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By L. S. Darken

IT has long been recognized that the driving force in an isothermal diffusion process may be regarded as the negative gradient of the chemical potential (partial molal free energy) of the diffusing substance. This equivalence is exactly analogous to the fact that a mechanical force is the negative gradient of the potential energy. Nernst1 in 1888 expressed these driving forces in terms of osmotic pressure, which is directly related to the chemical potential and free energy. The relationship between the diffusivity, mobility and activity coefficient of electrolytes in aqueous solution has been developed in great detail by Onsager and Fuoss2 with results which have recently been confirmed experimentally by Harped and Nuttall.3 This interpretation of the driving force in isothermal diffusion has been discussed earlier by the author 4.6 who pointed out4 that "for a system of more than two components it is no longer necessarily true that a given element tends to diffuse toward a region of lower concentration even within a single phase region"; departure from the behavior of an ideal solution may be so great that the concentration gradient and the chemical potential gradient, or activity gradient, may be of different sign, thus giving rise to "up hill" diffusion. Since, in the discussion of that paper,4 some skepticism as to the validity of this conclusion was expressed, it seemed desirable to adduce experimental evidence to support it. Evidence of such diffusion in nonmetallic systems has already been reported. For example, it was observed by Hartley11 in a series of experiments in which sodium chloride diffused from a saturated solution in about 5 pct acetone in water into a solution virtually free of salt but with essentially the same acetone concentration. Specifically, a wine glass containing crystalline salt and saturated solution was totally immersed in a large glass cylinder containing the acetone-water solution without salt; the difference in specific gravity was such as to prevent convection. Diffusion of salt was accompanied by a marked depletion 0f acetone in the wine glass; after 3 days the acetone concentration decreased from 5.37 pct at the top of the glass, where the salt concentration was low (0.93 pct), to 1.84 pct at the bottom where the salt concentration was high (21.64 pct). This "uphill" diffusion was found to be such that the partial pressure (activity) of acetone was essentially equalized throughout the system when a steady state gradient of sodium chloride was maintained. In order to demonstrate the existence of such diffusion in metals, a series of four weld-diffusion experiments was made. In these measurements pairs of steel of virtually the same carbon content, but differing markedly in alloy content, were welded at the end and held at 1050°C for about two weeks. Subsequent analysis showed that carbon had diffused so as to produce an inequality

Jan 1, 1948

By T. Crivits

"Freeze lining technologies are used industrially to protect the integrity of furnace walls in pyrometallurgical reactors. This is achieved by solidifying a protective layer of slag on the inner furnace wall. In the current study, laboratory experiments have been undertaken to produce freeze linings in ‘Cu2232 O’-‘FeO’-MgO-SiO slags under controlled conditions using an air-cooled probe technique. Whilst most thermal models of freeze linings have assumed the freeze lining-bath interface to be at the liquidus temperature of the bulk bath and to be planar in geometry, the current research has demonstrated that this is not the case. Experiments undertaken using this high-temperature slag system have shown the interface at steady state conditions to be at subliquidus temperatures. The solid phases present at the interface do not include the primary phase and the interface is non-planar. The study indicates the need for improved understanding of the fundamentals of freeze lining formation, and of the influence of system properties and process parameters"

Jan 1, 2015

By Robert C. Ellman

Lignite and subbituminous coals are utilized essentially as mined without beneficiation. Most of the present production is used to generate electric power and the major problem in this use is ash deposition on fireside surfaces. The preparation at existing mines involves principally crushing and screening operations. Blending of production from different locations within the mine is practiced in several mines to control ash composition. Drying and oil treatment for freezeproofing, of lignite are used to a limited extent during winter. Future processing may involve both washing and drying operations to alter ash composition by ion exchange and upgrade the low-rank fuels to higher heating values. Research has been initiated to determine the feasibility of such processing.

