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By J. M. Menacho, J. M. Reyes

"Batch and continuous regrind tests were conducted in 3 kW and 15 kW tower mill units, respectively. Single particle size classes of a chilean copper sulphide concentrate were employed in the batch tests, while a fraction of the plant stream was deviated to the continuous unit operated under different conditions.Results are interpreted in terms of the simplified grinding kinetic model energy-based and conveniently adapted to this application. Based on the above figures plus some industrial data supplied by MPSI Inc., a scale-up relationship was developed for the apparent specific rate of breakage siE, as a function of the net power draw P, i.e.siE = siE text (P/P test) 0.089This equation fit very well the available data at the three scales and its application to regrind 4400 t/day of rougher copper concentrate from 70% below 325 Tyler mesh to 95% below same mesh, involves around 30% energy-saving compared to standard ball mill for same grinding task.INTRODUCTIONImpact and abrasion-attrition breakage are two extreme mechanisms present in any grinding system in a proportion defined by specific design and operating conditions. Impact breakage is generally efficient for coarse grinding, while abrasion-attrition is adequate to produce fine particles. Efficiency of conventional tumbling mills decreases as fineness of the product increases, even though distribution of applied stresses is always much stronger than internal force distribution in the particles. On the other hand.in a vertically stirred ball mill like the tower mill, distribution of applied stresses and particle strengths are in the same order of magnitude, making possible nearly ideal abrasion conditions (1).Tower mill configuration includes a cylindrical body vertically mounted and provided with a central screw with flights to produce circulation of balls moved up through the inner region to return down by the external space. Fresh material can be fed into the top , center or bottom in order to assure appropriate agitation of suspended particles. Size reduction and evacuation rates should compensate settling of coarse particles to avoid sanding of the screw. Detailed description of the tower mill and its operation have been given elsewhere (2),(3)."

Jan 1, 1989

By Ethan Steward, Kyle Perry

To test the effects of impact on mine seals, a projectile generator and two seals have been constructed. The projectile generator is a 12-inch (30.5 cm) inner diameter steel pipe with a 4-inch (10 cm) wall, is 8.5 feet (2.6 m) in length, and sealed on one end. Projectiles are propelled by a charge of black powder with a wooden wad and are held in place by foam sabots in the bore. This system, combined with the large bore, allows firing of many different potential projectiles that may be found in an underground mine at a high velocity into the seals.

Feb 1, 2020

By Frank E. Cash

Although during the past 10 years Alabama has attained an enviable position by its coal-mine accident experience and, like most of the other coal-mining States, has made progress in the safer operation of coal mines, there is still room for improvement, which can be realized only by still greater efforts on the part of employees and employers. From 1993, when accidents were first recorded by the Alabama State Mine Inspection Department, to 1934, inclusive, 3,451 men lost their lives in the production of 569,722,676 tons of coal. The primary purpose of this report is to bring to the attention of the mining industry in Alabama end elsewhere statistics of fatal accidents for 1931-34, with the hope that a study of the causes may lead to reduction of similar accidents in the future.

Jan 1, 1936

By V Rodríguez, M Hormaza, R J. Romañach, C Pinzón-de la Rosa

The authors have presented their ideas for developing a powder sampling device in the I-Corps™ program sponsored by the National Science Foundation (NSF). This is an intensive customer discovery program developed to increase the economic impact of the research sponsored by NSF.The I-Corps™ program requires performing at least 100 interviews with potential customers in various industries. These interviews are essential to establish the need for a particular product or solution, and identify potential commercialisation partners and competition. The interviews have revealed the absence of Theory of Sampling (TOS) principles in many companies. The interviews are designed to identify the difficulties associated with current sampling practices that do not meet TOS principles.The I-Corps™ program is a significant challenge for scientists who often avoid discussing a concept in fear of losing their research idea. The program teaches how to obtain information without releasing the important intellectual property related to a product development idea. The I-Corps™ methods have been used to discover the prevailing ideas on sampling in various industries.I-Corps™ also teaches how to present ideas to investors; another significant challenge for a scientist. We are currently learning to present sampling and TOS to investors and business development experts, and will share some of these experiences.CITATION:Pinzón-de la Rosa, C, Rodríguez, V, Hormaza, M and Romañach, R J, 2017. Theory of Sampling meets the National Science Foundation I-Corps™ program, in Proceedings Eighth World Conference on Sampling and Blending , pp 351–354 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

