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By Joseph A. Holmes, Henry Kreisinger

At the Mining Experiment Station of the U. S. Geological Survey, in Pittsburg, an investigation of the process of combustion is being carried on in a specially-designed furnace having an unusually long combustion-chamber. This work is conducted by a con~mittee consisti~lg of 11. Kreisinger, mechanical engineer; Dr. J. C. W. Frazer, chemist; and Dr..J. K. Clement, physicist. The problem, essentially one of physical chemistry, is estremely interesting to all who are concerned in the burning of coal or the construction of furnaces. The main object of these experiments is to ascertain the relation between the amount of' the volatile combustible driven from the coal and the combustion-spaces necessary to burn it completely. Our best steam-coals vary from 15 to 45 per cent. in volatile matter and from 40 to 75 per cent. of fixed combtistible. The greater part of the latter is burned on the grate: but the volatile combustible leaves the freshly-charsed coal and must be burned in the combustion-space. If this space is not large enough, the volatile combustible mill leave the furnace only partly burnecl, and the result will be a considerable heat-loss and a smoky stack. Strictly speaking, the factor which determines the completeness of combustion of the volatile matter, after it has been mixed with a certain amount of air, is the length of time the mixture is allowed to remain in the combustion-space; but this length of time depends on the extent of the space itself. Let us suppose, for instance, that, when a given coal is burned at a certain standard rate, the volume of the volatile combustible driven oft' per second is 10 cu. ft. Adding, say, 10 cu. ft. of air, the volume of the resulting burning mixture is increased to 20 cu. ft. If the combustion-space is 30 cu. ft., the burning mixture will stay in it,

Jan 1, 1911

By E. C. Winegartner

In producing and selling coal, the coal company is faced with many different parameters by which the quality of its product is evaluated. One type, which we choose to call the economic parameters, includes moisture, ash, sulfur, and Btu's. These are reasonably well understood by both the coal supplier and the customer, and the dollar values can be placed on them. This is the group of parameters of primary interest to most purchasing agents buying coal. A second group of parameters governs how the coal will behave in the boiler itself and is of primary concern to the engineers designing the boiler and to the men who must operate and maintain it. Since we have not yet learned to put dollar values on these parameters, they generally show up in coal contracts simply as cutoff points, the purchaser simply saying that he will not accept coal outside of certain limits.

Jan 1, 1975

By Matthew D. Marks

"The Sacramento Area Flood Control Agency initiated the Natomas Levee Improvement Program in 2006 which would bring the entire 42 mile Natomas Basin perimeter levee system into compliance with applicable Federal and State standards for levee protecting urban areas. The soil-bentonite slurry cutoff has been utilized as the primary construction method for addressing the under seepage deficiencies. To date, a combined total of over 4,500,000 square feet of slurry cutoff wall have been constructed utilizing excavation methods to a maximum depth of 75 feet and deep soil mixing methods to a depth of 90 feet. The construction of these cutoff walls has required the use of newly designed and custom built long boom and stick attachments for large hydraulic excavators and additional resource will be required to complete future phases. Key components of the NLIP program have included advancements in the development of soil-bentonite backfill mix designs, specified ranges on the soil backfill gradation to address concerns of long term consolidation of the backfill material, evaluation of the trench slurry filtrate loss with regard to cutoff wall acceptance, maintenance high slurry densities to provide greater trench stability, and continued development of backfill mixing procedures.IntroductionThe Natomas Levee Improvement Program (NLIP) was initiated by the Sacramento Flood Control Agency (SAFCA) in 2006. The long term objective of the NLIP is to provide 200-year level flood protection to the basin. To date, approximately 21 of the 42 mile Natomas Basin perimeter levee system has been completed, totaling over $100,000,000 in construction contracts, of which slurry cutoff walls make up approximately $25,000,000. Other construction elements include excavation and removal of unsuitable levee materials, raising or widening existing levees, construction of landside seepage berms, drainage canals, and miscellaneous structures.Although each construction phase of the NLIP includes various construction elements of levee restoration program, the slurry cutoff wall is the primary construction element for addressing the under seepage deficiencies. To date, approximately 4,500,000 square feet of slurry cutoff walls have been installed using excavation and deep soil mixing (DSM) methods. This includes approximately 2,000,000 square feet of slurry cutoff wall along 5 miles of the NCC South Levee and 2,500,000 square feet of slurry cutoff wall along 16 miles of the Sacramento River East Levee (SREL). The work has been completed under 8 separate contracts, through SAFCA, and performed between September 2007 and December 2012. A summary of the contract phases and associated cutoff wall square footage is provided in Table 1. Most of the work has been performed within the seasonal dry weather period in the Sacramento valley, which occurs between April and October. This has required much of the work to be performed on an aggressive construction schedule, year after year."

