Search Documents

By Arnulf Muan, Carlos Landolt

Equilibria involving Cu-Pt alloys, copper oxides, and atmospheres of known ox2gen pressures have been determined at 1000' and 1200 C. The data obtained have been used to calculate activity-composition relations in the alloys. A moderate negative deviation from ideality is found. At high copper concentrations, the results of the present study are in good agreement with those of previous investigators, whereas at low copper concentrations the activities obtained in this investigation are slightly higher than those reported previously. The present study is part of a research program dealing with the determination of phase relations and thermodynamic properties of copper-containing systems at high temperatures. The information available for such systems is very scanty, particularly for copper oxides and their combinations with other oxide components. Platinum is commonly used as a container in studies of oxide equilibria. To evaluate quantitatively the extent of reaction between the oxide and the container, a knowledge of activity-composition relations in Cu-Pt alloys is necessary. Such data are not available for Cu-Pt alloys in the temperature range of particular interest in the present research program, and particularly for alloys low in copper. Studies of various aspects of the systems Cu-Pt and Cu-0 have been reported in previous literature. The system Cu-Pt is known1 to form a continuous solid-solution series above 812.C, whereas ordered phases are present in certain composition ranges at lower temperatures. Thermodynamic data for the system have been reviewed by Hultgren et al.,' who presented free energies of mixing at 65Oo C, mainly derived from electromotive force cell measurements by Weibke and Matthes.3 Enthalpies of mixing at 640°C have been obtained by Oriani and Murphy4 with liquid tin calorime-try. Their results differ considerably from those derived from the temperature dependence of the data of Weibke and Matthes. Thermodynamic data for the disordered alloys have been obtained by Assayag,5 and more recently by Schmahl and Minzl,6 by Myles and Darby,7 and by McCormack, Myers, and Saxer.8 The two latter sets of data7'' became available after the present study was completed. In the system Cu-0+ two oxides are stable at high temperatures, CuO and CuzO+ each having only minor deviations from stoichiometry. Equilibria in the liquidus temperature region of the system Cu2O-CuO have been studied by Roberts and systemsmyth,9'10CuzO-CuO by Vogel and ocher,I1 by Osterwald,12 and recently the the present authors.13 The system is of the eutectic type with a eutectic temperature of 1083.C The composition of the eutectic liquid corresponds to Xcu0 = °.44, and the oxygen pressure of the coexisting gas phase is Po2 = 0.55 atm.13 Equilibrium oxygen pressures for coexistence of solid CuO and solid Cu2O have been determined by Schmahl and Muller,l4 by Gadalla, Ford, and white,l5 by Bidwell,16 and recently by the present authors.13 There is reasonably good agreement among the various sets of data. Free energies of formation of Cu2O(s) from the elements have been derived by Tretyakov,17 by Bidwell,16 by Kiukkola and wagner,18 by Pal'guev and Neuimin," and by Steele and Alcock,20 There is particularly good agreement among the latter three1'-20 sets of data. THEORETICAL BASIS Consider a subsolidus isothermal section of the system Cu-Pt-0, as shown in Fig. 1. Two phase as-

Jan 1, 1970

By Toussaint LF

A brief history of the mineral sands industry is given from a radiation protection standpoint, with gamma radiation and inhalation of radioactive dust being identified as the main sources of radiation exposure of persons working in the plants. The principal sources of gamma radiation exposure are identified and the history of early bagging methods is discussed. The concept of ALARA is introduced and the impact of the "bulka bags" (and more effective monazite storage facilities) are detailed as illustrative examples of dose minimization, together with the requirements for the transport of monazite. The dose from radiation received from inhaled dust is dependent on a number of parameters of the dust, some of which are not well known. ICRP 30 (1978) makes recommendations relating to the intake of radionuclides by workers. These recommendations are discussed with respect to the inhalation of dust containing thorium. The possible pathways of radioactive material throughout the body are also described. The effect of having parameters that differ from ICRP 30 is discussed and suggestions are made relating to measurements that can be carried out to more accurately determine these parameters. Since in some instances the exposures to dust yield personal doses which may exceed the annual ICRP 30 based limits, it is necessary to define more accurately parameters of the dust so as to determine more accurately personal Doses.

