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By M. S. Badollet

"The study of the physical properties of asbestos minerals requires a careful isolation of the fiber from the wall rock and, at a later stage, a comparison of these physical properties with those of fibers that have passed through the milling and beneficiation processes.The effects of mineral impurities, loss of fiber length and the formation of extreme fines (asbestic and/or associated minerals) often show up in the formation of special asbestos products as well as in the commercial production of asbestos papers, mill-boards, asbestos cement products, plastics and insulation materials, and in the filtration of blood plasma and wines.Numerous test methods have been developed in Canada and in England for use in the asbestos industry. Special treatments of asbestos fibers have been used to improve their physical and chemical properties and to eliminate impurities.Numerous problems connected with the use of asbestos fibers are discussed, such as the effects of asbestos on filtration, surface area, surface treatments using organic or inorganic materials, the surface charge on the fiber, the presence of magnetite and air pollution elimination. Biological studies on finely ground asbestos, when dispersed in 0.9 per cent sodium chloride solution and then sterilized and injected into hamsters, show that by reducing the dose, the tissue damage can be largely avoided. In these experiments, Arizona asbestos fibers were carefully extracted from the wall rock, finely ground, and examined chemically and micros-copically for any mineral impurities that might be present so that any effect on the hamsters would be directly due to the presence of the asbestos. The harsh Arizona fiber induced more extensive tissue response than the soft fiber when tested in hamsters."

Jan 1, 1969

By A Domanti, C Jewkes

This paper describes the design and constructability issues investigated in the selection of a trenchless solution in comparison to trenched construction options as part of a scoping study for the augmentation of the existing Bulimba Creek Trunk Sewer in Brisbane. Initial work involved the planning of alignment options vis-a-vis ground geology, geotechnical conditions, location and depth of shafts considering potential construction technology, flotation and stability of the tunnel, availability of construction sites and the influence of construction works on neighbourhood properties and the immediate environment. Two design pipe sizes, DN1200 and DN1500, were considered, and factors including jacking forces, specification of product pipes, pipe joints, pipe jacking methods and the associated impacts of ground settlement were carried out. Of particular interest was research on suitable lubricating fluids with the potential to minimise jacking forces and maximise the length of pipeline between launch and reception shafts.

Jan 1, 2008

By Donald R. Rathburn, Jung K. Mok

An historical review and a survey of current practice in the application of fine dry grinding in the iron ore industry are given. Both closed and open-circuit applications are reviewed, and the advantages, disadvantages, and process considerations for these two systems are discussed. The ground ore temperature rise, and the cool-ing of ground ore and mill ventilation are also discussed, along with the agglomerating characteristics of dry ground ore. Screening during the production of high-grade lump ore for blast-furnace burden, particularly from recently developed ore deposits in Australia, South America, and Africa, has resulted in large tonnages of fine iron ore. Certain owners have decided to stockpile these fines until some later date. Others have either sold these fines "as is" for agglomeration at the steel plant or have established their own pelletizing plants to produce a premium quality agglomerate. In almost all cases some grinding is required prior to pelletizing. Most of these ores occur in the weathered state which may result in difficulty in the thickening and/or filtering stages when ground in a wet system. The resulting filter cake would probably require partial drying to provide a product suitable for the subsequent balling operation; however the partial drying and subsequent material-handling steps often produce random agglomeration. Normally, these agglomerates will cause problems in the green ball formation process. Thus dry grinding has developed as a solution to this problem. Most of the dry iron ore grinding installations utilizing the standard-type rod or ball mill are grinding high-grade natural ores that do not require beneficiation. Although power consumed per ton of final product is 120% or greater in dry grinding as compared with wet grinding, the additional power required for dewatering and handling a wet ground product can easily exceed the initial power savings. Dry grinding of raw feed and clinker has been practiced in the cement industry for many decades but its major application to the iron ore industry has taken place only within the past ten years. The successful application of dry grinding to iron ore has required the solution of several unique design and operating problems. The purpose of this paper is to review recent developments in fine dry grinding of iron ore for pelletizing and to discuss the various designs and operating parameters involved.

