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By G. L. Oldwright, Virgil Miller

"The data presented in this paper were collected at the smelter of the Consolidated Mining & Smelting Co. of Canada Limited, Trail (Tadanac), Brithish Columbia. The authors are greatly indicated to S.G. Blayrock, vice president and general manager; James Buchman, smelter superintendent; and the staff members mentioned in Report of Investigation 3243. The authors are exceedingly grateful to George Murray, assistant smelter superintendent, for his keen interest, suggestions, and help in carrying out this investigation.INTRODUCTIONThe methods of charign the blast furnaces at Toole and Kelloggs were noted in Report of Investigations 2957 and 3094 respectively. Report of Investigations 2957 cited (4 to 9 inclusive) Hofman's Metallurgy of Lead (p. 226) and the work of A.S. Dwight, Thompson and Sicka, the staff of the Engineering and Mining Journal, and L.D. Anderson, N.F. Collins, in The Metallurgy of Lead (Chas. Griffin, London, 1910) also gives (pp. 247 254) the principles that he believes govern the successful charging of the blast furnace."

Dec 1, 1934

By R. W. Heckel, R. A. Tanzilli

Treatment of the finite, diffusion-controlled, two-phase, moving-interface homogenization problem has been carried out by numerical methods for a wide range of input parameters. Solutions have been obtained for planar, cylindrical, and spherical diffusion geometries. The effects of parameters such as the interdiffusion coefficients (concentration-independent) of- both phases, the concentrations (time-independent) of each phase at the interlace, mean composition, initial size of the dissolving- phase, and initial composition of- the two phases are considered. The results are displayed to show both the position of the interjace and the degree of homogenization (expressed in terms of concentration at the matrix phase symmetry boundary) as a function of diffusion time. Typical exaw~ples to which the results may be applied are discussed. A limited number of exact, closed-form solutions to the multiphase, diffusion-controlled, moving-interface problem exists in the literature, e.g., Refs. 1 to 7. The exact, closed-form solutions generally consider the outermost phases to be infinite in extent and also assume an interfacial velocity function. It is through use of such boundary conditions that closed-form solutions are readily obtained. An extensive literature also exists on numerical solutions to the mathematically analogous solidification problem, e.g., Refs. 8 to 12. In addition, a numerical solution involving mass transfer with spherical interfaces and infinite boundaries has recently been carried out.13 A practically important class of diffusion problems exists, however, in which the boundaries of each phase away from the interface are finite. For example the finite boundary condition arises when one sets up a model for analyzing the homogenization behavior of two-component powder compacts in two-phase systems or for studying the solution behavior of precipitates. Although exact, closed-form solutions have as yet not been found to this class of problems, solutions are possible using numerical methods. The purpose of this paper is twofold: 1) to describe a numerical method for treating the two-phase, diffusion-controlled, moving-interface problem involving finite boundaries with planar, cylindrical, and spherical interfaces; 2) to present the results of a parametric study which identifies the role played by each variable appearing in the analytical model. R. A. TANZlLLI,Student MemberAIME,onleaveofabsence from the General Electric Co., Re-entry Systems Department and A. W. HECKEL, Member AIME, are Graduate Student in Materials Engineering, and Professor, Department of Metallurgical Engineering, respectively, Drexel Institute of Technology, Philadelphia, Pa. Manuscript submitted May 6. 1968. IMD MATHEMATICAL MODEL The three geometries analyzed are shown in Fig. 1. For each configuration a symmetry element is shown, across whose boundaries the mass transfer is zero. Mean composition, C, and the characteristic solute-rich phase half-thickness (or radius), 1/2, are the independent variables while the characteristic symmetry element half-thickness, L/2 (measured from solute-rich phase center to the matrix phase plane of zero mass transfer), is a dependent variable. The symmetry element for a planar interface accurately represents a real diffusion situation involving the stacking of symmetry elements of constant size. Because cylindrical and spherical symmetry elements of constant size cannot be stacked to fill space, the meaning of the dimension, L/2, for these situations may be considered in terms of the following approximations: and where NA is the number of parallel cylindrical elements per unit area on a surface normal to the cylinder axes and Nv is the number of spherical elements per unit volume. The model consists of a solute-rich phase matrix phase composite of limited mutual solubility. The concentrations at the interface are assumed constant with time; no assumption of local equilibrium at the interface is necessary except for the case where the

