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By M. J. Nicol, T. Moyo

Ammoniacal solutions are an effective lixiviant for the oxidative dissolution of some mineral sulphides. A detailed study of the anodic dissolution of chalcopyrite in ammonium sulphate-ammonium hydroxide solutions has been carried out using cyclic voltammetry, chrono-amperometry and rest potential measurements. The role of the copper(II)/copper(I) redox couple in the oxidation process has been evaluated. Rest potentials have been found not to be affected by oxygen but to increase with an increase in initial copper(II) concentration. Pseudo-steady-state anodic current densities measured in the absence of copper(II) ions at the rest potentials obtained in the presence of copper(II) ions increase with increasing concentration of copper(II) ions, confirming the positive effect of copper(II) ions on the rate of dissolution of the mineral. Cyclic voltametric and chrono-amperometric data show that in the absence of initial copper(II) ions, the rate of dissolution in the presence of dissolved oxygen is significantly lower. These results confirm that the effective oxidant for the mineral under the conditions of the study is copper(II) and not dissolved oxygen. Coulometric measurements have been used to establish the stoichiometry of the anodic reaction at different potentials.

Jan 1, 2014

By R. C. Bunge

The selective flotation of semi-soluble salts with fatty acids is often negatively affected by the interaction of the potential determining cation with the ionic surfactant in bulk solution. This problem can be avoided by floating at low pH which involves the emulsification of the collector. The research presented here focuses on the influence of the Ca2+ ion on the flotation of fluorite with palmitic acid at low pH. Our results show that the surfaces of collector emulsions are dominated by precipitation phenomena similar to those encountered in bulk. In turn, fluorite in palmitic solution at intermediate pH displays surface properties similar to those of the collector by itself. This may be due to two alternative mechanisms (i) adsorption of bulk precipitate on the fluorite surface or (ii) the formation of a bilayer of surfactant ions on fluorite. Possibly, both mechanisms occur simultaneously.

Jan 1, 1993

By D. Harrington

This circular presents Part III-A of a series reviewing the literature on effects of breathing dusts with special reference to silicosis; it deals with the economic and legal aspects of dust diseases in industry; Part III-B will contain data on the status and cost of compensation for silicosis, Parts I and II of the series have been issued as Information Circulars 6835, 6840, and 6848; Part I defines and classifies dusts, indicates sources of exposure, and describes the physiological effects of breaching dusts; Part II-A discusses the principal dust factors producing pulmonary pathology and methods of determination of dust in air; and Part II-B presents data on the engineering and medical control in the prevention of dust diseases and general recommendations for their control in industry. A summary and general conclusions will complete the series.

Jan 1, 1935

By J. P. De Carvalho, R. Dimitrakopoulos

This paper presents an actor-critic reinforcement learning (RL) method to allocate trucks and shovels in open-pit mines, while defining short-term production scheduling of an industrial mining complex, given new information collected during operations. This new data obtained from sensors update the uncertainty of the orebody models. The RL agents interact with the mining complex environment; exploring the solution space, learning actions to improve metal production and equipment utilisation. A case study is presented at a copper mining complex, highlighting the method’s ability to adapt and make informed decisions while collecting new information.

Sep 1, 2021

By A. Tikhonov, D. Kipper, V. Korovin, A. Olifirenko, Yu. Shestak

The present paper deals with vanadium and molybdenum sorption from industrial wastes and intermediate processing products using Cybber macroporous strong- and weak-base anionites. Vanadium and molybdenum recovery by Cybber anion-exchange resins as well as desorption processes were studied in static and dynamic modes; their efficiency was demonstrated for that purpose. The results of the work may be used to design technologies for complex processing of both ores and industrial wastes containing vanadium and molybdenum.

Jan 1, 2011

By S. Aram

Product Lifecycle Management (PLM) solutions have been serving as the basis for collaborative product definition, manufacturing, and service management in many industries. They capture and provide access to product and process information and preserve integrity of information throughout the lifecycle of a product. Efficient growth in the role of Building Information Modeling (BIM) can benefit vastly from unifying solutions to acquire, manage and make use of information and processes from various project and enterprise level systems, selectively adapting functionality from PLM systems. However, there are important differences between PLM?s target industries and the Architecture, Engineering, and Construction (AEC) industry characteristics that require modification and tailoring of some aspects of current PLM technology. In this study we examine the fundamental PLM functionalities that create synergy with the BIM-enabled AEC industry. We propose a conceptual model for the information flow and integration between BIM and PLM systems. Finally, we explore the differences between the AEC industry and traditional scope of service for PLM solutions.