Jan 1, 1986

By Arthur D. Silber

The economic success and growth of any metropolitan region depends on mobility. Today, mobility between New Jersey and New York is threatened by a transportation system that cannot meet 21st century travel demands. The transportation bottleneck created by the Hudson River threatens the viability of one of the world?s great centers of commerce and culture. Fortunately, there is a solution: The Access to the Region?s Core Mass Transit Tunnel. The US$8.7-billion Mass Tran-sit Tunnel?s (MTT) new two-track line will double commuter rail capacity under the Hudson and create a new, state-of-the-art cavern station in Midtown Manhattan, with wide platforms, high-speed escalators and other features to improve riders? travel experience. The capacity and other benefits of the MTT project will launch a new era of prosperity for the region, just as the Pennsylvania Railroad did almost 100 years ago when it built the existing two, single-track rail tunnels that now form the sole commuter rail link between New Jersey and New York. The existing tunnels run from North Bergen, NJ, under the Hudson River to Pennsylvania Station at 33rd Street in Manhattan. Construction on the MTT, the largest public works project in the United States, is scheduled to start this year and continue through 2017. The MTT is ready to go to construction thanks to a major commitment of financial, engineering, project management and other resources from NJ TRAN-SIT, New Jersey?s statewide mass transit agency, and the Port Authority of New York and New Jersey, a bistate agency that operates the Holland and Lincoln tunnels, the George Washington Bridge and other major transportation facilities in New York and New Jersey. The project is also strongly supported by the state governments of New York and New Jersey, as well as that of New York City. The MTT is New Jersey Governor Jon Corzine?s number one transportation priority.

Jan 1, 2009

By C. H. Mathewson

MICROSCOPIC rnetallography has been exploited quite well enough to bring about a very general understanding that the typical metal or alloy is composed of minute crystalline particles blended into a coherent microstructural mosaic. One does not have to be a specialist in metallography to realize that the properties of such an aggregate are essentially a summation in appropriate form of individual effects derived from the shape, size, placement or orientation and cohesive characteristics of the component particles. It is clearly of great importance to consider the various forms of discontinuity which may occur at the boundaries between these crystalline particles. When a number of particles each possessing the same orderly arrangement of atoms are brought together into a close-fitting system of purely haphazard contacts, not unlike a handful of snowflakes compacted into a snowball, the particles are said to possess random orientation. There are no generally accepted views concerning the arrangement of the atomis or the constitutional reaction between atoms where one crystal meets another, but these contact regions are characterized by strength rather than weakness and it is customary to require the presence of many rather than few boundaries in preparing metal for useful service. Under certain circumstances all of the particles in a metal may be nearly alike in orientation. Other general tendencies of orientation may be associated with particular forms of mechanical and thermal treatment. In contrast with these cases of fortuitous or statistical diversity of orientation, we often find adjacent particles united along a plane which possesses a grouping of atoms belonging equally well to both structures. This, of course, determines a fixed relationship between the two orientations and it is always possible to derive one from the other by some form of rotation or reflection prescribed by the symmetry of the crystal structure under consideration. Particles united in this manner are known as twin crystals although the term refers to the form of association rather than the number of individuals concerned.

By H. M. Morse

During the year 1942 there were 66 wildcats drilling in Mississippi. One cored in oil sand, the Macro Drilling Company's Longbell No. I in Clarke County, but as yet it has not succeeded in recovering the oil. These drillings broughi to light five salt domes, two of which had heavy oil showing; one drilled by the Magnolia Petroleum Co. in Warren County, and

Jan 1, 1943

By H. M. Morse

During the year 1942 there were 66 wildcats drilling in Mississippi. One cored in oil sand, the Macro Drilling Company's Longbell No. I in Clarke County, but as yet it has not succeeded in recovering the oil. These drillings broughi to light five salt domes, two of which had heavy oil showing; one drilled by the Magnolia Petroleum Co. in Warren County, and

Jan 1, 1943

By J. Leon-Torres, D. M. Stefanescu, P. A. Curreri, S. Sen

"Experiments were performed under terrestrial gravity (lg) and during parabolic flights (10·2 g) to study the solidification and macrosegregation patterns of Al-Cu alloys. Alloys having 2% and 5% Cu were solidified against a chill at two different cooling rates. Microscopic and Electron Microprobe characterization was used to produce rnicrostructural and macrosegregation maps.In all cases positive segregation occurred next to the chill because of the shrinkage flow, as expected. This positive segregation was higher in the low-g samples, apparently because of the higher heat transfer coefficient.A 2-D computational model was used to explain the experimental results. The continuum formulation was employed to describe the macroscopic transports of mass, energy, and momentum, associated with the solidification phenomena, for a two-phase system. The model considers that liquid flow is driven by thermal and solutal buoyancy, and by solidification shrinkage. The solidification event was divided into two stages. In the first one, the liquid containing freely moving equiaxed grains was described through the relative viscosity concept. In the second stage, when a fixed dendritic network was formed after dendritic coherency, the mushy zone was treated as a porous medium.The macrosegregation maps and the cooling curves obtained during experiments were used for validation of the solidification and segregation model. The model can explain the solidification and macrosegregation patterns and the differences between low- and high-gravity results."

