Search Documents

By J. M. Floyd

Technology in use commercially and available for commercialisation for injection processing of base and precious metals in bath reactors is surveyed and compared. Differences between bath smelting and suspension smelting systems are highlighted in relation to important smelting criteria. The factors affecting the results achievable with various tuyere and lance injection bath smelting systems are discussed in relation to the various smelting, converting and refining operations involved in copper, nickel and precious metal processing steps. Process chemistry, process dynamics and heat and mass transfer rates are discussed for the different systems.

Jan 1, 1993

By Roy L. Wilfong, LeRoy R. Furlong, Louis P. Domingues

The bulk and apparent densities , particle size , and surface area of ceria powders derived from the ammonium sulfate , carbonate , nitrate , oxalate , and sulfate salts and heated at 950 ° to 1,500 ° C for 1 to 24 hours were studied . The bulk and apparent densities and particle size generally increased , and surface area decreased with increase in temperature and time of heating ; surface area was more sensitive to changes in temperature and time than the other properties studied . These properties of the ceria powders had a marked dependence on temperature and a lesser dependence on duration of heating at a given temperature ; and the source of oxide and thermal treatment cannot be considered optional in the preparation of refractory powders by thermal decomposition . The ammonium sulfate and sulfate salts heated at 950 ° and 1,200 ° C produced oxide powders with the lowest bulk density , the smallest particle size , and the highest surface area . The highest apparent densities were achieved for oxides resulting from the carbonate and the sulfate but the carbonate - derived material was considerably coarser . The surface areas of ceria powders derived from cerium salts decrease in the order of sulfate , ammonium sulfate , nitrate , oxalate , and carbonate . The observation of these physical properties are useful in predicting the sintering behavior of various oxide powders .

Jan 1, 1964

By J. M. Manka

American mining companies operate many drum hoists that hoist from various depths with varying payloads. This paper will review the procedure of selecting optimum wire rope constructions for these existing hoisting installations. Selection for proposed installations along with recommended hoisting parameters will also be presented. To achieve this optimum rope performance, preventative and corrective maintenance procedures will be reviewed along with examples of rope problems and their causes.

Jan 1, 1992

By G. S. Rice, R. V. Wheeler

"In September 1923, a proposal was made through official diplomatic channels by the British Safety in Mines Research Board to the United States Bureau of Mines for ""closer cooperation between the two countries in investigations into the causes and means of prevention of mining dangers."" This proposal was cordially accepted by the Bureau of Mines and was officially approved.In the spring of 1924 cooperation was .formally begun. It contemplated, as stated officially, ""full exchanges of information, a joint program of research, and periodic exchange of personnel so as to assure concordant results. By making the resources of both organizations available it will hasten the attainment of results, will secure better: checks for, accuracy, and in the end will save money for both by avoiding duplication and repetition.""This joint work has been carried-on successfully since that time and has developed valuable results, reports on which have been issued from time to time. The progress report which follows gives the results of the studies and work carried on in 1929.During 1929 all the phases of our cooperative research, begun in previous years, have developed normally. The exchange of formal monthly reports on all programs of mutual interest has been continued and has proved an invaluable, means of maintaining contact between the investigators of both organizations. There has been no diminution in the exchange of routine progress reports on specific subjects or in direct correspondence. The interchange of personnel has been maintained, and we can say that the mutual benefits to be derived from this form of cooperation are so great as to be difficult to overestimate. It leads to an appreciation of methods of research and modes of thought in the interpretation of results obtainable in no other way, and engenders a frankness and intimacy which must continuously enhance the value of future cooperation.Dr. S. R. Katz, who was assigned for service with the Safety in Mines Research Board in April, 1928, returned to America in May, 1929. During his stay in England he completed, in cooperation with members of the board's staff, the equipment of a gas-mask laboratory and designed and tested a new form of gas-mask canister. A publication of the Safety in Mines Research Board dealing with this investigation has been prepared and approved and will .be .issued in the near future. In additions Dr. Katz imparted to those with whom he was associated much of his knowledge and technique regarding his particular subjects. He delivered two lectures to the board's staff, the subjects be ""Gas Masks"" and ""The Intensity of Odors"", and gave papers before the Midland Institute of 'lining Engineers and the Birmingham University Mining Society on the subject of ""Industrial Gas Masks""."

