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By D. J. Wall, T. D. Johnson, M. T. Parry, G. R. Heath

In coal-fired power stations coal is ground to a fine powder and then transported pneumatically at 25-30 m/s velocity to remote burners. Wear of the conveying pipework is a well recognised problem and traditional lining materials are Nihard and basalt. In many cases these are being replaced by alumina tiles in order to improve life and reduce the frequency of replacement. A programme of laboratory testing of candidate aluminas with AIO, contents between 85% and 99-5% has been undertaken and the results compared with field experience. This gives confidence in the erosion tests, which were designed to replicate most of the field conditions. However, it has not proved possible to draw correlations between the laboratory erosion rates and any of the materials’ bulk properties. SEM, TEM and microanalysis studies have therefore been made in order to look for microstructural aspects that could be influencing erosion rates and it has been shown that intercrystalline cohesion, the matrix phase and porosity appear to have most influence on wear performance. It is necessary to quantify these microstructural parameters if reliable erosion performance is to be obtained. This paper was read at the Institute of Ceramics Annual Convention at the University of Durham, April 1988.

Jun 12, 1905

By T. T. Campbell

Studies were conducted by the Bureau of Mines to develop a process for preparing thorium-magnesium master alloys or pure thorium metal by magnesium reduction of thorium tetrachloride in a semicontinuous reactor. Thorium tetrachloride was prepared in a fluidized-bed reactor by chlorination of thorium oxide or thorium oxalate. Conditions were established for producing a suitable thorium oxide feed for a fluidized-bed reactor. Thorium tetra-chloride was purified by vacuum sublimation and subsequently reduced by magnesium in a semicontinuous reactor to form thorium-magnesium alloys. Relatively pure thorium was produced by removing magnesium from the alloys by vacuum sublimation. Close to 100 percent of the thorium fed into the reactor was recovered either as metal (~93 percent) or as thorium oxide (~7 percent). The oxide can be recycled directly into the process.

Jan 1, 1971

By Larry A. Haas

The Bureau of Mines constructed a torsion effusion apparatus to measure the equilibrium vapor pressure of pure metals, alloys, and compounds at temperatures up to 1,500° K. The reliability of the apparatus was established by determining the vapor pressure of silver. The data obtained on solid and liquid silver in the temperature range 1,200° to 1,500° K can be expressed by the following equations:

Jan 1, 1965

By T Dawson, B Haskins

Fatigue is it the newest buzz word or is fatigue a real phenomenon that is creating safety and organisational risk for you? There is no debate that fatigue is natural, and it affects us all, just like gravity; however, there has been much debate on the severity of its impact in the workplace. For many years the impact was not measurable, hidden out of sight and, quite frankly, written off as the infamous ‘operator error’. Over the last several years, advancements in technology have provided safety and health professionals, sleep scientists, fatigue experts and organisations with the ability to monitor and detect fatigue events in real time, as well as predict and monitor increased risk for fatigue events. Caterpillar Safety Services has assembled an extensive and exceptional set of technologies that will provide the best methods and data to measure the impact of fatigue. This paper will discuss fatigue in the workplace and review the technologies and data sets available, which will allow the reader to determine whether this risk is real or rubbish.CITATION:Haskins, B and Dawson, T, 2017. Fatigue risk in your operations – real or rubbish? It actually depends , in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 137–142 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 16, 2017

