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By Fred N. Kissell

This U.S. Bureau of Mines report is a guide for the control of air contaminants during tunnel construction. Topics discussed are calculating air quantity requirements, types of ventilation systems, planning ventilation systems, control of methane gas, control of dust, control of diesel emission, ventilation to remove blasting fumes, measuring airflow, and measuring gases. This report does not provide detailed design information, but seeks to answer practical questions on air contamination issues.

Jan 1, 1995

By Donald Bruce

The three types of specifications which are used for micropile work are: ? Performance Specifications: The contractor is permitted control over certain design and/or construction procedures but must demonstrate to the owner through testing and/or certification that the final product meets the specified performance criteria. This method allows and encourages the contractor to provide a competitive and/or innovative micropile design within the framework of the overall design requirements. The responsibilities for the work are shared between the owner and the contractor. ? Open Specifications: These leave the scope and design of the installation up to the micropile contractor. This method is the most common for securing bids on temporary micropile work. The responsibility for design and performance is clearly placed on the contractor. Open specifications are not recommended for permanent applications. This method allows the contractor to select the most economical micropile system. ? Prescriptive Specification: The Owner describes specific procedures that must be followed, but which may not necessarily describe the objective of the work. When prescriptive specifications are used, the owner is responsible for the proper performance of the system. The contractor is responsible for satisfying the details of the specifications. Performance specifications are the most common and best reflect the challenges and interests of micropile technology and applications.

Jan 1, 2004

By Harvey Alter

National attention in, recycling focuses on municipal solid waste (MSW), even though only about 50'million tons or so of MSW can be recycled, including grass, leaves and other yard wastes. The scope and value of the recycling of industrial "wastes" is much greater. It is possible to account for some 240 million tons of material recycled at the industrial scale annually, which is likely a conservative estimate. Some of this recycling reduces what would otherwise be hazardous waste to 'comrnodities and non-hazardous residue. Global trade in recycled commodities is outlined, as well as the-effect of the Basel Convention on the Trans boundary Movement of Hazardous Wastes A recent Decision under the Convention can, diminish the trade; deny developing countries needed secondary raw materials, and put world markets in chaos. Current U.S. government policies and activities toward ratification of the Convention, and possible new regulation of industrial recycling activities, will be discussed. There are federal proposals that would regulate industrial recycling differently for on-site and off-site facilities and judge legitimate or "sham" recycling according to the concentration of so-called "toxics along for the ride."

Jan 1, 1995

By Sidney A. Hiscock

INTRODUCTION Lead and zinc are today rightly regarded as sister metals. Historically, however, they differ markedly with lead being known and in general use as the metal since 3000 BC in several countries which at that time might have been described as mature economies. Zinc was not isolated and recognised as an industrial metal with distinct and valuable properties until about 1700-1800 AD (although it had, of course, been utilised as a constituent of brass for some 2000 years previously). c were well established as industrial metals by the beginning of the 20th century. The present paper briefly reviews the overall growth in world consumption* and changes in the three main areas which today represent the mature economies or industrialised areas, i. e. ,Europe, the United States and Japan. Trends in overall consumption are determined by the demands for the individual uses for lead and zinc. The changes in patterns of use in the industrialised areas - individually and collectively - and reasons for the changes are also considered. LONG TERM TRENDS - 1900-1984 The World Picture Since the beginning of the 20th century the world consumption of lead (3.9 million tonnes in 1984) has grown almost fourfold and that of zinc (4.7 million tonnes in 1984) is almost eleven times greater than it was in 1900. The long-term trend has been one of continuing expansion for both. metals although the pattern has been severely disturbed at certain periods, for example in the years immediately following the two world wars and at times of marked recessions in industrialised areas. Apart from such major setbacks, new levels of consumption have been established regularly every few years. Recently, however, consumption has not really grown and with only a slow and partial recovery in world industrial activity at present, there is no indication that the peak consumptions of 4.2 million tonnes of lead, set in 1979, and 4.8 million tonnes of zinc (1973) will be exceeded in the near future. The growth in world lead and zinc consumption since 1900 is shown in Figure 1 (which includes changes in copper and aluminium for comparison). Overall growth over the period 1900-1984 has been about two percent a year for lead and about three percent for zinc (annual growth for copper has also been about three percent). Increases in tonnage consumption and growth rates by decade for lead and zinc are summarised in Table I. However, the growth rates by decade sometimes conceal very large individual annual increases and decreases. For example, in 1975 lead consumption fell by 13 percent and zinc consumption by 22 percent compared to 1974. In 1976 consumption of lead and zinc rose by 12 percent and 18 percent respectively. The years when consumption 'landmarks' (ie one, two, three and four million tonnes) were first reached are shown on Table 2. Clearly, the pattern of shorter periods being required to attain each extra million tonnes of consumption was broken in the 1970's. The consumption of zinc overtook that of lead for the first time in 1940, and since 1946 has always been at a higher level. Trends in industrialised areas The two key industrialised areas at the beginning of the 20th century were Europe and the United States which between them accounted for some 95 percent of world lead consumption and 98 percent of zinc consumption. Figures 2 and 3 show the growth in lead and zinc consumption, and Figures 4 and 5 the percentage shares for each area since 1900. Europe has usually been the major user of lead except for some years in the 1920fs, most of the 40's and early 50's when consumption in the United States was larger. In 1900, Europe accounted for about 64 percent of world lead consumption and the United States just over 30 percent. Currently, Europe takes about 40 percent of world consumption and the

