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By H. Firmstone

Deposits of cadmia, or impure oxide of zinc, are of common occurrence in the upper parts of blast furnaces using ores containing zinc, and were very common in the charcoal furnaces of Virginia working the brown hematite ores found near the Cadent black slate. These deposits were known to the old charcoal founders as "sulphur rings," and the characteristic green flame of burning zinc frequently to be seen at the tymp of furnaces working ores containing zinc, was held by them to indicate the presence of a "sulphur fall." When zinc is burning in considerable quantities at the tymp, the

Jan 1, 1879

By G. C. Gardner

A new correlation of blast penetration in model and operating blast furnaces is presented which overcomes objections to prevzous correlations. It is shown that the tuyere diameter is only of small importance in determining the magnitude of the penetration. The data from operating furnaces correlate satisfactorily with the data from models whose cross section is a segment of a circle. A bubble-shaped gas space called a "raceway" normally exists in front of the nose of a blastfurnace tuyere. The periphery or "wall" of the raceway is well defined and is composed of densely packed charge particles. The blast. issuing as a jet from the tuyere, entrains gas from the raceway, in the usual manner of a jet, as it flows to the opposing wall. There it divides and flows back around the walls to be entrained once more. The blast must, of course, eventually leave the raceway and pass up through the charge column, but before it does it may, on the average, make several circuits of the kind described and in doing so it carries with it charge particles, which, because of their fast and circulating motion, suggested the name of "raceway". A fuller description of the raceway may be found elsewhere."' Here it is only necessary to mention, in addition, the measurement which characterizes its size. If an iron bar is pushed through the opened peepsight of a tuyere, .as far as it will go with ease, it will be stopped by the relatively impenetrable opposing raceway wall arid the distance that the bar has been pushed from the tuyere nose is called the "penetration". This measurement may be of practical importance and has; been the subject, with considerable success, of several attempts at correlation with other variables2-5 as stated in the next section. There is still, however, a serious objection to the most recent correlation,3 which is overcome by the correlation proposed in this paper. It will be shown that the objection is not trivial, in that the new correlation will attribute considerably different importance to the variables affecting the magnitude of the penetration. The data to be treated were made available by Wagstaff and are the same as those used in his correlation. They include measurements taken on small models, in which a cold air blast was used and no combustion occurred, and they also include data from operating blast furnaces at Wheeling and Fairless. The information from the blast furnaces will be shown to be in substantial agreement with those models whose plan views are segments of a circle and which are thus like segments of a blast furnace. First, Wagstaff's most recent correlation3 will be discussed and the objection will be given. Then the new correlation will be developed and its implications considered. CORRELATION OF J. B. WAGSTAFF Wagstaff's correlation is where and D — the penetration D,-the internal tuyere diameter V —the blast velocity in the tuyere

Jan 1, 1961

By Thierry Lavoie, Mark K. Larson

"Engineers at the National Institute for Occupational Safety and Health (NIOSH) and Itasca Consulting Group, Inc., conducted a study to determine the procedure for calibrating a caving model implemented in FLAC3D. The model is calibrated to measured surface subsidence. This sedimentary caving model was developed by Itasca for NIOSH for the purpose of more closely simulating mechanical processes during caving. When a model is considered calibrated to surface subsidence, the load between the extracted panel's roof and floor is a reasonable estimate of gob loading. Such information can also provide an estimate of the amount of overpanel weight that is transferred to the abutment. This load distribution is a parameter needed, for example, to estimate loading of pillars in longwall gate roads. For the current case, a calibrated model resulted in a calculated abutment angle of 30.6°considerably higher than the assumed value used in empirical methods, but reasonable considering the presence of massive stratigraphic members in the overburden. Because of additional information available after this study that the extracted seam height was actually greater in the first panel, a corrected range of abutment angle was estimated to be from 27.7° to 30.6°, still significantly higher than the empirical assumption. The expectation is that better estimates of abutment loading profiles will result in improved evaluations of mine layout design and, therefore, reduce the number of fatalities and injuries resulting from falls of ground.INTRODUCTIONThe safety of miners in underground coal mines depends on careful consideration of the mechanisms involved in failure and transfer of load. The successful design of pillars and panels in longwall and room-and-pillar coal mining requires thorough attention to any information and measurements available that help understand these mechanisms. Although empirical methods, such as Analysis of Pillar Stability (ALPS) Mark (1987); (Mark, 1992) or Analysis of Retreat Mining Pillar Stability (ARMPS) (Mark and Chase, 1997), can provide a sense of success or failure, complex geology and failure in the roof or floor material or complex material behavior of the coal can make evaluation by an appropriate numerical modeling tool necessary. The numerical tool must simulate important mechanisms and appropriate detail that underlie the mechanism. For example, Starfield and Cundall (1988) advised using ""the simplest model that will allow the important mechanisms to occur, and could serve as a laboratory for the experiments you have in mind."" To that end, data gathering about the geology, geometry, and material behavior is very valuable. Such data facilitate selection of an appropriate model and model inputs. Moreover, this data facilitate improved assessment of risk to miners and how to minimize that risk."

