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By Georges Croisé, Les-Lee Thompson, Adrien Debergé

Membrane filtration systems have regained focus in recent years as an effective means of liquid-liquid separation to increase the concentration of valuable elements, recover reagents or remove impurities. ORANO Mining (formerly AREVA) investigated this cost optimization process opportunity as early as 2011 for implementation at the Trekkopje project (Namibia). The key focus was to separate and recycle bicarbonate from the uranium bearing eluate solution. The performance targets were successfully achieved at lab- and pilot scale with an ultrafiltration and nano-filtration configuration system. Early 2015, ORANO Mining further launched an investigation into the use of membranes for acid recycling at the KATCO In Situ recovery mine in Kazakhstan based on the favorable results from the original bicarbonate application. KATCO is the world leader in ISR uranium mining with an eluate processing capacity of 80 000 m3/yr. This site consists of two processing plants namely, Muyumkum and Tortkuduk, located 40 kilometers apart, both operating under acidic conditions whereas precipitation and packaging are based in Tortkuduk only. This paper serves to present the results from the integration of a nano-filtration system at the Muyumkum satellite processing plant. The project consisted of screening laboratory bench studies conducted at ORANO-CIME followed by process validation at KATCO through further bench and pilot test work. The feasibility study assessments were successfully concluded which led to the implementation at an industrial scale in Muyumkum of a nano-filtration process to reduce eluate volumes being sent to the uranium precipitation section whilst achieving effective separation of uranium from sulfuric acid. Nano-filtration technology has drawn significant attention due to the efficiency and reproducibility of the process and its moderate capital cost relative to operational savings. The reliability of the previous results is a great opportunity to reduce operative expenditures within ORANO’s next ISR mining project in Mongolia.

Jan 1, 2020

By Sergey S. Gudkov

In the current climate of changing the approach to mining and treatment of mineral resources, processing technologies are being developed that require little maintenance and are economically as well as ecologically sustainable. This may also involve the development of entirely new ways of ore processing. One promising approach is to use bioleaching for the pretreatment of gold refractory ores to cyanidation. Capital costs for vat bioleaching of concentrates and ores are very high and cannot be applied for small or medium-size deposits. IRGIREDMET JSC carried out bio heap leaching test work on refractory ore samples from three Russian deposits. Following this biological treatment a combination of flotation, vat bioleaching, and cyanidation are used to recover gold. After heap bioleaching, gold recovery was 75-80 per cent. It was found that efficiency of heap bioleaching process depends on ore feed size. High duration of this process is another feature and it lasts for about a year. This process can be also used for carbonates in the combination with other process during which acid generation occurs. The results of our studies have shown that this technology is amenable for refractory gold ores. Its introduction allows an increase gold recovery and to solve a number of environmental problems. Keywords: heap biooxidaton, the refractory of the ores, the degree of oxidation, arsenopyrite, pyrite, CIL

Sep 1, 2012

The combined production value of natural abrasives, which consist of tripoli, special silica stone, garnet, and emery, decreased in 1985. Shipments of processed tripoli increased slightly in quantity but decreased 6% in value, Production of garnet, an abundant iron-aluminum silicate, increased 24% in quantity and 20% in value. There was an 11% increase in the quantity and a 7% increase in the value of refined garnet shipped when compared with 1984 shipments, a new record high. Production of crude special silica stone decreased 10% in quantity and 14% in value, and shipments of finished special silica stone products decreased 85% in quantity and 68% in value. Both the quantity and value of special silica stone finished products sold or used were the lowest since 1981. Production of emery, an impure aluminum oxide, decreased 56% in quantity and 61 % in value of product mined and shipped. [ ]

Jan 1, 1987

By S. Schutte, J. Pelders, F. Magweregwede, S. Ngobese, W. Botha

A people-centric, systematic approach that involves different stakeholders is considered necessary to successfully address changes associated with modernizing the South African mining industry. In this paper we discuss the inclusion of various South African mining industry stakeholders, particularly the employees, in equipment design and development processes. Data was acquired through a literature review and inputs from South African mining industry stakeholders through focus group discussions, interviews, and an online survey. It was suggested that some of the areas that could be improved by the inclusion of employees in the process are design quality, ergonomics, equipment acceptance by the workforce, safety, efficiency, skills, insight into context of use, and early design iterations and identification of problems. Among the issues considered to be barriers to inclusion were lack of buy-in, lack of resources, difficulty in manufacturers accessing the mines, difficulties in involving too many people, intellectual property concerns, and unavailability of mine employees due to their key responsibilities. Identified critical factors in the equipment design and development process include iterative design, stakeholder participation throughout the process, needs analysis through consultation, and change management. A guideline was developed for worker inclusion in equipment design and development that could be used by the South African mining industry. The study identified several economic and social benefits of including stakeholders in the early stages of design and development. It is recommended that the South African mining industry considers using the developed guideline.

