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By George Rice

WITH so tremendous a subject, an attempted review of the coal situation of the world in a short talk must necessarily be of a sketchy character. It is hardly necessary to tell a body of engineers that had it not been for nature's gift of coal the material side of modern civilization would never have reached its present status. On the other side, it is regrettable that it was a byproduct of coal, T. N. T., which made possible Germany's initial success in this war, because that country had an enor-mous development of manufacturing plants that could be immediately utilized to make this destructive agent. One sometimes hears the casual remark that when the coal of the world is exhausted we shall use electricity; but, of course, electricity is ordinarily only a means of transforming and transmitting energy derived from fuel or water power, and chiefly from coal. It is true, we have much undeveloped water power, but it is more or less remote from the centers of industry; and when all shall have been developed it will not begin to supply the power requirements of the world. It is, however, reasonable to expect that before the world's supply of coal shall be exhausted, methods will have been discovered of harnessing other forces of nature, such as the tides, or the energy emanating from the sun. Petroleum and natural gas naturally come to mind, but the days of both, as fuel, appear to be numbered, although the products of petroleum, if economically used, doubtless will be available for internal-combustion engines, automobiles, trucks, and boats. for a long time, provided the reckless use of crude petroleum as an ordinary fuel is stopped. The products of petroleum are too valuable to mankind for such waste to be permitted. The civilization of the world, therefore, appears to rest, and, so far as can be seen, will indefinitely continue to rest, upon coal.

Jan 1, 1918

By Thomas E. Garnar

Zirconium and hafnium are the twin elements of the periodic table because they are always found together. They resemble each other so closely that hafnium was not discovered until 135 years after the discovery of zirconium. Zirconium was discovered by Klaproth in 1789 and isolated 35 years later by Berzelius. Because hafnium's chemical properties are so close to those of zirconium, it was not discovered until 1923 when Coster and von Hevesy detected it using X-ray spectrographic analysis. These elements occur most commonly in nature as the mineral zircon (ZrSiO,) and less commonly as baddeleyite (ZrO,). They also are found as a variety of other silicates. Zircon was identified as a component in alluvial and beach sands in 1895, but it was not produced in any quantity until 20 years later. During World War I, it was produced as a coproduct of beach sand mining for titanium minerals just south of Jacksonville Beach, FL, and was patented as a refractory. It was not until the 1930s, when Zircon Rutile, Ltd., began mining at Byron Bay on the east coast of Australia, that zircon was first used as foundry sand. Later in the 1940s, NL Industries and Humphreys Gold Corp. began production of zircon sands from fossil beaches in northeast Florida. Baddeleyite first became available as a commercial product in 1916, but never in the quantity of zircon. Zircon holds a unique position as an industrial mineral because it is used for both its physical and chemical properties and as an ore of zirconium and hafnium metals. Australia is the major zircon producer followed by the Republic of South Africa and the United States. Zircon is also produced in India, Sierra Leone, Sri Lanka, Malaysia, the former USSR, China, Thailand, and Brazil. The location of world zircon mines, baddeleyite mines, and undeveloped zircon ores are shown in [Fig. 1]. World production of zirconium mineral concentrates is shown in [Table 1].

Jan 1, 1994

By J. A. Bownocker

THE EXISTENCE of petroleum in the rocks of Ohio and Indiana seems to have been first shown by wells dug for salt. The fuel, however, was objectionable owing to its odor and inflammability. Not until the brake well was drilled in 1859 did the people appreciate the value of rock oil, and then they at once began plans to secure the coveted fuel.. The first successful well in these two states was near . Macksburg, in southeast .Ohio, where at a depth of 59 ft. (17 m.) :oil was found in commercial quantity (1860). A year later this fuel was secured on Cow Run, in the same county, and at about the same time in Noble, Morgan and perhaps other counties in that part of Ohio. The second great step in the production of oil in Ohio and Indiana was taken in 1884 when the reservoir of natural gas in the Trenton limestone of northwest Ohio was tapped, and where a year later oil was secured in the same formation. Petroleum in this limestone was obtained in Indiana in 1889.1 The third step in the production of oil' in Ohio and Indiana is associated with the Clinton sand of Ohio. Natural gas in large volume was discovered in that rock at Lancaster, in 1887, and the area has been extended until it has become the largest individual producer in the world. The presence of natural gas in such great volume all but demonstrated to the driller that-oil lay hidden near by. Soon the search for it was started but not until 1899 was petroleum in commercial quantity found in the Clinton sand, and a large pool was not located in it until 1907. The fourth step in the development of the industry was taken in 1913, when the pool in Sullivan County, in western Indiana, was opened. The producing rock is the Huron sandstone, which is the topmost member of the Mississippian system.2

