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By B. E. Field

COBALT is a silvery white metal with a slight bluish cast, strongly resembling nickel in its appearance and properties, notably its resistance to corrosion, although its alloys with other metals differ quite decidedly in their properties from those of nickel. The name cobalt was derived from the German "Kobold" meaning goblin and this came to be applied to the cobalt minerals which, although they resembled ores, did not readily yield metal when smelted by the primitive processes available in the Middle Ages. Cobalt minerals were used as pigments by potters and glass workers before the Christian era. Cobalt blue glass was found in the tombs of the Egyptians and in the ruins of Troy, and many colors used by the ancient Greeks and Romans contained cobalt. The ancients were entirely unaware that the colors they used were caused by cobalt and the metal itself was only isolated about the middle of the eighteenth century by Brandt although the preparation of cobalt compounds had been carried on in a small way ever since the opening of the silver-cobalt deposits at Schneeberg, Germany, in 1470. The metal is fairly hard, with a density when pure of 8.81 in the cast state and 8.92 after working. The com¬mercial grade of cobalt has a density of about 8.75 in the cast state. The atomic weight is 58.97. The Brinell hardness of the pure metal is 124; that of the commercial grade varies from as low as 100 to as high as 138, depending upon the impurities present. Pure cobalt has a sharp melting point at 1478°C. The tensile strength of the pure metal in the cast condition is said to be higher than that of any other pure metal. Kalmus gives it as 34,400 lb. per sq. in. for cast unannealed metal; the effect of annealing at 850 to 900°C. is to raise the strength slightly. The yield point is close to the ultimate strength and the reduction in area and elongation are both low. Mechanical working raises the tensile strength of pure cobalt rapidly and in the form of wire it will be over 100,000 lb. per sq. in. The presence of small quantities of carbon in the commercial metal raises the tensile strength to as high as 61,000 lb. per sq. in., the reduction in area and elongation being raised at the same time to approximately 20 per cent.

Jan 1, 1933

By J. J. Forbes

Investigations by the Bureau of Mines and by mining-research departments of European countries have established definitely the value of rock-dusting to prevent or limit the propagation of coal-mine explosions. Its effectiveness in this connection has been demonstrated not only by research but by actual coal-mine explosions in which hundreds of lives have been saved because of its presence. In a general way this paper gives pertinent facts concerning rock dusting practices in the United States. Information has been obtained from many reliable sources, and various coal-mining companies have furnished data on cost and other details.

Jan 1, 1939

By Earl L. Phillips

The Bureau of Mines conducted laboratory tests on samples of pozzolaniccement concrete to develop a low- strength backfill . Results show that support costs can be lowered by replacing a portion of the portland cement in mine backfill with pozzolan ( fly ash ) and lime . Unconfined compression tests on various ratios of fly ash to cement in 84 samples produced compressivestrength curves that can be used to estimate the best backfill mix for any mine .

Jan 1, 1964

By F. Sawyerr

A bubble population balance model is proposed for the prediction of Sauter mean bubble diameters in mechanical flotation cells. In the model, the flotation cell is treated as two separate, statistically homogeneous zones?the impeller zone, and the bulk tank zone. Balance functions for the rates of bubble breakage, coalescence, recirculation and inlet-outlet events are proposed based on classical chemical engineering research in two- and three-phase fluid mixing systems. An initial simulation of the population balance model shows trends in bubble size distributions comparable to measured distributions in industrial mechanical flotation cells.

Jan 1, 1998

By C. J. Roos

Ground-engaging tools are used to prevent damage to the main components of earth-moving equipment. These tools consist of everything from shovel teeth to replaceable drill bits to dozer wear plates. The costs of these "consumable" items are increasing with the costs of raw materials. This project developed a tool to be used by Newmont Mining Corp. to predict the consumption of excavator teeth at a particular mine site. This paper presents the results of the Montana Tech research project in which an equation was developed to predict excavator teeth consumption based on production rates and rock properties.