Jan 1, 1969

By A. Noble

"Froth flotation circuits are widely used throughout the mineral processing industry for the concentration of fine particles. It had been estimated that nearly 2 Gt (2.2 billion st) of ores are treated globally each year using this versatile separation process (Fuerstenau, 1999). Due to the high feed tonnage, a large economic incentive exists for flotation plant operators to optimize the performance of this critical processing circuit. Prior to the 1950s, the optimization of flotation circuits primarily involved the manual adjustment of operating variables based on visual observation and sporadic sampling (Lynch, Harbort and Nelson, 2010). During the next several decades, however, the advent of improved on-line instrumentation coupled with the rapid development of high-speed microprocessors allowed the industry to develop more advanced control systems that could quickly adjust operational parameters in response to disturbances in ore characteristics and plant flows. These early online controls typically involved feedback loops designed to stabilize cell performance through the automatic manipulation of process variables such as pulp levels, gas rates and chemical dosages. The set-points for these controllers were often set by plant operators based on one or more operator objectives, such as maximizing throughput, recovery or grade. More recently, these regulatory controllers have been interfaced with high-level data display and management systems that provide operators with the ability to better optimize flotation plant performance based on mathematical models and rule-based algorithms (Greet, 2010).While tremendous strides have been made during the past several decades, even the most modern flotation plants are still faced with the long-standing question: “What are we trying to optimize?” From an operator perspective, some common responses include “Maximize tonnage of saleable concentrate” or “Maximize metals recovery at a customer-specified market grade.” These replies may or may not reflect those of management, who often focus on economic goals such as “Maximize profits for each operational unit” or “Maximize rate of return for all corporate assets.” Unfortunately, these high-level objective statements do not always translate well into practice due to the disconnect between plant operating protocols and product value. Attempts have been made by industry to overcome this issue using various types of optimization routines such as linear programming or other optimization engines. While this approach does have some merit, these blind routines require considerable input data and interpretational expertise and provide little or no fundamental insight that can be used to drive improvements in concentrator performance."

Feb 1, 2017

By Richard P. Reiff

"The Facility for Accelerated Service Testing (FAST) program has been involved in numerous rail wear tests since its inception in 1976. A number of specialized tools have been developed to aid in assessing specific performance parameters including gauge face wear, head height loss, metal flow, head area loss, hardness, and welded rail end batter. The layout of a test site, including position in curve, number of measurements per rail, and train operation must be properly controlled/monitored to provide valid wear comparisons.This paper will provide an overview of the above-mentioned tools and techniques. In addition, a summary of recent test results from FAST, including information on head hardened rail investigations, will be provided. A set of guidelines for establishing a revenue service field test site will also be provided to aid users in performing evaluations of their own.IntroductionBackground of Rail Wear Testing at FASTThe Facility for Accelerated Service Testing (FAST) located at the Transportation Test Center, (TIC), Pueblo, Colorado has been involved with testing of rail since program initiation in 1976. A huge data base of rail wear information has been gathered from FAST operations under a variety of rail metallurgies, lubrication conditions, and measurement techniques. Attempts at obtaining meaningful rail wear information from early (1976-1978) FAST rail wear data was hampered by two main factors: (I) measurement techniques were insufficiently accurate for the amounts of wear being experienced, and (2) the lubrication was not sufficiently controlled to obtain uniform conditions for a sufficient measurement time period.Subsequent test periods were operated with improved measurement techniques and controls that ensured statistically valid data. The policies and conditions that permit accurate rail wear assessment will be reviewed and outlined in this paper, along with some specific TIC and field examples that will allow the user to improve the accuracy of a field rail test on their own operating property."

Jan 1, 1988

By Stephen E. Kesler

Carbonaceous sedimentary rocks are abundant in the upper part of the caldera or maar that hosts the Puebio Viejo Au-Ag district, and much of the Moore sulfide zone is in these rocks. These rocks are thinly layered and contain scattered plant remains and variable amounts of volcaniclastic debris and pyrite. The carbonaceous matter in the sediments yields no X-ray diffraction pattern and is not graphite. It has C/N ratios of 4 to 10, and &13C values of about -25 per mil, which indicate that it is dominantly of marine organic origin and partly degraded. Atomic S/C ratios in the unmineralized part of the carbonaceous rocks have a median of about 1.2, much higher than most similar unmineralized rocks, reflecting not only the abundance of pyrite in the sediments, but also the fact that the organic material contains several percent sulfur. Extracts from the organic material indicate that it is thermally mature and that it reacted with the hydrothermal solutions. Atomic S/C ratios in the mineralized carbonaceous rocks are generally higher than those in unmineralized carbonaceous rocks, ranging to values of 5 and more. These differences indicate that significant amounts of carbon were consumed by the reduction of sulfate and metal chloride complexes in the mineralizing fluids as they passed through the carbonaceous sediments. Direct reaction between organic material and ferrous chloride-bearing, acid-sulfate hydrothermal solutions probably caused continuous deposition of pyrite during this period. Intermittent deposition of gold from chloride complexes by the same reaction was probably facilitated by boiling or C02 effervescence.