Jan 2, 1920

By W. B. Hincke, C. G. Maier

Commercial processes of lead softening directly involve the behavior on fusion of mixtures of the oxides of antimony and lead, and the vapor pressures of these materials. Practically no quantitative data have been available for the discussion of lead softening from the point of view of the fundamental metallurgy of the process. The Pacific Experiment Station of the United States Bureau of Mines, in cooperation with the University of California, in the course of its program of study of the fundamental properties of oxides and sulfides, recently made vapor pressure measurements upon the various forms of pure antimony trioxide.1 When these measurements were considered in connection with the softening and "fuming" furnaces which are often used for lead purification, an unexpectedly anomalous condition appeared. In brief, this anomaly consisted in the fact that in certain softening furnaces, where lead bullion of approximately 1 per cent antimony content was being treated at a temperature of approximately 1300" F., no appreciable volatilization of antimony occurred, there being produced only a "skim" containing from 15 to 20 per cent Sb, 65 to 60 per cent Pb, as mixed oxides. In the "fuming furnaces," where the temperature was only about 1400" F. and where an accumulation of "skims" from the primary softener was being treated with certain other antimony-containing materials, a considerable volatilization of antimony as oxide occurred; an "impure" skim of some 60 to 65 per cent Sb and 10 per cent Pb was also produced as mixed oxides. The latter material cannot be suitably treated in hearth-type or softener furnaces. The essential chemical difference between the first and second step is the customary use of some reducing material (such as petroleum coke) in the later operation. An obvious interpretation of the effect of coke in facilitating the fuming of the antimony is the supposition that the antimony may be reduced to metal, and volatilized as such. This supposition is improbable, however, when it is realized that a slight extrapolation of the vapor-

Jan 1, 1932

By A. Q. Tool

THE necessity of accurate temperature measurements in the glass-making industries is today being much more widely appreciated than in the past. The introduction of the modern simplified and perfected pyrometric methods in connection with exact regulation of furnace temperatures has caused a marked improvement in the glass product with a quickened rate of production. An example of the processes in which much improvement has been and still can be made is that of annealing or heat-treating the glass. This is one of the most delicate processes in glass manufacture and one that requires a most careful furnace control. The heat treatment is undertaken to decrease the possibility of breakage and, in glass for fine optical instruments, to prevent serious warping of accurately ground and polished surfaces and to make the glass more uniform throughout to the passage of light waves. These objects are accomplished by removing all the harmful stresses that exist in a piece of glass when it has been cooled too quickly or unevenly. Such stresses exist, for example, after it has been pressed, cast, or otherwise worked. Thus the process of annealing consists of heating the glass evenly to the temperature at which it softens just enough to relieve these stresses in a reasonable time and then cooling slowly and uniformly until the glass hardens again. Accordingly, the things that must be investigated and determined in order to anneal glass without loss of time are, the annealing temperature, the time that the glass should be held at this temperature while the stresses relax, and the quickest cooling procedure that will give satisfactory results. After these characteristics of the glass are known the problem is one of pyrometry and temperature control entirely. In cases when it is known that a glass article will be required to withstand some definite type of heat or mechanical shock it is often possible, by a proper heat treatment, to produce such a distribution of the stresses in the glass that it will be enabled to resist these shocks more effectively.

