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By M. C. Bluteau, G. P. Demopoulos

Arsenic reports in the effluents of many non-ferrous metallurgical operations. The production of scorodite, a crystalline ferric arsenate, is considered as an attractive option for the fixation of arsenic from aqueous effluents. However, scorodite solubility and long-term stability in the pH region of interest for tailings disposal have not been thoroughly investigated. In this study the long-term stability of scorodite in the pH 5 to 9 region and the mechanism of scorodite dissolution were studied. Construction of eh-pH diagrams indicated that scorodite stability is highly dependant on the nature (stability) of co-existing iron-hydroxide/oxyhydroxide. It was also found that when scorodite dissolves, a ferrihydrite phase having very small particles size (nano-scale) forms and that the growth and crystallization of this material are delayed by the presence of arsenate even under accelerated (75°C) ageing conditions. Around neutral pH and ambiant temperature (22°C) scorodite seems to reach an equilibrium with ferrihydrite after 48 weeks yielding soluble arsenic concentrations < 5 ppm.

Jan 1, 2004

By Richard P. Rothwell

In January last I published in the Engineering and Mining Journal a table giving, with a considerable degree of accuracy, the production of anthracite coal for the year 1874. At that time it mas impossible to give any correct estimate of the production of bituminous coal, for the returns I had been able to secure from such distant and scattered districts were not always forwarded punctually, and the work of .obtaining anything like a true estimate of the coal mined in districts from which I was unable to obtain official returns was both laborious and tedious. As will be seen from the detailed reports furnished herewith, I have succeeded in obtaining tolerably accurate returns of 20,093,704 tons; and upon careful revision by numerous well-informed local authorities, my first estimate of the amount of coal not officially returned to me has grown very considerably; indeed, as I get more information on the subject I find that our bituminous coal production greatly exceeds the amount we have been accustomed to hear it placed at, aggregating as it does, 26,465,704 tons. Mr. Andrew Roy, State Inspector of Mines for Ohio, has reported the production of Ohio at 4,168,445 tons, while his first estimates were but 3,820,000 tons; and similarly, in other cases, the more full the returns direct from the mines the more incorrect do I find all previous reports. I am able now to furnish, not an accurate statement, indeed, but by far the most full and reliable one that has yet been published of our coal production. The amount of labor involved in obtaining this admittedly imperfect report has been simply enormous. In the following tabular statement it will be perceived that Pennsylvania produces nearly one-half of all the bituminous coal mined

By J. Koskinen, P. Vanninen, T. Leskinen, A. Leppala

Continuous and accurate analysis of slurries has become a critical requirement in mineral processing. With on-stream assay data, automation procedures can be employed to obtain higher recovery and improved control of production. The Courier system was developed by Outokumpu Oy, taking advantage of mineral processing know-how, to provide means for achieving these objectives in the company&apos;s ore concentrator operations. It became evident, based on early experience with on-stream analysis, that the Courier should be a complete system to fulfill all functions of the analysis operation. The system includes equipment and techniques for primary sampling, sample preparation for assaying, and processing of data for final assay results. In addition, the on-line X-ray spectrometer unit was developed specifically for industrial use, incorporating a number of technical advances. A new system for converting spectrometric data to assays is based on a physical model programmed on a digital computer. The Courier system is furnished on a turn-key installation basis incorporating all elements needed for operation including calibration. The experience to date with the Courier system at the Pyhäsalmi concentrator is summarized. Reference is also made to recent results with installations at the Outokumpu and Vihanti concentrators.

