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By Shanxi Wu, Jialong Li, Haoyu Hu, Jiqing He, Zhaohui Wang, Bochao An, Shenyi Zhang

There are a large number of thick alluvium and thin bedrock deposits at depth in the Henan coal base. The degree of surface mining is high, and the surface environment is seriously damaged. Using indoor experiments, numerical simulation, and field measurement, it is studied the influence of the mechanical properties of thick alluvium on the surface subsidence characteristics of thick alluvium thin bedrock deposits at depth, taking Zhaogu No. 2 coal mine as the research background. The results show that the compressive strength and elastic modulus of the alluvial layer are linearly negatively correlated with the alluvial layer particle size, linearly positively correlated with the confining pressure, and nonlinearly positively correlated with the loading rate. The thickness of the alluvial layer has the greatest influence on the displacement of surface subsidence and the range of surface subsidence. The advancing mining rate of the working face has the greatest influence on the surface horizontal displacement. The mechanical properties of the alluvial layer affect the evolution characteristics of the caving arch and towering roof beam. The influence range of the 11012 working face is about 550 m, β is about 55.5°, and the maximum subsidence rate of the surface is 12 mm/day. The mining process and separation grouting can be adjusted to control the overburden displacement to reduce surface disturbance and protect the surface ecological environment. The research results of this paper can provide a research basis for the study of surface subsidence under similar geological conditions.

Apr 28, 2024

By Reginals W. Burroughs

Diatomaceous or infusorial earth, also called diatomite; fossil meal, or kieselguhr, is derived from the lowest form of vegetable life, the unicellular alga:. It consists of the siliceous remains of extremely minute aquatic plants, which exist in both salt and fresh water. Light i~ a prerequisite to their development. These very small particles secrete silica in much the same way that molluscs secrete lime to form their shells. The diatoms at death sink to the bottom of the body of water in which they lived, and the organic matter gradually decays and is washed away, leaving the skeletons. Thousands of years are required by this means to develop bed5 of sufficient thickness to be of commercial value. The siliceous remains vary in size according to the species, but all are very minute and, as a general rule, they can be identified only under a high-power microscope. Over one thousand types have been distinguished and named. They are all composed of a hydrous or opalescent form of silica, with silica content ranging from seventy to ninety-five per cent. Magnified, they present an attractive sight, a very fragile structure with many interstitial openings known as cells. Many of them consist of two parts, defined as valves, held together by means of a girdle. Certain species, belonging to the Pinnularia family appear as a long comb, in half longitudinal section. The spaces between the teeth are the cells. This particular genus is very common in Nova Scotian deposits.

Jan 1, 1928

By Lilong Zhu, Shaoda Zhang, Qian Wang, Shengping He

The effects of ZrO2, Y2O3 and Sc2O3, which are transition metal oxides, on the melting temperature, viscosity at 1300 °C, and break temperature of three mold fluxes (two weak-reactive type and one non-reactive type) designed for the high manganese and high aluminum steels, and one another conventional CaO-SiO2 based mold flux is studied. The results indicate that the melting temperature and viscosity increases slightly, and the break temperature increases dramatically with the addition of ZrO2, Y2O3 and Sc2O3 content in the conventional CaO-SiO2 based mold flux system. While, the addition of ZrO2, Y2O3 and Sc2O3 in the weak-reactive or non-reactive mold flux systems has a negligible in fluence on the melting temperature, viscosity and break temperature, suggesting that these transition metal oxides are possible to regulate radiation heat transfer without changing the basic properties of mold fluxes.

Mar 1, 2018

By Guangliang Wu, Dongchang Huang, Xinbin Liu

Oxidation Kinetics of SPHC was analyzed by TGA, and the curve of oxidation weight gain with different temperature was acquired. It is found that, when the oxidation temperature is between 500 and 600 , all the curves are linear; when the oxidation temperature is above 700 , the curves are close to parabolic. At the temperature of 900 , the oxidation weight gain increases dramatically. The TGA results indicate that the activation energy of SPHC steel is 146.19 kJ/mol at the temperature of 500 900 , and an oxidation kinetic model was set up for variable temperature. Based on the temperature change during rolling process, numerical simulation of oxide scales evolution was carried out for SPHC steel, and the simulation result agreed well with measured ones. It can provide a basis for estimating the scale growth and controlling the temperature on site.