By Wenjun Duan, Kun Wang, Qingbo Yu, Qin Qin

"A novel oxygen production technology noted chemical looping air separation (CLAS) was introduced and properties of Cu-based oxygen carriers used were investigated. The oxygen carriers were prepared by mechanical mixing. Al2O3, Fe2O3, ZrO2, TiO2 and SiO2 were used as binders during the preparation. XRD patterns show that spine! oxides are formed using Al2O3 and Fe2O3 as binders. Phases of CuO and binders keep stable using ZrO2, TiO2 and SiO2 as binders. BET values of oxygen carriers increase in the order of ZrO2>TiO2>SiO2>Fe2O3>Al2O3. The effects of temperatures, binders, particle sizes and flow rates on reduction/oxidation reaction rates were studied in TG experiments. The reduction reaction rate increases in the order of ZrO2>TiO2>SiO2. The effect of binders on the reactivity of oxidation is not obvious. The reduction and oxidation reaction rates both have the tendencies of increasing with the temperature increasing and with gas flow decreasing. However, the effects of gas flow and particle size are little.IntroductionChemical looping air separation (CLAS) is a novel oxygen production technology. The oxygen carriers used in CLAS release oxygen in reduction reactor and regenerate in the oxidation reactor. Selecting suitable oxygen carriers is the key for CLAS. Oxides of CuO, Mn2O3, Co3O4, Pb3O4, CrO2, SrO2, PdO2 and CeO2 have the property of releasing oxygen at suitable temperature and oxygen partial pressure [1]. Among these oxides, CuO, Mn2O3, Co3O4 are the most common compositions used to prepared oxygen carriers for chemical looping combustion (CLC) or chemical looping with oxygen uncoupling (CLOU) [2-5]. Moreover, thermodynamic calculations and preliminary experiments were carried out on oxides of Cu (CuO/Cu2O), Mn (Mn2O3/Mn3O4) and Co (Co3OJCoO) by Moghtaderi to ascertain their feasibility for CLAS process [6]. CuO has the highest oxygen transport capacity (0.1 g 02/g CuO compared to 0.03 g 02/g Mn2O3 and 0.06 g 02/g Co3O4). However, agglomeration is the biggest issue for copper oxides used at high temperature because of its low melting point (l 450°C for CuO, 1235°C for Cu2O and 1075°C for the mixture of CuO and Cu2O) [7]. In order to improve the capability of anti-sintering and stability ofCuO, binders (ZrO2, MgAl2O4, TiO2, SiO2, Fe2O3, Al2O3, cement) are added during the preparation of Cu-based oxygen carriers [8]. In this paper, the Cu-based oxygen carriers were prepared by mechanical mixing method. TiO2, Al2O3, Fe2O3, ZrO2 and SiO2 were selected as binder. XRD, BET and SEM were used to analyze the phase, surface area and surface morphology of oxygen carrier prepared. The reactivity of oxygen reduction and oxidation of oxygen carriers prepared were investigated in STA409PC thermal analyzer."

Jan 1, 2014

By Yong Pan, Srivatsan Jayaraman Sridharan, Purushotham Tukkaraja

Block cave mining method poses unique ventilation challenges compared to other underground metal mining methods. This research study focuses on assessing the airflow behavior in regulated airflow distribution systems by developing a 1:100 scaled block cave experimental model and a numerical model. This study also investigated gas flow behavior under various airflow conditions. Based on our findings, we observed that reduction in particle size and porosity of caved materials, decrease in cave footprint, and closure of undercut drifts would increase cave airflow resistance. The increased airflow is found beneficial for gas dilution regardless of its source locations, while the regulated airflow distribution system might deteriorate gas dilution situation when the source is located in the extraction drifts.