Jan 1, 1971

By D. Panias

Alumina hydroxides such as gibbsite (Al(OH)3) and boehmite (AlOOH) are precursors of many types of alumina that find important industrial applications. The thermal decomposition of AlOOH, which is a more energy saving precursor compared to gibbsite, gives rise to the formation of ?-, d-, ?- and a-aluminas that are used for the production of catalysts. The applications of the aluminas are governed by their properties that are a function of the precursor material and its microstructure. The microstructure in turn is a factor of the method and conditions applied, as well as, in the case of soft chemical processes, on the anions present. Towards these ends, this study was focused on the effect of different anions on the physicochemical characteristics of the alumina hydroxides precipitated in the first 5 minutes after the perturbation of the stability of a supersaturated sodium aluminate solution (Bayer liquor).

Jan 1, 2006

By Robert W. Bartlett

"Bioheap pretreatment of sulfidic refractory gold ore prior to cyanide leaching is a promising new technology, especially for low-grade ores that cannot afford to be oxidized by pressure leaching or roasting. When an ore contains both refractory and non-refractory (oxidized) gold, an economic decision must be made whether, or not, to pretreat before cyanide leaching. This choice is more complex than the familiar ore/waste cut-off grade decision. Pretreatment usually increases recovery but delays receiving revenue. Based on choosing the processing route that maximizes the present value of the ore, an equation is developed that computes a ""critical cyanide leachable gold grade"" for determining whether pretreating will be profitable. If the ore's actual cyanide leachable grade, without pretreatment, is above this ""critical grade,"" it will not pay to pretreat. The waste/ore cut-off grade, pretreatment yield (leachable grade after pretreatment), total gold grade, pretreatment operating cost and the project's financial discount rate are parameters in the equation. Results of example calculations are provided. This equation can be used for mine development planning and, when bioheap pretreatment is an available option, for daily operating decisions on individual ore blocks.IntroductionOres that are refractory because of sulfide mineral encapsulation of microscopic gold are becoming important. These ores must be pretreated to oxidize the sulfides to liberate the gold prior to cyanide leaching. The conventional pretreatment process technologies are pressure leaching with oxygen and two-stage fluid bed roasting. However, low-grade refractory ores cannot afford the high operating costs of these processes. And, small mines with limited reserves cannot justify the high capital costs of these processes."

Jan 1, 1997

By D. C. McLean

One of the few innovations in hydrometallurgy in recent years has been the utilization of the chemistry of basic iron sulfates called jarosites. These have been used to make iron-zinc separations in the processing of zinc concentrates and are a very important factor in both the Duval and Cymet copper chloride processes as a means of preventing iron build-up in the closed leaching circuits. Copper oxychlorides are kindred compounds in that they are insoluble basic salts that form at low pH (1.5 to 3) and precipitate selectively from many base metal solutions. They have been reported in the chemical literature as far back as 1860, and a few of them are known in their mineralogical forms (particularly atacamite) usually as nuisance minerals because of their chloride content. Several patents describe their synthesis and use as fungicides and insecticides, and papers have discussed their formation as corrosion pro¬ducts on copper and brass piping (14).

Jan 1, 1979

By Peter Sylvén, Darwin Morales

Despite being crucial for the smelting process, furnace tapping using oxygen lances has not been considered an operation that brings value. Therefore, these important tools have not seen a significant change in over 100 years. Problems related to the use of oxygen lances include: • Inaccurate tool: causing damages shortening the life of the taphole refractories. • Safety: extended exposure to the operator in an unsafe area of the furnace. • Cost: high oxygen consumption & high lance consumption. • Time consuming and frustrating to connect one lance to another. This paper will suggest a very good solution; new concept thermal lances. We will show how these provide an outstanding performance for a more efficient, faster and cost-effective furnace tapping operation. These new lances are very accurate tools that enable the operator to perform a more controlled operation; resulting in longer taphole life, fewer repairs and less down-time.

