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By André de Albuquerque Vicente

Observou-se porosidade de Kirkendall em juntas soldadas dissimilares de liga Fe-Cr-Al do tipo 23Cr-7Al, e aço inoxidável austenítico AISI 310 (25Cr-20Ni). Utilizou-se como consumível de soldagem a própria liga Fe-Cr-Al. O processo de soldagem utilizado foi o GTAW. Caracterizaram-se 3 conjuntos de corpos de prova soldados com diferentes energias de soldagem, antes e após o tratamento isotérmico a 1150oC por 936 horas ao ar. Nos corpos de prova tratados termicamente, observou-se a formação de poros bem como significativas variações dos teores de Al nos metais depositados e formação de camada protetora de alumina nas superfícies oxidadas.

Oct 30, 2017

By Zhang Chuanfu

The fibrous nickel oxide powder was prepared by the method of chemical precipitation and pyrolysis, that is, the NiO precursor was firstly precipitated from nickel ions solution with addition of oxalate salt and then the final NiO powder was obtained by pyrolysis of the prucursor. The effects of the pH, reaction temperature, reactant concentration, addition of surfactant on the morphology of the precursor particles were investigated. The influences of the various conditions, including the temperature and time, the air flow and the speed of the temperature increase on the morphology, average size and specific surface area of the NiO particles were also addressed. The fibrous NiO particles with IOO~ 120 in axis/diameter ratio and 5.5 m2/g of the specific surface area may be produced under certain operation conditions by this process.

Jan 1, 2003

The history of the discovery and development of the Kambalda nickel orebody. is reviewed and the decision to process the Kambalda concentrates by the Sherritt-Gordon process at Kwinana is discussed. The Kwinana Nickel Refinery is described and the problems encountered in the first year of operation are Outlined.

Jan 1, 1971

By M I. Pownceby, N A. S Webster, J R. Manuel, J M. F Clout, E Donskoi, N A. Ware

The relative influences of sinter mineralogy, sintering temperature, solid and pore macro- and microstructure on iron ore sinter physical strength are not yet fully understood. Whilst a range of analysis techniques have been used by researchers to evaluate sinter physical properties and sinter mineralogy, none have been able to directly link sinter mineralogy and physical strength under controlled conditions. CSIRO has developed a unique laboratory method to study the fundamental melting properties of fine iron ores in a laboratory furnace under a controlled temperature and gas atmosphere environment designed to simulate the industrial sintering process. Compacted tablet samples for a 0.41 per cent and a 2.5 per cent Al2O3 series were fired in a tube furnace at various temperatures, cooled, then tumbled using a modified Bond abrasion test apparatus to determine a relative tumble index (TI) at each temperature. Quantitative XRD (QXRD) analysis was then carried out on the tumbled samples and optical image analysis (OIA) was conducted on polished sections of a separately fired compact in each case. The amount of total SFCA was found to decrease with increasing firing temperature for both alumina series with the total amount of SFCA higher in the 2.5 per cent Al2O3 series compared to 0.41 per cent Al2O3 series samples. The increase in the amount of magnetite and hematite with increasing firing temperature was largely at the expense of a decrease in total SFCA. Overall, there was good agreement between the quantitative mineralogy determined from QXRD versus OIA for SFCA, hematite and magnetite. Qualitative analysis of high magnification images of the sinter correlated with both the OIA and QXRD results.

Sep 18, 2023

By Ahmad Ghahreman, James McNeice

Separation of rare earth elements (REE) is often achieved by acid leaching of mineral concentrates followed by subsequent solvent extraction (SX), to purify individual rare earth metals (REM). Cerium, the most abundant REE, is usually the largest component of these ores. Demand for less prevalent REE, such as praseodymium and dysprosium; have led to a market saturation and price collapse of cerium. One method of improving the economics of REE separation is to remove cerium from solution prior to SX. This is accomplished via the oxidation of cerium (III) to cerium (IV), which precipitates as cerium hydroxides. This study probes the efficacy of four oxidants; hydrogen peroxide, sodium hypochlorite, potassium permanganate, and Caro’s Acid with the goal of improving cerium removal whilst minimizing REE and reagent losses. The effect of oxidant type and dosage, pH, cerium concentration, and temperature on the kinetics of the process will be discussed.

