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By Frank R. Van Horn

It is customary to ascribe two general modes of occurrence to natural gas, namely, shale gas which, as the name indicates, is found in shale, and reservoir gas, which occurs in sandstone, conglomerate and dolomitic limestone. Both of these types are found in the Cleveland district. The shale gas has been produced on a small scale for a long period of years, probably dating back as far as 1883. Shale gas is a low-pressure gas, small in volume with variable pressure, and is limited to no definite horizon. It is generally independent of oil, may last for a long time, and is not dependent to any great extent on the structure of the rocks. There are many such wells in the district which range from 400 to 1,840 ft. in depth, although most have been completed at about 800 ft. This indicates that the wells pass through the Cleveland and Chagrin shales into the Huron or Portage shale of the Upper Devonian. During the last 2 years great interest has developed in a deeper-seated reservoir gas. What is commonly called reservoir gas is generally a high-pressure gas occurring in large volume at a definite horizon. Oil may, or may not, be associated with the gas, and in most regions in which reservoir gas is found, the geological structure is of great importance. This type of gas occurs in all large fields such as those of West Virginia which have been supplying Cleveland until the recent discovery of local gas at great depths in commercial amounts. Historical Outline The oldest well producing reservoir gas in the district was drilled in 1886 in Newburg for what was then known as the Cleveland Rolling Mill Co. This well was 3,000 ft. deep, and was thought to have reached the "Clinton" formation. Two "sands" showing small amounts of oil were recorded in the Niagara limestone at depths of 2,658 and 2,686 ft. This is about the horizon of the so-called Newburg sand which has proved to be of some importance as a source of gas and oil by recent drilling operations. The rock pressure was reported to be 400 to 500 lb. per square inch, but since the volume was only 14,000 to 16,000 cu. ft. daily, the well was not only considered unsuccessful but was thought to prove the absence of high-pressure gas in commercial quantities in the Cleveland district.

Jan 1, 1917

By M. W. Fabjanczyk, E. G. Alexander

INTRODUCTION The purpose of this paper is to summarise development of design processes used in the 1100 oreoody as a result of experience encountered. Design methods have been developed as a result of the history of ground behaviour, free-standing qualities of cemented back fill and mass blasting techniques. This paper contains an historical review of design methods previously described by Matthews ( 1972 ) , Hornsby and Sullivan (1977 and 19781, Kirkby, Blair and Hutton (19781, and Stewart (1980). The reasoning behind design philosphy changes are discussed and placed into context with methods now adopted. The 1100 orebody is Mount Isa's main producer of copper ore (5 million tonnes per year ) . Proven reserves are 120 million tonnes at 3.2% Cu. Location of the 1100 orebody in relation to overall mine geometry was well described by Dayton (1976). Geology The orebody is located in a series of massive brecciated shale lenses, in either a siliceous or dolomitic matrix, surrounded and separated by a uniform shale sequence. The whole formation is truncated at depth by a faulted contact with a greenschist facies metamorphic sequence below (Figure 1 and Figure 2) Mathias and Clark (1976). The breccia is known locally as silica dolomite and contains nearly all the economic mineralisation. Interfingering of shale and breccia often results in irregular boundaries to the silica dolomite and the ore limits. Geometry The geometry of the orebodies is shown by Figures 1, 2 and 3. Figure 3 also shows the location of the copper orebodies in relation to the lead orebodies. Structure Although the orebody is contained within the massive breccia (u.c.s. 150-250 MPa), it is cut by shear zones sub-parallel to the regional bedding (north-south striking, dipping approximately 60o to the west), and diagonally by major transverse faults (Figure A). These major faults have continuity in excess of 300 metres, with varying amounts of displacement up to 200 metres, and are zones of potential movement.

