The vapor pressure of chromium was described by the expression: over the temperature range 1283" to 1561°K. McCabe, Hudson, and paxton3 have measured the vapor pressures of pure iron and pure chromium by the Knudsen cell technique around 1500°K. The vapor pressure and heat of sublimation at O°K, AH,", for pure chromium agreed within experimental error with the measurements of Speiser et al. at 1200°C. Kubaschewski and HeYmer~ determined the vapor pressure of pure solid chromium in the temperature range 1170" to 1400°C by the Knudsen effusion technique combined with a radioactive tracer analysis of crS1. Their results agreed with the work of previous investigators. Edwards, Johnston, and Ditmars5 have measured the vapor pressure of pure solid iron by the Langmuir technique between 1356" and 1519°K. The vapor pressure of solid iron in the temperature range studied was given by: The data of McCabe, Hudson, and paxton3 on the vapor pressure of pure iron around 1500°K by the Knudsen effusion technique were in good agreement with those obtained by Edwards et a~.~ Hultgren, Orr, Anderson, and Kelley give the selected values for the AH: of pure iron and pure chromium as 98,990 *200 and 94,340 * 500 cal per mole, respectively. These values are the average values determined in the several investigations by different methods. The Fe-Cr phase diagram7 is shown in Fig. 1. Previous determinations of activities in this system have been carried out by several investigators, but most of the work has been done on solid alloys. Using a Knudsen effusion method with cr5', Kubaschewski and Heymer4 reported that the Fe-Cr system exhibits positive deviation from the ideal behavior for compositions ranging from NCr = 0.0398 to 0.699 at 1170"

Jan 1, 1969

By D. N. Seidman

In the course of a study of the electronic and thermodynamic properties of Pb-Se alloys it was found necessary to have an accurate knowledge of the phase diagram. However, the literature is in disagreement as to whether or not a monotectic reaction occurs in the lead rich portion of the phase diagram. Pelabonl reported only a two-phase region consisting of lead-rich liquid and solid PbSe extending from almost pure lead to the compound PbSe, and gave the melting point of PbSe as 1065°C. The data of Friedrich and Leroux2 are in general agreement with this type of diagram, with the melting point of the compound being 1088°C. However, Nozato and Igaki by inverse rate thermal analysis observed a monotectic reaction isotherm exlacing at 860°C with a monotectic composition of 20.5 at. pct Se. The miscibility gap in the liquid state extends from 7.5 to 20.5 at. pct Se. Hansen and Anderko4 accepted Nozato and Igaki's phase diagram in the region of the lead-rich monotectic. To reinvestigate this portion of the phase diagram, both thermal analysis and metallographic examination of various compositions were performed. The thermal analysis apparatus was constructed according to the specifications of the National Bureau of Standards. A t/t-l pct Rh thermocouple was calibrated against the melting point of copper (NBS), zinc (NBS), and antimony (A. D. Mackay), the emf being measured with a Rubicon Type B potentiometer sensitive to lpv. The absolute accuracy of the thermal analysis obtainable with this system is ± 0.5oC. Starting materials were semiconductor grade lead and selenium purchased from the American Smelting and Refining Co. Both elements were 99.999 pct pure with only trace impurities detected upon spectroscopic examination. One hundred galloys were sealed in quartz crucibles with a central thermocouple well under a vacuum of less than 1 p. This procedure prevented any composition change due to vaporization during the run. Cooling curves were obtained on the alloys listed in Table I. Data was taken by the direct method at cooling rates ranging between 1/2 to 2°C per min. The alloys were heated well above the liquidus and shaken vigorously to insure homogeneity. No evidence of an arrest indicative of the monotectic reaction was observed, and the two-phase region reported by Pelabonl and Friedrich and Leroux? was confirmed in general, although our data give higher liquidus temperatures than Friedrich and Leroux. The melting point of stoichiomet-ric PbSe determined for two different samples was 1080.7 0.5oC. The results of this investigation are compared with Nozato and Igaki's data in Fig. 1. To Complement the thermal analysis data, an 86 at. pct Pb specimen was examined microscopically. This composition was in the center of the miscibility gap reported by Nozato and Igaki.3 The alloy was heated to 1000°C, held for 1/2 hr, and water quenched. The specimen was polished using standard metallographic techniques for lead. The alloy was etched with an acetic-nitric acid etchant for 10 min at 45°C. Microscopic examination did not indicate the existence of two separate layers or solidified droplets imbedded in a matrix, as would be expected if a miscibility gap were present. The mi-crostructure shown in Fig. 2 consists of uniformly dispersed, dendritic PbSe in a lead-rich matrix.

