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By Ross R. Bhappu

A theoretical and experimental investigation into pyrometallurgical refining of chloride leach/electrowin copper is described. The two techniques investigated were (i) vaporization and (ii) gaseous halogenation. Experiments were carried out with a packed bed of electrowon copper crystals and a boat of melted copper crystals. Nitrogen gas and Freon 12/nitrogen mixtures were used as the carrier and reac.tive gases. Vaporization was found to be effective in removing Bi, Pb and S while halogenation was effective. in removing As, Bi, Pb, S and Sb. Silver resisted all attempts at removal. Iron was removed but less effectively than the other impurities.

Jan 1, 1985

By Binbin Luo, Northeastern University, Chuanyao Sun, Jie Liu, Yimin Zhu, Yanjun Li

"A series of new type collectors a-bromo-saturated fatty acids, CH3(CH2)5CHBrCOOH (a-BHA), CH3(CH2)7CHBrCOOH (a-BDA), CH3(CH2)9CHBrCOOH (a-BLA), CH3(CH2)11CHBrCOOH (a-BMA) were synthesized from saturated fatty acids and bromine by solvent-free method (Hell-Volhard-Zelinski reaction) in laboratory. The micro-flotation tests of quartz mineral were conducted at a relatively low temperature of 15 °C. The adsorption mechanism of such collectors on quartz mineral surface were established by zeta potential measurements, in conjunction with the results of quartz micro-flotation tests. The flotation results showed that the collecting ability is in the order of a-BMA > a-BLA > a-BDA > a-BHA for the flotation of quartz mineral, which also demonstrating that the a-bromo-saturated fatty acids (a-BFAs) are new selective collectors for reverse flotation to remove quartz mineral from iron ores at a relatively low temperature.INTRODUCTIONThe requirement of higher pulp temperature to maintain the activity of fatty acid anionic collectors which have been widely applied in technological process of iron ores reverse flotation lead to a great deal of energy consumption.The purpose of this paper is to synthesize a new modified collector with carbon chains from eight to fourteen atoms, with strong electronegativity bromine atom introduced into a-carbon position to improve the activity and solubility of the reagent so that it can be adopted at a comparatively low pulp temperature. The collecting performances of these new collectors on quartz surface were studied, and the structure - properties were discussed in light of zeta potential measurements and quantum chemistry calculations."

Jan 1, 2016

By H. R. Babitzke

The purpose of this investigation was to evaluate the potential of columbium-hafnium alloys as structural materials for use at elevated temperatures. The work described in this report was conducted to determine the properties of columbium-hafnium alloys and to select the more promising ones for further improvement. Properties determined in this report were machinability, hardness, workability, tensile strength, and oxidation resistance. Ten ingots, ranging from 100 percent columbium to 70 atomic-percent hafnium, were prepared and subjected to tests. The test results showed that the alloys with 33 and 50 atomic-percent hafnium were superior in workability, strength, and oxidation resistance. For the alloy series tested, the strength and hardness values increased with the increasing hafnium content. Maximum values were reached with 50 atomic-percent hafnium. The oxidation resistance was poorest at the 1 atomic-percent hafnium level but improved with increasing hafnium content through 70 atomic-percent. Eight of the ten ingots were fabricable at room temperature. The two remaining ingots, those with 5 and 10 atomic-percent hafnium, required hot-working.

