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By Nathaniel Herz

PARTING of bullion before shipment to the mint had been considered by the Homestake Mining Co. at various times, but had never been attempted before 1933, be- cause the margin of profit appeared to be too small to warrant the complications in refining. When the gold standard was abandoned by the United States in the spring of 1933, however, parting of the bullion was decided upon. The method selected was the Miller or chlorine process, which consists of the passing of gaseous chlorine into a bath of molten bullion, converting all metals other than gold into chlorides, and remov-

Jan 1, 1935

By Jim Hardy, Tim McKnight

"The thermal mass flow controller, or MFC, has become an instrument of choice for the monitoring and controlling of process gas flow throughout the materials processing industry. In the semiconductor industry, these MFCs are used on over 70% of the processing tools. Reliability and accuracy are major concerns for the users of the MFCs. Calibration and characterization technologies for the development and implementation of mass flow devices are described. Sources of inaccuracy in process gas handling are described, and a model to correct for these inaccuracies is outlined. A gravimetric calibrator is described that allows flow sensors to be calibrated in corrosive, reactive gases to an accuracy of 0.3% of reading, at least an order of magnitude better than previously possible. All described capabilities are implemented in a Department of Energy User Facility which is available to industry and universities to test and develop gas flow sensors and controllers and evaluate their performance related to environmental effects, reliability, reproducibility, and accuracy.IntroductionMaterials processing is at the heart of semiconductor manufacturing. To make today's advanced integrated circuits, silicon wafers are subjected to over 200 process steps. Most of these steps involve processes such as etching, implanting, diffusion, annealing, deposition, and lithography (resist deposition and hardening). Often one or more process gases are used to complete the process step. To achieve the quality and performance required in the micro devices, accurate measurement and control of these gases is essential. The Oak Ridge National Laboratory (ORNL), in conjunction with the semiconductor industry, has been working to improve process gas measurement and control accuracy and reliability. Standardized test methods have been developed to characterize and benchmark the performance of mass flow controllers (MFCs), the method of choice for monitoring and controlling gas delivery. Testbeds have been designed and fabricated to produce repeatable and accurate data using these standards. Baseline testing was performed along with development of a unique mass flow instrument, the gravimetric calibrator."

Jan 1, 1997

By Tanai Marin

Modelling of pyrometallurgical processes can become extremely challenging when the process involves complex chemical reactions, phase change, multiphase flows, heat and mass transfer and fluid flow. Traditionally modelling involving complex thermodynamic equilibrium and thermochemistry are treated separately from problems in which transport phenomena are dominant, such as CFD and heat transfer studies. The separation is also necessary due to the lack of modelling tools that can effectively couple both solution thermodynamic and transport phenomena or even multiphysics problems. However, there are, quite often, problems in high temperature process metallurgy in which it is not possible to simplify this two modelling approaches. Typical cases of this are for example, the modelling of slag freezing on furnace walls (electric or flash furnaces) to create a protective layer in front of the refractories hot wall, the formation of build up from the matte or metal phases at the hearth of the furnace, calcine smelting from charging piles into slag phase, etc. The problem is even more challenging in nonferrous pyrometallurgy as most, if not all, of the condense phases are highly non ideal solutions involving several components and exhibiting complex crystallization paths and miscibility gaps, such as the Fe-Ni-Cu-S matte, FeO-Fe2O3-SiO2, FeO-MgO-SiO2 slags, etc. In this paper, an approach to model coupled problems involving multiphysics and solution thermodynamic is presented. The approach consists in developing in-house a library containing the Gibbs energy minimization routines and using the local equilibrium concept for process modelling from a multiphysics commercial software (COMSOL). Simple test cases, such as building a non-ideal binary phase diagram on a CFD package is presented, the limitations and of other classic approaches such as equilibrium or Scheil cooling are discussed and compared to this model.

Jan 1, 2015

By George A. Morrison

This paper describing the methods of mining and crushing limestone at the West Winfield, Pa., limestone mine of the West Penn Cement Co., is one of a series being prepared by the Bureau of Mines on mining practices, methods, and coats in the various nonmetallic mining districts. HISTORY The limestone deposits of western Pennsylvania have been exploited for many years and have been quarried extensively at West Winfield in Winfield. Township, which lies in the southeastern corner of Butler County.