Jan 1, 1972

By Y. G. Seredkin, A. A. Vasiliev, A. Y. Senchenko, A. V. Aksenov

"The valuable materials resulting from the processing of gold-bearing ores are often refractory to direct gold recovery through cyanidation. There are multiple methods for chemical liberation of gold prior to cyanidation such as pressure and biological oxidation as well as atmospheric oxidation which is typically used in combination with physical activation of material by ultrafine grinding such as the Albion ProcessTM. This paper will examine the data from process testworks carried out to estimate the efficiency of the Albion Process™ for the oxidation of materials with a wide composition range prior to cyanidation. The data will be compared to that obtained by direct cyanidation of the feed (without oxidation) and from the testing of pressure oxidation on the feed prior to cyanidation. Albion Process™ tests were conducted in Institute TOMS with participation of Glencore Technology Pty Ltd (Australia). Refractory concentrates obtained from the ores of several Russian and CIS deposits were used as feed for the testing. These concentrates were also subjected to a material composition study and testing using conventional recovery methods. The resulted test data make it possible to perform an integrated assessment of process properties for materials with different compositions, compare performance of various process flowsheets for the materials under study, and conclude on efficiency of Albion Process™ application for gold recovery from refractory materials different in their composition.INTRODUCTION It is often the case that gold ore concentrates are refractory to gold recovery by direct cyanidation. This refractory nature is as a rule attributable to fine gold dissemination in minerals, most often in pyrite and other sulphides, as well as to the increased amount of components impeding cyanide leaching of gold due to cyanide consumption and reducing process conditions. The refractoriness of the concentrates results in low gold recovery values when conventional cyanidation technology is used. In this context, various additional processes are applied to breakdown such refractory sulphide concentrates, i.e. mechanical breakdown (fine and ultrafine grinding), chemical breakdown (atmospheric oxidation, e.g. Leachox, acid-oxygen oxidation, pressure oxidation – POX, bacterial oxidation – BIOX), and thermochemical breakdown (various roasting methods). Such breakdown processes allow for increase in recovery of finely disseminated gold during the downstream cyanidation, however, their application is cost-intensive and does not always ensure economic benefit."

Jan 1, 2018

By Monica Pavlik, Thomas Wildeman

Water from the Forest Queen mine adit near Silverton, Colorado drains into a natural wetland. Because the pH of the water averages 5 and the iron concentration averages 18 mg/L, it was thought that the wetland might naturally treat the water. Of most concern with respect to the aquatic environment is zinc whose concentration averages 0.60 mg/L. Starting in October 1997, the surface waters, ground waters in the peat substrate, and the sediments in the wetland were sampled and analyzed four times over the course of four months. The adit water primarily remains as surface water where Fe, minor amounts of Al, and no Zn are removed. After the adit water enters the peat, then it is found that the pH rises to 5.8-6.5 and sulfate is reduced. The removal of Zn and A1 is caused by these two changes. However, Fe in its reduced state is quite soluble and may be remobilized in the reduced environment of the peat.

Jan 1, 2000

By Ali Akbar Mottahedi

It is known for a long time that the reaction of oxygen with carbon, silicon, iron and many other elements is exothermic. The heat of released from these kind of reactions can decrease the time of fusion of iron and steel for metallurgical purposes in the electrical arc furnaces. By decreasing the time of fusion, we increase the rate of process and the amount of production. So, by blowing oxygen in to the furnace, we can reduce the consumption of electricity and save cost. There are many problems in the procedure of the oxygen blowing. In this project, the theoretical aspect of the oxygen blowing and its side effects into the arc electric furnaces are investigated. An oxygen blowing system into the arc electrical furnace of metallurgy department of Machine Sazi factory was also set up. This process reduced the consumption of electricity up to 22% and increases the rate of production, by reducing tap ? to ? tap time up to 15%. In this project; all oxygen blowing systems and its control were set up.

Jan 1, 2006

By D. T. Kinard, A. A. Schweizer

An operational 9 meter (30-foot) high gold heap leach pile was investigated by excavating test pits up to 6 meters (20 feet) deep, obtaining bulk and relatively undisturbed thin wall drive samples, and observing the ore distribution patterns exposed in the test pit walls. The clayey ore is crushed, agglomerated with lime and cement, and deposited on the leach pads using a radial stacker. Laboratory tests performed included moisture-density, gradation, compaction, Atterberg limits, permeability (constant and falling head), and triaxial strength tests. Discussion is presented on the effects of agglomeration on the permeability and strength characteristics of the in-place ore. Also discussed is the effect of deposition of the ore using the radial stacker.