Jan 1, 1962

By J. W. Meier

Introduction The great importance of air warfare during World War II and the introduction of large-scale air transportation and airborne operations created an immediate demand for large quantities of high quality light alloy products. Before this war, the use of magnesium, the lightest structural metal, was barely in the development stage, and considerable research work was needed to overcome difficulties in improving its properties and to attain uniform quality in mass production of magnesium alloy products. The Canadian Bureau of Mines was frequently called upon, by various agencies of the Armed Forces and of the newly established war industries, to examine magnesium alloys that had failed in fabrication or in actual service, and to advise on proper alloys and fabrication methods to be used. Failures in magnesium alloy castings were connected mainly with lack of knowledge of proper founding and surface-protecting techniques. Most of the defects were due to microporosity and faulty heat treatment. To aid the foundry industry, small-scale investigations were started on the effect of various factors in the casting technique in order to improve the quality of the products. These investigations were made in co-operation with representatives of the Armed Forces and the Canadian magnesium industry. This work was later co-ordinated into a broad research programme on magnesium alloys, comprising problems on melting, refining, various casting methods, heat treatment, and testing of properties of standard and special alloys. This research programme? is still in force, and the present paper contains some results of the first series of investigations on magnesium casting alloys carried out at the Experimental Foundry of the Bureau of Mines.

Jan 1, 1948

By Thomas F. Evans

Niagara Mohawk, like other northern coal users, has long experienced increased costs during winter months as a consequence of handling frozen coal. These costs include operating labor, maintenance labor and materials, equipment rental, fuel for thawing, demurrage, carrying costs for excess coal inventory and substitution of higher cost electrical generation for lost production capacity. In the winter of 1978-79, limited trials of several coal freeze conditioning agents were made to determine whether these would provide a cost-effective means of reducing the problems of handling frozen coal. Since these trials were generally effective, the Coal Purchasing Department arranged that all rail coal received during the 1979-80 winter from early December to mid March would be treated at the mines during loading. Inasmuch as the treatment costs are themselves appreciable and our various coal suppliers made a variety of choices of chemical supplier and equipment for application, an attempt was made to evaluate the unloading performance of each train received at the two generating stations which use coal as an aid in the future optimization of the use of freeze conditioning agents. These stations also receive coal by truck but this coal is not treated because of the short hauling time. The C.R. Huntley Station in Tonawanda, NY has a capacity of 800MW and burns about 5000 tons of coal per day during the winter months. The coal is primarily from central and western Pennsylvania but one source in southern Kentucky is also used regularly. Most of the Pennsylvania coal is washed and the fines are thermally dried. The coal is delivered in unit trains made up of mixed cars of 60, 75, and 90 ton capacity. Time between loading and arrival at the station averaged five days and ranged from three to eleven during the 1979-80 winter season.

Jan 1, 1980

By Bryn Harris

Much has been written over the past twenty years on the removal and chemical stabilization of arsenic from metallurgical process solutions. This paper reviews again the latest developments in this field, and concludes as before that the high-iron arsenical ferrihydrites, together with the high temperature arsenic minerals, scorodite and Type II, remain as the best and most viable vehicles for industrial control and disposal. However, a cautionary note is introduced, in that chemical environments cannot be considered in isolation, and that cogniscence has to be taken of microbiological activity in determining the disposal method. Data are also presented on a survey of industrial practice, which shows that arsenical ferrihydrite is by far the most widely-practiced and accepted method used worldwide. Finally, the disaster in Bangladesh is briefly discussed with reference to lessons that the metallurgical community might learn from this.

Jan 1, 2003

By Courtney Young, Jerome Downey

"The various technologies developed for treating spent potlining (SPL) from primary aluminum smelters have been reviewed on several occasions. The technologies generally involve physical, chemical, and thermal processes, either individually or in combination, with the primary objective of total recycle, waste minimization, or complete disposal. In general, those technologies geared for recycling involve separations and are therefore subject to recovery inefficiencies that are attributed to several factors. However, the inefficiencies could be reduced or possibly eliminated if the pots were designed for recyclability. This concept is applied to SPLASH, a recently developed SPL management technology.IntroductionAluminum is produced by molten salt electrolysis via the Hall-Héroult process. The process is conducted in an electrolytic “pot,” which is comprised of a steel frame first lined with insulating refractory brick, and then conductive graphite blocks, which serves as the carbon cathode [1, 2]. These materials are collectively referred to as “potlining.” Anodes comprised of petroleum coke/pitch are suspended above the pot and extend down into the molten cryolite (Na3AlF6) electrolyte. The electrolyte temperature is maintained at approximately 980 °C by resistance heating as low voltage (4-5 volts) and high current (50,000-300,000 amps) are applied across the two electrodes.High purity alumina is added to the cryolite bath, where it dissolves and becomes amenable to aluminum reduction at the cathode:"

