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By G. R. Strimbeck

The Federal Bureau of Mines has been developing processes for producing synthesis gas directly from coal, oxygen, and superheated steam. An atmospheric-pressure pilot plant was constructed and operated to: 1. Determine the operability of the plant for gasifying coals of different ranks under various operating conditions. Listed in decreasing order of rank, these coals included a Pennsylvania anthracite, a bituminous A coal from the Sewickley bed, West Virginia, and a subbituminous C coal mined in the Lake de Smet region of Wyoming. 2. Determine the effect of varying operating conditions on: (a) Standard cubic feet (std.c.f.) of oxygen and pounds of coal of different rank required to make M std.c.f. of product gas (carbon monoxide plus hydrogen); (b) carbon gasified, percent; (c) exit-gas temperature, degrees F.; and (d) heat loss, B.t.u. per pound coal. 3. Compare the gasification characteristics, indicated in item 2, of coals of different rank: Bituminous A, anthracite, and subbiturninous C. 4. Determine the concentration of dust in the gases produced and the efficiency of dust removal, and investigate the relation between the sulfur content in the coals gasified and the gases produced.

Jan 1, 1960

By H. V. Flagg

OPERATION of a modern steel plant presents a curious anomaly. Large-scale operations, in which large volumes or heavy weights of materials are involved, are not usually subject to close control or narrow specifications. On the other hand, operations that call for a high degree of precision are usually carried out under carefully controlled conditions with delicate, precise machinery and tools, and production is made secondary to quality. In a modern steel mill both extremes are taken as a matter of course. A strip mill making auto-body sheets must supply its customers with sheets that all come within a tolerance of plus or minus 0.003 in. in gauge at any point from side to side or end to end, and without blemishes either of color or surface. Sheets that were considered par excellence as recently as ten years ago could not even find a market today. Such exacting requirements have made necessary a nicety of control that approaches the watchmaker's art. Notwithstanding this necessity for precision, the scale of operation is stupendous.

Jan 1, 1940

By A. K. Kyllo, G. G. Richards

"The formation and control of accretions is an important aspect of process operation for gas injection. The nature of the accretion formed can have a considerable effect on a process, especially on the life of the lance or the refractories in the tuyere region. There are three basic shapes of accretion formed on tuyeres; pipes, hemispheres and hollow-cored hemispheres. However, there are wide variations within these shapes. Generally, the type of accretion formed will depend on the injector design, certain operating parameters and the physical properties of the bath materials. This paper seeks to collect the results of previous and current physical and mathematical modelling together with data gathered from operating furnaces, to obtain a better understanding of the effects of process design and operating variables on accretion formation.IntroductionAn important consideration in the design of a gas injection process is the possible freezing of the bath either around the tuyere or on the lance. With proper design, freezing may be controlled to provide protection of the lance or refractory, and to avoid blockage. Improper design may lead to tuyere blockage and significant refractory or lance erosion. In view of this, a good understanding of the heat transfer in the injection region is essential.While tuyere blockage has been a persistent problem since the inception of submerged gas injection processes, the problem of accretion formation was not studied in detail until the development of the shrouded tuyere by Savard and Lee. A number of studies relating to accretion formation have been carried out since then, but there is still little information available relating the nature of the accretion formed to the design of the injection system.The build up of materials on lances is a similar problem, and may also be either beneficial or detrimental, depending on circumstances. Unfortunately, there is even less information available regarding build up on lances than there is relating to tuyere accretions. While the form of build up on lances is generally a simple coating of the lance, accretions on tuyeres tend to be more complex. Tuyere accretions tend to occur in one of three basic forms: pipe, hemispherical and hollow-cored hemispherical (Figure 1). However, there appears to be a considerable variation within these forms."

