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By I. L. Nichols, D. C. Seidel, D. E. Traut

A fluidized countercurrent ion-exchange system was developed, operated, and evaluated by the Bureau of Mines. The system consisted of integrated multiple-compartment absorption and elution columns in which the solution flows are continuous except for short periods when resin increments are withdrawn. The exchange of uranyl sulfate between a simulated acid leach uranium solution and a strong-base, ion-exchange resin together with the subsequent elution with an acidified sodium chloride solution was studied. The effects of the number of sections, section heights, amount of resin withdrawal, and solution flow rates were investigated. Also examined were the kinetic and equilibrium relationships for the absorption step. The experimental data indicate a strong interdependence between variables. Solution retention time appears to be a major limiting variable. The column was efficient over a range of conditions, but close control was needed for optimum operation.

Jan 1, 1977

By D. G. Foot

The Bureau of Mines devised a direct flotation method for recovering potash from carnallite (KC1?MgC12?6H20) ore characterized by a high content of water-insoluble impurities. The method includes (1) a decomposition leach of the carnallite, (2) flocculation-depression of the insoluble slimes, (3) potash rougher, cleaner, and recleaner flotation, and (4) final product leaching. The technique eliminates the necessity for removing the water-insoluble slimes by mechanical or flotation de-sliming. Laboratory results demonstrated that the direct flotation procedure, when compared with conventional techniques, yielded equivalent or improved flotation results with equal or less reagent consumption. Locked-cycle testing of the direct flotation method recovered 87.8 pct of the potassium in the flotation feed in a final product containing 60.6 pct K20. A flowsheet incorporating the carnallite leaching-potash flotation procedure is presented.

Jan 1, 1982

By W. H. Eddy

The Bureau of Mines conducted laboratory batch and continuous flotation processing tests on waste granite fines from South Carolina to determine the possibility of recovering high-quality feldspar and glass sand. Three flotation systems were used for removal of the iron-bearing biotite: Two employed an alkaline anionic-cationic circuit and the third employed an acid cationic circuit. Commercial-grade products were obtained when the remaining biotite was magnetically removed from the feldspar and quartz concentrates. Continuous flotation processing yielded a feldspar concentrate containing, in percent, 3.60 Na20, 5.60 K20, and 2.25 Ca0, with recoveries of 75.3, 66.6, and 72.6 percent, respectively. The feldspar tailing was high quality glass sand containing 98.0 percent Si02 and 0.025 percent Fe203; about 60 percent of the quartz was recovered.

Jan 1, 1972

Many problems result when coal mine shafts are built in complicated geological conditions and serious shaft lining ruptures have often occurred in the eastern part of China since 1987. Grouting is applied as one of the major measurements for shaft lining ruptures. However, as the general location of reinforcement grouting for shaft lining is deep in or near the bottom aquifer, while using cement grout as the grouting material, the grouting mostly belongs to fracturing grouting in deep alluvium. In these conditions, the mechanism and behavior of fracturing grouting has not yet been understood. From these points of view, this paper describes the mechanism of shaft lining rupture and fracturing grouting and then discusses the effect of grout injection on the stability of shaft lining by means of numerical analysis and field data obtained so far.

Dec 6, 2010

By D. R. Tweeton, L. W. Lake

A modified push-pull field test and a computer model of cation exchange were developed to aid in evaluating cation exchange parameters prior to in situ mining. Reliable determination of these parameters is essential when modeling restoration of ground-water quality. The field test involves a much larger volume and much less disturbance to the ore sample than is feasible with laboratory measurements. This test can be per¬formed in two or three weeks. It is relatively inexpensive, requiring one injection-production well and two or more wells for collecting samples of leach solution. The use of the model in interpreting test results is illustrated with field data from an in situ uranium mine. Much of the research was performed by the University of Texas at Austin and was partially funded by the US Bureau of Mines.

