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By R. Barany

Thermodynamic calculations pertaining to the minerals gibbsite, kaolinite, halloysite, and dickite have been hampered by the lack of adequate heat and free energy of formation data. Previous data for gibbsite were highly uncertain, and there were no data for the other three substances. By use of hydrofluoric acid solution calorimetry, the Bureau of Mines derived heat of formation values from the elements and from the oxides for the four substances, and the data were combined with known entropy values to obtain the corresponding free energies of formation. The results show that gibbsite and halloysite are thermodynamically unstable with respect to the oxides (a- alumina, a- quartz, and liquid water) at 298.15° K,, while kaolinite and dickite are only moderately stable (to about the same degree), The instability of halloysite, in comparison with kaolinite and dickite, results in a 60°-lower equilibrium decomposition temperature.

Jan 1, 1961

By F. X. Tartaron

Behavior of hard-burned quicklime was compared with that of soft-burned quicklime in an oxygen converter utilizing oxygen blowing in a rotating cylindrical vessel, set at a 30° to 60° angle to the horizontal and operated at a predetermined speed of rotation. Four pairs of tests were made) each comparing hard lime with soft lime. Three of the pairs differed from one another in the quantity of lime employed) and the fourth differed in blowing time, All four pairs showed an increase in yield when soft lime was used. Three of the pairs revealed that the ratio of the oxygen consumed with soft lime to the oxygen consumed with hard lime was the same as the ratio of metal yield with soft lime to the metal yield with hard lime. The fourth pair contained an error and could not be included. Finally, a close inverse relation was found between the combined iron in the slag and the combined lime in the slag, which can be expressed by the equation pct Fe = 52.67 -0,906 (pct CaO).

Jan 1, 1967

By T. R. Strombotne

The purpose of this report k to document a contract undertaken by TSA Systems, Incorporated for the United States Bureau of Mines to develop a commercially available source of a continuous, working,, level detector for the measurement of radon daughter products in various working environments. The basic radon measuring technique was devised by Robert Droullard and Robert Holub and has been applied here. For further details or purchasing information contact: TSA Systems, Incorporated 4919 North Broadway Boulder, Colorado 80302

Jan 1, 1982

By S. H. Lorain

This paper briefly describes the principal commercial and near-commercial deposits of gold-bearing gravel and the important placer-mining operations in Lemhi County, Idaho. It is on of a series on western mining districts being published by the Bureau of Mines. This paper is based on a field survey of the placer-mining districts of Lemhi County in the summer of 1938. Available information concerning gold-bearing gravels was obtained from prospectors and claim owners; operators supplied the data on mining operations. No attempt was made actually to test the gravels. The principal object of the examination was to indicate placer areas worthy of further investigation by prospective operators.

Jan 1, 1939

By J. A. M. Cano

With a view toward increasing its product competitiveness in the foreign market, SAMARCO MINERACAO S/A has developed high MgO type pellets at its pilot plant for performing direct reduction simulation tests. Additives such as dolomitic lime and magnesite were used for increasing pellet MgO content. Comparative direct reduction simulation tests were conducted both in SAMARCO and foreign laboratories. The test results showed that it is possible to produce direct reduction type pellets with satisfactory metallurgical properties, which can be successfully processed at increased temperatures in direct reduction furnaces.