Jan 1, 2010

By D. R. McMullin

The purpose of this paper is to provide a method for mine planners and engineers to evaluate on a conceptual basis if a shaft or a ramp is most suited for their particular underground access requirements. Mine planners and engineers are often raced with the decision of choosing which method of underground access is best suited for their particular requirement. Underground access can be provided by a shaft, ramp, adit, or slope for either exploration and/or actual production operations. This paper will focus on the construction cost and schedule differences between sinking a shaft and excavating a ramp which are currently the most typical access alternatives used in the western United States. It would be wrong to state that one method is superior to the other in every case. There are many variables to be addressed, and the degree of sensitivity of each of them will eventually dictate which method is the most suited to the particular circumstances. This paper compares the construction cost and schedule or sinking a shaft to excavating a ramp at different depths given different ground and hydrological conditions. This comparison provides mine planners with "rules or thumb" that may be applied to the access selection process.

Jan 1, 1994

By Rob Domotor

This paper tells the story of using controlled surface and underground blasting methods to excavate hard rock in three areas on Australia’s largest road infrastructure project; the Airportlink Project in Brisbane; worth a total value of AUD $4.8 billion. The project used blasting methods including design, modelling, drilling and loading of the explosives that had never been used before in Australia, some of these were probably unique in the world.

Jan 1, 2012

Investigation of standard tests used to establish the decrepitation rating of Western Australian iron ore showed scatter in results which could be reduced by textural type sampling. Testing of individual textural types resulted in separation.of a range of decrepitation behaviour patterns. No unique correlation was established between water content in goethite, or between any single mechanism and breakage in shock heating. The latter depends rather on several mechan- isms whose operation is controlled by the texture of the ore. Texture studies were used successfully to predict decrepitation behaviour which could be related to orebody structure for mine planning, and blending for sales or processing requirements.

Jan 1, 1973

By Robert L. Clayton, Arthur Baker

Two massive sulfide zinc-copper ore bodies are in quartz-sericite schist (probably formed by regional metamorphism of sediments) and andesite of the Precambrian Yavapai Series, on opposite sides of a large rhyolite mass. The Copper Queen ore body is conformable with bedding of its schist host rock, but the Old Dick ore body probably crosscuts the strata. A lens of low-grade mineralization in chlorite schist, associated with the Old Dick ore body, crosscuts through 150 feet of strata. The ore bodies are almost entirely enclosed by premineral faults with less than 150 feet of displacement. The minerals of the ores are pyrite, sphalerite, and chalcopyrite, with minor arsenopyrite and galena and small amounts of intimately associated chlorite, sericite, and calcite. Old Dick sphalerite-chalcopyrite intergrowths have mutual boundaries, and sphalerite grains contain abundant exsolved chalcopyrite. Copper Queen sphalerite-chalcopyrite intergrowths have extremely ragged boundaries, the sphalerite contains no exsolved chalcopyrite, and the ore overall has a schistose texture. The pre-mineral fault on the hanging wall of the Copper Queen ore body has had 100 feet of post-mineral displacement. Wall rocks of the Old Dick ore body locally have been sericitized. Andesite and quartz-sericite schists for at least several hundred feet around both ore bodies have been chloritized erratically and contain traces of copper.

Jan 1, 1968

The nature of adsorbed calcium carboxylates (oleate and stearate) has been investigated by in-situ/ex-situ Fourier transform infrared internal reflection spectroscopy (FTIR/IRS). Previous spectroscopic studies in alkaline solution have shown that adsorbed carboxylate is characterized by a C-O stretching vibration at about 1550 em?1 for less than monolayer coverage. Similar results were found in this study. More specifically, in this study such a singlet at 1550 cm-1 was found for LB monolayers of calcium distearate transferred as a condensed layer at a high film pressure to the surfaces of fluorite and germanium. Normally the spectrum of bulk calcium distearate reveals a doublet at 1575 and 1540 cm-1, characteristic of a three dimensional 7-fold coordination for calcium carboxylate complexes. This doublet is generally found for carboxylate multilayers formed by spontaneous adsorption at the surface of calcium minerals. In this regard, the spectral evidence suggests that whenever the calcium dicarboxylate is constrained at a surface as a condensed layer, the 7-fold coordination can not be satisfied and the surface carboxylate is forced into a two dimensional symmetrical coordination with a singlet at 1550 cm-1. On the other hand, if the Langmuir-Blodgett (LB) monolayer calcium distearate film is transferred at a low film pressure the doublet is observed. This analysis is further confirmed by the spectral results for LB transferred calcium distearate monolayers at a hydrophobic silicon surface. Even though these are condensed monolayers formed at high film pressure, the carboxylate group, oriented away from the surface, is no longer constrained by the surface force field, and thus exhibits the characteristic doublet of the bulk calcium distearate salt.

