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By F. Baerhold, S. Mitterecker

"Acid recovery is an important process step in pickling and leaching processes. Pyrohydrolysis in spray roasters and fluidized beds is a well-established technology to recover hydrochloric acid, but the hydrolysis in the liquid phase is more and more considered as an alternative new process route. The characteristic features of these three processes will be discussed along with select industry trends. For example, hydrochloric acid based leaching processes for ilmenite and nickel laterite ores produce far larger volumes of waste acid streams than the steel industry. Scaling-up of the spray roasting technology to the highest possible capacity is necessary in order to become more cost effective. In addition, process routes based on ferric chloride pyrohydrolysis allow the production of super-azeotropic HCl (up to 30 wt.%). Finally, the new ECOmode concept optimizes the operation of both pickling lines and the spray roast acid recovery plant. Long term results from industrial applications show that fuel savings in the spray roaster of 25% are easily achieved without additional process steps. An attractive feature is also to upgrade existing installations to higher plant capacities.INTRODUCTION Pyrohydrolysis is the conversion of metal halides into metal oxides at elevated temperatures in the presence of water vapor. Reaction products are a hydrogen halide gas and a metal oxide. The process was originally developed and introduced into the market by ANDRITZ Ruthner in the 1960’s. It has found wide technical application in the field of acid recovery and oxide production. The introduction of this process has revolutionized pickling technology. The use of hydrochloric acid has strongly increased over the last decades, since pyrohydrolysis is available for the total recovery of waste pickle liquors from mild steel pickling, as illustrated in Figure 1.Chloride media are also used increasingly in the metallurgical industry. Oxide production processes for Mg, Co, Ni, and Al have been installed. Processes using hydrochloric acid are known for the leaching of ores as well as for the re-extraction of metals from organic solvents. In both cases the recycling of HCl is of substantial importance to achieve highly economic processes and to reduce waste."

Jan 1, 2016

The morphological changes that gold undergoes during transport in gravel-bed rivers are a function of transport distance in particular, as well as bedload material, river gradient and velocity, and bed roughness. Gold size, shape and outline are modified by abrasion, flattening, folding and breakage during transport. The resultant morphological characteristics can be used to predict source types, source location and transport distance, as well as the origin and dispersal patterns of gold in ancient placers where the transport history is unknown.

Jan 1, 1998

By C. O. Brawner, J. Kalejta II

The classical approach to control rock fall and ravel in open pit mining has been to use catch benches. The width and volume of benches is most dependent on the bench height, size of loading equipment, blast damage to the face and mining regulations. This was compatible with open pit slopes of less than about 45°. As our understanding of rock mechanics and blasting control has improved over recent years, much steeper rock slopes can be developed at many open pit mines. However, narrower benches result with less rock fall capacity. The transportation industry has been very successful in using catch fences to protect highways throughout North America and Europe for years. The authors recommend that cable and ring net fences have a potential major application in open pit mining to allow steeper rock slopes with significant economic benefit. This paper outlines the application, design and operation of catch fences in surface mining for specific conditions. Typical case examples are presented.

Jan 1, 2002

By Norman Maxwell

There was more activity in crude production in northwestern Pennsylvania in 1935 than for several years before, resulting in an increased oil production and also in the number of wells completed. Crude -production approximated 16 million barrels for the state, an increase of about one million barrels over 1934. Demand, indicated by refiners' runs to stills, increased proportionally, leaving stocks of available crude at the end of the year at the lowest point since the middle of 1934, when they reached an all-time low. The price of crude varied during the year from a low of $2.02 to a high of $2.27 at the end of the year for Middle district oil. The price of Bradford and southwest Pcnnsylvania oil changed accordingly. The average for the year would be a lower price than in 1934. A summary of the production data for the year 1935 is given in Table 1. In making up this table, 1935 figures were simply added to the table published by S. H. Cathcart last year1. A list of important wildcats is given in Table 2. Bradford Field Approximately 10,000 acres of the proven producing area of the Bradford field is in Cattaraugus County, New York, and it is possible, by differences, to distinguish the Pennsylvania production from the New York portion. The listed production for the Bradford field includes only that portion of the field situated in Pennsylvania, but also includes production from a small pool, locally known as the Mt. Jewett-Kanesholm pool, where the Bradford sand is being developed and flooded in precisply the same manner as that of the Bradford field itself. The Mt. Jewett-Kanesholm pool is not, strictly speaking, an extension of the Bradford field, but inasmuch as it is so closely allied with the Bradford field-—that is, the sand is the same and the production methods are the same—the production and drilling figures include this area.