Aug 1, 2013

By A G. L Pratt

Change and its relationship with the introduction of new technology is a constant of human history. The mining industry has many examples of this relationship. This record contrasts with its present day struggles to move beyond a public perception of being just ‘dirty, dumb and dangerous’. The drivers for the introduction of new technology are frequently listed as the occupational health and safety of people working in the mines, reductions in direct operating costs, and increases in productivity.This paper discusses the issues that a mining business needs to deal with to implement new technology with the best possible conditions for success. It comments on how the strategic and tactical components of technology planning relate to and interact with change management. The central discussion is directed at the role that people play in the successful implementation of new technology. The introduction of autonomous underground haulage equipment provides a background for the discussion of this topic.The paper uses case study references, equipment supplier information and research findings. The aim is to offer a high-level view of the issues a mine operator needs to consider when approaching the introduction of new technologies for underground mining.CITATION:Pratt, A G L, 2017. Technology change in underground mining – things to consider, in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 103–114 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 16, 2017

By E. D. Gardner

This is one of a series of papers describing mining and related subjects affecting mining in western mining districts and mineralized areas. The parts of this paper pertaining to current production, mining and milling methods and practices, and general conditions affecting mining were collected principally during a field survey made in May 1935. Some original data obtained on previous visits to the area are also included. The history, geological background, and past production of the mines and district are largely abstracted from previous publications, for which due credit is given later in the test. The principal districts in the Black Mountains are the Oatman or San Francisco and the Union Pass or Katherine. This range contains the principal producing mines of the State, in which gold is the only important metal. Although the total production of gold is relatively small as compared to other districts where the precious metals are obtained as a by-product in copper min¬ing, the area is one of considerable economic importance to the State.

Jan 1, 1936

By John R. Buzek

Thickeners are simply large tanks, usually circular in shape, which are designed to allow settling of solids and to operate with continuous overflow of clear water and underflow of thick pulp. The dimensions of the thickener are usually such that dewatering of very fine pulps may be accomplished while still 1 overflowing clear water. Some thickeners such as the Genter, Hardinge and Hydrotator types combine thickening with filtering2 while others such as the Dorr type are pure thickenersl,2,3. A schematic diagram of the traction type Dorr thickener is shown in Figure 1. This type is appropriate for tanks over 15 m (50 ft) in diameter. This tank employs a rotating raking mechanism which moves the settled material toward the central discharge. For this and other thickeners, it is common to have a shallow conical tank bottom in order to conform to the geometry of the raking mechanism, and it is often desirable to elevate the tank for ease of access to the product. When the tank does not rest on the ground, the forces resisted by the cone are large, and thick plates must be employed. The fabrication of these tanks requires temporary supports in order to erect the cone. A flat-bottomed tank could also be used because the settled material would soon form a hardened conical surface. However, because of the presence of large bending forces, even larger plate thicknesses are required than for the conical bottom. Significant cost savings often can be realized by the use of a scalloped-bottomed tank such as the one partially shown in Figure 2. The particular scalloped bottom discussed in this paper (and shown in the Figure) employs radial beams forming the outline of the cone-shaped bottom. These beams are supported directly by columns. Cone segments are hung between adjacent beams. The exact geometry of these segments depends upon the cone angle and radius, the number of radial beams, and their inclination. The geometry is chosen to satisfy certain clearance restraints and to utilize the material as efficiently as possible. The resulting thickness of these segments is significantly less than that of the

Jan 1, 1977

By Alexi J. Neill

"This presentation will showcase two challenging projects with deep excavation support systems in the Atlanta area where state-of-the-art instrumentation and monitoring systems were used to manage risk by confirming design performance requirements / calculations during construction. The instrumentation and monitoring system successfully reduced risk by recording real-time data on a project website while simultaneously sending email alarms to key site personnel when data exceeded pre-determined alarm thresholds. The monitoring data revealed unexpected performance at an early enough stage so that contingency plans could be engaged and remedial efforts devised in order to limit the consequences. Finite element analysis was used to model deformations, analyze the unexpected performance, and prepare theremedial design.INTRODUCTIONConstruction in densely populated urban areas is becoming more common in order to keep up with the increasing infrastructure demands of our growing population. America’s big cities continue to outpace the overall nation in population growth. The city of Atlanta, the nation’s ninth largest city based on metropolitan population, is a prime example of this. The population has grown at a rate of 6.6% between 2010 and 2013, nearly triple the overall growth rate of the United States during the same period (SustainAtlanta, 2015).As a result of increasing infrastructure demands in Atlanta, developers are now constructing larger buildings on smaller properties. In addition, developers are attempting to maximize space on their selected properties, often by designing underground parking garages to accommodate as many cars as possible on these compact sites. In some cases the selected sites are adjacent to buildings, utilities, and other existing structures. The risk associated with construction increases during underground work that requires a support of excavation system, particularly on confined sites adjacent to existing structures. There is a risk posed to people, property, and the environment that the project team should monitor when constructing in these conditions."