Jan 1, 2016

By Petrus van Staden, Dragan Milanovic, Francisco Sánchez, Eero Kolehmainen, Carlos Frias

"Currently there is no economical and viable process for on-site metal extraction from Low Grade, Complex or Poly-metallic deposits, and even more, there is not any industrial process or technology able to deal with polymetallic or bulk concentrates containing Cu+Zn+Pb base metals and also precious metals. Traditionally, metals recovery from polymetallic sulfide deposits is performed by mining, selective flotation to separate Cu, Pb and Zn concentrates, and finally, smelting/refining of those concentrates to obtain the refined metals. In many cases, selective flotation of that kind of complex ores produces low metals recovery and low concentrate quality containing impurities such as Hg, As, Bi, etc., which results in high penalties in treatment and refining charges, and consequently, worsening the economy of the mining business. Recovery of the valuable metals from Polymetallic, Complex or Low Grade ores could then be maximised by producing bulk concentrates or middling flotation products to feed novel hydrometallurgical processes, like the integral metallurgical system that is currently under development within the INTMET project. For example, producing bulk concentrates would increase more than 100% Cu+ Zn+Pb cumulative recovery versus conventional selective flotation. Founded by the Horizon-2020 EU Programme, the INTMET Project was started in February 2016 and will be running over three years. The INTMET consortium is led by Cobre Las Cruces (Spain) and integrates twelve partners from seven EU countries, and including Serbia and South Africa as well. The INTMET project represents a challenging opportunity to develop suitable technological solutions to deal efficiently with difficult, polymetallic and complex sulphide ores that are abundant in Europe and worldwide. Main activities carried out during the first 18 months of the INTMET project development includes: (i) An atmospheric leaching pilot plant having a capacity of 300 kg/h bulk concentrate which has been installed and operated continuously for nine months at the Las Cruces mine; (ii) Pressure leaching test work developed by Outotec; (iii) Bioleaching test work performed by Mintek in collaboration with MMI Bor. Prior test work was applied on bulk concentrate samples supplied from Spain, Portugal and Serbia. Some of the results of these technological developments have been very positive and are presented in this paper."

Jan 1, 2018

By L. Henry Smith, David C. Arthur

The Williams Mine is Canada's largest gold producer, with annual production of 14,000 Kg (450,000 ounces) from 2,300,000 tonnes of ore. Highly mechanized and automated underground mining practices are employed in order to achieve and maintain high levels of productivity and minimize costs. The Mine Ventilation System is modified to include a new Vent Raise and Variable Pitch Vane-Axial Fan. This addition allows several fan installations underground to be decommissioned. A substantial net savings in installed horse power is achieved. Heating costs associated with underground ventilation air are a significant portion of mine operating costs. Air heating costs are substantially reduced by recovering heat from upcast exhaust air, mine water and compressor cooling circuits. This waste heat is used to supplement propane fired air heating systems for underground ventilation air. An additional benefit is the availability of a heat sink for summer cooling of the compressors. System design, energy savings data and payback calculations are presented.

