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By J. E. House, J. L. Drobnick, R. R. Swanson, D. W. Agers

The paper describes an improved process for the recovery, purification, and concentration of copper values from acidic dump leach liquors. The process employs a new liquid ion exchange material (LIX® 64 reagent) capable of separating copper values from iron and other impurities common to dump leach liquors in the typical pH range of 1.4-3.0. Properties and performance of the reagent are discussed. Design scale-up information for both pilot plants and commercial installations, including preliminary economics, are presented. Economic considerations include the production of electrolytic copper from the purified copper aqueous concentrate. INTRODUCTION Since the commercial acceptance of the liquid ion exchange process in the mineral processing industry, it has been predicted that a wide selection of chemical reagents to efficiently and economically separate many metals in solution under a wide range of conditions would be commercially available. Several years ago, General Mills began a basic research and development program to determine if it were possible to develop a reagent to extract economically metallic ion from existing process streams. Progress toward reaching this objective was reported in late 1963, when development of quantities of LIX -63 reagent, a highly selective reagent for the extraction of copper, was introduced. The properties of this reagent are described in a previous paper.' The development work with this reagent indicated that perhaps the largest potential application for a copper extractant, the treatment of acidic dump leach liquors, would not be economically possible with LIX-63 because of limitations of the reagent to extract copper below a pH of 3.0. The relatively small pH adjustment required with LIX-63 would result in a significant processing cost and the undesirable precipitation of ferric hydroxide from the liquor. This pointed to the need for another copper extractant which would extract copper from dump leach liquors without pH adjustment. General Mills was successful in synthesizing a molecule which does not have the pH limitation of the LIX-63, yet possesses the selectivity-solubility properties required of a metallic extractant. The resulting LIX-64 reagent broadens the pH range from which copper can be effectively extracted and separated from other metallic impurities. Of special significance is the fact that the reagent, LIX-64 was developed by combining the technical requirements of a specific problem in hydro-metallurgy with theoretical organic and physical chemical principles.

Jan 1, 1967

By B K. Hebblewhite, F T. Suorineni, J D. Tibbett

Block caving is an underground mining method that can provide high production capacities at low operating costs. This enables the profitable extraction of massive, low-grade orebodies and attracts industry towards the method. Block caving operations require significant initial capital investment and predictable cave propagation is crucial to safety and economic success. Lack of access to observe the caving process hinders our ability to learn how the rock mass and geological structures are reacting to mining. Virtual reality scientific visualisation (VRSV) enables the integration and investigation of multiple, large caving data sets and provides a viable alternative to visualise rock mass response without physical access to the cave. Point instrumentation is incapable of providing an overview of cave performance and seismic monitoring, while providing an overview of the rock mass and the response of structures to caving, is only useful when linked to the caving activities. The integration of point instrumentation data with seismic monitoring information, coupled with scientific visualisation of the mining system in a virtual reality environment, provides a powerful means for understanding caving performance.This paper describes the use of a VRSV module at UNSW Australia, designed for investigating the block cave mining system from a case study operation. This module has been used to investigate the location and chronological evolution of seismicity to understand sources of damage resulting in seismic space-time sequences (SSTS) in the caving system. The events within an SSTS represent damage that is spatially and temporally related. An SSTS group represents a collection of microseismic events from a reasonably competent region of the rock mass that has experienced a stress change significant enough to cause sequential damage. SSTS group locations have been seen to be the path of subsequent cave propagation. Thus, SSTS analysis enables insight to further our understanding of rock mass damage in caving geomechanics through analysis of historic data. Such insight has operational potential to learn from recent rock mass activity for optimising the management of undercut advance, draw front advance and cave draw patterns.CITATION:Tibbett, J D, Suorineni, F T and Hebblewhite, B K, 2016. Understanding damage source mechanisms in a caving system using virtual reality scientific visualisation, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 439–452 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By Qi Wang, Zengzhu Kang, Jianguo Liu, Guanglei Liu

