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By Louis E. Dalverny

U.S. Bureau of Mines research to develop diagnostic methods to locate and evaluate fires in abandoned mines and waste banks and techniques to extinguish such fires was applied to an abandoned 60-acre underground bituminous coal mine (Renton, Allegheny County, PA) to locate and extinguish three separated fire zones. Mine fire diagnostics interpret changes from baseline values in subsurface pressures, temperatures, and mine gas composition under imposed pressure gradients induced by a borehole exhaust fan. The effective gas sampling area surrounding each borehole is greatly enlarged. Sampling iterations, using a "communicating" boreholes set, provide "fire signature" information for locating both heated and cold areas. Time-dependent monitoring differentiates heating and cooling periods resulting from combustion front movement and/or fire extinguishment activities. A water injection with fume exhaustion extinguishment effort involved injecting water through boreholes to quench the heated zones while exhaust fans actively removed heated gases from the mine. The technique was ineffective as implemented, primarily because of inadequate spreading of water from the injection points. The Bureau's diagnostic method determined the fire locations and the effectiveness of the water injection with fume exhaustion extinguishment technique.

Jan 1, 2010

By Kazusuke Sato, Takahiro Uno, Koji Hoshino

"A novel Ni coating technique of Ni(OH)2 powders was developed to improve the positive-electrode performance· of the Ni-MH batteries. It was found out that Ni(OH)2 powder was reduced by N2H4 without any catalysts in an alkaline - solution at high temperatures. In result of observation of pH and potential changes in the solution during the reaction, it was found that the reduced species was HNio2- ion dissociated from Ni(OH)2 in the alkaline solution. The molar fraction of reduced Ni of the Ni(OH)2 was increased in proportion to the amount of added N2H4. At the small Ni fraction, a porous Ni layer was formed on the surface of Ni(OH)2 powder. Open cell tests were carried out with the paste type electrodes made of either the Ni coated Ni(OH)2 powder or non-coat powder, and cell performances were compared. In result, it was found that the Ni coating technique is effective on improvement in the utilization of Ni(OH); as a positive-electrode active material under high current densities.IntroductionNi-MH rechargeable battery is generally used for the power source of portable machines and electric vehicles because of its good performance at high energy density and. long term cyclical life as well as cleanness and good safety. Cell component materials have been improved respectively, and as concerns ·the positive-electrode reducing 'the internal resistance is a principal problem to improve the discharging performance at higher current densities.In recent years, improved Ni(OH)2 powders coated with conductive materials as NI. or CoOOH have been developed for the· positive-electrode active materials in order to· reduce the internal resistance of the electrode1)· 2) The Ni coated Ni(OH)2, however, is costly because it is fabricated by .the -non-electrode plate technique which needs a expensive precious ·metal catalyst as PdC12We found that Ni(OH)2 powder was reduced by N2H4 without any cryatalysts in an alkaline solution at high temperatures. After the treatment, Ni(OH)2 powder become gray color like Ni powder from light-green color; and. turned into a magnetic. In this study, the mechanism of the -reducing reaction was investigated to apply the reactions .to a novel Ni coating technique of Ni(OH)2 powders, · and the performance of the Ni coated Ni(OH)2 powder obtained by the reducing process was evaluated as an -positive-electrode active material of Ni-MH batteries."

Jan 1, 2000

By D FitzGerald

A critical component of any new tunnel design in a complex geological setting is the development of an integrated three-dimensional (3D) geology model with a full set of geotechnical properties of the rocks present. A novel means of predicting the geology based upon sparse observations of structural geology at the surface and from drill holes has been developed and used in several major tunnel studies in Europe.An example of this is the Lyons-Turin twin rail tunnel which is still in a development phase. This tunnel has been in planning and development for over 15 years already. An important aspect of this work is to characterise geological uncertainty along various possible tunnel paths as an input into early design optimisations for time, cost and risk avoidance strategies. Once the tunnel works commence and more detailed geological data is collected by daily mapping, progressive refi nement of the geological model is desirable; geological conditions still to be encountered can be more accurately predicted. Faults and their offsets, dykes, geological unconformities, folding, as well as standard sedimentary processes are all correctly modelled in the software. It is important to allow for seamless interchange of geological models at various scales with CAD workflows so that sufficient detail can be readily accessed at the required scale. Also, the proposed tunnel in its correct geometry can become a ‘section’ in its own right. Progressive detailed local geology models in the vicinity of the advancing head are created from the regional scale work by cutting and pasting a starting model, then adding all the extra detail for the required engineering geology work.For all rocks, most standard geotechnical quantities such as sonic velocities, Young’s modulus and Poisson’s ratio are handled. These and any other phenomena from borehole observations can have variograms calculated and stratigraphically constrained estimations made in a least biased geostatistical manner, in advance of the tunnel. RQD, or a prediction of rock fractures, is handled by the faulting and folding modelling facilities. This is probably the more interesting issue to pursue, as the fractal nature from small scale fractures and joints, to large-scale faults, can now be characterised more convincingly.

