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By George A. Roberts

The development of an alloy system, high-speed steel, is used as an example of the progress of physical metallurgy. Tracing the history of men and their thoughts as they studied and invented and modified these materials, the story of high-speed steel since the 1890's is seen to be a long, slow, but steady progression of achievements. Today's multiplicity of high-speed steels are the result. Data are presented on quantitative metallography of carbides in high-speed steel with high vanadium content using the QTM instrument. Grindability as well as mechanical properties are related to the content of excess MC and M6C carbides in a series of high-speed steels and the newer matrix steels. These emphasize the present state of knowledge and show the current stages of thought that may affect the development in succeeding years. It is a great thrill for me, an ex-research metallurgist and ex-practicing metallurgical engineer, to speak to an audience currently engaged in both pursuits on the occasion of the 43rd Howe Memorial Lecture before the Iron and Steel Division of the AIME. I shall not review Henry Marion Howe's distinguished career, so adequately reviewed in Maxwell Gensamer's contribution in the 1965 AIME History of Metallurgy, except to point out that, while leading the life of an intellectual, he worked as a practicing research metallurgist and a practicing metallurgical engineer for significant periods of time and contributed greatly in both areas. For those of you who believe, as I do, that in the intellectual activity of metallurgy we are blessed with an intimate mixture of science and engineering (see Mehl's 1960 Howe Lecture), we might recall that Howe, while pursuing a life of writing and teaching in later years, served as the first Chairman of the Division of Engineering of the National Academy of Sciences. That metallurgists were called upon then to lead an engineering recognition movement is perhaps related to the strong part played by the AIME and its members in the recent establishment of a National Academy of Engineering and to the fact that a metallurgist is its head, 47 years after Howe served. I stress these engineering aspects for I wish to talk about a metallurgical engineering subject today. Alloy systems, physical metallurgy, and steel blended with an historical perspective and a report on new techniques to improve the old will, I trust, be of sufficient interest to bring these lectures back to the physical-metallurgy banner from which they have departed for 4 years. Those process metallurgists, open-hearth fiends, and physical chemists among you will just have to be patient. The development of an alloy system is the engineering application of scientific thought and fact. There are many interesting alloy systems, developed to a high degree of technology and sophistication over the past 40 to 70 years. These systems are bound together and related by a similar set of characteristics. For example, stainless steels are a system in which the members are related by a high chromium content which gives a corrosion-resistant characteristic. A subfamily in this system would be austenitic steels

Jan 1, 1967

By Enver Alan, MerkeziYapı

People are migrating because of economic, social, natural and political reasons. These natural and humane factors effects the distribution of populations. The need for tunnels has grown in order to provide a comfortable life and reduce losses such as waste of time, labor, energy, efficiency and so on. It is inevitable to carry out excavations in rock tunnels (shears, platforms, lines, connections, wastewater, distribution, energy, transportation etc.), that will be built by excavating with conventional method, by controlled blasting regarding with constrains. In this study of applied explosives engineering the blasting applications are evaluated, which were carried out for research and development purposes at Yenisahra Station tunnels in Kartal Formation which was built with the aim of solving İstanbul's transportation problem within the framework of the Kadıköy-Kartal Metro Project. Twenty-four shots were made by using explosives in 60 blastholes that were drilled in the tunnel faces, which were located between and outside of two different faults. Six microphones were used to measure the air shock and eight geophones were used to measure the parameter values of the vibrations (particle velocity, frequency, displacement, acceleration, amplitude, wavelength etc.), which were placed at predetermined points of the surface, occurred during the blasting applications. Data from the geophone and microphones were recorded on six seismographs. The coordinates and the distances between the shot points and the measurement stations are determined by an electronic theodolite. The total number of seismic records, recorded in seismographs, is 118. The number of records of vibrations that crossed the faults is 42 and the number of records of vibrations that did not cross the fault is 76. The particle velocity, frequency, amplitude, acceleration, displacement and wavelength were measured in transverse, longitudinal and vertical directions. The total number of measurements is 354. By evaluating all seismic records, the effect of delay intervals, faults and scaled distances on the particle velocity, frequency, amplitude, displacement, acceleration, wavelength and air shock were investigated. When the vibrations formed during the Research & Development (R&D) blasts were examined, it was determined that the parameter values of vibrations that crossed the faults are lower than the ones that did not cross the faults. In addition, when the particle velocity values of all vibrations are examined according to the present circumstances, it is determined that the waves did not cross the fault in all delay intervals are superposed in all directions, and that the least superposing occurred in the 50 ms delay range.