Jan 1, 1996

By Derek J. Fray

"In order to extend the application of fused salts in\the electrowinning and electrorefining of metals, it is necessary to maximise the current density, minimise the voltage drop and greatly increase the area of electrode surface so as to compete with the space-time yield of pyrometallurgical reactions. The various designs of electrowinning cell are reviewed and it is shown that by the application of a modest centrifugal field it is possible to reduce the anode to cathode interelectrode spacing to 4 mm whilst still maintaining a current efficiency of 85-90%.The thermodynamic potential for electrorefining is far less than for electrowinning yet fused salt electrorefining is only applied in limited cases. The reasons for this are discussed and the important design parameters evaluated. It is concluded that by using packed bed electrodes, separated by a diaphragm, the possibility of electrorefining with very low energy consumption can be achieved. Carbothermically-produced metals are always cheaper than those produced by electrolysis but suffer from the disadvantage of low purity. It is proposed that fused salt electrorefining may offer an energy efficient way of upgrading the metal. IntroductionThe majority of metals can be deposited from fused salts (1,2) but as commercial production is restricted to the more reactive elements, it is worthwhile considering the advantages and disadvantages of fused salt electrolysis as' compared to smelting and aqueous electrolysis. The advantages over aqueous extraction are as follows:1) the much higher conductivities and diffusivities result in much lower IR losses and higher current densities can be achieved at modest voltages;2) the elevated temperatures of operation result in larger exchange currents which give rapid kinetics and lower activation polarisation for the electrode reactions;3) the absence of water as a solvent means that it is not necessary to consider the evolution of hydrogen as a competing cathodic reaction. Furthermore, alkali halide salts, often used as solvents in fused salt electrolytes, have high deposition potentials;4) molten salts generally are mutually soluble and, therefore, concentration polarisation effects are minimised."

Jan 1, 1988

By M. Hames, K. Larmour-Ship, B. Grinbaum, E. Buchalter, R. Hackl, B. Wassink

Sodium cyanide continues to be the lixiviant of choice for gold dissolution. Many gold ore-bodies contain a significant amount of cyanide-soluble copper which increases the cost of processing due to high cyanide consumption and high cyanide destruction and disposal costs. Several cyanide destruction processes are in use today, however, there are just a few cyanide recovery plants operating. A solvent extraction process to recover cyanide has been developed which utilizes the organophosphorous extractants Cyanex 923, di-butyl-butyl-phosphonate (DBBP) or tri-n-butyl phosphate (TBP) in Bateman Pulsed Columns. Copper cyanide species are first converted to hydrogen cyanide (HCN) by acidification, with or without sulfide addition. HCN is extracted by the organic and stripped using a suitable base (eg. NaOH) resulting in a high strength cyanide solution (eg. NaCN) for recycle to the gold recovery process. Continuous pilot plant testwork on HCN extraction using a 40 mm diameter Bateman Pulsed Column demonstrated a cyanide recovery of greater than 99% with final levels of cyanide in solution of less than 10 ppm. These results illustrate the potential of this technology to recycle cyanide and to detoxify final effluent streams.

Jan 1, 2005

By G. A. Smyres

The Bureau of Mines investigated a HCI-02 leaching procedure to recover Cu, Ni, and Co from a low-grade bulk sulfide flotation concentrate prepared from the Duluth gabbro complex. Since the Duluth gabbro complex is the largest known and unexploited Ni resource in the United States, the development of options for extracting the metal values from the flotation concentrate of this domestic resource is necessary. Conditions were determined for producing a pregnant solution low in Fe to facilitate recovery of the metal values. Leaching experiments were conducted at 15 pct solids, 1000 to 1200 C, 0.2 to 0.3 g HCI per gram concentrate in a 50-gal reactor pressurized to 50 pSig with 02. Base metal extractions from the concentrate were, in percent, 90 to 92 Cu, 99 Ni, 97 to 99 Co, and 0.1 .Fe. Precious metals extractions were erratic and unpredictable; at best their extractions were, in percent, 55 Au, 90 Ag, 40 Pt, and 45 Pd. The reaction time at 1200 C was 0.5 h. The use of compressed air instead of 02 as the oxidant was also investigated. Solvent extraction using LIX 622 was used to remove Cu from the pregnant solution. Cementation on Cu was tested for precious metals recovery, while sulfide precipitation was used to produce a Ni-Co product. A conceptual flowsheet for treating the Duluth gabbro concentrate is proposed.