Jan 1, 1987

A combination field and office study of mining districts in Southwestern U.S.A., conducted in 1949 - 1950 by United Geophysical Company, embraced all of the essentials for a successful exploration project including factors such as geology water, transportation and many more. Perhaps the best known of several high priority areas chosen from the study was the Twin Buttes or Pima District in Arizona, however, the Turquoise District also ranked very high on this priority schedule. Following the discovery of the Pima Mine in 1951 and 1952, United initiated additional preliminary geological, geophysical, drilling and claim location work in the Turquoise District, but stopped shortly thereafter, when ASARCO began adjoining competetive activity. During the summer of 1957, sometime after ASARCO abandoned their claims in the area, Minerals Exploration Company began intensive exploration in the Courtland-Gleeson part of the District. This program was terminated in 1958. Later Bear Creek Mining Company supplemented the discovery endeavor with their own program during the period 1960 through 1962. This paper summarizes most of the geophysical work done by all of the groups except ASARCO and is intended to complement the recent paper "General Geology and Some Structural Features of the Courtland-Gleeson Area, Cochise County, Arizona" by Mr. Otis McRae of Bear Creek Mining Company.

Jan 1, 1966

By B. J. K. Sullivan, Brian Hornsby

INTRODUCTION Mount Isa Mines Ltd. operates a copper and silver- lead-zinc property at Mount Isa in northwest Queens- land, Australia. Mount Isa is located in the tropics at latitude 20°43&apos;S and longitude 139°30’E (Fig. 1). It is on the upper watershed of the Leichhardt River and at an elevation of 365 m above sea level. The average rain- fall is 360 mm/y, the greater part of which falls in January to March (the hot summer months). The mean summer temperature for these months is 30°C (dry bulb), with a maximum temperature of 43°C; the mean wet bulb temperature is 25°C with a maximum of 28°C. Mount Isa is located geologically towards the western edge of the Precambrian Shield of northwestern Queensland. This complex forms a north-tilting dissected peneplain which extends in the north-south direction for 640 km, with widths varying from 32 km to 190 km. The combination of differential erosion, regional strike, and steep dips has produced a corrugated topography of low north-south orientated hills and valleys. The field was first discovered in 1923 as a silver- lead-zinc field. Mount Isa Mines Ltd. was formed the following year and subsequently became the sole operating company on the field. Lead and copper ore have been mined and treated separately and simultaneously at Mount Isa since 1953. Intensive exploration commenced in 1954 and an active exploration program provided the justification for a series of production expansion programs in both silver- lead-zinc and copper (see Table 1 ). The most recent and largest production expansion program at Mount Isa commenced when a decision was reached in December 1969 calling for an increase in copper production from 100 000 to 150 000 t/y of blister copper. A major factor which influenced this decision was the substantial additions to the ore reserves in the so-called 1100 ore body which is a massive copper sulfide ore body with a known strike length of approximately 2500 m, a height which is variable up to 300 m, and a width of generally 300 m up to a maximum of 370 m (see Figs. 2 and 3). Host to the copper mineralization is a complex and variable rock generally called "silica dolomite." The ore body strikes 6.02 to 6.1 rad (345° to 350°), dips west between 0.78 and 1.13 rad (45° and 65°), and is truncated at depth by fault implaced basement rocks. It first occurs some 600 m below the surface and bottoms at about 1000 m below the surface. The unconfined compressive strength of the silica dolomite ore varies from 150 to 250 MPa, whereas the basement rocks, carbonaceous mylonite, slaty shale, buck quartz, and greenstone (a chloritic schist) are considerably weaker, varying in strength from 20 to 80 MPa. The distribution of mineralization within the ore body is variable, but can be considered as generally high grade at or just above the basement contact and diminishing towards the upper reaches of the ore body. The current

Jan 1, 1982

By Ritchie AS

The principles of chromatographic and electrophoretic separations are described in simple non-mathematical language. Brief details of the analytical procedures and of equipment are given. Partial analyses of rare earth elements in monazites from four localit- ies in New South Wales are compared with analyses from other localities. The presence of uranium in two of the monazites is recorded. The occurrence of rare earths in nature is outlined and its geological significance is indicated, A low capital cost method of analysis of rare earths in monazites is Introduced.