Jan 1, 1962

By Forrest T. Moyer

In conjunction -with the statistical survey of the lime industr-.r in 1939, by the Bureau of Hines, producing companies reported the lime-fuel ratios attained in their plants according to type of kiln and kind of fuel. Each ratio, expressed as the number of pounds of lime burned by a unit quantity of fuel, was weighted according to the tonnage of quicklime pro- . duced at the reporting plant and grouped with similar data from other plants, so that an average ratio for each type of fuel and,kiln could be calculated. By this method the variables trat affect ratios of individual plants are more or less equalized, and the computed average lime-fuel ratios provide a fair measure of kiln and fuel efficiencies during 1939.

May 1, 1941

By C Claassen, R Balusu

Computational fluid dynamics (CFD) models have been developed based upon field data collected from a longwall mine in New South Wales, Australia to study the behaviour of goaf gas flow in both active and sealed goaf areas. A base CFD model was built to represent the goaf situations when the active longwall retreats near the finish-off line. Results from the base model were calibrated and compared against field goaf gas monitoring data. The base model was then used to carry out parametric studies to investigate a number of operational scenarios and their impact on goaf gas behaviour. CFD modelling results indicate that the overall goaf gas flow pattern changes as the operating longwall retreats towards finish-off line. In all cases, oxygen penetration into the active goaf remains high, reaching 15 per cent or higher, even at some 800 m behind the longwall face.The modelling results also indicated that it would be difficult for early detection of an active goaf heating (on the maingate side) based upon CO readings in the return airflow, as the main stream of the gaseous product will be flowing into the sealed deep goafs in adjacent longwall (LW) panels. Monitoring points (such as tube bundles and bag sampling points) should be selected at deep seated seals along the active goaf so that abnormal CO or C2H6 readings can be picked up for early detection and location of potential heating spots; goaf inertisation can be better achieved by injecting inert gas such as nitrogen at deeper points (>200 m) behind the operating longwall; the injection of in-seam drainage methane into the goaf areas will only have a limited impact on goaf inertisation as much of the injected methane will migrate towards deep and higher parts of the goaf due to its buoyancy effect.

Sep 26, 2011

By C. A. Young

The remediation of cyanide (CN-) and nitrate (NO)-) anions in mine and agricultural waters by various photolytic methods has been reviewed and investigated. Photolytic methods such as direct photolysis, homogenous photolysis, and heterogeneous photocatalysis are briefly described and compared. Results and discussions show that each method has certain advantages and disadvantages. For each method, Eh-pH diagrams prove useful for determining reaction mechanisms. Preliminary results obtained for cyanide oxidation and nitrate reduction show that homogeneous photolysis can be superior due to faster kinetics than the other methods. The photolytic methods were individually, not simultaneously, tested and compared. Differences in concentrations of products were obtained and attributed to differences in photoconversion efficiencies and other inherent characteristics of .the photolytic methods. Various reaction mechanisms are proposed in accordance with the literature as well as measurements obtained from solution analysis using ion selective electrodes and ion chromatography .

Jan 1, 1995

By N. S. Phala

Declining gold grades, mineralogical complexity of ore bodies, increasing input costs, more stringent conditions in the licenses to operate, and uncertain gold price dynamics combine to exert significant ongoing pressure on margins of gold producers. Innovative approaches of extracting the metal from its ores are required to realize value from existing and future assets. In a conventional gold processing plant, size reduction of mined ore to produce floatable or leachable product is a significant cost contributor. A step change in cost reduction will be attained if radically energy efficient grinding approaches can be developed, replacing tumbling mills. In the path towards that goal, some quick wins are possible through waste rejection before grinding, and pre-treatment of mill feed to reduce grinding energy demands. Gold locked in complex mineralizations puts pressure on margins by increasing cost per oz (typically high $/t and low metal recoveries) in the hydrometallurgical steps. Gold miners are primarily price takers. The current narrow range of gold uses (predominantly investment and jewellery) is not an entirely desirable state. Some diversification into commercial uses would potentially be a price stabilizer. In this paper, promising research directions, some not always fully explored in the gold metallurgy research space, are highlighted to stimulate radical innovation for substantial value enhancements. The author strongly believes a shift from a traditionally conservative and incremental innovation approach to a more aggressive one, across all aspects of the gold metallurgy value stream (processes to products), is what the industry needs. Keywords: gold metallurgy value stream, thiobaccilus ferroxidants, HPGR

Sep 1, 2012

By T. S. Spicer

Inflammability and crossing point apparatuses were used to study the influence of increasing amounts of such inerts as ash, fly-ash, pyrite, limestone and Portland cement with several pulverized bituminous coals. The results indicate that it requires large proportions of inerts to substantially suppress the ease of ignition.