Jan 1, 1985

By S. D. F. Rocha, A. L. A. SANTOS, E. M. A. BECHELENI, R. M. Papini, P. R. M. Viana, F. P. C. Silvas

The kinetics of atmospheric sulfuric acid leaching from a Brazilian nickel laterite ore was assessed using distinct reducing agents and ore mineralogy. This transitional ore contains 1.63% Ni distributed as 1.27% in coarse size (− 500 + 150 μm), mainly as silicates (lizardite and chlorite—28.6%), and 2.06%in the fines fraction (− 75 μm), mainly as iron oxy-hydroxides (goethite and hematite—49%). The effects of temperature, acid concentration, reducing reagent type, and concentration were evaluated. The − 75 μm fraction limited the leaching efficiency and the use of reducing media with thiosulfate improved leaching and Ni-Fe selectivity. However, at constant Eh of 626–743 mV and a pH range between 0.2 and 1.1, no substantial rise in metals extraction, except for Co and Mn, has been observed. In order to determine the process control at 95 °C, two regions in the extraction curves were used in combination with the shrinking core model. Control by porous diffusion was observed and the kinetic constant was found to be in the order kFe<kNi<kMn<kCo<kMg for atmospheric leaching without Eh control. In reducing media for the first 15 min of leaching, the kinetic constant was found to be kFe<kNi<kMg≅kCo<kMn as derived from Ni disseminated into iron oxides structures.

Oct 7, 2020

By S. J. Aresco

The Bureau of Mines has been active in promoting the purchase of coal for Government use under specifications that define the requirements in terms of heating value of the coal, expressed in British thermal units, and the composition as shown by proximate analyses. To these, when required, are added the ash-softening temperature, the free-swelling index, and the Hardgrove grindability index. Under most of these specification contracts the bidders guarantee the quality of the coal, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled in accordance with instructions4/ issued by the Bureau of Mines, the samples are analyzed in the Bureau laboratory to determine whether the coal is of the quality guaranteed by the contractor and, if it is not, a price adjustment is made. Analyses of the delivered coal and tipple samples (samples collected at mine tipples as coal is being loaded into railroad cars or trucks) provide valuable data for use in evaluating future bids. In addition, the continuous sampling of coal as delivered is a check on the practical results obtained in burning the coal.

Jan 1, 1957

By M. Potesser

Higher prices for natural gas or oil have motivated the copper industry to reexamine the modes of oxygen and oxy-fuel burner usage at operating plants. With rising energy costs and the growing importance of environmental protection, burner usage and burner operations have become the focus of several investigations and optimization efforts. One possible approach to lower energy usage is through combustion using tonnage oxygen. When such oxygen is used, the flame temperature increases and operational efficiency is improved. As well, with the correct technology, due to the presence of lower levels of harmful substances such as NOx in the off gas, there is improved environmental performance. As regards copper production, furnaces are employed for both concentrate smelting or for melting and casting operations. The use of tonnage oxygen in concentrate burners for smelting provides for a higher thermal efficiency. For furnaces employed for melting, air-operated burners may in fact have an initial advantage because a long radiant flame is typically generated, thus providing for a higher degree of heat transmission. This paper describes the new experimental burner chamber of Messer Austria GmbH which provides for testing of the combustion of natural gas with oxygen or oxygen-enriched air and the use of special water cooling ducts that simulates a metal charge during melting, The operational effectiveness of the burner is determined from temperature and off-gas analysis data. The paper also discusses future trends in burner technologies including a new patented burner. Cu2007 - Volume III (Book 2) The Carlos Diaz Symposium ou Pyrometallurgy Edited by A.E.M. Warner, C.J. Newman, A. Vahed, D.B. George, P.J. Mackey, A. Warczok Toronto, Canada,

Jan 1, 2007

By P. C. van Aswegen

The Bacterial Oxidation (BIOX®) process for the pre-treatment of refractory ores for gold recovery developed by Genmin, the mining division of Gencor, has been operating successfully at the Fairview mine since October 1986. The continuous operation of a pilot plant at Genmin Process Research has resulted in further process developments to improve plant operating efficiencies. These new developments which include a higher solids content of the pulp feed to BIOX®, lower retention times, higher operating temperatures, lower power utilization for oxygen dispersion .and reduced nutrient addition have all been successfully implemented on the Fairview plant.lt has furthermore been confirmed that the arsenic precipitate formed in the neutralization of effluent solutions complies to the United States of America EPA standards. Continuous cyanidation pilot plant work conducted on BIOX® product has indicated that cyanide consumption can be drastically decreased if a continuous flowsheet is implemented in preference to a batch leaching system.