"Due to the increase of automotive vehicles, available parking spaces become a new type of limited resource in central cities of China, especially in those old districts without visionary urban planning. Additional mechanical parking in underground space is an efficient solution to provide parking spaces under the situation where the urban space is constrained. Shichahai district is an old protected zone in Beijing which is close to the Forbidden City and there are many Hutong (alleyway) and Quadrangles (courtyard house). No spaces are available for car parking on the ground and all vehicles are parking in Hutong without order currently. The local government plan to do renovation work for this district and improve the residential environment. Several innovative solutions are studied including parking in deep shafts, parking under existing buildings by under-pinned method, parking under buildings by covered excavation method, parking under roads built together with utility tunnel etc. 5000 difference types underground parking spaces are planned to be constructed in the following three years. Project examples are also introduced in this paper. INTRODUCTIONCar parking resources are very limited in central cities, especially in old districts without planning for increasing automotive vehicle volume. Traffic get worse when cars park on the side of the roads or move slowly to find parking spaces. Investigation shows the normal (parking space/ automotive vehicle volume) ratio is about 1.2 in most big cities such as New York, Tokyo and Hong Kong, while this ratio is only 0.5 in Beijing. One solution is to move cars out of central cities. But there are still huge parking requirements for the citizens living in central cities. Shichahai district is an historic protected zone in Beijing which is close to the Forbidden City and there are many Hutong and Quadrangles (refer to Figure 1 for project location). No spaces are available for car parking on ground and all vehicles are parked in Hutong without order currently. The local government had a plan to do renovation work of this district and improve the residence environment. 5000 different types of underground parking spaces are planned to be constructed in the following three years. One project designed and to be constructed by Zhongyan Technology will be introduced in this paper. Other innovative solutions will be introduced briefly as well."

Jan 1, 2017

By Richards S. M

The abundances and abundance relationships of lead, zinc, copper and silver in the major sulphide lenses at Broken Hill are examined, and their possible geochemical significance discussed.When expressed as atoms per cent, zinc is the most abundant base metal throughout the whole .group of orebodies, the highest average lead: zinc ratio (No. 2 lens) being about 0·45, the lowest (No. 1 lensZinc Lode group) being in the 0·12-0 ·14 range. Lead and silver are clearly higher in the lower two orebodies, but the abundance of zinc shows no apparent relationship with stratigraphical position. Among the base metals copper is conspicuously low and remarkably uniform, a feature noted in other conformable orebodies.Although, as has been recognised for many years, abundances of silver and lead, and lead and zinc, are sympathetically related, correlation within the pairs is variable and generally of low degree. Silver and lead show distinctly the better correlation, particularly in No. 3 lens. On the basis of lead: zinc ratios, No. 2' and No. 3· lenses, on the one hand, and the No. 1 lenses, Rhodonitic and Siliceous Zinc Lodes on the other, constitute two groups. However on the basis of silver : lead ratios, No. 3 lens stands alone, No. 2 lens showing clear affinities with the higher layers. Ternary relationships between copper-zinc-Iead and silver-zinc-Iead emphasize the very close constitutional relationship between the No. 1 lenses and the two "zinc lodes".The possible implications of these relationships are then discussed in the light of the' two principal theories-hydrothermal replacement or chemical sedimentation-held for the formation of the Broken Hill ores. It is pointed out that the ratios of the four metals in the ores are rather different from those found in most igneous and sedimentary rocks, and in seawater. For 'example, whereas copper and zinc are present in almost equal amounts in most terrestrial materials, copper in the ores is only about one-hundredth of the amount of zinc. Lead has increased somewhat, but the ratio of silver to lead has fallen; in spite of its recognition as a source of silver, the Broken Hill lode is impoverished in silver with respect to lead as compared with most common terrestrial materials.No solutions are offered to these prob'lems of abundance. Rather it has been the aim of the work to provide data, and to demonstrate the...

