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By George S. Dulikravich

An advanced semi-stochastic algorithm for constrained multi-objective optimization has been adapted and combined with experimental testing and verification to determine optimum concentrations of aJ10ying elements in heat-resistant and corrosion-resistant H-Series austenitic stainless steel alloys. The objective was to simultaneously maximize a number of alloy's mechanical properties. This research will result in a rigorous tool for the design of high-strength H-Series steels and other types of alloys unattainable by any means existing at the present time. Such a material-by-design tool will also be able to reduce or minimize the need for the addition of expensive elements such as Cr, Ni, Co, Nb, Ti, V, etc. and still obtain the optimum properties of an aJ1oy.

Jan 1, 2003

The Waste Isolation Pilot Plant (WIPP) is a geologic repository for disposal of transuranic waste and is operated by the US Department of Energy. The repository is located at a depth of 655 min the Permian age salt beds of the Salado Formation. The exhaust air from the facility is independently monitored by the Environmental Evaluation Group to verify compliance with regulatory release limits for radioactive materials. A May 1995 video inspection of the exhaust shaft identified fluid migration into the uppermost 25 m of the shaft. Since then, water has been observed flowing in from cracks in the shaft lining between 16and 25 m below surface level at an estimated rate of between 5 and15 m3/d. This water inflow has not only negatively impacted the equipment in the shaft, associated duct-work and monitoring equipment located at the top of the shaft, but also challenged efforts to verify compliance at the WIPP. This paper provides an analysis of these effects.

Jan 1, 2004

By Terry McNulty

DOUG HALBE: I've decided that we're going to change tactics here and we're going to be nice to people from now on. [Co-chair makes gesture of intense disbelief; laughter] I've also decided who's not going to be a co-chair next year. [laughter] We thought we'd get a couple of experts for our next presentation: some people with a lot of experience. We've asked them to tell us some of the things that all of you operators out there might be able to apply immediately to your plant. Our next two speakers have a tremendous amount of experience, and I think you'll find what they're going to say is highly pertinent to most plants. I looked through their paper and found some things that I could have used in the plants I operated in the past. Our first speaker is Terry McNulty. A lot of you know Terry. He was with Anaconda for a number of years as director of research. He then was president of Hazen Research. I'm going to continue with our new custom of saying nice things. Terry is the guy that I call when I don't know something, and he's always got the answer. SPEAKER: Who do you work for, Doug? [laughter] DOUG HALBE: Remember that we're being nice to people here, Joe. I know that's a stretch. [laughter] TERRY McNULTY: Thank you, Doug. I'm a little bit mystified by this sudden switch of tactics just before I get to the podium. Doug's been a good friend for a lot of years so I guess I do have to be nice. I won't say anything deprecatory about him, but I would have to comment that the observations made by earlier speakers have been far too generous. [laughter] During nine years of consulting as a mineral processor and extractive metallurgist, I have often conducted audits of the performance of client's plants. Usually these audits have been ordered by the plant management in hopes of identifying opportunities for improving processing efficiency or reducing costs. Some of the audits, however, have been financed by the Electric Power Research Institute (EPFU) and member utilities with the objective of

Jan 1, 1998

By R. K. Mehta

An electrochemical coal oxidation model involving heterogeneous kinetics is presented. This model was tested by collecting current transient data on three coals assaying different ash content under varying operating conditions such as particle size, temperature, and % solids. In all cases, the model fitted the data very satisfactorily. Three intrinsic rate constants, namely mass transfer coefficient of Fe(II) Ions diffusing from solution to the anode (kma), mass transfer coefficient of Fe(II) Ions diffusing from solution to the coal surface (kmc), and chemical rate constant for coal oxidation with respect to Fe(III) at coal surface (k), were calculated. It was interesting to note that in this system, the mass transfer at anode was as important as the chemical reaction at the coal surface. The validity of this model was further demonstrated through a comparison of the activation energy of coal oxidation: firstly, by utilizing calculated chemical rate constant and assuming Arrhenius' type of relationship: secondly, by utilizing conventional approach using limiting current values. The comparison revealed that agreement was quite close. This kinetic analysis is useful because such a model can be used in predicting the intrinsic rate constants so that the relative importance of mass transport can be rationally analyzed.