Jan 1, 2017

By Mortimer J. Richardson, Earl H. Malmstrom

INTRODUCTION The art of placer gold mine evaluation and mining has had an interesting evolution beginning in earliest times. DE RE METALLICA (c.1556), documents the use of rockers, circular sieves(jigs) and riff lest for classifying, concentrating and recovering placer gold, respectively. During the late 1800's in the heat of the international gold rush, a bucket ladder mining dredge containing its own processing plant was developed that enabled digging of placers to bedrock that were inaccessible to the hand miner. The power driven churn drill was developed at about the same tie that facilitated more rapid and larger scale sampling of placers to bedrock. The mineral jig was applied in the early part of the 1900,s to begin the replacement of riffles on placer dredges. Mining dredges proliferated in California and New Zealand to mine the deeper placers and spread throughout the world. The companies that were leaders in dredge mining technology conducted experimental work that advanced the state of the art by processing of gravels with jigs and amalgam systems to recover gold on board dredges in a continuous process. This paper will synthesize the technology of placer gold exploration, mine development and operation into guidelines for evaluation and development of small-scale prospects. Prospect Reconnaissance The location of a prospect usual1 y results from some physical evidence of the presence of gold and/or past mining activity. Any earlier activity that may have produced gold from the prospect, should be investigated before making the trip. The initial reconnaissance should attempt to verify a near-surface presence and then make observations concerning the geomorphic characteristics that relate to placer gold accumulation. Estimates of the probable depth, breadth and length of mineable gravels can be made from the surf ace by the experienced placer mining engineer. With this information, he can speculate on whether there is a viable prospect to be pursued. The placer mining engineer should be experienced in panning samples found in shallow diggings or from existing pits. This will give him immediate indications of gold presence without fear of "salting" by an over-ambitious promoter of the project. The same capability of panning is important during the other sampling phases. A thorough knowledge of logging and calculating the results is essential to proper evaluation of the deposit' s tenor. Evaluation Methods Depending upon the character of the prospect such as river, benches, terraces, jungle, the type of equipment to conduct sampling of the deposit must be determined. In most cases, the drill has replaced bulk sampling. The churn drill has had the greatest amount of accumulated experience but is slow. The reverse circulation drill (RC), is limited by its lack of verification in subsequent mining in order to prove its reliability. However, in the hands of knowledgeable placer mining engineers experienced with its use and calibration, it may be used. The RC Hammer drill (such as the Becker), can be as much as ten times faster than the churn drill and compress the time necessary to prove a prospect, or, to disprove it. All costs in balance, it is often cost effective over the churn drill.

Jan 1, 1987

By William Wraith

The availability of computer resources and data management technology, together with the prudent use of scientific management concepts, has made it possible to achieve important improvements in the control of maintenance and materials activities in the mining and minerals processing organization. The introduction of minicomputers and. the greatly improved efficiency of computer systems in general have put the use of computer technology within the reach of even the smaller mining companies which probably could not have afforded them just five to ten years ago. A number of progressive companies have implemented computer-based maintenance, purchasing, and supply inventory control systems. Using modern safety stock, demand forecasting, parts reliability analysis, and other control concepts, these new systems have helped minimize production losses by reducing the frequency and severity of supply shortages and unplanned repairs. At the same time, these systems are helping to conserve scarce capital resources by better utilization of supply inventory investments, reduced expenditures for maintenance, less frequent equipment replacements due to improved maintenance reliability, and greater capacity utilization of existing facilities.

