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By G. R. Fitterer

Trends in slag composition in acid open hearth practice, particularly the variation in iron and manganese oxides during refining, are reviewed. A procedure which is currently being used to control the refining reactions is described and partially explained through slag phase diagram considerations. In addition, the ionic nature of these slags is considered and it is proposed that silica combines with the oxide ion and forms a series of complex silicate ions. The effect of basic oxides such as FeO, MnO, and CaO is apparently additive in furnishing the oxide ion for this purpose. IT is now possible to control192 the refining of steel in an acid open hearth furnace to a surprising degree. This control has been brought about through the knowledge and use of several facts and tests. These are: 1—A planned charge analysis based on a knowledge of the type of fuel, the bath depth, etc. 2—Knowledge and control of rate of fuel input as well as its method of atomization, if any. 3—Determination of the slag fluidity. 4—Bath temperatures (use of the Pt-Pt-Rh thermocouple). 5—Periodic determination of carbon content (use of the Carb-analyzer or Carbometer). Through the use of these control methods, a heat may be made to "melt-in" with or without residual manganese and silicon. The rate of refining or carbon elimination may be controlled accurately, and the desired tapping (or "go-ahead") carbon may be approached at a rapid or slow rate according to preference and type of steel being made. Thus operating time may be predetermined and greatly reduced. Further, all of the refining can be done without any ore or other oxidizing additions, and the heat may be brought to the desired tapping temperature simultaneously with the attainment of the desired carbon analysis. This control procedure is being used in most acid plants in the United States today and has been de- scribed.', ' Although the slag metal relations are sufficiently well known to control the heat as stated, yet it is possible to account for only about two-thirds' of the 0, which must have been used for the elimination of the carbon and other metalloids. Phase diagram studies' of the slags, slag weights, the metal particle theory,' ore additions, limestone additions, etc., may all be taken into consideration; yet, the mechanism of oxidation and source of all the oxygen remain to be explained. This paper reviews some of the principles upon which the control methods were based and proposes other possibilities regarding the unexplained phenomena. Old and New Acid Open Hearth Practice Some of the recent statements in the literature regarding acid open hearth operation are based on old heat data which are not typical of modern American practice. These old heat logs have been responsible for many misconceptions regarding the acid hearth practice and represent heats which do not coincide with modern methods. In recent years, American practice has been altered materially and these changes will be briefly described. Modern American Practice: A typical log of a modern American acid open hearth heat' is shown in Fig. 1 which indicates that the refining time was only two hours, during which the carbon was eliminated rapidly and the bath temperature increased at a fast rate. The manganese and silicon contents of the metal were essentially eliminated and their oxides had become constituent parts of the slag at the "melt-down" period. During the course of the heat, the MnO content of the slag remained practi-

Jan 1, 1954

By R. Moldenke

The presence of nickel-chromium in pig iron made fro111 Cuban oles is so well known that the word "Mayari" is unconsciously associated with it. Since 1904, when exploration of the Mayari deposits of iron ore in northeastern Cuba was undertaken, there llas been increasing interest in these ores. Tlie Transactions contain numerous references to t1ieln.l This iron ore, which is shipped to the Tinited States in the nodulizecl state, has been thoroughly tested and found very valuable; the deposit covers over 25,000 acres and there is in sight over 500,000,000 tons of ore that, by systematic mining, runs practically constant in composition. With nickel and chromium present, also titanium in sufficient quantities to attract attention, as well as extremely low phosphorus and sulfur contents, the iron founder is naturally interested in the utilization of RInpari ore for pig iron for the better grades of finishrtl iron products. The present point of coilsn~iil)tion ol ILlapri ore is at Sparrow's Poi111, where hlayari pig iron of ally desiretl coml>osition is made. The composition of the dried ore is about as follows: Iron -29 per cent., silica 3 pc.r cent., nickel 1 per cciit., chroiniun~ 1.5 per cent., alumina 11 per cent., ant1 coinbined water 13 per cent. When nodulized, the iron runs up to nearly 56 per cent., the silic:~, :tlumi~i:i, nickel, and c~llromiurn are slightly highr than the arno~l~its just given. Practically all the, combined wntcr is driven off aild the iiodulizccl ore carries only a few- tenths per cent. of 1 C. M. Weld: Residual Rrolvn Iron Ores of Cuba. Tmns, (1909) 40, 299. C. K. Leitll nnd If'. J. Mcncl: Origin of Iron Ores of Central and Northeostr~n rlbn. Trans (1911) 42, 00. C. W. Hayes: May:~ri and Mos Iron-ore Deposits in Cuba. Idem, 109. J. E. Little: Maynri lron Mincs, as Developed by the Spanish-American Iron ('0. Idem, 152. J. F. Iie~np: M'ryari Iron-ore Dcposi(s. Trans. (1915) 61, 3. C. K. Leith 2nd N. J. Mead: Additional Data on Origin of Lateritic Iron 01cs or Eastern Cubn. Tmns. (1916) 63, 75.