Jan 1, 1991

By Stephen Njoloma, Ivan Hee, Ravi Jain, Mina Shinouda

"INTRODUCTION DC Water’s First Street Tunnel (FST) is comprised of a collaborative effort between DC Water, DC Water’s Project Consultants Organization (PCO) led by Greeley & Hansen and McMillen Jacobs Associates and the design-build team of Skanska, Jay Dee, and Parsons Brinckerhoff. The fast-track project includes elements that were designed by the PCO and released for construction by DC Water prior to Notice to Proceed (NTP) and elements designed by the Design-Builder from 30% to released for construction after NTP. This required effective communication and technical coordination for integrated engineering and efficient construction. The project, constructed in an urban residential neighborhood, included innovative construction methods such as multiple location ground freezing, utilizing a centralized freeze plant, to minimize community impact. The means and methods chosen for cast-in-place shaft linings, precast segmental tunnel lining, microtunneling, sequential excavation method (SEM) adits and near surface elements reflected the immediate and sensitive surroundings, which varied by construction staging area (CSA). Technical aspects of the project, relative to the evolution from pre-bid to construction documents, are discussed along with modified designs to suit means and methods. SCOPE OF WORK In 2012, four major storm events swept through the District of Columbia and hit the Northeast Boundary sewer shed particularly hard with the neighborhood experiencing severe flooding. The extreme nature of the flooding, the damage to private property, and the health risks associated with exposure to sewage led to a multi-agency response and community calls for answers and action. The Mayor assembled a Task Force to evaluate a range of potential actions to address combined sewer flooding including engineering, regulatory, code revision, and management improvements. The Northeast Boundary Neighborhood Protection Project was the outcome of the Mayor’s Task Force; it is a three-step infrastructure initiative designed to offload the undersized sections of the existing collection system that serves the Northeast Boundary drainage area by implementing the McMillan Stormwater Storage Project, First Street Tunnel Project and the future Northeast Boundary Tunnel Project. Until the Northeast Boundary Tunnel Project is completed, the First Street Tunnel Project will add 8 million gallons of combined temporary sewer storage in a new tunnel under First Street NW to relieve undersized sewers that traverse the Bloomingdale neighborhood."

Jan 1, 2016

By Abid Adekunte

"Whilst safety is considered to be of high priority in every aspect of engineering projects, it is equally important for designers and contractors to be continually aware of their obligations to the immediate environment and the society as a whole. These include responsibilities to minimise the amount of nonrenewable natural resources and energy used on projects, to reduce carbon foot prints on projects, to minimise the quantity of wastes produced on projects, to minimise the level of pollution on construction sites and to reuse materials and waste products whenever and wherever possible.In other words, professional engineering practice needs to be accompanied by an underlying fundamental objective to improve, restore and sustain the environment. However, achieving this objective requires continuous collaborative interaction and effective communication between the different specialists involved on every project from the early stages. In addition, developing a well-thought-out economical solution is key to achieving the sustainability aspect of the above objective.This paper focuses on the design, construction and management of a recently completed large multi-level basement scheme in Central London, with greater emphasis on collaborative approaches taken by the design engineers, commercial managers, construction managers and site operatives to deliver the most reasonably economical and sustainable solutions to the client. Solutions were based on combinations of general and specialist engineering knowledge, with due considerations for health & safety, sustainability, cost, practicality, time and community requirements.INTRODUCTIONUnderground structures have become vital components of urban life worldwide e.g. tunnels serve many water, wastewater, highway and railway schemes, basements have been incorporated into many urban commercial, institutional and residential developments, while many public underground car parks have been built to deal with the incessant problem of insufficient surface parking spaces in busy urban centres.The safe design, construction and maintenance of underground structures have been well-mastered by the deep foundation industry over the years. However, just like many other areas of engineering, aside the need to satisfy safety requirements, underground construction practice is now faced with a new set of requirements; the demand for more sustainable and cost-effective solutions, with reduced environmental and societal impacts. Designers and managers of underground construction schemes are now compelled to minimise the use of natural resources and energy, to minimise the amount of waste produced, to minimise the level of environmental pollution, noise and disruption to traffic and normal societal life at ground level around underground construction sites. In addition, the recycling of site wastes and reuse of materials have now become important aspects of underground space development. Considerable effort is being put into promoting sustainable development across the industry."