Mar 1, 2018

By P. Kim, M. Tangstad, T. Larssen, R. Kawamoto

The reduction rates of MnO and SiO2 were investigated for various charge compositions. The empirical activation energies of MnO and SiO2 reduction from SiMn slags were calculated between 1500 and 1650 °C under CO atmospheric pressure. The amounts of metal produced at different temperatures were compared, and the Arrhenius plots were described for each slag A, slag B and synthetic slag, which shows that the raw material have significant influence on the reduction rate. The rate of Mn-produced in slag A was faster than slag B despite of the relatively lower driving force. The lower rate constant in slag B implies that other kinetic factors, such as viscosity, affects the reduction rate. The estimated activation energies of MnO were 920, 304 and 975 kJ/mol MnO for slag A, slag B and synthetic slag, respectively. The rates of Si-produced were similar and slow for all slag types. However, the different activation energies of SiO2 between industrial ores and synthetic materials implied that the trace elements can have catalytic effects toward SiO2 reduction in SiMn slags. The estimated activation energies of SiO2 reduction were around 800 kJ/mol for slag A and slag B.

Mar 1, 2017

By S. K. Shaha, A. Gryguc, S. B. Behravesh, B. Williams, M. Wells, H. Jahed

Warm forging to near final product geometry shows promising benefits in terms of microstructure refinement and texture modification. In the present study, Semi-closed die forging was performed on extruded AZ80 magnesium alloy at a forging temperature of 400 °C and various forging ram speeds. Compression tests were performed to investigate the influence of forging at various deformation rates on the performance of extruded AZ80 magnesium alloy. The microstructural analysis showed that the extruded AZ80 possesses a grain structure typical in wrought magnesium alloys, with sharp basal texture. In contrast, the forged samples had a recrystallized microstructures and a spatially varying textures and crystal orientations resulting from the complex flow behaviour within the closed die forging. Furthermore, once forged, a significant increase in the material isotropy, homogeneity as well as failure elongation were observed. An increase in UCS of 9% was observed in the forging direction, while the UCS in the extrusion direction was similar to that before forging. The changes in UCS can be attributed to both the refined grain microstructure and crystal reorientation. Successful microstructure recrystallization occurs for strain rates which traverse several orders of magnitude, and in general, UCS isotropy increases with increasing strain rate. It is believed that forging cause’s grain refinement and texture modification which act to enhance the mechanical performance (UCS, fracture strain and superficial hardness) for the forging conditions investigated in this study.

Mar 1, 2017

By Yuanbo Zhang, Zijian Su, Bingbing Liu, Guanghui Li, Tao Jiang

With the depletion of rich manganese ores, high-Fe content manganese ores are becoming the mainstream resources for manganese extraction. Reduction roasting-magnetic separation process is reported as a relatively effective route to realize the separation of manganese and iron. This study investigated the phase transformation of MnO2 and Fe2O3 briquettes (molar ratio 1:1) roasted under various temperatures and CO–CO2 atmospheres. Results showed that when the CO content was in the range of 0–10 vol%, MnxFe3−xO4 (x = 0−1) phase was formed and its content increased with the rising of temperature. The formation of ferromagnetic MnxFe3−xO4 with strong magnetism resulted in an inferior separation of manganese and iron by magnetization roasting-magnetic separation process. With the increase of CO content to over 25 vol%, the MnxFe3−xO4 content decreased while the content of feebly magnetic substance (MnO)y(FeO)1−y(y = 0−1) increased. Further increasing the CO content to over 80 vol%, (MnO)y(FeO)1−y was reduced to MnO and metallic iron.

