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By D Chappell

Coromandel Peninsula gold mineralisation has an epithermal style which involves extensive alteration of host rocks and addition of pyrite over large volumes of rock. These altered rocks therefore have high potential for generating acid rock drainage. Natural acid groundwater discharges occur in altered rocks, but not in propylitically altered rock. There is little calcite available in mineralised rocks to neutralise this acid. In contrast, the mesothermal veins of the Otago Schist cause little alteration of the host rock, and that alteration has similar mineralogy to the host rock. Calcite is a common mineral in host and mineralised zones, and sulphides are generally subordinate. Hence acidification of Otago rocks is unlikely. This lack of acidification in Otago facilitates arsenic mobility in solution, up to hundreds of ppm. Arsenic is insoluble under acidic conditions in the Coromandel. Base metals are soluble under acidic conditions of the Coromandel, but they are immobilised by adsorption on to the widespread clay minerals where the solutions are neutralised. Base metals are generally immobile in Otago, but when they are mobilised, adsorption is less effectiveas an attenuation mechanism because clay minerals are rare.

Jan 1, 1998

On July 1, 1969, the Explosives Research Center merged with the Health and Safety Research and Testing Center to form the Safety Research Center, with facilities at Pittsburgh and Bruceton, Pa. Subsequently, passage in December of the Federal Coal Mine Health and Safety Act of 1969 (Public Law 91-173) had a major influence on the activities of the new center. These activities were conducted under two main programs, Coal Mine Safety Research and Explosives Research. The Coal Mine Safety Research program was concerned primarily with two categories of hazards: health-related hazards associated with the mine environment, due to such factors as respirable dust, toxic gases and vapors, and excessive noise; and accidents due to mine fires, explosions, and roof falls.

Jan 1, 1972

By N. E. Rogen, N. J. Grant

WHILE direct measurements of the growth of precipitate particles during aging is of fundamental value, few such measurements have been made. Direct measurements by means of optical or electron-microscopy and X-ray techniques are preferred, however, many of the aging studies have been based on indirect methods such as electrical resistivity and hardness. Because of the minute size of most precipitate particles (less than 1000A) the light microscope is of limited use while electron microscopy is subject to slowness, etching problems and consequent resolution problems. It is fortunate that alloys of the Nimonic type, based on Ni-Cr-Ti-Al, lend themselves to accurate and relatively easy particle size measurements. With proper balance of titanium and aluminum, the only aging precipitate is the gamma prime (r') Ni3,(Al, Ti)2 phase and this phase is the basis of the high-temperature strength of these allos.3-6 The Ni3(Al, Ti) phase is a face-centered-cubic, ordered structure with nickel atoms occupying the cube faces. Titanium atoms can replace three out of every five aluminum atoms and when substituting do so preferentially.2 Electron microscopy has shown that during aging of most of the commercial alloys of this type, precipitate particles are unusually uniform in size and distribution, and that the volume of (r') phase is large (20 pct).4,7 The aim of this investigation was to measure the growth of (y') phase during aging. In so doing, it was hoped that a clearer understanding of the aging process would be attained. X-ray line broadening was used as the measure of precipitate particle size. This technique was selected because it can measure and average the diameter of thousands of particles in one operation. The variations in hardness and matrix lattice parameter with aging were also studied and related to the particle size. EXPERIMENTAL PROCEDURE An alloy of the following composition was studied: Cr Ti A1 C Ni Wt pct 20.71 2.98 1.43 0.04 bal. At. pct 22.06 3.47 2.95 0.18 bal. The alloy, a 15- lb vacuum melt, was forged to 1/2-in. diam at a temperature of 1900" to 2200°F; was solution heat treated for 4 hr at 2000°F and water quenched; and was then aged in various ways. The ASTM grain size was 4 to 5. No (7') phase could be detected by X-ray analysis after solution treatment and electrolytic extraction. Aging was performed on 2-in. long specimens at 1400°, 1500°, and 1600°F for increasing times. One-half inch sections were removed after each time increment and were then electropolished in a solution of H3P04 saturated with chromium trioxide at a potential of 30 v and rectified with a tantalum electrode. Rockwell hardness measurements were taken using one side of the polished specimen. Matrix lattice parameter determinations were made on the other side using filtered chromium radiation references with the position of the (220) line of a silicon standard. To enable the precipitate particles of the (y') phase to be measured using X-ray line broadening techniques, it is first necessary to separate and concentrate this phase by electrolytic extraction. Extraction is necessary because the difference between matrix and precipitate lattice parameters is only approximately 0.5 pct and intensities of.the (y') phase lines are very weak relative to those of the matrix. The extraction techniques employed have been described before and found to produce a reasonably quantitative separation.398 A water solution of 15 pct H3Po4 is used at a current density of 0.5 amp per sq in. at 6 v. The precipitate particles are separated from the liquor by centrifuging and decanting and are then washed, dried and repowdered. A plot of the X-ray intensity vs diffraction angle for the (111) line of the precipitate particles was used as a measure of particle size. The intensity curve approximated the shape of Gaussian distribution function and its breadth was measured at the half height. The (220) line of a silicon standard was used to correct the measured line breadth for instrumental and other broadening errors. The Scherrer formula was used to calculate particle

