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By T. Suzuki

Acid leach liquors from spent lithium-ion batteries employing lithium cobalt dioxide (LiCoO2) as a cathode active material contain valuable metals such as cobalt and lithium, as well as common metals such as aluminum and copper. The objective of this study was to develop a hydrometallurgical process providing a high selectively between aluminum, cobalt, copper, and lithium from hydrochloric acid solutions. Batch experiment results showed that selective hydroxide precipitation approach was not suitable because a significant amount of cobalt and lithium was co-precipitated with aluminum and copper hydroxides. In contrast, batch experiments and the subsequent data analysis indicated that the sequence of solvent extraction circuits using PC-88A, Acorga M5640, and tri-n-octylamine (TOA) extractants effectively separates four metals of interest. In the first circuit of the proposed process, copper was selectively extracted by Acorga M5640 at the pH 1.0-2.0. Aluminum, cobalt, and lithium remain in the aqueous phase. In the second circuit, aluminium is selectively extracted by PC-88A at pH 2.0-2.5. For the separation of remaining cobalt and lithium, Acorga M5640 provided higher separation efficiency compared to PC-88A single extractant and PC-88A/TOA mixed extractant. However, the stripping efficiency of cobalt from the Acorga M5640 organic phase was found to be low (less than 10 %). Therefore, PC-88A/TOA mixed extractant rather than Acorga M5640 is an advisable choice for the separation of cobalt and lithium. Keywords: spent lithium-ion secondary batteries, solvent extraction, lithium, cobalt

Sep 1, 2012

Reduce the potential of haulage related injuries in underground mines by providing a method for quickly assessing the state of repair of mine haulage track. The Problem Currently, there are no established standards or procedures for inspection or cleaning of underground mine haulage track. Many track defects are hidden from an inspector because of layers of dirt and debris on the ballast, spikes, fishplates, etc. When a visual inspection can be performed, it may be highly subjective, except for a few items that can be categorized or counted, such as missing bolts or spikes. Track inspectors may even become tolerant of defects that can gradually worsen. For these reasons, mechanical inspection methods are needed to supplement visual inspections. Approach The Bureau investigated this problem and designed a towed vehicle to both mechanically clean and inspect underground coal mine haulage track. The vehicle was developed using a systems approach, paying particular attention to human factors issues such as operator field of view, operator ingress-egress, control positioning, and seating design. The prototype was built using simple fabrication techniques and off-the-shelf components.

Jan 1, 1990

By G. H. Gale, M. A. F. Fedikow, L. B. Dabek

Abstract-Rare earth element (REE) data are reported for ores, sulfide-bearing rocks and host rocks from massive sulfide deposits and barren sulfide facies iron formations in Proterozoic volcanic rocks of the Flin Flon-Snow Lake area, Manitoba. Some of the rare earth elements (e.g., Eu), are selectively leached in zones of intense alteration and redeposited together with the sulfides and silicates in the uppermost parts of the alteration zones and at the rock-water interface. Chondrite normalized REE profiles of layered sulfide ores and exhalites proximal to the deposits typically have positive europium anomalies and are enriched in light REE. In contrast, barren sulfide facies iron formations exhibit negative or ‘normal’ Eu profiles. REE data are useful to explorationists in determining the presence of ‘off-hole’ metal-bearing sulfide zones, in distinguishing metal-poor sulfidic layers related to ‘economic’ hydrothermal activity from barren sulfide facies iron formation and in some instances as a means of establishing ‘ore-equivalent’ strata.

Jan 1, 1997

By Justin R. Patts, Andrew B. Cecala, A. KYLE LOUK, Emily J. Haas

The U.S. National Institute for Occupational Safety and Health (NIOSH) and the former U.S. Bureau of Mines (USBM) have put significant effort over the past four decades into researching and developing engineering controls and interventions to reduce mine workers’ dust exposures during the bagging and palletizing of industrial minerals. Workers who perform the manual bagging and palletizing of 50- to 100-lb bags typically have some of the highest dust exposures of all workers at mining and mineral processing operations. This paper provides an overview of available dust control technologies for bagging operations and presents the findings of a recent case study conducted at four industrial sand operations to identify the current types of bagging and palletizing technologies being used and to evaluate their effectiveness in reducing workers’ exposures to respirable crystalline silica dust. An evaluation is also performed to determine if further reductions in respirable dust levels can be achieved by incorporating additional modifications or improvements into the existing technology.

