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By C. Gary Reiness

A safety glass eyepiece which had been repeatedly exposed to mine environment over a number of years was studied to determine some of its optical properties. In the regions from 385 to 400 mµ and from 625 to 760 mµ, the transmittance was less than the 89 percent required by the American Standard Safety Code for Head, Eye, and Respiratory Protection. From 200 to 320 mµ the relative transmittance of two parts of the eyepiece was found to vary widely, having a maximum of 38 percent difference at 315 mµ. Irradiation of the glass by ultraviolet light caused enhanced absorption in the range from 200 to 1,200 mµ. There was a time-dependent increase of 1016 color centers per cubic centimeter throughout this range after 36.5 hours of irradiation. The rate-of-growth curve for the optical density, at 243.5 mµ and 23° C, was resolved into linear and saturable components, indicating zero order and first order

Jan 1, 1968

By Fjeldstad Karin Jusnes

Two quartz types used in the silicon and ferrosilicon industry were heated to temperatures of 1600 and 1700 °C. The parameters varied were the temperature and the holding time at maximum temperature. The amount of quartz, cristobalite and intermediate amorphous phase were measured using XRD and the internal standard method. Type P showed a much larger ability to transform to cristobalite at lower temperatures than type A. Type P had a larger amount of alkali and alkaline earth impurities. This could have enhanced the transformation to cristobalite. For quartz type A the amount of cristobalite was larger at 1600 °C than 1700 °C. This can also be seen for some of the samples of type P at shorter holding times.

By M. Kucharski

The model of the Outokumpu direct-to-copper process deals with a steady-state process the parameters of which do not depend on time. To give a prediction for the process outcome, "a modified black box" method, which ignores most of the chemical reactions in the furnace, was used. This method takes input and output parameters into consideration. The presented model describes the Outokumpu direct-to blister process in the form of the set of linear equations which give mass and enthalpy balances as well as the distribution of elements between blister copper and slag. However, only major substances where quantities in the feed charge exceed a certain level (for example 0.5 kg/ lMg of smelted concentrate) are taken into consideration. Minor elements are distributed among slag and metal phases in a different way. Some of the equations are derived from distribution coefficients. The value of distribution coefficients can be calculated from plant production data.

Jan 1, 2007

By C. B. van den Berg

n this study, silver and palladium nanoparticulate inks with different metal-binder ratios were screen-printed onto a paper substrate. The printed layers comprised the metal nanoparticles and an ethylcellulose binder. The layers are not typical metal composites due to the low concentration of binder and high porosity. The electrical sheet resistivity of each particle concentration was measured, and the data fitted using the scaling law of percolation theory and the general effective media (GEM) equation. The percolation parameters, i.e. the percolation threshold and the critical exponent, for each system were determined from the fits and compared. The percolation threshold for the palladium layer (39.8 wt%) was lower than that found for the silver layer (44.9 wt%). The critical exponents determined for the palladium and silver layers were both lower than the universal value for three-dimensional percolation systems. Microscopy observations indicate that the difference in the percolation threshold for the two layers can be attributed to variations in their microstructure.

Jan 1, 2014

By A. L. de Vegt

For the past ten years Paques has been engaged in the development and installation of treatment systems based on biotechnological processes to remove sulfur compounds from water, air and gaseous streams. Metal and sulfate can be removed from mine waters using two biological steps: 1. Sulfate reducing bacteria convert sulfate to hydrogen sulfide (H2S). The H2S reacts with the dissolved metals to form insoluble metal sulfide precipitates. 2. Sulfide oxidizing bacteria convert excess H2S to elemental sulfur. Paques has designed and installed a groundwater treatment system for the Budelco zinc refinery in the Netherlands to remove metals and sulfate as described above. The system has been operating since May 1992 treating a flow of 5000 m /d. A pilot plant started operation in November 1995 at Kennecott's Bingham Canyon Utah copper mine to develop the processes for metal and sulfate removal from groundwater and selective copper recovery from leach water. The principle of the biotechnological methods, full scale experience, and an overview of the test program at the copper mine are presented.

