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By Marting J. Gavin

The twentieth century has often been spoken of as the age of petroleum, and from many viewpoints it can be justly considered so. Certainly the petroleum industry is one of enormous importance to this country, industrially, financially, and economically. The United States, however, at present producing over 60 per cent of the world's total output of petroleum, is not producing petroleum at a sufficient rate to provide for its own domestic, consumption. For several years this country has been importing increasing quantities of crude and partly refined oils from Mexico, and has been drawing heavily on domestic stocks of petroleum. Production in the United States is increasing, but it is not increasing at the same average rate as domestic consumption, nor is it probable that in the future domestic production will increase sufficiently to satisfy the demands of domestic consumption, but on the contrary, in the opinion of those best qualified to know, the peak in the curve of domestic production of crude petroleum will be reached in a comparatively few years, whereas the consumption of petroleum and its product will increase at a continually growing rate. This country, then, must turn, and as the increasing imports from Mexico indicate, is turning to other sources than the crude petroleum, produced in this country to make up the deficit between domestic production and domestic consumption of petroleum and its products,

Jun 1, 1920

By Samrat Mohanty

The construction of underground hydrocarbon storage caverns in Jurong Island, Singapore, is nearing completion. The facility, located beneath the seabed of Banyan Basin, is comprised of five storage caverns with a storage capacity of approximately 1.5 million cubic meters. The galleries of each cavern are 20 m wide by 27 m high and approximately 340 m long. In addition to the storage caverns, various access and operations tunnels are required to support the facility. Among these are water curtain galleries to ensure that hydrostatic pressures in excess of hydrocarbon storage pressure are maintained in the rock mass surrounding the storage caverns. Early in the design process, conventional steel rock bolts with resin polymer grout were considered for ground control. However, the construction contractor proposed using fibe-reinforced polymer (FRP) bolts with cement grout due to the corrosive hydrologic environment, weight and handling considerations, local construction preferences, and the requirement to have a cavern design life of 50 years. FRP bolts with cement grout were ultimately chosen for the project. The FRP bolting system has proven to be very successful, with no ground failures experienced where systematic FRP bolting has been applied. This paper discusses the properties of FRP bolt/cement grout bolting systems, their characteristics in relation to steel bolt/resin bolting systems, and numerical modeling results assessing their performance.

Jan 1, 2014

By James D. O, DeLa&apos

Multicomponent materials are common in nearly all areas of materials science and technology, yet the use of phase diagrams to represent these complex systems is hampered by the requirement of three or more dimensions for explicit graphical representation. In the present work, the "solid-modeling" capabilities of a computer aided design (CAD) system have been applied to the representation of three-dimensional phase diagrams. Relevant phase diagrams for a hypothetical quaternary eutectic system were constructed and used to demonstrate the capabilities of the technique. These capabilities lead to relative ease of phase diagram construction and improved access to qualitative and quantitative information. Results of this work are contrasted and compared to previous efforts toward computer ,representation of phase diagrams. It is concluded that solid-modeling of three-dimensional phase diagrams can be used to advantage in both education and research.

Jan 1, 1991

By William E. Brewster

Dating back some five years ago, various foundries made inquiries as to the probable total carbon content in a given specification and grade of pig iron. Up to that time we had no data, and except for a few occasional determinations of total carbon, no attempt had ever been made to set up routine determinations of total carbon. In fact, at that time, a cast analysis was considered sufficient, without examining at further length into possible variations of analysis between ladles of the same cast. In view of the various inquiries as to total carbon, we sampled all piles of all grades of pig iron, making complete analyses. Finding some variation in carbon content, we secured more samples and plotted the carbon content with respect to silicon in each grade of iron except for the higher phosphorus foundry iron, where it was necessary to divide the group into twenty-point phosphorus ranges. This is easily understood, owing to the falling off of carbon content with the increase in phosphorus content, silicon in each case being the same. In addition, these curves clearly demonstrate the lowering of the carbon content as the silicon is increased. In order to insure accuracy and reliable determinations the following method of sampling and analysis was employed: Two pigs selected from each end of the car, each car containing iron from one 50-ton ladle, are drilled with a 5/6-in. drill all the way through from top to bottom in the center of one section of the pig. The drillings are collected and transferred to an 80-mesh sieve; the portion passing through and the portion retained are placed in separate envelopes and labeled accordingly. The amount of sample in each envelope is weighed to obtain the proportionate amount of coarse and fine drillings, then a 1/2 factor weight of sample (1.3636 grams) made up of proportionate