Jan 1, 1981

By T. MacDONALD

ATHOUGH flotation has been a commercial process for over twenty years, the last two years have witnessed a sudden and phenomenal increase in our knowledge of how to separate minerals heretofore not considered amenable to flotation at all. As remarked by Professor Locke in the January issue. "Either commercial or laboratory flotation is reported on zircon, ilmenite, carnotite, kyanite, scheelite, chromite, fluorite, feldspar, cassiterite, wolframite, barite, and clay. Attractive patents on soap flotation are U. S. Nos. 2,000,656 and 2,040.187. A survey by Ralston in the February E. & M. J. adds many other minerals to this impressive list. The simple but pregnant fact is that any mineral can be coated, directly or indirectly, with a water-repellent coating, and since this is true, it follows that any mineral can be floated. Fundamentally, this is no new discovery, where, for instance, is the mineral that cannot he washed from a pair of dirty hands by means of soap and water, given the absence of refractory greases or oils which would have no proper place in flotation ?

Jan 1, 1937

By Jr. Wilkinson

In today's work environment a tremendous amount of data is required to provide the regulatory agencies justification to issue a mining permit. The demands for data, specifically environmental characterization data, grow and the mine plans must address the issues raised by the interpretation of that data. Computers and computer software can provide operators and consultants with the tools necessary to assimilate, digest and interpret these seemingly unmanageable data sets. This paper presents some examples of how Mincom's MineScape software can be applied to the task of developing coal mine permits in an electronic format.

Jan 1, 1996

By Ira B. Joralemon

Neighboring mines, like men who live in the same environment, often assume similar characteristics. In the Bridge River area of the Lillooet district in central British Columbia there is a remarkable exception to this rule. The Pioneer mine has a simple fissure over 3000 ft. long, with no faults of more than a few feet and with only minor variations in width; the Bralorne mine, 2½ miles away at the other end of the same intrusion, has developed one of the most intricate vein and fault systems in the West. Hinged faults displace the main vein for hundreds of feet, and sometimes become valuable veins themselves. The width of ore varies in a few yards from 2 to 60 ft. Changes in grade of ore are just as abrupt. The rocks that follow the veins or are cut by them often grade into one another or into the ore with no definite contacts. Although the complexity of the structure has left many problems unsolved, the development has indicated a fascinating geological pattern. The Bralorne is in the eastern portion of the Coast Range, 55 miles by spectacular mountain road from the Pacific Great Eastern Railway station of Bridge River. The adit tunnel runs easterly from Cadwallader Creek, a tributary of Bridge River that flows into the Fraser River. Steep mountains rise from 3300 ft. elevation above sea level at the creek to peaks and ridges at 8000 to 9000 ft. altitude. The lower slopes are heavily wooded while above 5000 ft. bare rocks, glaciers and snow-fields extend far above timber line. See Fig. 1. Story of the Bralorne The Lorne claim, staked in 1897, was one of the earliest lode locations in the Bridge River district. At that time it was 70 miles by steep and treacherous trail from the railway. For the next 15 years Arthur Noel, Will Haylmore and other local prospectors mined the small, irregular, oxidized quartz veins to a maximum depth of 200 ft., and treated the ore in arrastres and later a five-stamp mill. The total production to 1912 was only $55,000. Noel and associates later formed the Lorne Amalgamated Mines Co., which they worked in a desultory way until 1925. Increasing sulfide and arsenide content in the veins

Jan 1, 1935

By Ira B. Joralemon

Neighboring mines, like men who live in the same environment, often assume similar characteristics. In the Bridge River area of the Lillooet district in central British Columbia there is a remarkable exception to this rule. The Pioneer mine has a simple fissure over 3000 ft. long, with no faults of more than a few feet and with only minor variations in width; the Bralorne mine, 2½ miles away at the other end of the same intrusion, has developed one of the most intricate vein and fault systems in the West. Hinged faults displace the main vein for hundreds of feet, and sometimes become valuable veins themselves. The width of ore varies in a few yards from 2 to 60 ft. Changes in grade of ore are just as abrupt. The rocks that follow the veins or are cut by them often grade into one another or into the ore with no definite contacts. Although the complexity of the structure has left many problems unsolved, the development has indicated a fascinating geological pattern. The Bralorne is in the eastern portion of the Coast Range, 55 miles by spectacular mountain road from the Pacific Great Eastern Railway station of Bridge River. The adit tunnel runs easterly from Cadwallader Creek, a tributary of Bridge River that flows into the Fraser River. Steep mountains rise from 3300 ft. elevation above sea level at the creek to peaks and ridges at 8000 to 9000 ft. altitude. The lower slopes are heavily wooded while above 5000 ft. bare rocks, glaciers and snow-fields extend far above timber line. See Fig. 1. Story of the Bralorne The Lorne claim, staked in 1897, was one of the earliest lode locations in the Bridge River district. At that time it was 70 miles by steep and treacherous trail from the railway. For the next 15 years Arthur Noel, Will Haylmore and other local prospectors mined the small, irregular, oxidized quartz veins to a maximum depth of 200 ft., and treated the ore in arrastres and later a five-stamp mill. The total production to 1912 was only $55,000. Noel and associates later formed the Lorne Amalgamated Mines Co., which they worked in a desultory way until 1925. Increasing sulfide and arsenide content in the veins