May 12, 2022

By S. M. Runke

The purpose of the work described in this publication was to determine, on a pilot-plant scale, the practicability of concentrating low-grade bauxite deposits to render them suitable for the extraction of alumina. In 1941, when it became apparent that the United States might soon be drawn into war, the government, through its various agencies and bureaus, began to stimulate and increase production from domestic reserves of bauxite, which is the principal raw material for the production of aluminum. This activity, which was centered in Arkansas, where 95 percent of the domestic reserve is situated, reached peak production when enemy submarine warfare greatly hindered imports from foreign sources. During this period the average domestic production in Arkansas rose from approximately 300,000 long wet tons to something over 6,000,000 tons in 1943.

Jan 1, 1949

By Jiang Fan, Wang Haigang

"The three-dimensional complex multiphase turbulent flow in U-beam separators was simulated using the Reynolds stress equation models (RSM). To account for the effect of the stochastic characteristic of the instantaneous gas velocity on the particles, the improved Lagrangian stochastic model based on the Reynolds stress model for gas phase was adopted, which attributed to the successful prediction of the turbulence anisotropy and particle crossing trajectories effects. The interaction between the particles was also considered using the HardSphere model. To treat the particle-wall collision, the influence of the roughness of the wall on the motion of the solid particles was taken into consideration by imposing random collision angles. The result from this study not only shows the dynamic characteristics of the multiphase flow- in the separators, but also gives the relationship among the efficiency, structure and pressure losses of the separator.IntroductionCirculating fluidized bed (CFB) combustion is one of the most promising clean coal techniques. A main feature of CFB boilers is the un-delayed recycle of solid, coal and sorbant particulate, in an external loop. Separator, which is required to separate the solid particle from the flue-gas leaving the reactor of CFB, plays an importance role in the external solids recycle loop. It affects the combustion of CFB system greatly. Presently cyclone is the most commonly used as separators for CFB system and other chemical industrial processes. It provides high level of separation for CFB system for fine particles. However it suffers from some inherent disadvantages. It's volume and size is huge. Moreover, it is difficult to design and install when the CFB workload rises. The application of U-beam separators instead of hot cyclone separators in CFB boilers has many advantages. Publications indicate proposals or successful use of Ubeam separators in Swedenr11, USA 21, Russia r3land China [4]• But it is not possible to find results in the literature of detailed investigations of this new. type of separators or recommendations on the choice and calculation of an optimal design. For this reason, numerical simulation for the three-dimensional gas-particle two-phase flows with several rows of vertical U-beam elements, local in the chess order and blocking a way of outgoing from a CFB boilers dusted gases was carried out in this study."

Jan 1, 2004

By Amy McBrayer, Andrea Brickey

The paper discusses the mine planning methods used in the Powder River Basin (PRB), highlighting the differences from open-pit metal mines. It emphasizes the need for agile mine operations due to changing commodity markets and the challenges faced by the coal industry, such as volatile prices and reduced engineering manpower. The study includes a survey of mine engineers to document current practices and identify potential improvements.

Sep 1, 2023

By C. George Miller

"As the influence of governments has become more widely felt, the use of research techniques to analyze policy has increased. Mineral economics, as one of the foundations of mineral policy research, has grown accordingly. Policy research and analysis has been carried out within governments, university departments and the private sector. Each of these institutional environments has characteristics which influence the topics of study, the approach, the methodology and the output of the research. A brief survey of recent research activities provides illustrations of trends and developments occurring within this organizational framework.A radically different organization, the independent research institute, has begun to make an impact on policy research in recent years, and will have an increasing importance in the future. Combining certain features of the traditional research organizations, it nevertheless has important differences which are essential to its effective functioning. An overview of the formation, goals, organization and operation of one such institute is presented."