Jan 9, 1919

By Dorsey Hager

DORSEY HAGER, Tulsa, Okla.-I have been asked why the Dexter region is dry. I would like to know myself. I drilled two dry wells on that same anticline which has production to, the east and west and south and north. That same anticline has seven domes that have been drilled and only three have proven productive out of the seven. In other words, you have one well-defined anticline with seven domes along its length, all mappable, all checked carefully, and only three of those seven have produced. Now why the others did not produce, I do not know. L. L. HUTCHISON, Tulsa, Okla.-There is no appreciable difference in the character or structure of the sands? DORSEY HAGER.-NO, I have never .been able to see any appreciable difference in the sands where we got production and Where we did not get it. I will say that the deepest wells we drilled, in the vicinity of Dexter, had no sands at the point where they got the production farther north. I. N. -KNAPP, Ardmore, Pa.-I first went to the Kansas-Oklahoma field in 1895 and occasionally thereafter until 1899, when I began drilling; for oil. I started close to wells that were producing gas and which, when drilling, lead made good oil showings in a sand above the gas. I thought these showings were good enough evidence of an oil pool for me without looking for any anticline and I made a paying development in what' I was afterward told by geologists was probably a synclinal trough. If I remember correctly Dr. Orton's report on the lola gas pool (about 1898) he distinctly said that he found no evidence of anticlinal structure and concluded from the records of a large number of wells that there, was a terraced structure of the productive gas sands, of which there were no surface indications.

Jan 4, 1917

By Wolfgang Pietsch

Roller presses were first invented in the middle of the 19th century, for the economical size enlargement of coal fines as fuels. Coal briquettes became quickly accepted for industrial and domestic use giving rise to a large and sucessful industry, particularly in Europe, Japan, and North America. When, towards the middle of the 20th century, coal was more and more replaced by other energy sources, such as electricity, gas, and oil, roller press manufacturers searched for alternate applications of this equipment. In addition to contemporary coal briquetting, in fields such as smokeless fuel and form-coke, it was found that redesigned and modernized roller presses, which are now capable of exerting high forces, are versatile machines for many tasks in mineral processing. Today they are used for: - the "classic" pressure agglomeration and - the "new" high pressure comminution. In pressure agglomeration, the characteristics of fine minerals are improved by forming briquettes or granulated products from compacts. During size enlargement with roller presses briquettes are directly obtained while granular materials are produced by crushing and sizing of compacted sheets. The processes are carried-out essentially dry and often do not require binders other than those inherently contained in the feed and "activated" by the high forces and/or elevated feed temperatures (e.g. hot briquetting). Therefore, no foreign materials (impurities) are added. Another advantage of the technology is, that wide particle size distributions are acceptable or desirable as feed materials, including millimeter or even centimeter sized particles. Plastic particles deform and brittle materials are crushed during pressure agglomeration. A relatively new application of roller presses in mineral processing is the utilization of the crushing effect when brittle materials pass the nip area between the rollers. It was found that this crushing mechanism is very efficient thus saving energy, particularly in grinding circuits handling large capacities. The paper introduces the fundamentals of the process and describes the design as well as applications of modern roller presses in mineral processing.

Jan 1, 1995

By Reginald S. Dean

THE widespread occurrence of manganese in low grade oxide and carbonate ores not amenable to mechanical concentration has led to extensive investigations of hydrometallurgical methods for producing a pure manganese compound suitable for further treatment. Manganese carbonate is the preferable compound. This product when fully crystalline and of not too fine crystal size is easily filtrable and stable in air. It can be converted to other compounds such as the oxides by heating in air or can be reacted with acids for producing salts. A useful hydrometallurgical process must produce relatively concentrated solutions that can be purified easily, reagents must be cyclically used, and heat requirements must be small. Neither the ammonium sulphate nor sulphur dioxide leaching processes that have been tested extensively fulfill these 'requirements. Other hereto-fore proposed processes have obvious limitations and have not been tried on a large scale. The present process is based on the discovery by the writer of a new group of aqueous manganese-ammonia complex solutions highly concentrated in ammonia, which permit rapid solution of manganous oxide to concentrations of 80 to 100 g Mn per liter and from which a fully crystalline, easily filterable manganese carbonate is precipitated by the addition of carbon dioxide and partial ammonia removal. Although the process may be carried out with many ammonium salts, commercial advantages dictate the use of ammonium carbamate, which is obtained when CO2 is passed into concentrated aqueous solutions of ammonia. If the carbamate is used, the only reagents, ammonia and C02, are volatile and may therefore be recovered from solutions and residues by heating, thus eliminating washing and extensive evaporation. Impurities are controlled easily as most metal oxides are either insoluble in the lixiviant or fail to precipitate with the manganese carbonate. Others are controlled by sulphide addition. The process has been tested extensively on a small scale on a wide variety of ores; including Three Kids, Artillery Peak, Cuyuna, and Chamberlain; as repre-

