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By D Bruggemann, F Sereshki

There has been an ongoing research on coal and gas outburst for the past two decades at the School of Civil, Mining and Environmental Engineering, University of Wollongong. Research study began with a humble beginning, initially conducting basic laboratory studies on the coal and gas properties, progressing into the determination of gas content of coal by sorption technique and the effect of gas pressures on coal strength. The present laboratory facilities and research interests are extended to include the study of coal permeability and shrinkage properties and their effect of gas drainage characteristics with respect to gas type, and pressures. All the changes are examined with respect to changing in-site geological conditions of the coal deposit investigated. The aim is to provide a long-term support to industry in establishing a data bank for Australian coal deposit characteristics and properties.

Jan 1, 2005

By W. D. Monaghan

One of the major ignition sources of fires and explosions in underground U.S. coal mines is flame cutting and welding. On May 20, 2006, a flame-cutting operation at the Darby Mine No. 1 led to an explosion that resulted in five fatalities. On Jan. 22, 2003, another explosion caused by flame cutting at the McElroy Mine resulted in three fatalities and three serious injuries. On June 22, 1999, a flame-cutting and welding operation at the Loveridge Mine caused a fire that required sealing the mine for an extended period. On March 19, 1992, an explosion initiated by welding at the Blacksville No. 1 Mine resulted in four fatalities. These examples of mine incidents demonstrate the need to conduct research to develop best practices for safely conducting flame cutting and welding in underground coal mines. The National Institute for Occupational Safety and Health (NIOSH) conducted a study on fires and explosions in underground U.S. coal mines that were caused by flame-cutting and welding operations to determine the root causes of these types of incidents. The methodology included interviewing mining personnel who perform flame-cutting or welding operations in underground U.S. coal mines and visiting mines to observe these operations. In addition, MSHA reports of investigations and accidents statistics were analyzed. The findings were used to identify and compare differences between flame-cutting and welding practices and techniques in small and large mines, eastern and western mines, low-seam and high-seam mines, room-and-pillar and longwall mines, and between experienced miners and new miners. As a result of this study, best practices were developed to reduce the number of ?res and explosions caused by flame cutting and welding. This paper provides a summary of this research.

Jun 1, 2010

By Hong Zhong, Shuai Wang, Zhanfang Cao, Ting Dai

"Manganese is widely used in industries such as the steel industry and is now an essential element in modern industry. Technologies for the efficient and clean utilization of manganese resources must be developed and employed to ensure the sustainable growth of the manganese industry. Our research focuses on the use of beneficiation technologies to improve the grade of ores or the replacement of low-grade manganese carbonate ores with high-grade manganese oxide ores, and thus, to reduce reagent and energy consumption and the yield of electrolytic manganese residues from metallurgical processes; the study of leachate purification technologies; the study of electrochemical behaviors during electrolysis and energy-saving electrolysis methods; the development of chromium-free passivators as alternatives to the highly toxic potassium dichromate passivator; the non-hazardous treatment and resource utilization of electrolytic manganese residues and other manganese by-products; and the development of new manganese products. INTRODUCTION Manganese is widely used in the steel industry, nonferrous metallurgy, the chemical industry, electronics, batteries, agriculture, etc. Globally, more than 90% of manganese is consumed by the steel industry, and thus, it is said that ""No steel industry without manganese""(Banerjee et al. 2017, Zhang et al. 2017). Current manganese resources mainly include manganese ores, marine manganese nodules and waste catalysts. The total global output of manganese ore from land deposits is 18 million tons (metal volume), and the reserves, most of which is in the form of manganese oxide ores, are estimated to be 620 million tons (metal volume). More than 400 manganese ore deposits with a total reserve of 1.22 billion tons have been discovered in China. These deposits are predominantly manganese carbonate ores. Marine manganese nodules exist on the surface of the deep seabed at depths of 2000-6000 m. These nodules, which are also called polymetallic nodules, manganese balls, manganese aggregates and manganese tumors, are mainly composed of iron and manganese oxides. The total reserves of these resources add up to more than 3 trillion tons. Furthermore, the manganese in manganese-containing catalysts can be recycled after they become inactive."