Jan 1, 1969

By Georges Millot

USUALLY the search for clays is left to chance in unexplored areas. A local working by the inhabitants or an outcrop is often the only guide. If the conditions of genesis of clays were always known, a set of general rules could be drawn up that would apply to this search. For example, a certain type of clay might be found wherever the sediment indicated a favorable environment. This paper sums up the considerable amount of knowledge that has been accumulated about the genesis of sedimentary days and offers some rules to be observed in prospecting for new clays. ANALYTICAL STUDY OF SEDIMENTARY CLAYS Clays may be found in many formations, both recent and ancient. All the intermediums exist between the deep-sea deposit and the mud deposited by a stream. In order to find out whether the nature of clay deposits depends on the environments in which they were formed, the samples used in the investigation described herein were very carefully chosen from: (1) ancient sedimentary series (a few from recent ones), (2) zones where conditions of genesis are typical. Ancient Formations Ancient formations were chosen because they are less difficult to sample than the bottom sediments of present-day lakes and seas. Moreover, a geo- logical section makes it possible to define the conditions of genesis of a deposit based on its facies, fossils, stratigraphic relations, and paleography. A present-day deposit is defined only by its aspect at the moment. Its previous history may have caused mixtures, alterations, and changes of environment, which escape detection. Typical Conditions of Genesis Samples from ancient deposits were taken from zones where typical conditions of genesis prevailed. Only clays from marine, lagoonal, and lacustrine environs are concerned in this study because the nature of the original en- vironments could be affirmed. In this way an inventory of the nature of sedimentary clays has been made for rocks formed in typical and individual environments; therefore the extent of the results that may be drawn from such a study will need discussion.

Jan 1, 1952

By G. K. Herzog

THE problems relating to the construction and use o{ mining equipment are basically the same as those pertaining to equipment in other industries. It is true that much mining equipment is subjected to an unusually severe combination of shock, high stresses, abrasive wear, and corrosive ? conditions, but in other industries, also, equipment must operate under similar adverse conditions, so that their experiences may readily be applied to the problems of the mining industry. Steel and iron are for obvious reasons the most suitable materials for the construction of the greater part of the equipment used in the mining industry. For a large percentage of uses, the ordinary plain carbon-steels and ordinary or unalloyed cast-iron are, and probably will continue to be for a long rime, entirely satisfactory materials. There are, however, many. conditions which cannot be satisfactorily taken care of by these materials, and alloy steels and irons must be used where the greatest possible economy is desired. In general, alloy steels and irons are used where it is necessary or economically desirable to use materials possessing properties superior to plain carbon-steel or ordinary cast-irons, such as: (a) better strength (b) better wear resistance (c) better corrosion resistance (d) better resistance to high temperatures (e) better resistance to low temperatures or combinations of two or more of these advantages. There are also conditions where materials having other special properties are required, such as, for example, certain magnetic or electrical properties for electrical machinery; but in the great majority of cases, one or more of the five advantages listed are the most desired.