Jan 1, 1986

By John E. Young

United States Steel Corporation's Winifrede Mine is operated by Lynch District in the mountainous region of Eastern Kentucky. This region is characterized by narrow mountain ridges and precipitous slows which present both an opportunity and challenge in the design and selection of coal handling facilities for the movement of coal from the section belts to the railroad cars. The narrow finger ridges precluded use of underground haulage and, thereby, presented the opportunity to use high capacity equipment on the outside bench. The precipitous mountain slopes, steepest at the Winifrede seam horizon, presented a challenge to select a solution for lowering the coal approximately 1000 feet from the seam level to the valley floor railroad load-out point. It was evident from the start of planning that these two factors predominated; namely, rail haulage and coal lowering, and solutions to these would determine the final design of the Winifrede Mine coal handling facilities.

Jan 1, 1970

Membrane technology has been available for over 36 years, but has been used sparingly in the general mining industry. However, recent developments in polymer chemistry, spiral wound element construction, pretreatment equipment and techniques and an expanded understanding of membrane fouling and cleaning techniques have dramatically improved the reliability and robustness of membrane based systems in the mining industry. Harrison Western has expanded the use of this “new” technology to enhance the use of membrane technologies to separate metals from large volume heap leach mining solutions containing copper, zinc, and iron, gold or silver. Moreover, membrane technologies are ideally suited to fractionations that add value to processing fluids from refineries like separating metals from acids or concentrating acids and producing high quality process fluids. Finally, wastewater from Acid Mine Drainage (AMD) or, as in the case of the Newmont Yanacocha Mine in Peru, the treatment of excess barren leach solution created during the rainy season, can be cost effectively processed to meet World Bank Standards for surface discharge. Polymeric membranes, specifically thin-film composites, have been developed that will purify, fractionate or concentrate gold, silver, copper, zinc or nickel. Recent applications have been developed for spiral wound modules that operate across the pH spectrum from 0 to 14. Systems using membranes have been constructed that operate on feed streams from 140° C to 300 centipoise. Opportunities exist to apply membrane technology to concentrate gold, silver, copper, zinc or nickel using thin film composite membranes. Engineered membrane types can operate across the spectrum from low pH (<2) acid applications to high pH > 10 cyanide applications. Incorporating HW EMS™ membrane technologies into current mining operations could allow one to increase production because the membrane technology would be used to pre-concentrate heap leach solutions, and therefore, increase utilization of existing extraction and refinery capabilities.