Jan 1, 2008

By C Sylvestre

Leaders have invested heavily in traditional safety management to improve safety performance over the years. This primarily involved: • fixing the environment (eliminating the hazard) • improving the system (more/less rules, procedures etc) • making safety more conscious (more/better interactions about the importance of safety). These approaches have helped improve safety performance significantly during the last 50 years and will continue to play a role in the future. Although these approaches may be part of an overall solution, they are not enough to prevent many incidents. Today, these three approaches are used more than before, and are used better than ever before. Yet, workplace fatalities in Australia have stagnated from 2013 to 2019, as have the number of incidents, even serious ones. In the USA, workplace fatalities have increased by 15 per cent in the same period.

May 5, 2022

By Barry L. Warner

This program involves testing to determine whether a fire hazard exists when the exposed wood surface area of timber in a mine passageway equals 40 percent of the surrounding strata surface, excluding the sill. Twelve full scale fire tests were conducted in a simulated mine passageways, using kerosene pan fires as the ignition source. The tests included three timber sizes, plus one test with roof lagging, two wood types, plus one test with treated timbers, and two ventilation air velocities. The results show air velocity to be an important factor in the occurrence of flame propagation, and that the 40 percent surface area ratio of wood to surrounding strata appears to b0. a valid criteria for fire safety at 150 fpm, but not at 350 fpm.

Jan 1, 1975

By Kaustubh Joshi, Pradip, Beena Rai, Kesri L. Menaria, Venugopal Tammishetti

"Beneficiation of alumina rich iron ore slimes is a major challenge for the Indian iron ore industry. High alumina is deleterious for the performance of both blast furnace as well as sintering plants. Slimes generally contain 5 - 10% alumina, and hence despite assaying as high as 60% Fe, those are dumped in tailing ponds. The slimes are typically less than 37 microns. Selective flocculation of iron ore slimes using highly selective reagents is thus an option worth exploring. Our research is directed at employing state-of-the-art molecular modeling techniques for the selection/design of selective reagents for this separation. We have earlier reported our results on starch as a selective flocculant for iron ore slimes. In this paper, we present our results on the selective dispersion-flocculation of natural iron ore slimes using guar gum flocculant. With careful selection of various process parameters such as flocculant dosage, dispersant dosage, pH and settling time, we were able to obtain a concentrate assaying >66% Fe and <3.5% Al2O3 with an yield of 65 to 68% (recovery of iron values more than 70%) from a natural iron ore slime sample assaying 58% Fe and 7% Al2O3."

Jan 1, 2014

By M. Dupuis

It has been previously demonstrated [l] that there is no obvious thermal balance related issue limiting the size of a Hall-Héroult cell. Yet, it is well known that a forced-air sidewall cooling system is part of the AP50 cell design [2], In the present study, the authors analyze the impact of thermal loading on the mechanical deformation of high amperage cell potshells. The effect of adding cooling fins or a forced-air sidewall cooling system is then assessed.

Jan 1, 2005

By Naeimeh Shabani, Hamid Mirzaie, Javid Sadeghi, Hoda Jafarizadeh-Malmiri, Afshin Javadi