Jan 1, 1938

By L O. Filippov, C H. Veloso de Melo, A Correa De Araujo

Froth flotation of iron ores is one of the most widely used methods to upgrade iron ore into high-grade concentrates. In recent years, reverse cationic flotation of iron ores has been specifically the subject of several studies. Since quartz is the most common gangue mineral in iron ores, understanding the behaviour of this mineral was the main target of the majority of such studies. However, with the depletion of mineral deposits considered rich and easy to process, it has become more common to find iron ores with complex gangue minerals, which are composed not only of quartz but by a variety of silicates. The mineralogical composition of the ore is an important factor for determining reagents and mineral processing parameters. The mineralogical suite of an ore also presents a paramount role for operational optimisation of any given flotation process. Some studies were performed with different types of amphiboles and other Fe-bearing silicates, for example, but the influence of the mineralogical nature of these silicates in reverse cationic flotation has not been fully explored and will be discussed here. Changes in the traditionally used reagent scheme for reverse cationic flotation, generally including alkaline pH values, polysaccharides as depressant (mainly starches) and primary ether amines and diamines, are expected when dealing with iron ores with complex silicate gangue composition.CITATION:Veloso de Melo, C H, Correa de Araujo, A and Filippov, L O, 2017. Reverse cationic flotation of iron ores with complex silicate gangue minerals, in Proceedings Iron Ore 2017, pp 241–244 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By Laurance Reid

HIGH compression ratios, resulting from high injection pressures and relatively low recovery process pressures, constitute a major problem, which has confronted those engaged in gas recycling for condensate production since the beginning of that practice. Despite the numerous process developments and improvements, no entirely satisfactory solution for this prob-lem has been presented to date. Often, where the residue gas from the recovery process must be recompressed for subsurface injection, there is a substantial difference between the required injection pressure and the plant-operating pressure required to produce maximum recovery of condensate. These limitations result in high compression ratios, which, in turn, neces-sitate excessive compressor investment and operating cost. As an alternative, the operating pressure may be increased in order to lessen the compressor requirements but such a saving often is purchased at the expense of decreased condensate recovery, caused by operation at the higher pressure. Regardless of the choice, the net result is a diminished return on the capital invested in the project. The goal of future development in this field must be the complete recovery of all valuable hydrocarbon components in the reservoir fluid at pressures that, regarded as compressor suction pressure, will require minimum compressor horsepower to inject the residue gas into the formation. A com-pression ratio of 1.5 has been established as an optimum for modern compressor equipment." Therefore, in order to con-form to this optimum condition, a 3000-lb. injection pressure would require that the condensate recovery process be operated at 2000 lb. per sq. inch.

Jan 1, 1940

By Erwin A. Morlan

Present methods of boring large hole mine openings are briefly reviewed. Factors that influence the design and choice of down-the-hole equipment for rotary drilling large holes are discussed. With formation drillability taken as a starting point, graphs and charts are given as an aid in the selection of bit load, circulation system, flow rate, drill stem, cutter design and rotary speed.

Jan 1, 1961

By Lorie M. Dilley

Alaska Village Electric Cooperative (AVEC), an electric utility cooperative providing power to 51 Alaska villages, has made a concerted effort to install wind turbines in the villages they serve in an effort to mitigate the growing costs of electrical power generation. The subsurface soils in several of these villages consist of sands and silts with ground temperatures of between 30°F and 32°F. The presence of warm, degrading permafrost in three of the villages has required innovative foundation designs, including the use of helical piers and piles to support steel and concrete wind turbine foundations. The design of the deep foundations had to account for the effects of degrading permafrost likely resulting from observed climate change patterns. Uplift forces imposed on the foundations were approximately 100 kips per pile. Uplift pile load testing was conducted on the installed piers and piles in order to determine the actual working load that each pier or pile could sustain. In addition, pile driving analyzer testing was conducted on several piles installed in the permafrost and compared to pile load tests. Results indicated that the installed piers and piles achieved the necessary capacity with sufficient factors of safety. Thermosyphons were installed near the foundations in order to limit the effects of climate change on the permafrost. The two to four wind turbines in each of the three villages are currently operational. Refinement of the design based on the pile testing from the first village to the third has decreased the cost of the tower foundations and improved our understanding of designing for warm, degrading permafrost.