Jan 1, 1997

By W. A. Hodgson

"In order to be able to map the variation in the concentration of elements in soils, it is necessary to sample at intervals that will give adequate coverage of the area and will allow determination of the rate of fluctuation of concentration with distance in any environment. This rate of fluctuation with distance can be referred to as the continuity of concentration.The continuity of concentration in soils varies according to the chemical characteristics of the element being considered, the underlying rock type or orebody and in response to the dispersion processes that operated during soil formation. Within any environment there is a maximum distance between sampling points within which adjacent sample values are related. This distance, the critical sampling interval, can be determined by means of a correlograrm.Where the sampling grid has been chosen to provide an adequate coverage over unmineralized rock, adjacent samples being related, anomalies may be missed if the element continuity in the anomaly is less than in the background. Results show that a knowledge of the critical sampling interval of the environment being examined may used to select a more efficient sampling pattern for a geochemical survey."

Jan 1, 2014

By James A. Finch, Xiangzhou Ding, Yue Hua Tan

"The Jameson Cell is one of the choices of flotation machine in coal, base metal processing and other specialist applications. This paper determines the effect on vacuum pressure and bubble size of two design variables, orifice size and downcomer length, and the operating variable air-to-water (AWR) ratio. The main findings are: orifice size and downcomer length impact the vacuum but have limited effect on bubble size; AWR < 1 favours high vacuum, conditions are identified where vacuum is maintained at AWR > 1, and water flowrate has slightly greater impact on bubble size than air flowrate.INTRODUCTIONFroth flotation, the most common technique for mineral separation, has been in use for over a century. The process takes advantage of the difference in wettability of mineral surfaces to achieve the separation of valuable minerals from non-valuable minerals, or gangue. Numerous flotation machines have been invented and patented over the years. The Jameson Cell, invented by Professor Graeme Jameson in the late 1980s, is one successful example. First trialed at Mount Isa Mines (Queensland, Australia), Jameson Cells have been installed at operations around the world for the recovery of fine coal (Mohanty and Honakeri, 1999; Cowburn et al., 2006; Hacifazlioglu and Toroglu, 2007; Uçurum 2009), minerals of copper (Farr 1992; Atkinson et al., 1993; Harbort et al., 1997), lead/zinc (Rohner, 1993; Munro, 2003) and gold (Bennett et al., 2012; Lauder et al., 2003), and in water treatment (Yan and Jameson, 2004), solvent extraction de-oiling (Miller and Readett, 1992; Miller et al., 1997; Harbort et al., 2003; Young et al., 2006), oil sands processing (Neiman et al., 2012), and various food industries (Brenneman, 2014). One of the largest units is the 650 cm diameter separation tank with 24 downcomers installed in an Anglo American operation (Osborne and Euston, 2015). Scale up is relatively straightforward: to increase capacity the number of downcomers is increased with corresponding increase in size of separation tank.The Jameson Cell comprises two main parts: a vertical tube (downcomer) which provides self-aspiration and intense bubble-particles contact, and a (separation) tank where particle-bubble aggregates disengage from the pulp. The intense bubble/slurry mixing in the downcomer with air holdups reaching 60% (Marchese et al., 1992) accelerates particle collection enabling the greatly reduced cell volume compared with mechanical flotation cells and columns. The disengagement of the particle-loaded bubbles from the slurry in the separation tank is usually aided by addition of washwater."

Jan 1, 2018

By C. I. Everson

The Elkhorn mining district is located 35 kilometers southeast of Helena, Montana, on the southeast edge of the Boulder Batholith. Geologically the district consists of a folded sequence of Paleozoic limestones and shales which have been thermally metamorphosed and altered by monzonite to diorite intrusives related to the Cretaceous Boulder Batholith. For the most part, the skarns are associated with metasomatic: replacement of calc-silicate hornfels, diorite and marble by iron rich, dark green pyroxene, garnet, sulfides, the district contains excess of 30,000 Kg.