Jan 1, 2016

By J. C. Allan

THE purpose of this paper is to outline the pogress made in the development o the gravity separation method o ore dressing known as Sink-and-Float, which, in the opinion of the writers, has now reached a stage justifying the claim that this new method marks a highly important advance in the technique . The essential feature of the newest development of this process is the extremely accurate separation achieved. This is responsible for higher extraction in the sink-and-float unit on coarse sizes and, in consequence, for substantially higher overall recoveries. Whilst this is the most remarkable feature of the new process, it has further important contributions to make to ore dressing under the following heads: (1) The introduction of the sink-and-float separator as a buffer helps to iron-out irregularities in the mill feed. By supplying a concentrate of constant grade to the flotation section, the process also indirectly improves overall recovery. (2) The addition of a sink-and-float unit to an existing mill results in substantial increase in capacity at low per ton capital cost. (3) Where the plant can be installed underground for the pre-treatment of low-grade ores, there is a saving in hoisting costs, and excellent 'fill' is provided near the point of use. ( 4) Low-grade mixed oxide-sulphide copper ores may be pre-concentrated, thereby producing a flotation feed sufficiently rich to render the oxide residue from such flotation economic for subsequent treatment by leaching or other methods. (5) Application of the process eliminates hard gangue constituents which cause high grinding costs, or gangue constituents which adversely affect flotation. The plant is compact and easily controlled. No highly skilled operators or expensive reagents are required, and the labour and power per ton are low. The separator is extremely flexible, working equally efficiently on any throughput up to its maximum capacity.

Jan 1, 1940

By L. Xia, B. Hart, K. Douglas

In the flotation of Rare Earth Element (REE) bearing minerals, oxalic acid is reportedly acting both as a depressant and pH modifier. Testing has established the significance of oxalic acid in the flotation process however its specific role in either the recovery or selectivity of REE over their gangue minerals is not well understood. Pulp pH reduction trials with alternative acids have not shown the same effect on the REE mineral recovery or the depression of gangue phases. This work examines the effect of oxalic acid on the surface of gangue minerals (quartz and carbonates (dolomite and calcite)) in a series of conditioning tests. Gangue surface analyses by TOF-SIMS indicate that oxalic acid inhibits the transfer of secondary ions generated during the conditioning process from one mineral phase to another. In this regard, the oxalate anion acts to fix ions in solution through chelation, limiting their participation in surface adsorption.

Jan 1, 2014

By Z. Trojanová

The deformation behaviour of ternary magnesium alloys AJ (Mg-Al-Sr) and AX (Mg-Al-Ca) were investigated in tension as well as compression tests. The samples were deformed at temperatures between 20 and 300 °C and at an initial strain rate of the order 10-4 s 1. The flow stress decreases with increasing temperature. The macroscopic work hardening rate decreases with increasing flow stress and temperature. The stress and temperature dependence of the work hardening rate is a result of the hardening and softening processes. Stress relaxation experiments were performed in order to reveal features of the thermally activated dislocation motion. Internal and effective stress components of the applied stress were estimated. A decrease in the internal stress was observed at elevated temperatures, which indicates recovery process (-es). A more detailed analysis of the estimated values of the activation volume and activation energy helped to interpret the thermally activated processes during plastic deformation. It is concluded that the deformation behaviour of the alloys depends on the activity of non-basal slip that is strongly influenced by temperature.