Jan 1, 1987

By Bian Xue, Wu Wenyuan

In order to recycle the iron and rare earth from the Baotou tailings, a roasting method was developed involving the addition of C, Ca(OH)2, and NaOH, designed to both decompose the rare earth minerals and convert haematite into magnetite and allow its recovery. The effect of various parameters such as roasting temperature, roasting time, C addition, Ca(OH)2 addition, and NaOH addition on the reduction ratio of haematite (iron sesquioxide) and decomposition ratio of rare earth were investigated. The results showed that the reduction ratio of haematite and the decomposition ratio of rare earth could be as high as 85% and 95% respectively when the roasting temperature was 650°C, roasting time was 60 min, Ca(OH)2 addition was 4%, NaOH addition was 3%, and C addition was 1.5%.

Jan 1, 2014

Relatively few longwall mines in the U.S. operate under multiple seam conditions where the two seams are less than 200 ft apart. This paper describes the experience of six that do. These operations are located in PA, WV and UT, and include examples of both undermining and overmining. Some operate above or beneath their own workings, others are in historic mining districts and must contend with abandoned mines that are decades old. The lessons that these mines have learned cover a broad range of topics, including: • Whether to stack gateroads or place them under old gob areas; • How to size pillars and select artificial support to cross longwall stop lines; • How to use yield pillars to minimize multiple seam stresses and coal bump potential, and; • When to anticipate the creation of pathways for gas, water, or oxygen between current and abandoned gobs.

Jan 1, 2007

By George A. Desborough, Forrest G. Poole

Marine black-shale samples of Paleozoic age in the western United States that exceed 10 wt % organic carbon contain as much as 5000 ppm vanadium, 5000 ppm molybdenum, 1300 ppm nickel, 600 pprn cobalt, 16 ppm silver, 11,700 ppm chromium, 18,800 pprn zinc, 280 pprn cadmium, and 350 ppm selenium. Depositional set- tings include: (I) continental-rise and marginal- ocean basins, (2) continental-shelf and foreland basins, and (3) cratonic-platform embayments. Most of these metalliferous organic-rich shales have not been examined for resources because rapid weathering and poor exposures preclude easy sampling of unoxidized rock necessary to determine actual concentration and residence of indigenous metals. Generally, when interval thickness is considered, the marine black shales of Paleozoic age in the western United States are richer in metals than marine upper Paleozoic black shales in the eastern United States.

Jan 1, 1983

By A. E. Beasley, Ike McKinney

Scale is a broad term which includes many types of mineral deposits which have limited solubility in water. These mineral components precipitate when combinations of scale-forming cations and anions exceed their solubility. Scale deposits are tightly bound to each other and to the metal surfaces of a water system. Precipitates that do not readily adhere to each other or to metal surfaces are known as sludges. Sludges are easily removed from a system by flushing. For example, a sludge is formed in the internal treatment of boiler waters with orthophosphates where the calcium is purposely precipitated as hydroxyapatite. Calcium phosphate would have a tendency to adhere to the boiler tubes except for the addition of tannins or lignins. These sludge conditioners maintain the precipitated calcium phosphate as a sludge which can be readily removed by boiler blowdown.

Jan 3, 1973

Control the release of ground-water into active underground coal workings by short-term pumping from dewatering wells sited on fractures. Approach The sudden release of fracture-stored groundwater into underground coal workings often occurs when mine workings are developed beneath fracture valleys, Pumping from fracture trace-sited dewatering wells, prior to development of the underlying workings, can be an efficient means of intercepting fracture-stored groundwater before it is released into the mine. Dewatering operations are discontinued once the underlying mine workings have been fully developed, and the maximum possible reduction in fracture storage has been achieved through pumping. How It Works An aerial photographic technique known as fracture trace analysis is used to site dewatering wells on rock fractures in a valley bottom. Downhole caliper and temperature logs are used to assess the fracture flow potential of each dewatering well drilled.