Jan 1, 1998

By Willard S. Morse

The purpose of this paper is to record the results obtained in the use of the Russell process at Aspen, Colo., covering a period of fourteen months, from November, 1891, to December, 1892, during which time over 30,000 tons of ore, purchased outright, on sample and assay, were treated. No explanation of results will be attempted, nor will the chemistry of the process be discussed. The plant was designed by C. A. Stetefeldt, of San Francisco, and built by the owners by day-labor. The entire plant is run by water-power, supplied by a flume 3600 feet long, and a pipe-line 2200 feet long, with a head of 170 feet. A Pelton water-wheel, 8 feet in diameter, is used, from which power is transmitted by wire-rope to the main counter-shaft in the mill, a distance of about 250 feet. From the mill to the samplingworks, about 150 feet, power is also transmitted by a wirerope. A Pelton water-wheel, 3 feet in diameter, supplies power to the dynamo for lighting the plant. The works are located adjoining the Santa Fe railroad tracks, and all ore and supplies are unloaded directly from the cars to the works. The sampling-works are provided with crushers and rolls, the latter being used only on samples, and not on the entire ore. The Cornish hand-quartering method is used in sampling ore for purchase. After crushing and sampling, the ore goes to the bedding-floor, where it is made up into mixtures suitable for the mill. The drying-plant consists of four Stetefeldt double shelfdryers, six shelves high, and is provided with dust-chambers and a stack 65 feet high for draft. These dryers are fired with gas

Jan 1, 1896

By W. J. Douglas

The mine manager in today's environment is faced with a wide variety of problems and challenges which must be addressed if efficient and profitable operations are to be achieved. Expansion of operations has, in many instances, resulted in inexperienced work crews, face supervisors, and superintendents. The complexities of a mining system preclude rapid movement through the learning curve for moat personnel. The management of production suffers both from this inexperience and the lack of standard procedures and methods for planning, schedul ing and analyzing production systems. The lack of visibility of information, as well as of the operations themselves, due to their remoteness, adds to the problem of production management.

Jan 1, 1980

By N. Malakouti, R. H. Whipp, O. A. Kuby, R. M. Smailer

A detailed description of the development of the FIOR process (Brown, Campbell, and Saxon, 1966) and, subsequently, other technical papers related to the operation and start up of the FIOR plant (Violetta, 1975; Whipp, 1980) are available in the technical literature. The Fluidized Iron Ore Reduction (FIOR) process plant constructed in the Matanzas region of Venezuela represents the first commercial application of this technology. The FIOR process was developed by Exxon Co. during the 1950s and 1960s. The facility in Venezuela was designed and constructed by Davy McKee, with plant start-up in 1976. While there is a minority government ownership in the company, FIOR de Venezuela operates as a private sector company with the majority of ownership being private capital. The FIOR process is well suited to utilize the naturally occurring iron ore fines of the Cerro Bolivar and San Isidro iron ore deposits located less than 100 km (62 miles) south of the plant site. Availability of natural gas within 150 km (93 miles) to the north, and a location bordering on the confluence of the Caroni and the Orinoco Rivers makes for an ideal geographic site. Feed stock to the FIOR plant consists of naturally occurring iron ore fines from these ore bodies, which are screened to -6mm (-0.2 in.) prior to drying in the ore preparation plant. A simplified flow plan is shown in [Fig. 1]. The dried ore is then transferred to the top of a structure containing four fluid-bed reactors located above one another so the mineral may flow from one reactor to the next by gravity. A reducing gas containing 90% hydrogen is made by steam reforming of natural gas, a CO shift