Jan 1, 1997

By C. R. Masson, M. L. Pearce

The nitrogen contents of seven specimens of iron and steel were determined by the three methods. Good agreement won generally observed between the results of the isotope -dilution and Kjeldahl determinations, tltzts establishing the reliability of the isotope -dilutzon technique. For some specimens, the vacuum-fusion values at 1650 °C were lower than the corresponding Kjeldahl values by up to 0.0015 pct absolute. These differences were eliminated for a specimen of "pure" iron by performing the vacuum-fusion analyses at 2100 ° to 2240 °C. The reason for this relatively high temperature required m the vaczium-fusion analyses is discussed. ThE determination of nitrogen in iron and steel has been the subject of numerous investigations and a concise review of the extensive literature in this field has recently appeared.' Two methods of analysis are most commonly employed, the vacuum -fusion and the chemical or Kjeldahl method. Except in special cases where the presence of certain alloying elements may present difficulties, both methods are generally regarded as applicable, although the vacuum-fusion method is more sensitive and is often preferred for samples of very low-nitrogen content. The method of isotope dilution, first employed for the determination of gases in metals by Kirshenbaum and Grosse,2 has recently been applied to the determination of nitrogen in iron and steel.3,4 The method is attractive in that it does not require the quantitative extraction of gas from the metal specimen. Staley and Svec3 modified the standard Kjeldahlpro-cedure by introducing, along with the steel sample, a measured amount of ammonium sulfate enriched in the isotope 15N. The nitrogen content was obtained by measuring the isotopic ratio 15N/14N in the resultant solution. The technique involved the distillation of nitrogen as ammonia from alkaline solution and subsequent oxidation of NH4+ in the distillate to gaseous nitrogen. The results for iron and steel samples of commercial origin were often in reasonable agreement with values quoted by the suppliers, although occasional marked discrepancies were observed, particularly with the results of vacuum-fusion analyses. Preliminary work in this laboratory4 on the determination of nitrogen by isotope-dilution in the gas phase yielded results for three samples which were significantly higher than the values obtained by vacuum-fusion. The present paper describes an extension of this work to a wider variety of samples. Analytical results by the Kjeldahl method are also reported. EXPERIMENTAL The technique employed for the isotope-dilution determinations was similar to that described elsewhere.4 Several minor modifications were made to the apparatus. These included the use of molybdenum instead of platinum-rhodium suspending wires when crucibles were degassed at temperatures above 1600°C. The circulatory system used previously for converting CO to CO2 was replaced by a single chamber, the walls of which were cooled directly in liquid nitrogen. Temperatures were measured with an optical pyrometer which had been recently calibrated and, as in the previous study, were minimum values obtained by sighting on the center bottom of the crucible. Temperatures obtained by sighting on the interior walls were always higher by 100' to 130°C with the design of crucible employed. Flat-bottomed crucibles exhibited an even larger temperature difference. To check the efficiency with which crucibles were degassed in the isotope-dilution apparatus, several experiments were done in the vacuum-fusion apparatus, suitably modified4 for isotope-dilution studies. Faster pumping speeds and higher degassing temperatures were possible, the latter due to the use of a generator with a higher power output (10 Kva at 398 kc per sec). In these experiments the combustion of CO was omitted and a correction4 was made for the contribution of CO to the ion current at m/e 28, used in determining the isotopic ratio R = l5NP4N. This correction did not seriously influence the re-

Jan 1, 1962

By Joseph M. Driscoll

After 30 years of successfully mining gold, Newmont Gold has temporarily ceased production from the original Carlin Pit. In late 1993, the Carlin East decline was driven and an extensive underground exploration program was started. Today, Newmont Gold produces refractory ore from the Carlin East Underground at the rate of 864 t/d (950 stpd). Annual production is more than 3.1 t (100,000 02). More than 70 underground miners will be employed during Carlin East's estimated six-year mine life. About 70% of the ore at Carlin East is mined by mechanized longhole stoping with delayed, cemented backfill. The remaining ore is mined by underhand drift and cemented fill methods.

Jan 1, 1997

By Forrest T. Moyer

INJURY experience and related employment information are presented in the chapter for the coal-mining, coking, oil and gas, peat, and native asphalt industries in the United States for 1964. No attempt has been made to combine these data and present injury-frequency rates reflecting the mineral-fuel industries because the hazards of the separate industries are not comparable. All rates in the text are calculated separately on data before rounding, hence component rates may not add to the total rates shown in the tables. Tabulations showing the trend of injuries and employment for all mineral industries are presented in Volume III. COAL Injury experience of the coal mining industry was improved in 1964, as measured by the declines of 1 and 14 percent, respectively, in the frequency and severity rates. Although the total number of injuries increased in 1964, a slightly greater proportional increase in man-hours worked caused the frequency rate to drop to 44.65 per million man-hours. The injury-severity rate in 1964 was 7,832 days lost per million man-hours of exposure. Employment and injury data for 1964 are based on final data for anthracite mines and preliminary data for bituminous coal and lignite mines. Fatality experience improved significantly with a record low number of 240 deaths in 1964. This total was 44 less than in 1963. The Nation's coal mines during 1964 were free of major disasters (a single accident resulting in the death of five men or more) for the first time since 1956. The

