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By C. E. Corson

THE experiments of which the results and significance are set forth in this paper do not by any means cover the whole subject of the heat-treatment of the material referred to, yet they constitute a contribution to that general subject, rather than to the special department of annealing. The material here considered is acid open-hearth steel, containing from 0.50 to 0.80 per cent of carbon, with a nearly uniform percentage of other elements. This class of steel is rapidly increasing in commercial importance. It is even rumored that the rail-specifications of some railroads will hereafter require open-hearth steel. Yet this particular grade seems to have received less study and description from the standpoint of the metallographist than many others. The investigation here described was directed to the following points:-Steel containing about 0.50 per cent, of carbon : 1. The structure as related to the temperature, at the same rate of cooling; 3. The structure and physical properties as related to temperature at different rates of cooling; 3. The structure and physical properties as related to different finishing-temperatures and different rates of cooling; 4. The bearing of these observations upon the statement of Prof. Albert Sauveur.1

Sep 1, 1906

By Mingfei He, Jianhua Chen, Yingchao Liu, Yuqiong Li

Pyrite is one of the most common sulfide minerals on earth, which is usually grown with chalcopyrite and other sulfide minerals. In flotation practice, pyrite from different mines or different sections in a same mine may have different flotation behaviors. This is because the pyrite crystal contains lattice defect, including ionic vacancy and lattice impurity. The present work investigates the effects of three typical 3d transition metal (Co, Ni, and Fe) on the adsorption of CH3OCS2 −, OH−, and CN− on pyrite surface by density functional theory (DFT) calculations. Calculated results show that Co impurity reduces the adsorption energies of CH3OCS2 − and CN− on the surface of pyrite, while Ni and Cu impurities significantly increase the adsorption energies of CH3OCS2 − and CN− on the surface of pyrite. Co impurity has small influence on the adsorption of OH−, but Ni and Cu impurities significantly increase the adsorption energies. Calculations on Mulliken charge population of Co2+, Ni2+, and Cu2+ indicate that the Mulliken charges of Co2+, Ni2+, and Cu2+ after OH− adsorption are more than those after CN− adsorption. This suggests that the ionic property of the M-OH- coordination bond is greater than that of M-CN- coordination bond, while covalent bonding of M-CN- coordination bond is greater than that of M-OH- coordination bond. The adsorption results are discussed based on coordination field theory (CFT).

Oct 6, 2020

By Jasper L. Stuckey

GEOGRAPHICALLY, North Carolina consists of three divisions, the coastal plain on the east, the piedmont plateau in the center, and the Appalachian mountain region on the west. Geologically, the State may be divided into two main divisions, an eastern or coastal plain region, and a western or piedmont plateau and mountain region. The eastern region is underlain with unconsolidated sands, clays, marls, and shell limestones varying in age from Cretaceous to Recent. The western region is, in general, underlain with gneisses, schists, slates, sheared volcanics, and igneous intrusives of Pre-Cambrian age. In the mountain and upper piedmont portion of the western region are several areas of irregularly metamorphosed sediments of early Paleozoic age. Throughout the piedmont plateau and a part of the mountain portion of the western region, important areas are underlain with igneous intrusives of late Carboniferous age. Along the eastern edge of the piedmont plateau are two narrow belts, trending northeast-southwest, underlain with sediments of upper Triassic age. Although North Carolina contains a

Jan 1, 1947

By J. B. Dilworth

OUTCROPS of coal have bees discovered is many localities is the Philippine archipelago, and practically all of the larger islands contain deposits of this mineral. Very little prospecting has been done to determine the value of the various coal-bearing areas, but so far as known, the largest and most promising fields are found : (1) is northern Cebu; (2) is the small island of Batan, a part of the province of Albay is southeasten Luzon; (3) is the somewhat larger island of Polillo, off the east coast of Luzon, and (4) is southern Mindoro, sear the small coast tows of Bulalacao. Northern Panay, south-central Cebu, and various localities is southern Luzon, Masbate, Negros, and Mindanao also afford evidences of the existence of coal-beds, the extent and value of which have not yet bees proved. The general position of these islands and districts is shows on the map of a portion of the Philippine Islands, Fig. 1. Some of these coal-fields have been known for many years (coal was discovered is Cebu 1827 and is Batas is 1842),1 and several futile attempts were made by the Spaniards to operate mines is these districts. But owing to many circumstances, chief among which were indifferent management, the political unrest of the islands, natural difficulties of transportation, and those inherent in the mining of steeply-inclined and somewhat irregular seams, no considerable output was ever obtained from any of these mines, and the fuel required is the many departments of industrial and political life has continued to be drawn largely from Australia and Japan. These conditions exist to a great degree at present, and though much interest is the coal-deposits of the Philippines