Jan 1, 2018

By Adrian C. Deneys, David G. C. Robertson

"Fluid flow phenomena on the surface of a molten slag have been documented using video photography in a laboratory scale D.C. arc furnace. The flow on the surface of the slag appeared to be electromagnetically influenced. This was confirmed by varying the position of the anode, which changed the direction of flow on the surface of the slag. Temperature measurements in the bath also confirmed the change in the directional nature of the fluid flow induced by the arc.During some periods, solids were fed into the arc attachment zone (AAZ) down the center of the hollow graphite electrode. Significant movement of the arc around the basal annular surface of the hollow electrode takes place. The point of attachment of an arc on a hollow electrode was more variable than an arc attached to a solid graphite electrode. Video images showed that the solids were rapidly incorporated into the bulk of the slag. Temperature measurements confirmed the existence of a superheated slag layer at the slag-gas interface, which allowed the solids to be rapidly incorporated into the melt.This work has been conducted to study fluid flow, temperatures, and solid behavior during feeding, in the arc attachment zone of a D.C. arc furnace. The work also has relevance to optimizing furnace design for pyrometallurgical slag cleaning processes."

Jan 1, 1999

By A. Hasko

Phytoremediation is a new low cost alternative technique for remediation of contaminated soils from heavy metals that are emitted by ferrous and nonferrous mining and extracting processes. It is based on the possibility to use several plants that accumulate high level of metals in order to remove metallic pollutants from soils and render them harmless. Phytoextraction is an adjacent new technique that uses these hyper-accumulator plants in order to extract the metals from them using even the conventional smelting or refming processes. In our previous work, an extensive investigation of about 150 plants have been carried and several species were identified that could be used for nickel phytoremediation and phytoextraction because of their high accumulation of nickel. It has been found that five taxa from Alyssum genus specie had the highest ability to accumulate nickel with concentrations more than 10000 ug/g (dry weight) or 1%. The taxa showing the highest accumulation of this metal is Alyssum murale var. chlorocarpum with 28 600 ug/g or 2.86%, a good candidate for Phytoextraction. In this work, in order to optimize the phytoremediation and phytoextraction processes further Absorption Spectrometry measurements and biological studies were carried out to determine the parts of the plants that accumulate the highest amount of nickel and the best biological cycle during which they accumulate the highest amount. The results show that the greatest accumulation of nickel occurred in the leaf material (2.86%) and the least in the roots (0.43%). The investigation of the biological cycle of the genus Alyssum showed that: (1) the seeds germinated between 50 C to 30 0 C and more in 25 0 C; (2) 62.9 % of seeds germinated at A.m. var. chlorocarpum; (3) the emergence is almost continue from March to April; (4) the anthesis occurs from May to July; (5) the ripening of the fruit takes place 30 days after flowering; (6) the dissemination of fruits occurs from September to October. Due to these special characteristics it is reaffirmed that Alyssum murale var. chlorocarpum, as a nickel hyperaccumulator, is the most promising plant to be used for feasible phytoremedation and phytoextraction purposes. Keywords: Key words: Phytoextraction, PhytoRemediation, Nickel accumulators, Alyssum sp., Biological cycle

Jan 1, 2003

Many USBM research and information products are available through the systems or formats listed below: Mines FaxBack: Return fax service. 1. Use the touch-tone handset attached to your fax machine's telephone jack. (ISDN [digital] telephones cannot be used with fax machines.) 2. Dial 202/219 3644. 3. Listen to the menu options and punch in the number of your selection, using the touch-tone telephone. 4. After completing your selection, press the start button o your fax machine. Mines Data: Computer bulletin board. Log on via modem through 202/501-0373, or call 202/501-0406 for technical assistance. CD-ROM: This USBM disk is updated quarterly and sold by GPO's Superintendent of Documents. For information on the latest product, please contact Rodger Wedgeworth, 202/501-9557. Internet/World Wide Web: Text and graphics. Access via PC-based browsing software such as Netscape or Mosaic. Universal Resource Locator (URL) is: http:/www.usbm.gov Internet/Gopher Server Text and tables only. Using Gopher client software, access via port 70 as follows: gopher.usbm.gov Internet System Administrator: webmaster@usbm.gov (or contact your local System Administrator).