Jan 1, 1923

By R. Moldenke

The presence of nickel-chromium in pig iron made fro111 Cuban oles is so well known that the word "Mayari" is unconsciously associated with it. Since 1904, when exploration of the Mayari deposits of iron ore in northeastern Cuba was undertaken, there llas been increasing interest in these ores. Tlie Transactions contain numerous references to t1ieln.l This iron ore, which is shipped to the Tinited States in the nodulizecl state, has been thoroughly tested and found very valuable; the deposit covers over 25,000 acres and there is in sight over 500,000,000 tons of ore that, by systematic mining, runs practically constant in composition. With nickel and chromium present, also titanium in sufficient quantities to attract attention, as well as extremely low phosphorus and sulfur contents, the iron founder is naturally interested in the utilization of RInpari ore for pig iron for the better grades of finishrtl iron products. The present point of coilsn~iil)tion ol ILlapri ore is at Sparrow's Poi111, where hlayari pig iron of ally desiretl coml>osition is made. The composition of the dried ore is about as follows: Iron -29 per cent., silica 3 pc.r cent., nickel 1 per cciit., chroiniun~ 1.5 per cent., alumina 11 per cent., ant1 coinbined water 13 per cent. When nodulized, the iron runs up to nearly 56 per cent., the silic:~, :tlumi~i:i, nickel, and c~llromiurn are slightly highr than the arno~l~its just given. Practically all the, combined wntcr is driven off aild the iiodulizccl ore carries only a few- tenths per cent. of 1 C. M. Weld: Residual Rrolvn Iron Ores of Cuba. Tmns, (1909) 40, 299. C. K. Leitll nnd If'. J. Mcncl: Origin of Iron Ores of Central and Northeostr~n rlbn. Trans (1911) 42, 00. C. W. Hayes: May:~ri and Mos Iron-ore Deposits in Cuba. Idem, 109. J. E. Little: Maynri lron Mincs, as Developed by the Spanish-American Iron ('0. Idem, 152. J. F. Iie~np: M'ryari Iron-ore Dcposi(s. Trans. (1915) 61, 3. C. K. Leith 2nd N. J. Mead: Additional Data on Origin of Lateritic Iron 01cs or Eastern Cubn. Tmns. (1916) 63, 75.

Jan 1, 1923

By Josh Calnan, Paul M. Holmgren, Abigail N. Styer

Detonating cord is a staple of the explosives industry, used widely in the civil and defense industries. Detonating cord is a thin, flexible plastic tube filled with pentaerythritol tetranitrate (PETN). It has many applications in mining, construction and military disciplines. For civil applications, it is used to connect and initiate a series of blastholes in a desired pattern. In the defense sector, it can be used as a detonating agent, a priming agent or alone as an explosive charge. Research has been done to understand the initiation and detonation physics on the detonating cord. However, its sympathetic detonation characteristics needed to be further analyzed.