Jan 1, 1909

By HERBERT G. MOULTON

FROM prehistoric times to our own day man has struggled against extremes of climate. Human life, originating in semi-tropical or temperate areas, was unable to progress into the northern latitudes until fire was discovered and some form of clothing provided. It was found possible to maintain life even in the hottest parts of the tropics, but only at a great sacrifice of comfort and efficiency compared with the more temperate zones, or in cooler areas with the protection of clothing and artificial heat. It was no accident, but the natural result of climatic conditions, that efficiency became the greatest and civilization the most advanced in areas where the natural climate was favorable, or in cooler zones where protection against severe cold could be se-cured by relatively simple methods of conserving or producing heat.

Jan 1, 1933

By Armin W. Stuedlein, Steven R. Saye

The differences between calculated axial pile capacity and the capacity realized during and following installation has long presented a significant concern for foundation engineers and contractors. Such differences have increased in prevalence with the increased use of larger diameter steel pipe piles and the significant increase in design-build contracting. The writers present concepts to close the gap between calculated axial pile capacity and the capacity realized during and following installation of driven pile foundations, including: (1) pile set-up in plastic soils, (2) limitation of re-driving of piles after setup which serves to reduce pile capacity, (3) the use of a vibratory hammer to install piles in cohesive soils disturbs the supporting soils and reduces the pile side resistance capacity significantly, and (4) long pile installation times for open-ended piles can damage the pile side resistance. Examples are presented from practice to illustrate these concepts and to guide pile installation planning to recognize the installation impacts and either consider alternate installation approaches or to properly consider the installation impacts during design.

By James F. Davis, Matthew A. Conte, Robert F. Tonning

This is a paper demonstrating the steps taken to combine multiple types of piles for a single site to maximize the benefits and characteristics of each method. We intend to discuss the use of grouted displacement piles in lieu of traditional pile types that were specified on an individual project. We will show how implementing this alternate pile type can both supplement and replace the originally specified pile to increase efficiency and lower costs. We will demonstrate a reduction in spoils, vibration, crew hours, and equipment size while employing methods to overcome unforeseen ground conditions.

By Liao Jianfeng

The Baosteel Zhanjiang 5,050m3 blast furnaces have been built with highly independent integration and innovation technologies and represented the state of the art of the world’s huge BFs. The proper of BF1 and BF2 is designed with long-campaign technology; both BFs share the same set of stockhouse, water and PCI systems; the BCQS serial-hopper no-bell top, TRT and blower are all local equipment as applied; four top-combustion stoves systems are matched; the BFG is cleaned by fully dry process; and the automation control system for the main process is self integrated. The BFs have been started up and performing with sound indicators. Their smooth proceedings symbolize China’s huge blast furnace ironmaking technology ascending a new high.

Oct 30, 2017

By H. W. J. P. Neomagus, R. K. K. Mbaya, J. R. Bunt, N. T. Leokaoke, N. W. Makgobelele

Silicon Smelters consumes more than 80000 t/a of wood-derived charcoal as carbonaceous reductant in the production of silicon metal. More than 10% of this material is discarded as fines (<6 mm) generated due to abrasion during processing. Charcoal fine residues (<650 μm) and polyvinyl alcohol (PVA) binder were used in this study to produce mechanically strong charcoal briquettes for metallurgical application as carbonaceous reductant. The PVA binder was added in mass percentages of 1, 3, and 5 wt% to the charcoal fines. The compressive strength, abrasion resistance index (ARI), drop shatter resistance (SRI), and water resistance index (WRI) were measured as functions of curing for up to 7 days under atmospheric conditions, and the results compared with metallurgical grade coarse charcoal. The ash content of the produced briquettes was found to be high (6.6–8.0%) compared with the coarse charcoal (1–3%). The 3 and 5 wt% PVA-bound briquettes were found to be the strongest, with compressive strengths of 40 and 115 kg/cm2 respectively, with WRI values of 75 and 73% respectively. The produced briquettes were found to have lower ARI and SRI values compared to the coarse charcoal. Future work should include beneficiation of the fine charcoal discards prior to briquetting, and an increase in binder addition to above 6 wt% to improve the ARI and SRIn.