Jan 1, 1987

By P. K. Sharma

The acidophilic and chemolithotrophic Thiobacillus ferrooxidans bacteria grown in the presence of soluble ferrous ions and solid substrates (sulfur, pyrite and chalcopyrite) as their energy source have been used in the investigations. The cell surfaces are characterised by zeta-potential, contact angle, FT-IR and FT-Raman studies. The adsorption isotherms of the cells on pyrite and chalcopyrite indicate that the adsorption begins on pyrite at a much lower equilibrium cell population than on chalcopyrite. The isotherms tend to level off at a cell adsorption density corresponding to a horizontal monolayer coverage when the geometrical dimensions of the cells are considered. In the presence of cells, the xanthate flotation of pyrite completely depressed, whereas chalcopyrite flotation is unaffected. The results suggest that chalcopyrite can be selectively floated from pyrite, also at a neutral pH region, in the presence of T. ferrooxidans cells.

Jan 1, 1999

By Warren Weaver

Some of the advantages of the inductive method of electrical prospecting were emphasized in a paper by Dr. Max Mason. Since this emphasis was misunderstood by some to indicate a too exclusive interest in inductive methods, we are especially happy to help correct this impression by reporting on some of our work on surface potential methods. Earth Currents and Surface Potentials When two electrodes, A and B, are placed on the surface of the ground a distance d apart, and a 100-volt battery is connected across the elec- trodes, current flows from the positive electrode A to the negative electrode B. The current does not pass directly from A to B along the straight line joining these two points. In fact, a negligible amount of the total current chooses this direct path, and the flow actually takes place

Jan 1, 1929

By Michel Ruel, Ali Soltanzadeh

This paper describes how to make advanced control choices when difficult processes need improvement. The decision-making process involves choosing between a rules-based approach and a model-based approach as well as weighing benefits and drawbacks, complexity and simplicity, investment and results. This paper will present briefly each solution: basic control, advanced regulatory control, model predictive control and expert systems such as fuzzy logic controllers and neural networks. Three examples are presented: ARC (Advanced Regulatory Control) on pH in a comminution circuit, MPC (Model Predictive Control) for combustible management and FLC (Fuzzy Logic Control) on a Semi Autogenous Mill. The article then proposes a decision tree for selecting the most appropriate approach. A table will compare usage, development, commissioning, maintenance and lifecycle costs for each approach. Finally, conclusions and suggestions will summarize the methodology.

Jan 1, 2014

Design of underground extraction layouts to protect surface improvements is an important area of subsidence research in the Coal Mining Engineering Branch of the Department of Mineral Resources, New South Wales, Australia. Some conventional partial extraction layout are important with reference to coal recovery and surface subsidence. The analysis ofsubsidence data collected from field surveys over longwall panels in the Southern Coalfield of New South Wales allows assessment of the effect of pillars left unmined between the longwall panels in reducing surface subsidence. The availability ofa wide variety of layouts with ranging degrees of surface movements affords considerable flexibility in designing layouts to suit a particular situation.Total extraction of coal should be the aim as far as possible. Partial extraction layouts should only be considered when surface subsidence movements caused by total extraction are not acceptable to the surface improvements.

Jan 1, 1985

By F. Lynwood Garrison

There is probably no subject for study in the metallurgy of iron and steel of greater interest than the effect of manganese upon the properties of iron. Some of the peculiarities of iron and steel containing appreciable quantities of manganese were observed many years ago by Heath, Robert Mushet, and others; but it was not until the introduction of the Bessemer process, when a demand was created for large quantities of iron-manganese alloys, that such compounds of iron and manganese became articles of commerce. Since that time the demand for these alloys has steadily increased, the use of ferro-manganese not only becoming an absolute necessity in the ordinary Bessemer practice, but also essential to the manufacture of open-hearth, crucible steel and steel castings; in fact it is the only source of supply for all the manganese used in metallurgical opera-