Jan 1, 1931

By Arthur E. Morris

The primary market driver for improving process technology is innovation, which requires a skilled and educated workforce. However, many Materials Science and Engineering departments have eliminated extractive metallurgy and chemical thermodynamics from their curricula, yet these topics contain the necessary fundamentals for process innovation. As a result, most MS&E students are ill-prepared for careers in processing. The dearth of processoriented MS&E curricula has prompted some Universities to develop a “shared” effort to offer distance education between multiple institutions [1]. A target audience for a shared process simulation course would not only benefit students, but also be a basis for an on-line course for practicing engineers faced with new or changing career choices. To fill the gap, the basics of a process simulation course was developed in an abbreviated form as series of eleven articles and Excel workbooks published in Industrial Heating magazine between July 2012 and July 2013.

Jan 1, 2014

By R Ballantyne, M Adams

Time Usage Models, used as a basis for calculating performance indicators for mobile mining equipment, have developed from very simple to very sophisticated models. This development has paralleled the increased collection and analysis of production data that itself has been enabled by the evolution of underground voice and data communications along with the relevant information systems. A Time Usage Model divides the hours that equipment is (or is not) used into standard components, by a hierarchical breakdown, so that measures of productivity can be used to compare performance of both people and equipment. The calculation of equipment availability, and thus the underlying Time Usage Model, has always been an extremely emotive topic as different groups use time usage information for different purposes. The direct link between measuring performance Key Performance Indicators (KPI) calculated from these models and employee rewards impacts upon the workforce. This paper discusses the conflict in use by various stakeholders and proposes ways to address some of the more contentious issues each supported by case studies. The simple status code functionality used by early systems has proven inadequate, leading to the evolution of “work-arounds”. These workarounds have become the norm and unfortunately have become embedded in the next generation of models and the information systems that incorporate them. This paper contends that the industry should stop building Time Usage Models to accommodate shortcomings in proprietary systems, but rather collaborate with suppliers to develop innovative methods to deal with the fundamental requirements. There are many points of differentiation that are not clear-cut. Pitfalls are discussed as well as threats to success. A framework of rules is developed as guidelines for how a Time Usage Model should be developed and applied. This will hopefully stimulate the on-going discussion as to how Equipment Availability and other components of the model should be calculated.

Mar 15, 2021

Silver bearing bulk sulfide concentrates from several Peruvian mines were autoclaved in a 19 liter (five gallon) laboratory autoclave in Lima, Peru. Cyanidation of autoclaved concentrates following a hot lime jarosite destruction step extracted over 98 percent of the silver and over 95 percent of the gold. Autoclave operating parameters such as time, temperature, pulp density and autoclaved solids recycle were investigated and reaction rates determined. The problems of excessive heat generation, silver solubility during autoclaving, and formation of pellets containing unreacted sulfides were addressed. The data presented will be used to design a continuous autoclave pilot plant to pro-vide reliable scale up data for a 50 -100 ton per day facility.

Jan 1, 1992

By Paul Suver

The closed loop standing column well (CLSCW) system uses a closed circuit of water to develop the same thermal heat exchange characteristics that are achieved from traditional open circuit standing column well that uses the ground water directly. Pipe pile and pipe anchor foundations can be used as CLSCW components for ground source heat exchange. New data gathering and analysis techniques and equipment installed in the heat pumps allow any mechanical engineer to design the system without specialty engineering equipment and certifications.