May 1, 2021

By R. L. Setsepu, S. O. Bada, J. Abdulsalam

The utilization of biomass as a solid fuel for co-firing has received great attention from boiler manufacturers as a clean coal technology (CCT) option. This research aimed to produce biocoal pellets, as a clean energy fuel, using hydrochar from trees planted to rehabilitate acid mine drainage (AMD) water and fine coal discards. The hydrochar was synthesized by hydrothermal carbonization of Searsia lancea harvested from AMD-contaminated land at a temperature of 280°C and a residence time of 90 minutes. It was blended with discard coal (–1 mm) at ratios of 25% and 50% hydrochar to produce different forms of solid pelletized biocoal (BC). The physicochemical and mechanical properties of each of the biocoal pellet blends were determined. The 100% hydrochar had the highest calorific value of 29.99 MJ/kg, while the raw discard coal had a calorific value of 16.73 MJ/kg. The ash content decreased from 42% in the discard coal to 25% in the blend of 50% coal and 50% hydrochar biocoal pellets. Biocoal pellets comprising 25% hydrochar and 75% discard coal (BC25 HC/75 COAL) displayed the best mechanical properties (compressive strength 3.06 MPa) of all the fuels, but the physicochemical properties were inferior to the BC50 HC/50 COAL pellets. This research has demonstrated that hydrochar synthesized from a tree species planted for hydraulic control of AMD has the capability to act as a binder for improving the mechanical properties and energy characteristics of fine discard coal.

Dec 1, 2021

By R. M. Mashishi, T. Malehase, O. J. Okonkwo

The concentrations of selected trace elements (As, Cd, Hg, and Pb in run-of-mine (ROM) coal, discard, and coal product were investigated to assess the efficiency of beneficiation in reducing trace element concentrations and ascertain any implications regarding environmental compliance to regulatory frameworks. Samples were collected from a colliery in Mpumalanga Province twice a month for a period of 24 months. The samples were ashed to approximately 0.21 mm, then digested in a mixture of 70% HNO3 and 40% HF and analysed using inductively coupled plasma-mass spectrometry (ICP-MS). Except for Pb, the mean concentration of all elements decreased from the ROM stage to the coal product stage. The order in which trace elements occurred from the highest to lowest throughout the production chain was Pb>As>Hg>Cd. With the exception of Cd, the mean trace element concentrations in the discard were above the total concentration threshold (TCT) set for landfill disposal. The As, Hg, and Cd concentrations in the product were well below the thresholds for all land uses. However, Pb concentrations in the product coal were above legal limits, which is of concern with regard to environmental compliance and the performance and marketability of the product.

Dec 13, 2023

By K. Barani, F. Moradpouri, M. Godarzi

A sampling campaign carried out on the lead flotation circuit at Lakan lead-zinc processing plant demonstrated that the Pb recovery was only about 68-69%. Characterization of the Pb flotation tailing showed that 61.4% of the Pb is in the –37 μm size fraction, which is difficult to recover by flotation. Batch flotation experiments were carried out on a plant sample of the lead flotation feed and high-intensity conditioning (HIC) was used to improve flotation recovery. The results showed that increasing the collector conditioning time from 1 to 3 minutes significantly increases the Pb recovery from 42.5% to 57.3%. Further increases in conditioning time to 5 to 7 minutes decreased the Pb recovery. With a collector conditioning time of more than 3 minutes, due to the surface cleaning effect, increasing collector and frother dosage improved the flotation selectivity and recovery, even at higher collector dosages. The Pb recovery increased from 69.1% to 79.8% with increasing impeller speed from 600 to 1250 r/min. HIC increases the flotation kinetics and greatly improves the flotation recovery and concentrate grade.

