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By l. Bokányi, T. Varga

"The recycling of waste car tyres is a very important environmental task. The waste tyres usually are re-used or recycled by thermal processes like pyrolysis, gasification or incineration. The main problem associated with these processes is the sulphur content of waste tyres originated from the vulcanisation process, which pollutes the environment and the valuable products (i.e. pyrolysis oil) as well. In our research the desulphurisation of waste, mechanically prepared tyre sample was systematically investigated by the biosolubilisation with Acidithiobacillus thiooxidans, strain Karitas. Parallel, the experiments with sterile 9K nutrient medium were also carried out. It was found that the vulcanisation sulphur can be solubilised due to both the bio- and the chemical leaching, although the bioleaching is more effective. The solubilised vulcanisation sulphur then forms precipitates. The precipitates are forming in the bulk solution, as well as on the surface of rubber particles. The origin of the precipitates was investigated using XRD and scanning microscopy with micro probe. The origin of the precipitates is different: while in the process of the vulcanisation sulphur solubilisation with 9K medium the jarosite (KFe3+3(SO4)2(OH)6) forms, the course of the biosolubilisation with Acidithiobacillus ferrooxidans Karitas is accompanied by the formation of the jarosite and the halotrichite (FeAl2(SO4)4 · 22H2O) as well. The formation of the latter is the biomineralisation. The mechanisms of the bio- and chemical solubilisations are rather different as it was found and experimentally proved by several tests, and depends on the retention time of the solubilisation. Special efforts were done to elaborate the proper separation of the precipitates from rubber particles. Combination of intense dynamic stirring and recycling flotation process to remove the precipitates was applied for this purpose. The surface properties of synthetic jarosite were revealed using zeta-potential measurements at different pH and in presence of collectors. The parameters of the flotation were chosen based on the revealed surface properties of the precipitates. Finally, the sulphur recovery of the recycled rubber was achieved as low as <0.5%, sulphur content of it 0.17%, 12-times lower than that of the waste tyre sample after mechanical preparation."

Jan 1, 2018

By John C. Wangaard

A method of raising by use of a cage has been used with considerable success at the Cary Mine, Hurley, Wisconsin, on the Gogebic Range. The Cary Mine is owned by the Odanah Iron Company, Pickands, Mather and Company, Managers. This method is known to have been used previously at Tennessee Copper and probably in other districts. The Cary Mine was engaged in deepening the main shaft from the 34th to the 37th level. To accomplish this, and to facilitate development, a ventilation shaft 930 feet north of the main shaft was sunk from the 34th to the 37th level and crosscuts were driven on the 35th, 36th and 37th levels to the main shaft location, These levels are at 200 foot verticalintervals. All of this work was done in granite and the majority of the workings were not timbered. The next step was to get a raise through from the 37th to the 36th level, and from the 36th to the 35th level, which would later be stripped to full shaft size. Several methods of raising were considered including double-compartment cribbed and two single raises interconnected at regular intervals, but the cage method was chosen as it appeared to be a safe and efficient operation. The method in general consists in the use of a drill hole between levels through which to pass a hoisting rope to raise and lower a light cage.

Jan 1, 1958

By Raja V. Ramani, Robert L. Frantz

"In response to the U.S. Bureau of Mines (USBM) Request for Proposal (RFP) for "" the establishment of a Generic Mineral Technology Center (GTC) in Respirable Dust,"" the Mining and Mineral Resources Research Institutes (MRIs) at The Pennsylvania State University (PSU) and West Virginia University (WVU) in association with participating MRIs at Massachusetts Institute of Technology (MIT), and the University of Minnesota (UMN) have prepared the comprehensive research program described herein. Michigan Technological University (MTU) joined the Center as an affiliate after its inception. This program was developed with recognition of the stated objective of the Federal Mine Safety and Health laws which is to "". . . permit each miner the opportunity to work underground during the period of his entire adult working life without incurring any disability from pneumoconiosis or any other occupation-related disease . . . .""Exposure to respirable contaminants in mine atmospheres has long posed a serious hazard to miners. The control of these hazards, some of which can have sudden and catastrophic consequences and some others, slow and long enduring, has been a major concern for labor, management and the government. This concern has manifested itself in four mechanisms of control -- (1) regulatory control through minimum standard setting by the passage of mine health and safety laws, (2) engineering control through design and operation of mines according to the best recommended practices, (3) interaction of dust and lung control through periodic physical examinations, wearing personal protection devices, etc., and (4) legal and social control through workman's compensation laws for occupation related health deterioration."