Jan 1, 1935

Neighboring mines, like men who live in the same environment, often assume similar characteristics. In the Bridge River area of the Lillooet district in central British Columbia there is a remarkable exception to this rule. The Pioneer mine has a simple fissure over 3000 ft. long, with no faults of more than a few feet and with only minor variations in width; the Bralorne mine, 2½ miles away at the other end of the same intrusion, has developed one of the most intricate vein and fault systems in the West. Hinged faults displace the main vein for hundreds of feet, and sometimes become valuable veins themselves. The width of ore varies in a few yards from 2 to 60 ft. Changes in grade of ore are just as abrupt. The rocks that follow the veins or are cut by them often grade into one another or into the ore with no definite contacts. Although the complexity of the structure has left many problems unsolved, the development has indicated a fascinating geological pattern. The Bralorne is in the eastern portion of the Coast Range, 55 miles by spectacular mountain road from the Pacific Great Eastern Railway station of Bridge River. The adit tunnel runs easterly from Cadwallader Creek, a tributary of Bridge River that flows into the Fraser River. Steep mountains rise from 3300 ft. elevation above sea level at the creek to peaks and ridges at 8000 to 9000 ft. altitude. The lower slopes are heavily wooded while above 5000 ft. bare rocks, glaciers and snow-fields extend far above timber line. See Fig. 1. Story of the Bralorne The Lorne claim, staked in 1897, was one of the earliest lode locations in the Bridge River district. At that time it was 70 miles by steep and treacherous trail from the railway. For the next 15 years Arthur Noel, Will Haylmore and other local prospectors mined the small, irregular, oxidized quartz veins to a maximum depth of 200 ft., and treated the ore in arrastres and later a five-stamp mill. The total production to 1912 was only $55,000. Noel and associates later formed the Lorne Amalgamated Mines Co., which they worked in a desultory way until 1925. Increasing sulfide and arsenide content in the veins

Jan 1, 1935

By Ira B. Joralemon

Neighboring mines, like men who live in the same environment, often assume similar characteristics. In the Bridge River area of the Lillooet district in central British Columbia there is a remarkable exception to this rule. The Pioneer mine has a simple fissure over 3000 ft. long, with no faults of more than a few feet and with only minor variations in width; the Bralorne mine, 2½ miles away at the other end of the same intrusion, has developed one of the most intricate vein and fault systems in the West. Hinged faults displace the main vein for hundreds of feet, and sometimes become valuable veins themselves. The width of ore varies in a few yards from 2 to 60 ft. Changes in grade of ore are just as abrupt. The rocks that follow the veins or are cut by them often grade into one another or into the ore with no definite contacts. Although the complexity of the structure has left many problems unsolved, the development has indicated a fascinating geological pattern. The Bralorne is in the eastern portion of the Coast Range, 55 miles by spectacular mountain road from the Pacific Great Eastern Railway station of Bridge River. The adit tunnel runs easterly from Cadwallader Creek, a tributary of Bridge River that flows into the Fraser River. Steep mountains rise from 3300 ft. elevation above sea level at the creek to peaks and ridges at 8000 to 9000 ft. altitude. The lower slopes are heavily wooded while above 5000 ft. bare rocks, glaciers and snow-fields extend far above timber line. See Fig. 1. Story of the Bralorne The Lorne claim, staked in 1897, was one of the earliest lode locations in the Bridge River district. At that time it was 70 miles by steep and treacherous trail from the railway. For the next 15 years Arthur Noel, Will Haylmore and other local prospectors mined the small, irregular, oxidized quartz veins to a maximum depth of 200 ft., and treated the ore in arrastres and later a five-stamp mill. The total production to 1912 was only $55,000. Noel and associates later formed the Lorne Amalgamated Mines Co., which they worked in a desultory way until 1925. Increasing sulfide and arsenide content in the veins