Jan 1, 1992

By Rae Mackay, Kaveh Ranjbar Pouya, Ali Tolooiyan

"A major part of Melbourne’s central business district is underlain by a very soft silty clay deposit known as Coode Island Silt (CIS). Due to the low strength of CIS, most construction in the region is based on pile foundation systems. Traditionally, the design of pile foundations is mostly based on empirical and analytical methods. However, numerical methods such as Finite Element Methods (FEM) can be utilised for more accurate estimation of the bearing capacity and deformation of pile foundation systems, especially in complex loading scenarios. Unfortunately, no systematic effort is made yet to calibrate a realistic nonlinear constitutive model to describe the geomechanical behaviour of CIS in a numerically based solution. Among the nonlinear constitutive models, the Hardening Soil (HS) model is an advanced hyperbolic model which accounts for the nonlinearity of stress-strain relationship as well as the stress dependency of the soil stiffness. In this study, the HS model is calibrated based on laboratory tests performed on CIS. Also, to validate the accuracy of the calibration, the wellknown cavity expansion theory is employed to model the CPT cone tip resistance (qc) in CIS, and results are compared against the measured CPT qc profile at the field.INTRODUCTIONA large percentage of world’s coastal areas are covered with soft marine clay deposits. Having very low shear strength and high compressibility, the alluvial deposits are known as one of the most problematic soil layers for the design and construction of infrastructure facilities. A major part of Melbourne’s central business district is underlain by a very soft silty clay deposit known as Coode Island Silt (CIS). Basically, there are two main solutions for construction in such weak soil conditions. One is the use of pile foundations transferring the applied load to deeper and stronger soil layers, and the second one is to employ ground improvement techniques such as using deep soil mixing columns to improve the bearing capacity of the soil. In both cases, a practical geotechnical design should incorporate both stability analysis and deformation analysis to achieve a cost-effective and reliable solution. Most of the classic solutions for stability analyses such as limit equilibrium analysis disregard the stress-strain relationship of the soil for the sake of the simplicity (Chen, 2007; Sokoloviskii, 1965). In a similar simple approach, most of the past studies of deformation analysis have been established on the basis of linear elasticity. However, it is well recognised that the soil stress-strain behaviour is highly nonlinear even at very small strains (Burland, 1989). Hence, for a precise deformation analysis of the foundation of important geotechnical structures, the application of advanced nonlinear constitutive models is extremely beneficial. Precise deformation analysis is essential as geotechnical designers have to predict the displacement of geotechnical structure and the adjacent soil as well as the induced displacement and forces to adjacent structures. This issue is more highlighted recently in the analysis, and design of highly important infrastructures as geotechnical engineers are facing new challenges in the analysis and design of infrastructures in congested areas. Rapid population growth, especially in the major cities all around the world necessitates the design and construction of more integrated infrastructure facilities. Consequently, geotechnical engineers should employ more advanced design approaches to address the new challenges in geotechnical engineering practice. Complicated geometries, different loading scenarios and the application of nonlinear deformation models which is believed to be essential for a precise deformation analysis, necessitate the application of numerical methods to satisfy most of the design requirements."

Jan 1, 1900

"A growing public awareness of work-related diseases such as pneumoconiosis and the impact of this awareness on legislative bodies and on the skilled labour market are reasons why the Canadian mining industry must consider dust control of top-drawer importance. Measurements and standards related to the hazard are necessary to control a dust situation and to avoid excessive risk. The author discusses some of the methods of measurement, standards proposed and terminology used in this developing technology. The purpose primarily is to give a better understanding of the basic advances achieved by those who have applied current knowledge with a measure of success."

Jan 1, 1972

By A. H. Anderson

THE travelling grate coking process was developed by Shawinigan Chemicals, Limited, at their Shawinigan Falls plant. The first production unit went into operation a month prior to the outbreak of the war. Since then a substantial part of the coke used in the manufacture of calcium carbide has been produced by this process. In the following will be given a short account of the development work, a description of the process and the equipment, a discussion of the properties of the coke, the economics of the process and its future possibilities. EXPERIMENTAL WORK The carbide industry is a large consumer of coke, one ton of commercial carbide requiring for its production 1,200 lb. This coke must meet certain specifications in order to be acceptable. It should have a low ash content, preferably below 8 per cent, and the sulphur and phosphorus content must not be above specified limits. The size of the coke is also important. If it is too large it has to be crushed before it can be used in the furnaces, and if it is too fine it may have to be screened and briquetted. In addition, it must be dry. Although it was generally possible to purchase coke, including petroleum coke, and coke fines, in the quantities required, it became increasingly more difficult as time went on to obtain coke of a suitable quality at an attractive price. It was therefore natural for us to look to coal carbonization as a means of basing the supply of the fundamental raw material for carbide manufacture on something more solid than the shifting conditions of the coke market.