Jan 1, 1972

The 1980&apos;s has seen a revolution in gold mine developments in Australasia. We are witnessing a near ten fold increase in all phases of gold mine development ranging from exploration through to production. Ounces produced have yet to mirror this activity but have increased from a low point of 600,000 in 1980 to 1,800,000 ounces in 1985 in Australia alone. In 1980 the region had less than 10 gold mines, yet 14 new mines started production in 1985 and as many as 28 might start up in the next 18 months. Developing gold mines in the 1980&apos;s in Australasia has not been the easiest of jobs, yet the great number of new developments suggest that we have entered a new era that will rank in history along with the 1850&apos;s, 1890&apos;s and 1930&apos;s as high points.Within- our Australasian region two very distinctive styles of gold deposits are being discovered and developed. On the Australian mainland the new mines are in geologically old rocks and are mostly the low grade haloes surrounding worked out high grade deposits. Most are limited life open pit operations depending on recent innovative carbon-in-pulp or heap leach technology. In the Pacific Islands region the style of discoveries are geologically recent, large bulk-low-grade deposits often geologically analogous to porphyry copper deposits. These deposits are typically 10 to 20 times larger than those being proved up on the Australian mainland.

Jan 1, 1986

By R. H. King

Recently, the North American mining industry experienced a severe recession, forcing managers to take dramatic steps to cut costs and compete in the difficult international market. Some of these steps were closing mines, reducing work forces, renegotiating wage agreements, and purchasing the most productive equipment. Managers are now looking beyond these traditional avenues and are focusing more on advanced technology. In the present environment, it is essential that mine operators obtain the maximum use of capital expended on equipment. However, mine workers do not obtain maximum efficiency or productivity from equipment because the adverse and hazardous mine environment impedes human performance. Also, the efficient use of large, complex machines calls for levels of precision that many times are beyond the capability of even highly trained miners. A possible solution to this problem is a machine that mines without operators - autonomous mining machines. However, numerous problems confront researchers who are attempting to develop such equipment. Some mining tasks are not always composed of a series of cyclic motions readily performed by factory floor robots. In addition, mining takes place in the geological environment where conditions are highly variable and unpredictable. As a result, these machines must be able to sense and adapt to variations in operating tasks and environment. Considerable autonomous vehicle research has been completed, especially for defense. However, autonomous vehicle (AV) technology has not advanced to practical application yet (King, 1988) and mining research is necessary in areas: representing mining specific knowledge; •analyzing and reasoning about sensor data in the mining environment; and •discovering completely new mining methods or new approaches to existing methods that become apparent when we remove the constraints imposed by the necessity of human operators. A specific machine, the LHD, can be used to show the problems for researchers who are attempting to develop autonomous machines for mining. This author chose the LHD because it can borrow concepts developed for autonomous navigation by military programs. But considerable mining research is also required. Furthermore, studies done at the Henderson mine, in Colorado, show autonomous LHD &apos;s promise cost and safety benefits (King, 1988). At Henderson, LHDs load ore from draw points, tram to an ore pass, dump and return, or switch to another draw point. An autonomous LHD must sense vehicle position along the route, relate sensor data to stored-map information, to determine location, follow drift center lines, plan paths between dump position and initiate appropriate control commands, sense vehicle operating status and vehicle health, key on features or targets for special tasks like high speed turns, perform end of travel tasks (loading and dumping), and detect and avoid obstacles. These goals are similar to those for shuttle cars, trucks, and front-end loaders. Therefore, much of the technology is transferable. Each Henderson LHD extracts six to 40 dippers from each of a series of draw points. The LHD transports the ore to an ore pass within 55 m (180 ft) of the draw point, making the longest round trip 110 m (360 ft). The LHDs have very fast hydraulic dumping and loading systems that reduce the round trip cycle to less than one minute. Even though the LHD is capable of 500 trips per shift, the average production is 300 dippers. Man trip and lunch reduce available operating time to 6.5 hours per shift. Mucking difficulties (setting large boulders aside), operator breaks for activities like talking shop, and cleaning and smoothing roads further reduce operating time. Supervised autonomy can reduce the number of operating units by increasing operating time per shift since computer controlled machines can operate during lunch and between shifts and reduce operator errors. If dippers per shift increase from 300 to 350 (long-range goals are 500 dippers per shift), constant production requires only 10 operating LHDs and two spares. Manpower requirements drop from 24 to four by controlling five machines from one workstation. A review of technology available from the Autonomous Land Vehicle, the Advanced Ground Vehicle Technology, the Ground Surveillance Robot, and other programs, show the following differences between others work and mining industry needs: •If we focus initially on mobile haulage vehicles, we can navigate from a map. We do not need to explore. •We can modify the environment to reduce the navigation requirements. •We have a harsher environment than any of the research programs have encountered. •Our equipment must operate faster and more precisely than present AVs. •Our equipment must operate reliably over long periods of time. •We must have better onboard machine health monitoring and diagnostics. •The AV programs do not address geosensing. •The major AV programs are not cost-effective. For example, we cannot afford the computer power for robust image processing, yet. To computer control an LHD, we must replace the guidance and monitoring skills of experienced operators with sensors, computing hardware, interfaces, and several software mod¬ules. Experienced operators avoid collisions and load efficiently in piles that may contain oversize muck. Collision avoidance without an operator requires sensing all obstacles in the draw