Jan 1, 1961

By Y. Rao, Y. Huang, G. Wang, W. Liu

The properties and deterioration in strength of cemented tailings backfill (CTB )in the underground acidic environment under oxidizing conditions were studied. X-ray diffraction analysis and scanning electron microscopy of the surface of the CTB was carried out, and the sulphuric acid corrosion mechanism elucidated. The properties tested included compressive strength, elastic modulus, cohesion, internal friction angle, variation in the hydrogen ion concentration, and stress-strain relationship in different corrosion periods. The damage model of the CTB was established considering the effects of parameters such as corrosion time and strain on the damage evolution. It was found that the compressive strength, elastic modulus, cohesion (binder effect), and internal friction angle increased at first and then decreased with exposure time. In the long term, the peak stress decreased with corrosion time while the peak strain increased; elastic modulus, and deformation modulus also decreased. The damage caused by corrosion and by load were related by means of a mathematical model, which revealed the relationships between sulphuric attack, load, and damage to backfill in complex underground environments. During corrosion, the expansion of gypsum and ettringite caused microfractures in the CTB. With increasing corrosion time, micro-cracks developed and proliferated. The mechanism of corrosion damage was found to be the dissolution of hydrogen ions and a sulphate ion reaction that produces an expansive substance, resulting in deterioration of the strength of CTB.

Jun 1, 2021

By Alan Mayton, Bertrand Valero, Farid Amirouche

Handling of heavy vehicles such as tractors, trucks and buses require a large roll stiffness which causes large high accelerations at the seat level during impacts. To provide comfort and minimize the energy transfer from the chassis and the seat a pneumatic active seat suspension is proposed. An active seat suspension design and control algorithm under development at the University of Illinois at Chicago, UIC, is being developed and tested. Preliminary results are presented in this paper. The design of a passive suspension typically consists of optimizing the value of two parameters: the stiffness and the damping of the suspension. The general dynamic performance of the suspension is limited to the conditions under which these parameters were obtained. A change in the input conditions might lead to poor suspension and an amplification of the vibration transmitted to the body. The focus of this paper is a robust, semi-active suspension system with a variable controlled damping and using the body response an index measure to minimize the acceleration at the interface of the seat and operator. A summary of existing suspensions, such as MR and ER fluids, and spring loaded and dual valve shock absorbent will be discussed to highlight the need of a semi-active pneumatic suspension system design. Methods A model of the proposed suspension was developed in MATLB (Simulink) and different control strategies for the valve position in relation to the cylinder pressure tested. The effects of stiffening and softening resulting from pressure changes in the cylinder were examined. The vertical accelerations of the seat was computed for different control strategies and configurations of the suspension and compared to the response of a passive seat suspension. A lump -mass model was created to represent the human body including the head, the upper, middle and lower torso as well as the legs. The connective forces between body segments were modeled through modal analysis techniques from previous experiments at the Vehicle Technology Laboratory. ISO standards and absorbed power were used to evaluate the different configuration of the seat suspension system in relation to the dynamic response of the operator. Results Initial results of the semi-active suspension system show a significant reduction in the RMS value of the acceleration of the seat. A reduction of the total absorbed power by the operator is expected to provide an insight into the control strategies adapted in the active suspension.