By William James Kempson

This paper discusses ore handling systems in shafts. These are considered from the loading facility at shaft bottom all the way through to the discharge mechanism in the headframe. These systems will be discussed from the following perspective: i. Intrinsic safety of the systems ii. The efficacy of the systems to perform consistently iii. The maintainability of the systems iv. Overall system cycle times Particular emphasis is placed on the following specific areas: 1. The Shaft Bottom Loading Facilities The various shaft loading systems currently in use are discussed, the selection parameters surrounding these are quantified and the specific selection criteria are outlined. 2. The Various Skip Configurations In this section the various skip configurations in use around the world will be described and the specific design details associated with these will be highlighted. The advantages and disadvantages of these systems will be compared and the overall efficacy of these will be discussed. 3. The effect of the loading and skip configurations on the Load Cycle Times. The overall cycle time which can be achieved by a shaft system is strongly dependant by the speed and efficiency with which the ore can be loaded and transported out of the mine. The potential of the various systems to be optimized will be discussed. The emphasis of this paper is to highlight the lessons which have been learned with respect to ore transport system design and provide a common basis against which these can be compared in future applications.

May 1, 2013

By Paul M. Tyler

The literature on radium is already voluminous, but mcuh of it is too technical to be intelligible to the average reader, and there is no single publication that covers certain economic features of the radium industry. As a result of the renewed interest in the possibilities of domestic carnotite deposits a number of requests have been made to the Bureau of Mines for information, more particularly with reference to the business aspects of the industry. In order to meet this apparent need, the present paper has been prepared from material available in the files of the bureau. The technical data are compiled from various sources and are believed to be reasonably dependable, but the attempt has been not so much to achieve meticulous scientific accuracy as to brim; together facts of industrial significance and popular interest. GENERAL DESCRIPTION Radium is a brilliant white metal that melts sharply at about 700°C. and volatilizes appreciably at that temperature. With an estimated specific gravity of nearly 6.0, it is more than twice as heavy as aluminum and 25 per cent lighter than irons. Although it has been isolated in its metallic state, it is not used in that form, partly because it tarnishes rapidly even in dry air (forming a nitride), partly because of the greater expense of reducing it to metal, and partly because of the difficulty of dealing with such minute quantities of material. It is used always in the form of its compounds, the most important of which from the vie point of utilization are the bromide, chloride, and sulphate.

Jan 1, 1930

By Robert H. King

An analysis of low-voltage shielded trailing cables is performed to develop a method for calculating the differences in operating costs between shielded and non-shielded cables. Two types of shield constructions are considered (SH-C and SH-D) for the three major underground coal mining methods. Data from laboratory and in-mine testing are presented in addition to an analysis of safety benefits. Recommendations for further investigations are proposed. Example calculations with sensitivity analyses are presented. Recommendations for further investigation include costs impact considerations.

Jan 1, 1980

Real economic growth for 1988 may fall short of the 3.3% projected by the Department of Commerce in August 1988 because the summer drought and intense heat in many areas curtailed output more severely than expected. The economy grew at an average annual rate of 3.0% for the first three quarters of the year, slowing in the second and third quarters. Export growth, which occurred even as the dollar edged up compared with other industrial country currencies, was an important factor in the expansion. Notable gains were posted in sales of machinery, computers, aircraft, chemicals, and telecommunications equipment. Imports increased, but not as much as exports, and the U.S. trade position was still much improved from that of 1987. Personal consumption expenditures grew slightly faster than the economy as a whole. Purchases of consumer durables showed notable strength in the first half of 1988, but slowed down in the third quarter. Despite the moderate rise in interest rates, business spending for new plant and equipment also rose and contributed to 1988 gross national product (GNP) growth. Both new business investment and export demand spurred orders for U.S.-made machine tools. Orders for machine tools for the first 8 months of 1988 were almost triple those in the corresponding period in 1987.