Jan 1, 1935

By Akira Usui

Iron and manganese are very mobile metallic elements in the surface aqueous environment, particularly in the oceans. The elements are easily precipitated as oxides or dissolved back into water, controlled mainly by redox conditions, and the oxide precipitates often selectively accumulate other metallic elements. We have found clear evidence of fine-scale variations in chemistry, mineralogy, isotope composition and microstructures within various iron-manganese nodules and crusts, such as in the deep-sea basins and seamounts of the Pacific Ocean, and in shallow waters in the Baltic Sea. The patterns of variation with depth (that is time-lapse profiles of the deposits) are often correlated among samples and sometimes between remote localities. These fine-scale variations most probably reflect past depositional conditions and possibly image the environmental change, although they remain to be correlated to any physicochemical, geological, or oceanographic parameters. The hydrogenetic ferromanganese crusts have grown widely in the northwestern Pacific, accelerated by intensive circulation of oxygenated bottom waters during the last several millions of years, or earlier. The fine-scale (in millimeter) in-depth compositional and textural patterns with Be-10 growth-rate curves suggest significant changes in growth rate and also occasionally show a common microstratigraphic pattern among samples. Some of the samples indicate a correlation in growth pattern between remote locations, while others suggest short-range difference of oceanographic conditions with water depths.

Jan 1, 2004

By John W. Harshbarger

The Upper Santa Cruz Groundwater Basin lies in the drainage area of the Santa Cruz River in Arizona, and extends upstream from the community of Rillito to the international boundary, see Figure 1. The principal water use area lies between and includes the cities of Tucson and Nogales. A subsurface geologic barrier near Rillito provides a reasonable dividing line between the groundwaters of the Upper and Lower Santa Cruz Basins. The Upper Basin contains the Tucson and Sahuarita-Continental critical ground- water areas. The Tucson Water Use Area encompasses the Tucson metropolitan area and extends from the northern boundary of the Basin south to the boundary between the Tucson and Sahuarita- Continental critical groundwater areas near San Xavier. The San Xavier Use Area is the San Xavier Indian Reservation. The north and south boundaries of the Continental Use Area coincide with the limits of the Sahuarita-Continental critical groundwater area. The first study of groundwater in this valley was initiated by Dr. G. E. P. Smith in 1905 and the results were published in 1910, followed by a series of bulletins of the Arizona Agricultural Experiment Station, University of Arizona, covering the general field of groundwater development and utilization. Beginning in 1939, the Ground Water Branch of the United States Geologic Survey, in cooperation with the Arizona State Land Department and the Arizona Water Commission (AWC), have published a series of bulletins concerning groundwater occurrence and utilization in various areas of the state. In 1975 and 1977, the AWC published the "Arizona State Water Plan" (1), comprising a detailed inventory of water availability and use in the State of Arizona, and a study of alternative futures.

Jan 1, 1979

By Roger A. Blais, Michel David

"Matheron's geoslalislical method for the estimation of ore reserves has been developed to the point at which real-life problem may be handled effectively. The steps involved in the method are:(i) obtalning the variogram,(ii) fitting a model, and(iii) producing block estimates.All three steps may cause difficulty, and would-be users need a deep understanding of the theory if failure is to be avoided.To illustrate these points, specific cause are considered:(i) two almost equidimensional porpbyry deposits, one drilled randomly and the other regularly; and(ii) two iron formation, one drilled extensively and being mined, while the other is still at the stage of early estimation."

