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By R. Padilla

In most of the Chilean copper and gold concentrates, arsenic is present mainly as enargite, Cu3AsS4, which at the conventional roasting or smelting temperatures decomposes liberating arsenic as gaseous compounds. The objective of this investigation was to study the decomposition reaction of enargite in an inert atmosphere in the range of 500 °C - 750°C. The results obtained indicated that the decomposition begins at about 525 °C. Two distinct regions in the temperature dependence of the decomposition rate were observed: a low temperature region between 525 °C to 650°C and a high temperature region between 650 °C to 725 °C. The X-ray diffraction analysis suggests that the decomposition of enargite occurs through the formation of intermediate tenantite, according to the following sequential reactions: 4Cu3AsS4(s) ? Cu12 As4S13(s)+ 3/2S2(g) Cu12 AS4S13(s) ? 6Cu2S(s) + 2As2S3(g) + 1/2S2(g) The decomposition kinetics was analyzed by using the model for a topochemical reaction of spherical particles: 1-(1-X) 1/3 = kt, which represented well the data. Apparent activation energies of 113 kJ/mol and 60.5 kJ/mol were found for the low and high temperature regions, respectively.

Jan 1, 1999

By S. J. Page, P. Bolsaitls, W. E. Wallace, C. A. Hill, M. J. Keane

"Boiling respirable quartz dust in water for 10 to 40 minutes decreases the cytotoxicity for both erythrocyte hemolytic potential and pulmonary macrophage release of lactate dehydrogenase in vitro. The potential is reduced to near zero in the boiling concentration range of 1 to 10 mg quartz per ml water in boiling times of 20 to 40 minutes. Below this range the detoxification occurs over a longer boiling time. Above this range the hemolytic potential remaining after 40 minutes of boiling approaches native quartz potential with increasing concentration up to 30 mg quartz per ml water. Replacing the media with fresh at the midpoint of boiling results in full detoxification through 20 mg per ml. Pre—boiling the medium with quartz or silica gel reduces the effect of subsequently boiling test samples. Detoxification persists after mild drying at 110 C for 8 hours, and persists after three days of resuspension in water at room temperature. Additional data on persistence of the effect, on the use of acidic and basic media treatment, and on surface analyses are presented, with a discussion of a working hypothesis and research needs.IntroductionResearch underway to determine interactions of quarts and other mineral dust surfaces with pulmonary fluids and alveolar macrophages in culture led to the observation that when dusts were autoclaved in aqueous suspension, their cytotoxic effects on macrophages wore suppressed, in some cases fully and even after several days incubation with the cells. This finding was in direct contradiction to earlier results from both short term macrophage lysosaal enzyme release assays, as well as longer term cytotoxicity assays from macrophages in culture; in those studies, dusts were steam autoclaved at 121 121 ºC with no liquid water but with steam present. (1,2) However detoxification under boiling conditions has been reported in other research.(3). It was decided to use the hemolysis assay to further investigate these findings, because of its sensitivity, simplicity and cost."

Jan 1, 1988

By Breno Totti Maia

In the present paper, a new energy balance equation was developed, considering the slag phase, in order to define the effects of jet penetration and determine a new value for the factor K. The factor K measure the resistance to momentum transference between exit nozzle and metallic bath. The experiments were performed based on the same conditions of the article used as a comparison. The results showed the same behavior between the experiments and it was possible to determine a new value for the factor K, which changed from the unit order for the metal phase system to hundredths order for the metal and slag phase systems. These results are considered unprecedented.

Aug 17, 2017

By L. F. Heising

The Bureau of Mines evaluated 42 composite samples from selected Michigan-Wisconsin iron formations by reductive roasting-magnetic separation and flotation at minus 325 mesh. Samples having poor to marginal response on initial examination by conventional methods were reevaluated by finer grinding, by reagent suite modifications, and by selective flocculation-desliming techniques. Results ranged from excellent on Menominee Range samples to relatively on Gogebic Range ores. Marquette Range samples ranged from responsive to nonresponsive, depending upon grain size and mineral association.