Jan 1, 1992

By Kozo Takeda, Arashi Shimano

"Dry Jet Mixing (DJM) method as the representative deep mixing technique has been demonstrating best practice on ground mitigation works coping with complicated soil condition and limited site space. This technique plays an important role in many projects to stabilize soft ground involving troubles like sliding failure, settlement, bearing capacity etc. Serious disasters caused larger earthquakes make great demand on the application of deep soil mixing these days. Special design and alignment of deep soil mixing has been established against to liquefaction and serious failure due to liquefaction. In this paper, representative example of liquefaction mitigation by DJM method is summarized. The paper also present result of surveillance of sites installed DJM col umns after attack by Tohoku Pacific Ocean Earthquake. Performance of DJM columns suffered the earthquake is demonstrated at several sites even with conventional column alignment.INTRODUCTIONThe DJM method is a representative deep soil mixing technique of dry mixing manner in Japan. DJM can successfully install soil mixing columns trough automatically controlled binder injection based on pneumatic feeding theory and cumulative experiences.This method was joint-developed in 1978 by private organization under initiative of the Public Works Research Institute of the Ministry of Construction as the optimum method for improving the Japanese soft ground. Figure 1 shows full view of the DJM construction system. Figure 2 illustrates DJM working system indicating Binder Feeding Plant side and Mixing Machine side respectively.As typical soil mitigation method, many projects related with rivers and roads and city development has required DJM technology. The total number of the projects applying DJM has exceeded 5,000 with the total treated soil volume more than 32,000,000 m3 by the end of fiscal year 2013."

Jan 1, 2015

By Jens Markowski

The EU Directive 2000/53/EC on end-of life vehicles (ELVs) states that in 2015 at least 85 wt.-% of a vehicle has to be reused or recycled. This result in the obligatory need to separate additionally metallic and other components of the automotive shredder residues (ASR), so that they can be professionally prepared for recycling and reuse further. Currently the iron-containing fines of ASR are deposited as it is not possible to process in blast furnaces due to its particle size (< 4 mm), composition and material properties. Additionally problems are also caused in handling and transportation (dust) of the material. This work focuses mainly on the ASR materials utilization in blast furnaces. Material was further separated into two consecutive fractions by carrying out repeated crushing and magnetic separation twice. The two fractions have significantly higher iron content (up to 75 wt.-%) compared to the initial material mixture. The materials were assessed for their usage in blast furnaces based on the possible pelletisation with and without binders, stability of pellets, shape and size of pellets, etc. Pelletisation of the material was carried out with a single mould pellet press. Further lignite coal was added to the mixture as additive which improved the pelletisation behavior and the mechanical stability of pellets. Lignite coal was chosen as a reducing agent in the blast furnace process contributing towards additional savings in energy supplied. The experiments reveal that the production of pellets from iron-containing fines is possible with a lignite coal admixture of about 15 wt.-%. These pellets displayed good mechanical stability and can be used in blast furnace processes in recovery of the recyclable metals which are currently not recycled. The recycling of not yet recyclable metals would reduce the deposition and can be easily adopted into the economic cycle by their utilization. Keywords: Automotive shredder residue (ASR), FE-fines, pelletisation

Sep 1, 2012

By Namavari. H., M. Ashouri, M. R. Sarhadi, S. H. Mansouri, A. Sarrafi

The splash phenomenon and its effective parameters in metallurgical converters have been studied thoroughly for decades. The detailed studies of processes such as tuyere blockage, wave formation during air injection, entrapped phases, and also processes which control the formation of bubbles in viscous fluids are not feasible yet. In this research, we have used a converter-shaped vessel made of flexi-glass. Water and oil have been used as matte and slag phases respectively. The effective operational factors responsible for creation of splashing have been studied such as air flow rate, tuyere angles, depth of tuyere submergence, tuyere blockage, density and viscosity of liquids, liquids heights, etc. The results have been found as follows: the amount of splashing increases slowly as air flow rate increases. However, as the air flow rate reaches a critical value (depending on the physical specification of converter) the amount of splashing rises sharply, because the flow of air inside the liquid changes from bubbling into a jet stream; and most of the splashed materials are in the form of filaments instead of droplets. Changing tuyere angle from horizontal towards vertical position will increase the turbulence level on the fluid surface and causes an increase in the amount of splashing. The effect of tuyere submergence is related to the converter opening angle. As the converter opening angle is shifted towards the hood position, the amount of tuyere submergence and splashing will increase. As density of the liquid increases, the number of droplets splashing increases with a decrease in drop size. Therefore, the total amount of splashing decreases. However, as viscosity of the liquid increases, the splashing material increases due to the changes in the splashed material from droplet shape into filament form. The height of liquid inside the converter, depending on the relative height of heavy phase and light phase, is an important parameter regarding splashing. As the relative height of heavy phase to light phase increases the splashing will decrease. The tuyere blockage will cause the pressure in the inlet manifold to increase; and in real cases will increase the splashing. Finally, we have development a model based on dimensional analysis to relate the above parameters in order to calculate the amount of splashed material.