Jan 1, 1936

By Norman Maxwell

There was more activity in crude production in northwestern Pennsylvania in 1935 than for several years before, resulting in an increased oil production and also in the number of wells completed. Crude -production approximated 16 million barrels for the state, an increase of about one million barrels over 1934. Demand, indicated by refiners' runs to stills, increased proportionally, leaving stocks of available crude at the end of the year at the lowest point since the middle of 1934, when they reached an all-time low. The price of crude varied during the year from a low of $2.02 to a high of $2.27 at the end of the year for Middle district oil. The price of Bradford and southwest Pcnnsylvania oil changed accordingly. The average for the year would be a lower price than in 1934. A summary of the production data for the year 1935 is given in Table 1. In making up this table, 1935 figures were simply added to the table published by S. H. Cathcart last year1. A list of important wildcats is given in Table 2. Bradford Field Approximately 10,000 acres of the proven producing area of the Bradford field is in Cattaraugus County, New York, and it is possible, by differences, to distinguish the Pennsylvania production from the New York portion. The listed production for the Bradford field includes only that portion of the field situated in Pennsylvania, but also includes production from a small pool, locally known as the Mt. Jewett-Kanesholm pool, where the Bradford sand is being developed and flooded in precisply the same manner as that of the Bradford field itself. The Mt. Jewett-Kanesholm pool is not, strictly speaking, an extension of the Bradford field, but inasmuch as it is so closely allied with the Bradford field-—that is, the sand is the same and the production methods are the same—the production and drilling figures include this area.

Jan 1, 1936

The Bureau has published much data on sulfur (4, 15, 23)3, most of it dealing with national or international aspects of the sulfur industry. Little information, however, is available on sulfur marketing in specific States or areas, Therefore, the Bureau has conducted a survey of the resources, production, consumption, and economic future of the sulfur and sulfuric acid industry in States of the Central and Southern Rocky Mountain area - Wyoming, Colorado, Utah, Arizona, and New Mexico - and in the Northern Plains States - North Dakota, South Dakota, and Nebraska, even though these States do not represent an economic or marketing unit. The purpose of this survey is to review the demand for sulfur and primary sulfur compounds that draws upon the natural resources of the region, to discover opportunities for better use of these resources, and also to analyze and evaluate the patterns of consumption, sources of supply, and other factors that affect the demand for these mineral products. While this survey stresses the economic and marketing phases of the industry, a complementary report (32) emphasizes the resources of sulfur in Wyoming, Colorado, Utah, New Mexico, and Arizona.