Jan 1, 2014

By R Lau

The fire safety design for road tunnels includes the following aspects: active systems, passive provisions and operational procedures. The active systems include the smoke control system, fire suppression system, detection system and fire fighter’s assistance systems. Passive provisions include escape passages, fire separation and fire resistance systems. The operational procedures refer to fire fighter access, reporting and alerts, evacuation processes and crowd control.Currently, these systems are typically designed by different designers or teams. These systems are intended to work together in a coordinated manner to provide the desired safety outcome. However, in practice, this is not always happening. The fire engineering process is supposed to bring together all these aspects and arrive at an integrated safety system. The fi re engineering process in practice is not integrating the design with the practice or reality and is thus arriving at less than desirably efficient safety systems.The example of design inputs shows how disconnected each system design basis is. The smoke control system design is based on the design fire size. The performance of the smoke control system is to achieve a smoke free environment for a defined space for a particular fire size – the design fire. The fire suppression system – most commonly sprinklers or deluge systems, is designed according to codes and to achieve a certain water discharge rate. The fire detection system is designed to detect temperature rise/rate of rise and perhaps density of smoke. Fire separation is determined to provide a certain period of service – mostly for structural elements. Escape route size and location is determined mostly by code compliance. Evacuation procedures are determined by Authority operational requirements rather than human behaviour.To arrive at an integrated fire safety system, the design basis and performances must be coordinated. An approach using fire scenarios would ensure all systems are designed to a common performance requirement. This paper will discuss how the current design approach outcomes compared with a fire scenario approach. More effective and efficient fire safety systems would require the stake holders to understand the implication of this approach and to embrace this through the fire engineering process.

Mar 8, 2011

By Charles L. Kimbell

For a study such as this, which summarizes and amalgamates much information collected, compiled, and utilized by the numerous U.S. Bureau of Mines country specialists and branch chiefs for inclusion in the country and regional reports that comprise the five other sections of 1991 Minerals Yearbook-International Review, it is clearly impossible to cite all sources of information used in its presentation, but some recognition is due. Generally speaking, this study and its related detailed studies on countries and areas would be much more difficult, if not impossible, without the efforts of the personnel of national mining and geological agencies throughout the world. Information that they collect, compile, and then publish, either in their own volumes or those of central statistical agencies in their countries, are the foundations on which this work rests. Thus, appreciation is expressed to the multitude of persons employed by these agencies.

Jan 1, 1993

By D. C. McKechnie

To the examining engineer, the ever-recurring problem involving the valuation of ore in a prospect presents at different times highly divergent aspects- some entirely physical or mathematical, others essentially personal. The majority of the problems discussed in this paper are obvious to the engineer, and need little elaboration. By the prospector and the general public, however, a number of these questions are often and completely over-looked, or else approached in such a way as to produce final results which are, to say the least, misleading and at times decidedly erroneous. While the purpose of this paper is to deal with prospects or potential mines, many of the problems considered apply equally well to mines with developed ore reserves. As the usual showings on a prospect consist chiefly of a few open-cuts and a limited amount of underground development work, an estimation of the actual ore reserves is a question of minor import, and seldom enters appreciably into an estimation of the probable value of the particular property. The physical valuation of a prospect mainly involves the consideration of such subjects as the general geological features exposed, the strength and type of mineralization, the width and persistence of any associated veins, shear zones, fractures or contact zones, together with the possible grade, size, and continuity of any ore-bodies that may there occur.

Jan 1, 1930

By R. H. Grau, R. Krog

The National Institute for Occupational Safety and Health (NIOSH) has conducted research to improve the ventilation of large-opening mines. The research has demonstrated that the ventilation of large-opening mines improves significantly by including ventilation requirements in the mine planning process and implementing somepractical techniques during mining. Planning the location of long pillars to reduce the number of crosscuts between intake airways and return airways, positioning auxiliary fans in their proper locations, and establishing ventilation stoppings with minimal leakage all significantly improve the ventilation of large-opening mines. Mine operators that adopt these techniques in the mine ventilation plan will reduce mineworkers’ exposure to airborne contaminants.