Jan 1, 1965

By Ramanathan C, Prasad P. V. S. R

The most critical challenge for any large size storage structures to be constructed on soft compressible soils is bearing capacity and consolidation settlements. Consolidation is the time dependent phenomena, as expulsion of water from soil voids on application of external load will take longer period. It is mainly influenced by soil consistency, permeability, thickness of compressible stratum and presence of free draining layers. This study deals with the foundation solution of a large size Mounded Storage Vessel (MSV) to be constructed on thick compressible stratum whose loading intensity is around 155 kPa and the estimated settlements are greater than 400 mm. Hence, the foundation solution using vibro stone columns is adopted as an effective technique to address the challenges of excess settlements and inadequate bearing capacity. Further to keep settlements within the permissible limit of 50 mm, preloading technique with 60% of actual loading intensity will be utilized. The consolidation analysis of stone column reinforced foundations is carried based on the method given by Han and Ye (2001). The quality of the stone columns is ensured by real time quality control measures and the performance of the stone columns shall be ensured by vertical load tests. Ground settlements was closely monitored with proper instrumentations and the actual degree of consolidation has been verified by Asaoka’s (1978) method.

Sep 1, 2022

By Robert L. Davidoff

Growing domestic and global demands for mineral resources have established an imperative need for developing comprehensive, versatile mineral supply analysis evaluation tools. The Minerals Availability System (MAS) of the Bureau of Mines is meeting this need with its computerized Supply Analysis Model (SAM). This paper describes the SAM system and the quantitative methods used by the MAS for mineral supply analyses. The MAS evaluating process consists of deposit identification, tonnage and grade determinations, engineering and cost evaluations, financial analyses, and supply curve generation. MAS has developed this computerized system primarily to facilitate the maintenance of data information for the constructing of commodity supply curves. The SAM system presently has the analytical capabilities of simultaneously (I) evaluating many mineral deposits, (2) updating mineral supply information to reflect inflationary changes in costs and prices, and (3) conducting sensitivity analysis to determine impacts on mineral supply under various conditions. Many potential users in both government and industry will find the SAM system a valuable tool for policy analysis, forecasting, and planning. The SAM system has been constructed so that any types of information that are similar to the data elements in the MAS data base may be used to perform supply studies. The storage space needed for the SAM system?s programs, files, and output data is approximately 14 million characters.

Jan 1, 1980

By Robert Dunne, John Angove

The physical properties of an ore body require determination for virtually all mining projects, new and existing. The extent and regularity of such determinations being subject to the size and homogeneity of the orebody. Such properties have an impact at the design stage of new plants, with respect to equipment specification, and thus effects capital costs; and also impacts on the operating costs of new and existing plants, with respect to power consumption, production levels and part replacements. All of these can severely alter the bottom line and can be the determining factor in the economic viability of many projects. This paper examines some of the most common properties that are measured, the procedures utilised in determining these properties, and their variability under conditions of reproducibil­ity, and to a lesser extent repeatability. The properties looked at were Impact Crushing Work Index, Abrasion Index, Bond Rod Mill Work Index and Bond Ball Mill Work Index. A number of testing laboratories throughout Australia and the US were utilised in the survey. The results showed up some interesting and important features of the procedures used, all of which have become accepted industry standards, and which had varying effects on the final result. Tests such as the rod and ball mill indices would appear to have reasonably robust procedures which allowed for the determinations of the respective index without the introduction of significant variations, although there were indications that variations could occur. The other tests gave a sufficiently different picture to be able to suggest that an argument could be made for a more intensive investigation to be undertaken, with the possible outcome that a modified test procedure or an alternative test is required.