Jan 1, 2016

By Pathik Deb Mallik, Shyamal K. Mitra, Rajiv Kishore, Shuvranshu Rout, Manos De

"This paper presents a case study on the design and construction of a deep underground pit structure constructed inside almost a century old existing plant building. The complexity and challenge for the design and construction lay in executing the work in a difficult subsoil condition especially the presence of deep mica schist. The limited space availability in the existing plant for construction work without hampering regular production in other adjoining areas of the plant made the execution more challenging. Experience with difficult subsoil and proximity to old foundations entailed a non-conventional engineering approach while ensuring complete safety in spite of maintaining the normal operation.INTRODUCTIONTata Steel Processing and Distribution Limited (TSPDL) is a subsidiary unit of Tata Steel Limited (TSL) having a CR processing facility inside the premises of Tata Steel Limited. TSPDL intended to install equipment for a new slitting line inside the existing shed including construction of very deep structure called “loop pit” where the strips from cut CR sheets collect in the form of loops and are recovered as scrap. The entire plant is located within the shed of existing plant. The construction of all foundations including the loop pit is to be executed in the limited area without disturbance to normal production work in balance areas of the plant and also maintain safety and integrity of existing structures.The existing shed is an old structure constructed approximately 80 years ago. The building column foundations are gravity type design of brick masonry supporting only the vertical load from the columns. This type of foundation designed with no eccentricity of loading provides no allowance for implementing any foundation stabilizing design. The present project required civil construction for the new equipment foundations safely within this area."

Jan 1, 2015

By Hervé Le Bissonnais, Jean-Pierre Janin, Anne Bergère, Pierre Renier

"The most important impact on the environment of a tunnel excavation is the creation of surface settlements. Nowadays, the mechanized tunneling allows minimizing the settlements, applying a confinement pressure which counterbalances the ground de-confinement. It is thus essential to determine the correct amount of confinement pressure. In this paper, the authors present a 3D numerical study simulating the EPB-TBM excavation of a water tunnel, in the Flanders clays (north of France). Firstly, a simplified 3D simulation, based on the concept of instantaneous longitudinal settlement curve, was performed to predict the surface settlements for different values of heading confinement pressures. Secondly, the same pressures were tested by the EPB-TBM in a monitoring zone. The comparison between the prediction settlements and the measurements was very satisfactory and allowed validation of the numerical approach and the choice of the optimal confinement pressure value for a sensitive area of the project. INTRODUCTION The excavation of a tunnel can create displacements of the surrounding soil which may affect existing structures and generate unacceptable dysfunction. The development of the closed shield tunneling has permitted to reduce the volume loss generated around the excavation and consequently the surface settlements. In this case, as explained by different authors (Clough et al., 1985; Kastner et al., 1996; Mair and Taylor, 1997), the ground movements are influenced by the TBM works: the heading confinement pressure, the shield overcutting and conicity, the annular void grout injection parameters, the segment concrete lining rigidity, the consolidation of the grout. Hence, in the tunnel design, it is important to take into consideration these different processes of the excavation works to simulate correctly the tunneling process."

Jan 1, 2016

By Tristan Joubert, Fabio Panella, LiLing Chen, Yung Loo, Michael Devriendt, Nasir Qureshi, Ahmad Ali

Tunnel inspections have traditionally been carried out manually by inspectors writing up observations and taking photos of defects. The results from the inspection and the defects observed are dependent upon the rigor of the inspectors and may be subject to repeatability and consistency issues and is often time consuming with elevated health and safety risks. This paper will discuss work that is being carried out in developing and implementing an innovative hardware and software solution integrating machine learning to automate the process of capturing objective tunnel condition information, offering cost and programme savings as well as health and safety improvements

Jun 13, 2023

By Toshiaki Tsuru, Takeshi Ohgai, Hisaaki Fukushima, Shigeo Kobayashi, Tetsuya Akiyama