Feb 1, 2020

As Coal Mining Areas develop, problems relating to strata control increase. The "easy" coal has been extracted and the future development lies in the direction of greater depths of cover and more difficult strata conditions. To provide solutions to the problems encountered the techniques of constructing and testing physical models have been developed and refined. With a sound knowledge of model theory allied to practical experience, mining research engineers use physical cemented material models to examine, assess and solve mining problems relateu to strata behaviour and environment. For a model to provide the answer to a particular mining problem it is essential that as much information as possible be obtained from the mine or area of a mine which the model is to represent. Details relating to the strata, geological malformations, and the stress environment must be collected and collated to ensure reliable results.

Jan 1, 1976

By V Mutton, L Potts, D Joyce

This paper describes the method of extracting sill pillars within the underground operation from under unconsolidated mullock fill at the Cracow Gold Mine. This pillar recovery method was initially successfully used to recover sill pillars at Crusader Mine, Western Australia in 2001. Globally significant resources have been sterilised due to the placement of loose rock fill above crown pillars and within adjacent stopes. The method described here offers significant opportunities to increase recovery of sill pillar recoveries.The royal orebody sill pillars at Cracow Gold Mine form a significant resource. Extraction of these pillars needed to be undertaken with minimal ore dilution and maximum ore recovery. The application that was selected to consolidate the loose mullock fill above each pillar used an injection grouting process (Minova FB200).Cracow Gold Mine mining method is bottom up bench mining. The pillars were left within the orebody to allow for stoping to commence whilst the decline was being developed. Due to the remainder of the orebody being extracted the only access to consolidate the backfill was from the sill pillar extraction level. Numerous problems were encountered and overcome from product selection and trial, system of injection to extraction.This pillar recovery process achieved a 95 per cent recovery of the sill pillar compared with an estimated 60 per cent typical for other mining options.CITATION:Potts, L, Mutton, V and Joyce, D, 2012. Pillar recovery at Cracow gold mine using grouted consolidated mullock, in Proceedings Narrow Vein Mining 2012 , pp 179-184 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

By Michael Drozd

"The operation of an activated charcoal system has five separate unit operations. These unit operations have common points for CIP, CIL and CIS system, which vary widely in application.The unit operations are:a. Absorptionb. Desorption (Stripping)c. Acid Washingd. Reactivatione. Carbon Handling (carbon transportation, sizing, dewatering, etc.)Cost optimization starts with the basic operating parameters (design philosophy) set down at the time of engineering design. These parameters undergo almost immediate change due to site specific ore requirements, throughput changes, operator requirements or reagent availability.Activated charcoal is sometimes viewed as simple, uncomplicated reagent that requires not optimization. To some extent, this statement is true, but under most circumstances, if the time necessary to optimize the use of activated charcoal is available, the effort is rewarded with significant savings. CPL-Carbon Link has embarked upon a program of supplying technical support with its activated charcoal. Several operations in the United States have undertaken to have CPL-Carbon Link do an operational survey to determine if potential savings are possible. CPL-Carbon Link has offered to do these surveys for projects that are clients or simply would like to have CPL-Carbon Link review their operation. The information accumulated by CPLCarbon Link is being used to attempt to fashion industry standards so that a common reference point can be established for activated charcoal usage."

Jan 1, 2008

By G. Tranell, L. Kolbeinsen, S. Gaal, J. Safarian

The effect of carbon material properties on the rate of MnO reduction from ferromanganese slag by solid graphite was investigated. A sessile drop technique was used to study the reduction rate of a synthetic slag containing 45 wt% MnO at 1500 and 1600 ºC. Different types of graphite substrates were used and the con-tact angle between slag droplets and substrate were measured in-situ. Moreover, the slag droplet volume during the interaction with the graphite substrates was calculated and normalised. The mathematical relationship between the slag density during the reduction and the normalised slag droplet volumes during the reduction were derived and the MnO reduction curves were then calculated. A method for measuring the slag reactivity of solid carbon was defined and used to qualify the propensity of the different graphites to react with the liquid slag. Some supplementary studies such as manganese evaporation measurement and EPMA analysis for determining the extent of MnO reduction were also carried out. It was observed that there is nota significant difference in the wetting angle of the graphite substrates by the slag, and the wetting is not changed within the temperature range of 1500-1600ºC. However, the changes in the contact angle during the slag reduction at 1600ºC are more than at 1500ºC. The kinetics of MnO reduction is dependent on the type of graphite and it is more dependent on the graphite properties at lower temperatures. On the other hand, the dominant properties of graphite on the reduction rate vary with temperature. A multivariate analysis on the graphite properties and the parameters related to the slag reactivity indicated that the kinetics of MnO reduction is mainly dependent on the temperature, and then on the graphite properties. It was also found that at1500 ºC the surface area and the CO2 reactivity are the most important graphite properties for the slag reduction, suggesting that the reactivity of carbon is rate controlling at 1500 ºC. However, the porosity related parameters are the most important graphite properties at 1600 ºC, suggesting that CO gas desorption is rate controlling at high temperatures.