Jan 6, 2006

By U König, N Norberg

To cope with varying raw material qualities and increasing prices for energy, a more frequent and accurate monitoring of the processing of iron ore became the focus in sinter plant operations. Traditionally, quality control in iron producing industries has relied on time-consuming wet chemistry or the analysis of the elemental composition. The mineralogy of a sinter that defines the properties and behaviour in the blast furnace is often not frequently monitored. One fast method to analyse the mineralogical composition of iron sinter, raw mixtures and iron ores is X-ray diffraction (XRD). Recently statistical methods such as similarity analysis or partial least square regression (PLSR) in combination with XRD raw data has become more and more popular in handling large amounts of data and correlating process-relevant parameters directly with an XRD measurement. PLSR can be used to correlate process parameters directly from the XRD pattern without investigating the mineral content. Hidden information that is present in the measurement but not determined with traditional methods can be used to improve the characterisation of the analysed materials.CITATION:König, U and Norberg, N, 2017. Iron sinter process control using X-ray diffraction – part : monitoring of low temperature degradation, in Proceedings Iron Ore 2017, pp 75–78 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

The Porgera gold deposit is an epithermal gold base-metal deposit located in the Enga Province of Papua New Guinea. Gold-silver-sphalerite-galena-pyrite mineralisation is related to stocks and dykes of dioritic composition which have intruded a series of folded marine sediments, mainly shales and siltstones, often with calcareous and carbonaceous horizons, of middle Jurassic to middle Eocene age. The most intensely mineralised zone is at Waruwari Hill, where the mineralisation occurs predominantly as massive mixed sulphide veins, and less frequently as quartz-chlorite veins and as disseminations. Mineralisation occurs in all rock types and several phases of mineralisation have been recognised.

Jan 1, 1980

By A. Boulton

Low molecular weight synthetic polymers substituted with hydroxyl, carboxyl or sulfonate functional groups were used to improve the flotation separation of zinc or copper sulfide minerals from iron sulfide gangue minerals in three massive sulfide ores of different mineral composition. These polymers produced significant improvements in zinc or copper grades as a result of a selective depression of iron sulfide minerals. It was shown that this selectivity was the result of preferential adsorption of the polymer on the surface of the iron sulfide minerals. The different types of interaction between the functional group on the polymers and the sulfide mineral surfaces could explain the trends observed in the flotation results.

Jan 1, 2003

By C J. N Wilson

The central Taupo Volcanic Zone is a region of intense Quaternary silicic volcanism accompanying rapid crustal extension. Modem central TVZ is the most frequently active and productive silicic volcanic system on Earth, erupting rhyolite at c.0.28 m3 s-1. The rhyolites show no major compositional changes with time, but the total extent of magma chamber zonation has changed with the advent of rifting and crustal extension at c.0.7 Ma. At least 34 caldera-forming ignimbrite eruptions have formed a complex sequence of relatively short-lived, nested and/or overlapping volcanic centres in central TVZ. Taupo contrasts with other large silicic magmatic systems in the exceptionally high frequency, but small size, of caldera forming eruptions. This contrast reflects the thin, rifted nature of the TVZ crust that precludes the development of long term magmatic cycles at Taupo. Within central TVZ, non-rhyolitic compositions have been erupted apparently irregularly in time and space; in particular there is no evidence for a geographic separation of basalts from andesites. TVZ is a rifted arc, but its segmented nature, high thermal flux and voluminous rhyolitic volcanism make it unique on Earth.