By A. S. Chekmarev, T. Z. Lygina, K. G. Egorova, A. V. Skvorcov

"We have conducted analytical and technological evaluation of sepiolite containing clay. The possible areas of application of the sepiolite have been investigated and complex methods of enrichment of natural sepiolite have been identified. It was determined that for preserving the structure of minerals after processing the most effective method of the natural agglomerates disintegration was the soft abrasion of the clay fraction up to 0,5 mm. Disintegration of sepiolite clay along with using high energy-stressed effects on the matrix can deteriorate the rheological properties of clay suspensions and reduce the yield of drilling mud and sorption properties. To improve the quality of clay powders we used combined gravity-modifying method of wet enrichment. After the wet enrichment the yield of drilling mud increased up to 12.7 m3/t, with the addition of MgO up to 20,3 m3/t. It was noted that drilling muds contenting more than 50% of sepiolite are stable in mineralized (salt) waters. Based on the studied activated sepiolite rocks we obtained the effective heat-insulating materials with relatively low thermal conductivity – 0,165 W/m·K, average strength – 7,29 MPa and water absorption-49,0%.INTRODUCTION The modern development of the Russian economy requires the implementation of scientific and technical tasks. The solutions of it involves a radical reduction in energy, heat losses and material consumption of products, rational and efficient using of all types of resources, as well as the using of new types of mineral raw materials and materials based on it. An example of a new type of mineral raw materials for Russia is sepiolite containing rocks, due to unconventional conditions for their soils accumulation in the climate of the Far North. Sepiolite is a unique type of nonmetallic mineral. It is formed in soils, marine and saline basins, occurs in carbonate and carbonate-clay rocks in the form of lenses and lens – shaped layers, rarely nodules, loose powdery masses, shell-like concretions. Sepiolite may have a soft porous macroscopic appearance or less often the structure of the fibrous mass. Color of sepiolite is from white to cream with gray, green, pink and even crimson shade depending on the degree of pollution. Sepiolite can be in two forms - a-sepiolite (parasepiolite), which occurs in the form of large packets of crystalline fibers and ß-sepiolite, which occurs in the form of amorphous aggregates or small flat rounded particles. The sepiolite fibers have a length of from 0.2 to 2 Å, width from 100 to 300 Å, the thickness from 50 to 100 Å (Geological dictionary, 1973)."

Jan 1, 2018

By D. B. Dowling

The interest which has been aroused in prospecting for oil in the foothills of southern Alberta, and in the oil possibilities of the known gas fields situated in the less-disturbed areas, called for a much closer examination of the structure, thickness, and composition of the underlying rocks of the region than had hitherto been made. The areal geology of the larger part of the great plains was outlined by Dawson, McConnell, and Tyrrell, between 1881 and 1885. The foothill area was not critically examined at that time, owing to the time which would have been required for its proper study and the difficulty that was found in recognizing in the foothills the divisions which had been adopted in the mapping of the formations of the plains. This was due in great measure to the paucity of exposures in continuous sections of the lower divisions of the Upper Cretaceous. Since the pioneer work on the plains was published, the beds which form continuations south into Montana have been critically examined, The Canadian beds arch over the end of a flat anticline which rises to the south; and two sections in Montana, one on each side of the anticline, help to explain some of the difficulties previously encountered in the mapping of the measures found in the foothills. The index map, Fig. 1, shows the area studied, and its relation to southeastern Alberta, and to Montana. Problems of Correlation The principal difficulty experienced in correlation was in connection with the measures known as the Montana group. The beds of this group did not seem to agree in the two Montana sections. They showed the same differences to some extent as are encountered in comparing the foothill measures with those of the plains. The Montana group in Dakota and Manitoba consists of a series of shales of marine origin. In the eastern Montana section two sandstone members appear, leaving a shale member at the top and another