By Carl Hendricks, Malcolm Scoble

There currently exists no viable means of obtaining continuous, quantified feedback on blast efficiency. This paper describes the adaptation of a loading shovel to serve as a diagnostic tool in evaluating the success of ground preparation practices. Work undertaken in a large western Canadian open pit involved microprocessor-based instrumentation for the performance monitoring of an electric mining shovel. The monitored shovel responses proved to be reliable indicators of variations in muckpile d&ability. This approach is considered to provide a very comprehensive survey of post blast conditions since the shovel must physically interact which every cubic yard of blast fragmentation.

Jan 1, 1991

By J. B. Zadra

Tungsten metal, chemically equivalent to commercial grade, is produced by electrolysis of impure tungsten compounds or scheelite in an alkali, phosphate or borate electrolyte. A preliminary investigation of fused-bath electrolysis shows the effect of electrolyte composition, temperature, and current density on current efficiency, yield, crystal structure, and purity of product. Experiments show that tungsten can be electrowon from scheelite in a fused alkali, phosphate, or borate bath with similar results. Studies on electrolyte composition show that the addition of sodium chloride is essential to both electrolytes in treating scheelite. Although its main function is to react with or flux the CaO, it also increases the bath fluidity. Temperature studies revealed optimum ranges between 900° and 1,100° C.; 900° C. proved satisfactory for tungsten trioxide, and 950° to 1,050° C. for scheelite. Current efficiencies were satisfactory for all current densities ranging from 10 to 57 a./dm.2. Yields were 400 to 650 g./kw.-hr. over the same current-density range. Crystal size and purity of the product are functions of temperature, current density, and amount of impurities in the electrolyte. Deposited crystals vary in shape from spherical grains to clusters of dendritic hexagonal needles, and in size from smaller than 35 to 570 microns. The purity of the tungsten metal produced ranges from 99.7 to 99.94 percent.

Jan 1, 1959

By S. Sakurai, N. Shimizu

The stability of slopes is a crucial problem not only in open pit mines, but also in civil engineering situations. The deformational behaviour of slopes is in general monitored during/after the excavation by carrying out field measurements where displacement measurements are commonly adopted. In monitoring the slope stability it should be emphasized that the measurement results must be properly interpreted so as to assess whether the slopes are stable or become unstable in the future. In order to interpret the data, back analysis is extremely useful. In this paper a slope stability monitoring system is described. It consists of displacement measurements by GPS, and a back analysis of measured data. The use of GPS has a great advantage, because of the fact that continuous displacement measurements with high accuracy for a large extent of concerned area can be easily achieved. On the other hand, the back analysis can reveal the mechanical characteristics of the ground, which make it possible to assess the stability of slopes quantitatively.

Jan 1, 2006

By Fredrick L. Johnson

The Bureau of Mines, under Congressional mandate, conducted a mineral survey on the Park Range WSA (Wilderness Study Area) in 1984 and 1985. The WSA, located about midway between Tonopah and Ely, encompasses 47,268 acres. No mineral resources were delineated, nor were workings found, during the investigation. There has been, however, exploration in and near the north end of the study area. ASARCO is actively exploring a block of 41 claims for hot-spring type, low-grade, large-tonnage gold deposits. Their claim block is almost entirely in the study area. The Morey mining district, 7 miles southwest of the study area, produced silver and lesser amounts of gold and lead sporadically from the mid-1860's through the mid-1960's. The WSA is underlain by Tertiary rhyolitic and latitic volcanic rocks and by Paleozoic sedimentary rocks. The Paleozoic rocks have been faulted, silicified, brecciated, and hydrothermally altered, and have anomalous concentrations of precious metals and pathfinder elements. Additional exploration in the north part of the Park Range WSA may lead to delineation of gold resources.