Jan 1, 1991

By ALBERT F. J. BOARDEAUX

(Canal Zone Meeting, November. 191(j.) I. GENERAL INTRODUCTION. 1. Historical. ALLUVIAL gold was first discovered in Guiana in 1852, in the sands of the Arataye river; by Paulino, a Brazilian convict. During the following years, gold was found also in the rivers Orapu, Cirubé, etc. In 1873 the famous placers of the Sinnamary system were opened: Saint-Elie, Dieu-Merci, Adieu-Tat, and Couriége. This group of mines has produced nearly $10,000,000, according to official records, not including the gold that escaped the taxes. The discoverer was a mulatto named Vitalo. Except in a few rich spots, the gold was rather evenly distributed along the creeks. In one instance, gold was found in the red dirt from the slope of a hill, which, after transport to the creek, gave an amount of 150 kilograms. The placers of the Mana system, Enfin, Elysée, Pas-Trop-Tot, date from 1878, and their production has been about $5,000,000. In 1888, the Awa placers, along the boundary between the French and Dutch Guianas, on the Maroni and its tributaries, were discovered. They have yielded $12,000,000. The only industrial company,, the Dutch Guiana French Mining Co., produced in 15 years about 2,500 kg. of gold, worth $1,500,000. From 1893 dates the famous Carsewene discovery, in territory then in dispute between France and Brazil. A settlement was made recently in favor of Brazil, by arbitration of the Switzerland State Council. Carsewene is said to have pro-duced about $18,000,000 in six years (1894-1900), but not even one-fourth of the production went through French Guiana and

Nov 1, 1910

By Randy Reed, Barbara J. Arnold

Respirable crystalline silica poses a significant health risk, with the American Lung Association estimating that 2.3 million workers are exposed to silica in the workplace. This includes mine workers as well as those in many other industries. Reducing dust formation is sometimes not possible so other methods to reduce exposure are critical. These methods include the use of surfactants to reduce airborne dust particles. However, it is the proper selection and application of surfactants that leads to reduced dust exposure. A discussion of how surfactants work, especially for silica dust, leads to guidance for surfactant selection followed by a review of technologies for their application.

Feb 1, 2024

By Joseph A. DeCarlo

This information circular presents data for 1960 on individual coke plants in the United States. All oven-coke plants in existence, whether active or idle at the close of the year, are listed in this report. With two exceptions, only beehive plants on which reports were submitted to the Bureau of Mines are included. Although the Bureau was unable to obtain reports from these two active plants in 1960, the number of ovens and annual coke capacity are estimates, based on previous reports filed with the Bureau of Mines. Accordingly, there were 73 oven-coke plants in existence at the end of 1960 of which 70 were active. Reports were received on 44 beehive plants of which only 13 were in operation at year end. Oven-coke plants are listed alphabetically by States in table 1 which shows the name and address of the company, location of plant, classification or type of ownership, number and type of ovens, annual coke capacity, and coal-chemical materials produced. The terms "furnace" and "merchant" plants used in this and all other reports of the Bureau of Mines designate the type of ownership. Furnace plants are those owned by iron and steel companies whose main business is production of coke for use in their own blast furnaces. Merchant plants are those associated with chemical companies, gas utilities, as well as those that produce for sale on the open market metallurgical, industrial, and residential-heating grades of coke and coal-chemical materials. The annual coke capacity shown for each plant in this table is based on the minimum coking time necessary to produce coke with qualities suitable for its intended use. Therefore, the annual capacity of a plant may change from year to year, depending on age and condition of ovens, the character and quality of coal carbonized, the grade of coke required, and other factors. For example, annual coke capacity of a coke plant primarily making foundry coke with longer coking cycles would be lower than one making blast-furnace coke. Also some ovens must be operated at slightly lower than normal flue temperature because of the condition of the refractories and maximum capacity would be somewhat lower than designed capacity. For this reason, the capacity reported to the Bureau of Mines may differ from the designed or rated capacity estimated by the coke-oven builders at the time of construction. For example, if the generally accepted standard coking rate of one inch per hour were used on all ovens to calculate total annual capacity, it would have been 80.4 million tons or 2 percent higher than the capacity reported to the Bureau. Because of the factors mentioned above, the annual coke capacity shown in this table is believed to be a reliable measure of the practical operating capacity of the industry.