Jan 1, 1893

By Kenneth J. Miller

The Bureau of Mines conducted an investigation to improve the flotation response of coals that are difficult to wash by froth flotation. A literature survey and experimentation showed that, for the most part, refractory coals can be floated with oily collectors and frothers. Collector reagent consumption can be minimized and the selectivity of the flotation enhanced by assuring adequate, but not prolonged, reagent conditioning. Where flotation selectivity is especially poor, two-stage rougher-cleaner flotation is recommended. It was concluded that a major problem with refractory coals is predicting when they will appear in a flotation circuit so that supplementary flotation collectors can be added. Coal losses due to variation in the floatability of the feed might be reduced if a nonpolar collector such as kerosine or fuel oil is used along with a frother as general coal flotation practice.

Jan 1, 1977

By Jean L. Leroy

The Lead Smelting works of Metallurgie Hoboken S.A. are located on the banks of the river Scheldt a few miles South of Antwerp. Lead refining began at Hoboken in 1687, when it was restricted mainly to desilverizing lead bullion from Central America. Since then, various changes have been made to develop the works into a comprehensive and integrated custom smelter and refinery. Multiple hearth roasting furnaces, down-draft sinter machines and blast furnaces of standard design are used for the treatment of "complex" lead ores and secondary materials. A lead refinery based on the Harris process, with Parkes desilverizing followed by vacuum dezincing and Kroll Betterton debismuthizing was commissioned in 1967. Facilities for the recovery of precious metals, bismuth, antimony, arsenic and sulfuric acid are available. Special problems arise from the presence of large quantities of copper in the materials treated.

Jan 1, 1970

By W. Mostowitsch, H. O. Hofman

In a previous paper,' The Behavior of Calcium Sulphate at Elevated Temperatures with Some Fluxes, we published the results of our investigation into the behavior of calcium sulphate in air; that is, under oxidizing conditions. The results as a whole hold good for a neutral atmosphere, or one which has no chemical effect upon calcium sulphate. The present paper deals with the behavior of calcium sulphate under reducing conditions, the reducing-agents employed being carbon monoxide and carbon, and the changes the calcium sulphide formed undergoes when it is subjected to an oxidizing-roast. Technical literature deals very sparingly with the subject. The information furnished by the recent leading chemical manuals is general. Thus Dammer,2 Missan,3 and Abegg4 quote Berthier as having reduced, in 1823, calcium sulphate with carbon, and Stammer as having done the same in 1851

Jan 1, 1911

By Ernesto Villaescusa, Andres Brzovic

Rock masses of the primary copper ore at the El Teniente Mine are very competent and massive. The rock mass contains almost no open discontinuities. Nevertheless, there is a high frequency network of small discontinuities coupled with widely spaced faults. A data collection campaign designed to characterize the rock structure was recently implemented. The results show that conventional analysis in terms of discontinuity frequency does not predict differences between two studied sectors. However, when an empirical definition of a weak discontinuity is applied, appreciable differences between the two sectors appear in terms of discontinuity frequency and predicted in situ block size distributions. These differences are in accordance with actual observations at the mine site. Due to the geological features of the primary copper ore, rock mass classification schemes cannot be readily applied to characterize these rock masses.

Jan 5, 2007

By I. D. Shah

Thermal decomposition of copper (II) sulfate (CUS04) and copper (II) oxy-sulfate (CuO?CUS04) are important steps in the overall oxidative roasting of covellite (CuS) and chalcocite (Cu2S). Nonisothermal thermogravimetric techniques were used to investigate the decomposition reactions in flowing Na and air. Thermal decomposition of CUS04 and CuO?CUS04 followed "linear" kinetics with an apparent activation energy of 55±2 and 66±3 kcal per mole decomposed, respectively. These apparent activation energies comply with those previously reported when isothermal kinetic techniques were used. The addition of oxygen decreased the rate of decomposition, while small amounts of iron which were admixed with CuO?CUS04 did not have a significant effect. Neither oxygen nor iron had any appreciable effect on the apparent activation energy of the decomposition reaction.

Jan 1, 1972