Iron oxide nanoparticles (Fe3O4 NPs), despite their small size, are stable and have a large surface area that allows for absorption and removal of ions as well as turbidity in a short period of time. Thus, the present study addressed the synthesis and characterization of Fe3O4 NPs synthesized using the co-precipitation method and evaluated their effect on the coagulation process in water treatment. The Fe3O4 NPs characteristics were evaluated as follows: magnetic properties were measured using a vibrating sample magnetometer (VSM), surface area using Brunauer–Emmett–Teller (BET), crystal phase using X-ray diffraction (XRD), and morphology using field emission scanning electron microscopy (FESEM). In addition, the effects of the synthetic Fe3O4 NPs on the turbidity reduction of water in various pH levels were evaluated. The synthesized Fe3O4 NPs were without any impurity in the sizes of 22–32 nm, surface area of 99.6 m2/g, pores’ mean diameter size of approximately 10.6 nm, and maximum magnetic saturation of 66.21 emu/gram (emu/g). Using 0.2 g of synthetic Fe3O4 NPs with an initial turbidity of 17 NTU and pH of 6 could reduce all water turbidity (100%). Considering the cheap and facile production and separation, as well as the possibility to reuse them and reduce the sludge water content, iron oxide Fe3O4 NPs can be effectively used for turbidity reduction in the water treatment process.

Oct 26, 2020

By Gustavo Díaz, Miguel A. García, Carlos Frías

"Under the auspices of the Commission of the European Union, a consortium composed of six European organi~ations has conducted a project to scale up the PLACID electrowinning cell to industrial size within the Placid process development. This paper is concerning the results and achievement of the industrial cell prototype after more than 1,000 hours operating time and about 10,000 Kg electrolytic lead production. In general, results have been very satisfactory, demonstrating the ability ofthe PLACID electrowinning cell to produce top quality electrolytic lead (> 99.99 %) with high current efficiency and low energy consumption.IntroductionThis paper is concerning the development of an industrial size PLACID electrowinning cell within the PLACID process development. This project began on January 1993 and was finished on April 1996.Lead metal production and manufacturing industries produce large amounts of dusts and also lead bearing slags. Spent lead-acid battery recycling also produces lead oxides from the battery pastes rather similar to those mentioned above. Those lead secondary materials are hazardous and difficult to handle by usual procedures.Existing processes to treat-lead oxides may inflict considerable damage on the environment, incur high operating costs and have limitations to produce top quality lead.The main aim of this project has been to develop a novel hydrometallurgical process able to deal with different lead bearing materials, mainly lead oxide secondaries: lead-acid battery pastes, lead fumes, furnace slags, oxide residues, etc., producing ""four nines"" pure lead in an efficient manner with a benign influence on the environment; it is called the PLACID process."

Jan 1, 1997

By Pietro Navarra

Cooling of critical furnace equipment to produce freeze lining is of particular interest as many metallurgical processes are intensified while attempting to prolong campaign life. This idea was combined with high-capacity heat pipes in the design of a copper slag launder. The design methodology of the launder and heat pipe cooling system is examined in this paper. With reliable material properties and operating conditions, CFD was used to quantitatively predict the skull thickness and the corresponding heat load applied to the slag launder. The operational limitations of heat pipe technology were considered and an appropriate cooling system was incorporated into the model. Parametric modeling was used to simulate several launder and heat pipe configurations. The generated results were then used to optimize the design of the launder, which was built and tested in August of 2005. The experimental performance of the cooling system is evaluated and compared with the model results.

Jan 1, 2006

By Eleonardo Lucas, Christ Barriga

The use of saline water, a product of the sea water osmosis process, for the processing of the mineral from the Bayovar Mine in Peru, is part of the process of final disposal of the studied tailings. In this sense, this paper presents an experimental program implemented for the correct evaluation of this fine low-density phosphate tailings, the behavior of six solids contents prepared in the laboratory with limits between the range 8.5% to 21% were analyzed. The results achieved, from settling and consolidation tests by hydraulic consolidation test, attested to the effectiveness, in addition to being representative, based on the analyzes and comparisons instituted and the definition of the compressibility and consolidation characteristics of the phosphate tailings of the evaluation.