Jan 1, 1986

By Claude Deveau

"Studies on the performance of Falcon batch type concentrators treating ultrafine tantalum at Tanco have revealed that very fine heavy minerals are concentrated within certain areas of the concentrate bed. This information led to the design of a bowl which would allow entrapped lighter low grade particles to escape while providing more space for heavier particles to be recovered in the bed.Numerous tests were then completed with a modified batch-type and non-fluidized Falcon bowl in which the diameter of the discharge lip was adjusted downward manually in steps. This allowed for the gradual building of a higher grade concentrate bed.This work ultimately led to the design of a new Falcon with an automated continuously variable lip. In April 2005, Tanco commissioned the first Falcon UF600.This paper will discuss laboratory scale results and also plant performance of the Falcon’s UF technology.INTRODUCTIONTantalum Mining Corporation of Canada, also known as Tanco, is a wholly owned subsidiary of Cabot Corporation based in Boston, Mass. Operating since 1969, the underground highly mechanized room and pillar operation produces tantalum, lithium and cesium minerals and is located a 2 hour drive east-northeast of Winnipeg Manitoba, Canada.At Tanco, tantalum is recovered using conventional gravity concentration, enhanced gravity concentration and flotation. This paper will discuss how the need for improved equipment to treat very fine tantalum particles was filled by a machine which was modified to the point of creating a completely new technology.In November 2003, Tanco began the investigation for the potential use of a high g-force smooth walled concentrator for treating ultra fine tantalum produced by its flotation circuit. Until then, the tantalum flotation concentrate had been treated by a circuit which consisted of a Mozley Multi-Gravity Separator 902 (MGS), a Mozley MGS 900 and a Bartles cross belt concentrator. Through QemScan analysis, it was found that the majority of the losses from this circuit were of an extremely fine nature which exceeded the recovery limits of equipment on hand. Mean particle size of the tantalum losses was less than 10 µm."

Jan 1, 2006

By Madan B. Karkee

The understanding and the development of sound theoretical basis concerning the pile foundations has been phenomenal during the past few decades, considering the thousands of years the piles have evidently been in use. The importance of the quality assurance and the need for verification of load bearing capacity is being further reinforced rather than undermined by these developments. This is evidenced by significant developments made in the pile load test technology in recent decades, making it possible to make judicious selection of a test method, or a package of test methods, suitable for a given situation. The selection depends on the objective of carrying out the test and the reliability desired. Presently, the possible selection ranges from dynamic to static methods. The extent of dynamic effect in a test can be reckoned based on a dimensionless parameter defined as the 'relative duration'. Examples of different load tests are given for illustration of the different methods currently in use.

Jan 1, 1997

By S. Haggarty

"Wholly owned by Corona Corporation, the Nickel Plate Mine is an open pit, gold mining operation located near Hedley, 50 km west of Penticton, in Southern British Columbia.Milling capacity is 3,400 SDT /Day with an average feed grade of 0.080 Oz Au/Ton. Gold processing involves three stage grinding including tertiary pebble milling, two stage cyanide leaching and filtering and Merrill-Crowe zinc precipitation.A summary of process improvements required to increase milling capacity above the initial design tonnage of 2, 700 SDT /Day are described -Installation of a 42"" x 65"" Allis Chalmers Gyratory crusher replacing a 42"" x 48"" Traylor jaw crusher.Installation of polyurethane screen panels replacing woven wire cloths on an 8' x 20 ft triple deck screen.Installation of a hopper clarifier to reduce filtrate turbidity.Automated control of solution balancing and effluent treatment circuits.INTRODUCTIONThis paper describes mining and milling practices at the Nickel Plate Mine and details post start-up process modifications which were required to attain design tonnage.Wholly owned by Corona Corporation, the Nickel Plate Mine is an open pit, gold mining operation located near Hedley, 50 km west of Penticton, in Southern British Columbia.Mining capacity from the open pit is approximately 32,000 TPD with an average waste/ore ratio of 8.4:1.Milling capacity is 3,400 SOT/Day, above initial design tonnage of 2,700 SOT/Day. Feed grade averages 0.08 Oz Au per ton yielding 85,000 troy ounces of gold per year."