Jan 1, 1967

By Kazuyuki Kakegawa

"Sintered body of lead zirconate titanate (PZT) was prepared through the spark plasma sintering (SPS) technique. When the mixture of raw materials was calcined at 800°C and sintered at 900°C for 10 min. with SPS technique, the sintered body had almost theoretical density but was a mixture of lead titanate (PT) and PZT. When a calcining temperature of 1100°C was employed, sintered body had a single PZT phase but a lower density. High dielectric constant was obtained for a sample calcined at 800°C, sintered with SPS tecbriique and fired again in the air at 1100°C.IntroductionSpark plasma sintering (SPS) is a recently developed technique for sintering metals and ceramics1. The scheme of SPS is shown in Fig. 1. Sample is put in a graphite die in a vacuum chamber. It is pressed and pulse voltage is applied. The electric current heats the die. It is said that the pulse causes a spark-plasma between particles in the sample. Because of the spark- plasma, sample can be sintered at temperatures lower than that in the ordinary sintering by several hundred degrees of Celsius. The sintering period is also very short2Low sintering temperature and short sintering period in SPS technique cause low reaction rate. It is both disadvantage and advantage. In some cases, the reaction cannot be completed under the SPS conditions. If a mixture of several compositions having different properties can be sintered without a compositional change by the diffusion during the sintering, combination of properties, and therefore a design of property will be possible3. The low reaction rate of SPS may enable such combination."

Jan 1, 2000

By Warren D. Stanford Stanford

Introduction The Sleeper mine is a near-surface gold mine located in a remote area 56 km (35 air miles) northwest of Winnemucca, NV (Fig. 1). The deposit was discovered in 1984 by an Amax exploration geologist. Favorable drilling results led to feasibility studies and metallurgical testwork. Final evaluation of the mine potential proceeded very quickly. The project received Amax board approval in July 1985. Eight months later, the process plant was fully operational. The first gold ($1 million) was shipped one month later, in March 1986. Total plant capital was $27 million. Payback was achieved in six months. The Sleeper mine was expected to produce 1.6 t (53,000 oz) of gold and 1.3 t (41,000 oz) of silver annually. However, the ore body exceeded all expectations. Production for the first 10 months of operation amounted to 4 t (128,000 oz) of gold and 2.9 t (94,000 oz) of silver. Direct cash operating costs are in the $1.77/g ($55 per oz) range. Amax is actively conducting exploration nearby for additional reserves to extend the mine's life. (See update on page 242.) Geology The Sleeper gold deposit is located on the northwestern flank of the Slumbering Hills and in the Awakening Mining District. Rocks exposed in the vicinity of the deposit are interbedded siltstones, sandstones, and limestones of Triassic age. They are overlain by latite lava flows and tuffs of Tertiary age. Dikes and sills of latite and andesite intrude the sedimentary rocks. Quaternary deposits of mostly sand with minor gravel and clay cover a pediment containing the gold deposit. The sedimentary and volcanic rock units have been transsected and offset by extensive north- northeast trending faults and less abundant northwest trending faults. Both fault systems fractured and prepared the ground for subsequent invasions of mineral-bearing hot spring geothermal waters. The hot spring systems produced widespread hydrothermal alteration and gold mineralization at silicified centers near feeder fault structures. The deposit is hosted by siltstone and latite that have been hydrothermally brecciated. The main breccia is elongated north-northeasterly. The hydrothermal breccia zones appear to dip steeply to the west. Gold mineralization consists of native gold and electrum deposited in two or more high-grade quartz-breccia veins. Lower grade gold mineralization occurs

Jan 4, 1987

By M. D. Loy

In addition to products available from private vendors, many useful programs are developed at universities - in fact, many of these programs led the way to commercial development. Other projects are assigned to consultants with backgrounds in system design and mining. Both types of development have led to programs that can be acquired for the cost of a tape or disk. This paper highlights several underground mining packages. These programs consist of: ? USBM model-developed by the United States Bureau of nines. ? PSU model-developed by Pennsylvania State University. ? VPI model-developed by Virginia Polytechnical Institute and State University. ? NUS model-developed by NUS Corp.

Jan 1, 1987

By James W. Reeves

DuPont was the titanium metal pioneer who put the greatest effort into both R&D and commercial sponge and powder metallurgy production. This was concentrated in the period 1945 through 1963. The commercial results were development of the chloride process for TiCl4 using ilmenite, development and improvement of the Kroll process, development of a modified Hunter process to make titanium powder and commercial development of a direct powder process. The powder metallurgical process failed because of the inability to meet powder chloride specifications. All this work remained a trade secret until published in NMAB -392 by Mahla in 1983. There were other processes explored by DuPont, both improved sponge and powder processes. Much of this work has been continued by others but none, as of yet, resulting in new improved titanium metal capacity.