Sep 30, 2022

By Y. Wang, G. Xu, N. A. Amoah, A. Kumar

Mining-induced coal dust causes various respiratory diseases to mine workers, such as coal workers’ pneumoconiosis (CWP). Current available underground monitors are expensive, heavy and only measure mass concentration. These disadvantages limit them for regulatory sample monitoring purposes only while personal exposure levels for most miners remain unknown, risking miners to potential overexposures. Low-cost light scattering PM sensors offer a potential solution to this problem with capability of high spatio-temporal resolution PM characterization. However, these sensors require careful calibration before they can be applied in mining environments. There is basically no comprehensive study in the literature using a standard protocol assessing these sensors for coal dust monitoring. With the aim of calibrating the PMS5003 sensors for coal dust monitoring, we design the calibration method and system to calibrate these low-cost PM sensors coal dust monitoring. Working principles of present coal dust monitor and low-cost sensors are presented in detail. The linear regression calibration model which is used for the sensor calibration is further described. Sensor calibration and evaluation protocols are comprehensively compared and discussed. This investigation reveals the feasibility of low-cost sensors for real-time personal coal dust monitoring in underground coal mines.

Mar 2, 2022

The introduction of nitro-carbo-nitrate (NCN) blasting agents has been one of the most significant innovations in the explosive industry in the last twenty years. The most commonly used blasting agent is a rather narrowly proportioned mixture by weight of 94% ammonium nitrate (AN) and 6% No. 2 diesel fuel oil (FO) that is generally designated as ANFO. Other formulations have been developed but none of these have been as extensively used as ANFO. The relative safety of the nitro-carbo-nitrate (NCN) blasting agents almost immediately suggested bulk loading techniques to obtain economies in materials handling. The first attempt at bulk handling was to pneumatically load boreholes with ANFO. When the initial experiments were made in 1957, it was apparent that there were three problem areas which needed study to minimize potential hazards. These were: 1. Static Electricity 2. Fumes 3. Safe Handling Procedures Since those early days, considerable work has been performed in evaluating these problem areas and in arriving at procedures and recommendations that would provide the required safety. Despite the relative insensitivity of ANFO type products, all normal practices for the safe handling of explosives should be obselved. Smoking should not be tolerated in the vicinity of blasting agents and misfires should be handled in the same manner as a misfire with a dynamite charge. The purpose of this Technical Report is to discuss the problems of static electricity and fumes and the solutions that have been developed. Safe handling procedures have been discussed by the Bureau of Mines and are specified by various state and local regulations. Since regulations vary from state to state, the local, applicable regulations must be followed within the area of their jurisdiction. General information is contained in a U. S. Bureau of Mines report, IC 8179, "Safety Recommendations for Sensitized Ammonium Nitrate Blasting Agents" (1963).

Jan 1, 1973

By K. Rainer Massarsch

In some parts of the world, vibrators are used extensively for different types of foundation engineering projects. If used correctly and in suitable soils then vibratory pile driving for example is very efficient. However, soil conditions and the installation procedure have great significance for the driving resistance and affect the bearing capacity of vibrated piles. Also the intensity of ground vibrations which are transmitted to the surrounding soil is affected by the vibration process. In spite of the increasing use of vibrators and the rapid development of vibrator technology, many aspects of pile-soil interaction are not yet understood. In order to asses the importance of factors, which govern pile installation (and extraction), it is necessary to consider the entire chain of vibration energy transmission from the vibration source to the pile, the interaction between the vibrating pile and the soil and the wave propagation in the subsoil, Fig. 1. [ ] Fig. 1. Transfer of vibration energy from the vibrator through the pile into the ground In the present paper, some important aspects of vibratory driving and their significance for pile installation and soil compaction will be discussed.