Jan 1, 2016

By Frank Hirthammer

The paper explains the procedure of implementing Track & Trace solutions for manufacturers of explosives based on customer experiences. By using concrete examples, the process from project start to implementation is described. Lessons learned from the experiences of European explosives manufacturers are presented.

Feb 1, 2020

By A. L. Engel

IN the treatment of complex ores by flotation, one of the most important steps is conditioning the feed. Conditioning primarily consists of the addition, in the grinding circuit, of an alkaline reagent, for example sodium carbonate, which neutralizes any acidity of ore and mill water, counteracts the effect of 'harmful soluble salts, disperses colloids, and provides the necessary alkalinity for the best metallurgical results. The several minerals of the ore should be put in such condition that they may be floated or rejected as desired, through the action of further reagents thereafter used.

Jan 1, 1932

By Ramamritham Sridhar, Vaikuntam I. Lakshmanan, Dan A. Macki

Historically, introducing new technology to the mining industry has been problematic. In general, the industry is reluctant to take risks with new technology because it is already heavily tied to risk, even using existing technology. Risk in the orebody itself can be substantial. The company is dependent on drill hole patterns that are expected to define what is underground, and process test work is often based on drill cores and other samples, which occasionally produce surprises. And even well-proven processing techniques can blindside the producer, resulting in embarrassing and costly difficulties. But if the industry is to grow in knowledge and become more efficient, new ideas must be introduced. How to introduce new technology is the essence of this paper.

Jan 1, 2001

By Z Chang, S A. Mrozek, S Windle

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. It is important to understand skarn-porphyry transitions in order to use exposed skarns to look for associated and potentially larger porphyries. For such purposes, a good start is to understand the transition between porphyry and skarn in known deposits. In this contribution, we report the transition at Antamina, Peru, where skarns occur in and around a Miocene complex comprised of more than seven porphyritic intrusions. There are three types of skarn-porphyry relationships. The earliest intrusive phase, P1A, contains both endoskarn and porphyry-style quartz veins with secondary biotite halos. The porphyry quartz veins and endoskarns formed at the same time. Locally, the intrusion contains only endoskarn without porphyry quartz veins and is surrounded by exoskarns in carbonate wall rocks. In the third scenario, later porphyry (P2) intruding into P1A porphyry and skarns related to P1A contains abundant granular quartz veins and secondary biotite alteration but does not have significant endoskarn. The granular quartz veins also extend into earlier P1A skarns. The scarcity of endoskarn associated with P2 is related to the supply of Ca. The earliest P1A intrusion intruded into carbonates that supplied abundant Ca, therefore both endoskarns and exoskarns formed. In contrast, where the wall rocks of the later P2 intrusion are P1A or skarn related to P1A, there was little free Ca, therefore only porphyry-style quartz veins formed.CITATION:Chang, Z, Mrozek, S A, Meinert, L D and Windle, S, 2015. Skarn-porphyry transition – an example from the Antamina skarn, Peru, in Proceedings PACRIM 2015 Congress, pp 409–414 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By T S. Cochrane

A variety of practical tests have been tried in the mining industry to determine the support properties of mine roof bolts. Such tests include torsion wrench readings, hammer blow tests and the use of plates with built-in tension indicators. This paper gives some details of pull tests with a hydraulic jack, as carried out in coal mines of western Canada. M A~Y criteria exist for establishing the efficiency of roof bolting, and the one adopted de-pends on the nature of the problem and on the individual leanings of the investigators. Consequently, sufficient studies have not been made from a common viewpoint or under similar geological and techno-logical conditions to compare these methods of evaluation. However, regardless of whether certain tests provide sufficient factual data to form a basis for theoretical research on bolting or not, many of these tests can and do provide a positive means of judging the suitability of chosen roof bolting techniques and equipment under definite geological conditions.