Jan 1, 1979

By K. L. Purdy

Electron spectroscopy for chemical analysis (ESCA) was used to determine the-surface characteristics of products from operating Pb-Zn-Cu concentrators on the New Lead Belt of southeast Missouri and pure galena and sphalerite samples treated-with flotation reagents in concentrations similar to those used in the mills. The emphasis was on the action of surface modifiers such as Na2Cr207, starch, SO2, CuSO4 and NaCN in sphalerite flotation and in the galena-chalcopyrite separation. The objective of the investigation was to monitor the relative oxidation states of the mineral and reagent constituents and correlate these surface concentrations and oxidation states with flotation theory and practice. ESCA was able to follow the action of all the modifiers except NaCN. The existence of PbCrO4 on the surface of galena conditioned with Na2Cr207 was verified. The Pb in the bulk PbS-CuFeS2 scavenger concentrate was found to be significantly more oxidized than the Pb in the bulk PbS-CuFeS2 rougher concentrate. ESCA was found to be most useful for investigating the actions of modifiers rather than collectors due to the large amounts of sulfur and background carbon already present on the mineral surfaces. After calibration for the particular chemical system of interest, ESCA can yield semi-quantitative analyses of the oxidation states of many elements (except hydrogen, and helium) present in the outer 10 to 25 A of a sulfide mineral surface.

Jan 1, 1975

By Israel Liebman

The Bureau of Mines conducted an investigation to determine those factors that are significant in affecting the velocity of flames propagating along the boundary separating gaseous fuel and air. In addition the aerodynamic motion of the gases in the vicinity of such interfacial flames was delineated. Parameters in the study included flammable zone thickness, flammable zone concentration of gradient, fuel type, and position of the flame relative to various environmental surfaces. Of all these factors, the flammable zone thickness and burning velocity of the stoichiometric mixture were found to have the most significant effect on the flame speed. Notion of the gases in the vicinity of the interfacial flames was examined by particle track and interferometric techniques. The relative velocity of the interfacial flame with respect to the unburned gas on the central streamline was found to equal the burning velocity of a stoichiometric homogeneous fuel-air mixture. In addition, it was observed that the composition of the lean fuel-air mixture at the boundary of the combustion zone appears to be less than that defined as the fuel's lower flammable limit.

Jan 1, 1968

To improve the ventilation of large-opening under-ground stone mines by using stoppings made from stone left in place. Background Underground stone mines typically use large room-and-pillar openings with little ventilation control. Stone miners may be exposed to contaminants that include silica dust, diesel particulate matter (DPM), exhaust gases, nuisance dust, and face shot (blasting) fume gases. The health risks from breathing these fine particles and toxic organic materials are well documented. Although contaminants such as dust or diesel exhaust can be some-what controlled at the source, the escaping contaminants are often diluted and removed from work areas using ventilation with minimal controls. In many cases, current mine ventilation practices use trial-and-error techniques to improve ventilation. The growing realization of the importance of a healthy work environment along with increased regulations will require many stone mines to implement new ways to improve ventilation. In-place stone stoppings are one option. Mine air flows from one point to another because of a pressure differential between those points. This pressure differential is established using a mechanical fan in conjunction with separations (stoppings) between high-pressure (intake) and low-pressure (return) airways. The separation of intakes and returns is an important concept that is used in most other types of mines. Normally, air moves through underground stone mines with minimal control technology. Fans are placed in locations where they are thought to be most beneficial, and intakes are not separated from returns. In a few smaller underground stone mines, proper ventilation can be achieved with a few strategically placed fans. However, as these mines increase in size, moving adequate quantities of air through-out the mine becomes harder, and separation of intakes and returns becomes a problem. Building traditional mine stoppings to separate the intake and return airways in entries with a cross-section area often exceeding 800 ft2 is difficult. The stoppings must be able to withstand both the dynamic pressure from face shots and the static pressures created by the fans. Construction and maintenance difficulties, as well as high costs, are the main factors preventing these traditional mine stoppings from gaining wide acceptance by the stone mining industry.

Dec 1, 2002

By A. K. Kuhn

In virtually all jurisdictions, comprehensive environmental protection regulations or standards are in place that apply to all industries, including mining. The only other legitimate mine-permitting concern is post-mining land use (PMLU). PMLU includes all uses of land after mining as well as the ecosystems appropriate for those uses. Although flawed, the New Mexico Mining Act (NMMA) of 1993 is a PMLU-based permitting statute. It requires measures during closure that will establish a PMLU or self-sustaining ecosystem for each mine unit. PMLU-based permitting avoids prescriptive, one-size-fits-all measures and keeps permitting focused on the legitimate goal of responsible land management..