Jun 1, 1930

By R. R. Brown

The solubility and the activity of aluminum chloride hexahydrate, A1C13?6H2O, in aqueous solutions were determined as a part of the Bureau of Mines, U.S. Department of the Interior, research to improve mineral processing technology for recovering alumina from low-grade domestic resources. The solubility of A1C13 in pure water was found to be 31.09 and 31.77 wt-pct at 25° and 85° C, respectively, and decreased drastically to 10 and 0.1 wt-pct when the respective amounts of 20.3 and 37 wt-pct hydrochloric acid (HCI) were added in solution. The equilibrium constant for the solubility of hexahydrate, activities, and activity coefficients of A1C13 and H2O were calculated and compared with the results from the available methods of estimation. The results were shown to be useful in leaching nonbauxitic ores for extraction of alumina by changing the solubilities of component salts upon addition of HC1. Simultaneous solubilities of A1C13, FeC13, KC1, and NaC1 in solutions of HC1-H2O were also determined and their effects on the purity of A1C13?6H20 crystallized from mixed salt solutions are briefly discussed.

Jan 1, 1979

By Gaurav Soni, Roe-Hoan Yoon

A first principle flotation model has been derived from the basic mechanisms involved in flotation. The model consists of a series of analytical equations for bubble generation, bubble-particle collision, attachment, detachment, and froth phase recovery. The model can predict flotation from both hydrodynamic and surface chemistry parameters such as bubble size, particle size, energy dissipation rate, ?-potentials, contact angles (?), etc. The model predictions have been compared with the results of a series of laboratory flotation tests conducted using mono-sized glass beads of different particle sizes and contact angles under different operating conditions. Some of the experiments were conducted using a 1:9 mixtures if hydrophobic silica and hydrophilic magnetite, so that the product graded could be readily determined by simple magnetic separation. The model predictions are in good agreement with the experimental results both in recovery and grade. A computer simulator developed on the basis of the model is capable of designing a preliminary flotation circuit on the basis of feed characteristics, e.g., size-by-liberation data, and the hydrodynamic information on the flotation cells to be incorporated in the circuit.

Jan 1, 2014

By Yong Pan, Purushotham Tukkaraja

Block caving is a preferred underground mining technique due to its high production rate and low operation cost. Before its final step into a mature caving system using gravity to break rock, drilling and blasting are required to form drawbells to connect the production level and undercut level and induce the initial caving propagation in undercut level. A large amount of toxic fume generated by blasting activities poses a big threat to people working in a confined environment and ventilation is assumed to be the most economical and efficient way to deal with this issue. Past research shows that it’s common to use traditional methods like using a formula or using numerical method (Computational Fluid Dynamic (CFD)) simulation to predict re-entry time after each blasting, but it fails to consider the percentage of toxic fume entrapped in muckpile, which could reach up to 70%. In this paper, CFD was used to investigate the blasting toxic fume characteristics under different entrapping percentages and under changing muck pile properties like broken rock size and porosity. It showed that CFD was a very useful method to study blasting fume in an underground mine and it took much longer time to dilute toxic fume into a safe level with higher entrapping percentage. The dilution time increased with a decrease of broken rock size and porosity.

By Victor L. Stevens

The Oso tunnel is one of three tunnels located on the San Juan-Chama Project in south-central Colorado. The purpose of the tunnel is to carry water from the upper San Juan watershed through the Continental Divide into the Rio Grande watershed. The Oso tunnel contract was awarded by the U.S. Bureau of Reclamation to a joint venture of Boyles Brothers Drilling Co., Gibbons & Reed Co., and Cimco in February 1966. The Oso tunnel is 26,660 ft long and has a rock section of 10 ft, 2 in. with a lined diameter of 8 ft circular. The main portion of the rock formation was in the Lewis shale. This formation is quite consistent in hardness and texture with exception of localized limestone concretions and sandy siltstone inclusions. The job was bid on the basis of using a James S. Robbins mole of the P221 series. The decision for using a mole was predicated on the geology and the experience of the same joint venture on the adjoining Azotea tunnel where a mole was successfully used. The Robbins P221 series mole is capable of cutting from 9 ft, 11 in. to a 10 ft, 7 in. diam without any major change. It is 40 ft long and weighs 60 tons. The cutting head has 22 disk-type cutters and one center pilot (standard 9 7/8 -in.) tricone bit. The head is powered by four 75 hp electric motors. Gripper pads at about the midway point on each side of the machine are pushed into the tunnel ribs and thrust-cylinders in front of each gripper apply pressure to the face as the head rotates. The regripping cycle is 3 ft and then the grippers are retracted and advanced. Each cutter on the perimeter of the head is followed by a bucket which scoops up the cut material, almost in the same manner as a water wheel, and dumps it into a conveyor situated along the top of the mole. The muck from the mole conveyor is dumped into a gantry-type conveyor. The gantry conveyor is 350 ft long and is pulled