Jan 1, 1989

By Joël P. T. Kapusta

Back in 1995, Air Liquide and Union Minière presented a joint paper at the Copper 95 – Cobre 95 Conference in Santiago, Chile, describing the first full scale plant trials of shrouded sonic injection in a Hoboken converter at the Hoboken smelter in Belgium. Almost a quarter of a century later, the technology known as ALSI, or Air Liquide Shrouded Injection, has been tested or commercially implemented in several copper and nickel smelters. Despite these successes, the copper industry did not adopt it widely in the same manner the steel industry adopted the Savard-Lee tuyere in the 1970s and beyond, not even in the way the lead industry adopted it with the Queneau-Schuhmann-Lurgi, or QSL, process. The development and implementation of bottom-blowing smelting and converting technologies in China in the last ten years, however, changed the industry’s perception that high- and ultra-high oxygen injection in copper smelting and converting was indeed possible under specific process conditions. In this paper, I retrace the key learnings of my journey with sonic injection over the twenty five years from my humble beginnings in my early years with Air Liquide, through plant trials and technology implementation in the late 1990s and into the first decade of the new millennium, and ultimately, to the most conclusive proof that the sonic injection design methodology I established is valid, and the calculation tools I developed are accurate. I conclude by sharing my thoughts about whether the deployment of the Savard and Lee legacy within the nonferrous industry was just a pipe dream or whether it will become a reality. INTRODUCTION In the context of lower quality ores and changing economic markets, copper smelters need to continuously innovate and improve to remain competitive and respect their corporate social responsibility engagements. One avenue towards this business, social, and environmental goal is to increase process intensity while lowering fossil fuel consumption to lower greenhouse gas emissions and reducing process off-gas volumes to better capture As and SO2–laden emissions. I believe high oxygen sonic injection for submerged tuyere copper bath smelting and converting is one technology that can help smelters achieve that goal of higher business, social, and environmental performance. Twenty five years ago, when I discovered that the Savard-Lee tuyere had revolutionized the steel industry (Savard & Lee, 1966; Knuppel, Brotzmann, Fassbieder, Savard, & Lee, 1972), I had a dream — or was it a vision? — that within the first decade of the new millennium, modern copper smelters operating submerged tuyere bath smelting and converting vessels will have implemented high oxygen sonic injection and will be reaping the financial and environmental benefits that the steel industry enjoyed in the 1970s. As we approach the end of the second decade of the new millennium, I have to admit that my dream has been all but shattered as the majority of copper bath smelting and converting vessels today continue to operate under bubbling regime conditions. This mode of operation is archaic, still requires tuyere punching and blows at inherently low enrichment levels, particularly in converting, producing large volumes of process off-gases. Under such operating conditions, regulations and emission quotas for As, SO2, and particulate matter oblige smelters to use not just primary or secondary hoods, but sometimes even tertiary hoods. I vividly recall being told, fifteen or twenty years ago when visiting smelters to promote the application of the Savard-Lee tuyere in nonferrous processes, that implementing sonic injection was not economically viable due to the high cost of compressing air and oxygen. Some of the smelters I visited back then have since mandated their engineering partners to design and build secondary or even tertiary hoods. I cannot fathom how secondary and particularly tertiary hoods, with all of their auxiliary equipment and added ducting, could be more economically viable than purchasing and installing a few compressors, expanding the pipeline network for compressed air and oxygen, and installing a new control valve train to feed sonic tuyeres. Besides, adding hoods does not address the problem of As and SO2-laden fugitive emissions at its source but merely provides a costly mitigation for it by capturing larger volumes of process off-gases rather than reducing these large volumes in the first place. Moreover, hooding does not reduce energy consumption nor does it increase process intensity, two aspects that I believe are critical for smelters to remain competitive and sustainable in a deeply changing market environment.

Jan 1, 2019

By Elders. Wilfred A.

Petrological and geochemical methods, the utility of which has long been established in the mining industry, are proving useful and cost-effective in elucidating the thermal evolution of active geothermal fields. In return, they yield insights into sulfide-silicate equilibria, mass and energy transfer in convecting hydrothermal systems, and the genesis of hydrothermal ore bodies. Within the Plio-Pleistocene sediments of the delta of the Colorado River, in the Salton Trough, several active geothermal systems are known. Temperatures vary from 100-365°C, at less than 2 km depth, and salinities vary from 3,000 to 280,000 ppm, total dissolved solids. The hydrothermal alteration causes marked induration of the sediments, producing greenschist facies metamorphic minerals, including hydrothermal ore minerals. Subsurface authigenic minerals show strong correlation with increasing temperature. A typical sequence in sandstones is (below 150°=C) montmoril-lonite-kaolinite, (above 180°C) chlorite + illite, (above 225°C) calc-alumino-silicates, (above 325°C) biotite. There is a transition from porosity-dominated\to fracture-dominated permeability in the hottest and deepest geothermal reservoirs. This regular series of minerals provides a practical tool during exploration drilling. From drill cuttings, we can make predictions on reservoir temperatures, useful in making decisions on well completion. Other types of geothermometry we have employed include light stable isotopes, fluid inclusions and vitrinite reflectance measurements. A combination of these techniques not only improves our temperature predictions, but together with fission tack annealing studies, permits us to model the dynamics of temperature change and fluid flow in these geothermal reservoirs.