Jan 1, 2010

By G. Guiglionda, A. Deschamps, F. De Geuser, M. Langille, B. J. Diak

"Increased demand for light-weighting in passenger vehicles has created a need for strong, light, ductile materials to be used in body-in-white applications. The AA6xxx-series of aluminum alloys are suitable candidates meeting most requirements but can fall short of the formability demands of designers, necessitating an understanding of what controls the formability in this alloy series. This work examines the effect of copper alloying in AA6xxx on the pre-ageing and natural ageing responses of the microstructure and mechanical properties. The changes in microstructure observed by differential scanning calorimetry and hardness testing are related to the work-hardening and strain-rate sensitivity parameters for these alloys measured by tensile testing. An observed asymmetry in the measured strain-rate sensitivity associated with increasing versus decreasing strain rate changes suggests that a different mechanism operates for the two conditions. It is postulated how this asymmetry in strain-rate sensitivity will impact the necking and ductility behaviour of these alloys.INTRODUCTION The widespread use of AA6xxx series alloys in the form of sheets has provided the need for a more thorough understanding of the complex interactions between composition, processing, resulting microstructure and ultimately, the mechanical properties of the alloys. Conventional industrial practices involve the production of rolled AA6xxx sheet (typically 1 mm thick) to be used for body-in-white (BIW) applications for auto body panels (Hirsch, 2004, 2014). The final metallurgical step prior to the shipment of these panels to manufacturers involves a solution heat treatment (SHT) reverting the ageing products of the alloys into solid solution and the product is then shipped to the customer. During this shipping time and while sheets are waiting to be used, the natural ageing (NA) process occurs whereby the strength of the alloys increases resulting in reduced formability. This can result in a product that is unable to meet the formability demands of the automotive manufacturer. As a result, industry has moved towards performing pre-ageing (PA) treatments to prolong the “shelf-life” of the material prior to it having insufficient formability. Once formed into BIW panels, the parts are then painted and subsequently undergo the paint curing heat treatment which consists of a short period of time at medium temperature, typically 20 minutes at 170–190°C. This short artificial ageing (AA) treatment, known as the paint bake (PB), provides additional strength and improved dent resistance for the material, but reduced formability. The PB result is strongly dependent on the PA treatment performed prior to the forming operation. Furthermore, the addition of copper (Cu) to a base Al-Mg-Si composition is known to increase the alloy’s strength. The goal of this work is to study the effect of Cu on strength, strain hardening, and strain-rate sensitivity (SRS) of these alloys, to understand the strength-formability compromise, for two separate heat treatment schedules; one including and one excluding the PA treatment, both followed by NA."

Jan 1, 2018

By V. R. Garfias R. V. Whetsel

Production of crude petroleum in Mexico during 1935 totaled approximately 40,082,000 bbl., an increase of 1,925,000 bbl. over the previous year. Successful development continued in the Poza Rica field during the year, increasing production in that area from 3,708,000 bbl. in 1934 to 9,542,000 in 1935. The output of the South fields (Golden Lane) area decreased by 3,000,000 bbl. during the year, and the heavy-oil district of the Northern fields by 1,500,000 bbl. Production in the Tehuantepec fields showed a slight gain. Production of natural gasoline increased from 430,000 to 600,000 bbl. in 1935. Crude run to stills in local refineries is estimated at 30,000,000 bbl., some 4,000,000 bbl. more than in the previous year. Exports of crude and refined products were approximately 22,000,000 bbl., or 2,000,000 bbl. less than in 1934. Exclusive of ships bunkers, domestic consumption increased about 900,000 bbl. during the year, reaching an estimated total of 14,500,000 barrels. Only 74 wells were completed, as compared to 148 in 1934 and 91 in 1933. In proven areas 58 completions resulted in 33 producers and 25 failures. In northeastern Mexico, near the United States border, six wildcat wells were completed, all of which gave little or no encouraging results, except Rancheria No. 3, near Camargo, which is a fair-sized gas well. Four wildcats were drilled just northeast of the Northern fields (heavy-oil district), all of which were failures. A deep test was completed a short distance southeast of the Golden Lane (South fields) in Palo Blanco, which encountered small production not sufficient to exploit. On the Isthmus of Tehuantepec a wildcat well was completed for an estimated initial production of 2000 bbl. daily, a short distance south of the old Jalapa field, which was perhaps the most important new development of the year. Four other wildcats drilled in the Isthmus district resulted in failures. Fields Northern Fields (Heavy-oil District).—In the Northern fields, 18 producing wells and 20 failures were completed, as compared to 34 producers and 71 failures in 1934. The initial production of the new