Jan 1, 1936

By William E. Brewster

Dating back some five years ago, various foundries made inquiries as to the probable total carbon content in a given specification and grade of pig iron. Up to that time we had no data, and except for a few occasional determinations of total carbon, no attempt had ever been made to set up routine determinations of total carbon. In fact, at that time, a cast analysis was considered sufficient, without examining at further length into possible variations of analysis between ladles of the same cast. In view of the various inquiries as to total carbon, we sampled all piles of all grades of pig iron, making complete analyses. Finding some variation in carbon content, we secured more samples and plotted the carbon content with respect to silicon in each grade of iron except for the higher phosphorus foundry iron, where it was necessary to divide the group into twenty-point phosphorus ranges. This is easily understood, owing to the falling off of carbon content with the increase in phosphorus content, silicon in each case being the same. In addition, these curves clearly demonstrate the lowering of the carbon content as the silicon is increased. In order to insure accuracy and reliable determinations the following method of sampling and analysis was employed: Two pigs selected from each end of the car, each car containing iron from one 50-ton ladle, are drilled with a 5/6-in. drill all the way through from top to bottom in the center of one section of the pig. The drillings are collected and transferred to an 80-mesh sieve; the portion passing through and the portion retained are placed in separate envelopes and labeled accordingly. The amount of sample in each envelope is weighed to obtain the proportionate amount of coarse and fine drillings, then a 1/2 factor weight of sample (1.3636 grams) made up of proportionate

Jan 1, 1936

By R. Tessier, C. R. Larsen

"INTRODUCTIONOn November 10, 1982 Nor and a Inc signed an agreement with Golden Sceptre Resource Ltd. and Goliath Gold Mines Ltd. to construct a mine and milling facility.The Golden Giant mine is located in the Marathon area of north - western Ontario, immediately north of Highway 17 and about- 3.5 km west of Highway 614.With the exception of selected unit processes, the mill was designed for a nominal throughput of 2500 tonnes per day with early operating data to be used to identify sections requiring possible expansion to achieve an ultimate throughput of 3000 tonnes per day.Commissioning of the highly instrumented milling complex which includes crushing, grinding, cyanidation, and carbon in pulp processes commenced in February 1985. After water testing various sub-circuits from grinding through tailings, waste ore was introduced to ensure proper mechanical and electrical operation of process equipment.The first ore was milled as a mixture with waste on March 4, 1985. The first gold bullion was poured April 6, 1985.Initially, ore was only available from mine development at a rate of 700 t/d, which was milled at a minimum rate of 1200 t/d. While regular weekly shut downs of two to three days was useful for mechanical maintenance, changes, and modifications, process tuning was more difficult due to the non-steady operation. As increased quantities of ore became available, regular weekly shutdowns tapered off and process operation improved accordingly. For testing purposes and as ore was available, mill throughput was increased regularly to 2300 t/d and for very short periods of time to nearly 3000 t/d.No major design or operating problem has been encountered to date. The following is a brief description of the milling process and various operating highlights. Process flowsheets are shown in Figures 1 through 6."

Jan 1, 1986

By Sam Tour

OF the new alloys achieving commercial prominence during the year, an aluminum-silicon magnesium casting alloy, which is similar in many respects to the 4 per cent copper alloy, developed about 1921, which has attained such a wide field of service, may be mentioned. The new alloy, like the old, is a heat-treatable type and develops about the same physical properties. The alloy casts easily and is relatively insensitive to high pouring temperatures. Its ability to produce substantially leak- proof castings is noteworthy. A second casting alloy development is the new Aluminum Co. of America No. 132, "Lo-Ex" piston alloy, a result of nearly eight years of research. The alloy contains about 14 per cent silicon and varying amounts of nickel, copper, and magnesium. It exhibits a low coefficient of expansion and thus permits small piston clearances. Its lower specific gravity is a further advantage.