Jan 1, 2007

By D. Turnbull, R. E. Cech

EXPERIMENTAL studies of precipitation of iron from solid solution in copper by Gordon and Cohen 1, Bitter and Kaufmann 2 and Smith 3 revealed that the precipitate particles were initially paramagnetic but could be changed to a ferromagnetic

Jan 1, 1955

By Stella Agatzini

Column leach tests were conducted to evaluate the amenability of poor Greece nickel laterites to heap leaching with dilute sulfuric acid at ambient temperature. The ore tested was a limonitic laterite with less than 1 % nickel and it was subjected to a suitable pretreatment with water prior to it being loaded into the columns, following findings of preliminary research work. The acid solution was recycled after suitable pH adjustment. Factorial designs were used to determine the effects and interactions of the following factors: sulfuric acid concentration, ore column height, ore grain size and ratio of leach solution volume to the ore quantity. The response which were investigated included nickel and cobalt recoveries, codissolution of iron, calcium, magnesium, aluminum, chromium and silica and also sulfuric acid consumption. Experimental error was also detennined. The tests showed that a nickel recovery of 88% could be achieved in 60 days.

Jan 1, 1993

By R. D. Groves, G. M. Potter, T. H. Jeffers

Experiments on ammonium carbonate leaching of native copper ores crushed to 1-inch size showed that in 30 days 55 percent of the copper was extracted from 0.7 percent copper conglomerate-type ore, and 85 percent was extracted from 2.1 percent copper amygdaloid-type ore. Cupric ions were not necessary to initiate leaching, and dilute solution containing only 2.2 grams per liter NH3 and 1.9 grams CO, was a suitable solvent. Copper was recovered from the leach liquor by solvent extraction and electrolysis of the strip solution. Cyclic testing of the leach-solvent extraction-electrolytic procedure is in progress on a 6-ton charge of minus 12-inch conglomerate-type ore assaying 2.2 percent copper. Oxygen is metered to the closed leach vessel as required by the leaching reaction. Initial copper dissolution was much slower than from minus 1-inch ore, but the leaching rate then markedly improved.

Jan 1, 1974

By Y. A. Attia, M. Elzeky

The effects of bacterial adaptation and partial replacement of leaching solution on the rate and extent of bioleaching reactions of a complex sulfidic gold ore were investigated. The ore was first concentrated by bulk sulfide, flotation, and the sulfide concentrate was treated by bioleaching using Thiobacillus ferrooxidans. The residues from bioleaching were treated by cyanidation to extract the gold and silver. Bacterial adaptation before bioleaching significantly increased the rate and extent of bioleaching reactions. Similarly, the daily partial replacement of leaching liquor enhanced to a great extent the leaching rate, and in some cases, increases of up to ten fold were observed. Both bacterial adaptation and solution replacement increased the gold recovery by about 2-fold and that of silver by about 1.3-fold. In this work, more than 95% of the gold and more than 98% of the silver could be recovered from the sulfidic gold ore when bioleaching was used ahead of cyanidation, compared with 18.3% and 52.3% by direct cyanidation.

Jan 1, 1992

By M. Elzeky, A. Attia

The effects of bacterial adaptation and partial replacement of leaching solution on the rate and extent of bioleaching reactions of a complex sulfidic gold ore were investigated. The ore was first concentrated by bulk sulfide flotation and the sulfide concentrate was treated by bioleaching using T. Ferrooxidans bacteria. The residues from bioleaching were treated by cyanidation to extract the gold and silver. Bacterial adaptation before bioleaching significantly increased the rate and extent of bioleaching reactions. Similarly, the daily partial replacement of leaching liquor enhanced to a great extent the leaching rate and in some cases up to ten fold increase was observed. Both bacterial adaptation and solution replacement increased the gold recovery by about 2-fold and that of silver by about 1.3-fold. In this work more than 95% of the gold and more than 98% of the silver could be recovered from the sulfidic gold ore, when bioleaching was used ahead of cyanidation compared with 18.3% and 52.3% by direct cyanidation.

Jan 1, 1989

By R. S. Olsen

Intensely altered rock has had a large effect on slope stability as slopes increase in height at Island Copper mine. Traditionally used, fracture-controlled rock slope stability design techniques have been supplemented with analyses of failure modes which include failure along curved surfaces typical of soil materials. A rock mass rating (Pa) system has been developed that addresses the lower end of rock mass strengths. Rock masses are rated in terms of fabric integrity, alteration, fracturing intensity and gouge strength. Rock mass classes have been defined using statistical frequency distributions of rock mass rating values. Strength values have been assigned to the various classes from shear testing, back analyses of failures and engineering judgment.