Jan 1, 2013

By Marco D. Boscardin, Kenneth A. Pidgeon, Adriane G. Boscardin

"Hollow bar tiebacks can offer an economical alternative to conventional solid bar and strand tieback systems for use in temporary excavation support construction. However, the limitations associated with the installation of hollow bar tiebacks require special attention during design, construction and load testing to verify conformance with conventional performance and proof testing criteria (PTI, 2014). In particular, providing a reliable free length is complicated by the 10-foot (3-m) -long, segmental, couplingto- coupling nature of the free length sheath in the hollow bar system, and addressing the fully grouted annulus of the bond zone and the free length zone at the end of installation are key concerns. In addition, it is often more convenient to install a greater number of more closely spaced, lower capacity tiebacks with the hollow bar system, compared to conventional tiebacks. This paper examines how these issues were addressed for a project involving a 60-foot (18-m) -deep sheet pile excavation through a highway embankment and a 70-foot-deep sheet pile and soldier pile and lagging excavation through a railroad embankment, both supported by a hybrid system of hollow bar tiebacks and hollow bar soil nails. The project involved approximately 300 tiebacks and 400 soil nails.INTRODUCTIONEngineers Construction, Inc. (ECI), constructed a pair of 32-foot (9.8-m) -wide (clear span), 30-foot (9- m) -high (21 feet (6.4 m) above the stream bed), cast-in-place concrete arch culverts as a design-build project for the Vermont Agency of Transportation (VTrans) in East Ryegate, Vermont. The new culverts replaced an existing 8-foot (2.4-m) -wide by 6-foot (1.8-m) -high cast-in-place concrete culvert under US Route 5 (RTE5), and twin, 2-foot (0.6-m) -wide by 5-foot (1.5-m) -high granite block culverts under the Washington County Railroad (WACR) alignment. The culverts convey Manchester Brook eastward, through the embankments for RTE5 and the WACR, on its way to the Connecticut River. The Connecticut River is located approximately 100 feet (30 m) east of the WACR embankment. The existing structures were undersized and backed up water behind the embankments during high flow events; and often trapped debris that flowed down the brook and became clogged. The existing culverts also had cracks and openings that have resulted in the loss of ground into the culverts and the formation of sinkholes in the sides of the embankments. Moreover, the reason for the large cross-sectional dimensions of the culverts was to make them of sufficient size and openness to encourage the migration of fish up the stream to spawn. The culvert through the RTE5 embankment is 144 feet (44 m) long, and the culvert through the WACR embankment is 128 feet (39 m) long, with a 57-foot (17.4-m) -long by 32–foot (9.8- m) -wide by 17-foot (5.2-m) -deep 10 feet (3 m) deep above the stream bed) open channel section between the two culverts. A plan view of the culvert alignment is presented in Figure 1."

Jan 1, 2016

By R. Van A. Norris

The following tests were made, during 1889, for the Susquehanna Coal Company, to determine the relative efficiency of several styles of mine-car wheels in use at their collieries at Nanticoke, Pa. The wheels experimented upon may be divided into two classes: The "old style" (Figs. 1 and 2), which are oiled at every trip; and the "new style" (Figs. 3, 4, and 5), which require oiling about once in two to four months. Fig. 1 shows a section of a plain cast wheel, with patent annular oil-chamber. This is held in position on the axle by a square, split cotter-pin. Fig. 2 is a similar wheel, with a patent cast bushing, which is readily replaced when worn. The lubrication is effected by a simple oil-hole, but the oil is delivered a little inside of the gaugeline of the wheel, where it is most needed. Figs. 3, 4, and 5 are sections of a " new style " patented, self-oiling wheel. In this, the outer end is cast closed, and the wheel is fastened to the axle by a spring cotter-pin passed through one of the plugged holes. Dirt is prevented from entering the open end by a cap, with faced end and packing-ring, fitting over the end of the hub. The lubricant is introduced into the oil-chamber through one of the plugged holes in the hub. When the wheel is in motion, the lubricant is thrown by centrifugal force away from the axle, enters the two ports shown, and is