Jan 1, 1962

By G. E. Bogin, C. Strebinger, J. F. Brune

"Evidence shows that methane gas emanates from the mined-out area or gob of a longwall coal mine and can travel towards the working face, posing an explosion risk. Since the gob consists of varying levels of compacted rock, many researchers have modeled fluid flow through the gob as a Darcy-type porous media with a specified porosity and permeability. When studying methane gas explosions near the gob fringe, the Darcy flow assumption may not be applicable to describe the methane flame interaction with the gob. Computational fluid dynamic studies were performed modeling methane flame propagation across a simulated gob which was modeled as both a Darcy porous medium and as discrete rock objects with varying sphericity. Modeling the gob as a Darcy porous medium results in unrealistic methane flame propagation since the porous media assumption does not consider any differences in rock size and/or distribution. Additionally, the porous media model does not allow for ignition within and subsequent flame propagation through the porous medium, which must be modeled to understand the potential for methane gas explosions in the gob area. Modeling the gob as discrete rock objects produces more realistic methane flame dynamics and agrees with experimental observations. Modeling results show flame propagation across circles, hexagons, and squares, meant to represent rock rubble in the gob, produce different levels of turbulence which affects methane flame propagation velocity. This research demonstrates that modeling methane gas explosions in a longwall coal mine environment, specifically near the gob area, requires modeling obstacles, such as rock rubble, as discrete physical objects to capture the complex coupling of fluid dynamics, thermodynamics, and heat transfer. INTRODUCTION Although there are methods to mitigating methane accumulations in a longwall coal mine, explosive gas zones (EGZs) of methane and air may exist and pose an explosion risk to nearby miners and equipment (Brune, 2014) (Karacan, Ruiz, Cote, & Phipps, 2011). In the event of an explosion, the resulting methane flame and pressure wave can be catastrophic as evidenced by the Upper Big Branch explosion in 2010 that killed 29 miners (Page, et al., 2011). Since the mining process is transient, it is difficult to determine exactly where these EGZs exist, but investigative reports show in many cases, these EGZs can be near the working face, behind the shields, or within the gob area (Brune, 2014) (McKinney, et al., 2001). Additionally, miners have recounted seeing flames moving back and forth within the gob and under the roof supports (McKinney, et al., 2001) and in other cases, anecdotal evidence of hearing small pressure pops deep within the gob area (Brune, 2014)."

Jan 1, 2019

By C. W. Smith

The Bureau of Mines conducted physical and chemical beneficiation studies on three samples of waste investment casting molds to devise a method to liberate and recover zircon. Rod mill grinding, autogenous attrition grinding, and caustic leaching were liberation methods inves-tigated. Flotation, gravity separation, and caustic leaching and sizing were recovery methods investigated. Flotation techniques produced con-centrates containing up to 74.2 pct zircon with a zircon recovery of 53.4 pct. Gravity concentration produced concentrates containing up to 98.6 pct zircon; however, recovery of the zircon was only 57 pct. Caustic leaching and sizing produced concentrates containing up to 98 pct zircon with attendant recoveries of 81 pct.

Jan 1, 1985

By W. Torres Pino, L. Mariscal Samaniego

The Ilo Smelter has been continuously operating since 1960 with Reverberatory furnaces and Pierce Smith converters producing blister copper. The original installed capacity of 1.134 tons per day of concentrated was expanded in 1976. A process of modernization started in 1995 and 1998 with the installation of an El Teniente Converter, a sulfuric acid plant and an oxygen plant to reduce the gaseous emissions to the atmosphere. With the official approval of the Environmental Compliance and Management Program (Programa de Adecuaci6n y Manejo Ambiental - PAMA) in January 1997, Southern Peru Copper Corporation made a commitment to capture 91. 7% of the S02 generated at the smelter by January 2007. After an evaluation of six different technologies, the ISASMEL T process was selected because it can be easily adapted to the present operation, has a lower capital cost and it is a simple process. The fast learning curve to reach the total capacity will allow to fulfill the PAMA commitment in time. The project construction is in process and SPCC is prepared for a successful start-up and transition of the current operations at the end of year 2006. This paper outlines the factors considered by SPCC in its choice of ISASMEL T technology and describes the construction and the start-up activities of the new facilities.

Jan 1, 2007

By O. W. Borgeson, D. K. Honsberger, R. T. Bell

The Scully Mine, situated in the Labrador Trough near the Quebec-Labrador boundary, is one of the world's largest continuous ore deposits. This paper outlines the sequence of the mining operations from the planning stages to the delivery of the ore to the crusher at an average rate of 50,000 tons per day, 7 days per week. The principal equipment required to maintain this production rate includes four 12.\1.1-inch rotary drills, seven 8-cu.-yd electric shovels and a fleet of large haulage trucks. Particular attention is given to grade control, programmed by computer, drilling and blasting techniques and operational aspects inherent with open-pit mining in Canada's North.

Jan 1, 1969