By Philip W. Johnson, Charles D. Haynes

"Abstract - The coalbed methane industry has become a prominent source of domestic natural gas, with its technology having evolved over the past 30 years. Whereas most coalbed methane wells are able to produce without major interruption over their economic lives, wells operating in an underground mining area are subject to being mined-through. If mine-through occurs, the productivity of the well is at least compromised, and may even be terminated. The economic consequences of mine-through may be relatively simple if mineral ownership and extraction rights are common for the coal and coalbed methane. However, if ownership is not common and a superior coalbed methane lease exists, the coalbed methane ownership must be compensated for lost production caused by mine-through. This paper presents a relatively straightforward method to calculate the value of the lost production caused by the mine-through. It uses technology from mining and petroleum engineering, as well as simple economics and financial management techniques.Sommaire - L’industrie de la production de méthane houiller est aujourd’hui une source importante de gaz naturel domestique dont la technologie a considérablement évolué au cours des trente dernières années. Bien que la plupart des puits de méthane houiller peuvent être mis en production durant l’entièreté de leur vie utile sans interruption majeure, les puits implantés en périphérie de mines souterraines sont sujets à être recoupés par ces dernières. Un tel recoupement peut compromettre, ou même mettre fin à la production d'un tel puits. Les conséquences économiques du recoupement par une mine souterraine peuvent être relativement simples quand les droits miniers et les droits d’extraction sont détenus en commun pour le charbon et le méthane houiller. Si toutefois ces droits ne sont pas détenus en commun et qu’il y a eu octroi d’une concession de méthane houiller de qualité supérieure, les détenteurs du méthane houiller doivent être compensés pour la perte de production résultant du recoupement par une mine souterraine. Cet article présente une méthode relativement simple pour calculer la valeur des pertes de production suite au recoupement par une mine souterraine. Cette méthode fait appel aux technologies de l’industrie minière et pétrolière ainsi qu’à des techniques simples d’économie et de gestion financière."

Jan 1, 2006

By Erling Stranden, Leiv Berteig

INTRODUCTION The measurement of the total activity of radon daughters in the air of mines has become a routine procedure in order to control the radiation exposure in miners due to the inhalation of these radionuclides. Normally the measured concentration is given in terms of total potential L-energy of the short lived radon daughters. The unit most frequently used is 1 WL (working level), which is defined as the potential a-energy of 1.3.105 MeV per 1 of air. The a-dose to the respiratory tract is, however, not proportional to the inhaled potential a-energy. In addition, the degree of equilibrium between the daughter products in air and the fraction of daughter products not attached to aerosol particles (the unattached fraction) must be known. Theoretical calculations of the equilibrium between daughters and the unattached fraction have been presented by different authors (Jacobi, 1972; Porstendörfer et al, 1978). Such calculations must take into account the plateout of daughters on surfaces, the attachment of daughters to aerosols and removal of daughters by the ventilation. The situation in mines will however be very complex and no single model will cover all situations. In most cases the radon and radon daughter concentrations will be described by a combination of different models. Domanski (1979) used the experimental results of Breslin et al. (1969) from uranium mines to relate the equilibrium between the individual daughters to the equilibrium factor, F. Once the equilibrium factor is known, this seems to be a useful approach to assess the individual daughter concentrations. The concentrations of radon and daughter products may vary considerably during the day. Seasonal variations are also frequently found. It is therefore important to have knowledge of the magnitude of these variations and of the factors having the strongest influence upon the concentrations. The unattached fraction of radon daughters in uranium mines was investigated by George and Hinchliffe (1972) and Raghavayya and Jones (1974). Mercer (1975) later modified the results of Raghavayya and Jones. Both these investigations indicated that the aerosol particle concentrations was the main influencing factor upon the unattached fraction. In this paper we will summarize the main results of a study on the radiological characterics of nonuranium mines. We will also discuss the correlations between the unattached fraction of the potential a-energy and the unattached fraction of the individual daughters, and between the equilibrium factor F, and the individual daughter ratios. More detailed discussions of this study will be published elsewhere (Stranden and Berteig, 1981 and Stranden and Berteig 1981 a). MATERIAL AND METHODS During 4 two-weeks periods corresponding to the seasons in the Norwegian mine where the highest radon daughter concentrations occure, the parameters listed in table 1 were studied. TABLE 1 Parameters measured during the study [Parameter Methods Radon Scintillation flask/Continuous ionization chamber Radon daughters Tsivoglou(1953)/Kusnetz(1956) Respirable dust Cyclone Unattached fraction Wire screen (Stranden and Berteig 1981) Atmospheric pressure Continuous baragraph Temperature and Continuous thermohygrograph humidity] At a fixed location, the radon concentration was measured continuously by a ionization chamber (Stranden, 1981), during these two-weeks periods in order to study short-time and seasonal variations. RESULTS Correlation between equilibrium factor and individual daughter ratios. The mean value of the equilibrium factor in all Norwegian mines measured during the last ten years was 0.46 with a minimum of 0.08 and maximum of 0.93 (Stranden and Berteig, 1981). The correlations between the equilibrium factor F, and the individual radon daughter/radon ratios were studied and the results indicated high correlations. In table 2, these correlation formulae are listed together with the correlation coefficients. TABLE 2 Correlation between the equilibrium factor, F, and individual radon daughter ratios [Formula Correlation coefficient RaA/Rn = 1.14 F 0.551 0.76 RaB/Rn = 1.00 F 0.940 0.99 RaC/Rn = 0.77 F 1.120 0.92]