Jan 1, 2007

By T Kitajima, T Kawaguchi, T Nakamura

Carbothermic reduction of iron oxide is an attractive mechanism to produce metallic iron, since it can directly utilise coal as both reductant and fuel. To improve energy efficiency and productivity of the metallic iron production based on this mechanism, the combustion bed process packed with the composites of iron oxide and coal powder was experimentally evaluated. The process has a potential of high heat efficiency since it can automatically utilise the heat of reduced materials as that necessary to the subsequent reduction of the composite by a large heat exchange rate between the packed particles and gas flowed across the bed. However, it is hard to perfectly prevent the reoxidation of formed metallic iron in the bed. The present paper reports the effect of coal content, pellet size and so forth on the reduction/metallisation degrees of the samples after the reduction experiment. It also discusses the effect of pretreatment of the composite pellets using CaO bearing materials to suppress the reoxidation of formed metallic iron in the bed.

Jan 1, 2000

By J. B. Cheatham, J. G. Yarbrough

Although adequate removal of cuttings from beneath a drill bit is important for efficient drilling operations, very little basic data are available relative to the fundamentals of chip removal by hydraulic jets. A discussion is presented in this paper of an experimental investigation of the jetting action of hydraulic jets in removing loose particles from the bottom of a cylindrical hole. Conditions for which the jet is no longer capable of removing chips from the bottom of the hole are determined. This situation represents equilibrium between the chip removal force and chip Bolddown forces such as gravity and pressure. In most of the tests loose particles were jetted with water or a water-glycerine mixture to determine the dependence of chip removal on hole size, jet size, height of jet off bottom of hole, flow rate, particle density and fluid viscosity. ,A test with a pressurized mud system indicated that relatively low pressures can completely overcome the removal action of a hydraulic jet. Although the system studied herein is not directly applicable to a rotary drill bit, the work with such simplified systems can provide a better understanding of the chip removal action of jets, and with logical extensions it may provide a reasonable basis for the best use of fluid jets in drilling. INTRODUCTION The primary deterrent to maximum drilling rates is the inability of the drilling system to remove rock cuttings efficiently enough to prevent interference with the drilling action.1-2 The objective of chip removal studies is to permit predicting and controlling removal forces under downhole drilling conditions. Conditions at the bottom of a hole during rotary drilling are exceedingly complex and are not likely to be described in a quantitative way by investigations in terms of the total drilling action until a better understanding is developed of the simplified components of the problem.3 The present study is concerned with the elementary condition of removal of chips by a single central jet. Even this relatively simple model provides mathematical difficulties because of the turbulent nature of the flow from the jet and because of the shape of the bottom of the hole beneath the jet. Theoretical and experimental studies have been made of turbulent jets impinging normally on an infinite body and deductions based on analytical solutions to simplified problems can give some insight into the problem of cutting removal by a jet. However, because of the present lack of understanding of the behavior of the interaction between the fluid jet and the chips being removed, an experimental approach was chosen for the present study. Methods have been developed for maximizing hydraulic horsepower, impact force and jet velocity; but whether maximizing these parameters maximizes chip removal with present drilling bits has not been demonstrated. Simplifying the problem of chip removal may make it possible to develop some understanding of the manner in which the jet velocity is dissipated. Better understanding of a simple case should materially assist in extending analysis to more complicated cases. Thus, we are not concerned in the present study with the rock fracturing process itself but only with the removal of the debris from the bottom of the hole. A problem which is quite similar to the chip removal problem is the suspension of solids in stirred vessels. This problem has been studied by the chemical industry and correlations have been obtained by dimensional analysis which permit the design of mixing vats7 An approach similar to that used in the mixing vat problem is used in the analysis of the jetting data in the present paper. EXPERIMENTAL PROCEDURE The test equipment arrangement shown sche-matically in Fig. 1 allows the jetting action to remove particles until an equilibrium height is attained for each combination of hole size, jet size and flow rate.*** Equilibrium conditions require that the removal force is unable to remove additional particles. This balance between holddown and removal forces implies a relationship between the two forces which is constant for the particular system. When the holddown forces are constant,