Jan 1, 1932

By A. Haldar

This study focuses on the flow characteristics of hypereutectic Al-Si alloys in thin sections. The pattern assembly consisted of spiral horizontal patterns, 6.25 mm (0.25 inch) and 12.50 mm (0.50 inch) in thickness with a common sprue. Al-Si alloys with silicon levels of 14%, 18% and 22% were poured with superheats of 60°C, 115°C and 170°C. It was observed that metal fluidity (in terms of flow length and metal velocity) increased with increase in silicon levels and superheat for both section thicknesses. It was also observed that, for a section thickness of 6.25 mm (0.25 inch), silicon level had more pronounced effect on the metal fluidity. For 12.50 mm (0.50 inch) thickness, both silicon level and superheat affected the metal fluidity. The surface hardness of the castings increased with an increase in silicon level of the alloys at the gate and the flow tip. Detailed study of the flow tip was also carried out with a view to understanding the effect of silicon level and superheat on undulated flow length, surface hardness and microstructure.

Jan 1, 2007

By Ernst Lindemann

The SMS group has developed the ultrasound technology “HD scan” for inspection of the internal quality of as-cast products. This method of sample analysis requires less preparation work and is safer than the current, most common technique of etching and/or sulphur printing. Furthermore, this technology offers a three-dimensional view into the sample of the cast product and thus more representative information for a better quality evaluation. The internal quality evaluation can be performed automatically and objectively by software based on clear statistical methods. A quantitative centerline segregation rating can be assigned to each sample, based on the size and distribution of segregates detected by the unit. Internal crack statistic (length, position, orientation, etc.) and narrow side profile can also be measured. Grain macrostructure can also be visualized which allows for a potential optimization of casting parameters like strand cooling, soft reduction or electromagnetic stirring. The accuracy of the new method was proven by parallel metallographic investigations of more than 100 samples of different steel grades and sample shapes. Automatic defect evaluation and classification was compared against macroetching results. It was found that HD scan identified more defects and the visualization of the macro structure could be performed in more cases than with macro etching. All tests, comparisons, further developments and analyses for various steel producers and steel treatment companies have been conducted at the HD scan unit, located at the SMS group headquarters in Düsseldorf, Germany (Figure 1). Based on the results, SMS group has designed a unit which can be used in industrial scale.

Aug 17, 2017

By J. H. Fowler

Canada's gypsum industry began over two hundred years ago in the Maritime Provinces when farmers attempted to supplement their incomes by selling "land plaster" to traders bound for the United States. Rising from such humble beginnings, gypsum now contributes significantly to the economies of nine of Canada's ten provinces. Thirteen open-pit and three underground mines produced a total of 8.38 million tonnes of crude gypsum and seventeen processing plants manufactured 2.49 million tonnes of finished products in 1985. Recent economic growth in North America has resulted in steady increases in gypsum production, however, competition from foreign producers and by-product gypsum poses a growing threat to Canada's gypsum mining industry.