Jan 1, 1952

By Allen Garrison

IT is the purpose of this article to present. the results of an investiga-tion of certain clay and shale suspensions having viscosities that are materially influenced by fluid motion, and to discuss the bearing of these results, upon the choice of policy in the control of drilling fluids. A previous article described the design and the characteristics of an instru-ment adapted to measure the viscosity of plastic suspensions during continuous uniform motion and at a variety of speeds.1 It has long been recognized that the viscosity of a clay suspension depends on the past history of the fluid motion. Since an abundance of literature is available on this phenomenon,2 it is not necessary to describe it in more than general terms. It is usually observed that rapid motion reduces the viscosity of a clay suspension, and that some time is required for the viscosity to fall to its equilibrium value after the steady motion is started. On reducing the speed of motion to some lower value, the viscosity again rises, but it also requires some time to attain a steady viscosity value at the slower rate of motion. Thus clay suspensions are usually observed to be increasing in viscosity as time passes when the measurement has been immediately preceded by fluid motion that was more rapid than that employed in the measurement. And it is usually observed that the viscosity falls as time passes when the measurement has been preceded by more quiescent conditions. Reed,3 and Broughton and Hand4 have reported a condition of observa-tion of clay suspensions in which the viscosity was observed to fall during the first few moments of steady motion, and rise thereafter. The characteristics of the new instrument are particularly well adapted to studies of this kind. With it we have been able to observe all of the phenomena described above, and it is important to understand their nature because they all occur at some time during normal drill-

Jan 1, 1939

By J. B. Dyess, H. A. Miley

Tarnish films on some of the common metals (particularly on copper and silver) have been of much scientific and commercial concern for a long time, but before the development of the electrical method1 of measuring film thicknesses there was no satisfactory quantitative approach by which to study the separate parts of these complex films. This method has been adapted to the measurement of duplex (cuprous-cupric) oxide films on copper.2 In the present work it has been used to measure tarnish films on copper when they were mixtures of cuprous oxide and cuprous sulphide, and also when they contained cuprous oxide, cupric oxide and cuprous sulphide, each component part being measured at a different potential value. Oxide-coated copper specimens, prepared by heating copper in air at chosen temperatures for given periods, were exposed to moist hydrogen sulphide in air to forml the various oxide-sulphide films studied. The comparative resistances afforded by (I) different thicknesses of oxide films, and also (2) equal thicknesses of oxide and sulphide films, against severe attacks of hydrogen sulphide were measured. The electrical method requires that the time be observed for the cathodic reduction of each part of the film substance, and these respective time values multiplied by the constant current give the corresponding quantities of electricity expended. Then each millicoulomb per square centimeter represents a film thickness of M X 108____ 2DX 96,494 X 103 where M is weight of oxide (or sulphide) giving one gram-atom of oxygen (or sulphur) for cathodic reduction, D is density of the oxide (or sulphide) and t is the thickness in Angstrom units per millicoulomb per square centimeter. The value of t for cuprous sulphide (cubical) is 14.27, and is obtained by substituting 5.78 for D and 159.20 for M in equation a. Previous values hf t for cuprous and cupric oxides (12.36 and 6.39, respectively) were used in the present work.