Jan 1, 1976

By John C. Machisak

STATISTICAL data on injuries and employment pertinent to metal mines and to their mills, and/or processing plants are presented in this Information Circular for the calendar year 1960. The information pertains to metal mines, as well as ore-dressing plants and primary nonferrous smelters, refineries and reduction plants, and their auxiliary works. These data are voluntarily submitted annually to the Bureau of Mines by the operators, and contribute greatly toward the promotion of safety in the mineral industries. The data presented are classified according to the principal mineral produced and include information on copper, iron, lead-zinc, gold-silver lode, gold placer, uranium-vanadium and miscellaneous metals. A breakdown of miscellaneous metals by commodities is shown in table 19, page 41. The data also relate to workers engaged in production, exploration, development, construction, and maintenance and repair work, as well as supervisory personnel and office-workers at the mine or plant site. Injury and employment data at metal mines and metallurgical plants in the United States for 1960 are shown under the following general sections: 1. General injury experience: Tables I-5-Data on injuries, injury-frequency and severity rates and related employment data, work location, and degree of injury.

Jan 1, 1963

By Francis M. Walters

IN spite of the war and the preoccupation of many physical metallurgists with work on secret or confidential problems, definite progress was made during 1944 in our understanding of the behavior of steel and of the effect of alloying elements. During the first two years of the war there was much concern over the possible unavailability of certain alloying elements; this period saw the development of the N.E. (National Emergency) steels. However, the measures taken eased the alloy situation and currently, highly practical problems under study are the graphitization of low-carbon steel and weld-cracking, while investigations of more theoretical interest have concerned hardenability, isothermal reactions, the effect of hydrogen and the interpretation of the notched-bar impact test.

Jan 1, 1945

By C. Sun

The Leeville underground mine has been in operation since 2006 and currently produces 2,903 t (3,200 st) of ore per day, with an average gold grade of 0.4 opt. The mine’s horizontal extent is large, 762 by 152 m (2,500 by 500 ft), while its vertical extent is 6 to 61 m (20 to 200 ft). A high density of joints occurs within the host rock. Based on rock mass rating and field observation, the ground conditions at Leeville can be characterized as poor to very poor. As such, heavy ground support is required for its mining operation. Ore zones with a height in excess of 10 m (35 ft) are considered for longhole stoping. A typical stope measures 6 m (20 ft) wide, 30 to 55 m (100 to 180 ft) long, depending on the ground conditions, and 10 to 30 m (35 to 100 ft) high, depending the thickness of the ore body, yielding 9,100 to 18,000 t (10,000 to 20,000 st) when completed. Narrow ore zones, less than 10 m (35 ft), are mined using cut and fill. Drifts at the Leeville Mine are 4.6 m (15 ft) wide by 4.6 m (15 ft) high. Because of poor ground conditions at this mine, the establishment of a ground control monitoring system is key to operating both safely and successfully. This monitoring system is composed of comprehensive instrument design and installation. Instruments include multi-point borehole extensometers (MPBX) and “stretch measurement to assess reinforcement tension” (SMART) cables. The monitoring system covers the mining zones and infrastructure openings. After about two years’ application and measurement, useful data has been collected and continues to be collected; this information will be used to design future stopes and infrastructure. The system makes engineering and operation teams able to do their job with more confidence and efficiency.