Jan 1, 1962

By Manqiu Xu, Songtao Yang, Zongfu Dai, Robert Pelton, Carla Abarca

"Fine mineral particles are difficult to process by flotation because of their low collision efficiencies with air bubbles. Decreasing air bubble size and increasing mineral particle size through flocculation are the most common approaches to improve flotation efficiencies. Herein we demonstrate that nanoparticle flotation collectors can be engineered to selectively induce fine mineral particle aggregation and promote flotation.Flotation tests of clean fine pentlandite (Pn) and Clarabelle Mill (CBM) rock tails and pyrrhotite (Po) tails that contained significant amount of fine pentlandite have confirmed that the nanoparticles can serve as both collectors and selective flocculants for fine pentlandite. In the case of clean fine Pn, the nanoparticle collectors virtually can float almost all Pn fines. Scoping tests on CBM tails have shown significant improvement in nickel recovery. Addition of nanoparticles as a flotation aid can recover 20% of the nickel contained in the rock tails and 40% of the Pn contained in the Po tails compared to current mill operations giving 0% nickel recovery from rock tails and no Pn selectivity from Po tails. Ongoing work includes attempts to identify optimal strategies for employing nanoparticles in fines flotation.IntroductionFine particle flotation is an industry-wide challenge in mineral processing. Fine mineral particles are difficult to process by flotation because fine particles have low mass and thus low momentum, which results in their low collision efficiency with air bubbles (Dai, Fornasiero, & Ralston, 1999). In addition, fine particles have not only high specific surface area but also more active surface area, which causes high reagent consumption. For base metal sulphide minerals, particle size between 10 µm and 70 µm is a typical range where high flotation recoveries can be achieved with conventional flotation chemistry and acceptable cell residence times. For pentlandite, the flotation recoveries decrease sharply when the particle size is below 10 µm and hydraulic entrainment is the dominant mechanism, giving recoveries proportional to water recovery and no Pn enrichment. (Jameson, Nguyen, & Ata, 2007)"

Jan 1, 2015

By Hong Zhong, Shuai Wang, Xin Ma

"In this paper, we report a simple and effective process for producing a surfactant mixture of O-isopropyl-N-ethyl thionocarbamate (IPETC) and 4-(tert-butyl)benzyl mercaptan (BBSH). The composite collector was synthesized via one-pot reaction of sodium isopropyl xanthate, 4-tert-butylbenzylchloride and ethylamine using tert-butyl alcohol as solvent. The whole process for the synthesis of composite collector involves neither foul smelling reagents or intermediates, nor any by-products requires special treatment for disposal, and thus can be scaled up to an industrial level. The flotation response of chalcopyrite and pyrite independently with IPETC and BBSH collectors and with their mixture (the mole ratio of IPETC and BBSH is 1:1) was assessed. The microflotation results showed that the collecting ability of BBSH was slightly stronger than that of IPETC and that IPETC was more selective collector than BBSH against pyrite, and that the composite collector displayed a stronger collecting ability toward chalcopyrite than IPETC, and superior selectivity for chalcopyrite against pyrite than BBSH. The batch flotation results showed that composite collector exhibited better performance than IPETC and BBSH. It was demonstrated that the mixing of IPETC and BBSH would give rise to a synergistic effect significantly enhancing overall flotation performance. In addition, the adsorption mechanism of BBSH on the surface of chalcopyrite was conducted by adsorption test and infrared spectrum measurement, and the results showed that the interaction of BBSH on the chalcopyrite surface was dominated by the chemical adsorption, and the formation of a strong S-M bond plays a key role in the adsorption of mercaptans on minerals surfaces. The developed flotation reagents with special preparation method is the author’s original design, patented (patent of the People’s Republic of China) and have no analogues in the world of mineral processing. (Application number 201810100107.1, ""Alkyl thioether alcohol compounds, methods for their preparation and applications thereof "", China).1. INTRODUCTION Froth flotation is an essential method widely used in the mineral processing industry to selectively separate valuable minerals from gangues[1]. Worldwide, more than 109 tons of materials are treated annually by this method with the majority being metal sulfides and oxides[2]. Nowadays, the judicious utilization of complex sulfides to meet the ever-growing demand of mineral resources gains more attention, due to the gradual depletion of deposits with high grade, making imperative the development of new high-efficiency collectors and mixtures of collectors to process complex minerals. In comparison to individual collectors, the use of mixtures has several notable benefits including lower dosage requirements, improved selectivity, rates and recovery and an increase in the recovery of coarse particles[3-9]. Moreover, in terms of cost and environmental issues, using collector mixtures can reduce the total amount of agents used, thus reducing the overall effect on the environment and economic costs without affecting the flotation performance. Therefore, the search for high-efficiency mixtures of collectors is still interesting and relevant."

Jan 1, 2018

Phelps Dodge has recently operated a commercial scale, super fine grinding circuit of copper concentrates for use in a medium-temperature pressure leaching process. Two 355 kW vertical stirred mills were installed in series, targeting a grind of 80% passing 7.5 µm and 98% passing 15 µm as outlined in Phelps Dodge's concentrate leaching patent portfolio. This paper details the operation and results of the test program at Bag dad, as well as some of the operating challenges encountered.