Jan 1, 1963

By R. Barbaroux, J. -M. Lalancette, D. Lemieux, K. Nasrallah, G. Garcia Curiel

"Arsenic released from the lithosphere by mining and metallurgical activities is a growing global environmental concern. Dundee sustainable technologies (“DST”) has developed a processing technology to sequester arsenic by means of vitrification. This method can effectively sequester arsenic trioxide without the need to oxidize from As (III) to As (V). Arsenic oxide is incorporated within a silica glass matrix that is stable as per the Toxicity Leaching Characteristic Procedure (“TCLP”) or EPA Method 1311. In this paper, the conventional treatment of arsenopyrite, commonly referred to as “two-stage roasting”, is discussed along with the options traditionally available for the remediation of the arsenic trioxide by-product. The drawbacks limiting the adoption of this processing flowsheet are discussed and a new processing route is presented for the treatment of arsenopyrite. This new flowsheet outputs an auriferous aluminosilicate highly amenable to gold extraction (> 96%) while eliminating the sulfur dioxide production associated with the second-stage roasting of pyrrhotite and ultimately uses vitrification as a definitive sequestration solution to arsenic trioxide.INTRODUCTION Faced with the depletion of conventional gold ores, the gold industry has witnessed a trend towards the exploitation of arsenical deposits. Arsenic is a naturally occurring metalloid often found in mineralogical association with gold. Many northern Canadian regions, from the Northwest Territories to Northern Manitoba, Northern Ontario and the Abitibi region are facing significant arsenic challenges. Projects are deemed uneconomic or prevented from going into operations due to the costs associated with handling arsenic material and there are penalties imposed to complex concentrates by smelters. In addition, Canadian mining operations have left an environmental legacy of gold tailings with grades typically of up to 9 grams per tonne with no processing solution as they also contain significant arsenic contamination at grades of up to 20%. Table 1 presents a list of Canadian deposits known to contain arsenic."

Jan 1, 2017

By R Durchholz, A-J Heiertz, R Schmitz

Mining of lignite is the largest bulk materials handling activity in Europe. In order to mine this lignite, with an average calorific value of only a third of bituminous coal in an economical way, highly efficient opencast mining technology is mandatory. The total continuous mining of overburden and lignite was introduced more than 60 years ago and was subsequently developed stepwise into the largest mass transport system of the world. In 2011, the Inden Mine, one of three RWE Power mines, stripped 90 Mbcm of overburden to produce 22 Mt of lignite. In total, nearly 100 Mt of Lignite was produced from the three mines of RWE Power in Germany. Beside bucket wheel excavators (BWE), several high-performance in-pit crushing and conveying (IPCC) systems, which allow the adoption of continuous mining systems, even for typical shovel and truck (S&T) operations, are available today. RWE Power assists operators considering a change from the S&T to IPCC technology, both in the planning process involving large-scale belt conveyor systems and later with operational know how transfer. In a number of cases, the challenges associated with this system change have been addressed and solved successfully. One key challenge is managing the development of skills for operating the belt conveyor systems efficiently. This paper compares the effectiveness of S&T to different configurations of continuous mining operation for an up to 170 m deep mine with a total annual output of 117 Mbcm. From the mine operatorÆs point-of-view, the quantity and skill level of staffing required for operation and maintenance are discussed in detail. The main conclusion of this paper is the larger the operation becomes and the longer the mine life is, the earlier fully continuous mining systems should be planned and implemented.CITATION:Schmitz, R, Durchholz, R and Heiertz, A-J, 2012. Change challenges for large open pit mines, in Proceedings Eighth Open Pit OperatorsÆ Conference , pp 103-110 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 18, 2012