Mar 8, 2011

By E. J. Duggan

CLIMAX ore is an altered and highly silicified granite, about half of the gangue being quartz. Molybdenite is the only mineral recovered and most of it is intimately associated with the quartz in fine veinlets. Other minerals are molybdite, pyrite, and chalcopyrite. Although the molybdite may be readily extracted by hydrometallurgical methods, its content is too low to make this profitable. The pyrite ranges from 2 to 5 per cent and the chalcopyrite from 0.03 to 0.05 per cent. There is not enough copper to make its recovery attractive and one of the problems is its elimination, and that of pyrite iron, from the final product. On account of the high degree of dissemination of the molybdenite and the necessity of eliminating the iron and copper, fine-grinding followed by flotation is the only known feasible method of concentration. Two factors, peculiar to Climax ore, have a predominating influence on the metallurgical attack: (1) Molybdenite is one of the most easily floated minerals. High recoveries may be made with pine oil alone if the

Jan 1, 1946

Halide media are considered as suitable alternatives to cyanide for extracting gold and have received much attention lately. The extraction of gold by iodide-iodine mixture has been patented and briefly studied without much attention given to the fundamental aspects of this process. This paper reports recent studies on the kinetics of gold extraction in iodide media, using hypochlorite, iodine and hydrogen peroxide oxidants. The kinetics of dissolution was found to be dependent on the solution pH, reagent concentration and most importantly the iodide- oxidant molar ratio. Without proper control, the gold surface can be passivated due to the formation of solid products. Thermodynamic modelling was carried out to determine the equilibria governing the dissolution process. The formation of AuI solid was also identified as a possible product during the dissolution.

Jan 1, 1992

By Carolina Ayala

Dado que las empresas enfrentan escasez de recursos, materias primas, y exigencias ambientales o laborales; la sociedad también enfrenta fenómenos de movilidad social. En consecuencia, el crecimiento de las empresas se ve influenciado por las exigencias de los grupos de interés. En ese sentido, el presente texto señala que la relación de empresa- sociedad debe ser de coexistencia y búsqueda de beneficios mutuos. Sus principales objetivos son: disminuir y mitigar impactos, asegurar y cuidar recursos escasos y la creación de nuevas realidades que generen un valor superior.

Jul 1, 2013

By Shenghui Guo, Ying Lei, Wei Li, Jinhui Peng, Libo Zhang, Yu Li

"In this work, the Panzhihua low grade ilmenite and graphite were milled for 1, 2, 4 and 8 h firstly, then the temperature rising behavior of milled sample in microwave field were studied. The average heating rate of samples milled for 1, 2, 4, 8 h were 1.86, 4.08, 2.82, and 2.32 K/s; Before optimize the microwave reduction process, several experiments were conducted in order to confirm the parameters range. After milled for 4 or 8 h and reduced above 930 oC, the Fe metallization are higher than 90%; Then the optimization was investigated by using response surface methodology (RSM), the significance of predict model and each terms were analyzed, and the optimization parameters were given as: milling time is 4 h; reduction temperature is 1001 or 1070oC; the holding time is 37.5 or 26.9 min. Under these conditions, the Fe metallization given by predict model is 91 or 92 %.IntroductionThere is about 9.66 billion tons of Vanadic Titan-magnetite deposits in Panzhihua, China. In this reserve, there is about 8.73×108 t of TiO2, accounting for 90.54% of the Chinese reserves, and 35.17% of the international reserves and ranking first in the world. [1] Titanium mineral deposits are classified into Rock type and Placer type. Rock type is the igneous mineral, which have high content of FeO (Relative to Fe2O3) and gangue. The Panzhihua ilmenite is a typical rock type ilmenite ore. The higher contents of MgO, CaO, SiO2 and the complex mineralogy are making its direct reduction progressively more difficult."