Jan 1, 1999

By Yuanbo Zhang

Zinc leach residues produced by hydrometallurgical zinc plants contain many valuable elements (zinc, iron, lead, gallium, indium silver, etc), while they have not been utilized effectively hitherto. In this paper, a new process of flotation-reduction roasting-magnetic separation to recover these valuable elements from zinc leach residues is developed on a basis of mineralogy investigations of them. The results show that silver concentrate with grade of 4321.6 g/t and recovery of 80.69% have been obtained, using 1750 g/t Na2S as conditioner, 750 g/t ammonium dibutyl dithiophosphate and SN-9 (assistant collector) as combined collector and 100 g/t terpenic oil as frother, if zinc leach residues with 523 g/t silver are floated at pH = 5.0. When the flotation tailings are subjected to reduction roasting at 1100? for 2 h, the volatilizations of zinc, lead and indium are over 96%. After roasted products are treated by wet-grinding and magnetic separation, the grade of gallium and gallium in the concentrates achieved respectively reaches 1805 g/t and 1536g/t, and the recovery of them is high to 94.67% and 93.20%, respectively.

Jan 1, 2006

By Gerhard Lang

"Slurry Microtunneling is a well-established technology building on over 20 years of experience in successful tunnel installations under all kinds of soil conditions across the U.S. and Canada. Recent microtunnel installations prove that initial hesitation, e.g. curved drives, is fading and long-distance pipe jacking projects as well as lake outfalls are being considered. One of the younger technologies is Direct Pipe®, which combines the benefits of HDD and Slurry Microtunneling. It fits exactly into the area where HDD is not feasible or too risky to apply. The paper points out the benefits of the Direct Pipe® technology for owners, engineers and contractors and discusses the latest developments of Slurry Microtunneling for long-distance, curved drives and sea/lake outfalls with wet recovery of the equipment such as on the ‘Keswick Outfall Project’ in Ontario. The first Direct Pipe® installation in the US was executed in August 2010. Since then, another 22 crossings have been carried out amongst a total of more than 60 Direct Pipe® crossings worldwide. INTRODUCTION Pipelines installed underground are indispensable for supplying the growing world population with water, oil, gas and electricity, for removing wastewater and for providing functioning telephone and communications networks. During recent years the limits of trenchless applications have been permanently shifted, leading to higher and more stringent project requirements and consequently new technologies, either as further development of existing methods, or through the development of new methods by incorporating elements of proven technologies. MICROTUNNELING TRENDS IN NORTH AMERICA Slurry Microtunneling has a wider geological application range in comparison to EPB and hard rock Microtunneling. The Slurry MTBM can be equipped with specific cutting wheels to cope with different soil conditions. The most flexible and most often employed type is the mixed soil cutting wheel, which contains a mixture of disc cutters as well as scrapers for varying soil conditions from cohesive soils (clay, silts) to highly permeable soils including sands, gravels and cobbles and even hard ground formations such as rock and boulders. A detailed geotechnical report provides the appropriate data to configure the MTBM and its features to the ground conditions expected. Mixshield or hydroshield (AVN/AVND) MTBMs in particular, can be safely operated with little overburden (~ 3-5 x machine diameter) and minimum risk of frac-out or settlement on the surface. This is especially beneficial in urban areas with sensitive buildings or for river crossings with protected fish habitats."

Jan 1, 2016

By H. O. McDonald

The Bureau of Mines reviewed the chemical vapor deposition (CVD) literature of the group IVB, VB, and VIR elements. This review was utilized in the Bureau's research to provide erosion-, abrasion-, and corrosion-resistant coatings for valve components used in coal gasification units. This report attempts to bring together the many CVD references that have been published since 1966. Each of the group IVB, VB, and VLB metal coatings were reviewed, and some of their preparation methods, uses, and properties are given. A total of 160 references were found for the nine elements. Isotope separation, stronger steels, solar absorbers, alloys, superconductors, optical fibers, and coatings to increase the life of materials are some of the new uses for CVD.

Jan 1, 1979

By B. A. Firth

The presence of misplaced ultra-fine particles has been shown to decrease the separation efficiency of unit operations used in coal preparation. Although the classification of fine coal was considered to be adequate for the needs of the coal industry during the 1970's and 1980's, it has become apparent that further improvements in the yield/ash/moisture relationship achieved by coal preparation plants will require increased efficiency in this size separation step. This paper describes the issues which are evolving in this area, and the capability of current and developing techniques to address the problems which need to be overcome.