Jan 1, 1995

By Claude Hubert, Robert Sansfaçon

"The Malartic gold camp includes the Malartic Gold Fields, Barnat, East-Malartic, Canadian Malartic and Sladen mines. From 1935 to 1984, these mines have yielded 212 403 kg of gold. They occur within a 900 m wide belt of highly sheared, dislocated and faulted volcanic and sedimentary rocks (Piché and part of the Pontiac groups) herein named the Malartic Tectonic Znne (MTZ). The zone trends WNW-ESE and separates two lithotectonic sedimentary domains, the Cadillac to the north and the Pontiac to the south. The sedimentary domains are characterized by their coherent fold generations consisting of open to tight reclined and recumbent F1 folds that have been refolded into series of asymmetric upright F2 folds. A flat-lying schistosity (S1 ) and a vertical pressure-solution cleavage (S2) are ubiquitous throughout. Discrete sets of brittle and brittleductile faults are synchronous and parallel to each of these two fabrics.The MTZ trends N320° in the northwestern sector of the town of Malartie, changing to N2800 at its easternmost extremity. The Malartie and Sladen faults constitute its northern and southern boundaries respectively. These two faults also bound another set of faults oriented N305°. Throughout the MTZ, the faults at N280° and N320° and those at N305° outline a series of anastomosed motifs that constitute the principal structural feature of the Malartic district. Locally, a fourth set of minor faults at N065° combines with the other three prominent sets. All these faults have disrupted the gold-bearing volcanic, sedimentary and intrusive rocks encountered throughout the MTZ.The MTZ comprises numerous lozenge-shaped blocks of komatiites and basalts or greywackes and black shales which are cut by disjointed dikes, sills and small intrusions of felsic and mafic rocks. The latter includes gabbro, diorite, lamprophyre, monzonite and pegmatite. They frequently fill conjugate sets of fractures. In some areas, they are clustered into coalescent intrusions. The present morphology of these intrusive bodies( cube, chocolate-tablet boudin, parallel epiped and cigar) is not representative of their primary forms but the result of late shearing and faulting indicative of a major tectonic event subsequent to their emplacement. The intrusions were injected during a brittle stage of deformation related to the F1 folding but prior to the development of the F2 folds and subsequent tearing and shearing by late brittle and brittle-ductile faults . The ultramafic and mafic rocks are intensely altered to serpentine, tremolite, actinolite, carbonate, biotite, hematite and pyrite according to the nature of their proto/it h. In the vicinity of the MTZ, all lithologies exhibit mineral assemblages indicative of the upper greenschist or lower amphibolite facies of metamorphism.The structural evolution of the MTZ involved superimposed folding, shearing, transposition, mylonitization, brittle and brittle-ductile faulting. Each lenticular motif results from the combined effect of conjugate sets of shear zones that outline lozenge-shaped blocks where strain markers indicate different strain states from cores to margins. Bedding in ultramafic flows and/or sedimentary rocks is either NW-SE or NE-SW within the blocks but, in the vicinity of the Malartie and S laden faults, it has been rotated to become subparallel to the faults.Ore shoots are most commonly associated with altered and deformed bodies of diorite and monzonite, or some mafic and ultramafic schists and, at the Canadian Malartic, Sladen and East Malartic mines, with metasedimentary rocks. The shoots occur in close proximity to the various faults of the MTZ but the gold itself is intimately associated with pyrite, biotite and carbonate in halos bordering fractures crisscrossing the different host rocks. The density of fractures and the width of their altered zones have been significant parameters in the production of economic ore shoots. Grains of gold are visible in some veins of quartz a"

Jan 1, 1990

This paper was developed as part of an effort by the National Institute for Occupational Safety and Health (NIOSH) to identify risk factors associated with bumps in the prevention of fatalities and accidents in highly stressed, bump-prone ground conditions. Changes of failure mechanism with increasing confinement, from extensional- to shear-dominated failure, are widely observed in the rupture of intact specimens at the laboratory scale and in rock masses. In the previous analysis conducted in 2018, both unconfined and triaxial compressive tests were conducted to investigate the strength characteristics of some specimens of a Utah coal, including the spalling limits, the ratio of apparent unconfined compressive strength (AUCS) to unconfined compressive strength (UCS), the damage characteristics, and the post-yield dilatancy. These mechanical characteristics were found to be strongly anisotropic as a function of the orientation of the cleats relative to the loading direction.

Jan 7, 2020