Jan 1, 1944

By Stefan Schwank, Alexander Blatt, Franz-Werner Gerressen

Diaphragm wall technique is usually used to install diaphragm walls, which are known as underground structural elements commonly used for retention systems and permanent foundation elements as well as deep groundwater barriers, named Cut-Off-Walls (COW). In this exploration project, the diaphragm wall equipment was used in the 2019 summer season to perform the first part of an exploration and bulk sampling program for a potential mine on the Star Kimberlite. Beside the idea of using the diaphragm wall technique as bulk sampling equipment, the sampling program required the adaption of equipment and tools for a depth capability never reached before by a trench cutter in any commercial application worldwide. The paper will explain the development of the sampling program as well as the challenges occurred with the local geology and the specific demands of the exploration and sampling program. It will also provide an overview of the lessons learned during the 2019 season and will give an outlook to the approaches of optimization for the second phase which will be carried out in 2020.

By H. Akgun

Design of plugs for abandonment of boreholes and shafts may be governed by the bond strength between the plug and host rock. This paper presents the results of push-out tests on cement grout plugs in salt. Two expandable cement grouts have been tested. The average interface shear strengths ranged from 2 to 12 MPa. Peak shear stresses at failure, assuming an elastic stress distribution along the interface, were up to eight times higher. Standard deviations commonly reached 20%. Dissolution along the interface was observed, and may have been enhanced by clay inclusions in the salt. This dissolution appears to have reduced bond strengths. Application of the results to the design of plugs for larger openings (e.g. shafts, drifts, or boreholes) is discussed.

Jan 1, 1991

By Charles Vaught, Henry J. Kellner, Michael J. Brnich, Henry P. Cole, William J. Wiehagen

In 1985, U.S. Bureau of Mines and University of Kentucky researchers began a series of studies relating to self-contained self-rescuer (SCSR) donning proficiency. During the next 5 years investigators examined a number of factors that have a bearing upon miners' ability to put on and use the apparatus in an emergency: the procedure being taught; availability and utilization of training models; opportunities to practice; hygiene; and on-the-job training. This report presents an overview of that research. It is concluded that companies should adopt a hands-on training protocol that allows them to integrate SCSR donning practice into other workplace routines such as fire drills.

Jan 1, 1993

By T. H. Aldrich

There are two conditions generally prevailing upon the earth—those within atmospheric influence, tending towards oxidation, and those away from atmospheric influence, tending towards reduction. Practically all mineral substances from mines of any depth a.re in a reducing condition. Since the cyanide process, in order to dissolve silver or gold, requires that the prevailing conditions under which it operates shall be oxidizing, and the materials usually acted upon bei~lg of a reducing character, it becomes necessary to supply oxygen to the solution carrying the cyanide. This oxygen is usually supplied through the medium of dissolved air in the solation, or through the medium of various chemical compounds, which upon combining vith the solution or the ore give off a part of their oxygen. Strange as it may seem, practically all mineral substa~~ccs are partly soluble in water, especially water carrying alkali or cyanide. The greater the surface exposed and the finer the material is ground, the greater mrill be the rate of dissolving of the reducing-agents from the ore into the cyanide solution. In most cases, if the solution carrying the ore particles is agitated with air, the air will dissolve into the solution faster than will the reducing-agents; but in some cases the reducing-agents will dissolve more rapidly on account of easy solubility or greater surface exposed. It is a dissolving race between the oxygen from the air and the reducing-agents from the ore, and if the reducing-azents predominate, cyanide will not dissolve the gold from the ore. In many cases it will dissolve some of the gold, because in a mass of irregular shape some of the gold particles might be exposed upon the outside surface of a particle of rock; but if the solution had to penetrate through cracks, the side-walls of which were lined with reducing-agent-