Jan 1, 1987

By A. W. Hesse

VENTILATION of all types of coal mines is fundamentally the same, in that sufficient air must be provided to properly dilute and remove dangerous and obnoxious gases and leave the oxygen content of the air not under 19 per cent in all places where men and animals must work. Perhaps animals should not be mentioned, as the speed of mechanical loading leaves livestock behind and outmoded. Since this paper has to do with the influence of mechanical loading equipment on ventilation, the problems will be confined to the splits and the coal-producing places of the mine. The removal of coal dust from the air, or its rapid transmission to the return air courses; the possible increase in the liberation of gases by the multiplication of cuts in the coal made during one shift or multiple shifts; and the additional electrical equipment at the faces, are the factors that cause the added importance to good ventilation in the permissible equipment area of gassy bituminous coal mines. VENTILATION FOR MECHANICAL LOADING IN GASSY MINES In gassy mines, the air currents must be maintained across the faces in such a way as to prevent short cuts to the returns and leaving pockets in which accumulation of gas might occur. To do this, two or more doors are required on almost every entry containing a track to the face, so located that in no event will a trip of cars block open the doors and permit the air to by-pass some place or places on the air-approach side. This method frequently requires the use of unusual lengths of duplex cables to reach the mechanical equipment at the faces, particularly where the distances between parallel working places are 100 ft., as at the Nemacolin mine. Fig. I shows a pillar section being worked with mechanical loaders. This layout requires carrying the air in on the right and releasing it on the left, because the track clearance is on the right side and the line brattice is built on this side from the last crosscut to the face. Thus, the air travels to the face with greater velocity, and gives more assurance of sweeping out the gas that might be exuding from the crevices of the coal. All working places, in driving through solid coal, are thus treated alike. They are all potentially gassy and must be swept clear of whatever may contaminate the air. Once the air starts into the working section, it is not released until it does a good job. Of course the volume of air must be large enough not only to dilute the gases but to carry away explosive fumes and fine coal dust quickly. Mechanical loading entails cutting and drilling of the coal during the same working period as the loading when two-shift and three-shift operations are employed, and all three processes create finely pulverized coal, which in itself is hazardous if not controlled by some means. If the ventilation is inadequate and gas accumulates, and a spark from defective electrical

Jan 1, 1941

Mining steeply dipping coal seams is a difficult task. Prior to 1996, fully mechanized longwall mining methods along the seam strike direction were tried in China and other countries. Due to its larger coal reserve in steep seams, China made more, but still limited, progress on mining such seams than other major coal-mining countries. In the last two decades, accelerated research efforts have tried to improve the mining technology in steeply dipping coal seams. Based on this work, a dynamic model of a roof-support-floor (R-S-F) system under asymmetrical constraints in mining steep seams is established here, and a theory of strata control and hazard prevention is formed. The key technologies for mining steep coal seams include global and regional strata control methods in the longwall face; methods for the longwall face machines to sustain static and dynamic loads; and flexible protection technology. These theories and technologies have been successfully applied in China to the mining of steep coal seams of varying thickness and hardness, with hard and soft roof and floor, and with a high potential for spontaneous combustion. In recent years, the technology has been introduced to Russia, India, Uzbekistan and other countries where steep coal seams are mined.

Jan 1, 2013

By A. Ehsani

"Seas and oceans constitute about 70% of the earth’s surface. They contain an enormous stock of various mineral resources such as sedimentary (marine placers), massive sulfide ore deposits, manganese nodules and cobalt-rich ferromanganese crusts. Sea and ocean floor ore deposits could well contribute to the meeting of ever-rising demand for raw materials in the metal industry. In this regard, more research and development in science and technology appear to be required to ensure maximum benefit from the mineral resources of seas and oceans. Since the 1960s, a variety of mineral and metallurgical processes have been studied and developed to deal with marine ores and to extract metals such as gold, nickel, copper, cobalt, manganese, tin, platinum group metals (PGM), zirconium, thorium, etc.In marine environments, there are many parameters which can affect the selection of the mineral and metallurgical processes. These include the extent and grade of the deposit, mineralogical and chemical properties of the deposit, and physical properties of minerals present with particular reference to particle size distribution and mineral liberation size.In this paper, we briefly review the latest trends in processing and extraction of marine mineral resources. Mineral processing technology is mostly applied for recovery of precious metals i.e. gold and PGM, in particular, from marine placers. In general, pre-treatment (sizing, classification, dewatering), gravity concentration techniques (shaking tables, spirals, jigs, etc.,), flotation, magnetic, and electrostatic separation are the options for enrichment of marine placer ore deposits. In the case of massive sulfides, manganese nodules/cobalt-rich crusts, hydrometallurgical and pyrometallurgical methods (as proven technological methods) can be exploited for extraction of metals from concentrates after physical separation or directly from marine ores. The hydrometallurgical treatments involve acid (e.g., sulfurichydrochloric) and alkaline (e.g., ammonia) leaching with different reducing agents and pre-treatments such as roasting. Alternatively, pyrometallurgical treatments involve mostly smelting, chlorination and segregation processes."