Jan 1, 2017

By C. Flores

It is well known that manganiferous silver ores containing manganese intimately associated with silver are not amenable to conventional extraction methods. The segregation process has been applied primarily for recovering copper from oxidized and oxide-sulfide ores. A new alternative process combining segregation roasting followed by flotation to recover silver from refractory manganiferous silver ores, was studied using a 23 factorial experimental design. Laboratory investigations have been conducted on a manganiferous silver ore analyzing 0.02% copper, 0.09% lead, 0.33% zinc, 12.55% manganese and 187 g/ton silver to study the effects of additives salt, coke and copper oxide on silver recovery. Results indicate that 79.3% silver recovery can be attained in the absence of copper oxide and 88.4% when the copper oxide content is 1.5% at &apos;750°C, 2% salt and 1% coke and 30 minutes of roasting time. It was concluded that doping with copper oxide improves silver recovery.

Jan 1, 1994

By E. LaRocque

Denison Mines Limited has been processing uranium ore in the Elliot Lake area for the past 20 years. As the original concept of uranium processing has been modified somewhat over this period, the present paper will describe the current recovery practices at the Denison mill from crushing through concentrate drying and packing . Special emphasis will be placed on the leaching, ion exchange and precipitation sections of the process, with consideration being given to the entire circuit. Descriptions will be given of equipment now being used and control strategies will be discussed.

Jan 1, 1979

By Xiao-hui Fan, Li-shun Yuan, Xu-ling Chen, Wei Lv, Min Gan, Yi Wang

"As the amount of ferrous scrap increases every year, it becomes more and more urgent to deal with this iron-bearing resource properly. This paper puts forward a method on resource-oriented utilization of ferrous scrap (cold-bonded pelletizing), and these cold-bonded pellets can be used as coolant in a converter. The influence on the pellets qualities by using different kinds of chloride as rust agents is studied, and results show that the strength of cold-bonded pellets increases significantly by using a combination of the three kinds of chloride -NaCl,MgClz,FeCh, their best dosages are 1.2%, 0.2%, 0.1% respectively. Other iron-bearing materials also have an effect upon the pellets strength, by adding 5% iron powder and maintaining for 48h, the compressive strength of the clumps surpass 2500N/A, dropping strength surpass 4 times/ A, and 10% iron slag or 20% steel slag can replace 5% iron powder while obtaining the comparative quality. The influence of different ratios of three ferrous scrap (converter mud, iron scale and dust) is further studied, and results show that when the ratio is 30% : 30% : 40%, the pellet strength reaches the maximum. After maintaining for 24~48h, the clumps can meet the mechanical as well as the physical-chemical requirements as BOF steelmaking refrigerant.IntroductionGreat amounts of converter mud, dust and iron scale are produced in steel production process. These materials are of great values, and their accumulation not only leads to environmental pollution, but also wastes the precious resources, which restricts the sustainable development of the steel industry [1,2] The main approach at present to dealing with the ferrous scrap is to add them into sintering. But in this way, the utilization factor of sintering and the quality of sinter decline while the energy consumption increases [3].Therefore, more advanced and efficient technology is needed to make the best of these iron resources. Cold consolidation of ferrous scrap is a simple process that has many advantages such as less investment, quicker effect, lower energy and lower cost [4-5] But the conventional maintaining period is too long, usually up to four-six weeks, and the pellet strength is low. Therefore, the key points of the cold-bonded pelletizing are to develop a new adhesive [4,5] to shorten the natural maintenance cycle and to improve the strength of the pellets. A method on resource-oriented utilization of ferrous scrap (cold-bonded pelletizing) is brought forward, and these cold-bonded pellets can be used as coolant in converter. After maintaining for 48h, these cold-bonded pellets can satisfy the mechanical requirements to replace the converter coolant [6]."

Jan 1, 2013

By Ryan Marsters, Adam Pring

The Rawah Ditch is a mountainous water supply diversion which supplies Larimer County, Colorado with water since 1903. The ditch includes two historic tunnels excavated by drill and blast through a gneissic rock buttress. Both rock tunnels were failing with annual convergence. After a snowshoe-accessed eld investigation, nite element modeling, and an alternatives analysis, a diameter DE pipe was inserted within each tunnel and the annulus lled. The proect was implemented in an Alternative Delivery contract lasting ve months from eld investigation through procurement and construction.