Jan 1, 1965

In the last four years, 2007~2010, 9 out of 24 metal/nonmetal underground mine fatalities were caused by ground fall across United States of America (Mine Safety & Health Administration, MSHA). To reduce or eliminate incidents/accidents caused by ground fall, this paper clarified how to design and select ground support based on different ground conditions, how to use mine ground support standards, what geotechnical engineers and underground operators should do to keep mine production free of ground failures.

Jan 1, 2012

By Tian Sugui

By direct aging treated, creep properties measurement and microstructure observation, the influences of the direct aging treatment on the creep behaviors of Hot Continuous Rolled GH4169 superalloy are investigated. Results show that the creep resistance of Hot Continuous Rolled GH4169 superalloy may be obviously improved by directly aged treatment. Under the applied stress of 700MPa at 660, the creep lifetime of the alloy is enhanced to 126h from 60h. During hot continuous rolling, the deformation features of the alloy are the twinning and the double orientations slipping of the dislocation activated within the twinning regions. After direct aging treated, the alloy displays a smaller grain size, and the finer g² phase is dispersedly precipitated in the matrix of the alloy, which is thought to be a main reason of enhancing creep lifetime of the alloy.

Jan 1, 2010

By Roger T. Laine

"The Carswell structure, located in the western part of the Athabasca Basin, northern Saskatchewan, has been extensively explored since 1967. This exploration has been successful and lead to the discovery, in 1970, of the D sandstone-hosted unconformity related deposit. By the end of 1984, five additional basement-hosted unconformity related deposits had been delineated: the OP and N discovered in 1970, the Claude in 1971, the Dominique-Peter in 1981, and the Dominique-Janine in 1984. The D deposit has been mined out; the Claude open-pit has already produced more than 500 tonnes of uranium, the development of the Dominique-Peter underground mine (first phase) has been completed, and production from the latter started in 1985.All six deposits are located in the southern part of the Aphebian metamorphic core, 18 km in diameter, which has intruded at least 1250 metres of Helikian Athabasca Group sediments during a cryptoexplosion event at 480 Ma, unrelated to the emplacement of uranium mineralization. The metamorphic rocks, affected by the Hudsonian Orogeny, are divided in two lithostratrigraphic units: the Peter River gneiss, aluminous gneiss series, and the Earl River complex, mixed quartzofeldspathic and mafic gneiss series. A well developed regolith profile is recognizable in the south along the contact with the sandstone and inside the metamorphic core sometimes associated with conformable sandstone beds.Basement and sandstone-hosted uranium deposits show many similarities:-linkage to unconformity;-mineralogy and geochronology with a first phase mineralization characterized by a polymetallic sulphide-uraninite-brannerite assemblage dated at 1150 to 1050 Ma, a second phase characterized by a simple sulphide-uraninite assemblage dated at 890 to 820 Ma, and a third phase characterized by a pitchblende-hematite dated at 380 Ma; and,-linkage to early Hudsonian structures with remobilization of these structures during intense hydrothermal alteration resulting in Mg chlorite-illite halos."