Jan 1, 1996

By S. K. Sharma, R. Markandeya, G. Venkateswara

"In this study, a three level Box- Behnken factorial design combined with Response surface methodology (RSM) for modeling of process parameters of Multi Gravity Separator (MGS) for recovery Iron values from sub grade iron ore, Deposit No. 5, Bailadila complex has been developed. The three significant operational parameters of MGS, Drum rotational speed (RPM), Drum inclination (degrees) and quantity of wash water (LPM) were considered in the experimental work. Other parameters like feed percent solids, shake frequency and shake amplitude were maintained constant. The ‘as received’ sub grade iron ore sample is admixture of lump and fines and chemically assayed 40.80% Fe, 40.90% SiO2, 0.24% Al2O3 and 0.22% Loss on Ignition (LOI). The obtained results were evaluated with the Box-Behnken factorial design, RSM and also Quadratic programming(QP). Second order response functions were produced for Fe in terms of grade (%) and recovery (%) of the concentrate fraction. Taking advantage of QP, it was observed that maximum grade of 62.21% Fe achieved at an inclination of 4.3degrees, 2.7LPM of wash water and at a drum speed of 198 RPM. Similarly a maximum Fe recovery of 65.37% weight can be achieved at 4.3degrees inclination, 2.6LPM wash water and at a rotational speed of 212 RPM Predicted values of responses obtained using model equations were in good agreement with the experimental values. The influence of the process variables of the multi gravity separator concentrator on grade and recovery of concentrate fraction were presented and discussed."

Jan 1, 2014

By Mayfield P. L J, Honeyands T. A

BHP's two million tonne per annum nominal capacity Hot Briquetted Iron (HBI) plant at Port Hedland in the Pilbara region of Western Australia is based on FINMET¦¦ direct reduction technology. The FINMET¦¦ process produces direct reduced iron (DRI) by reacting fine iron ore with reformed natural gas in a series of fluid bed reactors and then hot briquetting this DRI into dense, high quality iron briquettes. The Port Hedland HBI project represents a major investment in the chemical processing of Australian minerals to higher value products prior to export to Asian markets. This paper describes the FINMET" process and technical aspects of the high-quality HBI product, and provides an update of the current status of the project.

Jan 1, 1999

By Erik Bengtsson

Phenol was discovered in coal tar by Runge (1)1/ in 1834 and was isolated (2) in 1841 as pure phenol by distilling the tar, extracting with caustic soda, acidifying the extract, and fractionating the tar acids. Later, o-cresol was isolated (3) through careful fractional distillation of the tar-acid mixture. The m-and p-cresols distilled within a boiling range of about 1.50 c. and had to be separated by other means. Raschig (4) fractionated the tar-acid mixture to obtain pure o-cresol, sulfonated the mixture of m-and p-cresols, and treated the cresol-sulfonic acids with superheated steam at 1200 to 1300 c. to hydrolyze the m-cresol sulfonic acid, the p-isomer was not affected at that temperature. He also attempted to make use of the different crystallizabilities of the m-and p-cresol sulfonic acids (5). When treated with sodium bisulfate and sodium pyro-sulfate at 100° to 110° C. or with sulfuric acid (90/0) at 20° C., only the m-cresol was sulfonated (6). Hoffman-La Roche (7) treated the meta-para mixture with concentrated sulfuric acid at 40° to 100° C., when m-cresol and part of the p-cresol was sulfonated, and precipitated the m-cresol sulfonic add by diluting with water. The same sort of separation may be carried out by means of 80 percent sulfuric acid at 35° C. and 35 mm pressure (8).

Jan 1, 1950

Meeting of June 26, 1914.-The President was authorized to appoint Advisory Committees to co operate with the United States Bureau of Mines. The President announced the appointment of Edward H. Benjamin and W. C. Ralston as additional members of the Committee on Arrangements for the San Francisco meeting, 1915. H. T. Van Ells and Judd Stewart were appointed to represent the Institute on a joint committee of several technical societies to consider the standardization of graphical methods for the presentation of statistics. The President announced the appointment of H. Foster Bain to succeed Edward H. Benjamin, resigned, on the Committee of Management of the International Engineering Congress, 1915. The Secretary was authorized to issue a new circular advertising the sale of back Transactions and to sell back Transactions, bound in cloth, at a price of $35 for 46 volumes, provided sufficient orders were received to warrant the special binding. The sum of $177.50 was contributed to the San Francisco Local Section. Upon recommendation of the Committee on Membership, 70 Members, 4 Associate Members and 7 Junior Members were elected to their respective classes; there was also one change of status from Junior Member to Member.