Jan 1, 2007

By A. M. Raichur

The selective adhesion of hydrophobic Mycobacterium phlei to coal particles is responsible for flocculation of fine coal from associated ash forming minerals. The driving force for the differential adhesion is the hydrophobic interactions between the fatty acid surface of the organism and hydrophobic nature of coal. The effect of Mycobacterium phlei on surface hydrophobicity, surface charge and mechanism of adhesion on coal and associated minerals are controlled by several factors including hydrophobicity and surface and solution chemistry of the system. Adhesion measurements indicate that maximum adhesion occurs below the isoelectric point (IEP) of the coal particles. While massive adhesion of Mycobacterium phlei is observed on coal, however, negligible amount of Mycobacterium phlei attaches to mineral pyrite and quartz.

Jan 1, 1995

By Robert P. Moodry

It was attempted to revitalize an old sulfide leach dump by increasing the oxygen content within the dump. Compressed air was introduced into the old dump. This was accomplished by drilling 300 foot angle holes into the dump surface with an Aardvark drill which holes are then cased with 1-1/2 inch perforated PVC pipe. Compressed air is injected through these cased holes during a 10 day rest cycle. The second case consists of bedding perforated polyethylene pipe at the interface between the old dump surface and the next Lift of a new dump. Compressed air is then blown through the bedded perforated pipe on a continuous basis while leach solution is applied.

Jan 1, 1976

While the United States and the rest of the world struggles with record-setting oil prices Canadian oil sands producers are ramping up production to meet demand for oil while also fighting against a host of negative images. In recent months, the price of oil has skyrocketed. Most of that oil comes from Saudi Arabia. In Alberta, Canada there are unconventional oil reserves that rival those in Saudi Arabia in the vast Canadian oil sands, sometimes called the tar sands. Proponents of the oil sands say that Alberta?s oil sands can be a secure source of oil and energy for the United States for many years to come. With new mining and drilling projects, the industry has said that it could quadruple its production to nearly 4 million bbl/day by 2020. Time magazine once called the oil sands, ?Canada?s greatest buried treasure that could satisfy the world?s demand for petroleum for the next century.? So why hasn?t the United States embraced this close, politically secure source of energy? Because, getting usable fuel from the oil sands can be a dirty business, say opponents. The oil sands are a combination of clay, sand, water and bitumen. It is a heavy, black, thick oil. Oil sands can be mined and processed to extract the oil-rich bitumen, which is then refined into oil. The bitumen cannot be pumped from the ground in its natural state. Instead, tar sand deposits are mined, usually using strip mining or openpit techniques, or the oil is extracted by underground heating with additional upgrading. These methods require a huge amount of energy and water and produce a large amount of carbon emissions. Environmental groups that have long spoken out against the oil sands projects got some political backing in the United States in June when a group of mayors from large U.S. cities spoke out against the oil sands, as did presumptive Democratic candidate for U.S. president Barack Obama?s senior energy advisor. During a convention of large-city mayors in Miami, FL, Alberta?s oil sands were singled out in a nonbinding resolution calling for national guidelines to track the lifecycle impact of different types of fossil fuels. The resolution urges cities not to use unconventional sources of energy with a large carbon footprint, such as liquid coal and oil shale and oil sands.

Jan 1, 2008

By Robert C. Johnson

Single crystal whiskers of ZrO2 and TiO2 were grown by solution and crystallization of these oxides in molten baths. Mixtures of Na2B407 and LiC1 were the most suitable growth media for zirconia. Sodium borate alone and Na2CO3 plus SiO2 were best suited for titania. The solubilities of zirconia and titania in molten sodium borate were determined, Whether zirconia whiskers were dendritic or nondendritic depended on the temperature used. The best single crystal whiskers were grown below 1,100° C. Titania whiskers always grew as single crystals. The tensile strengths of zirconia and titania whiskers were about 15,000 psi and 50,000 psi, respectively. Modulus of rupture was about 49,000 psi for zirconia whiskers and 75,000 psi for titania whiskers. Chemical analyses showed the zirconia and titania whiskers to be pure. The zirconia and titania whiskers were shown by X-ray analysis to be, respectively, baddeleyite and rutile.