Jan 1, 2016

By T. H. Aldrich

(Chattanooga Meeting, October, 1908.) Tars paper is intended only to give a preliminary account of experiments made, and conclusions reached, concerning the treatment of certain refractory low-grade gold-ores, the profitable reduction of which may furnish a useful guide to the solution of similar mining and metallurgical problems, not only in the gold-bearing belt of the Southern United States, but perhaps in other regions also. It must be regarded as simply a ?report of progress," preceding a more elaborate and conclusive report of regular practice. The mines of the Hillabee Gold Mining Co. are located upon what is generally known locally as Hog Mountain, on the northern edge of Tallapoosa county, Ala., about 15 miles from Goodwater and 14 miles from Alexander City, stations on the Central of Georgia Railway. Gold has been known since 1839 to exist on this property, where it was discovered in that year by a man named Johnston. The property was worked for placer-gold by the old miners, and there are now the remains of four attempts to operate it by stamp-mill and plate-amalgamation. The present owners purchased it in 1896, and since that time they have experimented at frequent intervals, in order to devise a process that would satisfactorily recover the gold. In 1903 regular operations were begun. Geologically, the mountain consists of an intrusion of what has been pronounced true granite in altered sedimentary slates. The cooling of the granite produced shrinkage-cracks, which have become veins. There is considerable question as to the period of the slate formation; but it is undoubtedly, in my opinion, of Carboniferous age. The veins, about 50 in number, strike N. 60° to 80° E.; dip approximately 65° from the horizontal; vary from a few inches to 25 ft. (being in gen-

Nov 1, 1908

THE alkaline method for the estimation of zinc cannot, in the writer's opinion, be relied. upon to within very narrow limits between two assayers on unknown quantities of zinc. The end point is not decisive enough, and allows the personal factor toenter largely into the assay. The following investigation was undertaken to see how accurate the acid method is on Broken Hill concentrates and ores, and what should be the limit between the results of two assayers. The method adopted is as follows:Weigh sufficient amount of ore to give titration (between 20 and 50 cc.), place in tall 400 cc. beaker, cover, add 7 cc. nitric acid and heat till brown fumes cease to be evolved. Wash dock glass into assay, add potassium chlorate, evaporate to dryness on a slow fire with the beaker uncovered. When no smell of chlorine or nitric acid is observed, remove and cool. Add 100 cc. boiling water, then 7 grm. ammonium chloride, W cc. ammonia (.880 sp. gr.), boil for five minutes, filter, wash...

Jan 1, 1911

By Miguel Ângelo Menezes, Carlos Alberto Alves Viana

O presente trabalho possibilita o entendimento e a análise dos processos de conformação a quente dos metais. Isto, pela validação experimental do modelo de Johnson-Cook, para descrever o comportamento dos materiais no regime plástico, para grandes deformações, às altas taxas de deformações e nas altas temperaturas. Um entendimento dos parâmetros do modelo, utilizando-se um método analítico numérico simples, rápido e confiável foi desenvolvido anteriormente pela linha de pesquisa em Conformação Plástica dos Metais na UNESP – Campus de Ilha Solteira, obtendo-se as constantes empíricas do modelo referido. É proposto nesse trabalho a validação experimental do método simplificado para determinação dos parâmetros empíricos do modelo de Johnson-Cook através de um ensaio de tração a quente, considerando as propriedades mecânicas dos materiais analisados experimentalmente e/ou de dados de materiais disponíveis na literatura. De maneira geral, os resultados experimentais foram satisfatórios para o aço AISI 1045 à temperatura de 500 ºC, ensaiado à taxa de deformação de 1000 s-1, quando comparados aos resultados teóricos previstos pelo modelo proposto por SCADUTO e MENEZES. Particularmente, foi possível evidenciar erros máximos de 1,33% para o parâmetro n, 13,15% para o parâmetro B, 295,00% para o parâmetro C e 4,14% para o parâmetro m.