Jan 1, 1987

By A. W. Khair

In 1985, an extensive longwall mining research project was initiated by the West Virginia University Research Center entitled "An Improved Longwall Mining Technique" with the purpose of providing operational guidelines for the mining industry to enable efficient operation of its existing and projected longwall installations. One task involved in this extensive research project was monitoring ground movements due to longwall mining and evaluating their impact on surface and subsurface structures. This paper presents an analysis of the effects of topography on quasi-static and dynamic ground movements and the severity of damage inflicted on surface structures. The site was chosen for the study with an attempt to obtain a representative account of the topography experienced in the Northern Appalachian region, and more importantly to contain a substantial number of varying topographical features i.e., mountains, hillsides, valleys, and flat bottom land. The study was made possible by typical subsidence monitoring technqiues, however subsidence monuments were surveyed on a frequent basis, intermittently during face advancement. Ground movements were investigated under both quasi-static and dynamic conditions. This provided insight into the propagation of subsidence and the dynamic affects it has upon surface structures.

Jan 1, 1987

By J. B. Newkirk

IN 1939 Bitter and Kaufmann1 suggested that iron, precipitating from a copper-rich, Cu-Fe solid solution, appears initially as coherent particles of r-Fe which transform to the body-centered-cubic form of iron when the alloy is cold worked. Since then there has been considerable discussion, supported only by indirect evidence, regarding the validity of the concept. For example, Reekie, Hutchison, and Hether-ington2 interpreted the changes in electrical resistance accompanying the aging of Cu-Fe specimens in terms of a coherent 7-Fe precipitate which transformed to the incoherent a-phase during long aging or cold working. Greninger- ound that Cu-Fe alloys which had been water quenched from 1050" and then held at 650°C for 3 hr changed from weakly to strongly ferromagnetic as the aged wire was subsequently cold worked. He also found diffraction lines corresponding to body-centered-cubic iron in Debye-Scherrer patterns given by aged and worked specimens but lines corresponding to only one face-centered-cubic phase in specimens which had been aged but not worked. Knoppwost,&apos; and later Cech and Turnbull,5 found that aged Cu-Fe specimens showed a slight increase in ferromagnet-ism after they had be? cooled in liquid nitrogen. Very recently Denney6 followed the kinetics of the precipitation reaction as indicated by the saturation magnetization, hardness, and diffuse X-ray effects. The experimental results reported by all of the authors mentioned above are readily explained in terms of the Bitter and Kaufmann concept. However, most of the evidence is indirect when used to define the structural changes involved. It was the aim of the present investigation to determine the mechanism of precipitation of iron from a Cu-Fe solid solution in the light of available published information and with additional new and more direct experimental data. Experimental Method At 1060°C copper will contain up to 3 atomic pct Fe in equilibrium solid solution.7 The solvus slopes rapidly toward lower iron concentration, so that at 600°C only about 0.5 pct Fe remains in solution at equilibrium. Below the eutectoid temperature (850°C), the iron-rich phase in equilibrium with the copper-rich solid solution consists of body-centered-cubic a-Fe. Above 850 °C the equilibrium iron-rich phase is face-centered-cubic r-Fe. The alloy to be studied was made by melting electrolytic iron and OFHC copper by induction under vacuum in an Alundum-lined crucible. The metal was held molten for about 5 min, after which time the power was turned off and the crucible was tipped about 70" to promote directional solidification. The resulting ingot, containing 2.5 wt pct Fe by analysis, was clean, large grained, and free of gross segregation. Slices % in. thick were cut from the ingot, rolled to 1/8 in. in thickness, homogenized in hydrogen at 1060°C for 24 hr and, finally, quenched in cold water. Specimens for all subsequent tests were made from these slices. Squares measuring about 1 cm on a side were cut from the slices to make specimens for studying hardness and microstructure. Wires (0.020 in.) for the Debye-Scherrer survey were drawn from 1/8 in. sq rods which had been cut from the homogenized slices. Large crystals for observing diffuse X-ray diffraction effects were prepared by mechanically