Jan 1, 2011

By Gunnar Eriksson

Computer simulation has become an everyday practice in thennodynamic and materials research. Advanced thennochemical algorithms take into account heat transfer effects and salient reaction kinetics when applied for process models. In particular, the combination of mass transfer or overall reaction rates with multi-component Gibbs energy minimisation provides an effective tool for simulation of industrial thennochemical processes and processing of materials. In this work the combination of rate factors with the Gibbs energy technique was studied by using the novel program ChemSheet, which operates through Microsoft's Excel® spreadsheets. Such processes as, for example, CVD of pure silicon production, titania pigment manufacturing, vapour pressure of Mercury in amalgams (in Hg-Iamp manufacturing) and melting behaviour of low-temperature alloys have been modelled. Provided that the thennochemical data is available simulations can be performed with any thennodynamic system. The calculation can be performed as an affinity study without a particular reactor model or with a specific reactor scheme.

Jan 1, 2001

By Aloizio Cesar Gonzaga, Leandro de Paula, Ismael de Souza Dias, Gladston Santos

Looking for greater competitiveness, Gerdau started in 2013 the operation of its hot strip mill in Ouro Branco, being a milestone in Gerdau's history, where it definitely entered the flat products business. This mill consists of the reheating furnace, primary scaler, a Duo-reversible Quadrupole Steckel mill, accelerated cooling and final coiling. The Steckel mill works with two backup rolls and two working rolls, the backup rolls being responsible for supporting the rolling forces and the working rolls for shaping and surface quality to the strips, having as main requirement quality of surface finish. These rolls suffer high wear due to the lamination process and are exchanged with high frequency to ensure the quality of the laminated strips, after the exchange are sent to the Work Roll Shop for grinding and are positioned Grinded work rolls for the next planned change. This movement is accomplished through the crane and an exchange device that attaches to the cylinders to be transported from the Rolling Mill to the Work Roll Shop. The target in this article is focused on an improvement in this Device to increase operational safety and reduce stoppage losses downtime at the mill, improving the cost / benefit ratio and increase production.

Oct 1, 2019

By Helena Byrdziak

KGHM Polska Miedz SA, in existence since nineteen seventies, operates three underground mines and three smelters with total production of over 400 000 mtpy of electrolytic copper. Its impact on the environment, very serious in the past, has been gradually reduced. While in general emissions into the air and water have been brought under control, attention recently has shifted to the disposal of wastes and residues. The main streams of wastes are flotation tailings, slags and dust captured from the dedusting systems. Much effort has already been expended and is still being spent to utilize this waste for by-products production or to dispose of it within the process by recycling. The most effective measures taken up thus far, as well as present activities directed at tailings disposal, are presented.

Jan 1, 1997

By R. V. Lundquist, H. Leitch

Two hydrated calcium aluminates , formed by side reactions in the leaching step and desilication step of the lime- soda sinter process , were investigated to better define their influence on alumina recovery . The two calcium aluminates , Caз [ Al ( OH) 6 ]₂ and зCa0.Al½ 03 · ( 8-12 ) H₂ ) , were prepared and identified by chemical and X- ray analysis . The relative proportions of each of these compounds formed in typical leach solutions at several temperatures were determined . The influence of free lime as a promoter of calcium aluminate formation was also investigated . The formation and precipitation from leach liquors of calcium aluminates contributes to the low alumina recoveries in the process . The presence of carbonate ion in the leach solution suppresses calcium aluminate formation and precipitation and results in higher alumina recovery . Hydrated calcium aluminates are formed in the aging of lime - soda sinters in the normal atmosphere .

Jan 1, 1963

The National Mining Hall of Fame and Museum (NMHFM) in Leadville, CO will induct the class of 2011 on Sept. 10, 2011. Representing the coal, metallurgical/processing, research and development, marble and lead industries, this year?s inductees cover a diverse crosssection of the mining industry. William Francis Diamond, Wayne Hazen, Redfield Proctor and Jeffrey Zelms will join 210 other mining industry pioneers when they are formally inducted into the National Mining Hall of Fame at the 24th Annual Induction Banquet and Ceremony. The members of this year?s class were selected for being visionaries, leaders and ambassadors both within their own sectors and across the industry at large. Diamond had an illustrious engineering and managerial career that spanned four decades with Island Creek Coal Co. During that time, he was responsible for the engineering and construction of the deepest coal mines producing in North America at the time.