Jan 1, 2001

By E. W. Murbach

The oxidation of uranium carbide by oxygen at various pressures, and by air, has been investigated at temperatures up to 600°C. Arc-melted and cast uranium carbide displays oxidation behavior that appears to be dependent on its treatment after melting. ccReactive" uranium carbide, which results from exposure of freshly melted material to laboratory air, ignites in oxygen at about 275° to 350°C depending on pressure, and in air at about 350°C. The product of the initial oxidation appears to be UO2+.. Continued heating produces U30,. The initial oxidation rate is poportional, roughly, to the square root of the oxygen pressure. The activation energy determined for the initial oxidation reaction is 7.1 kcal, from 400° to 600°C in 10 mm of oxygen. AN investigation of low-decontamination methods for reprocessing uranium carbide reactor fuels is being carried out at Atomics International. One of the reprocessing cycles includes oxidation of the fuel at relatively low temperature (300° to 500°C) and reaction of the product oxide with carbon at elevated temperatures (above 1500°C) to produce uranium carbide. A number of small-scale experiments have been carried out in which uranium carbide was oxidized in air and oxygen at various pressures to measure reaction rates and to obtain other information concerning the oxidation process. In initial experiments with arc-melted UC, ignition was observed at about 275°C in oxygen or 350°C in air. However, similar experiments by Neymark' at 426°C in air showed no ignition. It was soon determined that the difference in oxidation behavior was due to the treatment of the UC following arc-melting. Neymark's experiments were carried out with freshly melted UC while those reported in the

Jan 1, 1963

By P. H. Jennings

Commercial tellurium commonly contains heavy basemetal impurities such as lead, copper, iron, etc., as well as selenium and oxygen. The base metals may be removed by vacuum distillation or by zone melting. Vacuum distillation is a convenient method for treating moderate quantities (~ 100 kg.) for the production of a material having a total content of heavy metals in the 10-30 ppm range. By zone melting, it is possible to lower all the heavy metal impurities tm below the limits of spectrographie detection. Neither vacuum distillation nor zone melting is effective for the removal of selenium, but treatment of molten tellurium with hydrogen converts selenium to hydrogen selenide. This procedure is too s low to be considered except as an adjunct to zone melting. In the course of air-melting, many of the more easily oxidized impurities form a dross and may thus be readily removed. Substantial refinement with respect to iron, tin, chromium, aluminum, sodium, silicon, magnesium, calcium and manganese can be achieved in this way. Although tellurium can be electrodeposited from either acid or alkaline solutions of the dioxide, various factors militate against successful electro-refining, amongst which may be mentioned the brittleness of cast tellurium anodes and the tendency for the metal to be deposited in dendritic form, even at low current densities.

Feb 1, 1966

By P. H. Jennings, J. C. T. Farge

Commercial tellurium commonly contains heavy base-metal impurities such as lead, copper, iron, etc., as well as selenium and oxygen. The base metals may be removed by vacuum distillation or by zone melting. Vacuum distillation is a convenient method for treating moderate quantities ( 100 kg.) for the production of a material having a total content of heavy metals in the 10-30 ppm range. By zone melting, it is possible to lower all the heavy metal impurities tm below the limits of spectrographie detection. Neither vacuum distillation nor zone melting is effective for the removal of selenium, but treatment of molten tellurium with hydrogen converts selenium to hydrogen selenide. This procedure is too slow to be considered except as an adjunct to zone melting. In the course of air-melting, many of the more easily oxidized impurities form a dross and may thus be readily removed. Substantial refinement with respect to iron, tin, chromium, aluminum, sodium, silicon, magnesium, calcium and manganese can be achieved in this way. Although tellurium can be electrodeposited from either acid or alkaline solutions of the dioxide, various factors militate against successful electro-refining, amongst which may be mentioned the brittleness of cast tellurium anodes and the tendency for the metal to be deposited in dendritic form, even at low current densities.