Jan 1, 1983

By I. Filzwieser, S. Wallner, M. B. Hanel, A. Filzwieser

Whenever thinking about increasing tankhouse performance two major aspects has to be considered, the technological feasibility as well as the economical impact. For meeting the requirement of an increased current density leading to an increased productivity, Mettop has developed the METTOP-BRX Technology, which allows the introduction of fresh electrolyte between each pair of anode and cathode. As an example of a green field approach the installation at Xiangguang Copper Co., Ltd will be described. Since the start up in 2011, Xiangguang Copper Co., Ltd operates one of their two copper refining tankhouse with a current density of 420 A/m2 and a current efficiency above 98% in average. At Montanwerke Brixlegg Ag, as an example of a brownfield installation, the annual production could be increased by 50%. Although for many years a total of two industrial applications are in operation, the successful implementation of this technology that result in significant operational and economic advantages has not been fully accepted within the industry due to misunderstandings, incorrect interpretations and lack of awareness. It is intended with this paper to create a better understanding about the parallel flow technology and help to eliminate worries and concerns.

Mar 1, 2017

By L. A. Wilson, N. H. Harrison, R. R. Clay, R. L. Reed. D. W. Reed

Experiments have been performed in a linear near-adiabatic system for the purpose of extending data on reverse and forward combustion from atmospheric pressure to 1,000 psig. Results obtained from reverse combustion appear to conform qualitatively with the existing description of the process when reaction kinetics are suitably modified to account for the increase in pressure, i.e., increasing tbe pressure decreases the peak temperature and increases the combustion zone velocity. Forward combustion appears to be a fuel dominated process wherein peak temperature and combustion zone velocity are not very sensitive to changes in pressure. The moderate effects of pressure that do exist at low flux virtually disappear at high flux providing all oxygen is consumed. With this provision. increasing the pressure decreases the frontal velocity and increases the peak temperature. Results me shown graphicaIIy which demonstrate the effects of presswe on peak temperature, rate of advance, oil recovery, air/oil ratio, carbon oxides produced and temperature distributions. INTRODUCTION Numerous field tests of oil recovery using the technique of underground combustion are now in progress. Operating pressures used are always substantially in excess of atmospheric pressure. Nevertheless, the literature contains no laboratory data pertaining to the effects of pressure except for those of Martin, Alexander and Dew.1 Unfortunately, these data appear to reflect heat losses which may have obscured some of the effects of increased pressure. The underground combustion processes are exceedingly complex, and general concepts relating to them have necessarily been described in relatively simple terms. Particularly with regard to forward combustion, the interaction between multiphase fluid flow, heat transport and various rate mechanisms is so involved that to date a rigorous treatment is not available. In this paper a linear near-adiabatic system is described which was found capable of operating at pressures up to 1,000 psig and temperatures of at least 1,100 F. Using this equipment, experiments on both forward and reverse combustion were accomplished at elevated pressures and the data presented as a function of air flux or temperature. It will be assumed that the reader is familiar with the papers of Wilson, Wygal, Reed, Gergins and Henderson on forward combustion and that of Reed, Reed and Tracht3 on reverse combustion, so that it is not necessary to repeat the details of the two processes. EQUIPMENT AND PROCEDURE It was decided to study the effects of pressure over the interval 0-1,000 psig using a near-adiabatic system. Since satisfactory operation of such a system requires very thin tubing walls, it proved necessary to insert the entire combustion tube and heater assembly into a high pressure jacket in such a way that the internal tube pressure could be counterbalanced by pressurizing the annulus. This meant that the numerous heater and thermocouple wires had to pass through gas-tight seals that required considerable effort to maintain effective. An unexpected difficulty arose in connection with the nature of the annulus pressuring gas. It turned out that the composition of this gas critically affected the functioning of the adiabatic control system. Operation of the equipment at elevated pressures was not particularly difficult. The problems that did arise were a direct consequence of the large numbers of connections and seals involved. EQUIPMENT The equipment consisted of the combustion tube which fitted within the pressure jacket. This jacket was in turn mounted on a wheeled carriage which facilitated movement and provided for rotation of the