"Electrodeposition behavior of Zn-Cr alloys from the methanol baths was investigated. In the methanol baths of low Cr3+ concentration, Cr (III) compound was incorporated in the deposits and no lusfrous Zn-Cr alloys was deposited. However, Cr was existed as metallic state in the deposits obtained from the baths of higher Cr3+ concentration. With an increase in water content in the baths, the chemical state of Cr in the deposits changed from metallic to trivalent state. Under the condition that metallic Cr can be electrodeposited, Zn deposition was significantly polarized to the potential of Cr deposition.INTRODUCTIONAn attention has been paid to Zn-Cr alloy plated steel sheet because of its excellent properties for body panels of automobile and electrical appliances [1]-[4]. This plating process can be operated using the sulfate solutions containing Cr3+ ion [1] - [6].In decorative single Cr plating, on the other hand, many attempts have been made to electroplate Cr from trivalent electrolytes, which is motived by environmental deficiencies of the presently used hexavalent process [7]. [8]. However, it has been reported that in the aqueous solutions the behavior of the electroreduction of 0 3+ is atypical due to the complicated nature of the chemistry and electrochemistry of cr3+ species [9]-[11]. Even in Zn-Cr alloy plating, it is difficult to codeposit metallic Cr with Zn in simple sulfate electrolytes [l]-[4], [12]. Therefore, it can be expected that the electrodeposition behaviors of Zn-Cr alloys as well as Cr are significantly changed when the electrodeposition is conducted in non-aqueous plating solutions.In this study, the electrodeposition of Zn-Cr alloy was conducted from methanol solutions to clarify the electroreduction mechanism of Cr3·-Cr0 in the alloy deposition process."

Jan 1, 2000

By Flávia Paulucci Cianga Silvas, Otávio da Fonseca Martins Gomes, Viviane Tavares de Moraes, Denise Crocce Romano Espinosa, Jorge Alberto Soares Tenorio, Guilherme Apostólico Bortolini, Stoyan Gaydardzhiev

"Printed circuit boards (PCB) are particularly problematic to recycle because of the heterogeneous mix of organic materials, metals, and glass fiber. PCBs are found in almost every electroelectronic equipment and their recycling process involves a pre-treatment to separate the products which contain targeted metals. In this work, a physical processing involving sequential shredding and hanuner milling were used to obtain a comminuted sample from scrap printers PCBs. The thus prepared sample was analyzed for particle size distribution and by optical microscopy as well was subjected to pyrolysis, leachabilty and chemical composition determination by XRF. The metals concentration was determined by ICP and AAS. The PCBs have been also analyzed by SEM-EDS (micro-analysis and X-ray mapping). The results show that the studied PCBs are lead free, multilayer with 4 copper layers, have 45% of metals and the copper is present in significantly higher concentration than the rest of the metals.IntroductionThe global generation of e-waste (electrical and electronic equipment waste - WEEEs) grows at a rate of about 40 millions of tons per year [ l].Among this e-waste there are PCBs that are present in almost all electronic equipment. Their composition is heterogeneous and varies according to several factors, including: kind of EEE, when and where it was produced, fabrication technology [2], etc. In printers, the PCBs represent about 6.6- 8 wt.% [3].The PCBs treatment may include physical, pyrometallurgical, hydrometallurgical, ectrometallurgical and more recently bio-hydrometallurgical process. Normally there is a combination between these processes [2, 4, 5, 6, 7, 8, 9, 10].The diversity between the different PCBs composition complicates the recycling process since the composition of metal and others materials can vary according to the models. So characterization is an indispensable step before any processing of PCB to begin. Owing to the above said, the main goal of this work has been set to characterize representative samples of PCBs from printers through physical, chemical and microstructural analyses."

Jan 1, 2014

By K. Anim, C. Calderon-Arteaga

Located in Mojave, CA, The Soledad Mountain mine is an Open pit Heap-Leach gold Mine, which is operated by Golden Queen Mining Company LLC. under private capital. Open pit mining began in 2015 while full production was reached in 2016. The open pit mine feed a processing plant that can process more than 13K tons per day of ore which is sent to a heap leach pad. The Soledad Mountain project is a poly metallic deposit with Au and AG being recovered as payable metals. As the mine became bigger after moving to the east pit phases, Golden Queen was facing new challenges to control the production and accurately determine KPIs to improve/increase the production. To maximize returns and asset value, a new fleet management system (FMS) was adopted and implemented. The new FMS has enabled the mine to interconnect the different stages of the mining, as well as to recognize issues and implement the necessary corrections. With the associated increase in complexity in the process, the requirement of the ore control system to accurately predict ore feed characteristics is critical to maximizing metal recovery. Implementation of new daily and weekly plans were needed to ensure the ore delivery and meeting the tonnage goals, while allowed the equipment operators to better geolocate and to maximize the equipment production. These conditions alongside with Golden Queen’s drive to increase profitability and maximize net asset value has created challenges. These challenges are numerous and multifaceted. However, the ability to accurately route the material from the mine, is critical to site success and some of these challenges have been overcome by the adoption of the new FMS, the implementation of daily and weekly plans and upgrades in the ore control workflow. Examples of how the integration of the new systems allowed golden Queen to improve production strategy, are discussed in this article.