Jan 1, 1995

By M. Fafard, D. Picard, J. -F. Bilodeau, G. Soucy

To simulate adequately the behaviour of a Hall-Heroult electrolysis cell, a finite element model must take into account the properties of each material. However, it has some lacking knowledge on the mechanical behaviour of materials, like the long-term visco-elastic (creep/relaxation) behaviour of cathode. A three-dimensional model is then proposed in this paper and will be ready to be implemented in the finite element code FESh++. The model was developed using the three-dimensional model based on thermodynamic of irreversible processes where the choice of the internal variables is based on a phenomenological approach. All parameters of the model are represented by constant constitutive tensors and the temperature and chemical dependencies are taking into account through scalar functions multiplying the constant constitutive tensor. The goal of the first part of this project was to determine the parameters of the threedimensional visco-elastic model at the reference state (virgin material at ambient temperature) of three different cathode materials. This paper presents the theoretical model and the results of creep tests at ambient temperature for the semi-graphitic carbon cathode.

Jan 1, 2006

By James J. Broderick

In the production of Pig Iron - Limestone, Coke and Iron Ore pellets are changed to the blast furnace and reacted at approximately 2,800 degrees F. The resultant products are molten iron and a molten slag - not unlike lava. The molten slag stream is channeled into open pits, cooled with water, crushed and sized for various industrial applications. The production of steel from pig iron in open hearth, B0P, BOF and electric furnaces results in somewhat similar slags: but since free lime is normally the flux, the resultant slags are not satisfactory for use in cement pastes. When exposed to water, the lime slakes, expands by 250% and ruptures the concrete. Thus, the slag discussed first is Blast Furnace Slag composed of 30 to 40% Silica (SiO2) Alumina (AL202) 7 to 16% Lime (CaO) 32 to 45% and Magnesia (MgO) 5 to 15%. The oxides do not exist as free oxides but rather as silicates and alumino silicates which are chemicall inert. Since transportation costs limit the area of use, blast furnace slag can only be found in concrete products produced within 60 to 100 miles of a blast furnace operation. Even within these areas where slag is in heavy supply, quite often the use of slag is minimal for concrete aggregate and the major outlet is road base.

Jan 1, 1985

By Maneesh Singh

During the various stages of iron & steel production a number of iron-rich by-products are generated. The traditional way to recycle them back to the blast furnace has been the balling - sintering process. These by-products can also be made into cement-bonded agglomerates for use as burden material for blast furnaces. In order to improve the quality of agglomerates the effects of various processing parameters on the properties of cement-bonded briquettes have to be controlled. This paper looks into the various aspects of producing cement-bonded agglomerates and using them as burden material for blast furnaces.

Jan 1, 2003

By M. K. Patel, K. A. Pericleous, M. Molaei

"The future trading of carbon credits and increased financial cost necessitates substantial cuts in incidental C02 emissions in the production of metals (iron, steel, aluminum, zinc, lead). Although greener methods of production are being developed, in the short term the use of point-source C02 extraction using existing technology remains attractive. Accelerated natural carbonation, in a fluidized bed is a feasible technological route investigated in this research. CFD modelling has been used to study the efficiency of C02 capture in a fluidized bed reactor containing a CaO solid sorbent. A Lagrangian/Eulerian scheme describes describe CaO particle trajectories and exchange of mass, momentum and energy with the carrier gas, with a typical off-gas composition. Different reactor geometries are considered (with uniform, stepped and gradually expanding cross-section), to maximize conversion for a given particle loading and size distribution (100-200 microns). Removal efficiencies of up to 80% are demonstrated, making this a viable process.IntroductionBased on Intergovernmental Panel on Climate Change (IPCC) reports, the major cause of climate change and global warming is due to a high level of C02 concentration in the atmosphere resulting from fossil fuel combustion, particularly in coal-fired power plants [1]. Carbon capture and storage is therefore the most important action proposed to reduce C02 from combustion flue gases. In this process, carbon dioxide is captured and may then be regenerated as pure C02 and conducted to a permanent storage, or simply stored as a solid carbonate [2]. Capture and storage of C02 has an economic penalty and the main cost of this penalty is associated with the capture plant. Capturing C02 with a lime-based solid sorbent (CaO) is a very promising technique, due to the low cost and the wide availability of the reactant. In this process, the CaO reacts with C02 based on the following reaction in a reactor called a Carbonator:"