By J. Álvarez, J. Mesías, C. O. Gómez

"Operations routinely run flotation tests in laboratory mechanical cells to determine adjustments to plant operation based on feed flotation response or the effect of new reagents and dosages. The metallurgical results of these tests are certainly affected by changes in bubble size, which simultaneously impact the recoveries of the collection and froth zones. It is known that bubble size depends on the characteristics and operation of the machine in use, particularly on the gas flow rate delivered to the unit and the selected frother type and dosage. Although flotation rate constants have been related to bubble size, bubble surface area flux seems to be a more fitting variable to correlate flotation kinetics and cell performance, as it integrates bubble size and superficial gas velocity effects. However, although some evidence has been provided, a categorical relationship between cell recovery and bubble surface area flux has not been established. Our interest is to demonstrate this relationship to use it as a basis for developing soft sensors to track on-line collection zone recovery in cells. Flotation tests were designed to produce Cu concentrates for a range of bubble surface area flux values, obtained through changes in frother concentration at a constant gas flow rate, and by increasing gas flow rate at the same frother concentration. The tests were run on samples prepared from an ore batch supplied by a local operation, following strict grinding and flotation procedures, with a shallow froth to approximate cell recovery to that in the collection zone. Bubble sizes were determined using the sampling-for-imaging technique developed at McGill. The results unequivocally showed a consistent positive correlation between cell recovery and bubble surface area flux, and significant variations in performance when frother addition and gas flow rate were changed.INTRODUCTIONMineral flotation is a separation process to produce concentrates of valuable minerals by selective attachment of particles to the surface of bubbles. The process is carried out in machines where air is injected through a mineral pulp to form bubbles, and operated to create two zones: a bottom one (collection zone) where bubbles are continuously generated under conditions adequate to form bubble-particle aggregates by collision of the rising bubbles with suspended particles; and a top one (froth zone) where bubbles and bubble-particle aggregates continue to rise while concentrating and forming a froth layer for water and entrained particles to drain back to the collection zone, before overflowing as a concentrate stream. The phenomena occurring in these zones are complex and, in many cases, interactive, as they simultaneously affect stages of the particle separation sequence occurring in both zones. Although there have been significant advances in instrumentation to characterize particle and bubble populations, these have not resulted in knowledge to explain or models to describe phenomena from fundamental principles. Measurements continue to be limited to the development of empirical models for predicting the effect of operating variables on performance."

Jan 1, 2016

By M Kilburn, A Edenton, M Adam, A Dehghan-Manshadi, R Smyth, L Lu

The blast furnace is a counter current reactor. The counter current principle of the furnace makes it very efficient in transferring the heat and mass required to drive the reduction reactions inside the furnace. However, this does impose a stringent requirement on the permeability of burden material in the furnace. Lump ore is one of the key ferrous feeds used in the blast furnace ironmaking process, often accounting for ten to 20 per cent of the blast furnace ferrous burden. As the lump ore descends through the blast furnace, it is dried, heated and reduced by the ascending hot reducing gas. To ensure good furnace permeability, generation of fines from burden materials including lump ore due to mechanical, thermal and chemical processes needs to be minimised. Unlike sinter and pellets, lump ore is subject to thermal degradation. To assess this behaviour of lump, the ISO decrepitation test (ISO 8371, 2007) is often conducted, and the result is calculated as a decrepitation index (DI). However, the DI values obtained from the existing ISO decrepitation test vary considerably between test portions and between laboratories, which makes meaningful comparison very difficult. In order to identify the sources responsible for the unacceptable repeatability, the effect of various testing conditions, such as particle size, heating rate, sample preparation and loading method, on the mean DI value was studied. The mechanisms contributing to thermal degradation in the top of the blast furnace and during the standardised decrepitation test are also discussed.CITATION:Lu, L, Kilburn, M, Dehghan-Manshadi, A, Adam, M, Edenton, A and Smyth, R, 2013. Thermal degradation of lump ore in the top shaft of blast furnaces, in Proceedings Iron Ore 2013 , pp 421-426 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By W. E. Crandall

The Star-Morning mine is a. 1000-ton-per-day lead-zinc producer located in the easterly part of the Coeur d'Alene Mining District of North Idaho. The property includes both the Star and Morning mines which are located on the westerly and easterly portions of the same complex of veins. The mine is 70% owned by the Bunker Hill Company (Gulf Resources, Inc.) of Kellogg, Idaho, 30% owned by Hecla Mining Company, and operated by Hecla Mining Company with head-quarters in Wallace, Idaho. One of the characteristics of mines in the Coeur d'Alene District is that many of the ore bodies extend to very great depths. The Star is no exception, but rather a leading example. The complex of near vertical veins and ore shoots extend some 7000 feet below the surface at present, with a maximum strike length of about 4000 feet. Ore has been mined on 20 separate veins and ore structures. More than 50 miles of headings have been driven and nearly 23 million tons of ore mined since the Morning mine started in.189S. The problems of mining at such depths are formidable temperature on the bottom level is 1100 F and high humidity problem. Pressure from the sheer weight of rock is as high foot. This paper will deal with providing a new access to the deeper levels of the mine and the installation of a hoist and related items to service these levels. By the time development had reached the 7100 level (Figure 1), it became apparent that a different 'hoisting system was going to be necessary if we were going to continue to mine at a profit. The main shaft extended to the 4000 level at which point a ?:3100"'foot winze shaft provided access to the 7100 level. The two hoists were limited to handling 3-ton payloads at 1200 to 1500 feet per minute. Some ores are still produced from above the 4000 level but as these ore reserves become depleted the hoisting of the desired tonnage (1000+/day-) from the lower levels of the mine would exceed the capacity of the existing hoisting system. A decision was made to sink a new vertical shaft at a point well in the south wall of the ore bodies where strong rocks and a minimum of faulting was expected and to purchase and install a new hoist capable of hoisting over 7000 feet. This new' shaft, designated as the No. 4 Shaft, was planned to reach 2000 feet below the 7100 level which was the deepest level at that time. The hoist would be in-stalled on the ,main 2000 Adit level which is used as an access and haulage level to the concentrator and surface plant in Burke.