Jan 1, 1991

By James L. Whitlock

Biological treatment of mining and industrial effluents reached full scale commercialization around 1980. These proven, low cost, technologies have been limited in application due to a number of factors, including extended periods of time and cost required for pilot testing as compared to chemical treatment technologies, lack of biological expertise in metallurgical personnel, longer treatment periods in some cases, and performance failures based on improper application. Renewed interest in biological treatment technologies is being driven by permits with lower effluent concentration criteria, permits with bioassay evaluation, the need to remove thiocyanate, nitrates, sulfates and? other parameters. Chemical treatment processes, in general, have not been able to meet these present requirements, or require elaborate? combinations of processes, in terms of effluent quality and treatment economics. This paper addresses biologieal treatment of mining and industrial waste waters and selected recent advances in these technologies. The future looks very bright for application of these low capital and operating cost technologies,

Jan 1, 1998

By Leland E. Paulson

The Grand Forks Energy Research Center and Commonwealth Edison of Chicago jointly conducted tests in which 400 tons each of subbituminous coal and lignite were dried in a commercial scale dryer, oil sprayed and cooled, then shipped in open-top rail cars from Pekin, IL to Grand Forks, ND and stockpiled. Cars containing raw coal and dried coal that had not been oil sprayed were also transported for comparative purposes. The tests were conducted in August and November of 1974. The subbituminous coal was dried from 26 to 16 pct moisture and the heating value was upgraded from 8,420 to 9,650 Btu/lb. The lignite was dried from 39 to 22 pct moisture and its heating value was increased from 6,420 to 8,300 Btu/lb. Before loading subbituminous coal was cooled to 115° F and sprayed with oil at a rate of from 2 to 6 gal/ton. Similarly, lignite was cooled to 85° F and oil sprayed at rates of from 1 to 2 gal/ton. Both shipments arrived in Grand Forks with a minimum of difficulty. The subbituminous coal was subjected to 2 inches of rain during transit with no change in average moisture content. The cars containing dried and oil treated coal had less material lost to wind than either cars containing raw or untreated dried coal. With both dried lignite and subbitnminous shipments, a moderate increase in temperature was measured during transit. With the subbituminous shipments, ignition occurred near poorly fitted bottom dump doors, but was limited to a very small area. The dried lignite was shipped when ambient temperatures were below freezing, and frozen coal was noted around the edge of the car. At Grand Forks, the coal was stockpiled using proven techniques and has remained stable to this date.

Jan 1, 1975

By Carl Havemann

[PAPER PRESENTED AT THE 8thINTERNATIONAL CORROSION CONFERENCE HELD AT THE SA NATIONAL MUSEUM OF MILITARY HISTORY, SAXONWOLD JOHANNESBURG DURING 14-15 NOVEMBER, 2006.]