Jan 1, 1939

By L. L. Wyman

The resultant embrittlement caused by the exposure of oxygen-bearing copper when hot and exposed to reducing gases has been the subject of many studies.' Little attention, however, has been given to the possible embrittling effects due to atmospheres or conditions that under some circumstances might be the source of a reducing gas. At rather infrequent intervals there occur reports of copper becoming embrittled during normal annealing cycles in commercial steam-atmos-phered furnaces such as customarily are used for this operation. As might be expected, several other factors exist—such as oil, dirt on the wire, or in the furnace, or metallic surface contacts—that might produce reducing gases and be the source of the trouble. However, in consideration of the statement made by Ruder,2 it would seem that under some conditions steam itself might prove to be the source of trouble. A consideration of the amount of the dissociation of water vapor up to temperatures of the melting point of copper shows that3 the amount of hydrogen that could come from this source is far too minute to account for any embrittlement. What such information does not tell is what will happen at the surface of copper when subjected to steam at elevated temperatures, for entirely different conditions may persist, which would account for Ruder's observation. Furthermore, there are no data as to what might happen at the surfaces of other materials present, the resultant of which might affect the condition of the copper present. For this reason, it was decided to make a series of experiments comparable to those previously conducted by the writer,' which would clarify the effect of the steam on copper, and in copper in the presence of steel. Material The material used in these experiments was tough-pitch copper wire of rectangular cross section, about % in. thick, picked at random from the regular factory production of material used for windings, etc., in the electrical industry. Chemical analysis of this material gave the follow-

Jan 1, 1940

By Sneddon J

This Is not a highly technical paper, but rather an attempt to give a general outline of coal mining for the benefit of those present who may have little or no experience in the industry, and is intended to give some general knowledge which may help to a better understanding of the problems of the industry. A knowledge of the disposition of workable material is necessary to give a comparison with other mining practices. Coal Is usually found in comparatively fiat seams of varying thickness, whereas other minerals are generally found in highly inclined lodes of variable width. However, even in comparatively flat seams unaffected by faulting, grades can, and do, vary greatly over short distances.This variation causes many local problems in working the small area affected. Even very steep seams, and some are much steeper than 1 in 1, vary considerably not only in grade, but also in direction of grade and level course. This is probably caused by folding during alteration of the shape and form of the basins after deposition.These swellies are common to most coal seams and vary only in extent. This type of variation in grade and direction of grade, while common to most ore bodies, is a matter of great importance in coal mining when it is considered that roadways are driven in the seam itself and have to be graded and made suitable for haulage purposes.The area of ground involved in an individual coal mining operation is often very large; many times larger than most metal mining propositions, and often comprises many thousands of acres.When it is considered that the specific gravity of coal may be only one-fifth of that of some ores mined, and the coal seam may be five or six feet in thickness, the vastness of the area necessary for continuous mining operations over many years will be realised.To achieve comparable outputs, with about five times the bulk of material to handle, much more ground and working places must...

Jan 1, 1947

By Orson Shepard

TEXTBOOKS on fire assaying list the following standard methods of assaying sulphide ores: (1) scorification, (2) litharge-niter, (3) soda-iron, (4) roasting, (5) combination wet and fire. The litharge-niter method has proved the most satisfactory, and is the usual method for assaying sulphide ores and concentrates. It gives good results when suitably conducted and when lead buttons of uniform size are produced so that the cupellation temperature can be properly controlled. The main objection to the method is the inconvenience of determining the amount of niter to add to each assay charge to produce lead buttons of suitable size from a set of fusions. For the assay of different materials, the niter requirement varies with the particular sulphide minerals present, the amount of sulphide minerals present, the slag composition, and the rate of heating the charge in the furnace. Except for some materials, so uniform in composition that the same amount of niter can be used in assaying all samples, the amount of niter must be determined for each sample to be assayed. This is done by either: (1) calculation from an estimate of the kind and amount of sul-phide minerals present in the sample, or (2) a preliminary fusion. Some assayers use one method and some the other. The estimation method takes the least time; but much experience is required to obtain close estimates on a wide variety of materials. At best, the sizes of the lead buttons obtained vary considerably. The preliminary fusion method usually gives lead buttons of fairly uniform size, although sometimes there is a variation because the oxidizing power of niter varies a little with the charge. This variation can be eliminated by two preliminary fusions: one to determine the reducing power of the ore, and the other to determine the oxidizing power of niter in the charge. The objection to the prelimi-nary fusion is the extra time and expense involved.