Jan 1, 1912

By G. G. Campbell

The Bureau of Mines initiated a field test of underground coal gasitication to investigate the technologic feasibility of gasifying a subbituminous coal. The test site is near the town of Hanna, Wyo., about 70 miles northwest of Laramie. Preliminary results of the experiment are described. The coal was ignited in the central well of a 16-well pattern. Both forward and reverse combustion techniques were attempted to prepare a path of sufficient permeability to permit the high air injection rat s necessary for gasification. Gasification between linked wellbores was sustained for periods as long as 3 months. Hydrogen-rich gas having a heating value of 100 to 150 Btu/scf was produced.

Jan 1, 1974

By John L. Bolles

The Phelps Dodge Corporation's Morenci Concentrator includes facilities for coarse crushing, fine crushing, grinding, flotation, tailing, disposal, concentrate filtering, and drying. The Morenci Concentrator daily throughput is in excess of 60, 000 tons. The ore milled is mainly a medium-hard monzonite porphyry in which the principal sulfide minerals are chalcocite and pyrite. The ore is transported by rail from the Open Pit Mine to the primary crushing plant located at the concentrator site. Ore is side-dumped from 80¬ton railroad cars into a sixty-inch gyratory crusher. The ore is then conveyed to a. 12, 000 ton coarse ore storage bin. Fine crushing is accomplished by four parallel lines of conventionally stacked crushers in open circuit. Each unit consists of one seven-foot standard cone followed by two seven-foot shortheads. Ti% product of the fine crushing plant is distributed by two tripper cars across a fine ore storage bin. The crushed ore is then fed by variable speed belt feeders into thirty parallel, single stage, closed circuit grinding units. Each of the 30 grinding units consists of one 6' x 23' conditioning drum, one 10' x 10' ha l mill and two 54" duplex spiral classifiers as principal equipment. The dry ore is fed into the conditioning drum with water to dilute the ore to a slurry of approximately 78% solids by weight. An aqueous solution of ammonium sulfide is also added to the conditioning drum. The ammonium sulfide primarily acts as a sulfidizing agent. The ore slurry containing the naturally occurring sulfide copper minerals and the sulfidized copper minerals discharges into the feed scoop box of the ball mill, where milk of lime, collector and-.dilution water are added. The ball mill product slurry is gravity fed: to the classifier pool where water is added to obtain the desired classifier overflow product

Jan 1, 1977

By Y. Ide, K. Kishitake

It is expected that an Al-Cr-N composite nitride film may have a higher resistance to oxidation at elevated temperatures than the well-known Ti-Al-N films. The formation conditions of Al-Cr-N films by a de reactive sputtering method and their properties were studied in this study. The films characterized with respect to their high temperature properties such as chemical composition, crystal structure, microhardness, wear and· friction. The crystal structure of the Al-Cr-N films changed from hexagonal phase to cubic phase with an increase in Cr content in the films. The resistivity to thermal oxidation of the Al-Cr-N films is superior to that of usual TI-Al-N films. A half of the friction coefficient in the Al-Cr-N film was obtained comparing with that in the ordinary TI-Al-N film at room temperature and the wear rate of Al-Cr-N film was 2 order smaller than that of TI-Al-N film. The Al-Cr-N films show a small friction coefficient at 500°C and then they are recognized to have good tribological characteristics.