Jan 1, 1971

By E. R. Smith

ANALYSIS of the requirements for gun perforation equipment suitable for penetrating casing and cement showed that these points would be involved: (1) Powder charges electrically detonated under high fluid lieads and at remote distances. (2) Selective firing of sliots in sequence. (3) Sufficient velocity for the bullet to penetrate at least two strings of seamless casing and all cement beyond the strings. (4) Heat-treatment of steels to withstand great pressures and penetration. (5) Esclusiorl of fluid under extremely high hydrostatic pressure. (6) Stranded steel wire line acting as weight - suspending and current - carrying medium. (7) Firing controls operated above the surface. (8) Determining gun depth and suspended weight by means of the wire line. (9) Portability for field use.

Jan 1, 1936

By Milton E. Wadsworth, R. Ted Wimber

Cobalt sulfate solutions containing ammonium acetate and chloroplatinic acid were reduced by hydrogen in a pyrex-glass lined autoclave in the temperature range of 170o to 232°C and hydrogen partial pressure range of 115 to 830 psia. The reduction rate was directly proportional to the hydrogen partial pressure and surface area of the pyrex glass and was independent of the quantity of chloroplatinic acid added initially. Experiments involving the variation of the relative concentration of ammonium acetate indicated that the reducible cobalt complex was probably the diacetate complex of cobalt, Co(AC)4H20, or a new mononcetate complex Co Ac, which was in solubility equilibrium with a pink precipitate of CO(AC)-4HzO. THE reaction in which a metal is dissolved by an acid to produce gaseous hydrogen and a salt solution was discovered early in the history of chemistry. In 1859 Beketoff found experimentally that this reaction could be reversed; i.e., a salt solution could be reduced by gaseous hydrogen to produce a metal and an acid. A review of work done on this phenomenon since that time may be found elsewhere., The hydrogen reduction of a cobalt salt solution is facilitated by complexing the cobalt ion. An ammonia complex of cobalt has been reduced commercially in the recovery of cobalt metal. A new reducible complex of cobalt was discovered5 when it was found that a co-baltous sulfate solution containing ammonium acetate could be reduced by hydrogen at temperatures in the region of 200°C. When a cobalt sulfate-ammonium acetate solution was heated to a temperature below its normal boiling point, a violet color became apparent, indicating complex formation. The nature of this complex was investigated5 by the addition of NH4Ac to a CoSO4 solution maintained at 85o. During the first additions of NH, Ac, the pH of the solution remained fairly constant at about 5.85. However, as the ratio of NH,Ac to CoSO, approached two, the pH rose and then leveled off at about 6.05. The absorption spectra of a Co(Ac), solution and a CoSO,, NH Ac solution were obtained at 85°C and were compared and found to be the same. These findings suggested that the diacetate complex of cobalt, Co(Ac),.4H20, was formed at 85°C. When a cobalt sulfate-ammonium acetate solution was heated to a temperature above about 165o, a finely divided pink precipitate appeared. The X-ray diffraction pattern of this precipitate indicated that it was Co(Ac), - 4H,O. In addition, it was discovered that when chloroplatinic acid, H,PtCl;, was added initially to the cobalt sulfate-ammonium acetate solution, a faster reduction was obtained. The roles of the solution complex, pink precipitate and chloroplatinic acid in the reduction process were then investigated. APPARATUS The experimental work was carried out in a two-liter stainless-steel autoclave. Adetailed description of the autoclave and the auxiliary equipment used in maintaining constant temperature and pressure may be found elsewhere.= Because the stainless steel was corroded, and also because it acted as a hydrogena-tion catalyst, an all-glass liner was fabricated such that the solution came only into contact with flame-polished pyrex glass. EXPERIMENTAL PROCEDURE The solutions used in the experimental work were prepared by dissolving reagent grade chemicals in distilled water. Although variation of the brand of ammonium acetate appeared to have no effect on the experimental results, CoSO, 7H O from the J. T. Baker Chemical Co. of Phillipsburg, N. J.,was found to give faster reductions than that prepared by Allied Chemical and Dye Corp., N. Y. The former was used throughout the course of the experimental work and was weighed up at the outset of each experiment. The ammonium acetate was dissolved to form a 6M stock solution, which was stored under refrigeration. A 10 pct solution of chloroplatinic acid (J. T. Baker Chemical Co.) was diluted to a 1.15 x 1Q2 M stock solution, which was standardized by precipitation of K,PtCl, as outlined by Scott. The appropriate volume of the chloroplatinic acid, H,PtCl,, solution was pipetted into the clean, dry glass liner. The cobalt sulfate-ammonium acetate solution, which had previously been saturated with