Jan 1, 1995

By Louis J. Cabri, Donald Hoy

"Samples with contrasting gold mineralization were studied quantitatively prior to metallurgical tests. The AD samples are coarser-grained and characterized by abundant Sb minerals (jamesonite, berthierite, stibnite). The finer-grained MW sample has abundant pyrite and pyrrhotite, with arsenopyrite and galena next in abundance. A large number of gold mineral particles were determined by SEM investigation of hydroseparation concentrates, ranging from 150 to 597 per sample. The grain-size distribution of the gold minerals shows evidence of bimodal grain-size distributions (volume %), with the coarse fraction being most significant in sample MW-1 (maximum ECD=308µm). The coarsest gold minerals in the AD samples range from 139µm to 281µm ECD.The deportment of gold minerals is as electrum, aurostibite, native gold, and a possible new mineral (AuNiSb4). Gold also occurs in nisbite. The gold minerals are dominated by electrum in three samples and aurostibite is next in abundance. The major gold minerals are probably representative of three stages of gold mineralization. The first stage is represented by electrum, which is partly to completely replaced by Sb-rich mineralization forming aurostibite, and the last stage is native gold, often occurring as rims on one or the other earlier gold mineral. The gold minerals are strongly associated with sulphides in the AD samples (55 to 60 vol.%). At the grind used for the hydroseparation the liberated gold mineral quantity (volume %) is also significant, ranging from 65% for sample MW-1 to 30 to 37% for the AD samples.INTRODUCTIONThe Clarence Stream deposit is located 70 km south-southwest of Fredericton and 25 km northnorthwest of St. George, south-western New Brunswick, near the international boundary with Maine (Fig. 1)."

Jan 1, 2007

By He Zhi-jun, Ning Zhe, Pang Qing-hai, Zhang Jun-hong, Zhan Wen-long

In this study, Raman spectroscopy was utilized to investigate the evolution of char structure in pulverized coal (PC) during microwave irradiation. The results indicated that though microwave treatment was carried out at low powers of 132W or 264W, significant variation in char structure was still observed. Char structure turned out to be more irregular firstly under microwave irradiation. However, char structure of superior regularity was obtained with the extension of irradiation time. It can be conclude that short time microwave treatment may facilitate the chemical activity of coal, while long time microwave irradiation on PC may deteriorate its combustion or pyrolysis property.

Jan 1, 2016

By Roy M. Schnabel

The Fashion Island Boulevard Bridge over the Marina Lagoon in San Mateo, California is an eight span precast, prestressed concrete girder bridge. It is approximately 495 feet in length and 61 feet in width. It is supported on 36" diameter octagonal, hollow precast-prestressed concrete pile columns. The bridge was constructed in 1968 and suffered considerable damage during the Loma Prieta Earthquake in 1989. A damage survey report prepared by the State's Office of Emergency Services (OES) recorded that sixteen of the twenty-one pile-columns sustained heavy to moderate damage from the Loma Prieta Earthquake. The damage consisted of cracking and spalling at the tops of the pile-columns. Spalls at the most heavily damaged columns exposed the prestressing strands and confinement reinforcing which also showed signs of corrosion.