Jan 1, 1961

By E. M. Cameron

Reconnaissance radiometric and geochemical data have been obtained for an area on the western shore of Wollaston Lake that includes the Rabbit Lake uranium deposit. The study area is extensively drift cover ed. The geochemical data were obtained by analysis of center-lake sediments and surface waters for a variety of elements and other constituents. The airborne radiometric data comprise measurements of eU, eTh and K obtained with a .50,000-cc NaI (Tl) detector at a mean terrain clearance of 120 m and 5-km flight-line spacing. Uranium in lake sediments and uranium in waters are the most effective geochemical indicators of uranium mineralization; the other elements measured are not notably anomalous. A sample site density of one per 1 8 km 2 is more than adequate for identification of the mineralized area. Because many water samples contain close to or below the current analytical detection limit of 0.05 ppb U, the use of sediments is generally favoured. for broad-scale reconnaissance in the region. Uranium in these lake sediments appears to be little influenced by variations in the organic or iron and manganese content. The most effective radiometric indicator of the mineralization is the eU/eTh ratio. This parameter is less influenced by environmental variation on the ground beneath the flight line than eU alone . The eTh/K ratio is anomalous under the Athabasca Formation unconformity where, in places, the uranium mineralization is localized.

Jan 1, 1977

"SAMPLING: THE IMPACT ON COSTS AND DECISION MAKING1. INTRODUCTIONFor years those in the minerals industry have been taking samples to assist them in making decisions; whether they be about investing billions of rand in a new mining operation, or simply whether a truck load of mineralised material should go to the mill or the waste dump, - we need a sample to help us make our decisions. This paper emphasises the importance and significance of sampling as a process, some of the associated technical problems and some of the advantages, especially in the light of traditional approaches that has usually left mine sampling to the least educated and lowest paid individuals on the mine. Perhaps the most important aspect that requires attention is the variability, usually measured in terms of precision, that tends to infect the sampling procedures. Francis Pitard 12 has stated: ""There is no such thing as reliable feasibility studies, unbiased ore grade control, accurate environmental assessments or effective process control, if you cannot identify and minimize the seven (ten) major sources of sampling variability. "" It is these ten sources of sampling variability and the way they arise that are briefly investigated. Variability is measured in terms of variances and rather than being self-compensating, there is good evidence to indicate that they are in fact additive at every step in the sampling and analytical process."

Jan 1, 2014

By Thomas W. Turk

The water treatment industry has historically been involved with reducing or inhibiting the inherant scale forming or fouling tendencies of natural waters associated with large industrial cooling water systems. Fouling is an extremely complex phenomenon. From a fundamental point of view, it may be characterized as a combined momentum, heat, and mass transfer problem. Chemical reaction kinetics is involved, as well as the solubility characteristics of salts in water and corrosion technology. It is a routine practice to over size pumps, piping and heat exchangers to compensate for fouling.

Jan 1, 1983

By Ratnakar Singh, Raj Kishore, Kisor Kumar Sahu, Ranjeet Kumar Singh, Ganesh Chalavadi

The Falcon concentrator is capable of separating minerals in fine size classes based on their differential density. Separation of mineral particles depends upon the fluid flow characteristics and relative movement of particles in a fluid. In the present study, a fluid flow characteristic inside the Falcon concentrator was established through experimentation and modeling. The Falcon concentrator has two fluid entry points: (a) Fluid entering through gravity assisted feeding system and (b) Fluid entering through the fluidized hole on the concentrator wall. In order to identify the role of fluid entering the concentrator, a tracer was injected into the system. As per the tracer based experimentation, it was established that fluid entering through the gravity based feeding system is responsible for thin flowing film formation in the stratification zone where particles are stratified based on their relative density. The momentum balance and continuity equations were simplified for a high centrifugal force field, and the fluid velocity profile was estimated inside the thin flowing film. Estimated fluid flow profiles will help to simulate the particle trajectories inside the Falcon concentrator. The influence of rotational speed, fluid flow rate, and cone angle on the fluid velocity profile were investigated. Fluid thickness over the concentrator wall is also estimated, and it is typically of the order of ~150–200 μm.