Mar 2, 2022

By K. Lillkung

The use of secondary sources has become a very attractive option in the production of platinum group metals as the demand for these metals has increased. One of the promising sources are the spent catalysts, which provide an attractive source as they have relatively high metal content compared with the ores where the metal is originally extracted from. The concentration of platinum group metals in catalytic converters is in the range of 0.1-1 mg/g as the concentration in ores is usually less than 10 ppm. Aqueous chloride solutions are claimed to be a cost effective way in which platinum group metals can be brought into solution and concentrated. In this work the effect of different parameters on the dissolution rates of Pt, Pd and Rh were investigated. The parameters investigated were the Cl- concentration, the temperature and applied potential. Chloride concentrations used were 62.5, 90, 125 and 250 g/l. Temperatures were 25, 40, 60, 80 and 94°C. Potentials were 950, 1050, 1150 and 1250 mV vs. SCE for Pt and Rh and 380, 410, 440 and 470 mV vs. SCE for Pd. Dissolution rates were calculated from the current densities determined by potentiostatic measurements. Thin wire electrodes were used in the measurements. As expected, higher temperature, higher potential and higher chloride content generally increasedthe dissolution rate. However, the effect was nonlinear and slightly different for different metals. The results show that strongly oxidizing conditions are needed in order to achieve reasonable dissolution rates. With the highest chloride content and at potential of 1250 mV vs. SCE and 94°C the dissolution rate of Pt was nearly 1 mm/h, whereas in similar conditions Rh achieved a rate of only nearly 100 µm/h. Similarly, with the highest chloride content and at potential of 470 mV vs. SCE at 94 °C the dissolution rate of Pd was nearly 1 mm/h. Keywords: Pt, Pd, Rh, redox potential

Sep 1, 2012

By Greg Corbett

The paper point out the styles of Pacific Rim epithermal gold mineralization. Some characteristics of differing styles of epithermal gold mineralization influence investment decisions (metallurgy, metal ratios, mining style), while others should be taken into account during prospecting (pyrite content and resistivity govern geophysical techniques, vein/breccia styles control drilling, gold distribution influences ore reserve determinations). Two groups of epithermal deposits are distinguished by the fluid style which controls ore and gangue mineralogy. High sulfidation systems develop from the reaction of hot acidic magmatic fluids with host rocks to produce characteristic zoned alteration and later sulfide (dominantly enargite-pyrite) and Au-Ag-Cu deposition. Ore systems display permeably controls governed by lithology, structure and breccias, typically phreatomagmatic breccia pipes, and should be distinguished from a group of generally non-economic acidic alteration including: steam heated alteration, lithocaps or barren shoulders, acid sulfate, and magmatic solfatara alteration.

Apr 24, 2001

By Hideaki Tokuyarna

Recovery of metal such as V, Ni and Fe from oil fly ash is important for efficient use of natural resources and protection of environment. Leaching of metals from fly ash followed by ion exchange of leached metals has been examined to develop a process which can selectively recover V and Ni from the fly ash. Experiment of leaching with water, HCI, H2S04 and NaOH leads us to propose a two-step leaching process as an effective and mild operation. The first step is leaching with water for removal of Ni, Mg, A1 and Zn and the second step is leaching with acidic solution for the recovery of V. The metals V and Ni are then separated from other metals in each leached liquor by ion exchange. Advantage of this separation process is that acidic leachant can be reused, which contribute to save separation energy.

Jan 1, 2002

By Jun Li

Rate processes of silver cyanidation were studied with the objective of understanding the reaction mechanism. The research was divided into three sections: anodic dissolution of silver in cyanide solutions, cathodic reduction of oxygen on silver surfaces and the direct leaching of silver in oxygenated cyanide solutions. The charge transfer steps plus the diffusion of reactants from bulk solutions to the silver surface were identified as rate-limiting and the rates of both anodic and cathodic reactions can be calculated using the Butler-Volmer equation and Fick's first law. Based on mixed potential theory and the results of electrochemical studies, a comparison of the rate obtained from direct leaching with that predicted from the calculation is made. Calculated results agree well with the experimental data.

Jan 1, 1992