By J. -M. Milazzo, T. Wallmach, S. B. Blancher, A. Amalric

In a FeNi electric arc furnace, the physical properties of the slag (chemistry, viscosity, liquid/solid/gas ratio) are of crucial importance in controlling the efficiency of the process. In this paper, we studied the slag crystallised on the walls of a semi-industrial furnace (freeze-lining), the slag rising through the burden during foaming phenomena, and the casted slag. The freeze-lining is the layer of oxides that crystallises on the refractory wall of a furnace, protecting it from chemical and mechanical aggression. It records changes in furnace conditions (slag chemistry, temperature, oxygen fugacity), which makes it possible to observe the impact of these elements. In the high reduction test, the freezing lining is composed of magnesian olivine. Switching to a low reduction process increases the Fe content of the olivine and causes orthopyroxene to appear, making the freeze-lining mechanically and thermally weak. Thermal incidents in the furnace cause significant slag foaming. This foaming is produced by a massive crystallisation of the olivine (due to the drop in temperature), and inducing an exponential increase in viscosity, preventing the free circulation of gases. These foaming episodes are also recorded in the freeze lining and form layers rich in gas bubbles, and therefore mechanically fragile. The slag casted and cooled in a ladle allows the first steps of slag crystallisation to be studied. Olivine is the liquidus phase, with a magnesium-rich core and an iron-enriched rim, contemporaneous with the orthopyroxene phase. The habitus of these phases is very similar to that found in komatiites for the same minerals. FeNi slag is therefore an industrial analogue that is easy to study and compare to komatiites. Keywords: Pyrometallurgy, ferronickel, slag, freeze-lining, characterisation, olivine, mineralogy

Jan 1, 2020

By Colin Lindsay

"The Collahuasi copper mine, located at an altitude of 4300 meters above sea level in northern Chile, commenced operations late in 1998. The mine is currently the 4‘h largest copper producer in the world and comprises an open pit, a 60,000 tpd sulphide concentrator, a 15,000 tpd oxide heap leach and SWEW plant and a 200 km concentrate pipeline to a port facility.Constructing, commissioning and operating a mine at high altitude presents unique challenges in terms of the performance of both equipment and people. It is important that these be recognized and carefully considered during the feasibility study and the detailed design stages and the success of the Collahuasi project is largely due to this. The plant design incorporates a number of features aimed at mitigating the problems of altitude and the construction methodology also took into account the particular site conditions.This paper discusses the Collahuasi project team’s approach to planning for the remote location and also some of the problems experienced during construction, commissioning and operation.INTRODUCTIONThe Collahuasi mine is located in northern Chile, some 250 km to the south-east of the port of Iquique and 15 km from the Bolivian border. The mine facilities lie between 3800-4300 m above sea level on the Altiplano, the central plateau of the Andes mountains, and cover a total of approximately 95,000 hectares. Although the area is arid, it experiences an average of 150 mm of precipitation annually and weather conditions can be extreme. Temperatures during the day range between -3 to +11 º C and are generally below 0ºC at night, sometimes as low as -20°C. High energy winds are common and humidity is low. Much of the precipitation occurs during the winter as snow but there also occurs a period during the Chilean summer known as the “Invierno Boliviano’’ (or Bolivian Winter) which is characterized by severe electrical storms and rain."