Jan 1, 1997

By T. W. Eddy

Research was conducted in which elemental mercury and its sulfide mineral (cinnabar) are removed from a copper sulfide concentrate by low temperature thermal applications. The goal of this research was to reduce, volatilize, and collect mercury vapor from concentrated smelter feed in a simulated drying environment while maintaining the chemical integrity of the residual. The study used synthesized concentrates composed of copper sulfide and mercury bearing minerals (such as cinnabar (HgS) or elemental mercury) to determine optimal residence times and temperature ranges.

Jan 1, 1996

By Howard N. Egan

EASTERN COAL CORPORATION is located in the heart of the Appalachian Mountain area of extreme Eastern Kentucky, The mountains are of sedimentary origin, and have been deeply eroded by streams as the area has been thrust up during geologic time. There are many seams of coal interspersed between beds of shale and sandstone. While some of the seams are thin, there are a number that can be economically mined. We are mining the Pond Creek, or No. 2 Gas Seam, at a rate in excess of 6,000 tons per day. Our central preparation plant utilizes tromp baths for the plus 3/8" size and Rheolaveur for the minus 3/8" portion. No provision was made to recover the fine coal, which was included with the plant effluent pumped to a 12 acre refuse pond. The pond is impounded behind the coarse refuse dump. This pond rose 15 feet last year. Obviously, no pond could stand many years at this rate. Limited pond space in this rugged area of steep hills and narrow valleys dictated a revised disposal method. Our first thought was that it would be necessary to dry the fine refuse sufficiently to permit inclusion with the coarse refuse, which is hauled uphill by monitor and then trucked to final disposal.

Jan 1, 1967

By Frank Marotta, Louis B. Lesem, Frank Greytok, John J. McKetta

Although one of the primary variables in the calculation of the flowing bottom-hole pressure in gas wells from surface measurements is the temperature at any point and its distribution in the flow-string, only few experimental data are available in the literature and little attention has been given to analysis of the problem. Virtually all of the recently published methods of calculating flowing bottom-hole pressures depend on the assumption that either the temperature is constant at some average value or that the variation is linear with depth. The purposes of this work are to analyze the problem theoretically and to verify the analysis by comparison with experimental data so that practical problems in the analysis of the behavior of gas wells can be solved with greater accuracy, reliability, and ease. MATHEMATICAL OUTLINE OF PROBLEM Assuming that: 1. The mass velocity and chemical composition of the gas stream are constant and in normal gas well operations, the change in linear velocity in the entire flow-string is trivial, 2. The product of the density and heat capacity of the gas is constant, 3. No horizontal temperature gradient exists in the gas stream, 4. Net flow of heat by conduction within the formation and in the gas stream in the vertical direction is trivial in magnitude and can be neglected, 5. The regional vertical geothermal gradient is constant, and 6. The temperature of the gas entering the borehole is constant, and equal to that of the reservoir, a set of two simultaneous, linear partial differential equations with appropriate boundary conditions was derived to describe the temperature distribution in the gas stream and the surrounding formation. These equations were solved by operational techniques for the distribution of temperature in the gas stream. The resulting integrals were evaluated numerically on an IBM 604 at the Machine Accounting Div. of the Railroad Commission of Texas. DERIVATION OF FUNCTIONS FOR THE DISTRIBUTION OF TEMPERATURE The physical system is a circular hole of radius a in an infinite medium with thermal conductivity K, density p8, and heat capacity c,. Under shut-in conditions the well is in thermal equilibrium with the surroundings and the increment in temperature is given by - ?T3/L x. Gas of density pg and heat capacity c.. flows upwardly through this hole in the direction of increasing x with a linear velocity W. Writing a heat balance on an element of gas ?x in thickness, convective heat transfer + conductive heat transfer + energy required to lift a unit mass of fluid = change in energy content. pa2W po Co To - pa2Wpo Co To x+xx - 2apK?x ?T8/?r r=a - Wpa2 po?x/778 = CoPopa2?x?To/?t... Dividing by (copopa2?x) and taking the limit as ?x tends to zero, -W (?To/?x + 1/778Co) + 2 K/a Po Co ?T3/?r r=u = ?To/?t