Jan 1, 1966

By A. Alonso, J. Daubenspeck

In the nickel extraction process at Nicaro, Cuba, dried and ground nickel bearing laterites are reduced at 1300-1400F in multiple-hearth furnaces. Nickel is leached from the reduced ore by aeration in an aqueous solution of ammonium carbonate. Nickel carbonate is precipitated from the liquor and calcined to yield nickel oxide. The following are the more important modifications of the Nicaro process since plant rehabilitation and expansion. Ten percent increase in tonnage was achieved without decreasing the fineness of the ore by minor mechanical modifications of the grinding plant. Another five percent increase in tonnage was attained by intentionally overloading the ore prepration and leaching circuits in an effort to control cobalt extraction. Modifications at the sintering plant allowed it to handle the entire output of the expanded plant. A fifty percent increase in leach liquor cooling facilities alone provided an increase in nickel production of five percent. Stronger fresh leach liquor for increased nickel washing efficiency was obtained through improved distribution of water to the ammonia absorption towers. Advantage was taken of the reduced calcine's capability to precipitate cobalt, and modifications in the leach liquor circulation provided controlled cobalt solubility with minimum harm to nickel extraction. Several process changes at the drying plant brought about a ten percent reduction in the fuel oil consumption at this pint. Controlled air addition to the reduction furnaces' upper hearths burned formerly wasted combustibles thereby reducing oil consumption by twenty percent. The nickel extraction process successfully emplayed on the extensive but lowgrade lateritic ores of Eastern Cuba at the U. S. Government owned Nicaro plant, has been previously described in various publications. The large mine and plant operated by the Nickel Processing Corporation, located on the northeastern shore of Oriente Province, have been recently expanded to a yearly capacity of about 50 million pounds of nickel. Essentially, the operation involves open pit mining of a limonite-serpentine ore mixture containing 1.3 to 1.4 percent nickel and 34 to 38 percent iron. The comparatively lumpy, wet (25 to 30 percent moisture) ore is first dried and ground prior to chemical treatment, to which the entire 7,000 tons per day feed must be subjected. In the initial chemical action the dried and ground ore is reduced with carbon manoxide and hydrogen at 1300-1400° in multiple-hearth furnaces. The resulting metallic nickel is selectively leached from the reduced calcine by aeration in an

Jan 1, 1961

By Per Svedensten

One of the most significant behaviour of a crushing plant is the constant variation in the process. The variation is caused by two major effects. The first and constantly changing is the rock material properties. During operation rock material with different strength and particle size distribution is fed to the plant which makes the performance of the equipment to vary. The second and more slowly changing variation is caused by wear on the processing equipment. These effects must be predicted in order to be able to optimise a crushing plant. This paper demonstrates how Monte Carlo simulation can be utilised to study and operate crush-ing plants. By introducing Monte Carlo simulation the varying process can be study and also optimised. To maintain the optimised process performance supervision is needed. This paper demonstrates how results from the Monte Carlo simulation can be utilised for process supervision. Charts for process measurements can for example be derived. These can then be used to guide decision making and understand how the variation and performance of the plant changes over time.

Jan 1, 2014

At Bulong, the mineralised (>0.8 per cent nickel) ore exists within numerous lithologies, which can and do occur coincidently. It is very important to discriminate between the different host units for estimation purposes, stockpiling and scheduling. This allocation of host unit has relied upon visual interpretation by the geologist recording the information, which can be very subjective by its nature. By using quantified constraints, such as assayed magnesium oxide and iron, the subjectivity of describing the host material of nickel laterite ore is reduced. The constraints permit consistent identification of the various host units, which improves the confidence in the overall estimation and scheduling of the ore.

Jan 1, 2000

By Tony Robles

"A new process is disclosed for the recovery of gold and/or silver values from activated carbon wherein they are adsorbed as cyanide complexes. A unique chemistry allows the new process to use mill process water containing an inexpensive, non-hazardous compound as the eluant. The new process has an elution period of 5 hours at 98°C. The gold in the eluant can be recovered by electrowinning or zinc precipitation. The new elution process is simple, reliable, and provides an eluted carbon that may not require thermal regeneration before reuse. Retrofitting the new process to existing processes such as Zadra, Anglo, and others will not require significant capital expenditures.IntroductionThe efficient and reliable elution process for gold/silver from activated carbon is a very important process in the gold mining industry. The most common techniques for elution of gold cyanide from activated carbon are the Zadra and Anglo procedures.Specialized elution techniques like the Micron and Acetonitrile processes have not been commercialized to significant extent probably due to relatively complex unit operations and expensive reagents.Important functions of the gold recovery circuit are:Efficiently recover gold/silver from the loaded carbon.Carbon is in good condition for reuse for optimum recovery.The pregnant solution is amenable to electrowinning or zinc precipitation to recover gold/silver from the solution.The whole process to be simple and short to reduce gold inventories.Present Elution ProcessesTable 1 shows some carbon elution processes that are available today. The two main elution processes used in the industry are: (1) the Zadra process, in which hot cyanide solution is circulated through an elution column and electrowinning cells; and (2) the Anglo American Research Laboratory (Anglo) process, consisting of a pretreatment step with caustic cyanide solution, followed by elution with deionized water."