Apr 2, 2022

By Teuku A. R. Putra, Patrick R. Taylor

Various pyrometallurgical methods for treating copper concentrates that contain appreciable arsenic are reviewed. Various aspects of the engineering of these treatment methods are discussed. The methods discussed include: complete oxidation with arsenic fixation; selective volatilization of arsenic; acid baking, soda ash roasting, and others methods. Methods for the ultimate disposal, or marketing, of the arsenic are discussed.

Jan 1, 2014

By D. D. Aksenova, V. A. Ignatkina, L. A. Samatova, A. V. Lygach, E. D. Shepeta

Calcium minerals such as scheelite, phosphate, apatite are valuable minerals, which have similar flotation properties to the calcium gangue minerals. An additional problem is the fine dispersion and close mineral association of valuable and other minerals. Low polar compounds (non-ionic surfactant), such as fatty iso alcohols, neonol and phosphol, and their combinations with sodium oleate have been studied using flotation of monominerals and ore flotation; ATR IR spectroscopy and TEM for study surface of minerals; UV spectroscopy for control solubility, aggregation and de-aggregation processes. Increase in solubility of fatty acid collectors was confirmed by low soluble (heteropolar) compounds. Oxyethylated esters of phosphoric acid are adsorbed on phosphorite by -O2PO2R2 and on other rock minerals by donation of OH bond. Same effect shows difference of adsorption of fatty iso alcohols on calcite and scheelite. The different forms of adsorption of ionic and nonionic compound on a sparingly-soluble mineral surface creates distinction of the flotation kinetics and technological balance of ore flotation. The results of the separation of flotation of scheelite from calcite depend on the order of pouring into pulp of fatty iso alcohols and oleate, and their ratio in the mixture. Increasing scheelite recovery into rougher scheelite concentrate by 3.6% for both the flotation and sludge classes was obtained. Calcite recovery varied slightly upwards or downwards by 0.8-2.4%. The use of the non-ionic surfactant phosphol in combination with a fatty acid soap allows for obtaining a phosphate concentrate with more than 28% P2O5 content and almost 80% recovery in flotation operation. It is not obtainable with other reagent regimes. Keywords: Flotation, calcium minerals, oleate, fatty isoalcols, neonol, oxyethylated esters, adsorption

Jan 1, 2020

By G. Akdogan, T. P. Kekana, Q. G. Reynolds

The DC arc plasma gasifier concept is currently under development at Mintek for testing the feasibility of producing syngas from waste coal fines and dry steam. The technology is intended for the valorisation of low-grade discard coals into market-quality syngas, which may then be used for largescale electrical power generation to address current grid supply challenges in South Africa. Other potential applications include feedstock for petro-chemical plants, fuel for transportation vehicles, domestic and industrial heating, and others. The proposed concept of a DC arc plasma gasifier was developed based on a plasma torch, metallurgical-based and entrained flow coal gasifiers. The principles of design and operation of the proposed gasifier are based on the concept of the Westinghouse Plasma Corporation (WPC) gasifier where the torches are substituted by graphite electrodes from which electric arc plasmas are generated. The DC section of the gasifier will be designed considering Mintek’s experience in the sealing of the furnace as carried out in the Mintek Thermal Magnesium Process. As part of the building blocks of a full conceptual design, the feasibility of the DC arc plasma gasifier was investigated through testing and modelling of its critical elements as proof of concept. The main activities of this work included pilot scale evaluation of the arc behaviour in the presence of dry steam, modelling of the temperature distribution within the reactor and explosibility studies on three different coal dust samples. Keywords: DC arc plasma gasifier, explosibility index, lower explosion limit, minimum ignition energy