Jan 1, 2011

By T. Sreenivas

This paper describes results of laboratory studies on recovery of dissolved uranium values from alkaline leach slurries of a medium-grade uranium ore from Gogi (Karnataka, India) using the resin-in-pulp (RIP) process. Besides anionic carbonate complex of uranium, the other major ionic constituents of the leach solution are CO32-, HCO3-, SO42- and MoO42-. The total dissolved solutes (TDS) are about 45 g/L. Various commercially available strong bases anionic resin-in-pulp (RIP) grade resins ? both macroporous and gel type, were studied with respect to their loading capacity. Parametric variation studies were then carried out with the short-listed resins. Results of the semi-continuous counter-current extraction and elution tests indicated extraction efficiency of about 98% and practically complete elution of the loaded uranium values with NaCl eluant using a gel type polystyrene based resin grafted with quaternary ammonium ion. Keywords: uranium, hydrometallurgy, ion exchange, resin-in-pulp

Sep 1, 2012

By Kevin Malone

Mercury, or quicksilver as it is often called, has many applications in modern technology. Used principally in electrical apparatus, industrial contol instruments, insecticides and fungicides, electrolytic preparation of chlorine and caustic soda, chemical processes, pharmaceuticals, and dental preparations, the liquid metal has unusual properties that make it a preferred material for many industrial uses. United States consumption of mercury during the past 40 years shows a rising trend. In all except 4 years, U.S. production has been less than the domestic requirement, and imports, principally from Spain, Italy, and Mexico, have supplied most of the deficit. After World War II, domestic output decreased rapidly until 1950, when it was the lowest in the 100 years covered by production records. Higher mercury prices since 1950 have reversed the decline in domestic output and reduced the gap between U.S. production and consumption. Domestic output in 1958 was the highest in peacetime since 1883; however, the nation still imported 28 percent of its mercury requirements from 1950 to 1960 the price of mercury was high as a result of industrial applications of the mercury cell, the impact of the cold war and the Korean war, and the Government stockpiling program. The stockpiling program, in effect, put a floor under mercury prices even though only 9,428 flasks of domestic mercury went into the stockpile under the original program which ran from July 1954 to December 31, 1957. Under an extension of the program, an additional 17,463 flasks was purchased.

Jan 1, 1962

By Yun Guo, Min-Min Lin, Bing Xie, Hong-Yi Li

The extraction of vanadium from vanadium-containing APV-precipitated wastewater by W/O microemulsion system was studied. In the N263/n-heptane/isoamyl alcohol/NaCl microemulsion system, N263 played double functions of cationic surfactant and extractant to form microemulsion in n-heptane, and isoamyl alcohol was added in the microemulsion as a cosurfactant. The extraction of vanadium by W/O microemulsion systems effectively accelerated the extraction and improved the extractatability because of the enormous increase in the micro-interfacial surface area. Due to ion association with extractant, vanadium was extracted into the microemulsion phase. The influence of different parameters on the extraction ratio (E%) were investigated, including the volume ratio of aqueous phase to microemulsion, surfactant concentration, pH value of the feed solutions, cosurfactant concentration, extraction time as well as temperature. In optimum conditions, the extraction ratio (E%) can reach 97.2%.

Mar 1, 2018

By B. Wasmund, K. Adham, K. O'Keefe, C. Lee

"Metal chlorides (e.g. iron and nickel) can be pyrohydrolysed at elevated temperatures to yield an HCl rich off-gas and a metal oxide product. Typically, the high energy requirement for pyrohydrolysis is provided by the combustion of a hydrocarbon fuel with air. Here, it is demonstrated that the use of oxygen-enriched combustion can result in lower fuel requirements and higher HCl concentrations. In addition, the oxygen enrichment can result in a smaller volume of off-gas and thus, smaller and less expensive process equipment. This new concept can be applied to both the spray roaster (SR) and the fluidized bed reactor (FBR). Similar to the aircombustion case, the oxygen-enriched process can use a direct contact venturi scrubber, to recover energy from the roaster off gas, but at a higher efficiency. The new process also uses an absorption tower for capturing HCl from the roaster off-gas, but generates a stronger HCl solution than is possible with pyrohydrolysis in air.BackgroundIn recent years, the metallurgical industry has become increasingly involved with developing methods for extracting metals, upgrading products or cleaning metallic products by using hydrochloric acid. These applications of chloride metallurgy often result in metal chloride solutions, which should be processed to regenerate HCl for reuse, and to recover the metal value as a product or by-product oxide [2, 3, 4].The pyrohydrolysis of metal chloride solutions has been done in two types of air roasters: spray and fluidized bed. The existing roasters burn a hydrocarbon fuel in air, to provide the required energy for evaporating the feed solution and to provide an elevated temperature for the chloride pyrohydrolysis to occur, according to the following reactions:"