Jan 1, 2007

By Kwan Ho Kim

The beneficiation study of low quality pyrophyllite is conducted to enhance the value of it by selective grinding. In mining stage, the main gangue mineral is quartz, and the content of quartz in ore has an adverse effect on the quality of pyrophyllite. Using the huge difference in hardness between quartz and pyrophyllite, the selective grinding is accomplished using stirred ball mill. As a result, a finer pyrophyllite particle can be easily separated from coarser quartz particle by simple size classification, and the content of Al2O3 of fine particle smaller than 45um increased largely. It means that the pyrophyllite particle is ground selectively compared to the quartz particle, and the quality of pyrophyllite is enhanced.

Sep 1, 2012

By H. P. Kritzinger, T. C. Kingsley

Rotary kilns are used for a variety of mineral processing operations. Hatch makes use of a kiln model developed from first principles to evaluate designs for its clients. This tool has been applied to a variety of pyrometallurgical applications. This paper illustrates the application of numerical optimization techniques in combination with the kiln model in the interrogation of a generic iron-ore reduction process. The fundamental modelling concepts are explained, followed by a description of the optimization approach. The results show how the combination of the two methods, with modern computing power, can generate a large number of viable design and operating candidates.

Jan 1, 2014

By Shiou-Chuan Sun

The froth flotation of coal, differing greatly from that of most minerals1-5, is not improved but rather impaired by temperatures higher than room temperature6-10 This phenomenon has long taunted us for an explanation. Gayle and Associates 8,9 reported the lack of relationship between their contact angle measurements and their flotation of American coals under various temperatures. Bailey and Whelan6 stated that the viscosity of flotation reagents, offering some clue for their flotation of British coals at low temperatures, could not be put forward as an explanation either in whole or in part for the effect of temperatures on coal-flotation. In this paper, a froth hypothesis is proposed to explain the flotation behavior of coals under various pulp temperatures. Test work involved the flotation of coals and the frothing of reagents.

Jan 1, 1966

By Edward K. E. ] [Williams

Conditioning is any treatment of an ore with or without reagents which affect its floatability. While it can start in crushing or grinding circuits and continue into the flotation circuit, conditioning will refer here only to reagent treatment in an agitated tank designed for the purpose. Such treatment is often unnecessary with sulphide ores and collectors or with amines,* but it has long been recognized as essential with fatty acid collectors in the flotation of non-sulphide minerals, The requirements can be extremely variable, depending upon ore alteration, the presence or absence of slimes, and 1 the minerals to be separated. The study described here was concerned with the recovery of oxidized molybdenum minerals from an ore containing the element in both sulphide and oxidized form. Flotation of the iron minerals with which the oxidized molybdenum was associated was the basis for the process. Recovery and optimum concentrate grade without desliming depended upon a twenty to thirty minute conditioning of the pulp with flotation reagents at forty to fifty percent solids and at high turbulence. The objective in the study was the determination of design and operating criteria for conditioners in order to permit scaling-up of the results without repeating the entire study on a larger scale.

Jan 1, 1968

By Paul G. Dunn

The planning of underground mines is a complicated process involving geological, engineering and operational constraints. MIRARCO is in the process of developing a 5D Mining Exploratorium where 3D mining models are combined with time (4th dimension) and costs (5th dimension). The mining exploratorium is a collection of external and inhouse software packages specifically geared to help underground mining companies arrive at better mine plans. This paper discusses the progress made in the development of the 5D Mining Exploratorium and a change in mine planning philosophy by conducting frequent audits in a Virtual Reality Laboratory. The development of genetic algorithms for optimising stope sequences is also presented.