Apr 5, 2023

By William Petruk

The development of automatic image analysers brought the application of image analysis into process mineralogy because the analysers can measure parameters more easily, quickly and accurately than by manual grain counting techniques, and can also collect data unobtainable by manual grain counting. Data from ore specimens and mill products are used to predict and to define the behaviour of minerals during processing. The analyses are generally performed on the basis of either surface areas or linear intercepts of grains in polished or thin sections, and the data are computer processed to give mineral quantities, liberations, size distributions, and characteristics of middling particles. For analysis, the minerals must be detectable and discriminatable from each other. An image editor is usually used when minerals are not easily discriminated. In addition BSE-8EM photographs have been used where the silicate minerals could not be discriminated from the mounting media. Methods of analysis, typical results, and their applications are discussed.

Jan 1, 1982

By David M. Koogler

If you are contemplating starting a small coal mining operation there is a good possi¬bility that you can not afford it. If you, have already started, you may be on the road to bankruptcy. If you are a small but well established operator you may be trading dollars, or even dissipating your capital, equipment and other assets. A bleak outlook? Yes! Meant to be discouraging? No! Just a reminder that, with todays costs of doing business, high interest rates, rapidly increasing costs and decreasing sales prices, a small businessman/miner had best watch closely or he will be mired in something worse than a soft bottom - namely a cash and credit shortage, and in too many instances In recent times, bankruptcy. We will not dwell on what happens once you are that far gone, though I could cite a good example. But, let us look at what should be done to avoid such a catastrophe.

Jan 1, 1981

By J M. Marwan, B Tang

Strain-type rockbursts, or strainbursts, are characterised by a localised violent failure. Their cause is attributed primarily to the sudden release of strain energy, which accumulates in a volume of highly stressed rock as a result of mining activities. Examples of such phenomena are crown/sill pillar bursts created in the mining process, pillar crush in room-and-pillar mining, face ejection in drift development headings at depth, and floor bursts associated with deep shaft sinking. The paper describes a simple method for the assessment of crown pillar bursts in steeply dipping ore deposits which are extracted by the overhand cut-and-fill method. The method is based on a theory previously established by the author to help assess the need for a remedial solution such as pillar destress blasting. Basically, the mining-induced energy storage rate (ESR) in the pillar is compared with the critical strain energy to come up with the so-called burst potential index (BPI).

Jan 1, 2001

By E. H. Griswold, C. E. Beecher

DURING 1931 the petroleum industry has faced the most hazardous periods of its existence, caused by large potentials, overproduction, and demoralized markets. Two state governors actually resorted to the use of the militia in an effort to restore a semi-stabilized condition within the industry, to prevent waste of the states' natural resources, and to restore prices to a level that would yield the states a reasonable tax revenue. These conditions have made it necessary to put into effect most. stringent economies and have produced a spirit of cooperation between companies to an extent that never before existed. The necessity for unified action on such matters as proration and the advantages to be gained by unit operation are being realized by the oil industry as a whole. Fewer wells have been drilled and wildcat operations almost eliminated: development and operation costs have been greatly reduced and more attention is being paid to efficient recovery methods. The net work of oil pipe- lines has grown rapidly especially in the area of East Texas. The construction and operation of natural gas and gasoline pipelines into areas far distant from the source of supply has been one of the outstanding accomplishments. Refining efficiency has continued to increase and the public is being supplied with a better grade of gasoline at a lower price. The unreasonable tax which state politicians have succeeded in placing on gasoline has encouraged tax evasion and unfair competition by un- scrupulous dealers and has misled the public as to the true price of gasoline.