Aug 31, 1989

By Márcia Maria da Silva Monteiro Pereira

Durante o lingotamento contínuo de aço, partículas de ZrO2 adicionadas na escória de molde facilitam a nucleação heterogênea de cristais devido à sua limitada solubilidade. A adição de ZrO2 promove a cristalização da fase cuspidina, o que auxilia na redução da transferência horizontal de calor no molde, amenizando desta forma o problema das trincas longitudinais. Outro benefício da adição de ZrO2 em pós fluxantes é reduzir a taxa de desgaste da válvula submersa (SEN) na interface metal/escória; a erosão da SEN é um problema sério. Através de testes de laboratório e de testes industriais concluiu-se que a adição de ZrO2 em pós fluxantes reduz a taxa de transferência de calor horizontal no molde durante o lingotamento contínuo de aço, considerando os dois tipos de pós fluxantes que foram analisados no presente trabalho. Além disso, observou-se que a adição de ZrO2 reduz a taxa de desgaste da válvula submersa na interface metal/escória.

Aug 16, 2017

By William J. Wuest

This U.S. Bureau of Mines report presents an overview of ground control considerations associated with floor heave. Factors affecting heave, such as in situ stress, floor characteristics, and mine geometry, are described. Floor-displacement monitoring and data analysis methods are outlined. Finally, floor heave remediation is discussed. The remedial techniques are divided into four categories: mine maintenance, supplemental support, mine structure, and techniques for multiple-seam operations. Other subjects covered in the report include laboratory and in-place testing of floor rocks, U.S. and international case studies, effects of mine layout, determination of excess horizontal pressure, and types of heave failure. The emphasis of this report is on practical considerations; theoretical discussions are kept to a minimum.

Jan 1, 1992

By D Misra, R Ganguli, S Bandopadhyay

The objective of this paper is to assess the accuracy and applicability of recent state-of-art methods such as the machine learning algorithms (MLA) for mineral resource estimation. Conventional methods such as geostatistics have been predominantly used in the mining industry for this purpose with varying success. Recent advances in the use of MLA have provided a fresh approach to obtain improved accuracy in the estimation of mineral resources. Two MLA methods: the neural network (NN) and the support vector machine (SVM) have been used to estimate a polymetallic ore deposit in Alaska.The general characteristic of SVM and NN emphasises the fact that they can approximate any multivariate non-linear relation among variables. Although neural network models are able to capture the nonlinear spatial relationships that may be present in the data, they are usually difficult to optimise under sparse data settings. Of the various NN alternatives, despite their effectiveness, the model selection and estimation process is typically difficult as it involves solving complex integration and optimisation of parameters. In support vector modelling (SVM), estimating of parameters involves optimisation of a convex cost function. The working principle of SVM makes it robust against noisy and extreme value data. At the same time, it can capture the spatial distribution of ore grade more effectively with careful modelling and selection of SVM parameters.The outcome of the MLA methods were compared to those of the geostatistical ordinary kriging (OK) application to study their generalisation ability. The comparison was made using the following goodness of fit criteria: mean-squared error; mean absolute error; mean error; and coefficient of determination. The results indicated that the MLA methods may improve the predictability of ore deposits and thereby reduce the inherent risk in mineral resource estimation.

Sep 26, 2011

By X. M. Yu

A large amount of polluted sludge is produced by a nonferrous metal factory after treating waste water with lime/ferrous salt. The concentration of arsenic in the dried sludge is high to 5.84%, a toxicity test is taken on the sludge according to GB5085.3-2007 and the extraction content is 15.75mg/L, which surpasses the arsenic extraction standard [As]=5mg/L, the sludge is categorized as hazardous waste. If put outside without disposal, it would be very harmful to environments. Here we report an optimum protocol to extract arsenic; S2- alkaline liquor is utilized to treat the arsenic sludge. At 85?, 10L 7% S2- liquor is added into 1kg dried sludge and the resulting mixture is stirred for 120min at 250r/min, then separated by centrifugation and the compressed waste residue dried naturally. The average arsenic content is 1.40mg/L, lower than GB5085.3-2007 Standard and arsenic-free residue is consistent with GB18598-2001 Standard, which can be bury safely. The extracted arsenic is transferred into copper arsensite for use as addictive in copper electrolysis and the waste water can be recycle after calcium is removed.