Jan 1, 1936

By V. R. Garfias R. V. Whetsel

Production of crude petroleum in Mexico during 1935 totaled approximately 40,082,000 bbl., an increase of 1,925,000 bbl. over the previous year. Successful development continued in the Poza Rica field during the year, increasing production in that area from 3,708,000 bbl. in 1934 to 9,542,000 in 1935. The output of the South fields (Golden Lane) area decreased by 3,000,000 bbl. during the year, and the heavy-oil district of the Northern fields by 1,500,000 bbl. Production in the Tehuantepec fields showed a slight gain. Production of natural gasoline increased from 430,000 to 600,000 bbl. in 1935. Crude run to stills in local refineries is estimated at 30,000,000 bbl., some 4,000,000 bbl. more than in the previous year. Exports of crude and refined products were approximately 22,000,000 bbl., or 2,000,000 bbl. less than in 1934. Exclusive of ships bunkers, domestic consumption increased about 900,000 bbl. during the year, reaching an estimated total of 14,500,000 barrels. Only 74 wells were completed, as compared to 148 in 1934 and 91 in 1933. In proven areas 58 completions resulted in 33 producers and 25 failures. In northeastern Mexico, near the United States border, six wildcat wells were completed, all of which gave little or no encouraging results, except Rancheria No. 3, near Camargo, which is a fair-sized gas well. Four wildcats were drilled just northeast of the Northern fields (heavy-oil district), all of which were failures. A deep test was completed a short distance southeast of the Golden Lane (South fields) in Palo Blanco, which encountered small production not sufficient to exploit. On the Isthmus of Tehuantepec a wildcat well was completed for an estimated initial production of 2000 bbl. daily, a short distance south of the old Jalapa field, which was perhaps the most important new development of the year. Four other wildcats drilled in the Isthmus district resulted in failures. Fields Northern Fields (Heavy-oil District).—In the Northern fields, 18 producing wells and 20 failures were completed, as compared to 34 producers and 71 failures in 1934. The initial production of the new

Jan 1, 1936

By Ajay K. Jha1

Drilling and Blasting are two important unit operations in the production cycle of a mine and a strong link exists between these two and other unit operations/subsystems like loading, transportation, and crushing. Under the present concept of ? Mine to Mill?, it is important to optimize the drilling and blasting operations by applying scientific approach to drilling and blasting using sophisticated instruments and new technologies, which depends heavily on Information technology (IT) to meet this imperative. Development of innovative models and software has lead to blast optimization process. Till date, the blast results are evaluated in terms of available empirical approaches like powder factor, which are too simple to exclude some key parameters or lack in providing reliability because of non-availability of user friendly IT enabled techniques. Although with the help of developed approaches, formulation of user-friendly software to assist the site engineers in effective post blast assessment has started but there is a dearth of holistic approach to design an optimum blast considering the techno-economic feasibility of the subsystems and the geo-mining conditions to achieve blast optimization. The science of IT enablement in drilling and blasting is capable to build innovative models for achieving blast performances which will be doped with productivity, economy and safety with due regard to environment. The present paper discusses the use of existing IT enablement in various mines of India citing the Indian scenario and the future requirements for achieving the techno-economics in overall mining operations.