Jan 1, 1932

By Dr. Peter J. Conroy

The current study is part of the U.S. Department of Energy's (DOE) on-going subsidence research program. The long-term objective of the DOE program is to develop analytical methods of subsidence prediction applicable over a broad range of geologic and mining conditions encountered in the United States. The DOE currently has several contracts in progress to develop a sound data base that can be used in the development of predictive models. Dames & Moore is currently under contract to the DOE to collect and analyze detailed subsidence and hydrologic data from a coal mine employing longwall mining methods in the Eastern Coal Province. Work under Contract No. DE-AC22-80PC 30335 began in October of 1980 and will continue through September of 1984. This paper summarizes the work that has been completed through September of 1981 and presents the results that have been achieved during this period. Technical difficulties encountered during both the installation and monitoring phases are discussed, and recommendations for future work are presented.

Jan 1, 1982

By J Zhou, L Crompton, K P. Galvin, J L. Sutherland, C P. Lowes, C Bezuidenhout, J Bijzet

Platinum Group Metal (PGM) bearing ores from the Upper Group 2 (UG2) reef often contain significant concentrations of chromite which can potentially be upgraded to produce a saleable product. A common approach is to implement gravity separation on the PGM flotation circuit tailings. However, where the particle size range of interest is broad and the lower size limit ultra-fine, the challenge is how to maximise the recovery at a saleable product grade without compromising throughput. This study was concerned with the performance of a REFLUX™ Classifier for beneficiation of a PGM bearing chromite ore and the benefits of size classification. The sample had a nominal top size of 0.5 mm and was processed over the complete size range and in two discrete size classes following classification at 106 µm. The primary goal was to produce a concentrate exceeding 40 wt. per cent Cr2O3, ideally approaching 42 wt. per cent Cr2O3, with minimal PGM losses above 106 µm. A major challenge was to process at the required solids throughput in a single stage with the feed pulp density constrained to a nominal upper limit of 30 wt. per cent solids. It was found that varying the controller density set point of the REFLUX™ Classifier produced strong control of the product grade. Products as high as 41.1 wt. per cent Cr2O3 were produced at 78.6 per cent recovery for the +106 µm material, while in the −106 µm portion the product grade was as high as 41.4 wt. per cent Cr2O3 at 83.2 per cent recovery. Processing the feed in discrete size classes enabled the volumetric feed and fluidisation rates to be optimised for a given application; hence, superior performance was achieved at the finer sizes. This work has demonstrated the value in considering feed preparation as well as technology selection in developing a robust process solution.

Aug 24, 2022

By Kelly D, Moore C

The Golden Mile, which has been mined continuously for the past 100 years by both underground and more recently open pit methods, occupies an area of 1.2 km by 4 km adjacent to the city of Kalgoorlie Boulder in Western Australia (Figure 1). Large-scale open pit mining at the Kalgoorlie Consolidated Gold Mines (KCGM) Fimiston operations is currently extracting 7.8 million tonnes of oxide and sulphide ore for a total production of 522 000 oz per annum. The effectiveness of grade estimation techniques at KCGM has been examined with reference to existing 10 m bench sample data from all operating areas within the Eastern Lode System of the Main and North pits. The aim of the study was to recommend practical parameters for grade control estimation. The review included comprehensive variography and comparison of nonparametric estimation methods (Joumel, 1983) such as indicator kriging and probability kriging with ordinary kriging, leading to the development of improved grade control parameters and procedures for both daily quality control and short term mine planning. This paper reviews the geological, statistical, geostatistical, mining and modelling features studied in order to present KCGM's Mining Department with recommendations for improving grade control.

Jan 1, 1994

By Philip Nash, Jie Zhou, Joshua Blackketter

"Large ingots tend to have internal defects such as shrinkage cavities and porosities, which have to be closed during the cogging stage to ensure sound internal quality of forged parts. In this work, finite element methods were used to simulate open die forging passes, with varying parameters that affect the void closure behavior profoundly. Numerical models ware constructed in ABAQUS, DEFORM and FORGE using data taken from footage of the forging process and material mechanical data obtained from the Gleeble compression tests. Forging variables such as pass rotation, reduction per pass, and feed ratio were studied with intense attention paid on the special properties of H13 steel, so that this study can be applied to solve real world problem.IntroductionCenterline defect closure is a frequently studied but still challenging topic in open die forging industry. In practice, open die forging is employed as an effective hot forming process to make desired shape of metal products as well as to ensure center consolidation of internal defects which result from the casting process. Nowadays, remarkable large forgings have been more and more required to meet industries demand. However, the increase in ingot size has tended to result in considerable macrosegregations and shrinkage cavities or voids, which need to be worked thoroughly during the forging process; but the size of the products and limitations of manufacturing capacity, such as the press load, make it difficult to achieve adequate local deformation to close those defects. Therefore, choosing optimal forging parameters under given work condition to ensure good internal quality of forged products is critically important."