Jan 1, 1962

By Guilherme Guidugli

The hot blast stoves are a regenerative heat exchange system, accounting for 10 to 20% of the total energy requirement in an integrated steel plant, responsible for the supply of about one-third of the blast furnace heat input and responsible for a constant flow of hot air to the blast furnace, according to the required production. Because of their important role in the hot metal production, a stable operation and an appropriate combustion control is necessary. This paper aims to present the results of an investigation and modifications performed as an operating multi-furnace plant, as well as the parameters considered to ensure thermal equilibrium, improving in the stoves heating cycle.

Aug 16, 2017

By P. T. Bissert, T. J. Lutz, J. A. Yonkey, G. T. Homce

"The National Institute for Occupational Safety and Health (NIOSH) has been researching refuge alternatives (RAs) since 2007. Refuge alternatives typically have built-in pressure relief valves (PRVs) to prevent the unit from reaching unsafe pressures. The Mine Safety and Health Administration (MSHA) requires that the PRVs vent the chamber at a maximum pressure of 1.25 kPa (0.18 psi, 5.0 in. H2O), or as specified by the manufacturer. To facilitate PRV testing, an instrumented benchtop test fixture was developed using an off-the-shelf centrifugal blower and ductwork. Relief pressures and flow characteristics were measured for three units: a modified PVC check valve, an off-the-shelf brass/cast iron butterfly check valve, and a commercially available valve that was designed specifically for one manufacturer’s steel pre-fabricated RA and has been adapted for use in built-in-place (BIP) RAs located at one mine. PRVs used in tent style RAs were not investigated. The units were tested with different modifications and configurations in order to check compliance with 30 CFR regulations. BACKGROUND The Mine Improvement and New Emergency Response Act of 2006 (Miner Act) (1) was enacted in the wake of three mine explosions/fires that claimed 19 lives that year. Intended to help improve underground coal mine accident preparedness, the MINER Act includes provisions that target mine safety issues in areas such as emergency response planning, adoption of new technology, training and education, and mine safety standards enforcement. Section 13 of the MINER Act specifically directed the National Institute for Occupational Safety and Health (NIOSH) to provide for research into the effectiveness and viability of refuge alternatives (RAs) for underground coal mines, and the Department of Labor to act on the results of such research as appropriate. These mandates culminated in the 2009 adoption of changes to 30 CFR mining health and safety regulations, requiring underground coal mines to provide mine emergency RAs and associated components, to provide a life-sustaining environment for persons trapped underground. Such RAs can be either self-contained mobile units or built-in-place (BIP) facilities. The regulatory changes also include provisions establishing requirements for the Mine Safety and Health Administration (MSHA) approval of RAs and their components, and among these provisions are numerous criteria for providing a safe breathable atmosphere under positive pressure within the RAs. One specific criterion for maintaining a safe RA atmosphere requires the inclusion of an air pressure relief valve that will activate at a maximum of 1.25 kPa (specified as 0.18 psi, or approximately 5.0 in H2O), or at a pressure as specified by the RA manufacturer, above mine atmospheric pressure in the RA (2)."