Sep 1, 2012

By Jason J. Ballentine

This paper presents a case study of how an asset strategy and zero based budget was developed for an existing crushing plant that had been purchased from the contract service provider by an Australian Iron Ore miner. The goal was to directly align the strategies and budget to the business goals. This however was not a simple task due to poor historical records and a general lack of information. These challenges were overcome and the benefits of a documented maintenance strategy, a justifiable zero based budget and employee engagement were realized.

May 1, 2007

By Larry Sevenker

On the basis of favorable salt characteristics, primarily compressive strength and impermeability, solution-mined cavities can provide structurally stable isolation chambers for waste. Solution mining techniques are established for storage of hydrocarbons. The proposition of waste isolation in engineered salt cavities is similar to this practice relative to characterization, certification and safeguards. What materials are isolated and how operations are conducted are principle differences. Compatibility of wastes with other wastes must be considered, but hazards can be precluded by avoiding certain mixtures. Waste material characteristics and cavity considerations are discussed.

Jan 1, 1981

By A. Ploszajski

This item examines the history and uses of tungsten, from discovery to superalloys via the lightbulb and electron beam instruments.

Apr 1, 2015

By R. F. Mehl, B. Lustman

THE formation of intermediate phase layers in cementation processes has been subjected to extensive qualitative investigation though to relatively little quantitative study; this work has recently been fully summarized by F. N. Rhines.1 It is necessary here only to enumerate the general conclusions drawn concerning the kinetic laws governing the growth of intermediate layers and to state what is known concerning the structural changes accompanying the generation of phase layers. I. When the intermediate phase is protective in type-i.e., when its density is less than that of the base metal, so that a continuous coating is formed and maintained the isothermal growth of the phase follows a simple parabolic equation: X2 = kt [I] where X is the thickness of the alloy layer, k the reaction rate constant, and t the time. The applicability of this equation to diffusion processes is tested by plotting the square of the thickness versus time, or by plotting the thickness versus the square root of time; the resultant achievement of a straight line in such. a plot has been con¬sidered sufficient proof of the validity of this equation. Exceptions have been found where liquid phases are involved in the reaction, where the diffusion layer is cracked,2 and where thin semimetallic oxide and sulphide coatings are formed on metals.3 In the first two cases the thickness increases linearly with time, and in the latter it is a logarithmic function of time. 2. The rate of thickening varies with temperature according to the Arrhenius equation k = Ae-Q/RT [2] where k is the parabolic rate constant of Eq. I, or some other rate-descriptive function, A is the action constant, e the base of natural logarithms, Q the heat of activation, R the gas constant, and T absolute temperature. This equation has been found to be generally valid except when transformations occur during reaction in either the base metal or in the reaction layer; in such instances Eq. 2 is still applicable with different values for the constants A and Q above and below the transformation temperature. 3. All phases that are stable at the temperature at which diffusion occurs will appear in the interdiffusion of two components. In some cases certain of the phases may be too thin to be observed and identified easily. Nonequilibrium phases have never been noted in thick reaction layers; i.e., layers of a thickness that may be discerned microscopically. The relative, thickness of each phase in a diffusion layer is proportional to the concentration gradient and to the rate of diffusion in that phase .4 The reaction layers tend to have a

Jan 1, 1942

By A. C. A. Howe, J. C. Rowntree

"The Bernie Lake pegmatite near Lac Du Bonnet in southern Manitoba is a complexly zoned pegmatite containing several lithium-bearing units in addition to the western world's largest known reserve of cesium. The pegmatite forms a flat-lying ellipsoidal body within an east-west-trending Precambrian amphibolite. The pegmatite enclosed by this vertically schistose amphibolite lies near the eastern tip of a granitic intrusive. The relationship of this intrusive to the pegmatite is obscured by Bernie lake. To date, the pegmatite body has been delineated aver an area of approximately 80 acres; it attains a maximum thickness of 280 feet. Several distinct zones, including three assemblages of economic importance, comprise the pegmatite itself. The combined spodumene and lepidolite assemblages provide a recoverable defined lithium ore reserve of almost 5 million tons averaging more than 2 per cent lithium oxide. The recoverable cesium ore of the pollucite assemblage provides 300,000 tons averaging more than 20 per cent cesium oxide; this represents more than half of the western world's pollucite reserve. The Bernie Lake pegmatite deposit, owned by Chemalloy Minerals Limited, is well located with respect to the growing United States markets, and its reserves of cesium are large enough to enable it, under favourable economic circumstances, to become the major producer of this metal in North America."