Jan 1, 1890

By Shane Andrews, Gustavo Vasquez, S. K. Varma

"The effect of solutionizing time on the corrosive wear behavior of 2014 aluminum alloy has been studied using the impact and continuous mode of scratching techniques. The transient currents (TC) evolved during the scratching of the alloy shows a linear dependence between the TC and the solutionizing time. Higher TC values at longer solutionizing time may be associated with the changes in the concentration of quenched-in vacancies, grain sizes and dislocations generated during scratching. These factors can either create (a) anodic sites or (b) pitting corrosion resulting in the generation of transient currents. The results have been compared with the similar study carried out for 6061 aluminum alloys. This 6061 aluminum alloy shows similar behavior but the rate of TC generation per unit solutionizing time is much lower than 2014 aluminum alloy. The morphological changes in the impact scratches and the TEM investigation in the scratch have been presented in this paper.IntroductionThe technique of studying corrosive wear of composites of 6061 aluminum in the monolithic and reinforced forms has been reported in the literature [1]. Two modes of scratching, consisting of impact and continuous, in a corrosive environment indicate that the composites, containing 0.10 and 0.20 volume fractions of alumina particles (VFAP), have higher corrosive wear rates than the monolith. A graph between the transient current (TC) generated during the impact scratching as a function of solutionizing time at 540°C indicates linear relationship between them. A similar slopes for the composites were observed and the TC values were less for the composite containing lesser VFAP."

Jan 1, 1998

By Yao Zhou

Under the United Nations Convention on the Law of the Sea (UNCLOS), the international seabed area (Area) and its resources are the common heritage of humanity (CHH). Patent rights can be incompatible with the CHH doctrine and its underlying principles because patent holders might charge unjustifiably high prices to license patented technology for exploring and exploiting the Area’s resources (creating a "patent holdup" situation), might choose not to license, or might license exclusively when doing so would contravene CHH principles. However, a reasonable patent licensing regime can contribute to sharing the benefits derived from the Area and promote environmental sustainability. Provisions of the UNCLOS that stipulated compulsory technology and financial transfers were removed in the 1994 Agreement relating to the Implementation of Part XI of the UNCLOS (1994 Agreement), but to promote equity and sustainability I propose a voluntary licensing regime modeled on the concept of reasonable and non-discriminatory patent licensing (RAND) that has been used in other contexts. The International Seabed Authority (ISA) or another entity will need to coordinate and promote this licensing regime through governance of intellectual property (IP) derived from the Area. This proposed approach can better effectuate the CHH doctrine and its underlying principles.

Sep 1, 2014

By Blake M. Loring, Robert A. Colton

MELTING procedures for most metals and alloys usually include some provision for the control of oxygen, since this element frequently has some undesirable effect on the properties of the metal or alloy concerned. In the melting of the various bronzes, this is especially true, since oxygen can be introduced into the melt in a number of ways, most of which are difficult to control. In making bronzes from virgin materials, oxygen is usually present in the commercial grades of copper used; electrolytic he refined copper ingots usually contain from 0.02 to 0.05 per cent oxygen. When ingot metal or scrap bronze is used in the charge, oxides are almost always present to some degree. Under certain melting conditions and in certain types of melting equipment the atmosphere over the metal may be highly oxidizing. This, of course, may be desirable in the melting practice used, but is certain to introduce appreciable amounts of oxygen into the melt, and that may not be entirely desirable. From the foundry viewpoint oxygen may have several harmful effects on bronzes. The formation of excessive amounts of oxides may produce drossy metal, which, in turn, means dirty castings and a potentially high rejection rate. It is claimed, too, that oxides in the metal may combine with hydrogen to form steam and thereby produce porosity in certain of the bronzes. The presence of certain refractory oxides, such as SnO2, may be undesirable from the viewpoint of making machining difficult, or as possible stress-raisers in the metal matrix. It is often said that excessive oxide present in the liquid metal makes the metal run sluggishly. Since it appears impractical to try to control the amount of oxygen introduced into the metal beyond taking the economical limit of precaution about charging dirty scrap, it would seem that control of the oxygen content of the liquid metal offers the most promising approach to this problem. This might be done by using slags, or covers, or by the use of some element or compound added to the melt to remove oxygen preferentially. Most aspects of this problem have been considered and considerable work has been done along these lines. A reconsideration of the problem is indicated, however, by the controversial nature of the evidence at hand, especially on the possibility of using a chemical deoxidizer to control the oxygen content of bronzes. CHOICE OF DEOXIDIZER The choice of the chemical agent selected as a deoxidizer would naturally depend first on the alloy in which it is to be used; in this particular case the alloy is Navy gun metal. In Table I are listed a group of elements that might be considered as