Jan 1, 1991

By Keith E. Dyas, John Nelson, Ronald T. Johnson

GENERAL DESCRIPTION The Bruce mine of Cyprus Mines Corp. is located in Bagdad, AZ. The mining method used is open cut-and-fill. Of the annual production of 81 647 t (90,000 st), approximately 83% is taken from load-haul-dump (LHD) stopes and the balance from slusher stopes. All ore is produced from the area between the 1250 level and the 2300 level. The average travel time from the shaft pocket to the stope is approximately 5 min. GENERAL ORE BODY REQUIREMENTS AND LIMITATIONS Size, Shape, and Dip The Bruce ore body occurs in quartz-sericite schist with Dick rhyolite on the footwall and andesite on the hanging wall. Diabase dikes are found in the hanging wall; there is also a dike coming off the footwall and crosscutting the ore body. All of the rock types are of the Precambrian Yavapai series and have been subjected to regional metamorphism. A composite of the ore body is given in Fig. 1. The deposit is of massive sulfides occurring as a steeply dipping replacement body. On the upper levels the ore is veinlike with widths from 0.6 to 4.6 m (2 to 15 ft), dipping at 1.4 to 1.5 rad (80° to 85°). On the lower levels the ore is dipping from I to 1.2 rad (60° to 70°) with widths from 3 to 16.8 m (10 to 55 ft). The strike length varies between 107 to 183 m (350 to 600 ft). The rhyolite footwall generally has a knife-edge contact with the massive sulfides. The exceptions to this are the upper levels where there is a 1.5 to 3 m (5 to 10 ft) band of silicified sericite schist between the sulfides and the rhyolite. In the southern part of the ore body the hanging wall is tuffaceous andesite and andesite. In this area the contact is generally sharp and easy to follow. However, to the north there is a large chlorite schist zone that crosscuts the bedding and comes in contact with the massive sulfides. This is apparently due to hydrothermal alteration of the andesite. The chlorite schist is highly mineralized with chalcopyrite and pyrite and quite often forms economic pockets of ore. In the massive sulfides the chief ore minerals are sphalerite and chalcopyrite. Pyrite is the predominant sulfide with considerable pyrrhotite throughout. Bright arsenopyrite ouhedrons in fine grain massive sulfides are quite common. Occasionally small amounts of galena are seen, usually near the foot or hanging wall contacts. On rare occasions tennanite is associated with massive arsenopyrite. Minor amounts of quartz, calcite, and un¬replaced remnants of sericite schist occur, but essentially pyrite is the gangue in which the ore minerals occur. The ore values are in excess of 3.5% copper and 12.5% zinc with some silver and rare gold as byproducts. Ground Conditions The massive sulfides are generally self-supporting. One exception is in the 1850 stope where the ore body is 9 to 11 m (30 to 55 ft) wide and 152 m (500 ft) long. There are flat to shallow dipping slips and seams in the ore, creating extremely blocky ground. For support, old 25.4-mm (1-in.) hoist ropes were installed tensioned to 27 t (30 st), and then cement grouted over the entire length in longholes [14 to 15 in (40 to 50 ft) in length) drilled on 3-m (10-ft) centers from the level above. This has tied the formation together very successfully and virtually eliminated the blocky ground condition. Both the hanging wall and footwall are quite shaley in some areas. Reasons for Adopting Trackless Open Cut-and-Fill Methods First, any method other than open cut-and-fill would have caused too much dilution. The use of rubber-tired mining equipment in the pro¬duction stopes requires a footwall ramp. The inclines in ore will be mined out, so this ramp in the footwall will provide access to and from the stopes (Fig. 2). This incline is very expensive, but necessary to convert existing stopes to LHD mining. 'The final cost of ore mined by the LHD machines has not been determined. As of 1972, tons per manshift in the 2150 stope-the only one to complete a full cut-had increased from 7.58 t (8.36 st) to 12.83 t (14.14

Jan 1, 1982

By J. A. Bowers

THIS investigation of the effect of bottom shape and life on slag volume was carried out in two Lectromelt top-charge furnaces whose rated capacity is 1000 lb per hour. Unfortunately, just as the work [ ] was started, our steel tonnage was reduced approximately one half, therefore we did not accumulate enough data from which to draw any definite conclusions. Furthermore, the life of the linings in these furnaces was greatly decreased by intermittent operation, which was a further handicap in making a study of this kind. The weight of the heats from which the data were taken varied 1200 lb but all the information was corrected to the standard weight charge for these furnaces of 4500 lb. Almost all the heats were plain carbon; a few contained a small percentage of added copper.