Jan 1, 1967

By Jerry Grott

Southwest Salt Company is solution mining the Luke Salt Body of probable late Miocene age. The discovery hole, from which the first core was recovered, was drilled in 1968. The deposit was encountered at a depth of 880 feet, and the bit was still in salt at the bottom-hole depth of 4,500 feet. The solar ponds, developed on land formerly dedicated to agriculture, have an annual capacity of about 90,000 tons. Because land values are very high, mining rates and procedures are governed by the need for near-saturated brine to minimize land requirements. Because of the frequency of dust storms, the salt operation uses a unique wet-harvesting method. Most inventory is kept in the ponds under brine and harvested only a few days before shipment. Studies of the nature of crystal growth and the distribution of windblown and brine impurities led to the development of procedures for processing salt of high chemical purity and low insolubles content. Chemical purity exceeds that of most salt produced in fuel-fired evaporators. Salt is shipped from Phoenix as tar east as west Texas and as far west as central California. Occasional shipments have been made to Hawaii and Alaska.

Jan 1, 1987

By P. A. Bepswa

A numerical study done to test the efficacy of heuristics developed for the design of measurement networks for high precision metallurgical accounting is presented in this paper. The heuristics considered were designed to maximise variance reduction of terminal stream measurements through data reconciliation for observable linear flow systems. A complex metallurgical process flow sheet from the mineral sands industry was used as a case study. Monte Carlo type simulations coupled with a non-linear programming based steady state data reconciliation algorithm were used as tools to investigate the heuristics. The results obtained suggested a close correlation between magnitudes of measured variances and the respective levels of variance reduction obtained through data reconciliation for both internal and terminal streams. It was observed that variance reduction through data reconciliation was maximised for terminal stream measurements in networks characterised by high precision measurement of internal streams and/or in flow sheets characterised by high ?stream to node ratios?. Terminal streams attached to highly interconnected parent nodes were observed to experience higher reductions in variance compared to terminal streams attached to less interconnected parent nodes. The results generally highlight the additional benefits of highly interconnected flow sheets and high precision internal stream measurement regimes on the maximisation of variance reduction of terminal stream measurements through data reconciliation. These findings are significant to metallurgical accounting and to process accounting applications in general in that they provide a conceptual basis for design decision making regarding the construction of measurement networks aimed at maximising variance reduction of targeted streams through data reconciliation.

Jan 1, 2014

By Isadora Dias Perez, Denise C. Romano Espinosa, Flávia P. Cianga Silvas, Jorge A. Soares Tenório, Mónica M. Jiménez Correa

In view of the rising generation of wastewater containing metals, sustainable and clean techniques to recover them are being researched. This study investigated the adsorption of aluminum, cobalt, chromium, copper, iron (III), magnesium, manganese, nickel and zinc presents in a synthetic ef fluent by chelating ion exchange resin Dowex XUS43605. The resin was tested in columns experiments and was analyzed the flow rate (0.45, 0.66 and 1.11 BV/h), at pH 1.5 and 20 °C. After loading the column, the elution experiments occurred with 1 M of H2SO4 and 4 M of NH4O. The concentration of the metals in solution was obtained by X-ray fluorescence spectrometry energy dispersive (EDX). The results showed that the breakthrough experimental curves demonstrated that the main metals (aluminum, cobalt, manganese and zinc) were immediately broken through just after the initiation of the feeding, while the breakthrough of copper began later. Therefore, the study showed that the chelating resin could be used to treat contaminated effluents with metals.

Mar 1, 2017