Jan 1, 1946

By Rene Grabowski

Optimization of workflows and intelligent stock management; Slab stacking improvement by automated transport orders; and System automatically registers any slab movements even in manual operation. Case story: Steel producer ArcelorMittal Eisenhüttenstadt GmbH in Germany uses Primetals Technologie’s new stock yard logistics system in its finishing department. An exact image of its slab storage at any times is given by the warehouse logistics system to the company. It not only enhances the composition of the stacks of slabs, but also automates recording of manual restacking operations. Therefore the solution improves workflows and simplifies stock control. Cycle times have also been reduced due to the fact that the slabs can be charged to reheating furnaces ahead of the rolling mill due to less restacking operations within the slab storage. The expandable, modular system is based on the Siemens Simatic IT and Primetals Technologies’ IT4METALS Logistics product platform. It provides a large number of organizational and commercial features in the form of sophisticated graphics and tabular evaluations. For example, it can show how many crane movements have been made per shift for any category of slab, so that the time and cost for each operation can be calculated accurately.

Aug 16, 2017

By M. S. Ellis, D. J. Nichols

In 1999, 1,100 million short tons of coal were produced in the United States, 38 percent from the Northern Rocky Mountains and Great Plains region. This coal has low ash content, and has sulfur content in compliance with Clean Air Act standards (U.S. Statutes at Large, 1990). The National Coal Resource Assessment for this region includes geologic, stratigraphic, palynologic, and geochemical studies and resource calculations for 18 major coal zones in the Powder River, Williston, Green River, Hanna, and Carbon Basins. Calculated resources are 660,000 million short tons. Results of the study are available in U.S. Geological Survey Professional Paper 1625-A (Fort Union Coal Assessment Team, 1999) and Open-File Report 99-376 (Flores and others, 1999) in CD-ROM format.

Jan 1, 2001

"The asbestos mining industry in the Eastern Townships of Quebec has early recognized the undesirable side-effects associated with mineral production, such as air pollution, noise and unsightly waste dumps. In order to efficiently achieve the industry's aim of eliminating or minimizing these objectionable features of mining, all of the asbestos producers in Quebec interchange information, knowledge and design dealing with the environmental control measures through the Environmental Committee of the Quebec Asbestos Mining Association.The paper describes what has been done and what is planned for the future in the various problem areas, such as control of dust emitted during the open-pit drilling operation, control of dryer stack emissions, control of the environment in ore, fibre and tailings handling operations, rehabilitation of the countryside covered by waste dumps, and many others."

Jan 1, 1971

By K. Hodgson, N. C. Joughin

The detailed mechanism of rockbursts and other forms of damage due to rock failure in underground mining is as yet unknown. Studies of the energy changes which necessarily occur when an excavation is made underground seem to provide the best understanding of the phenomena leading to rock failure and damage (see Cook 1). It is common knowledge that the damage and rockburst hazard increases with depth and is greatest at remnants and in regions mined in an irregular manner. The rate at which energy is released as an excavation is enlarged provides an objective parameter to describe mining geometry in terms which are significant to studies of rock failure. In this paper, it is shown empirically that the rate of energy release per unit area increase in the size of an excavation is closely related to seismicity and incidence of damage in the mine. Consequently, it is suggested that the energy release rate is an important parameter in the design of underground mine layouts. Observations were made at two mines: the East Rand Proprietary Mines, Ltd. (E.R.P.M.), at a depth of about 9000 ft, and at Harmony Gold Mining Co., Ltd., at a depth of about 5000 ft. At both of these mines continuous recording seismic networks were in operation. (See Cook and Joughin.3) DESCRIPTION At E.R.P.M. the gold-bearing reef dips at approximately 35 degrees and is presently being mined at depths from 8000 ft to 11,000 ft below surface. The rock surrounding the excavation consists of a very homogeneous quartzite extending far into the hangingwall and footwall. The stoping width is approximately 40 in.