Jan 1, 1961

By D FitzGerald, S Jakica, R Paterson, J Silic

A new 2.5D airborne electromagnetic (AEM) algorithm has been developed by Intrepid Geophysics and Jovan Silic & Associates. The advantage of 2.5D (2D geology, 3D source) AEM inversion in 3D geological mapping applications and identification of conductive drilling targets, compared to the more commonly used conductivity-depth imaging (CDI) transforms or 1D inversions, are demonstrated using examples from banded iron formations (BIFs) and other geological settings. We show emerging AEM systems are capable of providing estimates of economic rock unit thicknesses, dips and fault definition at an accuracy that mitigates the need for pattern drilling.The 2.5D inversion application used in this work and described in Silic et al (2015) is a substantially changed version of ArjunAir (Wilson, Raiche and Sugeng, 2006), a product of CSIRO/AMIRA project P223F. The changes include a new forward model algorithm and a new inversion solver. The application enables the accurate simulation of 3D source excitation for full domain models inclusive of topography, non-conforming boundaries and very high resistivity contrasts. Solution is accurate for a geoelectrical cross-section, which is relatively constant along a strike length that exceeds the AEM system footprint.The major innovation includes a new inversion solver with adaptive regularisation, which allows the incorporation of a misfit to the reference model and the model smoothness function.Memory usage has been dramatically reduced and is estimated prior to execution. For speed the software has been parallelised using Intel message passing interface (MPI) and can be used on standard computing hardware or computing clusters. Data from survey lines with lengths exceeding 100 km can be inverted on high end laptop computers.We allow flexibility in the selection of components and in the estimation of noise.AEM inversion examples are shown for surveys from BIFs, base metals (volcanogenic massive sulfides) and geological mapping projects and the results are compared with known geology and drilling. We demonstrate the much improved mapping and target definition delivered by this inversion method when compared with the other more common transforms or inversion methods used on these projects.CITATION:Paterson, R, Silic, J, FitzGerald, D and Jakica, S, 2017. High accuracy .D airborne electromagnetic inversion method for banded iron formation and other geological settings, in Proceedings Iron Ore 2017, pp 319–330 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By H. C. Van Der Merwe

In the 21st century, dynamic, accurate digital 3-D geological models are essential to the pursuit of safe, efficient and profitable mining. This is particularly true for the deep-level underground mines in South Africa. The Sirovision® solution is a collaboration project between the Australian CSIRO (Commonwealth Scientific and Industrial Research Organisation), Datamine Software Ltd. and AngloGold Ashanti Ltd (AGA). The purpose of the project is to provide a fully integrated digital rock face imaging, geological mapping and modelling system for the AGA gold mining operations. The CSIRO-developed Sirovision® Stereo Camera Rig (SCR) consists of two digital cameras, alighting system, a laser guidance system and image processing software. The imaging system works on the principles of photogrammetry, i.e. overlaying of two 2-D images with a central focus point, with mathematical algorithms extracting 3-D information from the 2-D image pair. The output from matching several image pairs is a computer-generated, full 3-D, virtual copy of the mining excavation. The image resolution and relief ares of sufficient quality to distinguish different rock types and structural contacts. Functionality within Datamine Studio3 is used to add geological intelligence to the 3-D images provided by Sirovision®. The geologist identifies and ?draws? lines representing geological features directly onto the image. By utilizing the inherent ?topography? of the 3-D image, the software is able to convert the lines into 3-D surfaces, ready for use in the 3-D geological model. Subsequent to promising underground test results from AGA?s Sunrise Dam Gold Mine (SDGM) in Australia and other mining operations worldwide, it was decided to test the Sirovision® system in the South African deep-level gold mines. The first underground tests at Moab Khotsong Mine began in January 2009. The objectives of these tests entailed the capturing of 3-D images of selected development ends, mapping of geological features onto the 3-D images and integration of the mapping data with the 3-D geological model. Some downsides have cropped up during the feasibility testing, related to practicality of the SCR for acquisition of 3-Dimagery in the deep-level underground operating environment. These constraints will have to be addressed prior to operational implementation. Facing such difficulties is not unusual when attempting to implement new technology in such a challenging working environment and testwork is still in progress at the mine in order to prove the concept of using this technology in a Witwatersrand underground gold mine. The great advantage of the Sirovision® solution is that it offers the geologist the opportunity to work remotely on a 3-D virtual copy of a mining excavation, without the heat, humidity, hazards and time constraints associated with physical mapping in an underground workplace.