Mar 1, 2017

By D. S. Barr

Mineralogical, lithological, and metallurgical studies were conducted on various gold ore deposits currently controlled by Freeport-McMoRan Gold Company. Ore samples were first lithologically and mineralogically categorized, then subjected to chlorination, roasting, and autoclaving pretreatments to determine their effects on gold recovery in a subsequent alkaline cyanide carbon-in-leach extraction. The studies indicate that, while organic carbon and sulfide sulfur are the primary refractory components, their effect on process response must be interpreted with respect to the deposit's geology and mineralogy. This approach has proven to be an effective method for evaluating metallurgical alternatives and fore-casting future mill performance.

Jan 1, 1987

By Thiago Rangel Bittencourt

Com a tendência de aumento da complexidade geométrica dos painéis de cobertura dos automóveis, aumento de resistência mecânica e diminuição da espessura dos materiais, a estampagem dessas peças tem tornado cada vez mais difícil. Neste contexto, dois graus de aços que exibem elevada resistência mecânica e boa conformabilidade, têm sido ofertados pela siderurgia à indústria automotiva, o Bake Hardenable (BH) e o Interstitial Free High Strength Steel (IFHSS). O presente estudo teve como objetivo avaliar aços BH e IFHSS, em termos de propriedades mecânicas, de conformabilidade, de ganho de resistência em função da deformação, envelhecimento e de resistência à indentação, em escala laboratorial. Desse modo, visou-se avaliar sob quais condições de estampagem deve ser decidido o uso do BH ou do IFHSS em aplicações de painéis automotivos. Os aços avaliados, de um modo geral, apresentaram desempenho similar em termos de conformabilidade. O aço BH foi superior ao IFHSS em relação à resistência à indentação. Portanto, o aço BH aparece como uma solução técnica atrativa, comparativamente ao aço IFHSS, quando aplicado em painéis externos (capôs, portas e paralamas) que requerem maior exigência quanto à resistência à indentação.

Aug 7, 2018

By Y Lanwin

The Australian mining industry, a cornerstone of the nation’s economy, is on a journey towards greater equity and inclusion. Th paper introduces a comprehensive exploration of how universal design principles, stemming from architectural roots, have evolved through automation and digital technology into the more encompassing frameworks of inclusive design and equitable design. The paper proposes a practical framework for those involved in work, facilities and equipment design in the mining industry to identify and assess for equity and inclusion. Universal Design emerged in the 1960s with a primary focus on architecture, aiming to create spaces accessible to people of all abilities. Its foundational principles sought to ensure equitable use, flexibility, simplicity, perceptibility, tolerance for error, low physical effort and optimal spatial considerations. Over time, these principles evolved and expanded beyond physical spaces, finding applications in various fields, including technology, education and transportation. In response to advancements in technology and a growing understanding of the multifaceted nature of diversity, Universal Design evolved into Inclusive Design. Inclusive Design goes further than mere accessibility, considering a broader spectrum of users with varying cognitive, sensory, cultural and socio-economic backgrounds. It emphasises user centred design, customisation options, diverse user research and continuous iteration. Equitable Design emerged as a framework that addresses not only the diversity of needs but also systemic disparities. It emphasises fairness, justice and the elimination of structural inequities. Equitable Design encompasses accessibility and affordability, representation and diversity, ethical considerations and community engagement. This paper will explore the applications of these design principles through a series of case studies including village and on-site facilities, remote operations and office based work design and technology design. By applying these frameworks in a mining context, the paper proposes that mining companies and suppliers can improve diversity, equity and inclusion leading to safer, more engaged and productive workplaces.