Jan 1, 1958

By K. Horikawa, S. Kitahata, H. Kobayashi

"It has been clarified that the Al-5%Mg alloys containing 200 mass ppm of sodium showed grain boundary (GB) fracture, even when tested at room temperature, as well as at high temperatures (~500°C). SEM/EDX study revealed that the GB fracture was associated with the segregation of sodium on grain boundaries of the Al-Mg base alloys. Differential scanning calorimetry (DSC) revealed that the GB fracture at room temperature of Al-Mg alloys was caused by sodium segregation in the solid state. It was also shown that the tendency of the GB fracture strongly depended on the heat treatment; the alloys after the solution heat treatment showed severe GB fracture compared with the alloys after the homogenizing treatment. Moreover, it was shown that the GB fracture at room temperature by sodium segregation was suppressed by the addition of bismuth or indium. The suppression of the GB fracture by the additional elements was believed to be the scavenging effects by forming the sodium bearing compounds in grains.INTRODUCTIONIt is widely known that Al-Mg base alloys containing high amount of magnesium(~5 mass%)show better workability at room temperature, while that the alloys show grain boundary (GB) embrittlement at higher temperatures ranging from 200 to 500°C, depending on grain size(Otsuka, 1984), sodium impurity level(Ransley, 1959, Okada, 1997, Horikawa, 2001)and testing strain rate(Yamada, 2012). In the case of coarse-grained Al-5%Mg alloys (~300 ?m), 2 mass ppm of sodium causes severe GB fracture around 300°C, however, the Al-5%Mg-2ppm alloy does not show GB fracture at room temperature. It has also been shown that the GB embrittlement caused by 2ppm of sodium was suppressed by the additional elements, such as bismuth (Talbot, 1995), antimony (Ueda, 1997) and indium (Horikawa, 2012). Basedon these facts, we have concluded that the GB embrittlement at higher temperatures of Al-Mg alloys is attributed to the synergy effects of GB segregation of atomic sodium and GB sliding. For the GB embrittlement mechanism of Al-Mg alloys, involvement of low melting point metallic phases has been pointed out (Lynch, 2002),since the GB embrittlement appeared only at high temperatures. Up to date, the effects of high amount of sodium addition more than 2 ppm on GB fracture were not fully investigated in Al-Mg alloys. In the present study, the effect of 100 ppm ordered sodium impurity on GB fracture of Al-5%Mg alloys was examined, together with the effect of another additional elements."

Jan 1, 2017

By G. R. Rubly, H. J. Steele

LOCATION AND HISTORY THE San Manuel property is in townships 8S and 9S, range 16E, Gila and Salt River Base and Meridan, State of Arizona. This area is in the Old Hat mining district, southern Pinal County, and is about 3;2 miles southwest of the town of Mammoth on the San Pedro River and one mile south of the Mammoth mine at Tiger, Arizona. The property consists of over 150 contiguous lode claims. The Old Hat district was prospected prior to the Civil War, but there was little or no production until 1881.1 The chief producers have been the Mammoth and Mohawk mines, now consolidated and operating as the St. Anthony Mining and Development Co., Ltd. Production to 1936 was $5,200,000, of which 83 pet was gold.2 Since 1940 the production has been chiefly lead and zinc, and some molybdenum and vanadium. There are a few small properties in the vicinity that have produced very minor tonnages of copper ore. In the San Manuel group there are claims which have been held continuously from 1906 to the present time, and at least two churn-drill holes were put down on or near the outcrop in 1917. No logs for these holes are available, but it is assumed that the grade of copper encountered was not sufficient to encourage further exploration. A small amount of ore has been shipped from open cuts on the San Manuel outcrop area, but there is no record of the tonnage or grade. It is estimated that not more than 5o tons were mined. These cuts, plus a few shallow shafts and some short adits indicate limited and unenthusiastic prospecting at San Manuel. In 1942, through the efforts of James M. Douglas, R. B. Giffin, Victor Erickson, and Henry W. Nichols, owners of the San Manuel group, the Reconstruction Finance Corporation and War Production Board authorized the United States Geological Survey to investigate the property, and by their recommendation, the United States Bureau of Mines was authorized to put down a limited number of churn-drill holes. The Bureau of Mines carried on drilling from November 1943 to February 1945. Seventeen holes were drilled, varying from 305 to 1990 ft in depth. The property was brought to the attention of Magma Copper Co. in June I944 and an option agreement was made with the owners. Subsequently, a group of claims lying north of the original group and held by the Apex Lead Vanadium Mining Corp., and a group to the east held by the Quarelli family, were optioned. A drilling program was laid out to conform to the Bureau of Mines pattern, and drilling started in December 1944. San Manuel Copper Corp. was incorporated September 1945, and has carried on the exploration program to the present time. GEOLOGY General The mineralized outcrop, chief copper mineral of which is chrysocolla, is a tri-