Jan 1, 1916

By O. C. Blade

"INTRODUCTION This report on the properties of motor fuels sold through service stations in the United States is a continuation of a series of reports made in accordance with a cooperative agreement between the Coordinating Fuel Research (CFR) Committee of the Coordinating Research Council (CRC) 3/ and the Bureau of Mines of the United States Department of the Interior. The first of these reports presented data on motor gasolines sold during the winter of 1935-36.4/ Further reports were issued describing motor gasolines sold during the succeeding sum¬mers and winters to and including the summer of 1941.4/ No reports were made on motor gasolines sold during the winter of 1941-42 and during the summer of 1942. However, starting with the winter of 1942-43, the semiannual reports were resumed.!The present report presents analytical data for 4,544 samples, represent¬ing the products of 124 companies. The samples represented in this report were obtained during December 19146, January and February 19-(. As in previous surveys, the companies covered Ly the survey include both large and small suppliers. Conforming to former reports, the data cover three groups of samples - regular-price, premium-price, and third-grade gasolines.As the number of analyses submitted for samples of third-grade gasoline are not considered adequate to represent this type of motor fuel, data for the analyses have not been averaged, but the individual items are tabulated. The number of samples, items, and brands comprising each group is as follows: Regular-price, 2,368 samples, 319 items, and 113 brands; premium-price, 2,172 samples, 289 items, and 106 brands; third-grade, 4 samples, 4 items, and 4 brands. The meanings of these terms as used in the surveys are as follows:"

Aug 1, 1947

By Kazuya Nakabo

In this article, influences of restraint and MgO content on densification of alumina-magnesia castable during heating were experimentally studied. High thermal expansion-alumina-magnesia castable specimens were surrounded by low thermal expansion-alumina-silica castables, and heated in an electric furnace. Doing so allows restrained heating of alumina-magnesia castable. According to the results of simple calculations, the restraint stresses were estimated to be between 2 to 20 MPa, so the experimental conditions were considered reasonable. As a result of the experiments, it was verified that restraint densifies alumina-magnesia castable, resulting in an increase in modulus of rupture and modulus of elasticity. The densification effect of restraint became larger as the MgO content increased. The effects are attributable to an in-situ spinel forming reaction, which improves corrosion resistance.Taking the temperature distribution in the castable lining into account, large restraint stress is expected for the hot face while only a little effect is expected for back end. Thus, excessive difference in material property in the thickness direction, which is undesirable in terms of structural spalling, is a concern.Hence, the MgO content of alumina-magnesia castable should be determined carefully, taking not only corrosion resistance but also spalling resistance into consideration.

Oct 30, 2017

By V. B. Chernyavsky, Ladokhin S. V.

Equipment and continuous casting technology for the production of small diameter copper rods and tubes are described. Industrial copper wastes, such as scrap and shavings, were used as the charge. An electron-beam installation for rod and tube production includes a crucible with an electromagnetic stirring system and a pouring hole in its bottom, a bottomless mold, .and a special cooling system, which includes an oil and water cooling devices. For the first time in the electron-beam technology, rods of 8 mm and 14 mm diameter mm tubes of 14 mm external diameter and 7 mm internal diameter were produced through continuous casting by pulling them out of the vacuum chamder into the atmosphere with depressurizing the vacuum chamber. The production capacity of a single strand continuous casting machine was 200 mm/tnin for rod casting and 150 mm/min for tube casting.

Jan 1, 2000

By Nikhil Dhawan, Débora Moreira, Yogendra Pratap, Himanshu Tanvar

A glauconitic siltstone sample with a potash content of 10% is investigated as a potential potash source. The fine grain structure comprises potash bearing phases of glauconite, muscovite, and microcline. The as-received samples showed poor dissolution ~ 5%. Planetary ball milling was attempted for the dissociation of the underlying silicate structure for the potash release, and ~ 60% potash was obtained after 12-h milling. Mechanical activation (8 h, 60% NaOH) prior to heat treatment (600 °C, 30 min) was found successful in recovering more than 95%K values from glauconite. The final residue consists mainly of quartz, indicating a complete breakdown of the silicate matrix. The mechanical activation process followed is simple, adaptable, and less energyintensive compared to existing methods.