Jan 1, 2012

By Edward R. Lauer

Energy conservation is an integral part of Canada's energy strategy. We must pursue conservation and energy management vigorously if we are to remain competitive in domestic and world markets, and minimize our reliance on external energy sources. Energy management in industry is discussed from three viewpoints: (l) as a means of directly improving profitability; (2) as a major factor in the supply picture; and (3) as a significant influence on Canada's balance of payments and over-all economic well-being. The Federal role in promoting a voluntary industrial energy conservation program is described.

Jan 1, 1977

By C. H. Smith

The present interest in beryllium seems to be the result of recent developments in the uses for the metal discovery of significant deposits of disseminated beryllium ores, and the development of chemical and physical processing techniques, for recovering the beryllium values contained in these ores. At the present time most of the new and potential uses for beryllium are in the research stage of development and are not consuming large quantities of the metal. However, they do point to an expanding market. Interesting new discoveries or extensions of previously known deposits have been reported during the past year from the Boomer Mine in Colorado, the Mesquite area of Nevada,, the Chemalloy pegmatites in Canada, the Brazilian and African pegmatite districts and from other areas, However, this paper will discuss only four of the beryllium deposits, which appear to be of special significance due to their; large reserves of ore and promise economic development. The new chemical and physical processing techniques are not discussed in detail, but it should be stressed that the development of an economical process to handle the pegmatitic and low-grade non-pegmatitic beryllium ores is of great importance to the development of the beryllium industry. Scientists in both government and industry are co-operating in this effort and it is expected that commercial processes will be developed in the near future.

Jan 1, 1962

By G. Sedelnikova

This paper is aimed to elucidate the problem of copper losses in pyrometallurgical slag. Currently, flotation is used to recover copper from the slag and return the metal into the pyrometallurgical process, but the percentage of recovery frequently remains unacceptable. The process of copper leaching from the slag flotation tailings using biologically regenerated ferric sulfate is considered here as an approach to the issue. A sample of the slag flotation tailings containing 0.67% Cu and 4.99% Zn was supplied by the Urals Mining and Metallurgical Company (UGMK, Russia). The Cu and Zn speciation analysis of the sample demonstrated that Cu occurred as 58.1% oxide, 15.4% native Cu, and 18.1% secondary sulfides whereas chalcopyrite proportion was as low as 8.4%. Prevailing Zn species were refractory (58.9% Zn ferrite), and zinc oxide and silicate species made just 37.2% of the total metal content. The silicate generated silica gel that strongly hampered filtration. As demonstrated, Cu recovery is a possibility, which is apparently not the case with Zn. In this work, the stirred tank bioreactor acid leaching employing bacterial Fe3+ sulfate solutions was studied, with ferric sulfate being a product of Fe2+ biological oxidation and not the chemical reactant adding of Fe3+ sulfate. Acidithiobacillus, Sulfobacillus, and Leptospirillum bacilli were employed in Fe2+ biooxidation. Temperature, pH, Eh, S:L ratio, leaching time, and Fe3+ concentration in the source leachate as the process controls were considered. As demonstrated, the process employing biologically regenerated ferric sulfate proved to be more efficient than conventional chemical leaching. Under the optimum conditions, the proportion of Cu extracted into leachate during 2 hours was 79.1%, and that of Zn 27.2%. Precipitation of high-grade Cu sulfide served to extract the metals from the leachate, and Cu extraction was 99.7%. All in all, 23.2% Cu, 0.03% Zn, and 0.02% Fe was returned into the pyrometallurgical process. Keywords: slag flotation tailings, copper leaching