Jan 1, 1970

By B. M. Flohr

Railroads are cost competitive with trucks for hauls greater than 500 miles - WRONG. Today I will tell you about many rail movements of less than 100 miles throughout the country. Rail is a short haul transportation alternative you must consider. Transportation today is the largest controllable cost in the total cost of production of goods. In fact it is the one cost area where aggressive management, using new tools, can achieve significant reductions. You can't control the price of metals in the world market, you can't control labor rates since they are tied to industry norms, and the price of raw materials are relatively insensitive to specific price reductions to your firm. Transportation is the one area where major savings are now being realized. Sample Movements First, I will give you several examples of short haul rail moves to make you a believer that they do exist. Then I will show you the reasons why railroads suddenly "like" short hauls.

Jan 1, 1986

By D. L. McCain

In considering slurry transportation for Consolidation Coal Company's Loveridge Mine in Northern West Virginia, many things were taken into account. The advantages of slurry transportation in comparison to shuttle car, belt and rail transport have been given in previous publications." These include increased safety and the potential for increased productivity. In addition to these considerations, the slurry transport system installed in an existing mine provides an alternate or additional transportation mode to the one already existing. In the Loveridge Mine, this is rail haulage. Since the rail system is a single track system and the distances involved are several kilometers, it is not always possible to provide for haulage of loaded cars, return of empties, supplies and maintenance in an efficient manner. Slurry transport of the coal from the production faces to the preparation plant allows the rail system to fulfill the remaining transportation needs in an efficient manner. Consol initiated development work in slurry transportation in the early fifties leading to the construction and operation of the 174-km (108-mile) Cadiz-to-Cleveland pipeline which carried 1,200,000 metric t/y (1,300,000 t/y) from 1957 to 1963. Development work on coarse coal slurry transportation for underground mines started in 1970 with feasibility tests on coarse coal at Conoco's Ponca City, Oklahoma, slurry test facility. A series of tests were conducted in several locations as development work proceeded on the various subsystems, mechanical equipment and controls required to produce a working system to follow a continuous miner in a room-and-pillar type mine, then to combine the coal production from several mine faces for mainline transportation to the preparation plant. The face system, including the crusher-pump vehicle, hose hauler vehicle, slurry booster pump units, return water unit and 900 to 1,200 m (3,000 to 4,000 feet) of pipeline was brought together for the first time and tested as a system at Consol's Robinson Run Mine in northern West Virginia in 1975. A pipeline wear test at the Loveridge Mine where 300,000 tonnes (330,000 tons) of minus 127-mm (5-inch) run-of-mine coal were pumped from the raw coal bin into the preparation plant and a large scale test in Ponca City on a multiple feed sump where several slurry flows could be combined to provide surge capacity and a constant reclaim rate for mainline transportation completed the preliminary testing for a complete system. A decision was made to commit the system to a mine, and the south half of the Loveridge Mine was chosen. This site required the transporting of coal from one longwall and two continuous miner development faces. To prevent startup and unexpected problems in the slurry system from shutting down production of coal from the longwall face, the rail car loading point from the main section belt was chosen as the feed point for the slurry system and the design would allow for rapidly switching from one transport mode to the other. Scheduling of required development entry work and the developmental nature of the system led to a decision to install only one continuous miner face slurry transport system rather than two for this first system. The type of continuous miner in use at the mine for the foreseeable future was the Joy 2BT6 twin boring machine. This machine cuts a stable, arch-shaped entry and was therefore allowed to mine about 26 m (85 feet) of entry before roof bolting was re¬quired. Since peak production from this type of machine was not high, a smaller transport system could be used with it.