By J. P. T. Kapusta

"The copper smelting industry faces increasingly stringent environmental regulations and must continue driving innovation to reduce energy usage in its production chain. With the coming of age of ‘bottom-blowing’ copper technologies in China over the last decade, much renewed attention has been brought to tuyere bath smelting for clean copper-making. Since bottom-blowing sonic injection was originally developed and implemented in steelmaking in the 1970s and lead smelting in the 1990s, the time seems appropriate to revisit the sonic injection concepts and dispel some myths. After reviewing the trends in the copper industry and providing a brief historical context of research and development related to sonic injection, the author presents a comparison of the main submerged tuyere bath smelting technologies, namely the Noranda Reactor (NR), the Teniente Converter (TC), and the Chinese Bottom-Blowing Smelting Furnace (SKS/BBS) for copper, and the Queneau-Schuhmann-Lurgi Reactor (QSL) for lead. The core of this article, however, consists of a brief description of the fundamental theories for sonic injection (jetting regime) and ‘sonic flow mapping’ to illustrate the relationship between the minimum tuyere back-pressure required to achieve sonic flow and the tuyere internal diameter. The article also offers a comparison between side- and bottom-blowing in jetting regime before concluding with the author’s vision of the new trend in submerged tuyere bath smelting. IntroductionIn the last decade, developments in the copper smelting industry have been driven by two key concepts: (1) increasing cleaner smelting capacity to meet the world’s growing copper demand, as illustrated in Figure 1, and (2) increasing process off-gas capture to comply with more stringent environmental regulations and abide by a corporate social responsibility ethic of a clean work environment (for smelter employees) and clean air (for families living around smelters). The copper smelting industry has also faced some major challenges in the last few decades, including (1) low treatment and refining charges (TC/RC or processing fees) impacting custom smelters, (2) lower concentrate quality and grades with higher levels of impurities (e.g. As and Hg), (3) higher processing and transportation costs due to the rising cost of energy, (4) restrictions in process intensification (tonnage oxygen usage) due to furnace integrity limits, and (5) scarcity of educated and trained personnel due to fewer metallurgists graduating from pyrometallurgical school programmes combined with a high retirement rate of skilled workers."

Nov 1, 2018

By Yoginder P. Chugh

Beginning in 2010, a scientifically-founded water spray system for continuous miners (CMs) has been in development at Southern Illinois University that significantly reduces respirable dust exposure for workers in the face area (patent pending). It includes engineered sprays around the cutting drum, outer bitring sprays, chassis sprays and side cutter boom sprays. About 3.6?4.5 m behind these sprays are additional sprays that cover the area between the CM chassis and the mine roof and ribs. The innovative spray system uses approximately the same volume of water as spray systems currently used on CMs and with similar operating pressures. The innovative spray system design also takes into consideration coal dust wettability. An Illinois mine decided to implement these concepts on a CM during the rebuild stage. Dust control performance of the rebuilt CM was evaluated using gravimetric dust sampling and real-time monitoring with multiple personal dust monitors. The average results based on gravimetric sampling of about 105 cuts show about 30 and 20% reduction in dust exposure for the miner operator and the haulage unit operator, respectively. Visibility in the mining areas was also significantly improved. Since the initial demonstration, the coal company has implemented the system on all of their operating CMs.

Aug 1, 2013

"In numerous meetings, conferences and discussions over the past year, the Conference Board of Canada has been impressed with the efforts of Canadian organizations to improve their competitive position. The attempt should be made to try to pull together and synthesize what has been heard. The topic of this paper, however, is even more daunting. The task is not only to analyze and discuss what is happening now, but also to look into the future—to the year 2000.The future seems to have an endless capacity for surprises, often unpleasant. This is one of the lessons learned in the twentieth century, particularly over the last 15 or so years.This paper covers three areas of managing in a changing com¬petitive environment: (1) the major global and domestic trends that will influence the ways in which Canadian organizations are managed (2) how Canadian companies are responding or will need to respond to these trends; and (3) the implications of the preced¬ing for human resource management and human resource professionals."

Jan 1, 1991

By E. B. REESER

EFFICIENCY is the foundation on which the prosperity of this Nation must be built. Your organization and the members thereof are constantly thinking of Gays and means whereby greater efficiency may be developed. It is often said that this Nation has become great because of its almost up limited supply of raw materials at low production 'costs. This was undoubtedly true in the earlier years but today we face an entirely different situation. We have learned that nature has been very generous in supplying all parts of the world with ample resources of various kinds to meet the demands. This applies to practically all commodities but for the purposes of this discussion, we will limit our remarks to petroleum.