Apr 16, 2024

By J. J. Antony

As the first wave of precious metal heap leach closures and reclamation projects occur, a number of companies are being hit with costly surprises. While this paper refers specifically to U.S precious metal projects, it could be conceptually directed at copper leach operations and acid rock drainage (ARD) problems on an international basis. ARD is Mother Nature's version of heap leaching, only with different products and timing. Although many precious metal deposits tend to be small in comparison with some base metals systems (porphyry copper deposits), adjacent or nearby discoveries have extended the operating lives of numerous precious metal mines. Now, depleted reserves, several years of relatively depressed precious metals prices and some properties with technical difficulties have resulted in numerous mine closures. As a result, our industry is getting a diverse and comprehensive initial look at mine closure and final reclamation. The situation has been further complicated by the evolutionary trend in regulations and their enforcement and increasing public and political awareness of all environmental issues. Concurrent (proactive) vs. deferred (reactive) reclamation and a realistic early appraisal of ultimate reclamation and closure requirements, not just regulatory compliance, need to be a part of project design. The U.S. and Canada are the current fertile testing grounds and have set the design, regulation and closure standards for the next wave of operations in Latin America, the CIS (?), etc.

Jan 1, 1994

By K. Adham, T. Buchholz

Debottlenecking of high temperature processes within an existing metallurgical plant can significantly increase the throughput to meet new production demands. Modeling and simulation can help to fulfil that aim through incremental changes and operational improvements, rather than the more expensive option of building new plants and facing new environmental and infrastructure challenges. This paper describes a methodology of how modeling tools can be used to simulate the processing steps, how to estimate their existing and ultimate capacities, and how to determine the minimum cost points for a plant capacity expansion. This technique is presented through a generic description that can be applied to different metallurgical processing studies. We start with heat-and-mass balances, draw a bottleneck diagram, brainstorm capacity increase options, and prepare a cost-capacity curve. Hatch has successfully applied this technique to a number of plant capacity studies, with great benefits to our industrial clients (Adhametal et al. in A Success Path from Process R&D to Commercial Plants, Montreal, Canada, [1]).

Mar 1, 2017

By C. H. Bucknam

A review of phase analysis methods used to characterize refractory gold ores is presented. Updating of assay methods using database technology, on-line instrument interfacing and response surface modeling is highlighted. The use of assay results to classify ores for metallurgical purposes is demonstrated.

Jan 1, 1987

By D. L. Crouse

The worldwide talc industry has experienced significant changes since the 1980's. Consolidation of companies and operations in Europe, Australia, and North America has altered the face of supply and distribution. Imports of Chinese and Australian crude have increased competition and product options. The number of processing operations without local mines has moved competition closer to the market area. Quality controls related to ISO certification and tighter specifications demanded by the customers have altered the way our mines and mills operate. Ceramics, coatings, and paper applications continue to consume the majority of processed talc.

Jan 1, 1997

By J Wen, P Hou, W Yu, M Hu, Z Jiang, C Bai

Vanadium titano-magnetite (VTM) is one of the important iron ore resources in the world. High viscosity and low fluidity are the basic characteristics of hot metal containing vanadium and titanium during the ironmaking process. Clarifying the influencing mechanism of the melt viscosity would be a significant issue for the high efficiency smelting of VTM. In this paper, a self-developed melt viscometer based on the principle of torsional vibration theory was employed to measure the viscosity of hot metal accurately. Simultaneously, the thermodynamic calculations and some modern detection methods were also used to investigate the precipitation behaviour of high-melting-point phases in hot metal containing vanadium and titanium. The measuring results show that the viscosity of molten iron gradually increases with the increase of titanium content when the mass fraction of titanium is between 0.09 wt per cent – 0.50 wt per cent. Meanwhile, the viscosity of the hot metal was affected significantly by the vanadium content. When the vanadium mass fraction was higher than 0.30 wt per cent, the viscosity of hot metal increased sharply, which will have a serious impact on the fluidity of the hot metal. Furthermore, it was revealed by thermodynamic calculations that an increase in titanium and vanadium content would result in the precipitation of high melting point phases such as TiC, TiN, VC, and VN in the molten iron, ultimately resulting in a decrease in its fluidity. Meanwhile, it was confirmed by Scanning Electron Microscope (SEM) observation that the precipitates in the hot metal were compounds consisting of V, Ti, C, and N elements, which agrees well with the thermodynamic analysis results.