Jan 1, 1981

By Honglei Zhang, Wuguo Xiang, Xinhao Huang, Guotao Xu, Xilai Chen

"The service behavior of refractories used in hot air pipeline for hot air stoves in a 3200 M3 blast furnace of WISCO was analyzed. The damage factors can be concluded as the poor quality of and alusite based bricks, the severe thermal shock damage, the more porosity in structures, loose bonding capability, and the unreasonable choice of materials and design of bricks. By analysis, the service life of hot air stoves can be enhanced by the measurements such as the reasonable choice of materials and their match, the use of light-weight refractories, the improvement of brick type, etc. Thereafter, the normal production operation of hot air stoves is guaranteed.IntroductionThe No.7 blast furnace of WISCO has been used for about 5 years and it was mid-repaired in March, 2012. The top phenomena of worn hot air pipelines are brick drop, breakage, severely local wear and deformation, existing hidden danger, so the worn hot air pipelines were renewed. Investigations have been done on the stove damage and design [1,2]. In order to clarify the wear mechanism, the used refractories for hot air pipelines were sampled and analyzed, the properties and structures of worn materials and reused materials are relatively studied."

Jan 1, 2013

By David E. Siskind

A Bureau of Mines survey of noise from quarry production blasting was conducted at seven crushed-stone quarries, providing information on close-in noise generation, comparative instrumentation, and evaluation of the sound levels as related to blasting parameters and existing State and local noise standards. The results from this preliminary survey will be useful in the design of a complete investigation of the problem of noise from blasting. There exists an immediate need for technical guidelines for noise pollution control agencies presently working on the regulation of impulsive noise sources. This survey and results from previous work by other researchers are used to derive interim recommendations on weighting scales, generated sound levels, and instrumentation. These recommendations are based on the limited data presently available and may be modified with subsequent investigation of noise generation, propagation, structural damage, and human tolerance.

Jan 1, 1974

By W. P. Yant, R. R. Sayers, G. W. Jones

In the treatment of any illness the early diagnosis is of very great importance . This is especially true in cases of carbon monoxide poisoning , whether acute or sub-acute in character. A diagnosis of CO poisoning is usually made from a correlation of the history , the possible place of exposure , and the symptoms produced . This , however, is not positive evidence because CO often is present in unsuspected places and can be absent in suspected places . Also , the symptoms of this type of poisoning are common to other causes . In many such cases the correct diagnosis may be very difficult , if not impossible by this method and as a result little or no treatment is given . Sub- acute cases , those in which the subject is exposed to concentration sufficient to cause only headaches , malaise , feeling of weakness and dizziness , may be incorrectly diagnosed and as a result , improperly treated . Probably the best method of diagnosis is by examination of the subject's blood . Many methods for the detection of CO in the blood have been developed , but owing to their various individual disadvantages have never come into common usage . Some of the quantitative methods are satisfactory with regard to accuracy but require elaborate and expensive apparatus , special technique and training, or are too delicate and cumbersome for field use . It is of vital importance in all industrial and domestic accidents occuring at places where CO might be suspected or where the symptoms are typical of CO poisoning that a qualitative and preferably a quantitative determination be made the extent of poisoning being of importance in deciding whether CO was the direct or contributary cause) to show the presence or absence of 0. This is indeed essential from a medical standpoint as it aids in prescribing treatment and from a legal standpoint to insure justice in the claims that are often unjustly decided for want of positive evidence.

Jun 1, 1923

By Vernon A. Mrak

The Powder River Basin of northeast Wyoming was the first area in the state to receive attention during the early days of uranium exploration. Although the uranium occurrences are many and widespread, most of the known ore deposits are quite small and difficult to mine. As a result of this, detailed regional exploration in the Powder River Basin has been neglected. The uranium ore deposits occur in that part of the Wasatch Formation that is of earliest Eocene age, and they are scattered over an area of about 400 square miles. All uranium ore deposits are associated with red beds or altered sandstones within the Wasatch Formation. Uranium ore was first shipped from the region in 1953. Total production through June of 1965 is 506,257 tons of uranium ore containing 1,922,527 pounds of U3O8. The average grade of ore is about 0.19 per cent U3O8. The major producing area of the Powder River Basin is the Monument Hill district where about 91 per cent of the basin's total uranium ore has been mined. The source of uranium is presumed to have been the Oligocene, Miocene, and perhaps Pliocene tuffaceous rocks that once overlay the area. Joints, fractures, and permeable beds or zones were the passageways for the migration of uraniferous waters from the overlying beds to the Eocene host rocks.