Jan 1, 2012

By François G. Bernardeau

Cement-bentonite (C-B) slurry walls have been used for ground water cutoff in deep excavations, contamination containment, and other applications. Hydraulic conductivity is of great concern for cement-bentonite slurry walls. The quality control program usually specifies permeability and strength tests to be performed in a laboratory on samples cast in the field and cured for a certain time. Currently there is no widely accepted in-situ test method for the performance of the constructed slurry wall. A recently constructed cement-bentonite slurry wall in South Carolina included a 200-foot-long test section done in advance of the production of an 8,300 foot-long wall. Intensive tests and investigation were conducted during and after the test section construction: Monitoring piezometers were installed using wet insertion method and packer tests were conducted in boreholes drilled in the post-28-day-cure slurry wall. The permeability measured from the packer tests was about two orders of magnitude higher than the design and the laboratory test values. Additional investigation was performed using a video camera to inspect the borehole walls especially the packer test sections. Test pits were excavated to observe both sides of the cement-bentonite slurry wall. A thorough inspection was conducted to evaluate the integrity of the wall. The lessons learned and issues regarding the disturbance effects of in-situ testing of cement bentonite slurry walls is presented and discussed.

Jan 1, 2008

By D Xiong, G Xu, L Yao, F Wang, Y Duan

The goal of this project has been to digitise and use drill parameter data from rotary drilling (measurement while drilling; MWD) for a more effective planning of the blasting process in surface mines. A more accurate and reliable digital drilling and automatic hardness identification technology was developed, which includes both a hardware and software system. In the aspect of hardware, we designed a positioning, navigation and hardness perception terminal system which consists of a global positioning system original equipment manufacturer board, programmable logic controller and sensors of measuring major parameters, and a wireless data transmission system which combines digital blasting platform and wireless transmission facilities. In the aspect of software, we developed the navigation software of locating blastholes using LabVIEW and C++, and the blasthole design software using AutoCAD ActiveX (C#) technologies. This new technology is applied at Jiangxi Dexing Copper Mine, and initially realising the digitisation of drilling and hardness identification in blasting zone.CITATION:Duan, Y, Xiong, D, Yao, L, Wang, F and Xu, G, 2015. Advanced technology for setting out of blastholes and measurement while drilling, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 593–598 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By D Genge, E Martin, T Goswami, M Rothery

Rio Tinto’s Hunter Valley Operations is a large open pit coalmine situated in the heart of the Hunter Valley in Australia. The Riverview West Pit has faced increasing production challenges in recent times due to decreasing dragline strike lengths and increasing environmental constraints on vibration, overpressure and fume generation. Conventional mining techniques would involve five to six production blasts per strip to recover multiple coal seams. Each blast event carries the risk of exceeding the strict environmental requirements. By working collaboratively with Orica, it was realised that the blasting method known as Stratablast™, in conjunction with advanced computer modelling techniques, could provide productivity gains whilst simultaneously providing more control over the environmental effects and the impact on nearby infrastructure.As a result of this change, the number of blasts per strip was reduced to one, with the implication that a great deal of care and forethought was needed to manage the increased challenge posed by multiple constraints in the proposed mining area. This innovative approach of combining throw and stand-up blasts allowed the extraction of all major coal seams in a single pass blast event. The blasts were initially designed with a large factor of safety to stay within environmental limits as they were over 1.1 km in strike length, with more than 800 holes and with a total charge weight of about 1000 t of bulk explosives. Furthermore, there were conflicting priorities around the desired blast outcomes. So far, 11 such blasts have been designed and successfully fired. After each blast, innovative design changes have been iteratively implemented to provide further control over environmental impacts, whilst continuing to improve productivity. As a result of these changes, blasts have progressively increased in complexity with the inclusion of features such as damage zones, mid-splitting, time gaps and different directions of firing. The consequence of this complexity is that the blast duration can be as long as 28 seconds to accommodate all components of the blast.This project has increased the productivity of the Riverview West Pit through blast design improvements and allowed the environmental impacts to be managed with far more control and predictability than would have been possible under a conventional blasting regime. There still remains room for further optimisation of mine productivity and this is being addressed through a process of continuous improvement.CITATION:Goswami, T, Martin, E, Rothery, M and Genge, D, 2015. A holistic approach to managing blast outcomes, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 645–654 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By David E. Albus, Ahmadreza Mortezaie, Bidjan Ghahreman