Jan 1, 2009

By B. P. Watson

The first crush pillars on the Bushveld platinum mines were introduced at Union Section in 1978. Before the introduction of crush pillars, serious problems were experienced when stoping advanced to a point 30 m to 40 m on both sides of the centre gully. At least three to four stopes were collapsing per month. The introduction of the pillars stopped the stope collapses in the mining area where they were introduced. The residual stresses of these pillars were never measured; however, the successful elimination of the ?back-break? problem suggests that the original pillars had a residual strength of at least 8 MPa. Apart from back analyses, very little work has been done to determine the residual strength of crush pillars and only very recently have any measurements been made. The lack of knowledge in this field has resulted in pillars being designed based on experience. Concerns about stope collapses, similar to the Coalbrook disaster, have led to larger pillars being cut in more recent times. If such pillars were cut in brittle quartzites they would always fail violently but the ductile nature of the Merensky Reef generally allows large pillars to fail without bursting. Occasionally, however, one would burst in a working area. Increased incidence of bursting has been reported on some mines at deeper levels but most of these bursts occur in the back areas. Nevertheless, the incidence of bursting increases the risk of falls of ground in already dangerous areas, and the larger pillars decrease the extraction ratio. This paper describes the evaluation of stress measurements conducted in two boreholes over a crush pillar with dimensions 2.5 m x4.0 m, and a height of 1.2 m. Boussinesq equations for vertical and shear stress were used to analyse the original measurements and provide a stress profile across the pillar as well as the residual strength of the pillar. The results showed an unexpectedly high peak stress of 280 MPa at the centre of the pillar and a residual strength of 48 MPa. The reason for the high residual strength is suspected to be the result of the stiff environment under which the pillar failed and the small height of the siding on the up-dip edge of the pillar. More measurements should be conducted on several mines to establish a range of residual strengths for narrow crush pillars.

Jan 1, 2008

By Richard E. Gray

Subsidence due to coal mining is poorly understood by non-specialists. This has led to numerous misconceptions and myths based on limited observations and lack of knowledge. The three most common are: 1. Mine maps are inaccurate. 2. Deep mines are not a problem. 3. If no subsidence has occurred for many years after mining, there is no risk of future subsidence. Maps are important during mining and most are carefully prepared. Future use to evaluate conditions at mine level often includes drilling to confirm what the map shows. Usually, little or no effort is made to tie the surface survey of the property to the mine survey, to conduct a well designed drilling program to confirm the mine map, or to drill test borings vertically. When a mine entry is encountered rather than a coal pillar, or vice versa, and conditions at mine level appear different than anticipated, the first reaction is the mine map is inaccurate. The idea of a safe depth from subsidence is often based on the false premise that mining results in sufficient breakup of the overlying rock strata that bulking compensates for the coal extracted. The safe depth idea first appeared in the literature about 1880 and remained prevalent well into this century. Sadly, it is still encountered. The modern understanding of fragmentation of the immediate mine roof with the overlying beds sagging down on the broken roof rock was first described in 1900. With full extraction mining, either longwall or retreat room and pillar, surface subsidence occurs regardless of the depth of the mine. Subsidence over longwall mines at depths of 2000 feet can be 90 percent of the mined seam thickness. Numerous studies of undermined sites conclude that mining occurred many years ago and since no subsidence has occurred, there is no risk of future movement. This is true if sufficient coal pillars have been left to support the overlying strata. However, every year subsidence occurs over mines that have been closed for 100 years or more. In a study of subsidence incidents over the Pittsburgh Coal, the senior authors found that 50 percent of the incidents occurred above mines that had been closed for at least 50 years and 10 percent over mines closed for at least 80 years.