Jan 1, 2014

By F. W. Brackebusch

Paste is a high density mixture of water and fine solid particles with a relatively low water content (10-25%) such that the mixture has a consistency as measured by the ASTM slump cone test from slightly greater than zero up to nearly 12 inches (305mm). Particles of different size classes will not segregate or settle when the paste is not being agitated or when it is stationary in a pipeline. Cement may be a component of paste. Larger particles of aggregate can generally be added to a paste without greatly changing the pipeline transport characteristics. A paste may bleed water slightly when it is allowed to be motionless for periods of up to several hours, but the solids do not become so dense that the paste cannot be easily re-fluidized. The dividing line between the definition of a high density slurry and a paste is not sharp. It is a practical matter that must be considered when designing a pipeline transportation system. If the pipeline is very short, there is very little risk of plugging the pipeline with a high density slurry when flow is stopped for short time periods. With longer pipelines the mixture must remain stable without motion for periods as long as several hours to avoid pipeline plugging. The fine particles in a paste mixture can be composed of mine tailings or naturally-occurring clays, silts and fine sands. The mineralogy of the particles thus can have a wide variety from quartz and feldspar to clays, micas and even salts.

Jan 1, 1993

By Karen C. Armfield, Gisele R. Passalacqua, Joanna Smith

New York City is an urban environment with a history spanning over 200 years. The coastline of New York has changed over the years. In the East River, old bulkhead and remnant of relieving platforms together with variable bedrock elevations pose challenges in the design and construction of deep foundations. This paper presents a Case History of high capacity deep foundations along the Franklin D. Roosevelt (FDR) Drive on the Upper East Side in New York City. The project consists of a ramp that overpasses the FDR Drive allowing heavy trucks to access the Marine Transfer Station (MTS) facility built over the East River. Large diameter drilled shafts and mini-piles socketed to bedrock were designed and constructed. Remnant of old bulkhead was encountered at the site and a Ground Penetrating Radar (GPR) investigation was completed during the subsurface investigation phase of the design. This paper discusses details of the subsurface investigation program and design methodology of the high capacity drilled shafts and mini-piles. It also describes construction methods and results of Osterberg Load tests documenting the field values of skin friction through the rock socket. Other construction challenges include construction and drilling rock sockets for drilled shafts over sloping bedrock. 1. INTRODUCTION New York City is a renowned urban city that always calls for the most delicate, yet complex, and robust superstructures and most importantly substructure designs. The historic preservation of this large 200 years old city of 319 square miles is ever changing. Shorelines are often extended to accommodate new infrastructure and very often many miscellaneous structures are discovered below the ground surface. The East 91st Street Ramp was constructed to provide access to the East 91st Street Marine Transfer Station over FDR Drive and York Avenue. Another alternative ramp will be relocated to the South Bound (SD) of the FDR Drive at 92nd Street. A subsurface exploration program was completed in accordance with the New York City Department of Design and Construction (NYCDDC) general requirements, Section 4.5, to perform subsurface investigation along the FDR Drive in Manhattan, New York.

Jan 1, 2019

By Mike Smith, George Chung

"A 23 million dollar Flotation Plant has been commissioned at the Iron Ore Company of Canada in 1998. Nine OK-50 cells &re used to float silica in this 1,400 tomes per hour plant. The paper details project development, construction and operating results. This plant gives IOC the capability to produce not only high quality blast furnace pellets of varying silica, CaO and MgO levels, but also a high iron, DR grade pellet. The first activity was simply to sit down with the suppliers, Outokumpu, Wemco. GL&V and Svedala, to discuss applications and share experiences. We learnt what each supplier had to offer, what features would particularly suit this application, what options were offered, what were the materials of construction, how the equipment is maintained, which wear parts require replacement, etc., etc. We tried to learn as much about the equipment as the suppliers themselves knew. Then we tried to learn more: we contacted users and asked about any weak points, which options were worth incorporating and which items were not. We then discussed these points with the suppliers and established how potential problems might be overcome."