Jan 1, 2007

By Hindmarsh J. W, McCoy A. E R

Instantaneous outbursts of coal and gas have occurred at various times in several working districts of Metropolitan Colliery, N.S.W.They have occurred in headings only, under both hand and mechanised conditions, and with seam gas ranging from mainly methane to nearly pure carbon dioxide. A modification of inducer shotfiring using a shear cut was introduced in 1955, and in 1961 full face firing both to a machine cut shear and off the solid was introduced. The current series of outbursts -1961 to 1963 - has been induced under these systems with full control of the time of outburst, but without prediction, and with some disappointing production features.Various aspects of current conditions and practices at Metropolitan are considered singular, such as the coarse granulometry of outburst coal, the prevalence of floor heave, the absence of strong structures at outburst sites, the possibility of outburst at any stage in pillar formation up to the last few yards, the effect of rate of advance on outburst occurrence, and the mildness of many outbursts experienced.It is concluded that inducer shotfiring is a reliable control but it suffers by comparison with outburst-free conditions, and that control by preyention would be preferable.INTRODUCTIONThe phenomenon of instantaneous outbursts of coal and gas has been described in detail previously (Hargraves, 1958). Briefly, it is a combined gas and stress hazard of deep coal mining, usually occurring in virgin work and during active face advance, when coal and seam gas burst from the face into the workings.Instantaneous outbursts have occurred sporadically at Metropolitan Colliery, N.S.W., since 1895. Early outbursts were recorded as firedamp and recent outbursts are of blackdamp.Mining methods used have been conventional hand work, with progressive and relatively complete mechanisation over the past 25 years to substantially conventional...

Jan 1, 1964

By A. J. Paul Laprairie

"ADVANCE planning of mining methods, from the first development openings to stope layout and pillar recovery, has long been accepted as a normal method of operating a mine. Recently, mine managers have become increasingly aware that advance planning of cost and accounting controls can also be considered a normal method of operation. The use of such controls is wide-spread in manufacturing industries. In mining, the gold mines of South Africa have pioneered, with marked success, in this field and have been closely associated with most of the research and field work in accounting control. Canadian mine managers are also beginning to realize the advantages of using planned costs. The control procedures which subsequently have been introduced at various mines have come to be known by such names as ""Responsibility Costing"" or Budgetary Control"".Budgetary control, the term used in this paper, is based on the concept of decentralized authority with centralized control. ;The control is achieved by measuring results against yardsticks which are in the form of budgets or standards. Bud-gets are made for the future activities of each possible operation as planned by the department head, and attention is directed to variations from this plan. Furthermore, the control process charges to each operation only those costs which are incurred directly for that operation, and which can be controlled by the person in charge. Thus, budgetary control relates results to the officials responsible for those results. Expenditures are analyzed according to the organizational structure of the mine and the people who run it, and not according to production processes."

Jan 1, 1960

Removal of Arsenic in Fluorite Ore by Simultaneous Grinding-Leaching with NaHS Generally speaking, a high-grade fluorite ore is converted into hydrogen fluoride (HF), which is essential for the semiconductor manufacturing. With the continuous depletion of resources, novel technologies for processing low-grade fluorite ores are urgently needed, in order to lower the arsenic concentration to less than 100 mg/kg. In this study, a low-grade fluorite ore was upgraded by removing arsenic, which is difficult to remove by conventional method. The mechano-chemical leaching of fluorite ore (i.e. the sample was ground in presence of NaHS, using a beads mill) was carried out to investigate the removal of arsenic from the low-grade fluorite. Experimental results showed that the arsenic concentration was reduced to 73.2 mg/kg.