Jan 1, 1996

By Scott A. Walker, Frank L. Rollo

"The San Francisco Museum of Modern Art (SFMOMA) in downtown metropolitan San Francisco, California, is supported on a mat foundation. Although the mat foundation of the original museum was designed to accommodate a future expansion, the plans for expansion that developed in 2010 required a larger footprint to accommodate the new space requirements of the museum. The new, larger expansion was designed by lead architect Snohetta. It will be a tall 12-story, steel-framed building occupying an area that was once the eastern part of the existing museum as well as two adjacent and newly acquired parcels.As designed, the expansion includes a 30-foot-deep excavation which is surrounded by adjacent buildings and improvements. Because of variable subsurface conditions at the site, geotechnical challenges included mitigating anticipated differential settlement between the existing and new foundations, preventing overstressing of the existing mat foundation, controlling groundwater to prevent settlement of surrounding improvements, and providing temporary support of adjacent structures during excavation for the new basement.To address several of the geotechnical challenges, soil-cement mixed (SMX) ground improvement was recommended by Treadwell & Rollo. However, during contract negotiations and construction, the specialty contractor proposed using jet grouting as an alternative technique for ground improvement. The jet grouting approach was accepted in principal, but when implemented was only marginally successful. Accordingly, the contractor eventually installed SMX panels using a Cutter Soil Mixing (CSM) machine. Because the CSM machine was a late arrival during construction, the contractor was not able to take advantage of the ground-improvement technique to install many of the shoring elements that we had originally recommended (such as the cut-off shoring wall). In the end, SMX panels were installed as ground-improvement beneath the new mat foundation to (1) reduce the potential for liquefaction in clean sand below the groundwater by providing increased rigidity to the soil, (2) reduce the potential for disturbing a weak underlying marsh deposit during construction, and (3) transfer vertical building loads to a layer of underlying dense sand.This paper also discusses the quality control and quality assurance programs that were implemented to check that the ground-improvement techniques used were thorough and complete and provided the required strength to transfer the new foundation loads to the underlying strata."

Jan 1, 2014

By Mark McComb, Geoffrey R. Lane

"Over the years many differing approaches have been developed to clearly understand the nature, mode of occurrence, associations and deportment of both free-milling and refractory gold in a wide variety of differing geologic environments and plant products. Many approaches can be taken to characterize the ore which may occur as complex fine grained gold, ultra-fine grained gold, coarse nuggetty gold, complex Asrich refractory gold and double-refractory gold. The approach taken in assessing small drill core composites from Novo Resources Beaton Creek Paleoplacer gold project located in the Pilbara region of Australia was complicated by the nature of the ore, the small amount of sample available from current exploration work, and the gold grade and the grain size distribution. In this case the scope of the study was limited by sample availability although significant amounts of valuable information was also gained. This gold characterization study included the following elements:??Size fraction assays??Ore microscopy??Preparation of heavy mineral concentrates from sized fractions (screening) of crushed or milled head using heavy liquids and Superpan table.??Systematic scans of the heavy mineral concentrate, middling, and tailing fractions using TIMA Automated Scanning Electron Microscopy integrated with an Energy Dispersive Spectrometry to provide semi-quantitative elemental analysis of the individual grains found in the sample.The unique methodology employed to detail the gold deportment was the combination of the Tescan Integrated Mineral Analyser (TIMA) and the Oxford INCA GSR software. This technique not only allowed us to document the deportment of gold but recognize other associated minerals, which included gersdorffite, chalcopyrite, uraninite, coffinite, brannerite and several Rare Earth-bearing minerals.INTRODUCTIONGold deportment studies are commonly carried out on preliminary gold exploration projects in order to determine the various limitations, which may effect processing of the potential ore. This is often because it may be expected that there may be a refractory component to the gold, which may limit physical separation techniques and suggest more costly hydrometallurgical techniques. Often when carrying out gold deportment studies the mineralogical methods may be limited to assuming that the gold will be fine and easily found using standard techniques of optical microscopy or Scanning Electron Microscopy. This may not always be the case as various geological environments may pose their own individual problems to determining the deportment of the gold grains."

Jan 1, 2015

Much interesting data on cemented carbides has been published over a period of years which, when classified and pieced together, gives a clear picture of this special branch of powder metallurgy. This is an attempt to present the essential information in an ordered account.THE HARD CARBIDES-THEIR PROPERTIES AND PREPARATIONThe so-called hard or refractory carbides are the carbides of a number of metals which are grouped together in the Periodic Classification. These metals are in groups IV, V and VI. They are titanium, vanadium, chromium, zirconium, niobium (columbium), molybdenum, hafnium, tantalum and tungsten. These carbides have attracted the attention of chemists because of their remarkable properties. They possess very high melting points, and are rather difficult to prepare in the pure state. Their outstanding propertyis their extreme hardness, which they share with certain other carbides, such as those of silicon and boron. In addition, these compounds possess distinctly metallic properties, such as lustre (in fused specimens) and high thermal conductivities.(l)t They are capable of forming alloys in two ways:1. With metals, particularly those of the iron group. 2. With each other (a case of solid solubility).The constitution of these substances is not that of ordinary salts, which obey the usual valency rules, but must be likened to that of certain intermetallic compounds. Actually they are "interstitial" compounds(2), that is, they are formed from the ordinary metallic lattice by the insertion of the relatively small carbon atoms in the interstices.. The energy required to fill the lattice completely is high, and this explains the difficulty often found in obtaining the exact stoicheiometric compound. Thus the carbides can have a range of composition, and can be considered as solutions of carbon in the respective metals.Physical Properties of the CarbidesThe hardness of these compounds is so great that it is difficult to compare the individual compounds on this basis. Becker(l) gives values on Moh's scale, which are not very accurate and are of no great value. Burden(3) has reproduced a diagram by Hatfield which indicates that the cemented carbides are between 1,400 and 2,000 on the Vickers diamond scale. However, the pure carbides are harder, tungsten carbide being about 2,200. Hoyt(4) describes a method of measuring hardness applicable to powdered specimenswhereby the powder is rubbed on a standard block of cemented tungsten carbide under standard conditions, and the rate of wear is determined. In...