Jan 1, 2000

By S. E. James

EAF dust has been listed as a "hazardous waste" due to the presence of lead and cadmium, and at times chromium. The 550,00 tpy production of . .EA]' dust, estimated for the United States alone, contains more than 10,000 tpy of lead and about 250 tpy of cadmium in addition to nearly 1'00,000 tpy zinc. Even though the listing of .EAF dust as a hazardous material stimulated extractive metallurgical work worldwide, process development efforts have focused only on the recycle of the potentially-valuable zinc units. However, the recycle of the lead and cadmium, while not lucrative, is the more critical effort. Horsehead Resource Development Company, Inc. (HRD), in conjunction with its sister company, Zinc Corporation of America (ZCA), has taken a unique approach to total recycle of the toxic heavy metals found in the EAF dust. Impure oxide, produced by either a Waelz kiln or FLAME REACTOR Process and containing the lead and cadmium, is calcined in a rotary kiln at Palmerton, Pennsylvania, to produce a refined zinc-rich intermediate for ZCA's electrothermic zinc plant at Monaca, Pennsylvania. During the calcining operation, lead and cadmium are concentrated in a fume product and shipped to ZCA's electrolytic plant at Bartlesville, Oklahoma. At Bartlesville, a new hydrometallurgical circuit has been constructed and the existing cadmium plant expanded. The combined facilities permit the total recovery of cadmium to refined metal and the lead to .a silver-rich intermediate, which is sold to lead smelters. In this paper the Waelzing, calcining and new leaching facilities will be described.

Jan 1, 1990

By A Guillen, J-P ChilFs

Most 3D geological modelling tools were designed for the needs of the oil industry or detailed mine planning and are not suited to the variety of situations encountered in other application domains. Moreover, the usual modelling tools are not able to quantify the uncertainty of the geometric models generated. The potential field method was designed to build 3D geological models from data available in geology and mineral exploration, namely the geological map and a digital terrain model (DTM), structural data, borehole data and interpretations of the geologist. This method considers a geological interface as a particular isosurface of a scalar field defined in the 3D space, called a potential field. The interpolation of that field, based on cokriging, provides surfaces that honour all the data. The 3D model and its parts are always consistent with the observations. New developments allow the covariance of the potential field to be identified from the structural data. This makes it possible to associate sensible cokriging standard deviations to the potential field estimates and to express the uncertainty of the geometric model. It also, for the first time, gives a statistically optimal, geologically sound way of interpolating geology, other than directly joining the dots as you do with CAD. Practical implementation issues for producing 3D geological models are presented: how to handle faults, how to honour borehole ends, how to take relationships between several interfaces into account, how to model thin beds over many kilometres, how to optimise lithological properties and how to integrate gravimetric and magnetic data. We describe all geology surfaces and volumes using implicit functions. These are then rendered onto the required sections, plans, etc. The estimation of orebody grades and tonnes, using an unbiased and optimal geostatistical technique, makes use of the stratigraphically bound 3D geology model. An application to the geological modelling of the Hamersley iron ore district, Australia, is briefly presented.

Jan 1, 2009

By Ryan P. Sullivan, G. Alan Klevens, Jian Huang

"BACKGROUNDLake Hamilton in Hot Springs, AR was created in 1932 when the Arkansas Power and Light Co. completed Carpenter Dam on the Ouachita River to generate electricity. Today, the 7,200-acre (2,914 hectares) impoundment is one of Arkansas’s most popular recreational and residential lakes.U.S. 70 crosses Lake Hamilton by means of a seven-span bridge featuring nine steel girders per span. Constructed between 1982 and 1984, the 1,410-foot long (430m) bridge carries four lanes of traffi c across the lake. The bridge is supported by six intermediate reinforced concrete piers composed of hammer heads, stems, footings and seals, which sit on the underlying rock. (See Figure 1). The bridge rises to a maximum of 33 feet (10m) above the surface of the lake and the footings and seals extend a maximum of 29.5 feet (9m) below the surface of the lake. The seals are situated on hard, fractured sandstone and shale.Routine underwater inspections in 1993 revealed large cracks in the lean seal concrete and refl ective cracks in the reinforced concrete footings. Infrastructure Engineers, Inc., The Arkansas State Highway and Transportation Department’s (AHTD) design consultant, then conducted an in-depth underwater inspection of the pier foundations. The investigation included cross-hole sonic logging, singlehole sonic logging, visual examination and strength testing of core samples, and petrographic analysis.The investigation revealed extensive cracking and low-strength concrete within the seals of all intermediate pier foundations. Many voids within the seal concrete had become fi lled with silt. There was evidence of continued seal deterioration between underwater inspections.AHTD and its engineers considered three rehabilitation solutions in the preliminary engineering stage: micropiles, a cofferdam supported concrete jacket, or a pile supported concrete jacket. The three alternatives were estimated to cost $1,250,000; $4,320,000; and $3,030,000 respectively. All three options would transfer the loads from the pier footing directly to the rock below, bypassing the seal concrete."