Jan 1, 1981

By Ellis S. Hertzog, James R. Cudworth

Tremendous interest has been evidenced in the subject of dewatering and drying ooal for the past 10 years, and yet little effort has been made to summarize the literature, at least so far as this country is concerned. Only a few published articles have dealt solely with dewatering and drying coal. In most cases the subject has been discussed briefly, either in general terms or as to specific installations. It is desirable that a compendium be prepared collecting in one place information on the dewatering and drying of coal, the needs for this process in various fields, the available equipment, and the current American practice in regard to it. This work was underta..lten by the :Bureau of Mines in cooperation with the University of Alabama. New coal-washing plants in which various types of dewatering and drying equipment were in operation were visited in-Pennsylvania; Ohio, India...~a~ and Illinois. The dewatering·and drying of coel has .been studied in this coimtry by the Surface Preparation ·Committee of the ·coal Operato~s• Committee of the .American Mining ·Oongress. In GermaIJY .it has received the special attention of the Reichskohlenr·at, and in Great Britain of the Utilization of Fuel Commi-t-tee of the Insti ti.ite of Min"ing Engineers.

Apr 1, 1938

By A. Romero

"Most underground mines require heating or cooling systems to meet health and safety standards in the working areas. In regions where daily or seasonal fluctuations of environmental conditions exist, these systems tend to be over-sized and operate at low average load factors, which increase both investment and operating costs. One possible approach to reduce the temperature variations of the fresh air supplied to the mine, and so reducing the investment in large heating or cooling systems, is to use rock as a thermal regenerator or thermal storage system. Packed rock beds act as thermal inertial units, damping the atmospheric temperature oscillations to provide a more constant fresh air temperature. However, although regenerators exist in some mines, and packed bed rocks have been studied in detail in solar thermal power applications, there is a lack of tools to design new and sufficiently large storage systems of this kind. This work fills the existing gap by presenting a methodology to design and evaluate the impact on the ventilation systems of these regenerators. The method is validated using existing rock bed systems found in the literature and illustrates possible designs for small and large size regenerators in both hot and cold climates.1 INTRODUCTION “ It is quite amazing how often answers to extremely complicated problems can be obtained in this way, by using greatly simplified models of the real situation for the purpose of calculation.” Whiller, A. in private communication to J. S. Stachulak (1989). Motivation Most underground mines located in regions with extreme climatic conditions require the thermal pre-treatment of the fresh ventilation airflows, whether for heating or cooling. Heating commonly is needed in sites with sub-zero temperatures and is usually effected by direct or indirect burning of natural gas or propane. Alternatively, cooling is required in areas with hot temperatures, or in mines with high underground thermal loads where the fresh air at ambient temperature cannot provide enough refrigeration. Thus, when the ambient air conditions cannot provide by itself enough thermal power to ensure safe underground working conditions, a heating or cooling plant is required, which involves a considerable equipment and operation cost."

Jan 1, 2019

By J. B. Salsman

As part of the research effort on investigating the effects of microwave energy on the chemical and physical properties of minerals and ores, the U.S. Bureau of Mines (USBM) Tuscaloosa Research Center has conducted research to measure the dielectric properties of these materials. The objective was to establish a reliable database for use in predicting the effects of microwave heating on a wide range of minerals. The dielectric constants and loss factors of minerals, commonly referred to as the dielectric properties, were determined utilizing the theory of microwave propagation through an open-ended, air-filled coaxial line that was terminated at its open end with the particular mineral under investigation. In this phase of microwave research, the USBM measured the dielectric properties of powdered minerals with medium to high electrical conductivities in the frequency range of 300 MHz to 3 GHz and as a function of temperature from 25 to 325 °C. Since the minerals were prepared as powders, techniques were used to relate the measured dielectric properties of the powdered minerals to the dielectric properties of the mineral at its theoretical or natural density.