Jan 8, 1914

By Harrison AT, Smart RM

Backfill systems using unconventional cementitious hinders have been successfully used in relatively deep and hard rock tabular mines for longwall, scattered stoping and shaft pillar removals. Two unconventional cementitious systems are discussed: 1. A ground granulated blast furnace slag (GGBS) with an activator containing lime. This has been used with a total tailings 'stable' slurry at a relatively low dosage of less than seven per cent, by mass, based on dry solids. The room and pillar stopes supported with this fill were up to 20 in high and the tailings were relatively high in pyrite. .\ GGBS binder plus a silicate based activator and gelling agent that virtually eliminated all water drainage (and hence post filling shnnkage). The system used a slurry, but the addition of the ;iutivator created a final placed product that had the behaviour of a paste. The system has been successfully used for almost ten years in the following applications: ò sloping widths (mining heights) above 1.6 in; and ò shaft pillar removals in seismically active areas at the end of the life of the shafts. \This paper discusses the technical merits and costs of the systems and compares them to other fill systems (including true paste systems).

Jan 1, 1998

By C Hamilton

Stawell Gold Mines (SGM) is an underground mining operation located in Victoria, Australia. The mining method employed is long hole retreat stoping, utilising up and downholes and artificial concrete pillars. Stawell is currently mining the Golden Gift and Magdala orebodies.Access to the Magdala and Golden Gift deposits is via 6.0 m wide by 5.5 m high declines developed at a gradient of one in eight to one in seven from the surface to a depth of 1500 m, with a planned depth of 1650 m. From the declines, cross cutting drives are developed to intersect the orebodies. Orebodies in the Gift system are discrete lodes which are generally mined from a bottom up centre retreat to minimise geotechnical stresses.Ore development fronts are currently located between 1000 m and 1500 m below surface, with all ore being hauled to the surface using a fleet of 60 tonne underground trucks. With the use of conventional pyrotechnic long period (LP) delays, broken rock of combined ore and waste is thrown 10 m from the face and the materials hauled to the surface. The majority of the mullock from development is consumed in the underground as backfill.With the use of Orica Mining Services eDev™ Electronic Blasting System for Tunnelling, the waste is thrown up to 40 m from the face, while majority of the ore is left 5 - 10 m from the face, effectively segregating ore and waste. This enables significant recovery of gold values with minimal loss and significantly reduced dilution. By using this technique in ore drives with a 30:70 waste to ore ratio, SGM is able to haul 24 000 tonnes less mullock to the surface annually. Resue mining is applied to narrow vein headings and gives a 40 per cent grade increase at the faces as well as increasing the economic footprint of development. This will also contribute to an improved grade profile for the year from 3.98 - 4.16 g/t Au and allow extra capacity for ore haulage from stoping and for milling.This paper describes the application and the successful blast outcomes achieved using the eDev™ Electronic Blasting Systems for resue mining at SGM. Results to date, since commencement in March 2010, have been achieving significant benefits in terms of ore grade as confirmed by geologists grab sample grades. Face advance have also shown improvement with better breakage of perimeter holes giving improved face profile. These benefits are delivering increased productivity and safety performance when compared to other resue firing techniques.

Mar 21, 2011

By T. Tamagawa

A gaseous chlorination process for hydrometallurgical treatment of a chalcopyrite concentrate was investigated. The overall process is visualized to consist of low temperature chlorination-selective oxidation, followed by aqueous chloride leaching and SX-EW for producing electrolytic copper elemental sulfur and ferric oxide. In this article, the chlorination phase of the processes is described. Initially, the chlorination behavior of chalcopyrite-concentrate micro-pellets was investigated using a small batch-type fluidized bed reactor. The optimum conditions thereby established was used in continuous chlorination tests. The chlorinated products thus prepared were used in the selective oxidation phase of the investigation.

Jan 1, 1999