Jan 1, 2020

By C. Bergmann, V. Ross

The concept of underground ore processing, in which valuable ore and waste are separated at a coarse particle size to improve the economics of operations and minimise the environmental impact, seems attractive from a sustainability perspective. Perceived benefits of such an operation include energy and cost savings due to a reduced hoisting load, a reduced footprint of surface operations, and using material for backfill that has not been contaminated by process chemicals. Progress in the South African mining industry in this area has however been below expectation, and opportunities for underground processing in deep, narrow reef operations were therefore explored by an Excel-based simulation with sensor-based sorting (SBS) as concentration technology. Various PGM mining scenarios incorporating factors such as the mining rate, depth of operation, and effects of dilution and particle size on the metallurgical efficiency, were compared. Whilst these initial results can be regarded as indicative only, they have shown that the economics of such an operation are driven by selective mining at significantly higher rates than achievable with conventional methods. Also, the cost of preparing, conveying and placing rock backfill will need to be lower than that of hoisting waste and depositing it on a surface dump. Another aspect to be addressed is whether ore sorting machines would be able to operate under harsh conditions underground and what provision would need to be made to ensure their efficient operation. Further investigations should focus on refining costs, incorporating environmental considerations in the modelling of economics and sustainability, and compare greenfields with brownfield scenarios. Keywords: Ore sorting, hoisting, backfill, mining rate, economics simulation

Jan 1, 2020

By Nishit Patel

Development work on the use of plasma torches in blast furnace ironmaking was completed in the 1980s. The technology developers planned to reduce blast furnace coke consumption using electrical energy and large scale coal injection through the tuyeres. Since this time, Westinghouse Plasma Corporation has improved torch reliability with industrial experience in solid-waste-to-energy facilities, as well as metallurgical applications. As coke makes up one-third of the hot metal cost, savings efforts frequently seek to lower coke consumption by increasing process efficiency or replacing coke with cheaper fuels. Alter NRG and Hatch assessed the merits of using plasma torch technology to superheat the hot blast. Coke rate savings, electrical purchase requirements, and a financial analysis to implement the torches are presented.

Aug 17, 2017

By M. A. Mekicha, M. B. de Rooij, C. Pelletier, D. T. A. Matthews

One of the main factors that reduce strip cleanliness are iron fines, which are formed due to the abrasive interactions of the roll surface and the strip in the roll bite during cold rolling. They can cause a problem in fouling of the cold rolling mill as well as downstream processes. It has been repeatedly observed that chrome plating the work roll improves strip cleanliness. In the present work, scratch tests and reciprocating sliding tests were carried out under lubricated conditions to explore the influence of chrome plating on iron fines formation. Scratch tests were conducted to study the influence of chrome plating on iron fines formation at single asperity scale due to its intrinsic property. Reciprocating sliding tests were performed to study the influence of chrome plating a rough surface on iron fines formation, taking into account the initial roughness. The scratches made using chrome plated pins showed lower friction, generated less iron fines and exhibited lower material transfer. Reciprocating sliding tests done using the uncoated pins showed galling at different sliding distances depending on the roughness of the pin. On the contrary, reciprocating sliding tests with the chrome plated pins exhibited no galling irrespective of the roughness.

Oct 1, 2019

By S. C. Schmelter

The destabilizing effect of water pressure on rock mass stability is examined quantitatively by the finite element method. A coupled code that accounts for the simultaneous effects of rock mass deformation and transient fluid flow is used for this purpose. The traditional soil mechanics assumption of an incompressible fluid is shown to be untenable for the analysis of porous, fractured rock slopes. A Mandel-Cryer effect, a transitory but elevated and potentially destabilizing water pressure following a cut, was not observed.

Jan 1, 1997

By E.C. Jong

Resumen ¦ Un sistema de comunicaciones “a través del suelo” (TTE) comercial y disponible fue evaluado en una mina de carbón subterránea en la zona Este del Estado de Kentucky. Este estudio de campo fue realizado como parte de una evaluación multisitio mayor de sistemas TTE disponibles. La mina detallada en este estudio se encontraba paralizada al momento de la evaluación, lo que proporcionó la representación más cercana a la realidad del medio ambiente en una mina luego de una operación de cierre. Para este estudio se probaron las comunicaciones superficie a subterráneo y subterráneo a superficie. El despliegue estándar del sistema TTE usando los procedimientos recomendados por el fabricante logró obtener comunicaciones claras y nítidas entre el socavón y la superficie. Otras disposiciones de las unidades arrojaron resultados mixtos. Existen planes para examinar más los fenómenos observados en esta mina.

Apr 1, 2016