Sep 13, 2010

By William J. Campbell

Expansion measurements of platinum, added as an internal standard, are used for thermal calibration of X-ray cameras and diffractometers. Accuracy of the temperatures derived by this technique depends on the precision of expansion measurements and the reliability of reference expansion data. Temperature measurements to ± 1° C. require ?d or ?a to be determined within ± 0.001 percent. Selected expansion data are concluded to be reliable to 2° C., 5° C., and 25° C., over the temperature ranges 0° C. to 700° C., 700° C. to 1,000° C., and 1,000° C. to 1,700° C., respectively. Tabular expansion values from 25° C. to 1,700° C. in 2° C. intervals were calculated from the following equation; Expansion, percent = [8.91 + 1.28 x 10-3(t-25) + 0.04 x 10-6(t-25) ] [t-25.104 ] These tabular values facilitate future corrections of published temperatures as more reliable expansion-temperature data become available.

Jan 1, 1962

By Narendra Gupta, Gaurav Srivastava, Abhinav Sharma

From the days when plain detonators and safety fuse were used for initiation of commercial explosives, the commercial blasting and mining industries have made rapid strides. With the advent of electronic detonators in the late ‘90s, the face of commercial blasting was changed forever. The Mining Industry in India initially took a while to embrace Electronic Blasting Systems (EBS), however, more recently the industry has taken to EBS in a big way.

Jan 1, 2015

By X. Baolin, R. Guru, M. Peiravi, M. K. Mohanty, Z. Qian, R. Ma, Z. Yude, L. A. Ackah

"Acid mine drainage (AMD) is produced when exposed pyrite (FeS2) reacts with air and water to form an acidic solution that usually contain contaminant levels of heavy metal ions. AMD can potentially contaminate surface water and soil if not treated. The primary objective of this study was to investigate the removal of dissolved aluminum, iron and zinc metal ions from natural AMD using water treatment residue (WTR), a low-cost adsorbent. WTR sorbent generated as waste material in drinking water treatment plants (WTP) was characterized and utilized for the sorption of Al, Fe and Zn in AMD collected from an abandoned coal mine site in southern Illinois that generates approximately 20 gallons per minute of AMD. Sorption experiments were performed using batch technique to obtain rate and equilibrium data. The effects of various parameters on sorption capacities of WTR were observed by varying contact time, pH of the AMD and WTR dosage. The adsorption studies showed rapid uptake in general for the first 80 minutes for Fe and Zn but much earlier for Zn. Further increase in contact time did not show significant change in equilibrium concentration indicating the onset of adsorption equilibrium. After the batch treatment of the AMD water with the WTR, the removal of Al, Fe and Zn were 99.8%, 99.85% and 95.5% respectively. The pH of AMD increased from 2.64 to a near neutral point of 6.74 after treatment. The laboratory results show that the low-cost WTR, which is an abundantly available industrial waste, has proven potential to significantly reduce the high metal ions in acid mine drainage. INTRODUCTION Mining activities provide the basic raw materials needed for infrastructure development and economic growth world-wide. However, it is well recognized that mining activities have been the cause of a variety of environmental pollutions, including AMD. Water seeping out of an old abandoned mine is generally characterized by low-pH with heavy loads of dissolved sulfates (SO4) and metal species such as Fe, Al and Zn among other dissolved elements categorized as toxic metals. The Bureau of Land Management’s Abandoned Mine Lands (AML) program reported the existence of about 46,000 abandoned mines in the United States. Several environmental problems have been reported to be associated with these mined out sites such as heavy metal poisoning, loss of vegetation, air pollution etc. (Boulanger & Gorman, 2004)."

Jan 1, 2017

Some early production records of the early companies operating in the Deep River field are said to be still in existence, but the writer has been unable to find them. (Table 63.) [ ]