By K. P. Fournier

This report describes work on the problem of predicting oil recovery from a reservoir into which water is injected at a temperature higher than the reservoir temperature, taking into account effects of vis cosity-ratio reduction, heat loss and thermal expansion. It includes the derivation of the equations involved, the finite difference equations used to solve the partial differential equation which models the system, and the results obtained using the IBM 1620 and 7090-1401 computers. Figures and tables show present results of this study of recovery as a function of reservoir thickness and injection rate. For a possible reservoir hot water flood in which 1,000 BWPD at 250F are injected, an additional 5 per cent recovery of oil in place in a swept 1,000-ft-radius reservoir is predicted after injection of one pore volume of water. INTRODUCTION The problem of predicting oil recovery from the injection of hot water has been discussed by several researchers. l-6,19 In no case has the problem of predicting heat losses been rigorously incorporated into the recovery and displacement calculation problem. Willman et al. describe an approximate method of such treatment. 1 The calculation of heat losses in a reservoir and the corresponding temperature distribution while injecting a hot fluid has been attempted by several authors.7'8 In this report a method is presented to numerically predict the oil displacement by hot water in a radial system, taking into account the heat losses to adjacent strata, changes in viscosity ratio with temperature and the thermal-expansion effect for both oil and water. DERIVATION OF BASIC EQUATIONS We start with the familiar Buckley-Leverettg equation for a radial system:* This is sometimes referred to as the Lagrangian form of the displacement equation. If the injection water is at some temperature Ti which is above reservoir temperature TR, then lw, the flowing fraction which is water, is a function of both water saturation and fluid temperature at any given time and position in the reservoir. The temperature dependence of lw results from the temperature dependence of the viscosity ratio µo/µm of which lw is a function. Thus:

Jan 1, 1966

By D. G. Hulbert

"Mineral processes are complex operations that have been modelled, controlled and simulated by diverse technologies. A review is given of some models of mineral processes in the literature. A new variation of a dynamic process model of flotation is presented. Process models, describing real and relevant physical variables, give a good understanding and good qualitative simulations, but can sometimes require prohibitively difficult and extensive parameter estimations. Process control is usually best done on operational plants by the fitting of system models, which can home in on the plant?s observability, controllability and optimisation. System models can be of a form amenable for use in appropriate techniques for controller design and implementation. The control of milling circuits is discussed in some detail. While simulators use models to predict dynamic or steady-state information, part of their strength lies in their ease of use and their ability to test different types of specifications. Some results are given for a flotation circuit simulator that can be made to solve virtually any permutation of specifications.INTRODUCTIONThe development and application of appropriate technology can lead to better operation of mineral processing plants in industry, so that substantial benefits can be obtained from improved throughputs, efficiencies and product qualities. This paper addresses some of the principles and methods used in the quest for the development and exploitation of such technology. Although the design of processes is often the motivation for modelling and simulation, this paper also targets the use of modelling and simulation for the control and optimum operation of mineral processes. The two processes given the most attention here are flotation and milling.Technologies used in mineral processing range from simple to very complex. Simple technical principles, such as mass and component balances, can yield some simple and effective strategies for modelling and control. However, minerals in particulate form have such complex physical and chemical properties that there appears no end to the complexity that emerges, as more and more factors are taken into consideration in the pursuit of better results and understanding. The situation is aggravated by the complexity of mineral processing plants, which have spatially variable conditions within process units, and complicated interactions between these units."

Jan 1, 2003

By Joseph B. Umpleby

PROGRESS in the petroleum industry in 1929 has been characterized by outstanding accomplishments in the fields of new discovery of supply, economic control of production, increased efficiency and reduced costs of recovery, and lowered costs and greater flexibility in manufacture. Resources have been developed in an outstanding degree in the Kettleman Hills. California, the Oklahoma City field (which adds a large potential area in central Oklahoma), the discovery of Woodbine sand production in East Texas, and the discovery of Wilcox sand production in west-central Kansas. Engineering technique has progressed both along the lines of development and production, with a net result that costs have been reduced and extraction increased in notable degree, although it is impossible to give a close measure of either. In the field of re- fining crude oils variations to the end of promoting reduced cost and greater flexibility has been more important than genera! acceptance of innovations in practice.