The structural evaluation of seismic performance of an existing hospital in Long Beach, California, required spring constants of foundation elements. The structure included support by deep foundation elements comprised of belled (underreamed) caissons. The available relationships in the governing building code (ASCE41-13) to compute axial stiffness is not applicable due to the belled configuration of the caissons. The large diameter of the bells required consideration of the foundation medium to the axial stiffness; a detail not clearly described in ASCE 41-13. Furthermore, prescriptive equations in ASCE 41- 13 used to estimate lateral stiffness only consider pile groups with the assumption that the only source of lateral stiffness is the axial reaction of individual piles. These assumptions were invalid for the project at hand where all caissons are configured as single foundation elements, not a pile group. In the present work, the approach taken to estimate seismic stiffness of single-belled caissons is described which accounts for the elastic behavior of the foundation medium below the bell base and lateral behavior of single-pile shafts. Results of the work provide a more satisfactory derivation of the spring constants consistent with current modeling methods. INTRODUCTION Seismic evaluation of an existing hospital in Long Beach, California, required geotechnical investigation followed by site-specific ground motion analysis. This evaluation was required by the Office of Statewide Health Planning and Development (OSHPD) in order to meet the requirements of the Structural Performance Category 4D (SPC-4D) published as a part of the 2016 California Building Code, CBC (Section 3412A). SPC-4D utilizes ASCE41-13, as modified by OSHPD, and involves two seismic performance objectives: BSE-1E (20% probability of exceedance in 50 years) and BSE-2E (5% probability of exceedance in 50 years). Spring constants and capacities of foundation elements were needed for evaluation of the structural performance of the building subjected to these two performance objectives. Our review of the as-built foundation plans indicated that both shallow footings and caissons were used for support of the structure. The plans demonstrated that all caissons are belled (under-reamed) and are individual, i.e. not part of pile groups. In this paper, the subject site condition and foundation elements are described first. This is followed by details of assessing spring constants and vertical capacities for belled caissons. The new requirements of the 2016 CBC concerning the evaluation of critical facilities will likely entail evaluation of other structures with belled caissons due to the more extensive use of these foundations in the past. This paper proposes a method to address the conditions of individual belled caissons not explicitly considered in the current code provisions.

Jan 1, 2018

By Evans E. C.

Discussion of the paper presented at the Manchester Geological and Mining Society' general meeting held in Manchester, March 14th , 1916, with Leonard R. Fletcher, President, in the Chair included contributions by Fletcher L.R., Paton J.D., Orchard A.J.A., Ross A., Gerrard J. and Stephenson H., with the author's responses