Jan 1, 2000

By Peter Jackson

Over a quarter of a century ago a New Zealand physicist suggested the possibility of detecting coal seam discontinuities by a seismic method carried out underground in the mine workings (Evison 1955). Twenty years ago initial experiments were performed in Germany (Krey 1963). Since then research has continued, notably in Britain and Germany, in order to provide a reliable fault and washout detection system. The National Coal Board of Great Britain has now carried out more than 250 surveys in Britain, France and Australia. The first NCB survey in the U.S., a successful application of the technique to an Ohio coal seam, will be described and the strengths and limitations of the method explained.

Jan 1, 1984

Synthetic hollow microspheres have demonstrated reliable sensitization and detonation characteristics in industrial explosives for almost two decades. During that time, water gel formulations and use conditions have changed. The introduction of emulsion explosives has also dictated technical improvements in microsphere sensitizers. In contrast to microspheres, gassing or other sensitizing techniques often cannot satisfy the manufacturing and blasting characteristics required of today's explosives. This paper discusses the sensitizing properties of microspheres, formulating guidelines and quality considerations. Packaging, sampling, transfer, metering, mixing and pumping information is also provided.

Jan 1, 1990

By A. Andreas Hejja

Flow of slag and settling of matte in slag resistance electric furnaces are discussed in conjunction with furnace geometries, stirring action of the electrodes, buoyancy and electromagnetic effects. The rectangular electric furnace was regarded as a channel reactor and the mode of slag flow as a channel flow. The flow is affected both by buoyancy and electromagnetic forces, however the effect of electromagnetic forces is minimal. The flow velocity is made up of two components; (i) that developed by the action of the electrodes, and (ii) the bulk flow velocity determined by the smelting rate and the volume of the reactor. Slag samples were taken from various depths of the molten bath and were analyzed microscopically to determine the size and distribution of matte particles, The action of the electrodes was described by a simple mathematical formula indicating a balanced settling rate in the area of electrode action.

Jan 1, 1996

By P. V. Golde, R. A. Poole, G. R. Baiden

"INCO is committed to proceed into the next century using automation and robotics to achieve safety and productivity goals necessary to enhance its competitive position. Stobie Mine, decades old, is the first of its mines to change from labour-intensive to automationassisted techniques. This paper is a synopsis of the progress made during the transition period including overviews of some of the projects as well as some of the difficulties in the assimilation of the technology. BackgroundThe ObjectiveThis paper is an update on remote control and LHD automation installation at Stobie mine. The communications system installed at the mine and the ability to remotely control underground equipment from surface is reviewed (Poole et al., 1996, 1997). It discusses some of the experiences and processes required to further the concept to consolidate the operation of multiple machines under a single operator. It considers the communications systems requirements and their focuses, particularly on the development of systems for the tele-operation of LHDs and drilling machines from surface."

Jan 1, 1998

By Evan Smart, Andrew Palangio, David Klingspor, Blessing Taiwo

This study presents a DMAIC-based approach to optimize blasting performance and achieve crusher-compatible fragmentation at the Walker-Severn Quarry in Ontario, Canada. By applying the Six Sigma DMAIC (Define, Measure, Analyze, Improve, Control) framework, the study aims to enhance the integration between blasting and primary crushing operations. Several representative blasts will be simulated and evaluated using both aerial and terrestrial image analysis technologies to assess fragmentation characteristics. The investigation was guided by quarry-specific Key Performance Indicators (KPIs), ensuring that blast design modifications were both practical and operationally relevant. Through structured analysis and data-driven refinement of blast parameters, the study reveals how this framework was used to address the quarry production demand for increased crusher throughput, and reduced processing costs. The existing quarry blast design was assessed as a baseline and compared against the crusher's inlet requirements and the acceptable fines level specified by the quarry. This evaluation aimed to identify and implement modifications to enhance blast performance. A drone (UAV) was employed to capture post-blast images and monitor blast pile displacement. These UAV images were used to generate an orthomosaic image, which was analyzed to assess fragmentation. The orthomosaic was overlaid onto a GIS platform using a 10m-by-10m grid to evaluate fragmentation distribution across the bench and identify areas requiring optimization. Additionally, drone imagery was utilized to monitor the impact of each blast on the subsequent blast's free face and to assess energy utilization for optimizing front-row holes to achieve improved fragmentation. The outcomes of this research offer a replicable methodology for continuous improvement in quarry blasting practices, with a focus on producing fragmentation that aligns with primary crusher requirements.

Jan 26, 2026