Jan 1, 1999

By D. W. McGlashan

Zeta potential changes were determined as a function of pH, metal ion, and surfactant concentrations. Prom the analysis of data, flotation experiments were carried out to correlate float-ability with the differences in zeta potential. Cassiterite in water bears a negative zeta potential, The zeta potential of cassiterite is sensitive to pH changes; the electric double layer arises from the preferential adsorption of H+ and OH- ions and subsequent ionization of the hydroxylated surface. It is suspected that hydronium-ion concentration may cause reversal in the sign of the zeta potential. The ZPC was found to occur at pH 3.4. Metallic ions and the hydrated ions thereof affect the zeta potential of cassiterite in differing degrees of intensity. Without prior activation, sulfonated surfactants do not change the zeta potential of cassiterite. Sodium alkyl aryl sulfonate is especially active on lead-activated cassiterite and ferric-activated cassiteriten Microcalorimetric fiests confimed the activity of ions on cassiterite and showed the hydrated character of cassiterite smfaces. Close correlation between zeta potential and microflotation results was achieved.

Jan 1, 1969

By Earl R. Maize

This is the first of a series of reports dealing with development of a method of strengthening bituminous-coal-mine roof. Later reports will describe the progress made with injecting high cohesive and adhesive bonding agents into bedding planes and mine tests of roof strata strengthened by the bonds formed. The concept of strengthening roof strata in coal mines by inserting steel rods in the form of bolts has been widely accepted by the coal industry. The benefits of increased production and safety derived from this type of roof support has more than justified the increased cost of roof bolting. However, not all coal-mine roof structure is amenable to this type of support, and failures occur owing to the heterogeneity and variable character of mine-roof strata.3/

Jan 1, 1957

By Ronaldo Santos Sampaio

This paper call attention to increasing ratio of oxygen depletion from atmosphere besides the global worries about CO2 concentration increase in the atmosphere. It highlights the big mistake in considering Carbon Capture and Storage, CCS, as a way to reduce the increasing concentration of CO2 in the atmosphere. As a hypothetical example it presents an existing pseudo-ecosystem of manufacturing that has real windows of opportunity to increase its share in the global materials production industry, even in highly industrialized countries. As a suggestion and example the author point out possibilities to almost fulfill the proposed simple rules to be considered inside an ecosystem of manufacturing utilizing the production of steel via biomass versus fossil coal. A relevant and difficult rule to be attained in a quasi-ecosystem of manufacture is to be a near zero atmosphere oxygen depletion integrated process. The industrial alternatives that utilizes the actual photosynthesis are the ones that can reach a higher ecosystem of manufacture’s index. It is presented an ideal integrated steelmaking process where the gaseous, liquids and solid residues generated in one part of the system are or can be utilized in the other parts of the same system. A potential ecosystem of manufacture to produce primary iron is illustrated in the paper.

Aug 17, 2017

By William R. Yernberg

The Mineral Processing Plant Design, Practice and Control Conference was held from Oct. 20through 24, 2002, at the Fairmont Hotel, Vancouver, British Columbia, Canada. The conference was attended by nearly 400 of the world’s top mineral-processing specialists, including plant-design engineers, mineral-processing consultants, academics, suppliers and equipment manufacturers. The meeting was sponsored by SME and cosponsored by the Canadian Mineral Processing Division of the Canadian Institute of Mining, Metallurgy and Petroleum (CIM). The conference covered all aspects of mineral-processing design, construction and operation. The meeting included more than 130 technical presentations. Topics included sampling programs, feasibility studies, design criteria, process technologies, construction, start-up operations and shutdowns. To stimulate interaction and discussion throughout the five-day conference, the sessions were presented consecutively. Attendees had the opportunity to attend every session.