Jan 1, 2006

Prior to 1975, most geochemical drainage surveys for gold were based on analyses for pathfinder elements, such as As and Cu, rather than direct analysis for gold, for two reasons. Firstly, analytical methods lacked the required sensitivity and precision to determine gold abundance at background levels in stream sediments (usually in the range 1 - 10 ppb). Direct analysis was also inhibited by concern about the potential for gross sampling error, brought about by the dispersion of gold as rare discrete particles of the extremely dense native metal. This sampling error, commonly termed the &apos;nugget effect&apos; has two components: erratic distribution of the element within the stream environment, related to hydraulic factors, and the difficulty in taking representative samples, both in the field and later in sub-sampling for analysis. In more recent years the collection of very large samples was commonly advocated to overcome the sampling problem (Hams, 1982; Nichol, 1986).Two methods have been widely used to evaluate the gold content of bulk samples (Elliott and Towsey, 1989). The preparation and analysis of heavy mineral concentrates has in recent years been largely superseded by the leaching of gold contained in bulk samples by cyanide, commonly termed the BLEG (Bulk Leach Extractable Gold) or BCL (Bulk Cyanide Leach) methods. The terms BLEG and BCL are essentially interchangeable and the latter will be adopted for the remainder of this paper. The strengths and weaknesses of these two techniques were compared with conventional total gold analysis on fine fraction (

Jan 1, 1976

By Egbert Burchardt

The challenge of "ore bodies getting steadily harder and lower in grade" was brought to light during the first oil crisis in the 70&apos;s. Shortly afterwards, HPGRs appeared on the scene with the promise of saving energy. This combined with developments in wear protection for the rolls ushered in a period of trade-off studies that considered the HPGR as an option to improve project economics or to even make projects feasible at all. Since then, applications of HPGRs at Cerro Verde (Freeport), PTFI Grasberg (Freeport), Mogalakwena (Anglo Platinum), Tarkwa (Goldfields), Boddington (Newmont), Penasquito (Goldcorp), and others have contributed to the creation of a formidable basket of operating experience. Collected through years of successful operation, this information has been used to validate design criteria, scale-up factors and establishing a clearer picture of what "to do" and what "not to do". This paper compares results from various mining operations using HPGRs in their processing plants. Some of the lessons learnt in different operating environments are reviewed in order to support proper implementation and operation of HPGR&apos;s. Some of the development programs that have been initiated to improve wear life of the tyres and to reduce overall operating costs are reviewed. It is timely to summarize today?s experience and analyse its implications for existing and new operations.

Jan 1, 2012

By D Johansson, A Nordqvist, D Mihaylov, N Petropoulos, M Wimmer

The flowability of the caved rock masses in the sublevel caving (SLC) mining method is of great importance. During the blasting process of a SLC-ring, the caved rock mass in front of the ring is compacted. As a result of this compaction, the mechanical properties of the fractured rock masses change, for example void ratio, angle of internal friction and structure of the compacted material. The changed mechanical properties of caved rock mass and recent blasted material can influence the mobility of the material, which could result in blockage of the flow path of the material. The identification of the involved mechanisms in this process can be done after a series of tests in different scales. However, there is no available equipment for dynamic measurements during blasting, ie velocity and displacement of the burden and in the caved masses. This study focuses on the development and laboratory evaluation of a measuring system that can be installed in a borehole. The first trial was carried out in a pillar, where two blastholes had been drilled (9.5 m) parallel with the drift and two measuring holes (16.5 m) were perpendicular to the drift. Two measuring systems were installed in the measuring holes. Some preliminary tests were carried out to find suitable initiation procedures for the emulsion explosive. Applicability and robustness of the developed measuring system were also evaluated. In addition to these tests, an expandable cement mixture was developed to firmly anchor the measuring systems in the boreholes. The measuring system consists of an anchor, armoured cable in a pulling tube and a protective case. The anchor is equipped with uniaxial and triaxial accelerometers. A potentiometric measuring system for displacement up to 2 m is installed at the end of the pulling tube and connected to an extendable spiral cable. All sensors are connected to a data acquisition system (DAS). Both measuring systems have their own DAS to acquire data in case of failure of one of the systems. The measuring system was tested in laboratory conditions with impact velocity up to 10 m/s. It was proven to be functional and gave reliable results.CITATION:Petropoulos, N, Mihaylov, D, Johansson, D, Wimmer, M and Nordqvist, A, 2015. Design of equipment for dynamic burden measurements, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 493–500 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By R. G. Davies