Jan 1, 1942

By William Gleason

"What will the mine of the future look like? Will it resemble the current operations that supply the world with the products it needs to function, or will it be something totally different? How will the demands from the communities that are most affected by mining operations shape the mine of the future? How will technology and innovation be used to help miners reach deposits that are getting harder to access, and what are the dangers of this new world? Who will work at the mine of the future, and what will that work look like?These are questions that do not yet have definitive answers, but they are questions that need to be asked for the mining industry to move into a future that is as filled with uncertainty and challenge as it is with promise and opportunity.On Feb. 16, the 2015 SME Annual Conference and Expo and the 117th CMA National Western Mining Association conference began with a keynote address, "The mine of the future: Forecasting opportunities and challenges for the global mining industry." Panelists from five sectors of the mining industry participated in the session, which was followed by the conference and expo, that in large part, were also trying to answer the question of what the mine of the future will look like.In coming months, Mining Engineering will continue the discussions and answer some of the questions submitted by members of the 2,000-person audience during the keynote address in a monthly feature called, "Predicting the Mine of the Future," and in Thought Leaders Podcasts with the panelists and other industry experts."

Jan 1, 2014

By Tomek Ulatowski

This article discusses four principal areas relevant to financing direct reduction facilities: (1) Lenders' differing requirements with respect to projected cash flows; (2) The impact of leveraging on project viability; (3) The importance of appropriate debt structure; (4) The significance of accurate and complete capital cost estimates. The overall findings emphasize the inseparable connection between the project economics and its financeability, and particularly how direcly intertwined they both are in the project planning.

Jan 1, 1978

By Donald O. Capstick

In 1981, U.S. Bureau of Mines personnel conducted a survey of claims and prospects in the Wheeler Ridge RARE II area to determine if mineral resources or potential for resources exists at deposits in the area. Results of Bureau of Mines investigations indicate the area contains no identified mineral deposits. However, the geologic setting at the Round Valley Peak Prospect near the center of the study area is considered to be favorable for the discovery of tungsten resources with associated molybdenum and copper. Tungsten deposits, should they be present, would be expected to occur at depth in tactite at or near the calcareous rock-granite intrusive contact. Sand, gravel, and stone deposits in the area are not considered to be resources because equal or better quality material is available closer to major markets. INTRODUCTION The 16,200-acre (6,560 ha) Wheeler Ridge study area is 11 mi (18 km) northwest of Bishop, California, on the eastern flank of the Sierra Nevada range. The John Muir Wilderness adjoins the study area's western boundary (fig. 1).

Jan 1, 1983

By Silvio E. Kruger

Real time measurement of wear and corrosion provides crucial information needed to determine an optimal schedule for corrective maintenance and is a powerful tool to maximise equipment availability and reliability. It also leads to savings from optimized spare parts handling and helps to avoid costs of accidents and their negative impact on safety and the environment. This paper presents the technology of ?painted-on? ultrasonic transducers that can be integrated to structures and accurately measure the remaining thickness and therefore determine wear or corrosion losses. These transducers have a small footprint, a performance comparable to other commercially available ultrasonic transducers and can sustain temperatures as high as 400ºC. The application of this technology to mining equipments and its potential benefits are discussed.