Jan 1, 1999

By Dwight K. Smith

Fly ash as an additive for oil well cement was introduced to the oil industry by the Halliburton Company in 1949. Since its early usage in the Illinois area of the U. S., the total amount of fly ash pumped into wells has exceeded 30 million sacks, The advantages of using fly ash-portland cement mixtures in wells are fundamentally the same as for concrete except the conditions of placement and curing are variable and the nomenclature of properties are expressed somewhat differently. In some instances deep wells have been cemented with mixtures of fly ash and hydrated lime together with an activator which functions as a catalyst for setting. This fly ash-lime formula has many advantages for high temperature-pressure conditions found in wells.

Jan 1, 1968

By A. L. de Vegt

For the past ten years Paques has been engaged in the development and installation of treatment systems based on biotechnological processes to remove sulfur compounds from water, air and gaseous streams. Metal and sulfate can be removed from mine waters using two biological steps: 1. Sulfate reducing bacteria convert sulfate to hydrogen sulfide (H2S). The H2S reacts with the dissolved metals to form insoluble metal sulfide precipitates. 2. Sulfide oxidizing bacteria convert excess H2S to elemental sulfur. Paques has designed and installed a groundwater treatment system for the Budelco zinc refinery in the Netherlands to remove metals and sulfate as described above. The system has been operating since May 1992 treating a flow of 5000 m /d. A pilot plant started operation in November 1995 at Kennecott's Bingham Canyon Utah copper mine to develop the processes for metal and sulfate removal from groundwater and selective copper recovery from leach water. The principle of the biotechnological methods, full scale experience, and an overview of the test program at the copper mine are presented.

Jan 1, 1997

By Maureen A. McGuinness

Kidd Mine, an Xstrata Copper operation in Timmins, Ontario, operates a 400 t/h pastefill plant that provides paste backfill to stopes at the depth of 9000 ft. This paper will cover the operating practices of the pastefill plant both on surface and underground, highlighting tailings excavation, paste mix design and the pipe maintenance program. Kidd Mine, une opération d'Xstrata Copper à Timmins, Ontario, opère une usine de remblai d'une capacité de 400 t/h. Le réseau de distribution permet d'acheminer le remblai en pâte juste qu'à une profondeur de 9000 pi. Cet article couvrira le mode opératoire de l'usine de remblai tant à la surface que sous-terre en mettant l'emphase sur l'extraction des rejets miniers, la recette du remblai en pâte ainsi que le programme d'entretient du réseau de distribution.

Feb 1, 2008

A portable electronic instrument was developed which will measure change of longitudinal wave velocity with change of uniaxial stress in rock columns. The instrument is a solid-state device powered by nickel-cadmium batteries. It uses a probe of two piezo-electric crystals spaced inches apart to send and receive a pulse through a stressed rock. A one-inch cathode ray oscilloscope visually displays the longitudinal wave. A reference chart is used to find the stress. Laboratory results have indicated that the average stress on a sandstone column can be found to within 35 psi. The feasibility of using this instrument to determine stresses in mine pillars is to be studied. The instrument may be used to investigate physical properties of rock.

Jan 1, 1970

By J. Paraszczak

Underground metal mining involves many challenges. Economic slowdown, tough international competition and sometimes volatile metal prices put constant pressure on mine operators to increase productivity and to reduce production cost. At the same time, countries such as Canada, the United States and Australia are experiencing skilled labor shortages that might even stall development of certain mine projects. Furthermore, some stages of underground production take place in particularly hazardous environments where the safety and health of miners is at risk. Automation of some processes in underground mining is one of the promising avenues to alleviate some of these problems. Loading and haulage are among the most critical operations and areas where implementation of autonomous vehicles has been targeted. However, although health and safety issues are a primary driver to opt for automation, the latter should ensure an acceptable level of productivity and pro?tability. With this in mind, this article focuses on the factors affecting operational effectiveness of autonomous underground loading and haulage equipment and the means to maximize it.