Jan 1, 1942

By H Zhou, T Honeyands, M Zhou

In iron ore sintering, packing the granules onto the sintering strand to form a porous bed with optimum permeability is a complex dynamic process. The packed bed voidage is the key factor determining the flame front speed and the final sinter productivity and quality. Previous studies have found that granules are soft quasi-particles with a typical structure of nuclei with an adhering fines layer. The deformation of the adhering layer greatly affects the bed voidage during packing, which is related to the strength of the adhering layer and the force exerted on the granules. In this study, tablets simulating the particle size distribution in the adhering layer of granules were made for four single ore blends. Both the tensile strength and shear strength properties of these tablets were investigated as a function of water content by the uniaxial compression test and direct shear test respectively. The results of compression tests show that the adhering layer becomes weaker and more compliant with the increase of moisture. The most porous ore has a more rigid adhering layer than the other three tested iron ores at any given moisture content. In direct shear tests, the internal friction angle of the adhering layer ranged from 31° to 37° and varied little with the moisture content or ore type. The cohesion constant is around 1 kPa and is quite small compared to the stress applied to the granules during packing. Combined with the results of granulation and packing experiments, the influence of the adhering fines layer deformation on the degree of voidage loss is specifically discussed.CITATION:Zhou, M, Zhou, H and Honeyands, T, 2017. Tensile strength and shear strength properties of the adhering layer of granules in iron ore sintering, in Proceedings Iron Ore 2017, pp 117–112 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By Jack Eloranta

This paper documents the relationship between material handling and processing coete compared to blasting cost. The old adage, "The cheapest crushing is done in the pit", appears accurate in this c!ase study. Comparison of the accumulated cost of: powder, selected wear materials and electricity; indicate a strong. inverse correlation with powder factor (lbe powder/long ton of rock). In this case, the increased powder cost is more than offset by electrical savings alone.

Jan 1, 1995

By Keith A. Heasley

At this point in time, approximately 800 M tonnes (880 M tons) of coal are mined each year in the United States. Forty percent of this coal or approximately 320 M tonnes (350 M tons) is taken from underground coal mines, and from this subtotal 16% or 50 M tonnes (55 M tons) is from longwall panels (1). If, for the sake of argument, an aver- age extraction thickness of 1.5 m (5 ft), an aver- age extraction ratio of 50 percent and an in situ density of 1360 kg/ms (85 lb/ft3) for this coal are assumed, then the 320 M tonnes (350 M tons) of underground coal translates to over 310 km2 (76,000 acres) that is undermined each year. Con- sidering that the total U.S. production of under- ground longwall coal to date is approximately 345 M tonnes (380 M tons), then a total of approximately 165 km2 (41,000 acres) (considering 100% extraction) has been directly undermined by longwall coal production in the United States. If the angle-of- draw is considered, the total area affected by longwall subsidence in the United States is probably twice the above value or 330 km2 (82,000 acres) . In the future, a number of other miscellaneous factors seem likely to multiply the number of potentially damaging situations that occur due to longwall coal mining. First, the overall production of coal in the United States is expected to gradually increase. This factor is further com- pounded by both the fact that the percentage of the overall production due to underground mining is bound to increase, since the vast majority of U.S. reserves (68%) are only recoverable by underground methods, and the fact that the percentage of the underground production of coal that is recovered by longwall mining is drastically increasing (1). Finally, as the nicest underground reserves are depleted, the remaining reserves will tend to be deeper, which increases the affected surface area, and under denser population concentrations, which increases the likelihood and severity of possible damages. Overall, considering the number of factor which are biased towards increasing the amount of undermined acreage, it appears that there must certainly be a corresponding increase in the number of possible damaging situations due to longwall-induced, ground subsidence.

Jan 1, 1986

The corrosion behaviour of a low carbon steel was investigated in synthetic seawaters with and without Sr2+. It was found that strontium substitutes for calcium in aragonite, rather than precipitating as discrete strontianite (SrCO3). The aragonite deposits that formed in the presence of Sr2+ were finer than those that formed in the absence of Sr2+. It is believed that an increase in the strontium content of aragonite induces a decrease in its solubility, which in turn results in a higher nucleation rate of the precipitates. Furthermore, the growth rate of aragonite is decreased by the presence of Sr2+in the solution. It is concluded that Sr2+is an essential ingredient in any artificial seawater when calcareous deposits are investigated on steel. Keywords: corrosion, seawater, calcareous deposits, strontium, aragonite.

Jan 1, 2007