Jan 1, 1947

By Carole L. B. Mitchell

The South 180th Street Grade Separation underpass in Tukwila and Renton, Washington, USA, permits vehicular traffic to pass beneath Burlington Northern Santa Fe and Union Pacific railroad tracks. The railroad tracks were temporarily relocated onto a shoofly crossing while the permanent bridges were constructed. The maximum underpass depth is approximately 25 feet (7.6 meters [m]). The majority of the sidewalls are supported using alternating reinforced and unreinforced secant pile walls. Temporary and permanent struts brace the top of the excavation. Because the groundwater is about 15 feet (4.6 m) above the base of the excavation and the subsurface materials are loose to medium dense fill, alluvium, and soft flood plain organics, the base of the excavation was strengthened and sealed using wet cement deep soil mixing (CDSM) methods. During construction, CDSM-treated ground temporarily acted as part of the railroad shoofly shoring while the remainder of the underpass was excavated on either side of active railroad tracks. The combination of secant pile sidewalls and CDSM bottom seal allowed for easy excavation, even during wet conditions. Using a 35-foot-thick (maximum) (10.7-m) CDSM layer both to act as a bottom seal and to resist uplift pressures is a unique, dual-purpose application of CDSM technology in the United States.

Jan 1, 2004

By J. E. Wilson

The Pittsburgh carbonization laboratory of the Bureau of Mines has determined the expansion or contraction of more than 300 coking coals in a modified Bethlehem-type sole-heated expansion tester. Information on the actions of coals or blends of coals when coked is extremely valuable to operators of commercial-scale coke ovens. Coals that expand abnormally or beyond expectations can cause extensive damage to coke ovens and result in costly shutdowns and repairs. Although test results for many of the coals have been given in various Bureau of Mines publications, considerable information was not published. Thus, it is the purpose of this report to furnish coal operators and the coking industry with a current appraisal of the expanding properties of all coals tested by the Bureau before September 1, 1958. These data should be useful in the normal long range planning of coal and coke production and will be essential if the demand for coking coals increases abnormally or when reserves of higher grade coals are depleted.

Jan 1, 1959

By Jacob Chacko

The Izmit Bay bridge, a 3-km-long suspension bridge crossing of Izmit Bay, Turkey is planned to be constructed in one of the most seismically active places in the world. The site, which has the potential to experience significant earthquakes associated with the relative motion accommodated on the North Anatolian Fault, is underlain by deep deposits of soft soils, and areas of unstable and liquefiable soils. Characterizing the seismotectonic setting, foundation soil conditions, potential fault locations, as well as other geohazards was a critical component for the project concessionaire to finance the project and obtain meaningful bids for bridge design and construction. Given the Build Operate Transfer (BOT) funding mechanism, executing this work in the least possible time was critical to the concessionaire?s financing scheme. Fugro was retained to provide geotechnical, geological, and seismological evaluations for the project region, and to generate data for contractors to develop reliable designs and bids. The uncertainties in these data made it difficult for the BOT concessionaire to finance the project and tender Bridge design and construction. The investment in an early and comprehensive site characterization program to evaluate and quantify those uncertainties allowed the concessionaire to save schedule, provide a robust bid basis to bridge contractors, and persuade banks to finance what was perceived to be a relatively high risk project.

Jan 1, 2011

By R. Chiarizia

Third phase formation, i.e., the splitting of the organic phase in two layers, is a common feature observed, under conditions of high loading, for many solvent extraction systems of both analytical and industrial interest. Although this phenomenon has been investigated in a large number of works, a structural and physico-chemical description is still lacking. In this work, small-angle neutron scattering (SANS) data for the tri-n-butylphosphate (TBP)-n-octane,Th(NO3)4-HNO3 solvent extraction system have been interpreted using the Baxter model for hard-spheres with surface adhesion. The increase in scattering intensity in the low Q range, observed when increasing amounts of HNO3 and/or Th(NO3)4 are introduced into the organic phase, has been interpreted as arising from interactions between small reverse micelles containing three TBP molecules plus solutes in their polar core. This intermicellar attraction, under appropriate conditions, leads to third phase formation.