Jan 1, 1931

By Morris Cohen

IT has been known for several years that in certain age-hardenable alloys precipitation of finely divided particles occurs simultaneously with the changes in physical properties; while, in other alloys, these changes take place prior to, or without any, precipitation. . The silver-copper alloys are generally considered to be the classical example of the first group, and the aluminum-copper alloys (duralumin) are typical of the second group. The two types of aging are explained by the precipitation theory and the knot theory respectively. ? It is well recognized now that these theories do not conflict with each other; the one used for a given aging system depends upon which way the alloy in question happens to age-harden. However, previous work on the aluminum-copper alloys1,2 has shown that if the aging temperature is raised sufficiently the hardening will be accompanied by actual precipitation. In fact, it is quite probable that all of the so-called knot-hardening alloys will harden by precipitation at elevated temperatures. Therefore, a combination of the knot and precip-itation theories is necessary to give a complete picture of the age-harden-ing of these alloys, and indicates that knot formation and precipitation are not independent processes. To test the generality of this concept, it is necessary to show that the alloys that commonly harden by precipitation will harden prior to precip¬itation if the aging temperature is sufficiently lowered. For this reason, it would be well to carefully re-examine the aging characteristics of the silver-copper alloys at aging temperatures somewhat below those used by previous investigators. If hardening can be detected prior to precipi¬tation in these alloys, it will lend great weight to the idea that knot forma-

Jan 1, 1936

By L. Li, K. Jiang

China is the world largest producer and consumer of zinc. Beijing General Research Institute of Mining and Metallurgy (BGRIMM) is one of major research and engineering institutes for nonferrous metallurgy in China. This paper (presentation) introduces the development of China’s zinc smelting industry, key production processes and main producers. The process research and development are reviewed as well as BGRIMM’s R&D activities in the last decade. China's refined zinc production was 4,829kt in 2012, accounting for 38.6% of world production. Primary production was 4,722kt. There are around 150 refined zinc producers in China. The traditional fluid bed roasting - leaching jarosite is still a dominant process for primary production and its production accounts for about 60% of country's total production. However, the direct leaching process is gaining market share. Seven direct leaching plants with 330kt/a capacity, including autoclave leaching and the Outotec direct leaching, have been put into production by June 2013. Five autoclave leaching projects with 590kt/a capacity are in the pipe line and are expected to be commissioned in 2014 and 2015. To cut the production cost and improve smelter economics, process research to optimize the production flow sheet, to improve the iron removal and to enhance the recovery of co-existed rare metals were carried out. The development trends of China’s zinc smelting industry from the view of cutting production cost, improving energy efficiency, increasing comprehensive utilization are discussed accordingly.

Jan 1, 2014

By G. L. Oldwright, F. K. Shelton, W. E. Keck

"INTRODUCTION Zinc must be of high grade to satisfy the present demand. Even when the amount of premium paid is small, the purer metal as the buyers' preference. The following specifications for spelter were taken from the American Society for Testing Materials for 1927, Part I, pane 524. (The specifications for 1930, p. 582, are tile same.)Another specification for zinc of a much higher grade than any of the above has been established lately by the same society. The committee on zinc die-casting (Proc. Am. Soc. Test. Mat., vol. 31, 1931, p. 263) reached the following, conclusions: I. ""That the purest of zinc is necessary to produce stable zinc-base die castings, and as a result requested specifications for zinc spelter .with total impurities not over 0.02 percent."" Their tests showed that the die castings made of the purest zinc had the least elongation and the greatest tensile strength, and exhibited the least changes with temperature.Still more far-reaching claims are made for the properties of zinc containing over 99.99 percent metal. Zinc foil, for instance, may someday be made as a common commercial product. It would seem likely that the demand for zinc of high grades rill continue and that even purer varieties may be desired. This demand fits in with the modern trend in manufacturing plants of reducing the number of variables to a minimum by using pure materials, and of controlling the processing of metals during their various stages of fabrication by mechanical means instead of by expert laborers."

Jun 1, 1933

By Ralph W. Barbaro

In many parts of the country, electric utilities use spot market coal to make up the difference between the amount of contract coal and the total amount burned. The utilities involved will normally have a structured contract for those companies supplying that spot coal. These contracts will often involve a pricing schedule with bonuses or penalties for coal above or below the specified coal quality goals. Normally, penalties will be assessed on the sulfur, ash, and other coal quality variables. This paper deals with some aspects of the pricing schedule of one of the eastern utilities that buys coal on the spot market. This utility has a number of plants that a supplier can attempt to supply through bidding procedures. The existence of the pricing schedule gives the supplier a number of different options. To the single-mine producer, options are available to send the coal to any demand site and to clean all, part, or none of the coal. In other words, he can ship to a number of different sites and can send different coal qualities to each site depending upon the level of preparation. In addition, the options to deliver blended coal to any given site will provide an additional level of complexity to the problem.