Jan 1, 2016

By Sam S. Taylor

[The discovery of many oil fields in Illinois since 1936, and their rapid development have brought the problem of brine disposal to the foreground in that State. The ultimate magnitude of the problem is not yet known, but already it is treat enough to warrant technical investigation. The Bureau of Mines, therefore, has made a general survey of the methods of handling oil-field b brines in Illinois rend has studied in detail three subsurface disposal systems.]

Jan 1, 1940

By A Gray

Physical separation features in almost every mineral processing circuit. The category encompasses a broad range of techniques and technologies including hydrocyclones, gravity concentration methods (including jigs, spirals, centrifugal concentrators, tables, heavy media separators) and thickeners, all of which make use of the inherent density differences between two mediums. It is also possible to include flotation, magnetic separation, and ore sorting in the physical separation category.However, opportunities for enhanced physical separation performance can now go beyond the common practice of optimising unit operations. Improved options exist for feed preparation ahead of the physical separation stage, enabling higher performance and lower cost outcomes for physical separation flow sheets and technologies.The use of new applications in breakage technologies combined with mineral liberation analysis to optimise liberation prior to the physical separation stage provides options for preconcentration and gangue rejection as well as better separation efficiency. The use of low cost gangue rejection and preconcentration can be an intermediate step between mining and processing that allows processing of lower cut-off grades from the mine whilst delivering higher grades to the mill.Optimising flow sheets and technology performance requires detailed understanding of particle size and shape distributions as well as liberation characteristics to suit the particular separation unit, combined with knowledge of the available technologies, their capabilities and the economic impact across the whole mine cycle.CITATION:Gray, A, 2017. The role of liberation in physical separation techniques, in Proceedings MetPlant 2017, pp 147–156 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 11, 2017

By I. I. Beloglazov, G. A. Iusupov, A. Ju. Feoktistov

"The aim of this paper is to study the numerical modeling of the crushing process in a jaw crusher with complex motion jaws using Discrete Element Method (DEM). The main goals are to ensure the conformity of numerical simulation results to the experimental data, optimize the operating modes and the crusher design and develop automated verification and calibration methodology. It is offered to use automated selection of mathematical model parameters using large- or laboratory-scale experiments instead of deriving parameters from conventional intensive material tests (e.g. drop-weight test). Experimental data were obtained from a large-scale crusher designed and manufactured by the company “Mekhanobr-Tekhnika”. Both jaws have their drive shafts located asymmetrically; one jaw is driven in the upper part, the second at the base. The crushing process involves fragmentation of single smoothed rectangular granite particles of the same weight. During the experiment, the required parameters such as particle size distribution were obtained for further computer simulations. Based on the obtained experimental data, the Rocky DEM model was built. Simulation breakage parameters were calibrated using automated parameter selection methodology based on multiple set of parameter-controlled simulations. A good correlation of the experimental data and numerical simulation data was obtained. The methodology in combination with well-known capabilities of simulation modeling will help reduce the research time in the development of new mineral processing equipment.INTRODUCTION Preparation of rock mass for enrichment includes the power-consuming processes of crushing and grinding. Initial rock mass crushing is performed by means of drilling and blasting operations. To reduce the average size of a rock piece, primary crushers, mostly jaw crushers, are further applied. The advantages of the jaw crusher are simple design, easy maintenance and repair. One of the drawbacks is large oscillating masses and, thus, high power consumption during operation (55 - 200 kW). Jaw crushing simulation will help optimize the crushing process and improve further rock transportation and processing performance."

Jan 1, 2018

Senior staff representatives of the Bureau of Mines and the National Institute for Occupational Safety and Health (NIOSH) met in Washington on September 6, 1972, to review and evaluate their cooperative accomplishments to date and to consider the planning and conduct of future coordinated activities. The six presentations given at this joint staff seminar are published here for the benefit of those concerned with the problems of coal mine health, and especially those with responsibilities in administering the Coal Mine Health and Safety Act of 1969.

Jan 1, 1972

By J. van Huyssteen, M. Cantor

Newmont Ghana Gold Limited's Ahafo Operation has matured from its project ramp up stage into steady state operations after three years of operation. Management focus has shifted from addressing construction and commissioning problems to optimization and improvement. This focus change has coincided with the introduction by Newmont of a Continuous Improvement (CI) program across the company which provided a project management methodology that can be used in the execution of smaller scale projects. This paper focuses on the application of CI principles at the Ahafo Plant through the discussion of several case studies that demonstrate how these principles are applied.