Jan 1, 2009

By A. B. Cecala

An evaluation was recently performed on a district recirculation system at a trona mine in Granger, Wyoming. A 1.52m (5 ft) diameter, 37.3kw (50 hp) vane axial fan was installed in a crosscut between the intake and return airways and recirculated approximately 31.4 m'/sec (66,578 ft'/min) of air back into the intake. This amounted to a recirculation factor of approximately 20 pct of the return air. This air was part of the primary ventilation to three different continuous miner sections at operating distances of between 6l0m (2,000 ft) and 1,829m (6,000 ft) from the recirculation fan. The mine environment was constantly monitored for respirable dust, methane, and carbon monoxide in the operating sections and in the main intake and return entries. In addition, air samples were taken with and without the recirculation system during the evaluation and analyzed using gas chromatography. The results of this study showed only small increases in dust, while all other mine contaminants remained at such low levels that it was impossible to determine any relative changes from the recirculation system. Because of this, a brief SF. tracer gas analysis study was subsequently performed to more precisely determine an increase in a mine contaminant with the recirculation system.

Jan 1, 1991

The additional information that Clarke and Taylor (1982) provide about the important but poorly documented Ardlethan deposit is, of course, very welcome. However their contention that structural considerations, in conjunction with petrology, alter the interpretation of the mineralogical and geochemical data presented previously (Scott, 1981) is not accompanied by adequate supporting evidence. Indeed characteristics of the orebodies studied invalidate their arguments.Heterogeneity between matrix and fragments is not a problem in the South Cherry and Ardwest orebodies because most samples are comprised entirely of interlocking hydrothermal assemblages with a fabric and mineralogy that is uniform through both former breccia fragments and matrix. In hand specimen, the rock superficially resembles altered granite and, as indicated by Clarke and Taylor (1982), a brecciated texture is difficult to discern. In thin section, relict brecciated textures can be observed as localized changes in the grainsize or in the distribution of minerals that outline former breccia fragments (P. J. Eadington, 1982, personal communication).Because of the intense brecciation and comminution of rocks (fragments < 10 mm are usual) in the South Cherry and Ardwest breccia bodies, hydrothermal recrystallization was complete, resulting in homogenization of fragments and matrix. Furthermore, the amount of sample analysed (-100 g for drill core and 2-3 kg for hand specimens) is sufficiently large to be representative of both former breccia fragments and matrix. The Carpathia and Stackpool orebodies, with their abundance of sedimentary fragments, have alteration superimposed on a heterogeneous fabric, and were not studied. Thus the problems of differentiating between fragments and matrix (Clarke and Taylor, 1982) are irrelevant to the particular orebodies described in my paper.Within the alteration halo, which is several hundred metres wide (Paterson, 1976), the very uniformity of the alteration assemblages implies that subsequent, postmineralization brecciation is of only minor significance.Indeed tourmaline pipes in the Ardwest pit are less than several metres across (Clarke, 1979) and produce minimal alteration in the surrounding rocks. Therefore the interpretation of the mineralogical zonation is not compromised by the recognition of several periods of brecciation.

Jan 1, 1982

By A. Mahmoudkhani

Primary cementing is the process of placing cement in the annulus between the casing and the formations exposed to the wellbore. Portland cement was first used in 1903 in the Lopoc Field in California for well cementing. Since then, the major objective of primary cementing has always been to provide zonal isolation in oil, gas and water wells, i.e. to exclude fluid(s) in one zone from another zone in the well. To achieve this objective a hydraulic seal must be created between the casing and cement and between the cement and the formations, while at the same time preventing fluid channels in the cement sheath. This requirement makes primary cementing the most important operation performed on a well. Without complete isolation in the wellbore, the well may never reach its full producing potential. The industry knowledge on cements relies heavily on empirical data, but the chemistry, physics and structure of cement are not fully understood yet. The strength of concrete can be increased essentially by reducing its porosity through optimizing the size distribution of its components and filling the residual porosity of the hydrated cement phase with inorganic fillers. This approach has successfully utilized in different ways and several technologies for placing high performance oil and gas well cements have been developed over the last few decades. There are reasons to believe that the next source of improvement will lie in the fine-tuning of the hydrates themselves and of the different parameters that drive short (ionic?covalent bonding) and long (ionic correlation) interactions.