Dec 1, 1916

By Jei Y. Choi, Paul G. Shewmon

The surface self-diffusion coefficient of copper (D,) has been measured between 847° and 1069 "C for six different orientations. These were the(111), (110, (100, and three higher index surfaces. The activation energy for Ds (designated Q s) was found to be about 49 kcal per mol for all six surfaces, and Do about 2 x 104 sq cm per sec. At any temperature Ds varied by no more than a factor of three over these orientations. It is shown that, if the free energy of a surface atom is uniquely determined by its number of nearest neighbors, it follows from the Principle of microscopic reversibility that Qs should have the same value for all surface orientations, and Ds should vary little with orientation. This model also suggests that for clean fee metals Qs ~ 2/3 AH, (heat of vaporization). This is true for copper. ALTHOUGH it has been appreciated for several decades that atoms can diffuse more rapidly on a surface than through the bulk of a crystal, it has only been in the last few years that reliable values of the surface self-diffusion coefficient (Ds) have become available. Tracer studies of Ds had been attempted prior to this period, but when a tracer is placed on a surface, an ever increasing fraction of it is drained off into the lattice. The correction for this loss involves a very difficult, and as yet unperformed calculation. Those who have worked with tracers have not corrected for this loss.1, 2 Thus their results indicate that Ds is greater than the self-diffusion coefficient in the lattice (Dl), but it has not been established that they give quantitative data on Ds. A procedure which avoids the problem of tracer loss is to study the rate of mass-transfer under the effect of surface tension. If the surface asperity being studied is very small, the mass transfer occurs entirely by surface diffusion. The kinetics at which a grain boundary groove forms on an initially plane surface is a well-studied case of this type. The smoothing of a slight scratch in an otherwise flat surface is another procedure that has been studied. If these grooves are up to 20 to 30 µ in width, the dominant mechanism for mass transfer is surface diffusion (at least in the case of metals with low vapor pressures), and the widths can easily be measured with an interference microscope. Of these two, mass-transfer techniques only in the case of grain boundary grooving has a rigorous mathematical treatment been given. This was done by Mullins.3,4 His analysis predicted that in the case of copper in an atmosphere of an inert gas, surface diffusion should be the dominant transport mechanism. This analysis gave an equation for the groove profile and predicted that the width of the groove would increase as (time)1/4. Mullins and Shewmon showed that both of these predictions agreed with experiments.5 Thus the validity of the values of Ds given by this procedure seems to be well established. Gjostein has used copper bicrystals and the grain boundary grooving technique to determine Ds and the activation energy for surface selfdiffusion (9,) in the [001] direction on surfaces ranging between the (100) and (110) planes.= He reported that Qs = 41 kcal per mole and Do = 6.5 x 102 sq cm per sec for all orientations studied. Since the results did not change with the dew-point of the dry hydrogen atmosphere or the type of refractory tube used, he concluded that the surfaces were clean, or at least that the results were not influenced by any impurities chemisorbed from the atmosphere. The work reported here reproduces and extends Gjostein's study in that D s and Q s were determined for copper over a wider range of orientations. To study the effects of impurities, two purities of copper were used as well as cathodic etching to remove any possible electropolishing film. Gjostein postulated that the diffusing atoms on a surface near a low index plane are the few atoms which are adsorbed on the smooth region between ledges or steps in the surface. A more rigorous derivation of the equation relating Ds to the concentration and jump frequency of these adsorbed atoms is given here. Using this treatment, our empirical observation that Q s and D s are essentially the same for all surface orientations can be shown to follow from the assumption that the free energy of a surface atom is uniquely determined by its number of nearest neighbors. The studies of D s using the scratch technique have been carried out by Blakely and Mukura on nickel,' and by Geguzin and Oveharenko on copper. The latter study using copper gives values of D s roughly