Jan 1, 2003

By J. R. Tickner

"Gold is conventionally analyzed using fire-assay or other destructive chemical methods that impose significant sample preparation, OH&S, and skilled labour requirements. Developed over the past 15 years by the CSIRO, PhotonAssay provides a new approach. A high intensity, high-energy x-ray source is used to activate atoms of gold and other elements in bulk mineral samples. The resulting activity is counted to automatically, accurately and rapidly determine metal grade. Samples weighing 0.5–1.0 kg can be measured in a few minutes with minimal preparation. As the method is matrix-agnostic, traditionally hard-to-assay materials such as highly refractory ores, carbon pulps and copper concentrates require no special treatment. We present the status of commercial PhotonAssay systems being developed by Chrysos Corporation. The first unit with a throughput of up to 80 samples per hour is to be deployed in an Australian assay laboratory in late 2017; smaller systems suitable for providing real-time assay directly at the mine-site will be progressively rolled out from mid-2018. Performance results from extensive testing using both mine-sourced and standard reference materials are presented, demonstrating the sensitivity and accuracy of the method. Implications for replacing conventional gold assay in exploration, mining and processing operations are discussed.INTRODUCTION Accurate methods for assaying ore grade are essential throughout the exploration, mining and mineral processing value chain. The discovery and evaluation of new ore deposits, reserve and resource definition, mine operations planning, ore processing, metal accounting and product quality evaluation all rely on accurate measurement of the valuable metal content of bulk materials. The analysis of gold presents particular challenges, stemming from the very low concentrations at which commercial operations run (often part-per-million (ppm), or equivalently one gram-per-tonne levels or below), and the highly heterogeneous nature of many gold deposits. These challenges mean that any analytical method must have high sensitivity and be capable of measuring large-mass samples. The most widely used quantitative analytical method for gold is fire-assay (Hoffman, Clark and Yeager 1998). An initial ore sample typically weighing several kilograms is dried, crushed and pulverized to allow a small sub-sample (10–50 g is common) to be representatively drawn. The sub-sample is mixed with flux, litharge (lead oxide), a reducing compound and other reagents. The mixture is fired at a temperature of 1000–1200°C until molten. After cooling, the slag is removed and the lead button containing any gold present in the sample is remelted in a porous cupel. The lead is absorbed into the cupel, leaving a gold prill which is either weighed directly, or dissolved in acid and analysed via atomic absorption spectroscopy (AAS) or inductively coupled plasma spectroscopy (ICP or ICP/MS)."

Jan 1, 2017

By Alex G. Sciulli

According to recent estimates, nearly 30 percent of the material from underground coal mining in the United States is rejected on the surface as waste. This accumulation of almost three billion tons of coarse and fine coal refuse is primarily from coal cleaning operations. The marketable coal is intermixed with sandstone, clays, shales, and carbonaceous rocks, which must be removed and disposed of in an acceptable manner. The disposal of mineral wastes is a major environmental concern. The most common types of environmental problems associated with coal refuse disposal are acid formation, erosion, and sediment control. Other areas of concern include air and water quality, combustion control, mine sealing, and reclamation. This paper focuses on these topics and attempts to outline special environmental features which can be incorporated into the design and construction of a coal refuse facility. Often these measures can minimize and possibly eliminate the potential environ- mental hazards. It is imperative, however, that these measures be adopted prior to and during construction, because of the relative ease and cost savings compared to post-construction implementation.

Jan 1, 1983

By George Comstock

Results are given of scleroscope and Brinell tests on specimens of cast 10-per cent. aluminum bronze, quenched and reheated at various low temperatures. The scleroscope was not found as reliable as the Brinell machine for measuring the hardness, for the size of the piece tested seemed to affect the scleroscope results. The maximum hardness was obtained by quenching and reheating to between 315° and 370° C. Softening was produced by reheating above 370° or 400° C. A series of polished and etched microsections showed a more reddish color in those that had been reheated above 400° C., and a change in microstructure above 500° C. IT HAS been known for many years that the alloy containing 90 per cent. copper and 10 per cent. aluminum can be hardened, like steel, by quenching from a suitable temperature, and that the hardened alloy can be softened again by annealing or drawing the temper. It does not seem to be generally appreciated, however, that the effect of the first slight reheating after quenching is actually increased hardness, the softening effect not taking place until a certain temperature of "drawing" has been exceeded. This paper gives the results of a few experiments on various specimens of cast 10-per cent. aluminum bronze, quenched for maximum hardness, and subsequently annealed at different temperatures. The hardness measurements were made with both a scleroscope and a standard Swedish Brinell machine; some peculiarities of the scleroscope test on this material are described. The author is not aware of many previous investigations of the hardness of this alloy when quenched and drawn, but two important papers on the subject should be mentioned. The earliest was by Portevin and Arnou,1 in which it was stated that tempering quenched 10-per cent. aluminum bronze at 400° C. increased the hardness as compared with the quenched untempered alloy and that reheating above that temperature was necessary to obtain any softening effect.