Jan 1, 2012

By Mitsuru Tanahashi

In order to develop an effective process for the production of a solar-grade silicon (SOG-Si) from metallurgical-grade one (MG-Si), the oxidation removal of boron from molten MG-Si was investigated at 1773 K by the following two CaO-saturated CaO-CaF2 flux treatment processes. I) Boron removal by flux addition onto the molten MG-Si followed by oxygen gas injection into the melt (Two-stage connecting process). II) II) Boron removal by simultaneous injection of flux powders and oxygen gas into the molten MG-Si (Simultaneous injection process). These processes can establish the special condition of both high basicity of the flux and the high oxygen partial pressure at the boron removal reaction sites. Through these processes, especially by the simultaneous injection process using a flux powder injection equipment, the boron content in MG-Si can be efficiently reduced. The obtained results clarified that both processes should be conducted for a time period as short as possible by using as much flux as possible. By repeating the simultaneous injection process for 60 s three times under the optimum operating conditions determined in the present study, the boron content in MG-Si can be reduced from 14 to 4.7 mass ppm.

Jan 1, 2003

Mineral resource development activities impact the health and well-being of many people, from workers, to families and surrounding communities. In the decade up to 2010, mining revenues increased from 6% to 14% of Australian GDP, and minerals contributed 55% of total exports, with a growth in mining employment from 1% to 1.7% of the national workforce (Connolly and Orsmund, 2011). The growth in Australia?s minerals operations is mostly located in remote areas, or in rural communities with a limited population. As a result, operations have increasingly implemented long distance commuting (LDC) programs, often called ?fly-in, fly-out? (FIFO) and ?drive-in, drive-out? (DIDO), as a staffing strategy to meet rapid industry growth in locations with limited local populations. The rapid expansion of the minerals industry has resulted in considerable public debate about the benefits and costs to all sectors of Australian society. In response to the concerns of constituencies from many parts of Australia, the Minister for Regional Australia, Regional Development and Local Government, The Hon Simon Crean MP, asked the House Standing Committee on Regional Australia on Tuesday 23 August 2011 to inquire into and report on the use of ?fly-in, fly-out? (FIFO) and ?drive-in, drive-out? (DIDO) workforce practices in Regional Australia. The recently published report highlights the national interest and the diverse opinions about this practice in Australia. Resource extraction companies have developed several options to meet the accommodation requirements of their long distance commuting workforce. In this paper, initial results are reported from an ongoing survey of FIFO (and other non-residential) resource industry workers (n = 286) in the Australian resource extraction industries. The purpose of this study was to better understand how accommodation arrangements may impact on the health, wellbeing and job satisfaction of non-resident workers; and to attempt to find a relationship between different accommodation variables and workforce wellbeing and retention. In doing this it investigates evidence for the linkage between accommodation factors, hours of work, health, well-being, job satisfaction and job retention in the LDC work force.