Jan 1, 1947

By Racquel Nottingham, Marc Mastrantuono

Micropiles often provide a favourable solution for many deep foundation problems especially when significant site constraints such as confined construction sites or vibration limitations have been identified. Often the durability of buried steel elements are heavily scrutinized in order to effectively determine the rates of corrosion and methods to reduce this while still maintaining the structural integrity of the engineered solution. Practices such as sacrificial corrosion loss and the introduction of plastic sheaths have become the go-to methods of corrosion protection. Since the introduction of the micropile, other solutions have been developed, namely protection with an adequate grout encapsulation. This paper will explore corrosion protection of micropiles and the guidelines provided in the published codes and norms. Since few codes define the exact way to verify the durability of these micropiled structures, the existing data is presented and the analysis of grout encapsulation as an effective corrosion protection method is evaluated.

Oct 1, 2022

By J. F. Shultz

The Bureau of Mines investigated the hydrogenation of carbon monoxide and carbon dioxide over Raney nickel catalyst and nitrided fused-iron catalyst using both a single-pass and a recycle system. Activation energy over Raney nickel catalyst is 29 to 32 kcal/mole for synthesis from either CO or CO2, Pressure dependence of the gas conversion is to the 0.3 power for synthesis from CO and to the 0.5 power for synthesis from CO2. Nitrided fused-iron catalysts were tested using high recycle rates and 3H2+lCO, 2H2+lCO, and 1H2+lCO feed gas at 21.4 atmospheres absolute pressure. The relative usage of hydrogen (moles H2 consumed per moles Ha+CO consumed) was larger than in corresponding single-pass tests, and the relative usage of hydrogen approached the feed gas ratio monotonically as conversion increased. Activation energy was found to be 12 or 13 kcal/mole fresh feed gases of 3H2+lCO or 2H2+lCO. For single-pass operation the activation energy under the same conditions was 19 to 21 kcal/mole.

Jan 1, 1967

The fundamentals of blasting involve both the properties of explosives and of the rock being blasted. Four of the most important explosive properties appear to be energy density, bulk density, rate of energy release and the pressure- time history of the gases produced. Important rock properties are density and porosity, strength, and energy absorption including the effective moduli of elasticity. Rock structure also has a marked effect on its properties: for example, joints, bedding, and fracture alteration. Several mechanisms enter into rock fragmentation by blasting. These include slabbing, radial fracturing, crushing and bursting by the gas bubble. All of these factors are closely related to properties of both explosives and rock. Slabbing depends upon the first generated stress wave, whose shape and magnitude are a result of the pressure generated by the explosive, its time history and the resultant response of the rock, including its ability to sustain the stress wave. Actual slabbing, in turn, is a function of the magnitude and shape of the pressure pulse and the tensile strength of rock. Further fragmentation depends to a great extent upon the amount of gas in the bubble and its energy and pressure.

Jan 10, 1967