May 1, 2003

By Norman L. Kotraba

Zia Metallurgical Processes, Inc. has developed and patented a steelmaking process capable of converting iron bearing metallurgical wastes into high quality steel products. The process utilizes a proprietary design rotary hearth furnace to convert iron bearing wastes, pelletized with coal, or other forms of carbon, into direct reduced iron (DRI). This DRI is fed, hot, from the rotary hearth furnace into a Zia All Purpose Vessel (ZAV) where it is smelted and refined into high quality steel. A specially designed turret with three independent arms, each supporting a separate ZAV, comprises the heart of the meltshop. No overhead cranes are required to transport molten metal from the smelting/refining operation to the ladle metallurgy station to the caster to an inspection station and back to the smelting/refining point. The molten steel is contained in the ZAV throughout the operations eliminating the possibility of steel con¬tamination by non-metallic inclusions occasioned by the exposure to ambient air during metal transfer into ladles. The result is the creation of very clean steel that can be alloyed to produce virtually any desired grade from stainless steel to common structural steel.

Jan 1, 1994

Quantitative probabilistic ecological risk assessment has been used to evaluate the likely effect on fish diversity and abundance of filtered and bioavailable metals in streamwater affected by acid drainage from the abandoned and remediated Rum Jungle U/Cu mine in the Northern Territory of Australia. The water quality was determined using monitoring data from a gauging station on the East Branch of the Finniss River, downstream of the mine site, and modelled assuming a number of potential water quality management options. The management options ranged from no action, through some flushing options to full catch and treatment of contaminated seepage from the waste rock heaps. The computer code AQUARISK was used to undertake the analyses. Critical criteria for contaminant water concentrations at the site, derived from probability density functions of available fish ecotoxicology data, were found to closely approximate the regulatory trigger values for the contaminants of concern. Modelled predictions of reduced diversity and abundance were also in good agreement with in situ biodiversity measures. Based on a reasonable target of 67 per cent species tolerance for this heavy impacted site, it was found that none of the low cost options for wastewater management was acceptable. Combinations of two of the options approached acceptability. Both of the catch and treat options exceeded the arbitrary acceptability target well. This implied that the more expensive option of liming to pH 10 might be unnecessary at this site. Thus, the use of ecological risk assessment modelling has proven useful in undertaking cost-benefit analyses for this site. The approach provides a management decision-making tool that can be economically used to link expensive on-site environmental engineering options with site-specific ecological goals rather than the previous nebulous aims of æreduced contaminant loadÆ or æimproved biodiversityÆ that often resulted in excessive expenditure without achieving successful environmental benefit.

Jan 1, 2003

By Zhijing Zhang

Sodium borosilicate is the basic composition of coating materials, Vycor and Pyrex glasses. In the present study, viscosities of Na2O-Si02-B2O3 ternary melts were measured under various compositions and temperatures. Experiments were carried out using rotary viscometer and graphite components. Our experimental results were compared with those in literature. Based on present experimental results, the previous structure based viscosity model was modified. The predicted viscosity results are in excellent agreement with the present experimental data in the temperature range with molten state samples. The fitting ranges of the model cover the composition of XB2O3 from 0.1 to 0.6 combined with xSio2 / xNa2O = 0.5, 1,2 and 5 respectively.

Jan 1, 1998

By Robert R. Brandom

The Boss-Bixby deposit is one of several iron deposits that occur in the Precambrian igneous rocks of southeastern Missouri. It differs, however, from all of those deposits by its significant contents of copper, cobalt, and titanium, and its close relationship with a basic igneous intrusion. Ore microscopic study of selected drill core samples has shown that the hypogene ore minerals are magnetite, hematite, chalcopyrite, bornite, covellite, ilmenite, rutile, sphalerite, cobaltian pyrite, carrollite, scheelite, and wolframite. Subsequent partial oxidation has formed martite, pseudobrookite, and anatase. Textural evidence indicates that two stages of iron and iron-titanium oxide formation were followed by the deposition of the copper-iron sulfide minerals and carrollite.

Jan 1, 1985