By G. M. Potter, F. S. Wartman, M. D. Schmid

"In matte smelting of copper it has been established that the sulphpr present will combine with copper as long as the latter is present, and that thereafter it will combine with iron. The Cu-Fe ratio in the matte is determined by the Cu-S ratio, presumably owing to the much greater affinity of copper for sulphur or, expressed thermodynamically, the greater stability of copper sulphide in contact with silicate slag. Now, the work of Fournet and of Schütz, which is quoted in many elementary metallurgical texts, indicates that manganese ranks ahead of copper in its affinity for sulphur. Hence, we might expect that manganese could be concentrated from its admixture with iron. Compounds by matte smelting, and Rotts / has patented such a process. This greater affinity of manganese or sulphur is used to advantage in iron metallurgy, also, in which it is well-known that sulphur will combine with manganese and separate from metallic iron as manganese sulphide. Manganese sulphide,however, is quite soluble in silicate slags. 5/ The loss of manganese in slag in any attempted matte smelting is therefore great.If this solubility of manganese sulphide is slag is a physical one and the reaction MnO + FeS MnS + FeOIs substantially complete, then it might be expected that the addition of copper sulphide, which is almost entirety insoluble in slag, would serve to extract the manganese sulphide with the formation of a manganese-copper matte on the other hand, if an equilibrium exists in the above reaction, a copper sulphide layer would displace that equilibrium in one direction or the other, according to whether iron sulphide or manganese sulphide were more soluble in the matter layer."

May 1, 1937

By Joel Moskowitz, Jan Cermak

"New York City has unique geologic conditions which must be considered when designing pile foundations. Where shallow foundations are not feasible, the City's subsurface conditions require a variety of deep foundation systems, ranging from high capacity rock socketed piles, to piles end-bearing on bedrock, to friction piles bearing in alluvial or glacial deposits. Pile load testing is essential in confirming pile capacities as pile analyses include assumptions on soil and soil-pile response, and pile driving equipment. Load test results must be interpreted to estimate the long-term pile behavior. Except for lightly loaded driven piles, the New York City Building Code (the Code) requires that pile capacities be confirmed by static load testing. The Code provides the number of static load tests required, test procedures, and acceptance criteria. In the last few decades, methods other than static load testing have been developed including dynamic and rapid (pseudo-static) load tests. Recently, those methods have also been employed on several projects in New York City. The traditional approach to pile load testing in New York City is discussed herein including engineering involved in the analyses of test data with examples. In addition, several projects which included non-static load testing are discussed INTRODUCTIONPile load testing complements the subsurface information and pile design by providing further data on pile-soil interaction for the selected pile type and installation method. Traditional approaches to pile load testing in New York City involve static load tests to verify the design capacity of the piles for a given minimum factor of safety.In the late 1950's, Dr. Phillip C. Rutledge summarized his views on the philosophy of pile foundations in an unpublished, in-house document. He viewed pile foundations as good illustrations of pertinent and impertinent aspects of geotechnical engineering. In the analyses of piles he divided engineering into four general types:(a) Theoretical engineering in which decisions are made based on theoretical analyses. This represents ideal engineering, in which all factors affecting the pile design are well established or, at least, few simplifying assumptions with known effects on the analyses are made."

Jan 1, 2005

By R. W. Fountain, J. Chipman

THE solubility of nitrogen in iron and steel has been of considerable interest due to the role of nitrogen in strain-aging and in quench-aging. It is generally considered that quench-aging is the result of precipitation of carbide and nitride particles from supersaturated solid solution, while strain-aging results from the segregation of carbon and nitrogen atoms to dislocations.1-9 The rate of strain-aging is controlled primarily by the amount of carbon and nitrogen in solution and the temperature. In experiments on strain-aging of pure iron with only carbon or nitrogen as impurities, Fast" has shown that even after 40 hr at 50°C carbon did not give any strain-aging while

Jan 1, 1959

By Richard DePew, Robert J. Auber

The Westerly Storage Tunnel is a 25-foot diameter segmentally lined storage tunnel that is a major component of the Northeast Ohio Regional Sewer District's Project Clean Lake that is designed to capture 39 million gallons of untreated CSO overflows from entering Lake Erie. During the final stages of the project completion, a large-scale rock fallout incident occurred during the final lining installation operations at the down-stream end of the tunnel that extended beyond the designed primary support system. This paper outlines the level of coordination and collaboration between the Owner, Designer and Contractor to remediate the situation safely, quickly and effectively.