Jan 1, 2007

By Ryan P. Sullivan, G. Alan Klevens, Jian Huang

"BACKGROUNDLake Hamilton in Hot Springs, AR was created in 1932 when the Arkansas Power and Light Co. completed Carpenter Dam on the Ouachita River to generate electricity. Today, the 7,200-acre (2,914 hectares) impoundment is one of Arkansas’s most popular recreational and residential lakes.U.S. 70 crosses Lake Hamilton by means of a seven-span bridge featuring nine steel girders per span. Constructed between 1982 and 1984, the 1,410-foot long (430m) bridge carries four lanes of traffi c across the lake. The bridge is supported by six intermediate reinforced concrete piers composed of hammer heads, stems, footings and seals, which sit on the underlying rock. (See Figure 1). The bridge rises to a maximum of 33 feet (10m) above the surface of the lake and the footings and seals extend a maximum of 29.5 feet (9m) below the surface of the lake. The seals are situated on hard, fractured sandstone and shale. Routine underwater inspections in 1993 revealed large cracks in the lean seal concrete and reflective cracks in the reinforced concrete footings. Infrastructure Engineers, Inc., The Arkansas State Highway and Transportation Department’s (AHTD) design consultant, then conducted an in-depth underwater inspection of the pier foundations. The investigation included cross-hole sonic logging, singlehole sonic logging, visual examination and strength testing of core samples, and petrographic analysis.The investigation revealed extensive cracking and low-strength concrete within the seals of all intermediate pier foundations. Many voids within the seal concrete had become filled with silt. There was evidence of continued seal deterioration between underwater inspections.AHTD and its engineers considered three rehabilitation solutions in the preliminary engineering stage: micropiles, a cofferdam supported concrete jacket, or a pile supported concrete jacket. The three alternatives were estimated to cost $1,250,000; $4,320,000; and $3,030,000 respectively. All three options would transfer the loads from the pier footing directly to the rock below, bypassing the seal concrete."

Jan 1, 2007

By A. C. Fieldner, G. W. Jones

Tests were made at the Government Fuel Yard , operated at Washington , D. C. by the Bureau of Mines , Department of the Interior , in order to determine and improve the adjustment of the carburetors on the trucks used for transporting coal from the Fuel Yard to the different Government buildings in Washington . The tests were made possible through the hearty cooperation of G , S. Pope , engineer in charge of the Fuel Yard . Joseph Burrows and A. E. Foote of the garage department assisted during all the tests and supplied information on the mileage obtained by the trucks for the months preceding and succeding the time the tests were made . The Mack trucks used range in capacity from 2-1/2 to 7-1/2 ttoonnss .. The majority of the carburetors were Stromberg G- 3 type , as shown in Table 2. During the winter months , when the demand for coal is heavy , from 30 to 35 trucks are used . At the time the tests were made , only about ten of the trucks were in daily use , owing to the small demand for coal during the summer months , and scarcity due to labor conditions . Samples of the exhaust gas were taken on the trucks kept in service for summer hauling in order to determine the carburetor adjustment as used . Changes were then made to a more economical adjustment wherever possible , without sacrificing flexibility of operation and power . In every case the adjustments were maintained for maximum power , but were adjusted to the leanest position to give that power . In all but one case the carburetors were found to be adjusted too rich for maximum power and economy . These results are considered in detail in a later part of this report .

Jun 1, 1923