Jan 1, 1993

By Walter S. White

The Michigan native-copper district has produced about 5,400,000 tons of copper since mining began in 1845. The copper occurs primarily as open-space fillings and replacements in amygdaloidal flow tops and conglomerate beds of the Portage Lake Lava Series, of middle Keweenawan age. Secondary minerals with which the copper is associated include microcline, chlorite, epidote, pumpellyite, prehnite, quartz, and calcite; zeolites, other than laumontite, are not abundant. A zonal pattern of the secondary minerals transects bedding and suggests regional metamorphism mainly to the grade of the prehnite-pumpellyite graywacke facies of Coombs. Most of the major copper deposits are near the upper limit of abundant quartz in this zonal pattern. The distribution of copper in both amygdaloid and conglomerate deposits is controlled partly by primary permeability of the rocks and partly by later tectonic fracturing that was concentrated in the mechanically weak flow tops and sedimentary beds. Ore shoots and deposits are therefore controlled partly by primary structural features, such as areas of thick and thin fragmental amygdaloid or the boundaries of conglomerate lenses, and partly by regional structure: a number of ore deposits are in synclinal downwarps. The copper-bearing solutions that formed the deposits were ascending. They may have come from a large concealed intrusive, or may have been driven out of the porous tops of lava flows when the rocks were compacted and metamorphosed at great depth in the central part of the Lake Superior syncline. The second hypothesis seems more consistent with the widespread distribution of the copper, its relation to mineral zoning that represents truly regional metamorphism, its native state, and the likelihood that copper deposition was later than most or all of Keweenawan volcanism.

Jan 1, 1968

By J. J. Sense

The Mission Unit of American Smelting and 'Refining Company is located in Pima County, Arizona, approximately twenty miles southwest of the City of Tucson. The Unit consists of an open pit copper mine and concentrator. The concentrate is shipped by rail to Company Smelters at Hayden, Arizona, or El Paso, Texas Mine stripping began at Mission in the fall of 1959, and construction of the 15,000 tons per day concentrator gas started in the spring of 1960, The first ore was treated in mid summer of 1961 and full ore production was reached in August of 1961. At that time over 46,000,000 tons of material had been moved from the pit. Current production (ore and waste) averages over 100,000 tons per day. Total production to date (ore and waste) over 120,000,000 tons.

Jan 1, 1964

Accurate hematite solubility data are required to construct predictive solution chemistry models for complex hydrometallurgical solutions. These data are useful in understanding Fe(III) speciation and precipitation in a variety of hydrometallurgical processes. Hematite solubility data were generated in 10 to 70 g/L H2SO4 solutions and at temperatures from 130 to 270°C, using specially modified titanium autoclaves. These measurements represent an improvement over previous experimental data because of better in-situ filtration of the sample aliquots, the approach to equilibrium via hematite dissolution, and the inhibition of Fe(III) reduction on titanium surfaces. Fe(III) reduction was particularly studied to evaluate the inflationary effect of Fe(II) on hematite solubility measurements. Chromate was found to reliably inhibit Fe(III) reduction on titanium. Finally, the generated hematite solubility data were used to construct a solution chemistry model using the OLI software.

Jan 1, 2006

By Mohamad Hussein

Low strain dynamic tests are performed to evaluate the structural integrity of driven or cast-in-place concrete piles. This type of testing requires minimal pile preparation, and is simply performed by attaching an accelerometer to the pile head and striking the pile head with a hand held hammer. The measured data is processed by a dedicated system, inspected for wave reflections, and interpreted based on one dimensional wave propagation theory. Piles are normally tested shortly after installation so that problems can be identified early and corrective measures taken before construction of the superstructure. However, evaluation of existing foundations is occasionally required. Often, pile installation records are not available rendering impossible any rational foundation reanalysis. This paper discusses three case histories where low strain dynamic measurements allowed determination of pile lengths and structural integrity under existing structures where pile heads were not accessible.

Jan 1, 1992

By Vance G. Leak

A technique for recovering copper and steel from metallic scrap has been developed by the Bureau of Mines based on preferential melting in molten salt baths at 1,150° to 1,250° C, The molten salt, preferably barium chloride or calcium chloride, both minimizes oxidation of the metals and promotes heat transfer. Cleanest separations (0.01 percent copper remaining in iron) have been achieved by pretreatment (dipping or spraying) with sodium sulphate or sodium silicate, which alters and coats the surface of the iron to inhibit the alloying or brazing with copper. An economic evaluation of the process was carried out on six combinations of sweating media and inhibiting reagents. On the basis of the postulated model, a cost of about $0.20 per pound of copper recovered has been determined for the sweating treatment operation.