Jan 1, 1958

By George Rice

Foreword Following the explosion in the Hillcrest mine, which occurred in the evening of Sunday, September 19th, 1926, and in which two men lost their lives, the writer was invited by the Hon. J.E. Brownlee, Premier of Alberta, to conduct an investigation into the causes of the disaster, and to make such recommendations as seemed advisable with a view to minimizing as far as possible the chance of future explosions in this and similar Alberta coal mines. Accordingly, the mine was visited, and extensive investigations were made underground on October 21st, 2.2.nd, and 25th, in company with Mr. John T. Stirling, Chief Inspector of Mines for Alberta, Mr. Moses Johnson, District Inspector for the Crowsnest Pass District, Mr. J as. A. Richards, Inspector of Mines, Edmonton, and also Mr. Thomas Davies, manager, and other officials of the Hillcrest mine. Hearings of the coroner&apos;s inquest were also attended on October 20th and 23rd, when testimony regarding the explosion was given by various witnesses. The following paper summarizes my general observations in tracing the place of origin of the explosion, and my efforts to determine the cause of ignition. Certain recommendations arc also made, and the writer invites discussion on these and the other matters dealt with in the paper.

Jan 1, 1928

By L. Becze, S. J. Hock, G. P. Demopoulos

"Regeneration of HCl from chloride solutions is commercially practiced by high temperature (800-900 °C) pyrohydrolysis associated with high energy consumption and capital cost. As an alternative to pyrohydrolysis a novel low temperature ( <200 °C) non-autoclave hydrolytic process has been studied in this research work, which comprises two steps. In the first step, ferrous chloride is oxidized by oxygen at 1;150 °C, followed by hydrolytic decomposition of ferric chloride to coarse hematite particles and superazeotropic hydrochloric acid (8-9M) operated at approximately 180 °C. This paper provides a summary of the laboratory results related to both oxidation and hydrolysis and presents a newly designed conceptual process flowsheet.IntroductionRecovery of base, noble and rare metals from ores and secondary materials (slags, dusts, residues) by chloride-based hydrometallurgical processes holds a lot of promise if a low cost HCl process becomes available. This is particularly so due to the high activity of HCl or more accurately activity of hydrogen ion [1] in concentrated chloride media and the formation of chlorocomplexes allowing for effective leaching under atmospheric leaching conditions and simultaneous ease of metal separation. However, during leaching significant amount of iron, which is associated with most of ores and secondary materials, goes into the solution. Hence, the obtained leach solution has to be treated to convert iron chlorides into easily filterable iron oxide and simultaneously produce concentrated hydrochloric acid. Apparently the critical operation of these processes is the regeneration of the lixiviant (HCl). Currently in the industry, its regeneration is accomplished by high capital and intensive pyrohydrolysis which operates at 700- 900 °C. Aimed at lowering the operational cost of pyrohydrolysis a process called PORI [2] was developed and tested in pilot plant scale in the 1970s for the purpose of treatment of pickle liquors without, however, resulting in industrial application."

Jan 1, 2011

By David Baker

A Discussion of the Paper of David Baker, read at the Lake Superior Meeting, September, 1904. (Washington Meeting, May, 1905.) MR. JOHN J. PORTER, Chicago Ill. (communication to the Secretary*) :-Mr. Baker&apos;s account of his experiences with stock-distribution has been particularly interesting to me, as it confirms the opinions which I had formed concerning the rapid failure of linings in several furnaces that have recently come to my notice. These furnaces, four -in number, are of modern construction, having been built or remodeled within the past two years, and are equipped with a well-known type of skip-hoist and double-bell charging-apparatus. In every case, a hot spot has developed within a few months after blowing-in, which has already compelled relining in two cases, and the probabilities are strongly against a long campaign in the other two. Since the hot spot in each case appeared in a position approximately opposite to the skip-hoist, and since the sizing, mentioned by Mr. Baker, is very apparent, it would seem as though there could be no doubt concerning the cause of the trouble. Nevertheless, there are some who cannot see it in that light; for the managers of two of these plants, at least, do not admit the existence of bad distribution, and have satisfied themselves by putting in cooling-plates, thickening the lining of the in-wall, and changing the brand of the fire-brick used for the construction of the walls. From observations of the clumping-action of the skip-hoist, and from subsequent inspection of the stock-distribution in the furnace itself, I arrived at the conclusion, some time ago, that no system of filling could be perfectly satisfactory where the stock is dumped into the hopper from one side, also that some