Jan 1, 1930

By L. A. Walker

DURING the past twelve years the underground shaft of the United States mine at Bingham has been sunk an additional 2000 ft. with stations and pockets cut every 200 ft. without interrupting the mining of 600 tons of ore per day and the advancing of 1500 ft. of development per month. Following is a brief description of the way the joint work is conducted. The vertical underground shaft is a three-compartment shaft with outside dimensions of 6 ft. 4 in. by 15 ft. 6 in., and inside dimensions for each compartment of 4 ft. 2 in. by 4 ft. 8 in. The manway compartment of the main shaft is used as the hoisting compartment in sinking operations; it is partially lined with 2 by 12-in, lagging and a bucket is used without guides or crosshead. Preparatory work includes the placing of a bulkhead in the manway compartment, 60 ft. above the lowest station or level, the installation of a hoist, a head sheave, a fleet sheave, a-signal system, air and water lines, and a trap door for handling waste.

Jan 1, 1937

By R. G. Knickerbocker, David Schlain, F. K. Shelton, J. H. Jacobs

"Many manganese ores contain from 0.1 to several percent cobalt. If such ores arc used for the production of ferromanganese, the cobalt is lost; on the other hand, if they are used for the production of electrolytic manganese, the cobalt can be recovered during the purification of the electrolyte.The production of cobalt in the United States is insignificant compared to the amount consumed, most of which is imported from the Belgian Congo. Cobalt-bearing manganese ores may therefore constitute an important reserve of cobalt in times of emergency. Moreover, the combined value of manganese and cobalt in some ores may be sufficient to warrant the recovery of both metals by the electrolytic manganese process, whereas the recovery of either manganese or cobalt alone might not be economically feasible.In view of the potential importance of manganese ores as a source of cobalt, a survey has boon made of the cobalt content of manganese ores. Most of the data have been obtained from analyses made in the Bureau of Mines, but valuable data have also been obtained from publications of the Geological Survey, various State publications, and other sources. Unfortunately, most published analyses of manganese ores do not include cobalt determinations; when such analyses were fairly detailed, but did not include cobalt, it was presumed that cobalt was not present in significant quantity.Information on the cobalt content of domestic manganese ores is given in table 1. Ores containing 0.1 percent or more cobalt are listed in table 2, and the districts in which such ores occur are shown in figure 1. Most of the known cobalt-bearing manganese ores occur in the southeastern part of the United States. A group of deposits in central Arizona and a few scattered deposits in other States also' contain cobalt."

Apr 1, 1946

By Elizabeth A. Johnson

The vaporization thermodynamics of the aluminum-silicon carbides Al4SiC4 and Al8SiC7 were studied by the Bureau of Mines over the temperature range of approximately 1,500 to 1,700 K. Vapor pressures were measured by a Knudsen effusion-mass spectrometry technique in which powdered samples were effused from graphite crucibles through small orifices. For each compound, a total of six orifice diameters was tested to verify equilibrium within the cell. Aluminum, mass number 27, was the only vapor species detected over the range 4 to 200 amu. Experimental results are based on the following equations for incongruent decomposition: A14SiC4(cr) - 4A1(g) + SiC(a,hex) + 3C(gr); Al8SiC7(cr) - 8A1(g) + SiC(a,hex) + 6C(gr). The observed vapor pressure-temperature relationships determined with a cell orifice area of 2.0 x 10-3 cm2 for Al4SiC4 and 1.81 x 10-3 cm2 for A18SiC7 are the following: Log P - (-18,682/T) + 12.476, for Al4SiC4 (1,550 to 1,643 K) and Log P = (-19,308/T) + 12.421, for Al8SiC7 (1,526 to 1,784 K), with P in pascals and T in kelvins. Third-law analysis of the data provided the following heats of formation: A14SiC4 ?H at 298.15 K - -50.0 kcal/mol and A18SiC7 ?H at 298.15 K - -92.1 kcal/mol.