Jan 1, 1981

By C. A. Hardie, G. F. Leichtle, J. A. Finch, J. A. Watson

"The recycling of wastepaper has become an important and common process worldwide. Techniques similar to those used in the mineral processing industry are used to produce high quality recycled fibres for use in newsprint. The mineral processing group at McGill University, in conjunction with the Pulp and Paper industry (Mechanical and Chemi-mechanical Wood Pulp Network), has adapted one of these techniques, column flotation, for the purpose of deinking wastepaper. This article describes the typical process of recycling wastepaper from a mineral processing point of view. It also presents results from McGill University’s flotation column test work at a Québec wastepaper recycling facility. IntroductionThe recycling of wastepaper has become an important and common process worldwide, including Canada which is now the world’s largest importer of wastepaper (CPPA, 1996). Much of the current drive to increase the utilization rate of recovered paper is a reaction to the solid-waste disposal problem that faces many Canadian and United States municipalities. The real problem in the disposal of solid waste is not the absolute amount of garbage that must be disposed of each year, but this amount in relation to available disposal capacity.Environmental restrictions on the creation of new landfill sites and incinerators (the two main options for disposal of municipal solid waste) have tightened the demand/supply balance in the solid waste disposal market. This shrinking availability of waste disposal sites in the face of increasing population with greater disposal requirements defines the Developed World’s solid waste crisis. Not only are there fewer disposal sites available, but the costs of using them is skyrocketing. These factors have increased government regulations mandating recycled paper content in newsprint. Conservation and environmental issues make the current drive for wastepaper recycling a real issue and business opportunity."

Jan 1, 1999

Pajingo Gold Mine Pty. Ltd. is a subsidiary of its United States of America parent the Battle Mountain Gold Company. Battle Mountain Gold Company was created in August 1985 as a spin-off of the United States of America Pennzoil Company's gold interests.Pajingo Gold Mine Pty. Ltd. currently has its headquarters and base for operations located in Townsville, Queensland. The Company's main current activities are the exploration and evaluation of the Pajingo Gold Property situated some 50 kilometres south-east of Charters Towers and in the northern Drummond Basin.The discovery of the Pajingo gold mineralisation by the Company was the indirect result of a regional program established to evaluate Carboniferous age volcanic plugs in north Queensland for gold mineralisation.