Jan 1, 2011

By Ebrahim F. Salmi, Tan Phan, Ewan J. Sellers, Thomas R. Stacey

Extension of ore pass length has become increasingly critical for optimising energy-efficient underground mining operations. Long and ultra-long ore passes, spanning from 300 to 700 m, can significantly improve the functionality and viability of underground mass mining operations though suboptimal performance has an extremely adverse impact on production. The public domain lacks substantial information regarding the primary engineering, geological, and geotechnical risks and challenges associated with the design, implementation, operation, and maintenance of such long ore passes. Therefore, the aggregation of past experiences and the insights of experts assume paramount significance. An innovative methodology is introduced to address this evident data deficiency and to establish comprehensive guidelines for the resilient design of such lengthy ore passes — combining gap analysis with expert elicitation techniques. This equips design engineers with the necessary tools to formulate and adapt strategies for assessing the numerous challenges and uncertainties that invariably accompany their projects. Expert elicitation techniques are summarised, and a gap analysis is conducted with subject matter experts, from various countries, collating their extensive ore pass design experience, to create a comprehensive list of effective parameters and key risks that must be considered. Quantitative analysis of the survey results enabled the identification and ranking of the numerous factors affecting the design, operation, and maintenance of long and ultra-long ore passes and highlights the complex technical challenges (substantial damage from rock particle impact, increased dynamic mining stresses leading to failure, air-blasts and back blasts, dust, preferential flow, turbulent and dynamic material flow) that are uncommon in shorter ore passes. Additionally, increasing length heightens the probability of intersecting weak rock or discontinuities, leading to a higher risk of structural failure and instabilities. Faulting, folding, and large-scale structures are also critical geological factors to be considered in the design of such structures. The key geotechnical factor is also the rock type surrounding the pass. Experts highlighted the lack of clear guidelines for decision-making, resilient design, and construction so this work suggests future investigations to determine the complex interaction between the effective parameters, using approaches like the rock engineering system, discovery of cascading hazards, and optimal controls.

May 3, 2024

By J. E. Lees

Advanced remote sensing can be a powerful new information tool to help private and public entities make better environmental and resource management decisions. However, some regulated entities are reluctant to develop or use this tool because of their concerns that it will lead to increased risks and costs of environmental legal liability. They fear that new ways of monitoring the environment will increase liability, undermine existing enforcement agreements, reopen compliance agreements, and generally provide a competitive disadvantage to early adopters by accelerating environmental cleanup costs. Others counter that the increased risks are marginal, and that several advantages outweigh these risks, including the opportunity to more effectively manage environmental operations, target and set priorities, measure and track management and compliance effectiveness, provide more defensible environmental assessments and baseline conditions, make and defend optimal siting decisions, and avoid or resolve environmental disputes. This paper offers strategic advice on ways regulated entities can enjoy the benefits of these powerful new information tools while mitigating down-side legal and compliance risks as much as possible.

Jan 1, 1999

By Thierry De Nys

A direct leaching process of sulphidic zinc-based concentrates in aqueous sulphuric acid solutions has been developed by the V.M. R & D Department. By a very accurate control of the oxidation potential of the leach solution, this process enables a separate recovery of the zinc, copper, silver, lead and sulphur of the concentrate and makes it extremely attractive for treating more complex ores. The iron, solubilized during leaching, is eliminated out of the zinc solution by means of the V.M. goethite process. Alternative flow sheets for a conventional zinc electrolysis plant are presented.

Jan 1, 1990

By Paul A. Glapa

Quality is much more than providing a product that functions properly. True quality is a way of thinking, a way of doing business, and, ultimately, a way of satisfying a customer?s long-term needs. A true commitment to quality requires a top-down management commitment, with a willingness to change what needs to be changed and to expand upon ?best practices? that are already done well. Is there a cost to creating and maintaining a quality program? Of course there is, but the cost of not having a focused program is much greater. We have come to regard quality as an investment that pays dividends to both the supplier and customer. The lack of quality costs everyone and the customer pays the ultimate penalty. With modern, highly engineered surface mining equipment the end user calculates cost in terms of lost production (revenue), not simply the cost of the part. Bucyrus International, Inc. is a company that has listened to its customers and has dedicated itself to implementing an advanced quality program. The ultimate goal being the creation of a high quality product with extended reliability for the customer. The result is reflected in Bucyrus? current product offerings and highlighted by the new 495HF electric rope shovels at Albian Sands mine.

May 1, 2003