Jan 1, 1965

By J. J. Moore

Combustion synthesis or self propagating high temperature synthesis (SHS) reaction systems are discussed with respect to thermodynamics and kinetics. In particular, tile effect of the process parameters, ego particle size, AHf, ignition and combustion temperatures on these self sustaining reactions is discussed. Combustion theory is used to investigate the effect of the overall activation energy of the SHS reaction on the combustion front propagation rate and in obtaining a clearer understanding of the transition from stable to unstable propagation. Finally, examples of the application of combustion synthesis to advanced materials processes are made, in particular the synthesis of Ni-Ti -X intermetallic shape memory alloys, TiC-Al2O3 and ZrB2 ?Al2O3 ceramic composite materials.

Jan 1, 1991

By Gordon Clark, Basar Arioglu, Zlatanic. Sanja, Nasri Munfah, Togan. Tolga

"The 13.2 m external diameter double deck Istanbul Strait Road Tube Crossing is one of the most challenging underwater tunnel projects in the world. Subjected to 11 bars of hydrostatic pressure, variable geology, and being in a very active seismic area, the execution of the project required innovative solutions, sophisticated construction techniques, and prudent risk management approach. The 5 km tunnel consists of 3.4 km TBM bored tunnel, 1 km twin NATM tunnels, and cut and cover sections. The project is being delivered in a Build-Operate-Transfer (BOT) contract in a public-private partnership. The technical challenges, coupled with financial and commercial risks required the implementation of sophisticated risk management tactics including the provision of Independent Design Verification. Presently, the project is in its advanced stages of construction with a recent successful TBM breakthrough on August 22nd 2015. The paper presents the technical challenges of the project from the design, construction, and risk management aspects and provides the status of the construction. PROJECT BACKGROUND The $1.245 billion Istanbul Strait Road Tunnel Crossing project, dubbed the Eurasia Tunnel, is one of several major infrastructure projects being implemented in the Republic of Turkey in a public-private partnership approach. The project provides a direct and easy connection between the Anatolian (Asian) side of Istanbul and the heart of its historical district on the European side across the Bosphorus Strait which connects the Black Sea with the Sea of Marmara. Upon its completion in 2017, the project will improve connections to a wide network of motorways on both sides, increase capacity across the Bosphorus by 100,000 vehicles a day, reduce congestion and save motorists an average of 45 minutes of commuting time in each direction, and bringing significant economic benefits to the city and the region; it will ease traffic across the strait, reduce congestion, decrease pollutants and emission while maintaining the historical silhouette of the city. Figure 1 provides a general view of the project location and alignment. The overall project consists of three parts totaling 14.6km. Parts 1 and 3 consist mainly of widening existing motorways, providing connections to existing roads, reconstructing local bridges and underpasses on the European and Anatolian sides respectively. Part 2 is the tunnel crossing across the Bosphorus; it is the most complex part of the project with the greatest challenges and risks. Part 2 is 5.4 km long consisting of 3.4 km of 13.2m external diameter TBM bored tunnel under the Bosphorus Strait, 1-km of twin NATM tunnels on the Asian side, cut and cover transition boxes in the Asian and the European sides and depressed approaches on both sides. In addition, this segment includes the toll plazas, ventilation buildings, and the tunnel control and maintenance facilities."

Jan 1, 2016

By A. Angelov, U. Peukerd, S. Gaydardzhieve, A. Stefanov, K. Grossman, V. Stoilov