May 4, 2020

By Gabriel Zarate

Mantoverde is a heap leach-SX-EW plant that was commissioned in December 1995 at a production rate of 42,130 tonnes of copper per year and 5.4 million tonnes of ore per year. Copper production was steadily increased reaching a maximum of 62,239 tonnes in 2012 for an ore throughput of 10,5 million tonnes. In order to get these production and throughput rates, a number of changes have been made in the metallurgical parameters of the plant operation since the start up, among them particle size, heap height, acid addition distribution in curing and leaching solution, leach cycles and pad type. Most of the modifications have been implemented after carrying out extensive column test work programs. The modifications implemented and the results obtained, as well as the test work programs carried out, are discussed in this paper.

By Thomas L. Hurst, Joseph M. Hans

INTRODUCTION The former Shiprock uranium mill site is located in the community of Shiprock, New Mexico on a bench overlooking the San Juan River (Figure 1). Both Shiprock and the mill site are located on the Navajo Indian Reservation. The millsite was built on a 230 acre tract leased by Kerr-McGee Oil Industries Inc., and was operated from 1954 to 1963. The Vanadium Corporation of America and its successor, the Foote Mineral Company, operated the mill from 1963 to 1968. During its entire operation, 1.5 million tons of uranium ore was milled producing 3711 tons of U308 concentrate. The concentrate was sold to the former U.S. Atomic Energy Commission. During milling, the ore was crushed to less than 35 mesh and acid leached to remove the uranium. The [ ] uranium was removed from the leach solution by solvent extraction and the uranium-barren solution discharged into raffinate ponds for disposal by evaporation and seepage. The spent solids (tailings) were pulped with waste process fluids and water and discharged to form tailings piles. The piles (ponds or dams) were formed with earth starter dikes. The dike walls were then raised using the separated sand fraction of the tailings. The slime fraction of the tailings were discharged into the diked impoundment. Since only a small fraction (0.25 percent) of the ore was U308 by weight, most of the ore bulk ended up as wastes. The wastes contain nearly all of the uranium decay chain radionuclides present in the ore except uranium. The mill was shut down and partially dismantled before the lease expired in 1973, and the remainder of the mill and wastes reverted back to the Navajo Tribe which was the lessor. Portions of the millsite were then occupied by the Navajo Engineering and Construction Authority (NECA), a Tribal enterprise. In order to provide skilled personnel to operate earth moving equipment, a heavy equipment operator's training school was also established on the mill site and was administered and operated by NECA. The U.S. Public Health Service (PHS) and the Environmental Protection Agency (EPA) staff conducted radiation surveys at four inactive uranium millsites on the Navajo Reservation in April 1974. During the survey of the Shiprock millsite, it was noted that the training activities were degrading its radiological condition. Both the PHS and EPA staff recommended that the training activities be directed towards the decontamination of the millsite area and interim stabilization of the tailings piles. Preparation for the decontami-nation work commenced in April 1974. In order to facilitate the decontamination activities, the mill site and its contaminated environs were divided into major areas labeled A through F (Figure 2). Areas A, B, and C are defined as "perimeter" areas and contained surface contamination ranging from 5 to 30 cm deep. Area D defined the mill yard and contained contamination ranging from 0.6 to 5.5 m deep. Area E contained several raffinate ponds which were removed to line up the northwest boundary of the tailings pile and to move the contaminants away from the vicinity of the occupied on-site buildings. The contaminants in Area E ranged from 0.05 to 5.5 m in depth. Area F encompassed the ore storage yard. Contaminants in this area ranged from 0.18 to 1.2 m deep. Washes, however, had contamination exceeding 7.6 m deep.

Jan 1, 1981

By V K. Singh, G Sural

The problem of spontaneous heating/fire is very common in coal mines all over the world. The coal industry faces many problems day by day due to the occurrence of spontaneous heating in the open pit coal mines. Presently, about 70 per cent of total coal production in Indian mines is being carried out by open pit mining. Fire in coal, particularly in open pit mines not only causes irreparable loss of natural wealth but also damages the surface structures and pollutes the environment. It is well known that 75 per cent of the fires occur due to the spontaneous combustion of coal. Spontaneous heating is a very common occurrence in coal mines and is a major factor contributing to mine fire. The liability of coal to spontaneous heating causes many serious problems before, during and after mining. In opencast mines, coal immediately oxidises and catches fire due to the intrinsic characteristics of coal, such as low rank, high moisture, high volatile matter, presence of sulfur in the form of pyrites, low crossing point temperature (CPT) and ignition point temperature (IPT) value and less incubation period. In opencast mines, when the coal benches are left idle for a longer time, heat accumulation takes place in favourable conditions and sometimes leads to fire. The purpose of this paper is to present the different successful case studies regarding the safety management of open pit coal mines from occurrences of spontaneous heating/fire.