Mar 1, 1905

By David R. Baughman, John C. Gathje, K. C. Oberg, Gary L. Simmons

Santa Fe Pacific Gold Corp. conducted pressure-oxidation pilot plant studies on refractory carbonaceous gold ores from the Twin Creeks Mine in Nevada. The tests were conducted at Hazen Research Inc., Golden, CO, during 1993 and 1994. Laboratory investigations using CIL cyanidation after batch pressure oxidation demonstrated gold recoveries of 90% to 95%. However, pilot plant testing showed that several of the same ore types responded very poorly, with gold extractions of only 45% to 75%. Plant testing was suspended for approximately four months while extensive research was conducted to determine why these ores responded poorly and to identify potential solutions. This paper describes the batch and pilot plant test results, the extensive research activities that eventually identified the cause of the gold recovery problem and the final semicontinuous and continuous pilot plant operations that confirmed possible solutions. Final pilot plant results showed gold recoveries that were consistently greater than 90%.

Jan 1, 1999

By G. Deschenes

"This literature survey discusses the recovery of gold from thiourea solutions. An overview of techniques used and general comments on the basic cyanidation methods are presented. The chemistry and mechanisms of cementation, activated carbon, resins, electrowinning, solvent extraction and pressure reduction are examined. Conclusions and recommendations give orientation for future research and development activities in this field.RésuméCette revue littéraire traite de la récupération de I ‘or des solutions de thiourée. Elle fait un survol de I ‘ensemble des techniques utilisées tout en introduisant des commentaires généraux sur la méthode classique qu&apos;est la cyanuration. La cémentation, Ie charbon active, les résines, l&apos;électroextraction, I ‘extraction par solvant et la réduction sous pression sont les méthodes analysées tout en considérant leur caractère chimique respectif ainsi que les mécanismes qui y sont rattaches. Des conclusions sont tirées et différentes recommandations sont suggérées pour orienter la recherche dans ce domaine."

Jan 1, 1986

By J. W. Hunter, J. H. Jacobs

"Approximately 355 tons of nodules from Chamberlain; S. D., ore were processed in the 1-ton-per-day electrolytic-manganese pilot plant of the Bureau of lanes at Boulder City, Nev., in a continuous 3-month operation. The ore, ground to minus 48-mesh, was found to be amenable to leaching with acid directly or after roasting under reducing conditions in a Skinner muffled multiple-hearth furnace.Unroasted ore gave an acid-leach extraction of 84 to 88 percent of the manganese, which after neutralization showed an over-all extraction of between 81 and 85 percent of the manganese. The amount of iron extracted varied, but it was always,enough to permit the use of ammonia for neutralization.Roasted ore showed an acid-leach extraction of 89 to 91 percent of the manganese. A large amount of iron went-into solution, so that it was not economical to neutralize it entirely with ammonia. By neutralizing with calcine to a pH of 5.0 and completing -neutralization with ammonia to a pH of a.5 an over-all manganese extraction of 84 to 86 percent was obtained. The slight increase in. extraction on roasted ore probably would not justify the cost of roasting.Acid consumption averaged 1.75 pounds per pound of manganese extracted. Settling rates of the residue in leach solution were to slow to permit clarification in thickeners, but a Moore vacuum leaf filter proved to be satisfactory. Purification of raw leach solution was .accomplished readily by hydrogen sulfide with a low gas consumption. Electrolysis was normal, without difficulty, and with -current efficiency ranging between 62 and 66 percent.The use of Chamberlain modules for the production of electrolytic manganese would result in an operating cost of 0.8316 cent per pound higher than the cost of producing electrolytic manganese from Three Wids ore."

Mar 1, 1946