Nov 11, 2019

By Yunhua Gan, Xiaowen Chen, Meilong Hu, Haige Li, Yang Tong

Ethanol is a kind of renewable fuel, which can be produced from biomass and applied in many energy areas, such as motorcar. The combustion of ethanol in meso-scale is facing great challenges, such as great heat loss, poor stability, and low combustion efficiency. Electro-spraying technique is an effective method to atomize liquid ethanol due to its great advantage of monodisperse and uniform characteristics. In present study, electro-spraying was applied in liquid meso-scale combustor to produce very small droplet diameter and uniform droplet distribution. Experiments were carried out based on nozzle-ring-mesh electrode structure using pure liquid ethanol as fuel. Electro-spraying characteristics were measured by Phase Doppler Anemometer (PDA) under different nozzle voltages, ring electrode voltages, flow rates, and steel mesh positions. The results may be helpful to the design of new meso-scale electro-spraying combustor using renewable liquid fuel.

Mar 1, 2017

By Charles D. Litton

Introduction The successful performance of a mine-wide fire detection system depends upon its ability to detect the presence of a fire rapidly and reliably. It should be sufficiently rapid so that there remains enough time to either safely evacuate a mine or successfully extinguish and control the fire or both. It should be reliable so that false alarms are minimized without sacrificing sensitivity or time response. Systems should also be durable enough to withstand the mine environment over long periods of time while maintaining a high degree of re1iability. Maintenance and calibration of the system should be simp1 e and not require the expenditure of excessive time and manpower to keep it operational. Sensitivity, reliability, and durability of mine fire sensors and their electronic support systems have been the subject of significant Bureau research within recent years. The bulk of this type of information, along with the reports from which the remainder of this paper is derived, can be found in the Bibliography. It suffices to say that there exist commercially available systems for use in mines. This paper addresses a strategy for the use of such sensors and systems. Many factors influence the design of a mine-wide fire detection system, such as the potential sources and modes of ignition, the types of combustibles involved and the quantities avai1able for fire growth and flame spread. Mine air ventilation influences the growth and spread of a fire and also serves to transport the products-of-combustion to other areas of a mine remote from the fire. Fire sensor alarm thresholds place limits on the sizes of fires that can be detected. The time to respond to a detected fire, either in terms of evacuation or control and extinguishment, place additional time constraints on the design of fire detection systems. These factors interact with each other, often in complex ways, and it is the definition and understanding of these factors and their interactions that hold the key to the design of adequate and re1iable fire detection systems. Our level of understanding of the problem has increased dramatically within recent years and it is the intent of this paper to discuss the progress that has been made and how the information can best be used to improve the level of fire detection in underground mines.

Jan 1, 1986

By R. J. Wysor

MORE than two years ago, in making efficiency tests on our hot-blast stoves, I was surprised to discover a marked difference in temperature as indicated by a pyrometer inserted near a stove on blast, and the regular recording instrument situated near the bustle pipe. A special hole was then provided at the junction of the hot-blast main and the bustle pipe, and portable pyrometers with bare fire ends were used, both at this point and in the stove necks. I had occasion to make a number of such tests on various stoves on the same furnace, the difference in temperature as shown by the two pyrometers varying chiefly with the temperature of the blast, and the distance of the stove from the furnace. However, this difference was always great, often averaging above 100° F., for the entire period of a stove on blast. Later, experiments were made with similar results on another group of stoves. The pyrometers used were properly standardized and checked against each other before and after each test. However, there was still a slight doubt as to the accuracy of the results obtained, as subsequently explained. But I have obtained corroboration of the magnitude of heat losses from blast-furnace hot-blast mains from two independent sources. I have learned from H. A. Brassert, Superintendent of Blast Furnaces, South Works, Illinois Steel Co., that he has recently clone some experimental work similar to my own, and found temperature drops of the same order of magnitude. Also, C. R.. Lyle, of the Armstrong Cork Co., has made some interesting theoretical calculations, based oil the thermal conductivity of fire brick, for the particular conditions of several of our tests; and his theoretical interpolations, all facts being considered, check our actual observations fairly well. I understand that Mr. Lyle expects to publish the results of his investigations.