Jan 1, 2011

By J. Coxon, G. W. Walker

The paper describes the discovery, location and events concerning three types of heating which have occurred in recent years: a) in a district being salvaged, b) in the shaft pillar at an air-crossing, and c) in the gate side of a production district, all of which have occurred in the Beeston Seam at collieries in the deeper eastern part of the area. The paper describes the precautions, air sampling arrangements, training methods and codes of practice which have been adopted at collieries where spontaneous combustion is, or is likely to be, a hazard. The air samples taken from behind the stoppings following the sealing off of the salvaging district are examined and interpreted. The problem of effectively sealing off where more than two stoppings are required is made apparent. Other lessons have been learned as a result of these heatings and are described in the paper.

May 23, 1905

By Earl Cook

A high-energy economy based on fossil fuels is in fundamental conflict with an ideal of clean air, clean water, undisturbed scenery, and maintenance of fragile ecosystems. There is an inevitable trade-off between the material standard of living of a modern society and the conservation of its environment. During the past four years, some of the costs of environmental protection have been internalized in the energy-flow system of the United States. The cost of bituminous coal and fuel oil usable under new air-quality standards has doubled or more. The cost of mining coal underground has risen because of a 20-30 percent reduction in productivity resulting from new environmental health and safety legislation; the economic impact of proposed surface-mine regulation may be equally severe. The cost of producing electric power has been rising at a 12 percent annual rate because of environmental costs, and would be climbing still more steeply were it not for the continued forced subsidy of natural-gas consumers by natural-gas producers. The efficiency of the automobile, already a monument to the triumph of self- indulgence over economy, is being further decreased by addition of anti-pollution devices. Part of the recent sharp rise in agricultural costs stems from the fact that five energy units of fossil fuel go into U.S. agriculture for every energy unit of raw food that leaves the farm; further large injections of fossil-fuel energy occur in the transport, processing, and refrigeration of farm products.

Jan 1, 1974

By W. D. Monaghan

One of the major ignition sources of fires and explosions in underground U.S. coal mines is flame cutting and welding. On May 20, 2006, a flame-cutting operation at the Darby Mine No. 1 led to an explosion that resulted in five fatalities. On Jan. 22, 2003, another explosion caused by flame cutting at the McElroy Mine resulted in three fatalities and three serious injuries. On June 22, 1999, a flame-cutting and welding operation at the Loveridge Mine caused a fire that required sealing the mine for an extended period. On March 19, 1992, an explosion initiated by welding at the Blacksville No. 1 Mine resulted in four fatalities. These examples of mine incidents demonstrate the need to conduct research to develop best practices for safely conducting flame cutting and welding in underground coal mines. The National Institute for Occupational Safety and Health (NIOSH) conducted a study on fires and explosions in underground U.S. coal mines that were caused by flame-cutting and welding operations to determine the root causes of these types of incidents. The methodology included interviewing mining personnel who perform flame-cutting or welding operations in underground U.S. coal mines and visiting mines to observe these operations. In addition, MSHA reports of investigations and accidents statistics were analyzed. The findings were used to identify and compare differences between flame-cutting and welding practices and techniques in small and large mines, eastern and western mines, low-seam and high-seam mines, room-and-pillar and longwall mines, and between experienced miners and new miners. As a result of this study, best practices were developed to reduce the number of ?res and explosions caused by flame cutting and welding. This paper provides a summary of this research.

Jun 1, 2010

By H. W. Leavenworth

Research was conducted by the Bureau of Mines to develop a technique to grow metallic fibers from a sulfide mineral. In this research, chalcopyrite (CuFeS2) was made sulfur deficient, and the remaining sulfur partitioned to the iron in the mineral to liberate metallic copper, or to the copper to liberate metallic iron. The metals formed on the surface as fibers and in the interior as spherical particles. Fiber growth is very fast. Lengths of 3 to 4 cm form in a matter of minutes, and the diameter of individual fibers is less than 1 µm. The mechanism of fiber growth is explained, and the reactions are reversible as predicted. Copper fibers can be made to grow from the surface at 400° C or to dissolve back onto the solid surface and be replaced by iron fibers at 625° C. Growth and dissolution can also be controlled to form copper/iron duplex fibers.

Jan 1, 1974