Jan 1, 1968

By N. Parnian

"Carryover of caustic soda (NaOH) in the steam path caused catastrophic failure of superheater 304H stainless steel tubes in a steam generator and led to an unexpected shutdown after just five months of continuous service of petrochemical following the start of production. The cause of the failure was studied, with a focus on the formation of sigma phase in the weld joint and effect of caustic embrittlement on stress corrosion cracking (SCC). The cracks were examined at the seam weld, heat affected zone (HAZ), and Ubend areas. Hardness was measured for the base metal, HAZ, and weld metal, and microstructures were examined using optical microscopy and scanning electron microscopy (SEM). Crack initiation is attributed to gouging on the precipitated carbide at the HAZ and also the formation of sigma phase in the weld metal, as shown by energy dispersive X-ray (EDX) analysis. In addition, cracking was propagated by caustic embrittlement because of residual stresses and hammering. Finally, the characteristic feature of fracture was illustrated by SEM fractography, and consists mostly of intergranular SCC and some quasicleavage transgranular. INTRODUCTIONThree key factors are needed for the initiation and propagation of intergranular stress corrosion cracking (IGSCC): a susceptible material, a corrosive environment, and sufficient stress. Although austenitic stainless steels are susceptible to sensitization and IGSCC, they are widely used in boiler and superheater tubes because of their high corrosion resistance, high oxidation resistance, acceptable mechanical characteristics at elevated temperatures, and low cost.Sodium hydroxide is injected to neutralize acidic constituents in the steam path, but caustic can concentrate in boiler tubes and attack the surface metal (known as gouging) even traces of caustic in the steam can deposit on surfaces and cause local concentrations of several percent (ASM handbook, 1992). Not only sensitized grains but also sigma phase formed in the weld metal can initiate caustic cracking. In this research, the cause of the failure of 304H stainless steel superheater tubes in a methanol petrochemical plant in Iran was studied with a focus on the effects of caustic embrittlement on IGSCC."

Jan 1, 2012

By R. Darlington, S. Ji

"High pressure die casting is a promising process to make thin-wall components with high dimensional accuracy and excellent surface quality. However, the non-uniformity is one of the important features in castings. The inhomogeneity in tensile properties and microstructural characteristics were studied for the castings with different thicknesses made by high pressure die-cast Al-Mg-Si alloys. For the local mechanical properties in the die-castings, the casting skin provided the highest, whereas the casting centre provided the lowest yield strength, UTS and elongation. The yield strength, UTS and elongation were significantly decreased towards the casting centre. The microstructural inhomogeneity is characterised by the segregation of coarse fragmented dendrites, the reduction of solute concentrations of Mg and Si, and the increase of porosity level from the surface to the centre of castings. The growth velocities of eutectic a-Al phase estimated using the Jackson-Hunt model confirm that the growth variation is larger in the thin castings than that in thick castings.INTRODUCTION Inhomogeneity is an inherent characteristic in as-cast microstructures of a variety of alloys because of their non-uniform chemistry, microstructure, defects, topology and the resultant mechanical properties in the different ranges of localization (Campbell, 2003). Generally, three types of inhomogeneities characterise casting microstructures, which include (a) the casting defects of shrinkage and gas porosity, misruns, cold shuts, inclusions, hot tears and hot spots; (b) the non-uniform microstructure from the surface to the centre of castings; and (c) the non-uniform microstructure from the dendrites grown from primary solidification and the structure formed during the subsequent eutectic solidification in inter-dendritic regions. The chemical composition and the morphology between the primary dendrites and the inter-dendritic eutectics also differ in the as-cast microstructure. Obviously, the inhomogeneity is different in the castings obtained from different casting processes."

Jan 1, 2018

By L. Shasko, M. Hurlbert

As climate change is increasingly perceived as a problem, and fossil fuel based power production options are increasingly limited through regulatory restrictions and public distaste, future options become constricted. Reflexivity and social learning elicited through qualitative and mixed research methods offer important insight into what future power production pathways might be. Given factors of cost, baseload requirements, and energy density, options such as nuclear may be increasingly accepted. This paper explores this literature and possible methods of pursuing the reluctant acceptance of nuclear energy.