Sep 1, 2012

By A. B. Coates, J. E. Crawshaw

"The use of such methods and apparatus as the Dautriche method and the Mettegang recorder for the determination of the rate of burning of black blasting powder and other strictly burning explosives has been found to give such erratic results that no reliance can be placed on the data thus obtained. Consequently, investigators of those factors which may affect the burning rate, such as size of grain, absolute density, chemical composition, and means of ignition have had to rely mainly on observations made during practical use for determination of the part played by each. Such tests are very difficult of interpretation.The purpose of this paper is to describe a method used by the explosives division of the Bureau of Mines for the investigation of such explosives and to present the results of an investigation using that method.The investigation was concerned with the effect of grain size, initial pressure, and means of ignition on the rate of burning or rate of pressure development of black blasting powder as compared with pellet powder.The Bichel pressure gauge was used for these tests, with the slight modification to the apparatus and method described in U. S. Bureau of Mines Bulletin 15.4 These modifications consisted of reducing the speed of the revolving drum on which the time-pressure record is taken, measuring the speed of the drum by a belt-driven tachometer, and introducing an induction coil in series with the electric squib or electric detonator to mark on the time pressure record the instant at which the squib or detonator was fired."

May 1, 1929

By A. W. Khair, L. D. Gehl

"This paper describes the study of bit wear characteristics on three types of rock namely Tennessee sandstone, Berea sandstone and Indiana limestone. High content of quartz with quartz cement in Tennessee sandstone causes removal of material from the bit body and dam2ge to the tip of the bit resulting into excessive weight and height loss as compared to other two types of rock. The drum speed and water spray pressure do not contribute significant effect on bit wear. The polycrystalline compact diamond (PCD) tipped bits are more wear resistant than the ordinary tungsten carbide (WC) tipped bits, but, due to wider body of PCD bits, the wear rate increases particularly at greater depth of cut. INTRODUCTIONThe impact of bit-rock interaction during the cutting process in underground coal mines has always attracted the-interests of mining operators, researchers and the manufacturers. Coal cutting bears directly on airborne coal dust generation which causes ""black lung"" in coal workers. On the other hand, rock cutting generates frictional sparks causing face ignitions. The bit wear not only produces airborne rcspirable coal dust , but also affects the productivity, safety and economy. Hun and Evans (J) concluded that the point attack bits have greater ignition potential than the conventional wedge shaped bits. The results of a study (2) suggested that after 7% of weight loss, the bit should be replaced. In a survey study (3), it was found that the bit consumption of bit had an effect on the productivity and utilization of the continuous miners. The mining industry is yet to receive a solution which could provide them with optimum operating parameters for coal cutting machines in underground C9al mines.The study was, therefore, taken up to determine wear characteristics as influenced by the rock propenies and varying operating parameters. For the purpose of this study, three types of rock, Tennessee sandstone, Berea sandstone and Indiana limestone were used. The machine operating parameters included (i) drum speed, (ii) water spray pressure and (iii) bit type. Besides studying the wear characteristics, the effects of these parameters on the required cutting force, specific energy consumption, acoustic emission generation and bit temperature rise were also studied. Also, the preliminary experiments were performed to compare the bit wear between PCD and WC tipped bits."

Dec 1, 1995

By Robert W. Freedman

In the Bureau of Mines study, a filter with a 20-by 20-inch-square cross section was inserted into the exhaust ducting of a 4-stroke-cycle, 90-hp diesel engine, and the efficiency of removal of total particulate was measured gravimetrically as a function of time. Removal efficiencies were close to 90 pct during the main portion of several extended runs employing several combinations of filter beds. Variations in engine load had little effect on collection efficiency. Particle size as measured by a Bureau-developed online instrument centered on 0.07 m based on number count. Removal efficiency increased rather sharply for both larger and smaller particles.