Jun 23, 2024

By Xiaofei Guan, Adam C. Powell, Uday B. Pal, Srikanth Gopalan

This paper reports a solid oxide membrane (SOM) electrolysis experiment using an LSM– Inconel inert anode current collector for production of Mg and O2 at 1423K. The electrochemical performance of the SOM cell was evaluated by using various electrochemical techniques including electrochemical impedance spectroscopy, potentiodynamic scans, and potentiostatic electrolysis. The effects of Mg solubility in the flux on the current efficiency and the YSZ membrane stability during SOM electrolysis were discussed and examined through experiment and modeling. The electronic transference number of the flux were measured to assess the Mg dissolution in the flux during SOM electrolysis. A negative correlation between the electronic transference number of the flux and the current efficiency of the SOM electrolysis was observed.

Jan 1, 2014

By I. Filzwieser, S. Wallner, M. B. Hanel, A. Filzwieser

Whenever thinking about increasing tankhouse performance two major aspects has to be considered, the technological feasibility as well as the economical impact. For meeting the requirement of an increased current density leading to an increased productivity, Mettop has developed the METTOP-BRX Technology, which allows the introduction of fresh electrolyte between each pair of anode and cathode. As an example of a green field approach the installation at Xiangguang Copper Co., Ltd will be described. Since the start up in 2011, Xiangguang Copper Co., Ltd operates one of their two copper refining tankhouse with a current density of 420 A/m2 and a current efficiency above 98% in average. At Montanwerke Brixlegg Ag, as an example of a brownfield installation, the annual production could be increased by 50%. Although for many years a total of two industrial applications are in operation, the successful implementation of this technology that result in significant operational and economic advantages has not been fully accepted within the industry due to misunderstandings, incorrect interpretations and lack of awareness. It is intended with this paper to create a better understanding about the parallel flow technology and help to eliminate worries and concerns.

Mar 1, 2017

By R. H. Eric, P. Taskinen, A. Bhalla, P. Halli

Sustainable development requires less energy consumption with lower carbon footprint. In this review the solid state reduction behaviour of three oxide ores using methane gas are briefly summarized based on experimental work conducted in our laboratories. The discussion concentrates mainly on mechanisms of the reduction studied through SEM-EDAX and X-ray diffraction techniques. Limited preliminary kinetic input is also mentioned. Iron ore containing titanium and vanadium could be reduced significantly in the solid state with methane-hydrogen mixture up to 400 °C lower than is needed in ordinary solid state carbothermic process. The reduction of chromite and manganese ores were possible similarly at lower temperatures with potential energy savings lower carbon footprint.

Mar 1, 2017

By M. F. Goudge

BRUCITE associated with highly metamorphosed Precambrian limestone was discovered in the vicinity of Rutherglen in northern Ontario by the writer during field work on the limestones of that district in 1937, and later was identified in similar limestone at Bryson and Wakefield, Quebec. The brucite occurs as granules disseminated through the limestone (Figure 1) and comprises from 20 to 35 per cent of the rock. Such rocks may be referred to as predazzites or pencatites, depending on the proportions of the constituent minerals. In this paper, however, the general term brucitic limestone is used to designate limestone containing brucite. In none of the deposits does the magnesia content of the rock approach that of magnesite, and in the deposits near Bryson and Wakefield the magnesia content is only that of dolomite. Therefore, without some method of concentrating the brucite, the deposits would be of little or no more value as a source of magnesia than is ordinary pure dolomite, which is abundant in many parts of Canada. Investigations in the laboratories of the Bureau of Mines have, however, resulted in the development of a method whereby, from certain of the deposits, pure calcined brucite, or magnesia, in granular form can be obtained, apparently at a cost that will enable it to compete in eastern Canada with imported magnesia. The granular magnesia so obtained appears to be highly suitable for use in basic refractories, for making magnesium metal, and for various other purposes for which magnesia is commonly used. Prospecting in the neighbourhoods of the original discoveries has resulted in a number of other deposits being found in each of the three areas, and there is now apparently available s1.dficient brucitic limestone of a grade that will lend itself to commercial exploitation to supply for many years a large part of the present and prospective Canadian market for magnesia and its products. Furthermore, it is expected that additional deposits will be discovered as prospectors and others become more familiar with the appearance of brucitic limestone.

Jan 1, 1940