Jan 1, 2007

By Hoda Emami

In this study, a combined pyrometallurgical and hydrometallurgical technique has been designed and used to recover rare earth mixture elements (REE) and cobalt from a NdFeB magnetic waste. while addressing the cost of reagent and process facility. This process can be adjusted to different magnetic wastes regardless of their compositions. Prior to the leaching, the magnet scrap was pretreated by two rounds of roasting (750°C in air) and a mechanical grinding in between, to convert iron metal to ferric oxide. Subsequent leaching was performed using optimized conditions (pH, temperature and retention time) where the extraction ratio of REE to Fe III is the highest. After removing iron content from the leachate (pH ≈ 3), REE was precipitated selectively and purified further. The produced REE concentrate reaches 99% purity with 85% recovery in a single run. The cobalt oxide was isolated from the PLS as a by-product with 99.8% purity.

By Manuel Alvarado, David Nemir, Jan Beck

"Thermoelectric generation using special N-doped and P-doped semiconductors is well known as a means for direct heat energy to electrical energy conversion without the need for moving parts. The technology is used today in niche markets for low level electricity production and has been proposed as a scalable means for capturing large scale energy from waste heat streams. The choice of geometry of the thermoelements and conductors is critical to the successful implementation of a waste heat recovery system in order to manage losses due to Joule heating and diffusive heat flows. This paper describes a simulation study to define the performance impact of different aspect ratios for the active thermoelements and the electrical interconnect. The use of a finite element model that incorporates the intercoupled heat and electrical energy flows highlights some of the issues impacting scalability.IntroductionThermoelectric phenomena arise out of the intercoupled electrical and thermal currents in a material. A two-element thermoelectric generator is depicted in Figure 1. It is constructed by connecting an N-type thermoelement and a P-type thermoelement in electrical series, with both elements in thermal parallel between a heat source and a heat sink. The electrical series connection is made by attaching conductors as shown. Ideally, these series connection elements will be both good thermal conductors and good electrical conductors.The two element generator in Figure 1 is disposed between two thermal reservoirs: the heat source, which furnishes heat energy; and the heat sink, which absorbs heat energy. Heat energy flux Q, flows from the heat source to the heat sink, driven by the temperature difference between the source and the sink. As depicted in Figure 1, when a resistive load, R, is attached, electrical current, I, may be extracted from the thermoelectric generator and furnished to the load. The N-type and P-type thermoelements, are the active portions that do the actual conversion of heat energy to electrical energy. Although thermoelements may be built using conductors such as bismuth and antimony, higher efficiency thermoelectrics are built using heavily doped semiconductors. Thermoelectric devices are generally formed by connecting many pairs (couples) of N and P type thermoelements in electrical series and in thermal parallel. A commercially available module having 127 couples (254 elements) is shown in Figure 2."

Jan 1, 2011

By Nutter R. S.

A methodology has been developed for qualitative safety hazard evaluation and quantitative reliability analysis of mine monitoring and control systems. Detailed application of these techniques were made to two commercial monitor/control systems and to a West Virginia University distributed microprocessor-based system. A controlled environmental test was conducted on a set of one of the commercial system's outstations. A software reliability evaluation methodology was also developed and applied.