Jan 1, 1986

By A. P. Paiva

Studies focused on the recovery of precious metals by solvent extraction have recently increased. either to devise suitable solvents or to clarify the involved extraction mechanisms and kinetics. In this work, a comparison of the performance exhibited by triphenylphosphine (TPP), bis-(penty1thio)-ethane (BPTE) and triisobutylphosphine sulfide CI"I'BPS) in the extraction of silver from acidic chloride media is carried out. Extraction and stripping isotherms involving the three extractants are presented together with the results obtained on the selectivity of silver extraction against high contents of iron, copper and lead. Attempts to clarify the mechanism of silver extraction by TIBPS were performed by studying the distribution coefficient dependence on ligand and chloride concentrations. The effect of temperature on extraction and stripping is also considered. The interfacial tension for the system, measured with different concentrations of extractant in the organic phase, is analysed.

Jan 1, 1994

By John R. Bartels

Jan 1, 2009

By R. J. Pruett

The Georgia kaolin district is the world’s largest producer of kaolin. Georgia production tripled from 2.87 Mt (3.17 million st) in 1968 to8.35 Mt (9.2 million st) in 1998. Development of the Georgia kaolin industry can be traced to the identification of the mineral resource, the adoption of innovative process technologies and the creation of markets for kaolin. Georgia kaolin is an abundant and high-quality resource that shows a range of advantageous properties. Technical developments in wet processing, delamination and calcination allowed production of high-value products. The use of kaolin pigments in the paper industry provided a market that absorbed the rapid growth in kaolin production.

Jan 1, 2000

By Ke Yang

In Chinese coal mines, extraction of deep, highly gassy soft coal seams sandwiched between soft floor and soft roof in complicated geology is commonly encountered. How to safely and efficiently excavate such seams is a very significant and important problem. It has been a focused research area in recent years. By combining the characteristics of fully mechanized longwall mining methods such as large cutting height and mining along the dip, an integrated method and technologies for the Zhangji Coal Mine were developed. This technology includes the design of a complicated geological exploration system, optimization of mining method and working face parameters, control of rock pressure and high levels of gas, reliability model of the production system, and selection and compatibility of equipment. Engineering practice shows that the integrated technology was successful in mining these complicated seams. This study not only enriches the mining method, but also improves the coal mining practice, especially ensuring both safety and productivity under complicated geological conditions.

Jan 1, 2009

By J. Marshall Rounsevell

It is probably not too far from the truth to say that the sulfur content of the steel bath at the first turndown of the basic oxygen furnace is influenced by every factor which varies in the operation of a BOF shop. However, the determination from normal shop operating data of the effect of a given factor on turndown sulfur content requires a means for collecting a large quantity of such data and a significant variation of the factor in question in that data. In this paper, operating data from 4000 heats collected on the computer at Inland's No. 4 BOF Shop is utilized to analyze the effect of four operating parameters -- hot metal sulfur content, hot metal manganese content, percent burnt dolomitic lime (dolomite) in the flux charge, and the presence or absence of transfer ladle slag skimming -- on first turndown sulfur content.

Jan 1, 1972

By C J. Hogan

Increasing demand for fine grinding to improve mineral liberation and metal recovery and the need for stricter control of the environmental impact of tailings deposition poses problems for tailings disposal. This has led to an increasing number of investigations of properties of tailings and their disposal. This paper describes laboratory model testing undertaken on Macraes mine flotation tailings to provide information on tailings behaviour under conditions of subaerial deposition. The in-place density or 'dry density' of the impounded tailings and the impoundment depth relationship are important for utilisation of the available impoundment storage facility and results of dry density to depth relationships are given for the Macraes mine tailings impoundment.

Jan 1, 1993

By Peter N. Yanker

The two types of dryers used in the drying of copper concentrates are the rotary dryer and the spray dryer. The rotary dryer has until recent history been the traditional drying method used, Although spray dryers have been used in the chemical field for many years it is only recently that they have been accepted for drying of copper concentrates. The comparison made here will apply in a narrower sense to the drying of copper concentrates as fed into the reverbatory furnaces of the Smelter. To compare a rotary dryer and a spray dryer, which are two totally different methods and pieces of equipment, it is best to view them as systems each made up of certain elements

Jan 1, 1976