Jan 1, 1983

By M. Katzer

The effect of selective dispersants as wet grinding aids for ores is demonstrated on laboratory scale batch and continuous grinding equipment. A complete characterization of behavior is performed on a given ore to demonstrate correlations involving torque, % solids, net production rate, and slurry weight and volume loading. The relationship between such laboratory data and industrial scale testing results is very consistent.

Jan 1, 1979

By J. F. Martin, L. M. Melnick, R. Rapp, R. C. Takacs

Recent studies on the determination of hydrogen in steel have shown that the hot-extraction method for removing hydrogen from a solid sample is preferable to its removal from a molten sample by vacuum fusion or by fusion in vacuum with tin. A number of techniques are available, however, for determining the hydrogen so extracted. They include: thermal conductivity, gas chromatography, pressure measurement before and after catalytic oxidation of the hydrogen to water and removal of the water, and pressure measurement before and after diffusion of the hydrogen through a palladium membrane. These techniques have been evaluated on the basis of initial cost, maintenance, speed and accuracy of analysis, and applicable concentration range. The results of this study showed that the palladium-membrane technique is best suited for routine use. FOR some time investigators have been concerned with the origin, form, and effect of hydrogen in steel. In such stdies', the analysis for hydrogen constitutes one of the most important phases. It is quite apparent that the results for hydrogen concentrations in a given steel are dependent on the method of obtaining the sample, storage of the sample until analysis, preparation of the sample, and analysis of the sample, including all the facets inherent in the calibration and operation of an apparatus for gas analysis. There are a number of means available for determining hydrogen. This is a critical study of some of the more common techniques in use today. In most conventional melting and casting methods, hydrogen concentrations of 4 to 6 parts per million (ppm) in steel are quite common. Because of the undesirable effects of hydrogen on steel there has been increased use of techniques such as vacuum melting,' vacuum casting, and ladle-to-ladle stream degassing, which lower the hydrogen content to levels on the order of 1 to 2 ppm. Therefore, the method used for determining hydrogen in steel must be sensitive and precise. In any analytical procedure for gases in metals there are two distinct operations—the extraction of the gas from the metal and the analysis of the extracted gas. To extract the gas from the steel, three methods have been employed: 1) fusion of the sample with graphite at high temperature; 2) fusion with a flux, such as tin, at a lower temperature; and 3) extraction of the hydrogen from the solid sample at a temperature below the melting point of the steel. Fusion with graphite is the least-acceptable method. The blank in this method is higher and more variable than in either of the other two methods. The hydrogen fraction of the total gas composition usually is between 10 and 50 pct; thus, a larger analytical error is possible. The vacuum-tin fusion4 extraction of hydrogen is probably the most rapid method in use today; the extraction time is usually about 10 min. However, with this system a bake-out of the freshly charged tin for 2 hr is necessary and a change of crucible and a charge of fresh tin are required after each day of operation whether one or thirty samples have been analyzed. In addition, frequent checks of blank rates are required since CO and Na are continually being given up by the steel samples dissolved in the tin bath. The composition of the gas in this method lends itself readily to analysis; although the hydroge concentration may fall to as low as 50 pct, more often it is above 90 pct, thus allowing a more precise analysis (because of less interference from other gases). In 1940 ewell' published the hot-extraction method for extracting hydrogen from the solid sample, comparing analysis for hydrogen extracted at 600°C with similar analysis for the gas extracted at 1700°C by fusion with graphite. Good agreement for hydrogen was obtained between these two methods, provided sufficient time was allowed for extraction at the lower temperature. carsone obtained good results in his comparison of this hot-extraction method with vacuum-tin fusion. Subsequent work by Geller and sun7 and Hill and ohnson' has shown that steel samples should be heated to at least 800°C to effect the release not only of the diffusible hydrogen but also of the "residual" hydrogen that may be present as methane. Since the rate of evolution of hydrogene9l0 depends on such factors as sample size and composition, thermal history, and extent of cold work, a fixed extraction time is not possible. Extraction times of 30 min are normal, but 2 hr are not unusual. Induction or resistance heating may be used in the hot-extraction method. With resistance heating the

Jan 1, 1964