Jan 1, 2020

By Frederick W. Breaks, Andrew G. Tindle, Julie B. Selway

"Abstract - Rare-element pegmatites may host several economic commodities, such as tantalum (Taoxide minerals), tin (cassiterite), lithium (ceramic-grade spodumene and petalite), and cesium (pollucite). Key geological features that are common to pegmatites in the Superior province of Ontario and Manitoba, Canada, and in other large tantalum deposits worldwide, can be used in exploration.An exploration project for rare-element pegmatites should begin with an examination of a regional geology map. Rare-element pegmatites occur along large regional-scale faults in greenschist and amphibolite facies metamorphic terranes. They are typically hosted by mafic metavolcanic or metasedimentary rocks, and are located near peraluminous granite plutons (A/CNK > 1.0). Once a peraluminous granite pluton has been identified, then the next step is to determine if the pluton is barren or fertile. Fertile granites have elevated rare element contents, Mg/Li ratio < 10, and Nb/Ta ratio < 8. They commonly contain blocky K-feldspar and green muscovite. Key fractionation indicators can be plotted on a map of the fertile granite pluton to determine the fractionation direction: presence of tourmaline, beryl, and ferrocolumbite; Mn content in garnet; Rb content in bulk K-feldspar; and Mg/Li and Nb/Ta ratios in bulk granite samples. Pegmatite dikes with the most economic potential for Li-Cs-Ta deposits occur the greatest distance (up to 10 km) from the parent granite.Metasomatized host rocks are an indication of a nearby rare-element pegmatite. Metasomatic aureoles can be identified by their geochemistry: elevated Li, Rb, Cs, B, and F contents; and by their mineralogy: presence of tourmaline, (Rb, Cs)-enriched biotite, holmquistite, muscovite, and rarely garnet.Once a pegmatite dike has been located, the next step is to assess its potential to contain Ta mineralization. Pegmatites with the highest degree of fractionation (and thus the most economic potential for Li-Cs-Ta) contain blocky K-feldspar with >3,000 ppm Rb, K/Rb < 30, and >100 ppm Cs; and coarsegrained green muscovite with >2,000 ppm Li, >10,000 ppm Rb, >500 ppm Cs, and >65 ppm Ta. Pegmatites with Ta mineralization usually contain Li-rich minerals (e.g., spodumene, petalite, lepidolite, elbaite, amblygonite, and lithiophilite) and may contain Cs-rich minerals (e.g., pollucite, Cs-rich beryl). The ore minerals of Ta are commonly manganotantalite, manganocolumbite, wodginite, and microlite; Ta-rich cassiterite is also commonly present. Tantalum mineralization tends to occur in albitic aplite, mica-rich (lepidolite, cleavelandite ± lepidolite), and spodumene/petalite pegmatite zones."

Jan 1, 2005

By Jamal Rostami, Tom Iseley, Saleh Behbahani

Tunnels and underground infrastructures assets, like all assets, deteriorate with time. At some point, they reach the end of their useful life. Therefore, frequent inspections, higher levels of maintenance, and rehabilitation are needed to address loss of life and safety concerns. The repair cost of tunnels will increase if maintenance of tunnels is not satisfactory and timely. Historically, tunnel inspections have primarily relied on visual and manual procedures. Due to their time-consuming nature and susceptibility to human error, there is a demand for alternative automated techniques that can enhance efficiency and reliability in tunnel inspection. By utilizing a tunnel scanning system, such as laser scanner and thermography, or photogrammetry system, tunnel inspection cost, time, and personnel can be reduced. The goal of this study is to utilize deep convolutional neural networks (CNNs) for automated identification of defects in tunnel lining inspection. This paper presents a framework to classify two types of defects in tunnel lining (water leakages and cracks) using CNNs. The CNNs were trained and tested using 4,608 images. The Precision, Recall, and F1 Score were each 99.6%, confirming the viability of this approach in the automated defect identification in tunnel lining.

Jun 23, 2024

By Liwen Hu, Jianxun Song, Hongmin Zhu, Qiuyu Wang, Shuqiang Jiao

The subchloride titanium was prepared by sponge titanium and titanium tetrachloride in the CaCl2 at 1173 K. The species were detected are mainly titanium dichloride, and the average valent in the melt are 2.05. The accurate equilibrium constants were obtained for the reaction 3Ti2+ = 2Ti3++Ti after the accurate activities of titanium chloride were evaluated with emf method, and the observed deviations from ideal behavior are discussed.

Jan 1, 2015