Jan 1, 2003

By Zhongxue Li, Cuiping Li, Xiaoyun Hu, Yiqing Zhao, Huaying Wang

"Under the auspices of World Federation of Engineering Organizations’ Committee on Engineering and the Environment (WFEO-CEE) and Society for Mining, Metallurgy and Exploration (SME) Task Force on Sustainability and Mining (TFSM), and aimed at helping raise global understanding on and promote capacity building of risk management, this paper presents a framework and prototype of toolbox or knowledge warehouse for facilitating the application of risk analysis, mitigation and management techniques (RAMT) in the mining and minerals sector. The conception, design and implementation of the intended system of knowledge warehouse of risk analysis, mitigation and management techniques (KWoRAMT) are outlined. The system architecture of KWoRAMT is based on a browser/server (B/S) structured platform with web oriented interfaces and composed of data base, knowledge warehouse, searching mechanisms, and risk assessment methodologies. The knowledge sources for KWoRAMT will come from the TFSM expertise and Internet, including laws and regulations, codes of practice, standards, guidelines and best practices. The functions and outcomes of KWoRAMT consist of guided navigations with web links, categorized risk tools, annotated best practices with cases, and integrated risk approaches and solutions based on typical risk methods. Risk categories include those impacting on mine safety, mine occupational health, and mine community environment throughout the whole of mine life cycle from exploration, construction, and exploitation and processing to post-mining closure. Mining associated hazards will be identified and linked by vulnerability onto risk receptors through pathways. Risk management techniques for assessing impacts and consequences of mining induced hazards will be categorized with their pros and cons or strengths and weaknesses. Best practices and significant cases including experiences and lessons with problems, solutions, and recommendations on how solutions would be derived will be illustrated. Integrated risk approaches based upon typical methods will be developed for alternatives and actions."

Jan 1, 2014

By G. J. Borbely, E. A. Devuyst, V. A. Ettel

"A new method for oxidative destruction of cyanide in industrial waste waters and slurries, such as gold mill barren liquors, tailing slurries and flotation tailings has been developed at the Inca research laboratories. Rapid decomposition of cyanide and related species is attained by treating the waste waters with a mixture of S02 and air at controlled pH and in the presence of a small amount of copper which acts as a catalyst. The approach selectively oxidizes cyanide and metal cyanide complexes, and also removes iron cyano complexes which are not removed by alkaline chlorination.The new method is shown to be less reagent intensive and therefore more economical than alkaline chlorination for treating gold mill and flotation waste waters. INTRODUCTIONOver 90% of the gold mined in Canada is extracted from the ore by ""cyanidation"". Wastes from the process consist of tailings which contain free cyanide, cyanide combined with heavy metals, thiosalts and thiocyanates. Because of the concern over the effect of toxic cyanides on the environment, all cyanide containing effluents will have to be treated in the future to meet certain government set concentration limits."

Jan 1, 1982

The regular activities of the Institute are financed mainly by income derived from members' dues, from advertising in MINING AND METALLURGY, and from the sale of publications to the public. In addition, collateral activities and special projects are financed each year by means of income from endowed funds controlled and administered by the Institute. In the aggregate, the principal sums of these endowments amount to more than $530,000. An active effort is being made to increase the endowment funds of the Institute through a standing committee, of which H. T. Hamilton is chairman, and of which the other members are: W. H. Aldridge, George D. Barron, Cleveland E. Dodge, D. C. Jackling, Henry Krumb and J. V. W. Reynders. This committee feels that there exists a tremendous opportunity for the Institute to be of ever-growing service to the public, to the mineral industries, and to the profession. It welcomes suggestions as to names of men of means who are vitally interested in the mineral industries, and to whom the opportunity to make a contribution or bequest might appeal favorably if presented in the proper light by the committee.

Jan 1, 1941

By Frances Badelow

This paper describes a design process for piled raft foundations supporting high-rise buildings. The design process comprises an initial stage of geotechnical site characterization using the results of investigation boreholes to prepare a subsurface model and derive geotechnical parameters for raft and pile design from empirical correlations. Following this a preliminary analysis is undertaken using a combination of elastic theory and allowances for non linear behaviour of the piled raft system to assess the viability of such a foundation system and any potential advantages of a piled raft over conventional fully piled foundation systems. Finally, a detailed analysis is undertaken using the GARP8 computer program. Case studies where this design process has been successfully used to design a more efficient piled raft system that has resulted in significant cost and time savings compared to conventional bored pile foundation options are also described.

Jan 1, 2006

By A. S. Appleton

The diffusion of carbon in Fe-Co-C austenites was studied as a function of cobalt concentration up to 12 at. pet, using an autoradiographic technique. The diffusion coefficient was found to initially decrease and then increase with increasing cobalt concentration, the trends being more marked the higher the temperature of diffusion. These effects were paralleled by variations in the activation energy and the constant for diffusion which, however, were found to be dependent also on the carbon content. The results are compared with the previously available data and their significance is discussed in terms of the kinetics of solid-state reactions in this systern. THE influence of cobalt on the diffusivity of carbon in austenite was first studied by Smoluchowski,' his data being that most commonly cited in works

Jan 1, 1964