Jun 23, 2024

By J. B. Newson

This is one of a series of circulars dealing with mining methods, practices, and costs. It describes the method of sinking a shaft 60 inches in diameter with a shot drill, as employed at the Idaho Maryland mine, Grass Valley, Calif. The operation involved a great deal of experimentation in applying the shot-drill method to large bore drilling, overcoming mechanical and other difficulties which developed during sinking, and developing operating technique. Under such circumstances, costs are obviously higher than they would be after the pioneer work has been done, but even so, these actually obtained compare favorably with costs of sinking by more conventional methods. ACKNOWLEDGMENTS The authors are indebted to Mr. Errol McBoyle, president of the Idaho Maryland Mining Co., not only for his cooperation and advice during the sinking of this experimental shaft, but for permission to prepare this article for publication with the inclusion of cost data.

Jan 1, 1936

By Hamid Butt

Information Technology ??Advanced Information Technology is dramatically changing information flow within organizations. This enables employees to have information at their fingertips to make informed and prompt decisions. ??Real-time information allows timely analysis, which dramatically reduces cycle times, making organizations faster and more flexible. Business Challenges ??Continual growth of mining and Mine mobile fleet.??Increasing maintenance costs. ??Difficult to identify and troubleshoot equipment problems while equipment is operating. ??New equipment is increasing in complexity and cost. Therefore, each failure results in a greater impact to production and cost. ??Troubleshooting practice is reactive. ??Protect and optimize the use of mining assets to realize maximum business value. ??Maintenance and Operating information is not easily accessible ?no near real-time system that provides complete information.

May 1, 2006

By W. McCombe, G. Remple, L. Nightingale-Mercer

The McClean Lake Mill is located approximately 850 kilometres north of Saskatoon, Saskatchewan, Canada, and is operated by Orano Canada Inc. (Orano). The mill was designed to process high grade uranium ores, and a multi-year expansion was completed in 2014 to increase its production capacity to 24 Mlbs U3O8 per annum. The mill also underwent various upgrades to allow it to safely transition from processing low grade ores to high grade ores from the nearby Cigar Lake Mine. During the metallurgical test work on the Cigar Lake ores, it was identified that some ore zones of the deposit have a propensity to generate hydrogen gas during acid leaching. Hydrogen is a volatile and explosive gas, which poses obvious safety concerns in the leaching circuit. Uranium processing is further complicated by the fact that an oxidant in the form of oxygen gas or hydrogen peroxide is required to regenerate iron in the leach, which further increases the risk posed by hydrogen gas. During 2013 Orano and its consultant Hatch designed and engineered several novel upgrades to the leaching circuit to mitigate the risk of hydrogen gas evolution in the process. Best in class technology was utilized in addition to control and operating strategy changes to ensure the leaching circuit could be safely operated with ores that evolve hydrogen gas. This paper reviews the design concepts and modifications implemented on this unique and challenging project, and also provides an update on the operational reality of hydrogen in the circuit gained through five years of operational experience with hydrogen evolving ores.

Jan 1, 2020

By J. A. Sanchidrián, P. Segarra, S. Gómez

Blasting is a common activity in mining that can cause significant damage in the remaining rock mass. The most commonly used method for predicting vibrations is the Swedish or Holmberg-Persson approach. It is a simple and fast method that uses empirical formulation to estimate the vibration levels based on the explosive charge weight, distance to the source, and other parameters. However, it has limited accuracy and does not consider the effect of free surfaces or other boundary conditions. On the other hand, recently developed methods as the full-field solution (FFS) can provide more accurate predictions of vibrations due to excitations provoked by cylindrical columns of explosive, but the inclusion of free surfaces in analytical methods is a challenging problem. This paper presents a new approach that includes free surfaces in the FFS to predict vibrations analytically in the near-field. The main obstacle to including free surfaces in the FFS was the belief that the solution was non-decoupleable in P- and SV-waves separately. The Heelan's approach was previously used to decouple them, but it only provides valid radiation patterns in the far-field and does not account for intrinsic attenuation. In this paper, we address this problem successfully, allowing for the inclusion of free surfaces in the FFS.

Jan 1, 2024