Jan 1, 1962

By E. J. Dulis, R. M. Fisher, K. G. Carroll

IT is well known that ferritic steels containing more than 15 pct Cr when subjected to temperatures in the range of 700" to 1000°F exhibit increasing hardness and decreasing ductility. The phenomenon has been widely termed the "885 °F embrittlement," after the temperature of most marked effect.'.' In view of the excellent review articles available in the literature3-6 only a brief account of experimentally established facts need be given here. The extent of changes in physical characteristics during embrittlement depends on chromium concentration and time at temperature, higher alloy content and longer time both promoting more rapid and extensive changes. In a 27 pct Cr steel, changes in impact strength and in angle of fracture in bending can be detected after only a 1 hr exposure at 885°F; after 50 hr this steel becomes quite brittle. Hardness increases slowly with time during thousands of hours exposure and may attain a maximum hardness number twice as large as that of the unexposed steel. Microstructural changes accompanying embrittlement have been described as an initial widening of grain boundaries followed by eventual darkening of ferrite grains. Embrittled steels etch more readily, e.g., the weight loss of a 27 pct Cr steel in acid solution may occur at a rate one hundred fold greater following exposure at 885 OF. Marked changes which accompany embrittlement have been observed in electrical resistivity, specific gravity, and magnetic coercive force. Changes in physical properties may be readily removed by heating at temperatures above the embrittling range, such as a treatment at 1100°F for 1 hr. It has frequently been noted that the 885 °F embrittlement suggests precipitation on a submicro-scopic scale of a chromium-rich constituent, the nature of which has not been revealed by X-ray diffraction. Progressive broadening of the body-centered cubic diffraction lines during embrittlement has been observed," and recent observations by Lena and Hawkes' upon single crystals have shown early asterism in X-ray photographs, disappearing within an hour at 900 °F. Many workers have ascribed8-13 the phenomenon to a precipitation of a phase (FeCr), which is known to cause embrittling effects at temperatures much higher than 885°F. Two general observations, however. suggest that a precipitation cannot be responsible for the 885°F phenomenon: 1—prior cold work greatly enhances a formation, whereas it scarcely affects the 885 °F embrittlement, and 2—the presence of an alloying element such as nickel or manganese may have an effect on the 885 °F embrittlement which is opposed to its effect upon a formation. The slight enhancement of a formation and 885°F embrittlement observed in the presence of elements with strong carbide and nitride forming tendencies' is probably a consequence of lessened chromium depletion of the matrix. The bar graph in Fig. 1 shows a typical example, taken from two 27 pct Cr steels used in this work, of the hardness after exposure for 10,000 hr at 900°, 1050°, and 1200°F. Steel A (0.03 pct C, 3.13 pct Mn) showed marked hardening at 900" and 1200°F, whereas steel B (0.12 pct C, 0.63 pct Mn) exhibited only the 900°F hardening. The cr phase was found in steel A at the higher temperatures but not in steel B. Presumably a formation is enhanced by the low-carbon and high-manganese concentrations in A," Thus there are two distinctly different hardening phenomena present which cannot both be ascribed to v precipitation without invoking a transition phase possessing remarkable properties. Materials A number of chromium steels exposed for long periods (5000 to 34,000 hr) at 900°F, as well as unexposed samples of one of the steels, were available for this investigation. Table I gives the chemical compositions and aging treatments of these steels. In addition to these steels exposed in the elevated temperature test furnaces of the National Tube Division, a number of high-chromium steels were heated for short periods in small laboratory air furnaces and lead baths. Supplementing these commercial steels, a sample of high-purity (0.018 pct C, 0.002 pct N) 28 pct Cr iron, exposed 1000 hr at 887°F. was furnished by the Union Carbide and Carbon Corp. In addition, an alloy of iron and chromium of high purity containing 46 pct Cr was used. This

Jan 1, 1954

By I. M. Roberts

The war emergency has affected every phase of industry. The gas and coke-oven companies have sought faithfully to discharge their responsibility in this critical period and have willingly modified their operations where possible to meet the ever increasing demands made upon them. Our company made commitments for blast-%urnace coke for war purposes which necessitated a reduction in coking time in order to produce the amount required to meet the new demands. At the same time there were certain customers of long standing, who had been supplied with foundry and egg-sized coke produced on fairly long coking periods, who also were engaged in war work and whose patronage we desired to retain. Coke produced on short coking rates from the coal mixture we were then using would not have been satisfactory for these customers. The average width of our ovens is 19¾ in., which is a little wider than the more modern ovens of the present day. They were originally designed to give somewhat cool tops in order to produce a rich gas. This necessitates carrying the heats a little on the warm side so that the tops will be fully carbonized. A reduction in coking time, as is generally known, is accompanied by a reduction in the average size of the coke produced. This is due to the greater shrinkage that takes place at the higher temperatures required to carbonize the charges in a shorter time. The net result is that the coke is more cross fractured and longitudinally fractured and breaks up into small sizes on handling. The cokes produced from the better coking coals seem to be more susceptible to fracture at high temperatures than those from poorer coking coals. A coal mixture that produces a beautiful foundry-sized coke at 30 to 36 hr. may yield a product at 18 hr. that would be so badly fractured as to be unsatisfactory for foundry practice. Coking Characteristics OF Coals Our problem was to find some economical innovation and develop a method that would enable us to reduce the coking time and still produce a coke satisfactory to our foundry trade. However, before discussing the results of our present operations, it might be well to present a few observations on the coking characteristics of coals in general. Most coke-oven operators carbonize a blended mixture of coals. It may consist of a single high-volatile coal with a single low-volatile coal, or of a combination of several high-volatile and low-volatile coals. Medium-volatile coals of the Eagle seam are used for the production of high-grade foundry coke. Medium and high-volatile coals are often blended with one or more low-volatile coals. The possibilities are almost infinite, but the combinations are limited by such factors as cost and facilities for handling multicoal mixtures, and by other practical considerations. Every coal has characteristics that make it blend better with a particular coal or coals in preference to others. This property has

Jan 1, 1944