Jan 10, 1915

By G. L. F. Powell, L. M. Hogan

Samples of silver and Ag-O alloy, 0.12 wl pet, have been undercooled to a maximum of 250°C by melting in a slag of commercial soda-lime glass. Grain refinement occurred in undercooled silver samples whet the degree of undercooling exceeded a critical value which varied from 153° to 175°C, depending on the melting conditions. In under cooled Ag-0 samples, the grain structure was fine and equiaxed at degrees of undercooling larger than 50oC. The grain refinement in both silver and Ag-0 alloy samples was the result of recrystallization during or immediately following freezing. When the oxygen content was increased, the degree of undercooling at which recrys-tallization occurred decreased. INVESTIGATIONS of the grain structure of strongly undercooled melts of nickel and cobalt1-4 have revealed a change in room-temperature grain size as a function of undercooling. At large degrees of undercooling the grain size was fine, but samples undercooled by smaller amounts exhibited a much coarser grain structure. The reported undercooling at which this grain size transition occurred in nickel varied between 140° and 175'C undercooling. Walker1 attributed this grain size change to an enhanced nuclea-tion rate. Cavitation at a melt-solid interface was con sidered to generate a high-pressure wave. This, in turn, produced nucleation in the liquid as a result of an elevated freezing point increasing the undercooling in the melt. A similar grain size transition was observed in undercooled silver between 133° and 153°C undercooling.5 The grain size transition in undercooled silver was found to be dependent on oxygen con tent. More recently, the authors5 showed that a simila transition occurred in an undercooled Cu-O alloy, =0.08 pet, but not in oxygen-free copper undercooled more than 200°C. The transition was attributed to recrystallization of the solidified grains after freezing; the greater the degree of undercooling, the more complete the recrystallization. In view of this effect of oxygen content on grain size transition, additional undercooling experiments were carried out with silver. This paper reports the results of these studies on silver and Ag-O alloys undercooled more than 50°C EXPERIMENTAL 1) Materials. The silver was supplied by Matthey Garrett Pty., Ltd., as fine granulate, silver mini' mum 99.9 pet, and contained the trace impurities shown in Table I. The silver originated from two different refineries resulting in the difference in impurity content shown in Table I. However, the variation in composition had no discernible effect on the undercooling behavior. Samples of the silver were melted in an open-ended, vertical, cylindrical resistance furnace, wound with Kantha] wire, the temperature of which was adjusted by means of a variable transformer, 2) Melting and Undercooling. Bulk samples of silver were undercooled by preoxidation and removal of oxidized impurities in a glass slag, as previously described,5 but special precautions were necessary to allow comparison between oxygen-free silver and a Ag-O alloy. Samples free of oxygen were prepared by first melting weights of granulate varying from 200 to 400 g in clean vitreous silica crucibles in air for approximately 15 min. A sample was frozen and a complete glass cover formed over the top surface by adding granulated glass rod. The sample was then melted and frozen several times until no oxygen bubbles appeared in the glass slag. Subsequent thermal analysis indicated that the oxygen content was negligible. The glass acted as an efficient barrier to absorption of oxygen from the air. Ag-O alloys were prepared by melting silver in silica crucibles with only a partial cover of glass, so that the top surface of the melt was in contact with air. The silver was held molten in air for several hours at 1000° to 1050°C, in the expectation that the oxygen in solution would reach equilibrium with atmospheric oxygen. At T - 1000°C the equilibrium oxygen content was calculated as 0.12 wt pet O, using Sieverts law and Eq, [l], derived by Mizikar et a!.7 from the data of Sieverts and Hagenacker8 for 1 atm of oxygen:

Jan 1, 1970