Jan 1, 2010

By A. G. Roach

Introduction The plant described in this paper is located at Coniston, Ontario, the smelting centre of the former Mond Nickel Company. Coniston is situated some eight miles east of Sudbury on the main line of the Canadian Pacific railway and on the Toronto-Capreol branch of the Canadian National-railways. The plant is now under control of the International Nickel Company, as a result of the merger of the two companies in 1929. The smelter proper includes four 50-in. by 240-in. blast furnaces and five 13 ft. by 30 ft. converters, and has a capacity of about 65,000 tons of ore charge per month. As accessories to the smelter there are a mill, where some 10,000 tons per month of low-grade ores are concentrated, and the sintering plant, which is the subject of this paper. The present 6-unit sintering plant replaces a former 4-unit installation. Here, fine ores, concentrates, and flue-dust are sintered on Dwight-Lloyd machines, the sinter produced being charged into the blast furnaces. At the time of writing (1931), only the concentrator is operating at capacity, due to present world conditions.

Jan 1, 1932

By Gary A. Kingston

This examination of Pacific Northwest (Idaho, Montana, Oregon, and Washington) ferrous scrap-industry operations, principally those in Oregon and Washington, points out factors influencing the supply and consumption of scrap materials, such as the complete dependence of steel ingot producers in these States on scrap as a metal raw material and the sizable quantity of scrap exported from Seattle and Portland to Japan. The pattern of the industry is presented as a movement of materials from their diverse sources to the consuming market. The geographic locations of the consuming industries in relation to the areas generating scrap materials and the movement pattern of the supply from source to destination strongly influences the cost of the commodity. The best measure of the scrap supply available in an area is experience in terms of how much scrap was withdrawn at a given price. Scrap availability is not finite, because the return of materials as scrap is secular and influenced by constantly varying market conditions. Steel ingot producers use 75 percent of the approximate 500,000 tons of scrap consumed in Oregon and Washington; steel foundries take 15 percent of the total; and iron foundries, ferroalloy plants, and other miscellaneous consumers utilize the remainder. Also, from 1955 to 1960 an average of about 200,000 tons has been exported annually from Oregon and Washington. The foreign exports are supplemented by lesser shipments to other steel producing States, principally in the western United States. From 1955 to 1960 the preferred and higher value heavy melting scrap grades accounted for about 60 percent of total withdrawals which varied between 600,000 and 950,000 tons annually. Total crap withdrawals from Oregon and Washington are projected to 1.8 million tons by 1985, 60 percent (1.1 million tons) of which will be heavy melting grades. No. 1 heavy melting scrap is most attractive to scrap consumers at $35 per ton or less. Price-supply relationships compared with projected scrap requirements indicate future prices possibly over $35 per ton. High prices over a long period could motivate the Pacific Northwest scrap consumers to produce steel from iron ore. However, technologic changes taking place at integrated steel plants could reduce scrap withdrawals from the Pacific Northwest, which might keep the scrap price sufficiently attractive to obviate production of competitive iron products by the Pacific Northwest scrap consumers.

Jan 1, 1964

By Larry M. Southwick

There is much ongoing work in research and development of new processes for the recovery and recycling of met.a.ls and other materials from various waste and scrap streams. Commercialization of such new technologies requires the bringing together and successful execution of a considerable effort involving a variety of activities. These include process conceptualization, research and development, detailed design and construction, and then plant startup and operation. Processes evolve through all of these steps by engineering due diligence, making objective and critical analyses of results, and troubleshooting processing steps to, hopefully, arrive at a sequence that has the best chance to succeed operationally and economically. After a summary review of the above steps, several processes will be described in more detail that provide mostly successful examples of the above procedures. Finally, some observations will be made on areas that will become critical in the near future to the success of new processes for wastes and residues.

Jan 1, 2000