Aug 21, 2024

By David A. Campbell

There has been a long history of ironmaking on the North East coast of England centered around the River Tees. The industry developed here because of the availability of good coking coals to the North in Co. Durham, and the discovery in 1851 of ironstone in the nearby Cleveland Hills, South of the .River. Cleveland ironstone is relatively poor in quality, with an iron content not exceeding h% and high proportion of sulphur and phosphorous. The iron exists in chemical association with alumina and silica, and physical beneficiation processes involve a serious loss in iron unless the upgrading is limited, when the economics of the process become doubtful. Over the years, richer foreign ores have replaced the local ironstone, and the last operating mine was closed in 1964.

Jan 1, 1982

By D. L. H. Forbes

(New York Meeting, February, 1912.) Introduction.. THE application of the cyanide process to complex sulphide ores for the extraction of their bold and silver is no longer a novelty, but, as an example showing modern tendencies in this direction, the following description of the new milling process at the Lucky-Tiger mine is offered: The extraordinary richness of the ore in the upper workings of this mine made any thought of milling in its early hays seen unnecessary. Its location in an almost inaccessible part of the rugged mountains just south of the Arizona boundary-line, and 60 miles from the town of Douglas, made the expense of bringing in machinery and supplies a very serious consideration. But, after the property had been shipping high-grade ore on mule-back for a few years, there remained in the mine a considerable tonnage of vein-matter that was too low in value to ship, but which it was thought could be milled near the mine at a profit. The first milling-experiment consisted in the installation of Nissen stamps in conjunction with concentrating-tables and Frue vanners, but, as the ore from the upper workings contained most of its silver in the form of cerargyrite, this type of mill was not successful. The proximity of the mine to the great copper-concentrating mills of Cananea and Moctezuma naturally made the influence of copper-milling, ideas felt in the company's next installation. At considerable expense a stage-crushing concentrating-mill, with a capacity of 100 tons per day, was built. This mill was modeled along the lines of the most approved practice in copper-concentrators at that time, the main idea being that crushing by stages in rolls was necessary in order to prevent losses from ?sliming." Largely owing to the fact that, when the mill

Aug 1, 1912

By G. B. Harris

Jaguar Nickel Inc. is developing the Sechol Nickel-Cobalt Laterite Project in Guatemala, Central America. Recognizing the potential advantages offered by chloride brine chemistry, Jaguar, at the facilities of Process Research ORTECH Inc, Mississauga, has developed an Atmospheric Chloride Leaching Process using a mixed chloride lixiviant to recover the nickel and cobalt, whilst leaving the majority of the iron and magnesium in the leach residue. Subsequent solution purification and mixed nickel/cobalt hydroxide product recovery is by standard precipitation methods, using recycled caustic magnesia, with a final stage of pyrohydrolysis of a portion of the concentrated magnesium chloride brine for recycling both the caustic magnesia and chloride lixiviant. The flowsheet that has been developed also offers opportunities for by-product recovery and efficient, environmentally clean process effluent management. The paper discusses some of the early leaching results in the context of strong chloride brine chemistry, with emphasis on how the controlling of water activity, hydrogen ion activity and chloride concentration permits the selective leaching of nickel and cobalt from an iron-magnesium matrix. Keywords: nickel, cobalt, iron, magnesium, Sechol, Guatemala, chloride, pyrohydrolysis

Jan 1, 2004

The use of coal as a fuel causes air, pollution in; a number of different forms, and in nearly all stages of its, handling, preparation, storage, use and-disposal of its residue. First let us consider the handling of coal. As shipped, particularly to large utilities, it is run-of-mine bituminous made up of large chunks as well as pulverized particles. Because it 'is in an open car or barge, it is subject to the action o winds and the small particles may be blown around adding to the-particulate load in the atmosphere. Mien un¬loaded from the barge or car, there is again an opportunity for the wind to blow the fine particles around. All of us I am sure have seen a barge at the dock of a utility plant being unloaded by a clamshell bucket. This, after grabbing its load from the barge, lifts it some 60 or 70 feet and, then drops it on a conveyor, which carries the coal to a storage area.

Jan 1, 1964