Jan 1, 1967

"A numerical procedure based on Smoothed Particle Hydrodynamics (SPH) is developed for rock blasting phenomena involving multiple intersecting joints. In this procedure, an elasto-plastic damage constitutive model has been applied in the framework of SPH to simulate yielding response of the surrounding rock medium. In this paper, a square shape rock medium with centrally located emulsion explosive in a borehole is numerically blasted with and without the presence of two diagonal rock joints. The model is simulated by assuming all four sides of the rock medium as free surfaces. The paper elaborates the propagation of stress wave, expansion dynamics of gaseous products, and development of fracture, fragmentation of the medium and dissipation of energy due to damage.INTRODUCTIONDamage prediction of rock mass and its mean fragmentation size are of important to design blast parameters for a given explosive. Current blasting practice solely depends on empirical relationships between fragmentation sizes to those blast design parameters while mathematical descriptions of the physical laws governing the process of rock blasting are limited. A constitutive relationship based on properties of explosives and rock mass is of special interest because of its capabilities in describing the key features of rock fracture and fragmentation, resulting in understanding of the physical process involved in rock blasting. It is well known that blast-induced damage and fragmentation of rock mass occur due to detonation induced stress wave and product gas driven fracture propagation. Nevertheless, the fundamental mechanism of the failure process and the behavior of rock characteristics under these two different loading are not well understood in many cases, which are closely related to growth of fractures and interaction of cracks under different loading conditions.Continuum damage mechanics is considered to be appropriate to describe the failure process under such high-amplitude stress wave. Based on this approach, several theoretical models have been developed to analyze the dynamic damage of brittle material such as rock and concrete with microstructure (Chen, 1999; Taylor et al., 1986; Wu et al., 2004; Yazdchi et al., 1996). These models are mostly based on the theory of damage mechanics or fracture mechanics with some statistical treatment to incorporate random distribution of microcracks. In the application of fracture mechanics theory, sometimes it is difficult to estimate the micromechanical parameters such as crack density and fracture toughness in different modes. In this study, damage in rock material is evaluated according to the earlier model developed by Grady and Kipp (1980), which is a fracture model coupled with a material description for stress wave propagation to predict quantitatively fracture and fragmentation under explosive loading conditions."

Jan 1, 2015

By S. J. Rothman, J. J. Hines, D. Rokop, R. Bastar

Self-diffusion has been measured along each principal axis of mosaic-structured and relatively perfect a uvaniuln single crystals. The anisotropy reported before,' D[loo] = D[001] » D[010 , has been confirmed. and is shown to represent volume diffusion. Diffusion along the dislocations in the imperfect crystals increases the measured value of D significantly without changingr either the shapes of the penetvation plots or the anisotropy. SINCE a uranium is orthorhombic, the diffusion coefficients along the principal crystallographic axes need not be equal. A previous measurement of self-diffusion in three mosaic-structured a uranium single crystals1 showed that Dil00| =D[001 >>D[010 This result was deduced from penetration plots similar to those in Fig. 1. That is, the plots for diffusion along [loo] and [001] were the straight lines expected from the solution of the diffusion equation for the boundary and initial conditions of the experiment, while the plot for diffusion along [010] was curved so that the part near X = 0 had a much steeper slope than the straight lines did. The observed anisotropy could have been due either to volume diffusion or to diffusion along the very large number of dislocations in such crystals, according to the model proposed by aart.' The authors of Ref. 1 argued that the latter possibility was unlikely, but did not exclude it. To settle the question, a simultaneous measurement of self-diffusion in mosaic-structured and mosaic-free crystals was carried out. This paper reports the results, as well as a measurement of the temperature dependence of self-diffusion in a uranium. EXPERIMENTAL The single crystals of a uranium used in this experiment are listed in Table I, together with other experimental details. '(Mosaic structured" here means crystals grown by solid-state phase change.3 The Laue spots from such crystals spread over about 6 deg of arc, which indicates that the density of dislocations is very large. "Perfect" crystals are ones grown by Fisher's grain-coarsening tehnique; the Laue spots from these are quite sharp,4 which shows that the dislocation density in these crystals is much lower. All of the crystals were made from high-purity uranium; a typical analysis is given in Ref. 1. The actual diffusion directions were within a few degrees of the nominal. The thin layer-sectioning method was used. The experimental techniques were similar to those described in Ref. 1, except the sectioning. Crystals Za, 2b, 2c, 4a, 4b, and 4c were sectioned on a lathe. Crystals 3a, 3b, and 3c were sectioned by grinding on glass plates, with 1 p diamond powder in butyl alcohol as the abrasive. The use of glass plates eliminated the crowning noted in Ref. 1, and the use of butyl alcohol as a lubricant simplified the chemical processing of the sections. Material from the sides of these three crystals was removed by spark machining before sectioning. The sectioning of crystals 4a and 4c was botched. A small cylinder of metal was extruded from the center of crystal 4a while turning off material from the side of the sample. Crystal 4c was misaligned by 2.1 x 10"3 cm because the dial gage jammed during the alignment. Notwithstanding these errors, useful data were still obtained from these crystals. The points