Jan 7, 1924

By W. G. McBride

THE present demand for men with engineering training exceeds anything in the history of the profession. Recent estimates indicate that mechanization of war has reached such a stage that at least twelve horsepower is required now for every one horsepower needed to run the machines of the first Great War. The scale of operations exceeds anything in the past, while more territory and people are involved than ever before. Many of our allies have inadequate or no facilities for producing the thousand and one articles absolutely necessary to the conduct of modern warfare. Lack of preparedness has made it necessary to produce at an unparalleled rate to gain parity with the enemy, while our losses have been so heavy that replacement, in itself, presents a task which might well stagger less courageous peoples. This means that not only is there an unprecedented demand for engineers to produce the machines, munitions, and supplies of war, but there is a correspondingly large need for men with engineering skill in the uniformed forces to operate and maintain the vast numbers of ships, &apos;planes, tanks, trucks, radios, and a myriad of other devices to carry on the varied activities of war. This abnormal demand came upon us after almost ten years of stagnation in the engineering industries. During this time many trained engineers drifted into other callings, while the lack of jobs for graduates caused a falling off in the number of men training for this profession. Consequently, the supply of well trained engineers was below normal when the madman of Germany precipitated us into the present turmoil. Added to all this, we in Canada are still suffering from governmental inefficiency in the utilization of the available supply of engineers. In the armed forces, engineers have been assigned to office and other work where their engineering training is not only wasted but for which men with more suitable training could be found. Mining engineers are debarred from service as aeronautical engineers, and students in mining engineering are denied the bursaries provided for aiding students in engineering. Mining and metallurgical engineers are both barred from the Ordnance department of the army. This arises from a misunderstanding in relation to engineering training. In Canadian engineering schools, all engineers are given a sound training in the branches of human knowledge which are fundamental to engineering: mathematics, physics, and chemistry. The basic difference between the several categories of engineers lies in the fact that training in the application of this fundamental knowledge to the solution of engineering problems is given in different subjects.

Jan 1, 1942

By E M. Gama, L Resende

The tailings are waste from mineral processing operations. The type of tailings of iron ore processing are classified into sandy tailings and mud. Already the overburden are showing significant levels of useful mineral. Both iron ore`s waste have in your composition phyllosilicates/clay that indicates the potential for use in niche markets as paving and cement. According to several studies, there are various technologies in bench and pilot levels that could be used on a large scale but there is not an economic environment, tax, regulatory and tax set. Many of these technologies are associated with the reuse of tailings and overburden in construction. All these factors influence for that so many initiatives remain in search formats and cannot advance to the new business format. There is no way to set goals of reuse of this waste, as already occurs in China, if there is not a fiscal, tax and economic structure to support such measures. The way to foster and ensure that reuse of tailings and overburden is an incentive for promoting a culture of circular economy that would allow the emergence of an ecosystem between the private, public and Government sectors with the objective of accelerating and subsidize the entire network of reuse of this waste. The closure of the mine could be the tool used to ensure and boost this ecosystem of reutilization to align it with the vocation of the area of the mining law. Following this model, the end of the mining activity could provide a financial return to the local population, a more effective environmental compensation and a reduction in costs related to the closure of the mine. In this study are shown how the Vale is working in the reuse of tailings and overburden.CITATION:Resende, L and Gama, E M, 2018. The challenges of the reuse of tailings and overburden, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 117–125 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Fred S. Karn

Inhibitors are used in coal mines as a precaution against accidental dust explosions. Although rock dust is the usual inhibitor many others have been tested. To facilitate testing a screening process using laser irradiation was proposed. The procedure includes irradiation of a coal-dust mixture followed by mass-spectrometric analysis of the evolved gases and an evaluation of the flammability characteristics of the gases. Carbonate-type inhibitors decreased the percentage of combustibles in the gases generated and inhibitors like NaCI (thermally stable salts) decreased the total gas generated. A suitable test procedure did not result from the investigation, demonstrating the inadequacy of fast heating, non-combustive techniques in rating inhibitors of coal dust explosions.

Jan 1, 1973