Aug 1, 2013

By G. E. Walden

The Bureau of Mines is currently engaged in a continuing investigation of the thermodynamic properties of certain inorganic compounds. As a part of this investigation, the heat contents of bismuth and cerous chlorides were measured throughout the temperature ranges of 370° to 630° K. and 370° to 1,200° K., respectively. Equations representing heat contents as a function of temperature were derived from the data by the method of least squares. These equations were used to calculate heat contents at selected temperature intervals ranging from the ice point to 650° K. for bismuth chloride and to 1,200° K. for cerous chloride; also, the heats of fusion of both compounds were calculated at their respective melting points. EXPERIMENTAL Materials The cerous chloride used in this investigation was supplied by the National Carbon Company of Cleveland, Ohio. A chemical analysis indicated Ce 56.57 percent and Cl 43.39 percent. No attempt was made to purify the compound or identify impurities since the analysis showed only about 0.04 percent total impurities. Reagent grade bismuth chloride was used without additional purification.

Jan 1, 1961

By F. E. Kottlowski

Widespread high-calcium limestones in New Mexico region are low -in magnesium, but some units include shale interbeds deleterious for sulfur removal usage. Thick limestones in Mississippian Escabrosa, Lake Valley, and Leadville, Pennsylvanian Madera and Hermosa, Pennsylvanian-Permian Horquilla, Permian Hueco and Capitan, Cretaceous U-Bar, and some Cenozoic travertines are high-calcium units. Significant outcrops are in mountains of southwestern, south-central, central, southeastern and north-central New Mexico, southeastern Arizona, southwestern Colorado, and northwestern Chihuahua. Coal-fired powerplants are mainly in northwestern New Mexico and eastern Arizona, thus transport is mainly by railroad.

Jan 1, 1994

By J. Rajek

The novel multi-component, multi-particle, multi-phase precipitation model developed recently is used to predict the precipitation kinetics in complex 9-12% Cr steels investigated within the European COST 522 project. These steels are used for tubes, pipes, casings and rotors in USC (ultra super critical) steam power plants for the 21st century. In the computer simulations, the evolution of the precipitate microstructure is monitored over the entire production heat treatment starting with the casting process, including austenizing, several annealing treatments and in-service conditions. The main interest lies on the concurrent growth and coarsening interaction of different types of precipitates. Keywords: Precipitation kinetics, heat treatment, power plant steels, simulation

Jan 1, 2003

By WM. G. Heeley

This paper will describe the experience gained and explain the deductions made from the phenomenon of the great squeeze which occurred at Brule Mines. The first indication of the commencement of the squeeze was the breaking of posts on the high-side rib of the slope. At first we thought this was due to a lateral pressure only, and we renewed the broken posts with new ones, the result being that the new posts also were soon broken. A noticeable bending and breaking of the collars occurred, with a corresponding reduction in the height of the haulage slope. These symptoms were also evident on the counter above the slope, indicating that the trouble was of an exceptional nature. In the meantime, we had concentrated a large force of repair men, renewing broken timbers and brushing the roof and floor, but in spite of all our efforts we could not overtake the damage being done. Our next problem was to find the cause of this trouble. We were in a new basin of coal (No. 2) which had only been opened a few months, as we had worked the previous four years in another basin (No. 3) where no such trouble as this had ever been encountered. Naturally our first thought concerned the adequacy of the size of the pillars. We had worked in the No. 3 south basin for the previous four years. without any such experience, with 60-feet pillars between slope and counters; whereas we had established 100-foot pillars in the No. 2 south basin between the slopes and counters with an 80-foot pillar between counter and first line of cross-cuts, and 100-foot pillars between the breasts.

Jan 1, 1924

By In-Ho Chi

In copper metallization, resistivity of copper seed layer is very important since the thickness of seed layer is less than 200iun. Conventionally MOCVD has been used for this purpose however electroless copper plating is simple process and the resistivity of copper deposit is less than that of copper prepared by MOCVD. In this study eIectroless depositions of copper were conducted on different substrate to find optimum conditions of electroless copper plating for electronic applications. To find optimum conditions, the effects and selectivity of activation method on several substrates were investigated. The effects of copper bath composition on morphology were investigated. The effects of pH and stabilizer on deposition rate was investigated. The resistivity of copper with thickness was also measured.

Jan 1, 2001