Jan 1, 1979

By Rees D. Groves

The Bureau of Mines conducted research on reactions of copper sulfide minerals with chlorine in an aqueous system. Selected samples of covellite, chalcopyrite, chalcocite, bornite, and pyrite were leached with aqueous chlorine solutions. The mineral samples were sized on to minus 100- plus 325-mesh, individually mixed with precleaned sand and leached in an enclosed percolation column. Each mineral was leached in stages to achieve about 90 percent mineral dissolution. The chlorine leaching solutions were produced by reacting sodium hypochlorite with hydrochloric acid within the closed system. The study showed that when the mineral dissolution was complete, the reaction products (copper, iron, and sulfur) were in their highest oxidation states and a stoichiometric amount of chlorine was consumed. Although elemental sulfur formed as an intermediate product, it was oxidized to sulfate during the leach.

Jan 1, 1973

By Bertil I. Pålsson

The most common REE containing mineral that is worked today is bastnäsite. It means that mineral processes are adapted to it and that the metallurgical separation techniques for winning of individual REE are adapted to bastnäsite concentrates. For all other deposit types, suitable mineral processing methods and separation technologies need to be adapted and/or developed. Preliminary mineralogical analyses indicate that slightly less than half of the REE in the tailings dumps at LKAB/Kiruna are associated to apatite. The rest is in the minerals monazite (maybe associated to apatite) and allanite. At least allanite is probably not floatable with reagents commonly used for apatite. Mass and element distributions for the tailings sand reveal that very little apatite is present above 300 µm, and that approx. 30 % is below 20 µm. REE does not follow P2O5 completely and are also present in coarser fractions. Flotation results show that the best condition for both apatite and REE winning is pH 9, high collector addition and low dosage of water glass. Under these conditions, the lab-scale flotation gives an apatite concentrate with at least 30 % P2O5 at 70 % recovery. REE follows apatite in the cleaner steps but only partly. Its recovery is approx. half compared with apatite. The reason for the low REE recovery is likely to be that REE to a large extent is trapped in non-winnable minerals, especially allanite. The REE grades in the concentrate are expected to be in the range 3000 ? 4500 g/ton. Keywords: flotation, REE, apatite, monazite, allanite

Sep 1, 2012

By d&apos, F. Elia

Hot cracking of magnesium (Mg) alloys during welding creates a barrier to enhancing the use of these alloys in automotive applications. As a result, it is imperative to understand the mechanisms responsible for hot cracking of Mg alloy welds in order to develop means of eliminating this problem. In this study, the hot cracking susceptibility of AZ91E and AE42 magnesium alloys were assessed using the moving torch Varestraint test method. Plates of 3 mm thickness were extracted from AZ91E and AE42 ingots and subsequently tested. Quantitative cracking data in terms of maximum crack length (MCL) was used for evaluating the cracking susceptibility. Scanning electron microscopy was carried out. The results suggest that AE42 showed a higher resistance to hot cracking in comparison to the AZ91E alloy. This was attributed to the difference in microstructure between the two alloys. In the fusion zone and HAZ of AE42, the brittle needle-like A1IIRE3 phase was seen to decompose to the more ductile particle-like Al2RE phase, thereby increasing the alloy's resistance to hot cracking. In contrast, SEM fractography revealed that brittle A16Mn and Mg17A112 intermetallic particles segregated to grain boundaries and triggered hot cracking in AZ91E.

Jan 1, 2011

By E. Allain

Extraction of basic metals from sulfides by conventional pyrometallurgical processing leads to the emission of SO2. To avoid this inconvenient, low temperature selective chlorination of sulfide concentrates could be an alternative. However, such process generates hazardous chlorides SxCly. A part of sulfur chlorides such as SCI2 can be recycled as a chlorinating agent of metal sulfides. Hydrolysis of sulfur chlorides, using a solution containing Na2S.9H2O, led to the recovery of more than 90 pct of elemental sulfur. Reduction of SxCly by hydrogen was investigated between 300 °C and 800 °C. About 70 and 90 pct of elemental sulfur were recovered from SC12 and S2C12, respectively. A flow sheet for the chlorination of metal sulfides and the treatment of sulfur chlorides was suggested.

Jan 1, 1998