Flotation concentrate originating from the Asarel-Medet porphyry copper mining and processing complex in Bulgaria has been subjected to regrinding using a Ro-Star mill; the effects of which on the downstream metallurgical behaviour are discussed. Particularly the effect on the liberation degree was studied through an optical microscopy and MLA-SEM automated mineralogy. On the other hand, copper selective flotation of the reground bulk concentrate was realised to evaluate the anticipated metallurgical improvement. Process parameters such as involvement of prior hydrocycloning and variation of collector dosage have been evaluated. Within a two-minute residence time inside the Ro-Star mill, an improved liberation degree of the copper bearing minerals has been observed. As a consequence, enhanced copper recovery and selectivity against pyrite was noted. It has been found that in order to guarantee efficient flotation of the resulting ultrafine particles, a modified flotation regime (i.e. changing collector suite and dosages) should be followed. Keywords: RoStar Mill, liberation, flotation recovery, ultrafine particles

Jan 1, 2020

By Arthur F. TQggQrt

THE approximate status of education in ore dressing in 1871 is reflected by Rossiter W. Raymond in an article written at that time presenting the curricula and descriptions of the laboratories at the various mining schools in the United States. For the most part, the curricula in which ore dressing was taught were for mining engineering. They comprised courses in geology, mining, and pyrometallurgy about equal in point or credit weights; a short course in ore dressing, and a somewhat longer course in assaying; and courses in surveying, hydraulics, power, and strength of materials-all superimposed on a broad foundation of physics, chemistry, and mathematics. Some curricula contained a fair content of the humanities. Then, as now, the emphasis on fundamentals was greater in the older colleges and universities. The report on the Columbia School of Mines, then relatively young, emphasized that a large percentage of its students were college graduates. As technical and scientific knowledge grew, first metallurgy and then geology were set up as separate curricula. So far as curriculum designation is con-

Jan 1, 1947

By H. W. Smith, N. Ichiyen

A convenient method for the calculation of metallurgical balances, based on statistical treatment of all available data, is presented. An error analysis is included. Examples show the advantages of the method, and also that such balances are less precise than might be supposed.

Jan 1, 1973

By L. Narhi, K. Haavanlammi

"Approximately two thirds of annual nickel production is used as a raw material in the making of stainless steel, and about 60% of these nickel products are in the form of metallic nickel such as nickel cathode or briquettes. In the stainless-steel production process nickel is blended with iron and chrome-based raw materials, and metallic nickel is typically only required for final steel fine-tuning. Outotec offers a new FeCrNi technology to enhance the nickel value chain for stainless steel producers. This involves the use of an HPAL-based intermediate nickel product (e.g., mixed hydroxides or NiO) as raw material in the Outotec FeCrNi process, for the production of a FeCrNi Master Alloy. The new process, designated as the FeCrNi process, offers multiple benefits compared to existing technologies such as: higher tolerance for impurities in the HPAL intermediate product, avoiding the need for further nickel refining, and the improved recovery of all metals in the FeCr process. The complete new FeCrNi value chain is based on proven technologies such as HPAL and the Outotec FeCr-process. This new innovative and promising value chain offers improved efficiencies for the HPAL based nickel production process combined with excellent sustainability aspects.INTRODUCTION In today’s global economy there is a constant need to improve the efficiency and sustainability of the metals production. The requirements for modern metal refining are tightening and cost efficient, safe and sustainable operation is the precondition for all investment. Outotec is offering now a novel way to combine FeCr and Nickel production to create a completely new value chain to source nickel to stainless steel. BACKGROUND Nickel The current nickel mine production is in the level of 2,000 tons annually and it is split 44% from sulphide based deposits and 56% from laterite deposits (Figure 1). Most (40%) of the nickel is refined to pure nickel metal whereas other products are FeNi (19%) and Nickel Pig Iron NPI (20%) (Roskill). The remaining part, roughly 21%, is nickel chemicals and intermediates. Most of the new investments in nickel are in the direct shipping of laterite to produce nickel pig iron. HPAL process is considered in few projects but no major HPAL projects have been started since the Ambatovy plant in Madagascar. Ambatovy reached the commercial production in 2014. The main primary nickel used is stainless steel manufacturing. In the year 2016 about 68% (~1,360 kt) of primary nickel production was used in stainless steel."

Jan 1, 2017