Jan 1, 1939

By J. A. Bownocker

The existence of petroleum in the rocks of Ohio and Indiana seems to have been first shown by wells dug for salt. The fuel, however, was objectionable owing to its odor and inflammability. Not until the Drake well was drilled in 1859 did the people appreciate the value of rock oil, and then they at once began plans to secure the coveted fuel. The first successful well in these two states was near Macksburg, in southeast Ohio, where at a depth of 59 ft. (17 m.) oil was found in commercial quantity (1860). A year later this fuel was secured on Cow Run, in the same county, and at about the same time in Noble, Morgan and perhaps other counties in that part of Ohio. The second great step in the production of oil in Ohio and Indiana was taken in 1884 when the reservoir of natural gas in the Trenton limestone of northwest Ohio was tapped, and where a year later oil was secured in the same formation. Petroleum in this limestone was obtained in Indiana in 1889.' The third step in the production of oil in Ohio and Indiana is associated with the Clinton sand of Ohio. Natural gas in large volume was discovered in that rock at Lancaster, in 1887, and the area has been extended until it has become the largest individual producer in the world. The presence of natural gas in such great volume all but demonstrated to the driller that oil lay hidden near by. Soon the search for it was started but not until 1899 was petroleum in commercial quantity found in the Clinton sand, and a large pool was not located in it until 1907. The fourth step in the developrllrnt of the industry was taken in 1913, when the pool in Sullivan County, in western Indiana, was opened. The producing rock is the Huron sandstone, which is the topmost member of the Mississippian system.²

Jan 1, 1921

By T. F. Bower, M. C. Flemings

The classical explanation for formation of the fine equiaxed "chill zone " in ingot solidification is that local supercooling near the chill wall causes copious nucleation in this region. This work indicates, however, that convection is an essential element in formation of the chill zone. In the absence of convection, no chill zone forms even though rate of. heat extraction is extremely vapid. Alloy studied was Al-l.5 pct Cu alloy solidified against a copper chill wall. When solidification was initiated at the chill wall in absence of. cor-vection, surface grain size was large (>I cm diam). When it was initiated in the presence of convection, it was fine (<0.05 cm diam). It is concluded that some form of "crystal multiplication" plays an important role in formation of the chill zone. INGOT macrostructures are generally classed as containing one or more of the three zones: "chill zone", "columnar zone", and central "equiaxed zone". These three zones are sketched in Fig. 1; their origin has been discussed in some detail.&apos;-&apos; The classical explanation for formation of the chill zone is that supercooling occurs in the region of liquid metal adjacent the mold wall, and copious nu-cleation then takes place in this region forming numerous small crystals. The columnar region then results by growth of favorably oriented grains (den-drites) which crowd out their less favorably oriented neighbors."5 The mechanism of the columnar-equiaxed transition has been the subject of considerable interest. The generally accepted mechanism, until recently, was that constitutional supercooling developed in front of the growing columnar grains with eventual nucleation of new, equiaxed, grains ahead of the growing solid front.&apos; Recently, it became evident this explanation was not completely satisfactory and it is now evident that "crystal multiplication" plays an important role. This crystal multiplication occurs by separation of dendrite arms from growing dendrites,8?"&apos; and has been shown to be strongly influenced by convection.6, 10-13 Reduced convection results, for a given alloy, in longer columnar zone, larger columnar grains, and larger equiaxed grains.7, 12