Jan 1, 1973

By Majorkiewicz A

Engineering of gold treatment facilities complete with infrastruc- ture in a remote location such as Papua NewòGuinea present unique problems to the design team. Site location, topography, ground conditions and infrastructure are some of the major hurdles to overcome when setting out on the design of such plants. This paper discusses two such plants, located in two distinctly different areas of Papua New Guinea and the solutions evolved in order to design successful operating facilities.

Jan 1, 1991

By C. H. Johannes, N. B. Strydom, C. H. Van Graan, J. G. A. Van Heerden

Note: The practical application of microclimate cooling in an underground stope in a gold mine by C. H. JOHANNES, C. H. VAN GRAAN, N. B. STRYDOM and J. G. A. VAN HEERDEN INTRODUCTION Although much information was available on the use of pre-frozen jackets as micro climate coolers in underground situations!, 2, no information was available on their performance under practical conditions in stopes. The objectives of this study were. O.F .S. Branch Minutes of the General Meeting held in the upstairs lounge at the Harmony Country Club, Harmony G.M. Co. limited, on Wednesday 12th November, 1975 at 4.00 p.m. NIM reports Report no. 343 A mineralogical investigation of gold-bearing sulphidic ore from the Florence-Devonian Mine, Barberton.(20th May, 1968; re-issued Dec. 1975). Report no. 1384 . Flotation tests on samples of Canadian copper-zinc ores. (12th Nov., 1971; re-issued Nov. 1975). The results are given of laboratory Report no. 1488 Extraction of rutile from Highveld smelter slags. (28th Sep., 1972; re. issued Nov., 1975). Report no. 1499 The production of medium -carbon ferrochromi'um. (4th Dec., 1972; reissued Nov. 1975). Report no. 1521 The dissipation of electrical power in the burden of a submerged-arc furnace. (15th Feb., 1973; re-issued Nov. 1975). Report no. 1527 The physicochemical properties of slags associated with the smelting of nickel sulphide concentrates. (21st Feb., 1973; re-issued Nov. 1975). Report no. 1544 The recovery of salable ferrochromium from material discarded by Ferrometals Limited. (11th Jun., 1973; re-issued Nov. 1975). Report no. 1547 Physicochemical and thermodynamic properties of slags in the system MgO-AlOl.5SiO2. (23rd Aug., 1973; re-issued Nov. 1975). Report no. 1548 Physicochemical properties of slags in the system MgO-Al2O3-SiO2 and their application to the technology of ferro-alloy smelting. (13th Jul., 1973; re-issued Nov. 1975). Report no. 1553 Characterization of the flotation properties of fluorspar from smallscale batch and pilotplant tests. (27th Sep., 1973; re-issued Nov. 1975). Report no. 1555 The analysis, by atomic-absorption spectrophotometry, of matte-leach residues. (2nd Oct., 1973; re-issued Nov. 1975). Report no. 1590 The separation of osmium from ruthenium in hydrochloric acid solutions. (18th Jan., 1974; re-issued Oct. 1975.) Report no. 1606 The electrical-resistance characteristics of the charge in the electric reduction furnace. (1st Feb., 1974; re-issued Oct. 1975). Report no. 1622 The electrical conductivity of the charge in a ferrosilicon furnace. (2nd Apr., 1974; reissued Oct. 1975).

Jan 3, 1976

By Bruce Geller

Attending the Prospectors and Developers Association of Canada (PDAC) meeting and exhibit has become an annual tradition for many in the mining industry. Similar to last year’s synopsis, this report is an overview of the 2003 conference from the eyes of a consulting mineralogist. It is supplemented by conversations with other participants. And it examines the conference handouts. Certain segments of the mining industry have seen improvement throughout the year in terms of metal prices, stronger demand and renewed interest by the investment community. Other segments continue their decline due to depressed commodity prices, higher oil prices, a continued weakness in the global economy and war uncertainties. SARS was known to the world, but it was not a Toronto epidemic during PDAC. In short, this year’s PDAC was permeated by an air of anxiety about the Middle East.

Jan 1, 2003