Jan 1, 1967

By Parsons A. E

The application of known pelletizing tech- nology was successful in the agglomeration of zinc concentrate into pellets of minus 6mm siz- ing using fine zinc calcine and sulphuric acid as binder. Subsequent roasting trials conducted in a 0.3 m diameter fluid bed reactor, showed that the pellets satisfactorily withstood hot physical abrasion during fluidization. Fines generation was low and the pellet calcine was hard, possessing excellent handling properties. Results of laboratory scale static pellet sinter- ing tests showed conclusively that the deterior- ation in sinter physical quality experienced with fine calcine was not apparent when the calcine was added to the mix in pellet form. Based on the results of small scale exper- imental work, a one tonne per hour pilot plant was constructed and operated. Several thousand tonne of pellets were produced-for fluid bed roasting in Badische Analin and Soda Fabrik (B.A.S.F.) turbulent layer (T.L.) roasters previously designed for roasting iron pyrite concentrate. Continuity of the T.L. fluid bed roasting operations was achieved when the waste heat boilers were replaced with atmospheric coolers and thus eliminated the problems of gas flow restrictions. Sinter plant trials were conducted over a period of two weeks with the addition of pellet calcine to the sinter feed. Results showed a marked improvement in sinter plant performance, and as a result of better bed permeability, increased sinter production was achieved, with- out significant deterioration in sinter quality.

Jan 1, 1974

By N. M. Saum, W. T. Caneer

Uranium may be in short supply due to the predicted energy needs in the coming years. As a result of this, a new surge of uranium exploration is underway accompanied by the refinement of numerous exploration techniques. One such technique is the monitoring of radon gas in surface soils and rocks as a guide to subsurface uranium deposits. The Colorado School of Mines Research Institute became involved in radon studies in 1967 on a project for the Atomic Energy Commission. Since that time the Institute has conducted numerous radon surveys for a large number of companies which have been active in uranium exploration. The objective of this paper is to relate the techniques utilized by the Research Institute and the results of some of the studies performed. Most of the studies performed by the Research Institute were related to roll front, sandstone-type uranium deposits. However, we have performed radon studies in various other types of rock. For those who may not be familiar with the application of radon "sniffing" in soils and rocks, a brief descriptive background should be given. The following question may be asked-why use radon as a guide to uranium mineralization? Some of the answers to this question are:

Jan 5, 1974

By S. Kelebek, U. Demir, T. C. H. Richards, E. Koss

"Laboratory-scale tests were carried out to investigate the response of a high-grade (~143 g/tonne) well-liberated gold ore to flotation using two collector types. Octyl and amyl xanthates, representing conventional types of collectors, were tested against an n-octanoic and hexanoic acids under moderate and high redox potential conditions. The latter was based upon a suggestion in literature that monocarboxylic acids are able to adsorb onto the surface of gold at redox potentials near 600 mV (SCE). This investigation did not demonstrate that these carboxylic acids could function as collectors for gold in real ores. In fact, they appear to have slightly depressed gold. However, the results demonstrated that octyl and amyl xanthates acted as highly effective gold collectors for this ore and that an increase in the collector dosage led to an increase in recovery for all mean particle sizes. In some tests, gold recoveries of around 95% were attainable in concentrates with grades around 6 kg/tonne, indicating that xanthate flotation remains a viable means of concentrating gold even at coarse grain sizes. Various aspects of the process such as grade-recovery performance and recovery by size are discussed.INTRODUCTION Three methods are used for the recovery of gold in mineral processing, either alone or in combination: gravity concentration, cyanidation and flotation. Gold occurs as a by-product in some ores together with platinum group metals and as the primary metal in other ores in the form of native gold and electrum, which are alloys of gold, silver and minor amounts of copper. Flotation is a viable method for recovering liberated gold where the gold is visible under an optical microscope (greater than 1 µm in size) and where the attachment of gold grains is not prevented due to bubble loading by competing minerals. It is generally known that grains finer than 150 µm in size will float with most collectors."

Jan 1, 2017