Jan 1, 1968

By G. E. Erdman

Gouverneur Talc produces a dry mineral filler from the tremolite talc rocks located near Gouverneur, New York. The raw material for this rock powder is a silicate rock and dust is controlled by water sprays whenever it becomes a problem underground. In the milling operation, there are some nine baghouse-type dust collectors which are utilized for the control of dust created in the crushing and grinding process. These collectors have been installed over a period of years since 1947 and are assigned to specific areas where the particle sizing of the dust can be returned to the plant circuit or product involved at the point of collection. It has been found very advantageous to mount most of these collectors on the top of the mill building and packhouses where the return of the dust can be accomplished by a gravity feed. In the years of effort involved in efficient control of dust generated in the plant, many things have been learned in the construction of ducts for control valves. The company has found useful such things as grasshopper legs for interconnecting silos with similar products, the elimination of fiat dust ducts, cleaning cyclones for coarse dust or heavy loadings, refractory linings for cyclones and certain duct areas, and the avoidance of square intersections when diverting or combining ducts. Operating cost records indicate that collectors handling the finest dust have the least expense. Operating costs on high-temperature dusts generally run higher than other types of material collected. Experience further indicates that the multiple cyclone-type collectors can provide a low cost and efficient way of removing hot dusts from process air streams before the introduction of the material into a baghouse. High moisture conditions and cold northern climates have been found to combine and create conditions under which baghouses can not efficiently function as dust collectors. Gouverneur Talc feels that its several dust collection systems have been a considerable maintenance expense but well worth the cost when it came to safeguarding the employees&apos; health and preventing air pollution.

Jan 1, 1974

By J. B. Dyess, H. A. Miley

Tarnish films on some of the common metals (particularly on copper and silver) have been of much scientific and commercial concern for a long time, but before the development of the electrical method1 of measuring film thicknesses there was no satisfactory quantitative approach by which to study the separate parts of these complex films. This method has been adapted to the measurement of duplex (cuprous-cupric) oxide films on copper.2 In the present work it has been used to measure tarnish films on copper when they were mixtures of cuprous oxide and cuprous sulphide, and also when they contained cuprous oxide, cupric oxide and cuprous sulphide, each component part being measured at a different potential value. Oxide-coated copper specimens, prepared by heating copper in air at chosen temperatures for given periods, were exposed to moist hydrogen sulphide in air to forml the various oxide-sulphide films studied. The comparative resistances afforded by (I) different thicknesses of oxide films, and also (2) equal thicknesses of oxide and sulphide films, against severe attacks of hydrogen sulphide were measured. The electrical method requires that the time be observed for the cathodic reduction of each part of the film substance, and these respective time values multiplied by the constant current give the corresponding quantities of electricity expended. Then each millicoulomb per square centimeter represents a film thickness of M X 108____ 2DX 96,494 X 103 where M is weight of oxide (or sulphide) giving one gram-atom of oxygen (or sulphur) for cathodic reduction, D is density of the oxide (or sulphide) and t is the thickness in Angstrom units per millicoulomb per square centimeter. The value of t for cuprous sulphide (cubical) is 14.27, and is obtained by substituting 5.78 for D and 159.20 for M in equation a. Previous values hf t for cuprous and cupric oxides (12.36 and 6.39, respectively) were used in the present work.

Jan 1, 1939

By E. H. Kelton

The purposes of this paper are to describe the use of adjustable cut and draw tools as a control test of drawing properties and to point out that no other well-known test or combination of tests determines this quality in zinc and zinc alloys. Rolled zinc has been used for making drawn articles, particularly battery cans, for many years. The development of rolling treatments satisfactory for these purposes followed the usual course of trial and error experimentation depending upon cooperation with customers to determine what type of material was suitable. A quick test of drawing quality was highly desirable, of course. Scleroscope hardness and temperll having no apparent relation to drawing quality, were used simply to check the duplication of rolling treatment and grade of metal. The dynamic ductility1 test, on the other hand, was believed to be so like the drawing operation as to provide a reliable index and came to be taken as the criterion of good drawing properties. Faith in this test was strengthened by the fact that metal having the highest ductility was more satisfactory for operations, such as the manufacture of battery cups, that required several redraws. No distinction was made at that time in specifying metal as to whether it was to be subjected to simple cut and draw, redrawing or forming operations. It developed, however, that in some grades of metal the highest ductility did not coincide with the most satisfactory quality when the material was used for a single draw. When zinc-base alloys, with their wider ranges of effective rolling treatments, came into increased use, their dynamic ductility and drawing quality appeared to have no connection whatever. Furthermore, comparisons of known drawing quality with other physical properties of the metal, including tensile strength, elongation and dynamic cold bends, were fruitless in yielding any clear relationship. Almost any test value produced in one piece of metal could be duplicated by another rolling or annealing treatment with attendant different drawing characteristics.