Jan 1, 2011

Alluvial diamond deposits covered with a thick overburden cannot be explored effectively and mined profitably with the available conventional techniques. A novel directional drilling technique has been developed and site trials have been conducted at the De Beers Namaqualand Mines situated at the western coast of South Africa. This paper describes the technique developed as well as the results of the site trials. The main task of the project is to develop a tool and a supporting system to achieve a remote exploration and ore extraction method for inaccessible alluvial diamond deposits. The project involves the acquisition of a system, commissioning on-site and evaluating the information obtained during assessment. The project consists of the design -of certain tools and instrumentation for the system, investigations and desktop studies as well as development of the system's logistics. The operating philosophy of the system is based on the keyhole surgery principle. In this study a pilot hole was drilled first, starting from the surface with an inclination to reach deeply seated diamondiferous gravel layers, followed by drilling into a more or less horizontal gravel layer for a certain length and finally pointing-upwards reaching ground surface at a predetermined exit point. The pilot drill bit was then replaced with a larger diameter reamer/mining tool and an HDPE tail pipe was attached behind the reamer. The drill string was retracted back to enlarge the guide hole and flush the excavated ore to the surface through the tail pipe. The material flow in between the sections of the system was' carefully measured to assess and record the gravel recovery rates. Several horizontal holes were drilled at preplanned drill paths to reach and follow the ore layer and the Ore extraction was achieved by means of a reamer/mining tool. Principles of the concept have been proven viable in this investigation.

Jan 1, 2010

By Gerald H. Luttrell

The determination of mass balances is the first step in analyzing the performance of processing circuits. Although conceptually very simple, the mathematics associated with mass balances can be cumbersome when conflicting data sets and/or complex circuits are evaluated. Fortunately, many of the spreadsheet programs available today include powerful search routines which can be adapted to solve common mass balance problems. To demonstrate these capabilities, a generalized mass balance program has been developed using the Microsoft Excel? spreadsheet. Compared to commercial programs, the spreadsheet format is user-friendly, more versatile and easier to customize. This paper reviews the mass balance problem and describes how spreadsheet tools can be used to reconcile conflicting data.

Jan 1, 1996

By R. Barbaroux, J. -M. Lalancette, D. Lemieux, K. Nasrallah, G. Garcia Curiel

"Arsenic released from the lithosphere by mining and metallurgical activities is a growing global environmental concern. Dundee sustainable technologies (“DST”) has developed a processing technology to sequester arsenic by means of vitrification. This method can effectively sequester arsenic trioxide without the need to oxidize from As (III) to As (V). Arsenic oxide is incorporated within a silica glass matrix that is stable as per the Toxicity Leaching Characteristic Procedure (“TCLP”) or EPA Method 1311. In this paper, the conventional treatment of arsenopyrite, commonly referred to as “two-stage roasting”, is discussed along with the options traditionally available for the remediation of the arsenic trioxide by-product. The drawbacks limiting the adoption of this processing flowsheet are discussed and a new processing route is presented for the treatment of arsenopyrite. This new flowsheet outputs an auriferous aluminosilicate highly amenable to gold extraction (> 96%) while eliminating the sulfur dioxide production associated with the second-stage roasting of pyrrhotite and ultimately uses vitrification as a definitive sequestration solution to arsenic trioxide.INTRODUCTION Faced with the depletion of conventional gold ores, the gold industry has witnessed a trend towards the exploitation of arsenical deposits. Arsenic is a naturally occurring metalloid often found in mineralogical association with gold. Many northern Canadian regions, from the Northwest Territories to Northern Manitoba, Northern Ontario and the Abitibi region are facing significant arsenic challenges. Projects are deemed uneconomic or prevented from going into operations due to the costs associated with handling arsenic material and there are penalties imposed to complex concentrates by smelters. In addition, Canadian mining operations have left an environmental legacy of gold tailings with grades typically of up to 9 grams per tonne with no processing solution as they also contain significant arsenic contamination at grades of up to 20%. Table 1 presents a list of Canadian deposits known to contain arsenic."

Jan 1, 2017