Jan 1, 1982

By L. M. Tavares, H. A. Petit, P. P. Cavalcanti

Iron ore pellets experience degradation during handling due low energy impacts and stresses. These impacts lead to volume or surface breakage of the pellets, creating fine particles that accumulate along the process. Some of the particles are in contact with the air and are dragged as dust into the workplace or into the atmosphere. The aerodynamic size of the particles allows them to be potentially inhaled by the workers or to be carried to nearby communities. Dust emission becomes critical at specific locations, such as transfer chutes and stockpiles. This work models the dust generation that occurs in an iron ore pellet stockyard using a methodology that combines experiments to quantify the degradation of the pellets to mathematical modelling of the dust emission mechanisms in the stockyard. First, laboratory tests were used to characterise the amount of mass and the particle size distribution of the dust generated by degradation under controlled conditions. Second, the flow over a stockpile of an iron ore pellet company was simulated with the aid of computational fluid dynamics (CFD) simulations. Third, semiempirical equations linked the data generated by simulations and laboratory tests to estimate the dust emission in the stockyard. Finally, results were validated with measured field data, obtained with a novel online measurement tool. Results suggest that the approach is able to predict dust emission with sufficient accuracy and can be used for further implementation in the management of operations and decision making in order to reduce the environmental impact of the process. Keywords: Iron ore pellets, abrasion, dust emission, mathematical modelling

Jan 1, 2020

By Deni Pageau, Deni Caron

"This paper describes the operations of the open pit and emphasizes particular aspects of Les Mines Selbaie. The open pit as well as its related services were incorporated into a complex which includes an underground mine and a concentrator. The equipment was chosen with the objective of auto-sufficiency during each phase of mining. The paper outlines the organization and the methods used in each step of mining, notably: drilling, blasting, loading, transporting and crushing. The responsibilities of the Engineering Department are also outlined from the conception of the open pit to the latest follow-up methods. A short resume of the results which have been obtained as well as suggestions for improvement are provided.Layout in Consideration of Main SiteThe A-I zone deposit is located I km from 8 zone. Open pit mining of A-I zone required the regrouping of different services to those already existing.I. The crusher was placed in an area close to the concentrator in order to minimize the length of the conveyors and to provide space for the crushed ore reserves (50000 tonnes).2. The location of the service building (warehouses, mine offices, maintenance, engineering and geology) raised a few problems. Because of the multiple services provided therein , it was impossible to fulfill all the requirements, and the garage in itself is located a fair distance from the pit. Added to this inconvenience is the fact that heavy equipment regularly travels throughout the main yard.3. The storage of explosive magazines has been changed to obtain more surface space and meet government regulations.4. A space has been provided for minor repairs in the garage used during exploration. A trailer was installed next to the garage to provide a lunch room for the employees working at the open pit."

Jan 1, 1990

By Samuel S. Adams

The Permian Salado Formation of west Texas and southeastern New Mexico is composed of halite and subordinate amounts of anhydrite, clay and potassium and magnesium-bearing evaporite minerals. Aspects of the geochemistry of the Salado Formation have been investigated through studies of the stratigraphy, mineral assemblages, textures and minor element content of the salts. These studies provide information on the origin of the evaporites when combined with data on equilibria in saturated salt solutions. The principal potash ore zone in the district is composed essentially of halite (NaC1) and sylvite (KC1). Data on the color, bromide content, and proportions of halite and sylvite suggest that this simple assemblage is the product of a series of replacements rather than primary precipitation. The bromide content of the salts also indicates that the brine which precipitated the Salado Formation was derived from the dissolution of older evaporites rather than the simple evaporation of sea water.

Jan 1, 1966

By Qiang Zhong, Bin Xu, Qian Li, Wei Gao, Yongbin Yang, Yaxuan Wang

Lump coal with high volatility is used for providing heat and reductive gas, and ensuring permeability in COREX. However, it is apt to be pulverized in transport and storage process. Therefore, comprehensive utilization of the pulverized coal to produce coal briquettes with appropriate binders is significant, among which the molasses binder cannot meet the technological requirements. In this paper, coal tar pitch binder and BJ additive were used in briquetting and carbonizing process of coal powder. The results showed that BJ effectively activated cold state cohesiveness of the pitch and make it bond the coke particles to a firm briquette at room temperature .Carbonizations of coal and coal tar pitch achieved obvious constriction and formed a carbonized skeleton. The drop resistance of wet briquettes reached over 50 times/1meter. When cured at 1000 °C for 1h under nitrogen atmosphere, the compressive strength of carbonized briquettes came to 6.43 Mpa.

Jan 1, 2016