Jan 1, 2001

By J. N. Van der Merwe

"The probability of survival of coal pillars is a more rational indicator of stability than the safety factor. Over time, pillars undergo reduction in size by progressive scaling of the sidewalls. The probability of survival is therefore not constant but reduces over time. The rate of scaling can be quantified, and the reduction of the probability of survival as a function of time can therefore also be quantified. The paper describes the link between the factor of safety, probability of survival, and reduction of the probability of survival. Using the safety factor, probability of survival, and the time at which the probability of survival will reduce to 50% is proposed as a more rational method of evaluating pillar stability than the safety factor alone.IntroductionCoal pillar strength has long been the subject of research in South Africa and several other coal-producing countries. However, it began receiving serious attention only after the Coalbrook disaster in 1960. The most important outcomes of the initial investigations were the groundbreaking research by Salamon and Munro (1967) that resulted in the well-known power formula for pillar strength, and the work by Bieniawski (1969) that resulted in a linear formula for strength. The former approach was based on empirical back-analysis of failed and stable pillar cases, and the latter on in situ strength tests on large specimens.The Salamon and Munro (1967) formula has been widely used in South Africa and even adapted for application to hard rock pillars by researchers such as Hedley and Grant (1972).At the time of the initial work by Salamon and Munro, there were only 27 failed pillar cases suitable for analysis. It was not possible at the time to determine site- or seam-specific strength, and the result was a general formula for use in all seams in all mining districts. Since that time pillars have continued to fail and the database continued to grow – as of 2013, there were 85 cases in the database. Using the additional data, there have been a number of re-evaluations of the strength formula and it has also become possible to differentiate between the different mining seams and areas."

Jan 1, 2016

By V. I. Lakshmanan

Recycling helps to save energy and is good for the environment. It is also important for preserving the limited natural resources. In addition, recycling creates economic benefits and frees up space at the landfill sites. Process Research Ortech Inc. (PRO) has conducted extensive testwork in the area of waste processing and recycling. A process was developed for the recovery of Zinc from galvanized steel by alkaline leaching followed by solvent extraction and electrowinning. Extensive testwork has been conducted at PRO to obtain a useful by-product from rice husk. Rice husk was combusted in a gas/solid reactor to obtain an environmentally acceptable amorphous silica ash suitable for use in high strength concrete. In another development, vanadium was recovered from fly ash by separating carbon first, followed by alkaline pressure leaching, solvent extraction and precipitation. PRO has also developed an environment friendly process for treatment of industrial wastewater for its reuse to obtain zero or minimal effluent discharge. In this paper, four case studies related to recycling of zinc scrap, controlled combustion of rice husk, processing of fly ash, and reuse of waste water will be discussed.

Jan 1, 2011

By A. D. Storrie

An underground wet shotcrete trial was completed last year to determine the effectiveness of wet shotcrete as an alternative support mechanism to dry shotcrete in the kimberlite environment. The wet shotcrete was manufactured at the underground batch plants, transported to site using an agiecar and transferred to the shotcrete pump. The wet shotcrete is pumped to the nozzle where compressed air at 7 bar and an accelerator, Meyco SA 160, is added and enables the shotcrete to be placed successfully onto the tunnel wall. No tunnel guard was previously placed on the sidewall and hangingwall. Geotechnical testing indicates that the Grace fibre performed extremely well with the energy absorption tests at 7 kg/m3and 8kg/m3where both achieved over the mine requirement of 750joules. The Grace fibre and wet shotcrete mix also achieved a compressive strength in excess of 55 MPa, well above the 45 MPa requirement for Premier Mine. The recommended wet shotcrete mix design is therefore based upon: [Material/ CriteriaQuantity/m3Units ?Lafarge 42.5 Duratech500kg ?Condensed silica fume40kg ?Rayton Sand1.558Ton ?Delvocrete stabilizer 103.6litres ?Glenium 27CH5.4litres ?Meyco TCC 7355litres ?Water230litres ?Meyco SA16025litres ?Fibre8kg ?Cement/Water Ratio2.35? ?Water/Cement Ratio0.43? ?Flow615 mm] If the wet shotcrete system is implemented there is a potential for Premier Mine to make major savings. In South Africa there are two suitable wet shotcrete machines available for the mining industry, the Spreymec, manufactured by Tamrock and the Fermel/Meyco wet shotcrete machine. The Spreymec is a fully imported machine. The Fermel component is manufactured in South Africa and the Meyco shotcrete components are imported and supported by MBT (Master Builder Technologists) in South Africa. The Fermel/Meyco machine is assembled in South Africa. Premier Mine has allocated some R2, 100,000 towards the implementation of the wet shotcrete system. If implementation is successful there should be an internal rate of return gain of 76% with regard to this project.

Jan 1, 2001