Jan 1, 1934

By George S. Rice

THE A.I.M.E. Ground Movement and Subsidence Committee, pro- posed in 1920, held its first technical meeting in February 1923, under the able chairmanship of Mr. H. G. Moulton. The following list of papers and discussions, indicating the scope of the problems and relation to various conditions and method of mining, were given at that meeting by the distinguished mining engineers: J. Parke Channing, on Subsidence at Miami, Arizona; Howard N. Eavenson, on Mining an Upper Bituminous Seam after a Lower Seam Has Been Extracted; J. J. Rutledge, on Subsidence in Two Oklahoma Coal Mines; Benjamin F. Tillson, on Caving Cracks at the Franklin Mine, New Jersey; Dr. F. W. McNair, on the Dome Theory; William Kelly, on disadvantageous effects in Mining and Back-filling Working Upward a Steep-Pitching Iron-ore Bed; Eli T. Conner, on the good results of Back-Filling by Hydraulic Means in Preventing Destructive Subsidence in the Anthracite District; Thomas H. Claggett, on the merit of Systematic Pillar Drawing in Preventing Cracks in an Upper Seam; Henry H. Otto, successful results in the anthracite district in Mining Lower Seams before Upper Seams; Douglas Bunting, on Leading Factors Incident to Successful Mining of an Overlying Seam; Edwin Ludlow, on there being "less damage to buildings when there was complete removal of coal with complete packing than when room and pillar is used without extracting the pillars"; Edward O&apos;Toole on "bumps" in eastern Kentucky mines, which he thought were the result of geologic stresses: H. A. Buehler, on Upheaval of Surface in an Illinois Case in Advance of the Face; and R. Dawson Hall, on The Mechanics of Subsidence from Mining. The author of this paper discussed various kinds of problems of ground movement and subsidence in both metal mining and coal mining; the production of great landslides by workings near an outcrop, as at Turtle Mountain, Alberta, Canada; and general

Jan 1, 1939

By D. Limpitlaw

Industrial mining in Zambia started in the 1930s when the world class copper deposits near the border with Katanga were developed. The discovery of these deposits began at the turn of the century when the first claims in the Copperbelt were pegged at Chambishi, north of what became the town of Kitwe1. World War I and the difficulties of raising sufficient capital for such large scale undertakings delayed the exploitation of these deposits. Following this hesitant start, a large copper mining complex was built, resulting in the development of five major towns, all highly dependent on the mining and beneficiation of copper and cobalt. Copper became so important to the country that, on independence, the only non-mining town to make it onto a list of the top six was the capital, Lusaka. From commissioning of the mines to the end of the colonial period in 1964, copper production increased to just over 640 000 t annually2 (see Figure 1). After the establishment of the new Zambian state, production continued to increase, supported by a benign legislative environment and strong international copper prices. The government of Kenneth Kaunda was intent on improving the conditions of the rural poor and reducing unemployment in urban areas. To this end, the government embarked on an ambitious project of refocusing Zambia&apos;s economy away from the colonial role of commodity supply to one of decentralized mass employment. The Copperbelt industrial complex was key to the success of this approach, and in 1969 the Zambian State acquired a 51 per cent stake in Zambia&apos;s two main copper producing companies: Roan Selection Trust and Rhodesian Anglo American Corporation. The former became Roan Consolidated Mines Ltd (RCM) and the latter became Nchanga Consolidated Copper Mines Ltd (NCCM). In the year they were nationalized, the mines produced at least 720 000 t of copper? and employed approximately 48,000 workers (see Figure 2)2-4. The subsequent economic policies of the Zambian Government depended heavily on the state&apos;s ability to monopolize the proceeds of copper mining.

Jan 1, 2011