Jan 1, 1986

By Richard O. Carlson

Ions of p31 and B 11 were implanted in natural insulating diamond macles. The thin (-0.4µ) layers showed sheet resistances of 107 to 1011 ohm per sq and activation energies of 0.17 to 0.34 ev above room temperature. However, no Hall effect could be measured, indicating that mobilities were less than I to 10 sq cm per (v-sec). Such low mobilities may be due to excessive scattering due to radiation damage in the bombarded layer or to very high concentrations of active compensating impurities. Annealing did not materially change the room -temperature properties, but the temperature was limited to -800°C by surface graphitization, the latter process probably being accelerated by lattice damage in our diamonds arising from the ion bombardment. A weak n-type thermoelectric power was detected after p31 irradiation, but it cannot be presumed that we have made the phosphorus ions active as donors in diamond. The natural diamonds have a high and uncontrolled concentration of impurities and, when coupled with the radiation damage and graphitization problems, would appear to seriously limit the quality of semiconductor that we can presently achieve by ion implantation in diamond. ALTHOUGH diamonds are usually thought of as insulating in terms of their electrical conductivity, it was found about 15 years ago that natural semiconducting diamonds do occur rarely, and these were designated as type IIb diamonds. These p-type semiconducting diamonds were found to be dominated by an impurity level 0.37 ev from the valence band. Evidence today based on correlation of the concentration of acceptor states from Hall effect measurements with the impurity concentrations determined by neutron activation analysis point to aluminum as the dominant acceptor impurity.' The compensating donor is believed to be nitrogen, which has a donor level 1.6 ev above the valence band.' However, only a small fraction of the total nitrogen content in the diamond is electrically active. An infrared absorption band at 7.8 p and ultraviolet absorption near 4 ev have been associated with nitrogen, the former providing a quantitative measure of nitrogen content.3 The nitrogen content is -l020 cm-3 in insulating or type I diamonds, but is less than 10'' in natural semiconducting diamonds. Much of this nitrogen is distributed in platelets oriented in (100) planes and not atomically dispersed in the diamond lattice.4 Semiconducting diamonds have been deliberately formed by incorporating impurities into the graphite charge in the high-pressure apparatus used to form diamonds.5 These manufactured semiconducting diamonds are always p-type, and while some show the 0.37 ev level due to aluminum, most such samples have been ascribed to impurity banding effects.6 The best natural or manufactured semiconducting diamonds have hole mobilities near 1500 sq cm per (v-sec) at room temperature, and those with the 0.37-ev level can be analyzed to reveal an acceptor concentration of 3 to 8 X 1016 cm-3 and a donor concentration 3 to 10 times lower.' NO bulk n-type diamonds have ever been reported, but the electron mobility has been measured as 1900 sq cm per (v-sec) by irradiating a diamond with ultraviolet to excite electrons out of the deep nitrogen donor level or other levels.7 New hope for the formation of n-type diamond has emerged from the ion-implantation method whereby desired impurities are introduced into a crystal lattice by bombardment with a high-energy beam of the impurity ion. It was found in the case of silicon that the usual donors such as phosphorus and arsenic and acceptors such as boron and gallium could be implanted into silicon. Wentorf and arrow' produced semiconducting layers on diamonds by an ionic bombardment in a glow discharge at potentials of about 2 kv. The observed typeness from thermoelectric probing seemed to depend on the atmosphere gas (nitrogen, argon, or hydrogen) rather than on the electrode material, but the nature of the conduction process in the thin damaged surface layer is completely unknown. A Russian group under Vavilov has attempted high-energy ion implantation in natural diamonds using boron and lithium ions9 and later also phosphorus, aluminum, and carbon ions.10 Their papers claim n-type layers from lithium, phosphorus, and carbon implant and a p-type layer from boron and aluminum implant, though the methods of type determination are not described in detail. Under government contract support, the Ion Physics Corp. has studied ion implantation in several semiconductors. While the bulk of their study1' was devoted to the irradiation of silicon, they did carry out a short study on boron and phosphorus implantation into natural diamonds. They did observe surface conducting layers but did not determine the typeness of the layers. For our experiments, phosphorus and boron were chosen as the dopant ions because of their respective donor and acceptor behavior in germanium and silicon. Moreover, they are the lightest mass dopants of the shallow level donors and acceptors from columns 111 and V of the Periodic Table (excluding nitrogen which is already present in diamond), and will have the largest depth penetration into the diamond lattice. EXPERIMENTAL Diamonds. As the target diamonds for our ion implantation study, we chose commercially available macles, which are flat, twinned diamond crystals. By scanning through the stock of a wholesale distributor

Jan 1, 1970