WeERTMANI has shown that the high temperature steady state creep rate, i, in lead and indium-base alloys obeys an equation of the form where AH is the activation energy, o the applied stress, n the stress exponent, and R and T have their usual meanings. He observed a variation in n from 4.5 for pure metals to 3 for concentrated alloys, which he interpreted as due to Change in creep mechanism from the climb of dislocations in pure metals to a micro-creep mechanism in the alloys. The Cottrell-Jaswon microcreep mechanism of the moving dislocation taking its impurity atmosphere with it was considered to be the most likely process, although short-range order and the segregation of solute atoms to a stacking fault will also give a stress exponent of 3. Steady state creep has been investigated in a Au - 27 at. pct Cu alloy at temperatures above 1/2 TIM where TIM the absolute melting temperature. As the oxidation resistance of this alloy is excellent all tests were carried out in air with a furnace built to give a temperature variation of less than 1°C along the 60 mm gage length. A lever-arm arrangement applied the stress with a load being adjusted between each creep test to maintain a constant stress. As each test produced less than 0.5 pct creep strain, the variation in stress during the test was negligible. The creep strain was measured by a transducer at the end of one of the alloy-steel grips, with the out of balance potential being finally recorded on a variable speed chart recorder. A typical creep curve is shown in Fig. 1. The results, Fig. 2, confirm that n is nearer to 3 than to 4.5; the creep mechanism could be any of those given above. The activation energy, AH, which is independent of stress, is consistent with a diffusion controlled process; the activation energies for the self-diffusion of gold and for the diffusion of gold into Copper are both -45 kcal per ml., There is now considerable evidence, that, when the steady state creep is dependent upon diffusion, irrespective of the actual creep mechanism, the activation energy is independent of the stress. The author would like to acknowledge the financial assistance provided by the International Atomic Energy Agency, Vienna, and the Argentine Atomic Energy Commission.

Jan 1, 1962

By Frederick H. Williams

The object of this paper is to bring to the attention of those members of the Institute who are interested in the subject, a method for the estimation of manganese, which has been frequently used in the labratory of the Vulcan Steel Works during he last eight months, and which is deemed worthy of more general use. It is simply an adaptation of well-known processes, for the purpose of determining this element in pig iron and steel. In general, the method consists in precipitating the manganese as binoxide dissolving in dilute sulphuric acid in the presence of an excess of a standardized solution of oxalic acid, and titrating the remainder of the oxalic acid left unoxidized with permanganate of potash. For this method, therefore, two standardized solutions are needed, viz., a permanganate solution and an oxalic acid solution. The permanganate solution is made so that 1 C.C. is equivalent to 1 mgr. of iron. By using so weak a solution and keeping tile bulk of the solution to be titrated down to 75 C.C. or a little leas, the accuracy of the process is greatly increased, since the final reaction is almost if not quite as sharp as if a stronger solution were used. The oxalic acid may be of almost any strength, but if made so that 1 c.c. requires 3 O.C. of the permanganate to oxidize it, it will auswer well. The process is then, as follows: from 1 to 2 grams of. pig iron or steel ate dissolved in 40 to 50 C.C. of concentrated nitric acid with the aid of heat. As soon as solution is erected, in the awe of steel, add gradually and cautiously, the solution being kept boiling, sufficient pulverized chlorate of potash to precipitate the manganese as binoxide. Two grams will be a great abundance. In the case of pig iron, first remove the carbon and silica by filtering the solution through asbestos and washing with concentrated nitric acid. Filter the strong acid solution in which the binoxide has been precipitated, through asbestos with the aid of the filter pump. When it has entirely passed through wash well with water. Blow the contents of the funnel into the beaker in which the precipitation was made and rinse the funnel with a little water.

Jan 1, 1882