Aug 1, 2013

By V. A. Kharchenko, V. M. Yeremeev

INITIAL PRECONDITIONS To solve tile problem of using the potential reserves of the different coal ranks efficiently (the coal reserves being many times superior in quantity to those of natural gas and oil) one must realise an integrated estimation of the coalfields' and coal deposits' reserves. The actuality of this problem increased especially in the recent years, when the Russian coal industry is being restructured. A structural reorgaisation of this industry, in order to in- crease its efficiency, covers a large spectrum of social and economic problems, comprising a withdrawal from mining the coal reserves that are unsafe from the standpoint of economy and labour protection. According to the information supplied by the 'Rossoogol' company, the Russian coal industry, accounting for abut a fifth of the world coal reserves, has a rather unsafe resource base, for about 5% of the reserves involved in mining do not correspond to the world practice conditions, regarding the coal grade, thickness, geological conditions, proneness to coal and gas outburst hazards. These concern first of all the Moscow, Kizelovsk and Donetsk coal basins, the Prokopievsk-Kiselevsk district of the Kuzbas basin and several other coalfields. Thus, the problem of efficient potential coal reserves' utilization calls for a paramount solution of two basic problems, namely: a) a comparative coalfields' and sections evaluation, and their ranging, in accordance with their industrial importance; b) choosing the 'active' reserves good to be efficiently mined under the present-day conditions. PRINCIPLES OF EVALUATION The investigations that had been carried out make it possible to formulate the following basic principles of the coalfields' reserves' estimation (or assessment). 1. The necessity, possibility and expediency of coal reserves' industrial exploitation are determined by a set of natural, technical, technological, practical, economic, environmental and social factors, thus calling for an integrated and gradual approach to problem solving. 2. One cannot consider the results of same reserves' estimation as being invariable because the former depend both upon constant (mainly natural) and market demands for different grades of coal (those of different power engineering and technological situations), capital investments, material and labour resources, economic (price-forming), technical, technological, environmental and other factors. 3. The rational size and sequence of the operating mines' and reserve sections' resources' involvement into mining depend upon the final aim of posing the problem, whose variants may be (the corresponding limitations being considered) providing for a maximum run-of-mine output (these essentially featuring the past stages of the industry's evolution); providing for a maximum efficiency, measured possibly by the specific or absolute indices of profits an expenses, labour productivity e. al. ; providing for a maximum extraction (maximum integrate utilization) of the known reserves. In this case an important park goes to the economic evaluation (or assessment) of useful application of the by-products being extracted (methane, mine water, rack) compared to the expenses necessary for their utilization. Regarding the steam coal (posing the problem any way it be possible), and extreme limit to the absolute non-efficiency of the coal reserves' exploitation may be posed, using the proportion of energy obtained from the possible amount of the coal to be extracted to the energy consumption necessary to extract, prepare, haul and consume this amount of coal. 4. The most reliable and efficient solutions providing for opening the reserves can be obtained for group of mines, rather than at the level of an individual mine section or an individual mine because it is only in the former case that the possibilities to re- distribute the expenses necessary to develop the good for mining and worse sections and seams can be realized to the greatest extent. Therefore the prospective approach to be considered is the one providing for an integrated organization and choice of the optimum combination of the variants of the ways to use the mines in operation and the free sections of the region in order to satisfy the growing up requirements for coal rather than the one providing for individual mine sections' resources' evaluation. 5. The future possibility and expediency of coal reserves' industrial exploitation will depend upon the prospects to implant at the mines in operation and reserve sections new engineering and technological elements and coal extraction technologies which may essentially change the actual idea concerning the coal reserves worth of being developed in an efficient way. For example, reserves not available to be exploited using conventional coal extraction technology may be regarded as potential resources for in situ gasification, e. g. the operating mines' reserves (non-commercial and non-mined commercial ones), balance and outside balance reserves of the free sections having proved not available to be mined using conventional coal-extraction technologies, as well as the non-extracted reserves of the abandoned and closed mines.

Jan 1, 1996

By P. L. Sibrell

Previous research by the U.S. Bureau of Mines has shown that autoclave cyanide leaching of used automobile exhaust catalysts for recovery of platinum-group metals (PGM) is technically feasible. The purpose of this work was to investigate the chemistry of the dissolution of PGM in cyanide solutions in more detail. Where possible, samples of pure, elemental PGM powders or foils were used instead of automobile exhaust catalysts, because of their greater purity. Ultraviolet spectra revealed that Pt and Pd were solubilized as the square planar tetracyanometallate (II) complexes, while Rh was solubilized as the octahedral hexacyanorhodate (III) complex. This explained the poor recovery of Rh from solution by carbon adsorption, solvent extraction, and ion exchange observed in earlier research, because of the higher anionic charge and size of the octahedral complex. Leaching rate studies showed that the rate of solubilization was greatest for Pd, followed by Pt and Rh. Although the rate of chemical reaction was the controlling step for the dissolution of elemental Pt and Rh samples, the rate of pore diffusion was rate limiting for PGM in catalyst samples.

Jan 1, 2010